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By M. J. Scoble, L. M. Daneshmend, C. Hendricks

Paper presented at a meeting on: Artificial intelligence in the minerals sector, held in Nottingham, UK, 20 April 1993. An attempt is made to relate emerging technologies to education and training requirements by examining the nature of the Canadian mining industry's human resources. Particular attention is given to the trends evident in mine automation and their likely impact on instructional needs. The characteristics of "computer-aided instruction" systems are reviewed and related to the implementation and support of mine-wide monitoring and communication networks, which are seen as fundamental to the eventual automation of underground hardrock mines

Apr 1, 1994

By B. E. Burakov, S. D. Lupal, O. A. R. Thalhammer, B. Saini-Eidukat

Electric-pulse disintegration is a mineral separation technique that liberates all mineral grains from any igneous or metamorphic rock irrespective of its lithology or grain-size distribution. The normal mechanical crushing of whole-rock samples is replaced by the rending effect of an explosion, produced by applying an electric current from a high-voltage power source. A voltage greater than the 100 kV necessary for the electrical breakdown of rock samples is achieved by using capacitors charged in parallel, but discharged in series. The sample sits in a water bath and the rapid distribution of electric pulses leads to an explosion which occurs preferentially along grain boundaries of the sample. Individual, undamaged mineral grains can be recovered in their original shape and form regardless of grain size. Examples are given of the liberation and concentration of important accessory minerals from different rock types. The examples show the recovery of diamond from two types of non-kimberlitic host rock in Popigai and Kumdykol in Kazakhstan and platinum group minerals associated with chromitites from the Konjdor intrusion and sulphides from intrusions in the Kola Peninsula in Russia

Apr 1, 1995

By I. W. Farmer

High horizontal stresses and high horizontal to vertical in-situ principal stress ratios in the plane of underground drifts and entries can damage weakly laminated roof rocks quite severely. Such stresses are difficult to measure accurately, as illustrated by case histories of in-situ stress measurement at Wistow and Lea Hall mines, in the UK. Their direction and relative magnitude can, however, be estimated from the absolute velocity vectors of continental plates. With the preliminary results from the World Stress Map project now available it is possible to indicate mining areas where regional horizontal stresses are low, such as Europe, and high, such as Australia and Asia

Jun 19, 1905

By L. J. Barnes, R. O. Koch, J. H. Versteegh, C. J. N. Buisman, P. J. H. Scheeren

Several water treatment options have been studied and piloted. A process based on activity of sulphate reducing bacteria combines sulphate removal and heavy metal removal in one process step. The anaerobic bacteria reduce the sulphate to sulphide and consequently metal sulphides will precipitate. The final design for the commercial scale plant is described.

Jan 12, 1992

By A. H. G. Mitchell

Most, if not all, of the six recognised post-Cretaceous, predominantly andesitic mineralised belts in the region are now thought to be subduction-related magmatic arcs. The Inner Carpathian arc and the Eastern Bosnia or Drina-Rhodope arc host numerous vein and replacement deposits with epithermal features and Zn-Pb+/-Ag as the predominant economic minerals. In contrast, the south Apuseni Mountains have produced over 1 600 t Au from epithermal veins but very little Zn-Pb. Recent age determinations and geophysical data from the Baia Mare district of the Inner Carpathians suggest that mineralisation succeeded volcanism by 1-2 m.y. and accompanied crustal extension and the cooling of a large, mushroom-shaped pluton whose boundaries define the mineral district. In the south Apuseni district, mineralisation can be explained by mixing of meteoric with low-salinity metamorphic water expelled during intrusion of mafic rocks into the middle or lower crust. The more continental or cratonic crust in the Drina-Rhodope and Inner Carpathian arcs precluded the input of low-salinity, Au-bearing metamorphic water; the Zn-Pb deposits formed where convecting meteoric water mixed with saline water, possibly introduced through carbonate rocks in the basement

Aug 1, 1996

By H. L. Paterson, R. R. Keays, M. J. Donaldson, D. J. Boyack, M. F. Smith, J. J. Gresham

"Albite-rich sedimentary rocks that contain abundant Fe sulphides occur in the lower portion of the ultramafic sequence at Kambalda and their broadly antipathetic relationship to most of the nickel orebodies is well documented. These sediments generally contain less than 0.1% Ni, but nickeliferous equivalents with 0.3 to >6% Ni occur locally in close spatial association with more typical volcanic peridotite-associated massive, matrix and disseminated ores. Nickeliferous sediments have been mined at several locations at Kambalda but, collectively, they constitute less than 2% of the total Kambalda nickel reserve. The nickeliferous sediments occur both on the ultramafic-footwall basalt contact and within the lower part of the ultramafic sequence, and are usually less than 5 m thick. They are commonly finely laminated rocks with a cherty appearance, composed essentially of layers of albite+quartz±amphibole, alternating with pyrrhotite+pentlandite±pyrite layers. Some contain a minor amount of carbon. The sediments are only of ore grade (> 1% Ni) immediately adjacent to massive Fe-Ni-Cu sulphides, which are interpreted as normal magmatic ores on the basis of geochemistry and the presence of distinctive ferrochromites. The nickel content of the sediments decreases to background levels (<0.1%) within about 20 m of the massive sulphides. In most locations the massive sulphides clearly have been emplaced tectonically within or adjacent to the sediments, which are commonly highly deformed. Typical nickeliferous sediments contain about 1% Ni, 0.1% Cu, 0.1% Zn, 400 ppb Pd, <0.2 ppb Ir and 10-200 ppb Au. They have lower Ni/Cu (average 10), higher S/Ni (average 6) and higher S/Se (average 11 200) than associated massive sulphides (average 40, 4.8 and 7400, respectively). The Pd/Ir ratio of the nickeliferous sediments (typically > 1000) contrasts markedly with that of associated massive sulphides (average ca 16).The high Pd/Ir values are similar to those which have been reported for hydrothermal Fe-Ni sulphides and barren sulphidic sediments of probable volcanic exhalative origin. They preclude a direct magmatic origin for the sulphides in the nickeliferous sediments, though S/Se and S isotope data indicate a magmatic source for the sulphur. The restriction of nickeliferous sediments to within about 20 m of normal magmatic sulphides and the lack of a widespread Ni dispersion halo suggest local redistribution of originally magmatic Ni. This probably occurred by diffusion and hydrothermal mobilization during deformation and amphibolite-facies metamorphism. Although not totally ruled out, a volcanic exhalative origin for the Ni seems unlikely."

Jan 1, 1984

By G. G. Barbante

An understanding of the thermodynamics of smelting copper anode slimes is a prerequisite for improvements to the process. During slimes smelting, a silver-copper selenide matte is formed and subsequently oxidised to silver metal. As part of a series of investigations, molten silver selenide matte was oxidised at 1 100 degrees C with pure oxygen. The chemical potential diagram for the system was developed and used for qualitative prediction of the results of the experiments. A simple, computational thermodynamic model of converting is presented, the adjustable parameters of which were determined by matching the model with the experimental results. The practical usefulness of the model was demonstrated by predicting the effect on silver recovery of smelting temperature and of using either oxygen or air as the smelting gas

Jun 21, 1905

By Y. L. Ding, N. A. Warner

Cylindrical pellets made from graphite and chromite mixtures were reduced in high-carbon ferrochromium melts at 1 600-1 695 degrees C, under an atmosphere of almost pure CO. The reduction rate, as measured by gas evolution, increased with increasing melt temperature and graphite addition and with decreasing pellet diameter or height, although reductant particle size had a very limited effect on kinetics. At a pellet size, heat and mass transfer were significant in controlling the early stages of reduction of large pellets while at chromite grain size, gas diffusion was probably a rate-controlling step. The time required for dissolution of unfluxed pellets into the melts was significantly longer than that for reduction. This indicates that pellet dissolution may be the limiting factor in determining the operating parameters for a proposed new process to produce high-carbon ferrochromium using melt circulation

Jun 19, 1905

By J. A. Finch, D. Lin

The robustness of the large-sections correction procedure, Hill's fast approximation, Barbery's correction and the PARGEN correction was examined by comparing their ability to reconstruct the true liberation distribution using sectioning data from computer-generated spheres. The results indicate that the flexibility of a correction procedure is related to the assumptions it makes about the continuity of the liberation distribution, locked-particle characteristics and ore texture. Overall, the large-sections procedure appeared to be the most generally applicable. The Hill fast approximation performed well, but this was probably because it partially incorporates the sphere model; the performance of the PARGEN and Barbery corrections varied from case to case.

Dec 1, 1995

By F. Tailoka

Bi was electrorefined from alloys containing 10-90 wt% Pb, together with Cu and Ag as minor impurities, in a basic cell and in a recessed-channel cell with 27.5:72.5 NaCl-PbCl electrolyte at 450-470 degrees C and 10 000-20 000 A/m2. The voltage in the basic cell was as high as 9 V, with some carryover of Bi to the cathode observed, whereas in the recessed-channel cell it was as low as 285-635 mV. Flow patterns observed in a room-temperature model indicated that the recesses provide both static liquid hold-up and good mixing of the alloy, enhancing cell performance in combination with the reduced anode-cathode distance of 0.90 mm. The purity of the resulting anode product is as high as 99.9%

Aug 1, 1995

By S. G. Ozkan

An investigation was carried out into the effect of physical parameters, such as particle size of the sample, residence time, solid/liquid ratio and impeller speed in the flotation cell, on the solubility in soft tap-water of colemanite (calcium-bearing borate) from Emet, in Turkey. Solubility increased steadily with residence time from 5 to 20 min but only minimally thereafter. There was a similar increase with impeller speed from 500 to 1 500 rev/min, beyond which a solubility of around 1.05 g/l was again established. There was a slight decline in solubility as the solid/liquid ratio was increased from 1 to 30%, with stable values around 1.05 g/l at a 20% ratio, while a sharp decrease was observed with decrease in size down to the -20 micrometre fraction. The effect of solubility should be taken into account if the application of a wet-processing method is being considered for the ore, while it can also result in losses of material during handling and storage

Jun 21, 1905

By W. D. Maier, H. V. Eales

Paper presented at the IAGOD international symposium on mineralization related to mafic and ultramafic rocks held in Orleans, France, 1-3 September 1993. A lithological and geochemical study revealed significant lateral variation of the interval over 170 km of strike, from about 30 m at the Union Section to 220 m near Brits. The cumulates also become more evolved and leucocratic with distance from the Union Section both towards the NE (Amandelbult) and SE (Impala, Rustenburg and Brits). It is inferred that the persistent heat flux from a putative major feeder zone near the Union Section impaired deposition of felsic cumulates in the vicinity, delaying crystallisation of successive phases in parts of the chamber near the feeder. New influxes were therefore deposited on a footwall of varying thickness and lithology in response to different degrees of crystallisation and accumulation along strike. The development of cyclic units of chromitite, harzburgite, pyroxenite, norite and anorthosite was interrupted at different stages in different parts of the chamber

Apr 1, 1994

By L. J. Cabri

Although no complete mineralogical balances have been published, the background knowledge and proven, highly sensitive analytical techniques to produce them already exist. For PGE-Cu-Ni sulphide ores a combination of ore microscopy, image analysis and electron microprobe analysis with proton microprobe analysis of sulphides for Pd, Rh and Ru and ion microprobe analysis for Pt, Ir and Rh (in some minerals) should provide the necessary data when combined with reliable assays. Other sulphide ores, such as the Cu-Ni-(PGE) ores of Sudbury, Ontario, require a similar approach except that the ion microprobe would be more suitable for the analysis of Pd, Pt and Rh because of its greater sensitivity. Oxide-silicate ores may be harder to deal with quantitatively, although the potential to confirm the presence of trace PGE within silicates and oxides may be greater than in PGE sulphide and Cu-Ni-(PGE) sulphide ores. However, solid solution of PGE in oxides and silicates still requires thorough documentation and evaluation in terms of their significance for the overall metallurgical balance

Apr 1, 1994

During a programme to determine the suitability of the UK site for deep disposal of radioactive wastes, geostatistical methods were used to characterise rock heterogeneity on the basis of seismic and wireline acoustic-impedance data. The data were analysed to yield semi-variogram models that quantified the three-dimensional spatial heterogeneity of acoustic impedance. These models were reconciled with geological interpretations of the area and used to generate simulations of acoustic impedance, with wireline acoustic impedance as conditioning data. The three-dimensional simulated images were compared with actual seismic acoustic impedance. The variography confirmed a vertical zoning effect in the Borrowdale Volcanics, showing that it is caused by preferential clusters of high acoustic impedance values corresponding to regions of relatively low porosity. The method provided realistic three-dimensional models from sparse, one-dimensional wireline data

Jun 19, 1905

By Jinsheng Chen, S. S. Peng

The relationship between support performance parameters and parameters representative of mining and roof conditions is characterised by uncertainty, non-linearity and dependence, so the theory of artificial neural networks was selected as a basis for shield design. A computer program based on a back-propagation training algorithm was written to derive the weighting factors between inputs and outputs from field data; once these had been established two mathematical models were developed to describe the relationship. Back-calculation of field data indicates that the results generated from the neural network models are much more accurate than those derived by traditional methods and can be used with a higher level of confidence. The support density, possible yield frequency of face supports and interval of periodic roof weighting under specific mining and roof conditions can be determined by application of the models

Jun 21, 1905

By M. Moinpour, Y. K. Rao

The catalysed direct reduction of copper sulphide with carbon and lime was investigated in the range 850-1000 degrees C using Cu2S-CaO-C and Cu2S-4CaO-4C reaction mixtures. The effects of the catalytic additives K2CO3, Li2CO3, Na2CO3, NaF, Na2SO3 and the ternary eutectic (K,Li,Na)2CO3 were determined. Potassium carbonate, sodium fluoride and the ternary appear to be the most effective catalysts for the direct reduction process. The rate enhancement of the catalysed carbothermic reduction of copper sulphide in the presence of lime was explained in terms of the catalysis of the Boudouard reaction

Jul 1, 1991

By G. G. Barbante

Anode slimes produced during copper electrorefining are a valuable source of silver, gold, selenium and tellurium. The conventional pyrometallurgical process for treating slimes involves preliminary leaching in sulphuric acid followed by smelting in a reverberatory furnace with fluxes, but it is slow and has many recycle streams. The chemistry of the phases and the reactions that occur in slimes smelting are poorly understood and and this prevents major improvements to the process. Laboratory-scale experiments were conducted using unleached slimes, with and without the addition of fluxes and under neutral, oxidising and reducing conditions. Results show that selenium is readily removed as gaseous selenium dioxide and that molten Cu-Ag-Se-O phases form when fluxes are added. Oxidation-refining of these phases by air injection and flux addition can result in the formation of silver suitable for further electrorefining

Aug 1, 1995

By F. T. Da Silva

Concentrates of titaniferous minerals containing around 30 wt% Ta2O5 are processed hydrometallurgically by hydrofluoric acid leaching and solvent extraction, followed by the precipitation of hydrated potassium heptafluorotantalate. A fundamental study of the thermodynamics of this precipitation and recrystallisation was undertaken to increase understanding of the conditions most conducive to the production of pure, well-crystallised K2TaF7. Activity-pH diagrams for the Ta-K-F-H2O system explained the dissolution of Ta2O5 in fluoride solutions quite well and also the precipitation-recrystallisation of K2TaF7.H2O. X-ray diffraction and scanning electron microscopy confirmed the thermodynamic observations. It was concluded that the best precipitating agent for K2TaF7 from fluoride solutions is KF but a recrystallisation step in a HF environment produces purer, well-crystallised K2TaF7.H2O, eliminating oxy-salts and other impurities

Jun 21, 1905

By L. E. Mordberg, E. N. Nesterova

Geochemical studies of the bauxite deposits show that the primary composition is gibbsitic. Some trace elements were relatively mobile during bauxite formation with the content of Th, U and Zr increasing and that of Rb, Ni and Co decreasing. Y and Pb were relatively immobile during lateritisation; their contents and ratios were inherited from different types of underlying rocks. The supply of Ni and Co took place at the diagenetic or epigenetic stages; their ultimate source was the crystalline basement in the region. The studies support the view that the bauxite was likely to have originated as a result of in-situ lateritisation and not through sedimentary transport and redeposition

Jun 18, 1905

By J. H. Morris, G. M. Steed

Paper presented at Mineralisation in the Caledonides, the Mike Gallagher memorial meeting held in Edinburgh, 27-28 June 1996. Oxygen isotope analysis indicates that quartz, carbonates and muscovite could all have formed in near-isotopic equilibrium with the mildly saline H2O-CO2 ore fluid at 330 degrees C. Calculated values for O, C and S in the ore fluids imply derivation from a deep, homogeneous source region and are consistent with formation either as a direct or an indirect result of igneous processes. Values for delta-O18 plot a little outside the accepted magmatic range, but have almost certainly been modified by exchange reactions with wall rocks. These reactions were also the most likely cause of deposition of the ore constituents. The chemical and isotopic character of the fluid was similar to that in many Archaean and later mesothermal auriferous vein systems, especially the Mother Lode region of California. If the Southern Uplands-Longford Down accretionary complex conceals an Ordovician arc, the tectonic setting was also broadly comparable

Jun 19, 1905