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A comprehensive axial test program has been undertaken at the WASM Dynamic Test Facility on the performance of 20mm threadbar. The threadbar tests had a double embedment configuration, with variation to the encapsulation lengths, debonded length and surface hardware and fixtures to examine failure mechanisms. Performance was significantly affected by the collar embedment length and type of fixture nut used. Results ranged from thread shearing occurring between the nut and bar at 1kJ of energy dissipated, to control plastic deformation of a central debonded length dissipating 22kJ.

May 1, 2009

By Mostafa Benzaazoua

Les remblais en pâte cimentés sont de plus en plus utilisés dans les exploitations minières souterraines. Une autre alternative d?utilisation du remblai en pâte consiste à le pomper et à le stocker dans des empilements de surface. En plus d?avoir des avantages d?un point de vue de stabilité physique des ouvrages, le remblai en pâte cimenté en surface permettrait également de stabiliser les contaminants dans la matrice du remblai à l?aide du processus de solidification et de stabilisation. Dans cette étude, des remblais en pâte constitués d?un résidu minier sulfuré renfermant beaucoup d?arsenic et de différents liants ont été testés afin d?évaluer la stabilisation des contaminants dans la matrice de remblai. La méthode utilisée pour évaluer la stabilisation et la solidification des contaminants est le test de lixiviation en extracteur de Soxhlet. Les résultats géochimiques issus de ces essais ainsi que la caractérisation chimico-minéralogique des remblais lixiviés ont été analysés pour comprendre les phénomènes chimiques présents dans les remblais durant le temps de cure. Les résultats obtenus montrent que les sulfures présents dans les remblais étudiés (pyrite FeS2 et arsénopyrite FeAsS) s?oxydent et provoquent la dissolution des hydrates les plus vulnérables (dissolution de la portlandite Ca(OH)2 et/ou décalcification des gels CSH). Le calcium produit permet de précipiter les sulfates (essentiellement sous forme de gypse plus ou moins hydraté) et l?arsenic sous forme d?arséniates de calcium plus stables. Les différents liants utilisés donnent des résultats différents en termes de stabilisation et de solidification qui seront discutés dans cet article.

Nov 1, 2002

By A. R. Miller, G. Desrivières, T. MacKinnon, H. Bursey, M. C. Bétournay, B. Replogle, D. L. Barnes, P. Laliberté

"A mine production locomotive, the world’s first applied industrial fuel cell vehicle, has been designed and tested in the context of a number of proof-of-concept projects supported by the Fuelcell Propulsion Institute, an international consortium of stakeholders dedicated to facilitate the commercialization of fuel cell vehicles.The locomotive’s simple electric-powered motor and controller system was ideal to study a number of requirements related to fuel cell power application: hydrogen power plant operation, underground hydrogen use, risk and regulatory requirements, production performance versus the conventional battery- powered locomotive version under measured duty cycles and production requirements, power plant design improvements for other fuel cell vehicles, and cost benefit aspects.This article will focus on the design and testing aspects of this project which has led to successful performance demonstrations of the vehicle under surface and underground conditions at two mines. It will also present information on the creation of a safe, reliable, and efficient power plant that fulfilled its design objectives, including longer productivity time for a given vehicle fill-up."

Jan 1, 2004

By Nick D. Rose

The importance of structural geology in open pit slope stability is overlooked in many mining operations due to pressures to cut costs and minimize mine personnel. As a result, mine geology staff are often unable to keep up with geological mapping of the pit slopes due to other day to day production oriented tasks. In some instances, key structural controls that contribute to slope instability may not be identified until after a slope instability has initiated, at which time it may be difficult or impossible to delineate these features in the field. Even for small slopes, understanding the engineering and structural geology of the rock mass, as well as the effects of groundwater and blasting practices, are of key importance to slope stability. Two case histories are presented as examples of mining operations that experienced slope instability with little more than anecdotal information about the structural and groundwater conditions encountered during mining. By conducting field reconnaissance, simple slope stability analyses and ongoing slope monitoring, practical remedial measures were implemented, allowing continued safe mining operation.

May 1, 2002

By C. Peña, C. A. Zaror, M. Bustamante, M. Vega

The goal of this paper is to present the carbon footprint of Chilean cathodic copper, as a function of the electricity generation mix, ore grade, and process efficiency. Ore grades and acid leach-solvent extraction-electrowinning (LX-SX-EW) yields in the range 0.5-1.0% and 60-80%, respectively, were considered here. Additionally, electricity supply from two Chilean suppliers, SING (1.0 ton CO2/MWh) and SIC (0.4 ton CO2/MWh) was assessed. Simulation results show that oxide plants located in northern Chile, served by the SING network, feature carbon footprint within 4.3 - 11.4 MWh I ton cathodic copper, as compared with 3.5 - 9.3 MWh I ton copper in plants served by SIC. The footprint was found to increase as ore wade and process yields decrease.

Jan 1, 2011

By Dale Dean, Bill Hancock, Raul Mondragon, Carlos Aguilar, Chris Martin

"In 1942, commercial mining operations began in what is now the Lucky Friday Ag/Pb/Zn mine in Idaho’s Silver Valley. Wholly owned since 1962 by Hecla Mining Company, the mine has produced more than 145 million ounces of silver and has been a mainstay producer in Idaho’s Silver Valley for over 70 years.However, by the early 21st century, the mill had fallen, technologically, seriously behind the rest of the industry. Accordingly, starting in 2005, the current mill management team set to revitalizing the milling operation. This paper will describe how the mill was systematically evaluated and the aging infrastructure replaced with more current technology. Driven by internal mill review studies supported by QEMSCAN mineralogical balancing, the mill has in recent years been through waves of upgrading – from the installation of new mechanical and column flotation equipment to the introduction of on-stream analysis, a technology well-accepted around most of the industry but alien to this technologically conservative mining district.The experience at Lucky Friday is a testament to the need for ongoing structured mill optimisation and technology upgrading in established mining operations. This paper will describe engineering experiences associated with upgrading equipment in an operating mill, contained in a confined building. Experiences in teaching the team new ways of operating a mill, and finally the metallurgical rewards that have been reaped will be described.INTRODUCTIONMining in Idaho’s Silver ValleyIdaho’s Silver Valley is a 64-km long valley flanked by the US Northern Rocky mountains, seldom more the 3-km wide, and stretching across much of Idaho’s northern panhandle, roughly 150 km south of the Canadian border. Mining has been continuously active in the area for more than 140 years, during which time, the Silver Valley has become one of the richest silver producing districts in the world, and as of 1985 had out-produced the 500 years of production from the famed Potosi district in Bolivia. Since 1885, almost 100 deposits have been discovered and worked in the district (Chapman, 2000)."

Jan 1, 2011

By M. Mononen, J. Huuskonen, M. Vauhkonen, J. Kourunen, A. Lehikoinen

"A new approach to measure process conditions in flotation cells is presented. Real scale flotation cells in a Zinc circuit are imaged using Outotec LevelSense sensors based on electrical resistance tomography. The latest results from long period plant tests show that the sensors together with FrothControl analysis give new information that correlates well with other process parameters. The sensors can compensate for electrical contact contamination using an automatic calibration technique and they are basically maintenance free. The results indicate that using the LevelSense sensors and FrothControl solution, the process control and optimization can be done automatically, stabilizing and improving the metallurgical performance of the flotation process.INTRODUCTIONThe froth flotation process is widely used in mineral industry for the separation of minerals from low-grade ore slurry. Different property parameters of froth and slurry could be measured to monitor and control the flotation process: air bubble size distribution, flow dynamics, thickness of the froth bed, amount of solids in the froth, etc. Some techniques already exist that can be utilized in studying these important parameters on-line. Examples of the techniques are the high-speed video imaging, simple conductivity probes, ultrasound techniques, floats and pressure transducers (Maldonado et al., 2008). These techniques, however, often suffer from some limitations. For example, the video imaging only gives information from the surface of the froth, simple conductivity probes suffer from contamination and the floats may get stuck and therefore do not give reliable signal for process control and optimization."

Jan 1, 2013

By W. M. Scheding

"There has recently been a resurgence of interest in unit flotation of mill discharges. At the Kidd Creek concentrator, this technique has been successfully applied to silver flotation in a 3050 mtpd silver-copper-lead-zinc division. The major incentive has been improved silver payment through increased overall recovery and better distribution between the sequential copper, lead and zinc concentrates. A large, but variable fraction of the silver in the ore is present as native silver and, being dense and malleable, is susceptible to overgrinding. Grinding circuit surveys showed high concentrations of silver in both primary and secondary circulating loads. Laboratory testwork confirmed that this was selectively flotable, identified the secondary ball mill discharge as the best feed stream and optimized flotation conditions. A 10 t/h pilot plant campaign confirmed that the rate of accumulation of silver was sufficient to sustain continuous production of a silver concentrate and that flotation of the whole stream was not necessary.The present 30 t/h production circuit recovers from 5 to 50% of the silver in the ore at a concentration ratio between 25 and 250. The circuit also contributes to a better understanding of ore mineralogy, as an 'on-line' indicator of elemental silver content."

Jan 1, 1985

By G. Ellie, D. F. Coates

"The mining of coal in thick and inclined seams is difficult, and there are only a few countries in the world that are really interested in the problems associated with their exploitation. In France a considerable amount of investment has been made in the mechanization of systems appropriate for such conditions.For seams inclined up to 50 degrees, of normal thickness, a new system was introduced in 1967. It consists of a longwall advancing to the rise with walking props, a shearer and hydraulic backfill. During the first two years the panel productivity was an average of 25 TN/MS, and they foresee the possibility of reaching an average of 30 TN/MS.A system for thick beds, both horizontal and inclined, is in p•rocess of being mechanized. In 1969 they started with a method consisting of a longwall in a footwall slice, or sub-level drifts with walking props, and caving and drawing up to a height of 20 m of coal. Recent experiments with a shearer have produced panel productivities between 9 and 11 TN /MS, and there is hope that with experience an average of 16 TN/MS will be obtained.In 1964 a method was initiated for beds inclined from 60 to 90 degrees, based on a mechanical cutter designed by the collieries in Lorraine. An overhand slice of 4.2 m in height is taken with a drum cutter mounted on the end of a boom. Hydraulic fill is placed at the completion of a slice. The face productivity, which has been from 13-20 TN /MS, can be perhaps increased to an average of 22 TN/MS. For those companies with important reserves in inclined and thick seams, these French systems may be worth the trouble of examining in some detail."

Jan 1, 1972

By Wm. L. Giachino

"Over the last 10 years, C-1-L has played a significant role in the major advances that have taken place in blasting technology, among them the following: development and introduction of capsensitive slurries; development of bulk slurry systems both for underground and open-pit operations; development of the TOE-DET and ANODET systems of delay blasting;introduction of the NONEL system of initiation;development of the Vertical Crater Retreat (VCR) system of mining.This paper identifies areasin which we foresee further developments in blasting technology over the next 10 years and outlines how and to what extent C-1-L will become involved."

Jan 1, 1980

By Jan E. Nesset, Julie Fournier, Jorge Torrealba, Colin Hardie

"Gas dispersion studies have been used to benchmark and optimize plant flotation performance for more than a decade, although this technology is not as widely in use as it likely should be based on the significant improvements that have been reported. Part of the reason may be a general lack of awareness within the industry of just what these improvements have been. This paper reviews a number of the reported case studies, groups them into categories of improvement, and draws some general conclusions. The paper will be of interest to plant engineers and technology providers seeking new approaches and tools for improving their own and clients’ processes.INTRODUCTIONThe sector of flotation hydrodynamics that is now known as gas dispersion technology, and the corresponding terminology, had its beginnings in the 1980’s and early 1990’s in the laboratories of McGill University where the students of Prof. J.A. Finch and Dr. C. Gomez conducted studies of gas holdup, superficial gas rate and water recovery on laboratory flotation columns (Laplante et al., 1983; Xu et al., 1991;, Banisi and Finch, 1994; Finch et al., 1999; Nesset, 2011). Sensors were developed for gas holdup (eg), gas rate (Jg) and bubble size (Db) distribution (Tavera et al., 1996: Finch et al., 1999; Dahlke et al., 2001; Chen at al., 2001; Hernandez-Aguilar et al, 2002, 2005). The sensor measurements were rapidly adapted for use in mechanical flotation machines in plant environments (Gomez and Finch, 2002; Gomez et al., 2003; Cooper et al, 2004; Torrealba-Vargas et al, 2004; Nesset et al., 2007). Somewhat parallel developments were being conducted by Gorain and colleagues at the University of Queensland’s JKMRC on pilot and industrial flotation machines using the McGill approach but utilizing alternate sensor designs for eg, Jg and Db (Gorain et al., 1997, 1999; Schwarz and Alexander, 2006) to link flotation kinetics to bubble surface area flux (Sb). Early industrial applications were those led by the university teams from McGill (Canada), the JKMRC (Australia) and the University of Santa Maria (Chile) at plants in North and South America, Australia, South Africa, Asia and Europe. Industrial organizations that brought the technology on-board in the early 2000’s included Teck Resources (then Teck Cominco), COREM, Vale (then Inco), Anglo American Platinum. Several of the major flotation cell manufacturers also purchased the McGill bubble viewer technology for their own equipment studies. The sensors have continued to evolve with multiple and continuous measurement of Jg (Torrealba-Vargas and Finch, 2006, Bartolacci et al., 2008), gas holdup by acoustic means (O’Keefe, 2007) and a combined Jg-Db device called the Anglo Bubble Sizer (Harbort and Schwarz, 2010). A review of the gas dispersion technology use and development have been provided by Gomez and Finch (2002), Harbort and Schwarz (2010) and Nesset (2010)."

Jan 1, 2015

By Dominic Fragomeni

"The mineral processing industry has had a long history of innovation that is recognized but not often celebrated. These include significant advances in mineral measurement, testing, comminution, mineral separation and process control technologies that have transformed mineral assemblages into ore.This presentation presents some of the major mineral processing innovations and the impact they have had on our industry. As we look to the future, it is critical that we innovate and change. We will explore some examples of the next developments and how they can be catalyzed in the face of risk management, lower metal price cycles, resource constraints, inertia and the challenge of short term value delivery."

Jan 1, 2017

By M. Lahtinen, P. Latostenmaa, I. Kojo, E. Peuraniemi, M. Lindgren, S. Jyrkönen, M. Jåfs

The year 2019 marks the 70th anniversary of Flash Smelting. The technology was operated on industrial scale for the first time at the Outokumpu Harjavalta copper smelter in Finland in 1949. Since then Flash Smelting technology, now owned and developed by Outotec Oyj and the first plant, now owned by Boliden Harjavalta Oy, have been evolving throughout history by optimizing the process for various feeds and raw-materials, as well as through developing the equipment and operating practices. Even though sustainability was not a popular theme during the first days of Flash Smelting, it has still been the key principle in guiding the development. This is well proven by the wide adoption of Flash Smelting for the processing of copper and nickel concentrates, mostly due to its ability to fulfil the economic and resource efficiency criteria demanded by its operators. This paper describes the history and improvements of the Outotec® Flash Smelting process by looking into the early days of operation and how the development of the process and equipment has taken place over time as a joint effort between the technology provider and the users of the technology. INTRODUCTION In the 1940s, Outokumpu Oy refined the concentrate produced in the Outokumpu mine into metallic copper initially in Imatra, and later from 1945 to 1949 in Harjavalta, based on the most modern electrical melting process of the world at that time. After the war, Finland lost a significant part of its hydropower production, and due to the increasing use of electricity, the availability of electricity weakened, and the price rose. To maintain Outokumpu's profitability, it was forced to look for a melting solution that was not based on electricity.

Jan 1, 2019

By G. Capobianco

"The coal industry is an important part of Canada's economy - as an energy source, employer, and generator of export earnings. Coal comprises 71% of our fossil energy and with rapidly advancing handling and burning technology will clearly play a major role in our national energy mix, eventually as synthetic gases and liquids.International coal markets are very competitive and Canada is disadvantaged by long rail hauls to port, and a heavy tax burden. However, high mine productivity has allowed us to increase our markets.Currently, domestic markets are dominated by coal use for electrical generation, a market with significant growth opportunities.Strong growth is expected in export thermal markets, while metallurgical coal demand is projected to show little or no growth in the medium term. IntroductionThe coal industry is a vital part of the Canadian energy scene .• Coal supplies 17% of Canada's energy.• On a per capita basis, Albertans use more energy in the form of coal than they do oil and gas.• The value of Canada's exports of coal last year was equal in value to all the cars we imported from Japan.• Coal is our largest single export to our seco nd largest trading partner, Japan.• The value of coal produced in Canada exceeds the value of any other single mineral produced in thi s country.• In Alberta, the safety record for coal mines is on a par with that of department store clerks.• The coal industry employs about 25% of the total number of people employed in all metal mines in Canada, directly and indirectly accounting for about 50 000 jobs.Coal comprises 71% of Canada' s hydrocarbon energy resources on a crude oil equivalent basis . This is more than double our oil sands resource and dwarfs our conventional crude oil and gas resources (Fig. I). In the short term, coal as a solid fuel plays a significant part in the Canadian energy scene. In the longer term, coal, in the form of electricity and eventually liquids and gases, has a tremendous role to play. In 1986, Canada produced 57.8 million tonnes, slightly down from the record high of 60.8 million tonnes in 1985. Our exports in 1986 were 26.0 million tonnes, a growth of 53% in three years."

Jan 1, 1988

By A. F. Brock

Introduction During the past ten years, shaft sinking has been going on continuously at Inco and new shafts and shaft extensions have been sunk under a broad diversity of conditions. The Murray mine and the Stobie section of the Frood-Stobie mine have?been opened and a main hoisting and supply shaft has been sunk at each of these mines; No. 2 shaft at Murray was sunk initially from surface to 1,960 feet and is now being extended; No. 7 shaft at Stobie was sunk from surface to 3,105 feet. No. 2 shaft at Garson has been extended from 2,200 feet to 3,200 feet in depth. At Levack, No. 2 shaft is being extended from 1,860 feet to 2,850 feet for ore hoisting from the 2,650 lev el. At Creighton, No. 6 shaft, collared on 52 level, was sunk 1,740 feet to a total depth of 5,563 feet below surface. It is the deepest Inco working. At Creighton, also, No. 7 shaft is being sunk from surface to the 30 level to handle the ore from caving operations. Ail Inco main hoisting and supply shafts sunk during the past twenty years have been vertical rectangular shafts equipped with two cages and two ore skips. The cages are standard and interchangeable for all shafts except Garson No. 2; they are single-deck, 13 ft. 4 in. by 5 ft. 2 in. inside and are designed to carry a maximum material load of 16,000 lb. The man load is 48 men. Skip capacities at the several shafts vary from 8 to 15 tons. Forty-two hundred feet bas been established as the standard vertical lift, and the permanent hoisting equipment at each shaft is designed for eventual hoisting from that depth.

Jan 1, 1950

By Henry Stoch

It?s a green, green world ? Public concern about the impact of human activities on the environment and the roles that businesses play in that impact is rising. What?s happened in the last few months? ? Recent news: ? British Columbia announces carbon tax in 2008 budget ? Federal Court ruling stalls oil sands approvals due to a lack of consideration of GHG implications ? US Energy Independence and Security Act could limit government procurement of oil sands-derived fuels ? Western Climate Initiative (WCI) suggests a ?first seller? approach for regulating generators outside WCI jurisdictions ? Implications ? A cost for carbon has arrived ? The lack of a GHG strategy can have a material impact on your business ? Regulations in other jurisdictions could affect your organization

May 1, 2008

"The application of telerobotics to mining is currently being introduced into production systems around the world. Mining companies in Canada, Sweden, South Africa, and Australia have tended to lead the international charge to this form of technology for mining. While this introduction is taking place, a few basic questions have yet to be answered. How many machines can a single operator run? How many types of machines can a single operator run?A Canadian Research Chair in Robotics and Mine Automation has been established at Laurentian University to investigate these questions and many more through a series of experiments in a telerobotics laboratory that connects Laurentian teleoperation workstations to model mining machines at Cambrian College’s eDome. The laboratory supports many experiments allowing researchers to physically run multiple robot scenarios differing the numbers and types of machines at one quarter scale. Further experiments are being designed to investigate the potential for managing time delays in telerobotics. This paper describes the laboratory, experiments, and some preliminary results."

Jan 1, 2005

By K. G. Thorne, M. J. McLeod, D. Hoy

"Throughout the Paleozoic, a variety of gold depositional environments were created in the New Brunswick segment of the northern Appalachians because of the complexity of arc and continental plate collisions and subsequent erosion of the orogen. In southwestern New Brunswick, recent exploration and research has focused on deposits and occurrences that can be broadly classified as intrusion-related, generated by late- to post-orogenic felsic to intermediate plutonic rocks emplaced during the Early to Middle Devonian. This work has led to the establishment of models for gold mineralization and guidelines for exploration in this area, which might also be applicable elsewhere in the southern part of the province and, perhaps, throughout the northern Appalachians. The deposits in the vicinity of Clarence Stream in southwestern New Brunswick exemplify this deposit type, and highlight the emergence of a possible major gold district in the region. Durant le Paléozoïque, une grande variété d’environnements aurifères ont été créés dans le segment néo-brunswickois des Appalaches du nord en raison de la complexité des collisions entre arcs et plaques continentales ainsi que durant l’érosion subséquente de l’orogène. Dans le sud-ouest du Nouveau Brunswick, les travaux d’exploration et de recherche récents se sont tournés vers les gisements et les indices appartenant à la classe des gîtes associés aux intrusions, générés par des roches plutoniques felsiques à intermédiaires tardi- à post-orogéniques mises en place au Dévonien précoce à moyen. Ces travaux ont permis d’établir des modèles de mise en place pour la minéralisation aurifère ainsi que des guides d’exploration pour ce secteur, lesquels pourraient aussi être appliqués ailleurs dans le sud de la province et, possiblement, dans l’ensemble des Appalaches du nord. Les gîtes aux environs de Clarence Stream dans le sud-ouest du Nouveau Brunswick sont un exemple de ce type de gisement, mettant en valeur ce qui pourrait devenir un district aurifère majeur dans la région."

Jan 1, 2008

By Stephen L. Chryssoulis, Stamen Dimov

"Preg-robbing has been known for many years, where increased losses are suffered because dissolved gold is removed from solution by adsorption onto carbonaceous matter. In direct cyanidation circuits it is reasonable to conclude that the preg-robbed gold is either in a gold cyanide [Au(CN) - 2, AuCN] or metallic [Au°] form. However, in circuits with a pre-oxidation step possibilities increase and multiply even further because of water recycle streams containing apparent and not-so-apparent gold ligands. It is in these circuits where speciation of sorbed gold, i.e. the identification of the gold compound, is useful. The importance arises from the fact that proper identification of the sorbed gold species can be used to determine how, when, where and why gold was removed from solution, thereby identifying the exact cause of the problem and providing clues as to how it may be rectified.INTRODUCTIONTo the best of our knowledge, this is the first attempt ever to speciate gold preg-robbed by carbonaceous matter using a surface sensitive microbeam technique. This approach enables the direct determination of gold species sorbed on carbonaceous particulates, opening an entirely new field in the understanding of the chemistry of gold sorption on carbon. The reasoning behind this effort was to add to the current knowledge of the detrimental effect chloride ions have on gold recovery by the pressure oxidation and in particular why in the ensuing CIL step, gold is not being desorbed from the surface of the carbonaceous particles (Table 1)."

Jan 1, 2004

By A. Lewis, J. Zachwieja, M. Widell, P. Zhou, W. W. Geissler, M. Svensson, A. Movahedi, H. Nordberg

Flotation collectors for sulfide minerals has been traditionally based on xanthate, thiophosphate, thiophosphinate and thiocarbamate, all derived from sulfur chemistry. Tecflote™ is a new family of patented collectors based on nitrile chemistry which can supplement or replace thiol collectors, depending on the ore types. A steep grade-recovery curve typical of Tecflote™ collectors was observed when using Tecflote™ as the main collector for the rougher and cleaner steps allowing a better recovery compared to current thiol collectors while maintaining the desired grade. Additional recovery increase has also been observed by the addition of scavenger steps using Tecflote™ collector in combination with current thiol-based collector. The selectivity seen in the lab is transferred to full scale trial and is clearly seen in the rough flotation where the increase in the rough concentrate grade of 5% after pumping Tecflote S11 directly into the tank cell. The mechanisms for Tecflote’s selectivity towards sulfides are currently under investigation and will be discussed. Results of TOF-SIMS analysis will be presented, demonstrating the collector’s selective affinity to different mineral surfaces in flotation. INTRODUCTION The history of collectors used today started in 1882 when Zeise first made xanthates. It was first used in flotation in 1925 – Cornelius Keller’s first patent (Fuerstenau, Jameson, Yoon, 2007). Between 1928 and 1930 American Cyanamid filed 7 patents for dithiophosphate, including flotation and chemical synthesis of the reagent, the first of which was filed by Christmann in 1928 (Christmann, 1933). Synthesize of thionocarbamates for mineral flotation was filed in 1954, by Dow Chemical Company (Harris, 1954). Now that the head grades have been declining over the last decades the need to find more selective collectors to extract difficult and complex ores has pushed the industry to look at different chemistries. Thiol collectors standard to the industry rely on the sulfur in the collector molecule to bond to the mineral surface. The electronic property of this group is modified by the adjacent chemical groups, such as additional S, P or N have the effect of changing the selectivity of the collector (Wills & Finch, 2016). In the case of xanthate the length of the hydrophobic group also has an effect on the selectivity with some minerals such that the ethyl xanthate is more selective against pyrite and pyrrhotite than the long chain xanthates (Wills & Finch, 2016).

Jan 1, 2019