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By Eiichiro Mizushima

Catalyst systems comprising (Ph3P)AuCH3 and acid co-catalysts were found to be highly efficient for hydration of alkynes to give ketones. Methanol was the best choice of solvents. Introduction Hydration of carbon-carbon unsaturated bonds is one of the environmentally benign routes to the carbon-oxygen bond formation. Hydration of alkynes forming carbonyl compounds, an important variation in this category, is a well known reaction which has been extensively studied. The reaction by acid-catalysis is the most conventional method, while it is applicable only to electron rich acetylenes to obtain satisfactory yields (1,2). The hydration of simple alkynes usually requires another catalyst (co-catalyst), typically a mercury(II) salt (3), which is inconsistent with the guiding principle of Green Chemistry (4).

Oct 1, 2003

By M. G. Beukes

"In South Africa most of the large gold mines operate between 1500m and 4500m below surface where reef is accessed initially through a vertical shaft system then via a network of tunnels and mined in either a longwall, sequential grid or scattered mining configuration. Due to the complexity of the ventilation networks used to ventilate these mines and the potential disastrous consequences associated with underground fires, it is of utmost importance that these mines are managed in such a way that underground fires are prevented. However, if they do occur the fires are managed to firstly prevent the loss of life and secondly protect the infrastructure and viability of the mine. The aim of this paper will be to: • Discuss current SA mining legislation regarding underground fire prevention and control. • Examine these fires from a risk management perspective by means of a bowtie assessment. • List and discuss the major Threats and Consequences as determined by the bowtie assessment. • Discuss the various prevention and consequence controls for deep level underground fires. • Examine how to effectively run an emergency control room. From this, a practical way of designing, implementing and managing an underground fire management system is explored. Lastly, the paper identifies new technology and ways of thinking and how these can be used to combat underground fires. INTRODUCTION The orebodies of South African gold mines are generally narrow tabular structures that vary in thickness between 0.8m and 1.2m with an inclination of between 200 and 700. This, coupled with depths of between 1500m and 4500m, as well as the unpredictable geology, creates unique challenges and significantly impacts on mine designs and mining methods. In general, gold bearing reefs are accessed initially through a vertical shaft system then via a network of tunnels and mined in either a longwall, sequential grid or scattered mining configuration (Figure 1). Mining is very labour intensive with very limited mechanisation opportunities and this increases the risk to human life if an underground fire occurs. On 16 September 1986, one of the worst mining disasters in SA mining history took place when 177 mineworkers were killed at Kinross Mine. An acetylene tank sparked flames that swept through the mining tunnel igniting plastic covering on the wiring and the flames also set fire to polyurethane foam. The burning plastic combined with polyurethane and the toxic fumes that filled the shafts caused the miners death. This incident was a stark reminder of the serious consequence that underground fires can have on human life as well as the crippling financial and asset impact for the mining companies. Over the past thirty years, the SA mining industry reduced the number of mine fires significantly by replacing normal timber support with fire retardant treated timber, alternative support systems such as backfill and elongate support and many other fire prevention initiatives. Although the number of fire incidents and number of fatalities due to fires does not show a direct correlation because of various factors, the controls put in place against fires has had an impact on the number of fire and explosion fatalities (Figure 2)."

Jan 1, 2019

By J. G. Kim, B. G. Chae, D. S. Cheon, E. S. Park

The underground structures such as high-level radioactive waste disposal thermal energy storage should be designed and constructed considering thermal-mechanical characterization because of long term and/or cyclic thermal stress. High temperature changes in these structures can extend the existing cracks and generate new cracks in surrounding rock mass. In case of long term and/or cyclic thermal stress conditions, it is possible to lose the function of structures caused by the significant cracks and fracture growth in the rock mass. In this study, the critical thermal crack temperature of the granite, limestone and thermal Kaiser effect were evaluated. Experiments were carried out with the heating speed of 1.5?/min. To avoid thermal shock and target temperatures were set at 150? and 250?. In order to verify the thermal Kaiser effect, the samples were heated by 150 ? after 2-3 repetition to 250?. The generation and growth of cracks were observed through an acoustic emission measuring system. The variation of the physical rock properties was measured before and after thermal experiments. After compared with the thermal experiments using PFC2D, numerical simulations were carried out at higher temperatures (400?). The experiments showed that the initial thermal crack temperature of granite and limestone is about 35?, 32? and the critical thermal crack temperature were about 69? , and 49? , respectively. The experiments confirmed the thermal Kaiser effect of experimented granite and limestone due to thermal cyclic loading. From the numerical analysis, the critical crack temperature showed the same tendency as the thermal experiments. The P and S wave velocity of the sample after the experiment were reduced. Therefore, when heat is applied in long-term and repetitive conditions, these cracks may affect the function and stability of the underground structure. Therefore, further studies of thermal stress effects should be performed.

Jan 1, 2015

By G. de Alva

"Industrias Peñoles S.A. de C.V. (Peñoles) is a private enterprise and is the main silver producer in Mexico. Peñoles is a Mexican Company, and since 1887 ranks as one of Mexico's main natural resources industrial groups.Peñoles Mining Group includes six operating Companies producing mainly gold, silver, lead, and zinc. All mines are underground operations, and the ore is milled in ten concentrator plants near the mine sites. Plant throughputs range from 150,000 to 810,000 tonnes per year.This paper gives a general view of the Peñoles Mining Group, their type of deposits, mining methods, and mineral processing work practices.The paper also discusses some of Peñoles work philosophies and measures being adopted to become more competitive. Due to the small size of the deposits, the mining methods used and size of the concentrator plants are somehow different to those typically seen in large deposits. This could make the paper more interesting.IntroductionIndustrias Peñoles S.A. de C.V. (Peñoles) since 1887 ranks as one of Mexico's main natural resources industrial groups; initially in the mining field and afterwards in the metallurgical, chemicals and refractories areas.Peñoles is integrated as follows: a Mining Group; an Exploration, Engineering and Construction Groups; the Metals Group; and the Chemicals Group.Peñoles is a Mexican Corporation devoted to the location, extraction, industrialization and commercialization of natural resources under its control, performed in an efficient and responsible manner for the benefit of its shareholders, employees and the communities where it operates, through blending and managing a portfolio of sound highly profitable business, offering products and services with integral quality; leaders in their respective fields or with an outstanding presence; technologically and operatively effective, with ecological consciousness and international projection, and an image of prestigious integrity."

Jan 1, 1996

By M. A. Roche

The property of the Hudson Bay Mining & Smelting Company, Limited is located at Flin Flon lake, 85 miles northwest of The Pas, Manitoba, on the Manitoba-Saskatchewan boundary. The area is at latitude North 54°, and is approximately 1,000 feet above sea level. The ore-body occurs in amygdaloidal greenstones, which are to be referred to the earliest basic volcanic flows in the district. It was discovered in an outcrop on a point of land jutting into Flin Flon lake, and subsequent diamond drilling proved that it extends under the lake both to the north and south of the point of discovery. After the taking of soundings from the ice during the winter months, it was estimated that l,000,000 tons of overburden, mainly mud and clay, would have to be removed to expose the underlying ore. Flat diamond-drill holes indicated that the ore-body was separated into more or less independent lenses by horses of unmineralized greenstone, and that in places the overall width, including horses of waste, reached 450 feet. These several] conditions were the main factors influencing the management in their decision to adopt an open-cut method for the mining of the upper portion of the ore-body. Before it was possible to commence stripping operations, it was necessary to dam-off the eastern portion of Flin Flon lake, instal pumps, and de-water the dammed-off area. Dams for this purpose were constructed of mine waste rock and clay filler from nearby hillsides. Material for the bottoms of the dams was taken across Flin Flon lake in hopper-bottom barges. Trestles were then built on the dam bottoms and dams were complete by the time trackage was available. De-watering commenced in April, 1930, and was completed by the latter part of May of the same year. Estimated pump output for the period was roughly four billion gallons. Two Morris 10-inch dredging pumps were used, direct-connected to 250 h.p. electric motors. Individual pump capacity was rated at 3,000 g.p.m. against a 150-foot head. Average head for the operation was 50 feet, which increased the total output considerably. The pumps were mounted on floating barges in cribbings of piling driven at the lowest points in the lake bottom.

Jan 1, 1933

By C. Sideco

"Concentrate drying at the Sullivan Concentrator goes back to 1937 when the original coal-fired dryer was put into operation. This was a second hand 8' dia. x 56' long Struthers-Wells rotary dryer that came from the phosphate plant in Warfield, B.C.In 1962, replacement of the old dryer was seriously considered. The shell and the auxiliary drive mechanism were badly worn and needed replacing. In April 1963, the new 8' dia. x 65' long fuel oil-fired Struthers-Wells dryer went in operation at an installed cost of $174,000.In 1965, it was apparent that a major rebuilding of the dust collecting system would have to be done. A study was carried out and a Ducon Dynamic Gas Scrubber was installed. The system went in operation in November 1966 and has fully met expectations.In the same year, the zinc dryer was converted from fuel oil to natural gas. The conversion has resulted in savings in fuel cost of 12 to 15%.Frame No. 1Zinc Dryer PerformanceDryer Make - Struthers-WellsDryer Size 3/4 8' dia. x 65' long Drum Drive - 100 HPSpeed of Rotation - 5 RPMFeed Rate - 50-65 TPHFeed Moisture - 10-12%Discharge Moisture - 4-6%Dryer Inlet Temperature - 1600-1800°F Dryer Outlet Temperature - 200-250°F Stack Gas Volume - 25,000-40,000 CFNDust Collecting Efficiency - 99.75-99.98% Duet Loss in Stack - 50-300 lbs./day"

Jan 1, 1972

By S. H. Castro

Molybdenite depression by shear degraded polyacrylamide solutions has been investigated. Aqueous solutions of polyacrylamide-type flocculants were subjected to shear degradation under a range of high-speed stirring conditions. Settling tests, carried out with quartz slurries and sheared polyacrylamides, showed reduced flocculant performance with increased degradation. As the sedimentation rate is strongly dependent on the polymer's molecular weight, these results fit well with the shear degradation theory, which predicts the production of shorter chain segments due to breakage of the polymer macromolecules. Microflotation tests on natural molybdenite showed that the depressing ability of a commercial polyacrylamide flocculant remained unaltered after shear degradation, even when the flocculating ability was entirely lost. Practical implications of shear degradation on molybdenite flotation are discussed.

Jan 1, 2004

By Diego L. Romero, Joy P. Romero

"IntroductionThe purpose of this paper is to explain the theory and demonstrate the industrial applications of electrostatic separation. Wabush Mines' use of this type of processing for the concentration of iron ore is unique in the industry. Other minerals are concentrated electrostatically but the process is not widely used.Typical minerals separated by electrostatic separation techniques are:Non-ConductorsAnhydriteApatiteBariteBastnasiteBerylCalciteChrysotileCorundumDiamondEpidoteFeldsparsFluoriteGarnetGypsumHornblendeKyaniteAcmiteAugiteBrookiteCassiteriteChalcopyriteChromiteColumbiteCopperDaviditeEuxeniteFerberiteFrankliniteGalenaGoldGraphiteHematiteMica (Biotite)Mica (Muscovite)MonaziteOlivinePerovskiteQuartzScheeliteSideriteSillimaniteSpheneStauroliteSulphurTopazTourmalineXenotimeZirconConductorsIlmeniteIlmenite-( High Iron)IlvaiteKoppiteMagnetiteMarmatiteMolybdenitePyriteRutileSamarskiteSphaleriteTantaliteWolframiteWulfeniteThe limitations of this process are:1. There must be a difference in conductivity between the minerals being separated.2. The size range must not be very wide.3. The specific gravity of minerals being separated should be similar or the minerals to be pinned should be lighter. 4. The feed must be dry.5. The particle shape should be more or less uniform. 6. The feed must not be high in true middling particles."

Jan 1, 1989

By Gary Walters, Thomas Gonzales, David George, William Davenport, Andreas Siegmund, Suping Yao, Shijie Wang

The previous survey of world copper smelters was in 2016 (Copper, 2016). The copper smelting industry has grown and improved considerably since then, including continuing growth in China and modernization in Japan (Extraction, 2018). Outotec flash smelting and Outotec flash smelting/Kennecott - Outotec flash converting continue to be adopted while newer processes continue to be adopted in China. In addition, some of the world's original flash furnaces have been completely rebuilt (Extraction, 2018). This paper provides recent industrial production data and discusses these new developments. INTRODUCTION A world copper survey was redone in 2016 after a thirteen year lag since 2003. Some of the notable changes were the significant increases in production particularly from China. Since then, several smelters have gone through modernization processes and decommissioning of older technologies. This paper will review the notable changes since the last publication at Cu2016. In the last paper, Copper Smelting: 2016 World Copper Smelter Data, the author gave an audible sigh after observing that copper smelter sites as well as new and notable smelters have been spreading like wildfire in China since 2003. Indeed, seeing is believing. Figure 1 shows the Ningde Copper Smelter (double flashing, 400,000 MT Cu/Year capacity) that started up producing copper in 2018; Figure 2 shows the Nanguo Copper Smelter that is under construction with 300,000 MT Cu/Year capacity (first phase, side blown smelting and continuous top blown converting). We should not only admire the Chinese copper industry’s significant technological developments, but also the copper price support that it has provided throughout this century.

Jan 1, 2019

By J. Stumper

The control of the distribution and movement of liquid water is crucial for increased reliability and durability of PEM fuel cells: whereas the proton exchange membrane requires a minimum amount of liquid water for optimum operation, water excess in the GDL will impede reactant gas access to the catalyst layer thereby reducing performance. In order to understand the relationships between water management on one hand and fuel cell performance and durability on the other, Ballard has been developing a number of minimally invasive techniques that can throw light on the role of liquid water for both cell performance and durability. This paper introduces a novel measurement method that can provide information about the amount and distribution of liquid water under operation. It is shown how the MEA Resistance and Electrode Diffusivity (MRED) method can be used to determine i) the amount of liquid water in the fuel cell, ii) the pure ohmic cell resistance and iii) the O2 -diffusivity of the cathode. Furthermore, through a combination of the MRED method with current mapping it is possible to determine spatially resolved MEA resistance profiles.

Jan 1, 2005

By N. Saracoglu, J. P. Golightly, R. H. Wallis, J. J. Brummer

"The McClean uranium deposits are in northern Saskatchewan, 11 km west-northwest of the Rabbit Lake mine. Their average grade is 1.8% UJ0 8 and they contain 6,350 tonnes of uranium oxide in seven pods of variable grade and mineral assemblage. They are hosted by both basal Athabasca Group and the regolith developed on the underlying crystalline basement. The major mineral facies are: sulphide, arsenide, 'bleached', and hematite, with the important uranium minerals being coffinite, uraninite and pitchblende.Abundances of carbon and sulphur isotopes are consistent with their derivation from pyritic graphite in basement gneisses. Isotopes of oxygen and hydrogen suggest mineralizing fluids were aqueous and at temperatures of about 200°C. Ar39/ Ar40 laser age determination of illite indicates mineralization began about 1300 m.y, ago and that significant hydrothermal alteration ceased about 1170 m.y. ago though Pb/U data suggest the deposits continued to evolve into the Mesozoic.The deposits are interpreted as the result of oxidizing ground water stripping uranium and other metals from either the Athabasca sandstone, especially the heavy mineral layers, or from the regolith, and precipitating these when encountering a warm reduced fluid emanating from the basement."

Jan 1, 1984

By F. Calizaya, S. Bhattacharyya

"This study presents the results of a set of sound level measurements carried out in three underground mines where auxiliary fans are used regularly. Sound levels as high as 100 dB(A) by the workings and 115 dB(A) by the fans were measured in these mines. These levels are quite high even for intermittent noise. Ventilation layouts and best practices used to overcome potential problems related to overexposure to fan noise in underground hard-rock mines are presented here. Factors such as fan type, rotational speed, and silencer-duct arrangements and their effects on noise attenuation are discussed. INTRODUCTION Auxiliary fans are used in hard-rock mines extensively. They are used to ventilate development headings, crusher rooms, conveyor transfer points, and underground shops. They are also used in developing long tunnels and ramps. Depending on the flow requirements and space restrictions, single or double stage axial fans with rigid or flexible ducts are used. Usually, they are high pressure (3.75 kPa) fans with flow rates ranging from 7.1 m3/s to 30 m3/s. The input power varies from 15 kW to 113 kW (Mutama, 2004; O’Connor, 2008). Typically, a 113 kW fan can produce sound levels as high a 113 dB(A) (Howes, 2005). Silencers are often omitted for cost reduction purposes or when used, they are not well maintained. Furthermore, silencers provide limited attenuation depending on their length and type. Typically, the sound attenuation ranges from 10 dB(A) for a 1 × D silencer to 14 dB(A) for a 2 × D silencer, where D is the fan diameter. In a mine, the silencer is subject to wear and tear, especially when the silencer is used in harsh environments. The interior lining can get clogged and the acoustic fill can get covered by dust and diesel soot, thus reducing the silencer performance. Periodic cleaning of the interior casing can increase the attenuation capacity of a silencer by 6 to 9 dB(A) (Dabson & Acuña, 2017). However, this requires a special silencer design in which the inner cartridge can be removed, the sound absorbing material replaced, the inner casing cleaned and the whole set retrofitted. A number of techniques can be used to reduce auxiliary fan noise in underground mines. These range from selecting the right fan for the job to installing adequate silencers. The choice depends on the air quantity requirement at the working place, cross-sectional area of the opening, duct diameter, fan type (axial or centrifugal) and local restrictions. Auxiliary ventilation layouts and best practices used to overcome potential problems related to overexposure to fan noise in underground hard rock mines are presented here. Factors such as fan type, rotational speed, duct diameter, and silencer-duct arrangements and their effects on noise attenuation are discussed."

Jan 1, 2019

By William C. Boggis

EKATI? Diamond mine is located 300km northwest of Yellowknife and 200 km south of the Arctic Circle in the Northwest Territories of Canada. The site is a remote tundra area with continuous permafrost and is in the Canadian Shield. EKATI? is the first diamond mine in Canada and is operated by BHP Diamonds Inc., which is a part of BHP Minerals. BHP Diamonds Inc. is an incorporated company based in Vancouver, BC. The mine is a joint venture of BHP Diamonds Inc. (51%), Dia Met Minerals Ltd. (29%), Charles E. Fipke (10%) and Dr. Stewart L. Blusson (10%). The mining area lies within the 10,960 ha land leases held by the joint venture. The total claim block covers 344,000 ha. To date over 136 kimberlite structures have been identified within the claim. Five of these provide the basis for the present mine plan with three others identified for future inclusion. At full capacity the mine will produce 4.5 million carats per year, approximately 4 % of world production and employ approximately 600 people, with over 33% being Aboriginal from the Northwest Territories.

May 1, 2001

By D. Adiguzel

In this research, providing the sustainability of production quality was aimed for a quarry which is located in Istanbul western part of Turkey and producing concrete aggregates with different types of rock. First, research field was divided in 3 different areas in accordance with the geological differences and parameters that control their product quality, limit values of standards and effect levels were determined. Concrete aggregate conformity tests which are stated in international standards were applied on samples which were taken from these 3 different areas and physical, geometric and chemical properties of each rock type were revealed. The properties of the 3 different types of rock which were produced in the quary were determined and the binary blends were composed. Blending studies were conducted with linear programming technique. In the linear programming model, the cost of aggregate production was aimed to be minimal. The limit values that meet literature and national standards for usability of aggregates in concrete were defined as constraints in the linear programming model and evaluated with objective functions, thus the most suitable aggregate blends were composed. In conclusion, to provide the sustainability of product quality, the most appropriate product blends were composed for the research field and the usability of this model for those quarries were revealed.

Aug 1, 2013

By Joseph Licavoli, Paul Sanders, Yang Yang

"Al-Sc-Zr alloys form thermally stable L12 precipitates which provide high temperature strength. Although the overall fraction of L12 Al3Sc and Al3Zr may be increased by increasing scandium (Sc) and zirconium (Zr) content, such additions may increase primary phase fractions and do not produce desirable secondary phase morphologies. Rapid solidification techniques, such as melt spinning, increase solute atom concentration within the matrix. When the supersaturated matrix is aged, higher precipitate volume fractions at low Sc and Zr levels can be achieved improving high temperature strength. Melt spinning was used to rapidly solidify (107 k/s) a thin ribbon of Al-0.5Sc-0.4Zr at. %. The ribbon was compacted and extruded into 99.8% dense rods, and then aged using multi-step isochronal heat treatment up to 600°C. Precipitation strengthening was evaluated by ambient hardness measurement. The ambient hardness of melt-spun ribbon after precipitation hardening increased by 450 MPa (~67% increment) during isochronal heat treatment.INTRODUCTION Small Sc and Zr additions to aluminum improve strength and creep resistance above 300°C due to tri-aluminide precipitation of Al3(Sc,Zr) in L12 structures similar to ??, Ni3(Al,Ti) in nickel superalloy, but the Al3(Sc,Zr) particles have a Sc-rich core surrounded by Zr-rich shell (Figure 1). The Al3Zr shell limits atomic transport between the Al3Sc core and the matrix and reduces coherency strain. These factors reduce precipitate coarsening rate at elevated temperature (Bergner & Van Chi, 1977; Fujikawa, 1997; Knipling et al., 2011; Clouet et al., 2006).Figure 1. Simplified schematic model of precipitate Al(Sc,Zr) in Al-Sc-Zr alloy. Shell is rich of Al(Zr) intermetallic phase, particle core is rich of Al(Sc) intermetallic phase (after Voorhees, 2006). Numerous Al3(Sc,Zr) particles increase alloy strength and creep resistance as the precipitates impede dislocation glide and to a lesser extent climb. Previous work on ternary Al-Sc-Zr alloys show large strength increases versus binary Al-Sc, and Al-Zr alloys in Table 1."

Jan 1, 2018

By S. E. Malouf, R. Hinse

"The Mineral possibilities of the Chibougamau area were first recognized by Richardson in 1870 and Low in 1885, both of the Geological Survey of Canada. The first record of interest by the Quebec Bureau of Mines is in 1904, when J. Obalski reported on the discovery of copper and asbestos by Peter McKenzie in the previous year. Reports of 1906 and 1907 covered the McKenzie Gold Mine find and other deposits. In 1908 Prof. Dulieux described the quartz vein on Merrill Island and the mineralized zone on the near-by mainland. In 1910 the Chibougamau Railway Commission, though commenting favourably on the possibilities of the area, concluded that a railway was not then warranted.In spite of this, prospecting in the district continued. The main Campbell Chibougamau deposit, the Blake showing on Merrill Island in Dore Lake, was found in 1920, and other discoveries were made soon after. Between 1927 the work of Mawdsley, Retty, and Norman tor the Geological Survey and the Quebec Bureau of Mines stimulated further interest. In 1934 Consolidated Chibougamau Goldfields Ltd., a subsidiary of Consolidated Mining and Smelting Co. of Canada Ltd., acquired the Merrill Island and Cedar Bay holdings of Chibougamau Prospectors Ltd. They embarked on an aggressive campaign, directed essentially at the gold quartz veins at Cedar Bay. Exploration there included a 522-foot shaft, 4,732 feet of drifts and crosscuts, and about 34,000 feet of surface and underground diamond drilling. Thirteen holes were also drilled on the replacement sulphide lens at Merrill Island. Operations were suspended in 1936, as the occurrence was too low grade for development at the existing metal prices and under difficult operating conditions.The completion of the Quebec Bureau of Mines highway from St. Felicien to Chibougamau in 1950 was followed by a project of detailed geological mapping by the Bureau. It also encouraged Campbell Chibou-gamau Mines to acquire the assets of Consolidated Chibougamau Gold-fields and commence a program of surface exploration. Between August 1950 and April 1951, 41,183 feet of diamond drilling was done on the Cedar Bay and Merrill Island holdings. The Blake showing off the west shore of Merrill Island developed at depth into a major orebody. A lease was obtained on adjacent ground from Merrill Island Corporation, and underground work commenced in November 1951. Development at Merrill Island to June 1st, 1955, included a four-compartment shaft to 1,225 feet, with 8 levels at 150-foot intervals, 5,317 feet of raises, 16,709 feet of drifts and crosscuts, 52,514 feet of surface and 96,593 feet of underground diamond drilling."

Jan 1, 1949

By László Guczi1

Nanosize model gold particles with varying size were fabricated by deposition of a 10 nm thick gold film onto SiO2/Si(100) substrate by electron beam evaporation followed by modification using low energy Ar+ ion bombardment. The change in particle size were monitored by the Au 5d valence band states determined by ultraviolet photoelectron spectroscopy (UPS). The gold/iron oxide interface was studied by iron oxide deposition on gold. It was found that the energy profile of Au 5d valence band states are strongly redistributed with decreasing the gold particle size mostly affecting at the lowest and at the highest binding energies. The size effect in the UPS spectra can be interpreted by the energy redistribution rather, than by narrowing the 5d states. The iron oxide deposition increases the catalytic activity in CO oxidation whether it is on gold nanoparticles or on a continuous 80 nm thick gold film. The activity enhancement is significantly larger in case of gold nanoparticles. The interface interaction is operative in enlargement of the catalytic activity even if gold particles are not exposed to the surface, but they are located below the iron oxide layer.

Oct 1, 2003

By D. B. Dreisinger, M. R. Tavakoli

Vanadium has been produced from both primary and secondary sources having various compositions. Vanadium pentoxide and vanadium trioxide are the most available and known sources of vanadium oxides. In this paper, an overview of leaching both oxides has been reported. The problem of vanadium pentoxide leaching under acid conditions is the low solubility of the dissolved vanadium. This was investigated and then supplemented with further studies of leaching at mildly basic pH’s as well as under acid reductive leaching conditions (to form vanadium (IV)). Atmospheric oxidative leaching of vanadium trioxide was investigated using oxygen and ferric ion as the oxidant. It was shown that the leaching of vanadium trioxide using oxygen is very slow; however, ferric ion can dramatically increase the kinetics and leach efficiency.

Jan 1, 2014

By M. Pötsch, A. Kluckner, P. Söllner, W. Schubert

"The in situ block size is a key parameter in the geomechanical characterization of rock masses. It describes the fracturing of the rock mass and thus is a measure for the degradation of the rock mass strength. Several classification systems use the in situ block size. For instance, the Geological Strength Index (GSI) requires the “blockiness” and joint surface condition factor as key input parameters. The “blockiness” has recently been related to the in situ block volume (Cai et al., 2004). Due to the limited information about the internals of a rock mass, it is not possible to determine the in situ block size directly. Currently, the in situ block size is determined by calculations using oversimplified models, vague estimations or, due to the lack of relevant information, it is neglected. As remote measurement systems have become available for rock mass characterization, a more comprehensive record of discontinuities can take place. Measurements can be performed on exposed rock outcrops and in particular on tunnel faces and walls, delivering the location, orientation, spacing and persistence of discontinuities at an arbitrary number and locations. An estimation of the in situ block size at the same level of sophistication is still not available. This paper aims at examining the relationship between visible and measureable information at the rock surface, and the in situ block size. Three-dimensional block model simulations were performed using the block model engine of the distinct element code 3DEC. Initial investigations focussed on the minimally required observation area in order to obtain reliable block size distributions. Based on a representative volume element, a reference distribution of the block area at the observation area for a specific discontinuity system was determined. Subsequently, the size of the observation area was decreased stepwise and each new distribution was compared to the reference distribution. For all analyzed systems, it turned out that the mean block area must be smaller than 1% of the observation area to achieve a reliable block size distribution. Further simulations focussed on discontinuity systems with three non-persistent sets. The results were compared to the formula proposed by Cai et al. (2004). A transformation factor T was introduced which replaces the persistence terms in Cai et al.’s proposed formula. The factor describes the correlation between block volumes generated by persistent and corresponding non-persistent discontinuity sets. The simulations included the variation of the discontinuity set spacing, persistence, and orientation. The mean and additionally the 25%-, 50%- and 75%-quantiles of the block size distribution were analyzed. Examining all values for the transformation factor the distribution can be described by a power function with a negative exponent. The function depends on the persistence only. Finally, the results of random simulations were compared to the analytical formula using the transformation factor. The predicted mean and selected quantiles show a good agreement with the simulation results. It gives a comprehensive picture about the block size distribution in discontinuity systems with three non-persistent sets."

Jan 1, 2015

By Andre du Preez

Emergency Fall Arrest System Rio Tinto?s Primary Objective: ?To achieve repeatable controlled safe deceleration rates during emergency fall arrest activation (Ontario OHSA Regulations) ?Must operate effectively on mine specified steel shaft guides.

May 1, 2013