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By Philip J. Bangerter, Chris Twigge-Molecey

Design for safety is critical to metallurgical plants, due to the inherently dangerous nature of their processes. Two significant areas of concern are: 1. preventing catastrophic process failures that cause damage or injury; and 2. operational safety that directly affects those working in or living near the plant. Process safety involves human behaviour, but the designer can eliminate or control hazards by engineering approaches, and control impacts through the design of the operating procedures. The tools available to guide safe facility design include bowtie analysis, hazard analysis, and hazard and operability studies. Clean plant design principles can guide the design process to address in-plant occupational health and safety issues. Auditing and review is a key part of the overall design process.

Jan 1, 2015

By Zhibao Li, Lanmu Zeng

The behavior of dicalcium silicate in NaOH-NaAl(OH)4-Na2CO3 solution is of significance for controlling the silica level in the production of alumina via the sintering process. Dicalcium silicate samples were obtained through a twostep approach: coprecipitation of calcium and silicate from CaCl2-Na2SiO3-NaOH solutions; and calcination of the hydrated precursor at 1200°C for 4 hours. The optimization of the synthesis parameters including temperature, solution concentrations and aging time was also investigated. Xray diffraction (XRD) and chemical analysis show that the calcined solids include dicalcium silicate with trace amounts of wollastonite. The solubility of the synthesized dicalcium silicate in HCl, NaOH, mixed NaOH-NaAl(OH)4 and NaOH-NaAl(OH)4-Na2CO3 solutions was determined. It was found that the solubility increases with increasing HCl and NaOH concentration. The effect of temperature on the solubility in HCl solutions is limited, but the solubility decreases with increasing temperature in NaOH solutions. The solubility of dicalcium silicate in NaOH-NaAl(OH)4 and NaOH-NaAl(OH)4-Na2CO3 solutions was shown to increase with increased temperature, Al(OH)3 and Na2CO3 concentration. The BromleyZemaitis model for the aqueous electrolyte system was selected to predict the solubility of dicalcium silicate. The model’s predictions yielded certain success compared with experimental solubility data.

Jan 1, 2014

By D. Marotte, M. David

"A new exploration procedure is proposed for volcanogenic massive sulphide deposits of the Abitibi belt. ""Samples"" of acidic volcanic rocks (Si02 > 60%) were compiled from the literature. From the 574 samples collected, 322 were used in each of a number of experiments. Forward inclusion linear discriminant analysis performed on the untransformed geochemical data shows a general depletion in Na20 and CaO along with an enrichment in MgO for a ""proximal"" group of samples relative to a ""distal"" one. The percentage of misclassified samples reaches 20% to 30%, but test sets shows good stability.The exploration procedure was applied to the Normetal deposit, where the authors took 160 samples during the summer of 1977. It quickly leads to the definition of targets for more detailed exploration together with a good recognition of the old known deposit.IntroductionVolcanogenic massive sulphide deposits in the Abitibi belt (Quebec) are mainly found in rhyolites or acidic pyroclastics in the uppermost portion of a calc-alkaline volcanic series (Descarreaux, 1972). The deposits are thought to have formed syngenetically by the action of volcanic hydrothermal exhalations during the waning episode of a felsic volcanic cycle (De Rosen Spence, 1976). Alteration pipes of disseminated sulphides are commonly present. Metal deposition from hot springs, initiating convection cells in a submarine environment, may have been the dominant process in ore formation (De Rosen Spence, 1976)."

Jan 1, 1981

By John A. Legge Jr.

"ACCOMPANYING Alberta's great natural endowments of oil, wheat, scenery, fishing, and hunting is also a generous endowment of geophysical problems to plague the interpreting geophysicist. These problems — by no means unique to Alberta — are sufficiently numerous and outstanding to be of major concern in exploration. Some of them have been adequately solved, others are well on their way to being solved, and still others remain almost completely unsolved. Often a problem readily solvable in one area can be solved only with great difficulty in another. Many are closely allied with the geological conditions and require the best co¬ordinated efforts of the geologist and geophysicist for their solution.It is a fairly general practice to study rather carefully the geophysical characteristics of known producing reefs in order to obtain data on which to base an interpretation of unproven areas. This practice obviously has a very sound basis, for, as discoveries become more and more widespread in the Alberta basin, it is found that the variation' in geological conditions has a marked effect on the seismic results, as would be expected. By carrying this analysis over an area it is possible more and more to anticipate the geophysical picture which should be obtained in connection with reefing under the varying geological conditions. Another phase of this procedure, and one that has received less attention, though it is certainly of importance, is the analysis of the all too numerous failures. A study of these failures may be more fruitful than a study of the successes for it may indicate weaknesses of field procedure, computations, or in¬terpretation not particularly obvious in the discovery areas. These studies must not only include the geophysical characteristics of the observed `anomalies', but should also be coupled with a thorough geological study to ascertain whether some unanticipated geological condition is responsible for the erroneous geophysical interpretation."

Jan 1, 1953

By K. Murase

Potentiostatic electrodeposition behavior of dendritic copper from acidic copper(I) chloride (cuprous chloride) baths containing sodium chloride and sodium bromide was investigated. The morphology, or appearance, of copper dendrite and the sodium content in the dendrite as an impurity were both influenced by deposition potential (0 to ?150 mV vs. SHE) and bath temperature (R.T. to 60 C), while the current efficiency for the deposition was 99% or more irrespective of the deposition conditions examined. The bath pH did not affect the deposition behavior in the pH range of 0 to 2. Bath temperature was found to be the most important factor influencing the deposition current. The current density of the dendrite deposition on a titanium cathode was lower than that onto a copper cathode with the same substrate surface area. The reproducibility of the current for the dendrite deposition was poorer when an as-polished titanium cathode was used, although it was improved by surface treatment of the cathode with an HF-HNO3-H3PO4 solution before electrodeposition. The deposition behaviors were discussed with the potential-pH diagram of the Cu-Cl-H2O system.

Jan 1, 2007

By L. E. Djingheuzian

"ForewordTHE FOLLOWING excerpt is taken from Fine Grinding Investigations at Lake Shore Mines (C.I.M., Trans., Vol. XLIII, 1940, p. 307):""MacCalman, who has carried out exhaustive testing on the accuracy of screen analysis, makes the following statement in his report, The Accuracy of Sieving Tests, Industrial Chemistry (London, England), Vol. XIV, p. 231:"" 'It will be shown that, as no specific relationship between the sieving value and the various dimensional features of the sieve is evident, though there is an apparent tendency for the sieving value to follow the average aperture size, it is apparently impossible to define the sieving value of a screen from dimensions alone, and the calibration of sieves for important tests on a specific material, whereby the sieving values of these sieves are related to that of an arbitrarily chosen master sieve by correction values, will be recommended."" 'It will be emphasized that these correction values are probably not applicable to other materials, or the same material of different size composition. Sieve users, for important tests or in cases of dispute, will be recommended to calibrate their sieves against a mutually acceptable standard with specified conditions of test, and to recalibrate at intervals' ""."

Jan 1, 1953

By Qing-hua Tian, Li-then Cheng, Xue-yi Guo

In order to recycle valuable metals from silver separated residue, a novel method using alkaline smelting at low temperature was proposed. The main factors affecting the main metal recovery such as the smelting temperature, smelting time, liquid-to-solid ratio and alkali addition were investigated comprehensively. The behavior of the main metal elements, such as Pb, Sn, Sb and Bi in silver separated residue was also discussed. The results indicated that amphoteric metals such as Pb and Sn can be smelted into the melt, while other metal elements, such as Sb and Bi were left in the residue.

Jan 1, 2011

By George Meadows

Consultation and Accommodation Introductions Consultation -Best Practices The Role of Negotiations The HVC Experience Summary / Conclusions The Challenge Meeting legal and policy obligations to consult while adhering to project priorities, timelines and budgets Defining who needs to be consulted, by whom, and ?how much?? Accommodation ?who is responsible and what is the appropriate scope? Social License -establishing positive working relationships with First Nations involved in project review / approvals / implementation in a manner that advances the interests of all parties

May 1, 2010

By E. Thune, F. Stålesen, E. O. Stensholt, O. M. Dotterud, E. E. Henriksen, P. O. Ramsdal

"The development and commercial operation of the Falconbridge chlorine leach process have been described in papers in 1985 and 1987. Since this time, various process improvements have been implemented and the capacity of the Kristiansand refinery has been increased to 85 000 t/y Ni, 40 0000 t/y Cu and 4500 t/y Co. The focus has been on continuous improvements in productivity, the use of energy and other costs. Several environmental issues have also been eliminated or reduced since 1987. IntroductionThe first nickel refining operation in Kristiansand, Norway, started in 1910 based upon raw materials from Norwegian mines. In 1929, Falconbridge Nickel mines purchased the refinery to acquire information and the patent rights to the Hybinette refining process that was practised at the small Kristiansand refinery. Falconbridge ownership has now, for more than 70 years, provided a strong base regarding raw material supply, financial resources and technical support for further expansions and major technical improvements at the refinery.The main concepts of the new chlorine leach process were developed in the laboratories from 1966 to 1969 and the process was piloted from 1970 to 1972. The main stages in the commercial plant were started in the 1975 to 1981 period. After 1981, there have been a number of process modifications, plant expansions and improvements to operating practices. The developments up to 1988 have been described in previous publications (Stensholt et al., 1986, 1988).This paper presents an overview of the process and how it is practised at Falconbridge Nikkelverk AS (FNA) today and describes some of the main changes that have been implemented since 1988. During this time, the nickel capacity has been expanded from 54 000 t/y to 85 000 t/y and the cobalt capacity from 2000 t/y to 4500 t/y. The paper describes how these expansions were achieved together with continuous improvements in operating efficiency and also gives an overview of the main environmental concerns at the refinery."

Jan 1, 2001

By Min-Sung Kang

Excavation and earthmoving equipment mostly operate in accident-prone areas. These areas normally have rollover, confinement, and fall or may be considered harmful work areas due to demolitions and sewage removals. It is inevitable that excavation and earthmoving systems should be developed to secure the safety of operators through unmanned and remote control systems. Therefore, this research proposes a system that enables excavators to be unmanned and remote controlled without any renovation, remodeling, change, or transformation by applying attachable and separable mechanism and modules. Moreover, this research proposes the sensor module to evaluate the dynamic status without processing remodeling or transformation the existing hydraulic drive excavation system by adopting the easy attachable and separable mechanism. The study verifies this proposal based on observed possibility and feasibility through the experiments.

Aug 1, 2013

By S. R. McCutcheon

"The regional stratigraphy of the Lower Carboniferous Windsor Group in the Moncton Subbasin indicates that evaporites could be present in the Marysville Subbasin, part of what was formerly called the Central New Brunswick Platform. The Windsor Group consists of basement-fringing, algal build-ups (Gays River Formation), in places with intercalated siliciclastics (Parleeville), which are laterally equivalent to deeper-water, very thin to thinly bedded, euxinic limestone (Macumber). The Macumber is overlain by stratiform, nodular to mosaic anhydrite (Upperton) that is hosted by carbonate or calcareous siliciclastics. The sulphate also is equivalent, in part, to the algal buildups. Deep-water salts (Cassidy Lake) which overlie and in places are laterally equivalent to Upperton rocks have a basincentre distribution. The Windsor Group is overlain by shallow water evaporites and mudstones (Clover Hill) or by greenish grey mudstone (""transitional beds""). The paleogeographic distribution of these rocks provide important clues that help predict where deposits of salt and potash can occur.IntroductionCurrently there are three known potash deposits in southern New Brunswick (2, 3 and 4, in Fig. I). All three deposits occur in the Windsor Group of the Moncton Subbasin, but until recently their exact stratigraphic position within the group was not known.The Windsor Group is a cyclic sequence of carbonates, evaporites and red beds that is up to 1.0 km in thickness (Schenk 1969, p. 1038). It is Late Mississippian (Visean) in age and the type area is near Windsor, Nova Scotia. The group was named by Dawson (1873) but the rocks were described earlier by Hartt (1867). Dawson (ibid.) was the first to assign rocks in southern New Brunswick to the Windsor Group."

Jan 1, 1983

By K. Kudo

Magnesium rods of 99.95% purity and approximately 6 mm in diameter were continuously cast at rates of between 15 and 25 mm/min by a heated mould process and their mechanical properties evaluated. It was found that rods cast at 15 and 20 mm/min consisted of a single crystal, while rods cast at a speed of 25 mm/min were multi-crystalline and showed a unidirectional structure. Although room temperature tensile ductility to fracture varied widely, it was found that with an appropriate crystal orientation, cast rods can exhibit elongation by as much as 215%.

Jan 1, 2006

In-Country Business Development Agenda ?Siting/Permitting/Operational Planning ?Securing, maintaining, enhancing social license to operate ?Biodiversity conservation and ecosystem services ?IFC Performance Standards ?Environmental, Social, Risk Governance (ESG) ?Climate change plan

Aug 1, 2013

By Hans Lundberg

An electric survey from a 'plane flown over the ground is much faster and cheaper than an electric survey carried out on the ground. The results are obtained as continuous recordings that are resolvable into both a depth expression and a conductivity effect, so that the indications are easier to evaluate, as well as to correlate from one flown line to the other. The prospecting technique adopted in our electric airborne surveys may be brie fly described as follows: A loop of many turns of insulated copper cable is fastened around the fuselage of the 'plane and connected to a generator supplying a few ampere alternating current, usually of a frequency less than 1,000 cycles per second. Just as the current in the primary coil of a common transformer will induce current in the secondary coil when shorted, the alternating magnetic field from this primary current now induces alternating current in electric conductors that happen to be located in the vicinity of the path over which the 'plane is flown. This induced secondary current in each conductive section of the ground causes, in turn, an alternating magnetic field, secondary field, which disturbs or dampens the normal alternating magnetic field from the primary loop flown by the 'plane. These secondary fields are then picked up and recorded by the help of detecting solenoids, amplifiers, and recorders carried in the 'plane. By closer study of such a secondary field it is possible to localize the secondary current causing it and, thereby, the conducting body that contains the secondary current. In the 'plane are continuously recorded, besides the amplitude or intensity of the field, also the phase, which is a measure of how much the recorded secondary field is out of step with the primary field.

Jan 1, 1950

By P. O. Parfitt

The Critical Path Method has proved its usefulness at Mcintyre Porcupine Mines Ltd. This paper illustrates the techniques of network construction and analysis, and the application of the method at the Mcintyre copper mine to various projects in the gold mine. C.P.M.'s use in a mill maintenance project is also discussed.

Jan 1, 1966

By Candido Bariáin

A new vapochromic material of formula [Au2Ag2(C6F5)4(bipy)2]n (bipy = 2,2´ bipyridine) has been developed and used for the detection of some volatile organic compounds as acetone either in vapour or in water solution. The material is presented in the form of powders which colour changes with acetone vapours turning from bright yellow in the absence of vapour to white in the presence of vapour. By using the sol-gel technique, the powder ? dispersed in tetraethyl orthosilicate- was easily deposited on optical fibres. In order to study experimentally the behaviour of this material for construction practical optical fibre sensors, a sol-gel material doped with the vapochromic material is deposited onto an extreme of a monomode fibre connected to a coupler. The behaviour of the material was studied for different wavelengths and concentrations of acetone vapours and acetone/water solutions. Changes up to 4dB in the reflected optical power were detected. Optical fibre sensors have many advantages over conventional ones, such as electromagnetic interference immunity, passivity behaviour, possibility of using multiplexation techniques, low weigh and little size, etc. Actually, there is an increasing interest in developing optical fibre sensor for vapour detection in the chemical industry and in fact many sensor had been developed [1]. Some are based on the deposition of a sol-gel-based material either over the core of an optical fibre [1] or onto the thinner zone of a biconically tapered optical fibre [2]. Others are based on Fabry-Perot interferometers [3]. Also there are sensors based on the reflection of the light on films, on the fluorescence of dye-doped polymer cladding in fibre, on colorimetric reagents in the core of a silica fibre or on surface plasmon [4]. The possible materials for the construction of such sensor should be colorimetric reagents able to change the colour or refractive index in the presence of same organic vapours. There are not many metallic complexes with these properties, although same interesting examples have been reported in the chemistry of palladium and platinum as [Pt(p-R-C6H4NC)4][Pd(CN)4] described by Nagel [5] and Mann [6], which reported the construction of some LEDs. We recently reported the preparation of a novel vapochromic material (Fig 1) [7] which can be used for the construction of optical fibre tapered environmental sensors [8,9] of vapour organic compounds (VOC´s). Also we reported other nickel and palladium derivatives which present this type of behaviour [10]

Oct 1, 2003

By Owsiacki. Leo

Both the 8 and A-C ore zones of the Heath Steele Mine contain extensive areas of brecciated ore. This texturally distinct ore type has been tentatively defined as a fragmental or conglomerate massive sulphide. It consists of subangular and round fragments of pyrite up to 30 em in diameter, smaller quartz clasts and chloritized, mineralized, lithic fragments in a faintly banded matrix of pyrrhotite and chalcopyrite. The chalcopyrite is concentrated in the pressure shadows of the fragments and appears to reflect remobilization and recrystallization during a deformation which postdates the formation of the clasts. A generally conformable relationship with the underlying banded pyrite-sphalerite ore, discordancy with the host banded argillites, spatial distribution and similarity to Kuroko ores suggest that the fragmental ore is of primary origin and that breccia formation is probably due to soft-sediment slumping or sliding initiated by volcanic explosions, as hypothesized for similar massive sulphides in various Japanese mines. It is nevertheless recognized that certain structural features in some clasts may result from deformation preceding the formation of the breccia, and at this stage a tectonic origin cannot be completely eliminated.

Jan 1, 1979

By Umbreen Agha, Stephan L. Chryssoulis, A. Margaritis

"The deportment of gold in samples of the biooxidation feed and product from the Harbour Lights mine in Western Australia was determined using optical microscopy and microbeam techniques such as Secondary Ion Mass Spectrometry (SIMS), Time-of-Flight Laser Ionization Mass Spectrometry (TOF-LIMS), and Electron Probe Microanalysis (EPMA). The main objective was to determine the mechanisms by which acidophilic bacteria (Thiobacillus ferrooxidans) liberate refractory gold which is locked in a sulphide minerals host as visible gold inclusions (> 0.1 µm) and as submicroscopic or 'invisible' gold.Using the integrated mineralogical approach approximately 99% and 100% of the assayed gold in the biooxidation feed and biooxidation product was accounted for. The results were compared to and verified by chemical assays.The gold deportment study indicates that during biooxidation, locked visible and 'invisible' gold is rendered cyanidable by the direct action of Thiobacillus ferrooxidans as well as indirect chemical leaching. Visible gold which is enclosed in sulphide minerals is liberated or partially exposed and is therefore rendered cyanidable as the host mineral is oxidized and dissolved. 'Invisible' gold either coalesces on the surface of the host sulphide mineral as the particle is dissolved or is released into the liquid phase and immediately adsorbs onto the surface of other ore particles with a net negative charge.The shakeflask suspension indicates that direct bacterial oxidation pits and channels correspond to zones of 'invisible' gold and arsenic (in pyrite) enrichment in the host sulphide mineral."

Jan 1, 1996

By Randolph A. Pax, Brian Cornish

The operation of grinding mills in an ore processing circuit is supported by monitoring the input and output variables. These can include the feed ore size distributions, ore feed and water addition rates. The outputs can include the discharge undersize density, oversize tonnage rate and the P80 of the discharge. The grinding mill performance is judged by the power draw, recycle rates and discharge grind size. Conditions inside the mill are inferred from loads cells or bearing pressures and past histories. An overall noise value is sometimes used to evaluate the load as well as the occurrence of excessive impacting of steel balls onto the liners/lifters of the mill. This paper presents results of the internal behaviour of a mill using non-contact stationary microphones located close to the mill outer shell (Pax, 2012). The noise generated by a mill can be attributed to a number of events that occur inside these mills and suitably analysed can provide real-time determinations of in-mill behaviour and can provide powerful insights into the operation of the primary comminution tumbling mills. The acoustically determined signals including a specific 'steel' signal, water hold-up, integrated area together with a classification of impact events. Specific results from case studies will show information of the trajectories inside a mill, steel to rock ratio as well as rheology effects. By incorporating a self-consistent understanding methodology for the in-mill processes from an array of microphones, the information can be used to diagnose the dynamic conditions inside a mill.

Jan 1, 2016

By K. Sakai, M. Miyaue, T. Aoki, T. Tani, S. Tanaka, N. Kudo

In the planning stage of a tunnel, due to limited technology in the geological survey and the financial restriction, tunnel supports are often designed from unsatisfactory information, and the tunnel construction is started. Therefore, "Information-oriented construction" is carried out in the construction stage, in which the design is rationally verified and modified by observations/measurements. Moreover, the ground conditions ahead of a tunnel face must be predicted for efficient and safe tunnel construction. The authors have examined effective prediction methods to the ground conditions ahead of a tunnel face under construction of mountain tunnels (Aoki et al., 2010) in view of the established method (Schubert et al., 1995). Though the prediction method of Schubert requires the displacement in the direction of tunnel axis, it is difficult to obtain its accurate data by the electronic distance meter. Then, we have proposed a method that uses tilt sensors installed at the tunnel crown near the face to obtain the slight tilting information. To measure inclination of the tunnel crown, this inclinometer was originally developed as a daily control measurement, such that the geological condition and its possible change behind the face could be detected early, and a steady advance and construction safety could be ensured. This paper describes the method of forward prediction mechanism and advantages of this suggested method. It then presents the typical results of a field verification test at a tunnel under construction and an example of evaluation of the ground conditions ahead of the face based on the 3D numerical analysis in three types of condition changes of ground deformation moduli.

Jan 1, 2015