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By H. Oterdoom, S. Pilger, T. P. Bui, J. Rotarius

"Most FeNi furnaces used to rely on post-combustion and off-gas cooling inside the furnace to eliminate the produced CO gas, and control the off gas temperature. As furnace load, capacity, and thus gas volumes increased over the years, this led to increased instabilities that can cause problems in controlling the operation. Some of the large capacity furnaces nowadays work with partial or full combustion outside the furnace, more similar to the steel industry. Forced combustion with or without enriched air and other additions can support in controlling post-combustion, stabilizing and even reducing off gas amounts, and affecting composition. This paper presents some of the possibilities and advantages of having a specially designed post-combustion system for the FeNi laterite industry, but that could also be applied to other processes as well.Large Scale Furnaces In the FeNi industry, the Rotary Kiln Electric Furnace (RKEF) process is still going strong in spite of continuous hope that hydrometallurgical processes will one day make the RKEF plant obsolete. Within the pyrometallurgical plants there is a continuous trend for larger scale furnaces. The development for a number of furnaces that were started before 1985 and increased capacity by “natural growth” is given in Figure 1. Natural growth refers to the development of the plants that after having mastered a certain level of operation, were ready for a higher load that could be installed either with a new furnace on the same site, or during a revamp. The advantages of natural growth are numerous, for example: •,Deep knowledge of the ore and its’ behavior, no need for testing, and little risk of surprises. •,Mining, laboratory, equipment, etc. is all proven technology for the conditions on site. •,Starting a furnace with increased capacity is a re-start, not a green-field commissioning. •,Typically, when increasing the production capacity of an existing plant, not the entire plant is commissioned for the first time, but only a part. In the FeNi laterite industry for example, the kilns may already have had the capacity to provide enough material."

Jan 1, 2017

By A. E. Flynn

THERE is at the present time a revived interest in amalgamation, due to the number of mines starting up, usually on high-grade ore, and utilizing this relatively cheap and convenient means of recovering gold, more especially in their initial stages of production. The marked increased use of the amalgamation process has revealed a dearth of amalgamators and there is no doubt the art of amalgamation has stood still for a generation or two and is not readily applicable to the modern practice of milling gold ores. Mill operators of long experience are learning the art for the first time and are giving it intelligent study, and considerable testing and research work is now being undertaken Most millmen consider amalgamation a simple process, and so it is when we have a clean ore with coarse gold, specially when stamps are used for crushing. In treating Nova Scotia ores by stamps and amalgamation, recoveries of 95 to 97 per cent are common and easily obtained. So-called 'under-water feed' is almost universally used in Nova Scotia and is quite beneficial. The water is supplied through jets between the dies and below the die surface and maintains this space as a live trap which catches the gold particles before they are overground and spoilt for amalgamation. With this method, the portion of gold recovered in the battery is higher than usual and often amounts to 80 per cent of the total gold in the ore, the remaining 20 per cent being caught on the plate. As a continuous amalgamator, the simple plate cannot be excelled. Some of the modern devices having moving or covered and not very accessible plates, which cannot be readily inspected and dressed to keep them in condition, do not give the best results in service. An exception might be drawn in the case of amalgamation of very heavy ore or concentrate which would bank up unless the plate is carried at such a steep inclination as to weep mercury. Difficulties in stamp-mill amalgamation are encountered when acid water is used or when grease is present. Also, certain sulphides and graphitic and talcose ores give trouble, resulting in poor gold recovery and high mer-cury loss. The older literature on gold milling deals with the common troubles of this type and the old-time amalgamator was well able to take care of day-by-day difficulties. When the difficulties were unsurmountable, the ore was classed as 'refractory' and other processes were used.

Jan 1, 1939

By J. Lui

At its Copper Cliff Smelter, bulk nickel and copper concentrate is processed in two Inca flash furnaces and Peirce Smith converters to produce Bessemer matte containing 0.6%Fe. After slow cooling and Matte Separation, Bessemer matte is converted into three main products using magnetic separation and flotation technology: (1) a nickel containing chalcocite concentrate (MK); (2) two types of copper containing nickel sulfide (ME and MR); (3) metallics (MYN). MK is further processed in the Inca top blowing bottom stirring MK Reactor to produce semi-blister copper containing ~4%Ni and ~3±1 %S. The semi-blister copper is then purified in the multi-purpose vessels (MPV) to produce blister copper by reducing Ni, Fe and S content through oxidation. High melting point NiO is formed inside the MPVs. The accumulation of solid NiO and other oxides requires periodic cleaning by adding reductant and furnace matte, a unique process called "washout" at Inca. For many years, the reductant used for the "washout" process has been 15%Si Ferro-silicon. With increasing cost and limited suppliers for 15%FeSi, alternative reductants were pursued. This paper summarizes the development and commercialization of new alternative reductants for MPV "washout".

Jan 1, 2007

By V. Vorontsov

Catalysts Mo-Ni-S were prepared by combining MoS2 and NiS in weight ratios 1:1, 1:2, 1:4 and 2:1, each of which was admixed with 5%wt Ag and 5%wt YSZ to increase three-phase boundary surface area of the electrode. For comparison catalysts comprising Co-Mo-S in weight ratio of 1:1 of CoS to MoS2 admixed with 5%wt Ag and YSZ and pre-sulfided NiMoO4 were made. The catalysts were examined for electrochemical oxidation of hydrogen sulfide in solid oxide fuel cells (SOFC) at 850°C temperature. The catalyst prepared from 1:1 (wt. %) NiS:MoS2 demonstrated highest performance. Current density up to 1,330 mA/cm2 and power density up to 300 mW/cm2 were achieved using pure H25 gas, which are the highest among the reported H2S-powered fuel cells ever published in the literature. Anode materials of different NiS:MoS2 ratios have been characterized by means of X-ray diffraction (XRD), simultaneous TG/DSC analysis and Neutron Activation Analysis (NAA). TG/DSC and NAA results show that addition of NiS and Ag increases fuel cell performance due to improved structure/integrity of the anode. It has also been demonstrated that MoS2 is a suitable anode material in H2S-powered SOFC, with high activity towards H25 oxidation and thermally and chemically stable up to 850°C.

Jan 1, 2005

By Iain Sommerville, Hugh Mountford, Dawid D. Smith, Claude Dube, Brett Hixson

JW Aluminum use lean and Six Sigma techniques to continuously improve their target of reliable, repeatable and reproducible (3R) manufacturing. Six Sigma’s second stage gate, known as "Measure" involves identification and qualifying appropriate measuring systems. Metal quality (inclusions) are known in the industry to be an important element in 3R casting. The measurement of inclusions at JW Aluminum historically depended on outside vendors. In order to establish real time inclusion measurement ability within JW Aluminum, inclusion measurement systems in the marketplace were investigated. The qualification of a MetalVision MV20/20 ultrasonic inclusion analyzer are discussed as well as the subsequent application of the system in melting and casting improvement projects.

Jan 1, 2015

By François Robert, Rex Brommecker, Don S. Bubar

"The Orenada Zone 4 deposit is a small vein-type gold deposit occurring directly within the Cadillac Break southeast of Val d' Or in southeastern Abitibi Sub province. Mineralization is hosted by the Piche Group which, on the Orenada property, consists of talcchlorite- carbonate, chlorite-carbonate, and sericite-chlorite schists, derived from ultramafic volcanic, mafic igneous, and intermediate to felsic volcaniclastic rocks, respectively. All these rocks have been carbonatized.Rocks of the Pichi Group display a strong east-west, subvertical S1foliation, which is superimposed by asymmetric, intrafolial F2folds with shallow to moderate plunge to the east and to the west. F2folds are accompanied by an S2, subvertical axial planar cleavage, and are interpreted to result from dextral transcurrent shearing along sr.The Zone 4 deposit occurs within a large F2 fold, 60 m wide and plunging at 45 to the east, down to a depth of at least 300m. The auriferous zones consist essentially of zones of closely spaced, parallel quartz-tourmaline-albite-carbonate-arsenopyrite veins concordant to Sr these veins have been folded by the large F2fold and may pre-date the folding. A few discordant quartz-tourmaline-arsenopyrite veins, post- dating the F2 folding, also contain gold. Wallrocks adjacent to concordant veins have been carbonatized, albitized and contain significant amounts of tourmaline and arsenopyrite, with which gold is intimately associated.The Orenada Zone 4 deposit is a unique example of a deformed vein- type gold deposit, and exemplifies one of several types of association of lode gold deposits with folds."

Jan 1, 1990

By X. S. Fan, T. R. Feng, D. Chen

To meet the flotation process requirements, the large-scale flotation cell must be designed for sufficient pulp mixing, reasonable air dispersion and solid suspension, which is very difficult to design for super large-scale flotation cell. Hence, the flotation cell scale-up and optimization for a short period is a challenge for super large-scale flotation cell design. Computational fluid dynamics simulation has been applied in flotation cell study, which is effective, timesaving and low cost in the study of the flow field distribution for super large-scale flotation cell. This paper demonstrates the flow field characteristics in the 600m3 flotation cell by CFD. The flotation cell model is meshed with hexahedral grid and the high mesh quality assures the computational precision. MRF model, namely a steady-state approximation, ensures that individual cell zones can be assigned different rotational speed. Euler-Euler approach is chosen for multiphase flow simulation to treat different phases as interpenetrating continua. Numerical simulation of single phase, two-phase and three-phase are investigated respectively. Results suggested that the flotation cell has the apparent upper and lower flow circulation. In condition of the impeller rotation, the air is dispersed reasonably. In addition, the solid phase volume concentration distribution in the cell has a little difference.

Jan 1, 2015

By Q. G. Reynolds, R. T. Jones

The choice of furnace design parameters has a marked effect on the integrity of the furnace that is constructed. The design methodology for DC arc furnaces typically begins with the chemical reactions and feed materials that define the process. The specific energy requirement of the process, and the feedrates of the raw materials largely determine the power requirement for the furnace. A chosen value for the 'power intensity' sets the diameter of the furnace. Justification is provided for why this is a good choice of scale-up parameter. Equations are presented to quantify the resulting trade-off between thermal efficiency and the degree of error that can be tolerated in the balance between power and feedrate. This improved understanding should provide a better rationale for selecting an appropriate power intensity (or furnace diameter) for future furnaces.

Jan 1, 2015

By N. Katsikaros, A. Lewis-Gray, P. Richards

"To optimize gold recovery in complex leach-to-electrowinning processes, Gekko Systems developed the Gekko resin exchange column (G-REX) as an intermediate step, using a highly gold-selective resin to isolate contaminant metals. The AuRIX®100 resin produced by Purolite is licensed exclusively to Gekko, with the G-REX column designed specifically for this resin. Operational experience has been gained at the Castlemaine Goldfields Ballarat gold mine. In near-continuous operation since 2008, the Ballarat plant treats unclarified concentrate leach solution. The extension of this technology to higher throughputs and more complex chemistry is discussed.RÉSUMÉ Afin d’optimiser la récupération de l’or dans des procédés complexes impliquant la lixiviation suivie de l’extraction électrolytique, Gekko Systems a développé la colonne Gekko de résines échangeuses d’ions (G-REX) comme étape intermédiaire, à l’aide d’une résine hautement sélective pour la récupération de l’or qui permet d’isoler les métaux contaminants. Gekko détient la licence exclusive pour la résine AuRIX®100 produite par Purolite, et la colonne G-REX a été spécifiquement conçue pour cette résine. C’est à la mine d’or Ballarat de Castlemaine Goldfields que l’expérience opérationnelle a été acquise. L’usine de Ballarat, en exploitation quasi-continue depuis 2008, traite une solution concentrée non clarifiée de lixiviation. L’extension de cette technologie à des capacités supérieures et à une chimie plus complexe est examinée.AURIX®100 RESINAuRIX100 resin is a crosslinked polystyrene alkaline resin developed by Henkel (Virnig, Mackenzie, & Adamson, 1996). The resin beads are off-white in colour and spherical, with a nominal size of 100% +600 µm. This resin is highly selective for gold and silver over many metals, by way of extracting precious metal–cyanide complexes from leach solutions with a pH of less than 11.5. The higher end of the pH scale produces the best selectivity according to the order of preference: Au > Ag > Hg > Zn > Ni > Cu > Co > Fe. Purolite produces the resin and Gekko Systems maintains licensing of AuRIX100 resin for use in its G-REX column, as part of its unique suite of gravity gold–handling equipment.Significant cost savings over carbon-in-solution (CIS) systems are realized with AURIX100 resin: approximately 4–12% in capital savings and 27–40% in operating costs (Virnig, Mackenzie, Katsikaros, & Gray, 2004). Additionally, AuRIX100 resin is not susceptible to fouling; that is, the resin does not load with inorganic salts or organic compounds that would affect the loading and extraction of precious metals. To counter any potential for fouling by inorganic salts, a dilute acid wash is periodically conducted in service on the resin to unblock resin pores."

Jan 1, 2017

By G. F. Liu, S. Owada

Platinum Group Metals (PGMs), Pt, Pd, Rh, have been widely used as a three-way catalyst to clean discharged gas from automobiles and therefore a considerable amount of the spent catalysts is generated annually. This paper proposes a novel concentration technology of PGMs by utilizing the double-deck structure of PGM bearing alumina-ceria and cordierite phases. The applied technologies are a combination of heating-quenching, selective grinding and screening for separating alumina-ceria phase from cordierite. Temperature change as a function of quenching time and the thermal stresses applied to both phases were simulated and calculated by FEM, and it was clarified the mechanism of micro-cracks generation at the phase boundary and micro-cracks in alumina-ceria phase, which indicated that separation of alumina-ceria phase from cordierite and selective breakage of alumina-ceria phase could be achieved in the subsequent selective grinding with an attritor. This process could concentrate 46 wt% of alumina-ceria phase into fine fractions with 86 % recovery efficiency. The remaining alumina-ceria phase can be further recovered by applying flotation and so on.

Jan 1, 2015

By J. Shanks

A S far back as 1925, Brazeau Collieries, Limited, became interested in .briquetting. This was brought about by complaints from their principal customer that stack losses, due to a high percentage of fine coal in their mine run, were excessive. The Company considered oil spraying of the fines. This, after some experiments and tests had been made, was ruled out as uneconomical and impracticable. When sufficient oil to be effective was put into the fines, it caused the coal in the tender of stoker-fired engines t0 arch over the screw feeder. The Company ultimately placed their problem in the hands of the Re-search Department of the University of Alberta. Experimental work was carried on by this department over a period of more than a year. The results obtained and the experience gained in this research work were conveyed to Brazeau Collieries in a report dated October 31st, 1929, and in a supplementary report dated February 2nd, 1935. Most of the results obtained in experimenting with Brazeau coal are embodied in a brochure, reprinted from the proceedings of the Second International Conference on Bituminous Coal, Vol. 19-24-28, entitled Principles in the Briquetting of Coking and Non-Coking Bituminous Coals, by E. Stansfield and W. A. Lang. All who are interested in briquetting should read this brochure. In the writer's opinion, iris the most important treatise on the subject printed in recent years. The results given in the paper are, of course, those obtained in laboratory investigation. It was pointed out to the writer that it would be most interesting to have such results correlated with those obtained in commercial practice. In this short paper, an attempt is made to do so.

Jan 1, 1942

By Z. Trojanová

Mg micropowders generated by gas atomisation of a magnesium melt with argon were mixed and ball milled with ceramic nanoparticles prepared by laser-induced gas phase reaction. The materials were then hot extruded. Specimens were deformed in tensile as well as compression tests at temperatures between 20 and 300 °C at a constant initial strain rate. The flow stress is significantly influenced by the test temperature. The yield stress decreases with temperature. This decrease and the flat character of the stressstrain curves at elevated temperatures indicate possible contributions of softening processes. The materials studied exhibit high-damping characteristics. The results are analysed and possible mechanisms are discussed.

Jan 1, 2006

Roasting of molybdenite concentrate is an important stage in the production of commercial molybdenum trioxide. The oxidation kinetic and mechanism of molybdenum sulfide concentrates from two plants were investigated at temperatures from 444 °C to 640°C. The rate of reaction was determined for thin layer samples in a muffle furnace at controlled temperatures, oxygen excess and removal of sulfur dioxide. For both concentrates the rate of reaction is fairly slow at temperatures below 500°C and remains fairly constant from 540 to 600 °C. It was observed that the concentrate from the first plant presents a tendency for sintering or glazing at temperatures above 620°C, whereas the same phenomena was observed at 20 or 30 °C higher temperature for the second concentrate. A kinetic model of two reactions, involving the formation of Mo02 as intermediate oxide for the production of Mo03 is proposed and activation energies of 23.0 and 20.8 kJ/mol for the first and second reaction were calculated for temperatures between 520 °C to 600 °C. These low values of activation energies indicate that the overall rate of oxidation is controlled by mass transfer, particularly in a porous layer of oxides. Therefore, the renewal of the surface by mixing and motion of the concentrate layer is of great importance. Sublimation of Mo03 becomes significant for temperatures above 650 °C.

Jan 1, 2007

By A. Demers, M. Chapman, N. Reynier, R. Lastra, M. Courchesne, C. Laviolette

Historic medical isotope production at Canadian Nuclear Laboratories (CNL) in Chalk River involved the dissolution of irradiated isotope targets prior to extraction of Mo-99. This process generated liquid waste that was cemented in 5-gallon containers and transferred to an outdoor waste-management facility for intermediate storage. Research was undertaken to develop an innovative method for uranium, mercury and cesium recovery from the radioactive cemented waste (RCW). Regulations prohibit the removal of active radioactive waste from the Chalk River facility. Thus, CanmetMINING produced surrogate material following the same procedures and conditions to those used at CNL. The selective recovery of the uranium from the surrogate radioactive cemented waste (SRCW) could offer CNL more disposition options for the resulting wastes. Leaching tests were performed using four different SRCW at 1 kg scale. Different conditions, operating parameters, and the presence of plastic and corrosion products were evaluated on solubilization. The research investigated the use of potassium iodide with the sulphuric acid leach to increase metals recovery. Iodine improves the solubilisation of metals and the U dissolution reached 99%. The increase of leaching time reduces the U solubilization due to silica gel formation. Therefore, it will be important to control leaching time to avoid the loss of U during the pilot scale experiments. For Hg, the solubilization ranged from 60 to 80% due to the presence of metallic mercury and mercury sulphide found in SRCW cured at 60°C and/or aged for 30 months. Ion exchange (IX) was found the best method to separate the uranium from the impurities and produce a purified and concentrated uranium solution suitable for yielding a uranium product (yellow cake).

Jan 1, 2020

By F W. Irwin

In recent years, a number of significant developments have occurred in the steel industry which are no-table and of general interest. This paper is confined to the steel-melting phase of the business. The development of high production rates on Stelco's Basic Open Hearth furnaces is chronologically summarized. Al-though various aspects of this subject have been presented previously, this paper summarizes the developments in high fuel rates, the usage of basic refractories, low and high oxygen rates and hearth maintenance. Background T HE interest which has been shown in steelmaking techniques in the past few years has been due, primarily, to the extremely high production rates obtained. Upon further study of the facilities and techniques employed to generate this steel at record rates, tonnage oxygen appears as the common factor. It can be stated that tonnage oxy-gen has revolutionized steelmaking techniques to a degree never before encountered. It was only about ten years ago that the use of large amounts of pure oxygen in a steelmaking

Jan 1, 1965

By J. Manchisi

This study has investigated the use of blast furnace slag as functional adsorbent for metal ions in acid mine drainage treatment. This opportunity has not yet been developed into a practical process partly because of limited understanding of rates and mechanisms of adsorption process and inconsistency in interpretations of adsorption data. The overall objectives were to determine the efficiency and mechanisms of sorption process of metal ions in a multiadsorbate system. We employed standard materials characterisation techniques to analyse composition, structure and surface morphology of the slag. Batch adsorption experiments were then conducted to study the mechanisms, kinetics and efficiency of metal sorption as a function of pH, phase ratio, mixing time, mass and particle sizes of slag. Both XRF and adsorption data suggested the slag to possess acid neutralising capacity. This slag is non-crystalline based on XRD pattern, has adequate porosity and pore volume comparable to similar commercial adsorbents but it has inferior pore structure, pore size distribution and BET surface area to be effective under wide applications. Metal sorption increased with decrease in slag particle diameter, decrease in initial metal concentration and increase in the mass of slag. Although slags have demonstrated to efficiently treat low concentrations of single and multiadsorbate effluents using fine particle sizes, they have limited capacity to treat multiadsorbate systems for some metal ions. This is probably due to low affinity, competitive adsorption or limitation in material?s adsorptive properties. Sorption mechanisms probably involve precipitation and ion exchange on the basis of alkaline pH and exchangeable slag surface ions. Sorption preference is proposed as Fe2+>Cu2+>>Cd2+>Co2+>Mn2+. Despite these limitations, deeper understanding of sorption behaviour of metal ions by slags for application in dilute and large volumes of effluents is necessary where precipitation and other standard techniques are either inefficient or uneconomic. Thus, this study has established that sorption capacity of slag to remove metal ions from acidic effluents is selective, limited to certain metal ions and for other ions only at low concentrations. Further adsorption studies in multiple solutes under various experimental conditions or those that can propose an economic slag activation process are needed that improves or widens adsorption window.

Aug 1, 2013

By Ralph H. Cleland

Introduction The mines of northern Ontario have entered the class of deep mines. It has often been asked: How deep can operations be carried on? What will the temperature be? This paper is a résumé of a brief survey of rock temperatures made by the Ontario Department of Mines during the year 1932. Present temperatures were recorded and the geothermal gradients that now exist were determined. No alarming situations were found, but many interesting ones have been noted. Northern Ontario mines are fortunately situated as compared with most deep-level mines of the world. The mean yearly temperature, as determined from meteorological records of the Federal Department of Marine, is from 33 to 38 degrees Fahrenheit. The tables on the next page show the temperature range in and about our mining camps ( l ). As no exact figures were obtainable for Kirkland Lake, the data for Iroquois Falls, which is about 50 miles northwest, were taken as applicable there. The figures for Timmins were checked against those of Cochrane and Iroquois Falls and found to be very similar, so that the Cochrane data may be used for the Porcupine camp. The yearly mean temperature is considered to be 33.5 F.

Jan 1, 1933

By L. T. Pasiechnyk

After a brief review of the various hydrocarbon storage methods currently being utilized and statistics on underground hydrocarbon storage, this paper will briefly describe the technology involved in solution mining salt to create caverns of engineered shape and size and briefly discuss the economical and environmental advantages of hydrocarbon storage in solution-mined salt caverns. Other possible uses of salt caverns will be mentioned.

Jan 1, 1978

By J. Paturaud, A. G. Villemiane, J. Y. Buffiere, D. Fabregue, M. Perrier

In this work, a detailed characterization of the cyclic damage mechanisms on duty in car heat exchangers has been carried out in order to improve their reliability. The material which consists in very thin (<0.3 mm thick) sheets formed of 3 co-rolled aluminum alloys (4045 /3916/ 4045) has been brazed in order to obtain metallurgical and surface conditions representative of those of the real components. Fatigue tests at constant stress amplitude have been performed at room temperature and 120°C in order i) to characterize the cyclic resistance of the studied materials and ii) to study the effect of temperature on the fatigue damage mechanism. The mechanisms leading to failure have been identified from post mortem fractographic analysis. The Wohler curves obtained show that, contrary to common structural Al alloys, this type of thin sheet brazed multi material can be cycled for several hundred thousand cycles at very high stress level (> ~ 80 % of the tensile strength). This behaviour is analysed with respect to the microstructure resulting from the brazing process and the low number of grains present in the sample thickness (around 5 grains).

Jan 1, 2015

By A. L. Mular

"This paper summarizes the present-day usage of computers in the mining-metallurgical industry. The industry appears to be following a path taken by other industries in improving the operation of processing plants, production schedules, grade control and haulage performance. A reduction in the cost of computers and computing has been a significant factor.An attempt is made to forecast the future of computers in our industry. Such developments as time-sharing, mini-computers, and easy-to-understand process-oriented languages will lead to wider usage. Considerable strides have been made in the use of computers for laboratory data acquisition. In general, the implementation of new methods, new techniques and new equipment will require plant personnel to develop new skills. The universities are meeting this challenge by re-structuring curricula and offering special courses. Most vendors of computers already offer special courses within their own facilities at a customer's plant."

Jan 1, 1970