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By J L. Merritt

Contour banks and waterways are standard soil conservation measures to assist farmers reduce the impact of gully erosion on sloping cropping land by reducing the slope length to the interval between the banks. The Universal Soil Loss Equation (USLE) developed by the USA Department of Agriculture Soil Conservation Service in 1930s predicts the long-term average annual soil loss (A).The equation is the product of the rainfall erosivity factor (R), the soil erodibility factor (K), the topographic factors of slope length and angle (L and S) and the cropping management factors (C and P). Contour banks reduce the slope length (L) only.Contour banks are a constructed earth embankment, incorporating a channel on the upslope side, typically traversing a slope on or close to the contour to control and/or prevent the erosion of that slope. The banks are also referred to as graded banks, terraces, or bunds (DSITI 2015). Contour banks are either broad based or narrow based. Broad based banks allow the passage of the machinery over the banks whilst narrow based bank batters are too steep preventing the passage of machinery. Waterways are a stable, longitudinally sloping water disposal area of sufficient capacity used to discharge surplus runoff from the contour bank and to allow it to flow to a lower level without causing erosion (DSITI 2015).The mining industry must decide what the role for contour banks and waterways is in each operation’s rehabilitation and closure plan.CITATION:Merritt, J L, 2018. Contour banks in spoil rehabilitation – a matter of timing, in Proceedings Life-of-Mine 2018, pp 147–149 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 25, 2018

By A E. Waltho, W J. Shaw

Predicting the physical characteristics of various ore types has for long been a difficult problem during mining. Grade control practices tend to concentrate on the chemical grade of the ore. Estimation of physical characteristics such as beneficiation behaviour is commonly limited to the simplistic application of historical averages. Large amounts of geochemical data are often gathered during the exploration and mining stages of a project, especially in ferrous and base metal deposits. In addition to the elements of principal economic interest, samples are often analysed for suites of gangue constituents to determine whether the mineralisation lies within target specifications. This multi-element data is often put to no other use than this simple chemical classification, yet it may present the geologist or metallurgist with valuable insights into the mineral content and physical characteristics of the deposit. Normative mineral estimates have been used as a method for characterising igneous rocks for almost 100 years. The method establishes and applies a set of sequential rules, by which the chemical components of a sample are assigned to mineral components. Provided that it is possible to make some realistic assumptions about the mineral species likely to be present in a rock unit or deposit and their paragenesis, this approach can be extended to a variety of mineral deposits. The geochemical data that are routinely collected when, for example, drilling iron ore and base metal deposits, can be used to derive estimates of normative mineral content. These estimates can be used to characterise physical or metallurgical aspects of the ore, such as density, beneficiation behaviour and metal recovery. This paper examines the application of normative mineral estimates to a variety of practical resource characterisation problems. The potential for predicting the lump and fines proportions of iron and manganese ores is also discussed.

Jan 1, 1999

By B Dold

"Mining has still today high potential for improvement in the exploitation efficiency. Especially low-grade ores have very low recoveries. In Cu bioleaching operations from porphyry copper deposits extraction of only five and 15 per cent with maximum of 40 per cent are reached. This means that 60–95 per cent of the resource is not exploited. Consequently, any metal not extracted will end up in the waste material, therefore increasing the risk of environmental pollution. This inefficiency is mainly due to the use of element concentrations for decision-making on the daily basis of a mining operation (eg cut-off ore grade, acid-base accounting – ABA). If, instead, quantitative mineralogical and geochemical data together with information on the bioleaching behaviour of the ore assemblage (the biogeometallurgical approach), is used for decision-making right from the beginning of the exploitation, higher recoveries and less environmental impact can be achieved, ie an increase in sustainability can be reached.CITATION:Dold, D, 2016. The Biogeometallurgical Approach – the Information We Need to Increase the Sustainability of Mining, in Proceedings The Third AusIMM International Geometallurgy Conference (GeoMet) 2016, pp 169–172 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

Jun 15, 2016

The cloud transform simulation is a technique used to generate realisations of correlated attributes. The principle of this technique is to partition the scatter diagram between the input attributes into several interval classes and derive for each class a cumulative distribution function (CDF) using only the data pairs of the scatter diagram in that class. The simulation then proceeds like a traditional Monte Carlo simulation but using the derived CDF in each class.The cloud transform simulation has the advantage of being a simple and fast technique that is able to reproduce the uncertainty in the relationship between the two input attributes regardless of whether the relationship is linear or not. However, the technique has three major drawbacks. First, the number of classes has an impact on final simulated results and there is not a robust approach to define such number. Second, simulated results exhibit some saw tooth variations that are unrealistic and third the reproduction of the spatial continuity of the simulated attribute is not guaranteed.This paper presents the use of the quantile regression approach in order to overcome the first two disadvantages of the cloud transform simulation. Details of the technique and how it can be coupled with the cloud transform simulation are presented along with a real case study.

Sep 26, 2011

Folklore suggests that oxidation is detrimental to sulfide mineral flotation, and in many instances is the reason given for values reporting in the tailing. However, while a considerable body of work examining galena oxidation is available in the literature there are very few studies that investigate the consequences of galena oxidation on its subsequent flotation in base metal sulfide ores. This work clearly demonstrates that pyrite forms a galvanic couple with galena, due to the large difference in their rest potentials, and results in accelerated oxidation of galena, particularly as the pyrite content of the ore is increased. The most obvious effect of the galvanic oxidation of galena by pyrite is the release into the system of galena oxidation products, providing an ample supply of lead ions available to activate gangue minerals, most notably of which in lead/zinc ores is sphalerite. The inadvertent activation of sphalerite by lead ions inevitably leads to the recovery of liberated sphalerite into the lead concentrate, and as a consequence a reduction in the lead concentrate grade. That is, a loss of selectivity for galena against sphalerite. If galena oxidation is excessive not only is there a considerable loss in lead concentrate grade, but also a marked decreased in lead recovery as the flotation rates of the gangue minerals increase, until they rival that of galena.

Jan 1, 2005

By I Villalba

The need to continue the development of the Ensham mine has led to blast up to 75 m to the Eastern side of a water dam in the vicinity of Ramp 23. The water dam wall is exposed to blasting over a distance of approximately 500 m. The first decision was to determine that the existing rock pillar between the Eastern side of the water dam and the blasting operations may not be less than 75 m in order to minimise the damage that the blast could generate to the dam wall. It was also necessary to define blasting practices to minimising the blast damage to the rock properties of the dam wall and to avoid adverse effects from vibration and gases generated by the detonation on structures.For this purpose analytical designs and test blasts were conducted to assess the ground vibration attenuation within the rock pillar. From this analysis, it was concluded that the best practice to reduce the rock damage was to create a zone of fractured rock adjacent to the side of each production blast. This fractured zone would create an effective filter both for vibration and for gases generated by the blast. This zone of fractured rock was created by firing two buffer rows. In terms of pattern size and powder factor the two buffer rows were designed just to generate a fractured rock zone. To date approximately 500 m have been excavated along the eastern wall of the water dam where each production blast was preceded by a Trim blast. This practice has given good results with regard to minimising the damage generated by production blasting.

Nov 8, 2011

By M J. Pejovic, S BoÜevski, I Miljanovic, M Hudej, A Milutinovic, A Petrovski

The paper deals with the problem of managing the supplies of consumables (energy resources, lubricants, explosives, explosive supplies, tires, spare parts, etc) in mines. After the introductory remarks and comments, a general stochastic model of supply, relating in general to the dynamic programming method is presented. A selection of stochastic supply model for experiments and research by the authors of this paper is not a coincidence, based on of their long experience, showing that this type of model is the most suitable to provide support for decision-making and management of supplies of consumables in mines.In order for the problem?of?consumables?supply?management to be reviewed, in whole and objectively from the aspect of risk, experimental tests of the stochastic model in real conditions were performed at the limestone open pit mine æZelenikovecÆ near Skopje, the capital of Macedonia. The scope of the experimental research enabled reliable analysis. The results obtained confirm the efficiency and reliability of the stochastic model and two separate manipulative-operational positions regarding its application, which may have an important influence on the optimisation of supplies.

Sep 26, 2011

By E J. Hill, F Huang, A Otto

Geochemical data from drill core samples is used in mineral exploration to enable geologists to understand subsurface geology. However, it is challenging to analyse these data sets rigorously and consistently. Manual data interpretation relies on the knowledge and experience of logging geologists. When multiple geologists are involved, it is possible to introduce inconsistencies in logged lithology type and scale of logging (‘splitters’ versus ‘lumpers’). Machine learning (ML) is a powerful tool for analysing high dimensional data (ie data with many variables) and large data sets (ie data with many samples). However, ML methods applied to drill hole samples do not incorporate spatial information and this can result in high misclassification rates and small-scale ‘noisy’ results. We demonstrate the use of multiscale spatial analysis (wavelet tessellation) as a pre-ML step to analyse spatial information. This step helps reduce misclassification and filter out unwanted small-scale variation in the data. In an experiment, we used wavelet tessellation and supervised ML to predict litho-geochemical rock types from geochemistry data. The data set is from the Valhalla uranium deposit near Mount Isa, northern Queensland. First, geochemical knowledge and statistical analysis was used to select appropriate geochemical elements for litho-geochemical classification. Second, the elements were processed using multiscale spatial analysis. Third, we trained a Random Forest model with the data set and found that the model performs worse in predicting rare rock samples than common ones. We applied over-sampling and down-sampling methods in aim to overcome this issue. As a conclusion, the combination of multiscale spatial analysis (to define rock unit boundaries) and Random Forests (to classify rock units) is a good method for rapid and accurate analysis of drill hole geochemistry.

Mar 22, 2022

By Rolley P

In the course of reviewing grade control practices at the Marvel Loch gold mine in Western Australia in 1992, FSSI Consultants developed and implemented a novel approach to ore selection using a method to maximise financial return (the MP method*). The approach was based on improved grade control sampling and an ore selection method which directly incorporates both a measure of the uncertainty in knowing the true grade of selection units in the definition of ore, as well as the operating cost and revenue parameters of the mining operation. During the past four years, FSSI Consultants have evaluated and refined the use of this approach and have implemented customised variations of the MP method at seven gold mines and a gold-copper mine in Australia. The previous methods of ore selection at most of these operations were based mainly on polygonal - sectional methods of grade estimation. At all of the sites where grade control optimisation has been given a fair trial over several months of production, the use of the MP method has been consistently rewarding to the mining operations. The benefits include increased run of mine ore stockpiles and low-grade stockpiles and decreased fluctuation in the production grade. Most operations have also benefited from a consistent ability to improve production grade through high-grading of the increased ore production. The increase in ore production has the logical benefit of reducing stripping ratios, increasing mine profitability and mine life.

Jan 1, 1997

By A Reid, A W. Musk, O Jones

In this paper, the authors attempt to bridge the gap that currently exists between the duty-of-care responsibilities of underground mining industry personnel, and the multifaceted health challenges facing mineworkers in Western Australia’s metal mines where diesel-powered mobile equipment predominate. In addressing this issue, the complexities of the nature and extent of the challenges are discussed along with the current inadequacy of existing regulatory metrics. Support is given to the need for well-organised in-mine baseline studies to clearly define the distribution and aging characteristics of the toxic and carcinogenic pollutants within the mine ventilation system, with special emphasis given to exploring the validity of biomonitoring systems. The paper concludes with the proposal that a template risk assessment data sheet be prepared for the industry to provide mining personnel with a sound basic knowledge of the health risks involved and the control measures and precautions available for minimising and/or eliminating the hazard.CITATION:Jones, O, Musk, A W, Reid, A and Davis, C, 2017. Risk assessment tool for mines using diesel-powered mobile equipment, in Proceedings 13th AusIMM Underground Operators’ Conference 2017, pp 151–154 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Oct 16, 2017

By R M. Yanamandra, S K. Tripathy, N Mangadoddy, P Sudikondala, P Ankireddy

Spiral concentrator is one of the most commonly used gravity concentration devices in mineral processing. The particles are classified based on their specific gravity and size. The present work analyses the experimental and numerical investigations of the water flow field, such as fluid depth and free surface primary velocity of two high gravity spiral concentrators at different flow rates. The measurement techniques use a flow depth gauge and flow visualisation technique adapting lycopodium powder as the tracer. Flow features in terms of liquid depth and primary velocity at the free surface of the flow are captured across the trough in two different high gravity spirals. A highspeed motion camera with an imaging frequency of 5400 frames per second and 768 × 768 pixel resolution is utilised to track the tracer particles in the liquid flow on the dark surface background. Further, the two-phase flow is studied numerically on high gravity spirals based on the volume of fluid (VOF) approach utilising the RNG k-ε model and Reynolds Stress Model (RSM) for predicting the fluid flow on trough surfaces such as water depth and free surface primary velocity. The CFD predictions of the flow field for the two spirals are attempted to validate against experimental data. The high gravity spiral concentrators show lower flow depths and free surface primary velocities but steep velocities on the outer trough zone compared to that of low gravity spiral concentrators (conventional coal spirals). Among the computationally tested high gravity spirals, higher pitch and higher secondary slope design shows greater flow characteristics.

Aug 24, 2022

By D Reid, J McKibben, M Noppe

International mineral disclosure standards and guidelines aligned with the CRIRSCO (Committee for Mineral Reserves International Reporting Standards) template were developed to inform stakeholders about the relative accuracy and confidence levels of publicly reported information and to support investment decisions, particularly when advancing projects through different development stages. The traditional stages range from early to advanced exploration, through pre-development (with Mineral Resources and pre-feasibility and/or feasibility levels of study) before the final development stages, where a decision to proceed with construction or production (or both) is made. The traditional definition of Mineral Resource and Ore/Mineral Reserve classification categories and techno-economic study levels (including Preliminary Economic Assessment (PEA), Scoping Study (SS), Pre-Feasibility Study (PFS) and Feasibility Study (FS)) were defined with pre-development project assessment in mind. As such, these definitions are not necessarily well aligned to the reporting structures required by operating mines which need to consider a range of timelines spanning short to long-term operating conditions. However, the same terminology and definitions are used, or expected to be used, by both project developers and mine operators when reporting resources, reserves and techno-economic study outcomes. This paper discusses how various stakeholders in the minerals industry (including competent/qualified persons, mining company leaders, investors, lenders and regulators), generally interpret the definitions of Mineral Resource and Ore Reserve categories in terms of the relative accuracy of the estimates, their link to techno-economic study levels and their contribution to life-of-mine (LOM) schedules. The paper examines the degree to which mining companies recognise, and apply, enhanced operational knowledge to reflect short-term views of the relative accuracy and confidence levels associated with publicly reported Mineral Resource and Ore Reserve estimates and forecasts. Furthermore, this paper explores how this knowledge is applied to support ongoing Mineral Resource, and particularly Ore Reserve, generation and reporting. This paper is informed by public data and responses to an internal survey prepared by the authors and completed in 2021 by several mining companies.

Mar 22, 2022

By M Forbes, R Jeuken

Brownfields geoscience measurement such as drilling and surface geophysics can be costly and it is often difficult to weigh the cost of data collection and processing against the value it unlocks at the time of extraction. This makes it difficult to prioritise geoscience expenditure and find the optimum intensity of geoscience activity across competing assets. There are multiple options for managing resource uncertainty and spatial variability through mine planning and resource engineering such as varying marketing strategy, adjusting stockpile or other infrastructure design and product blending. Consideration of these alongside increased data collection further complicates finding a comparable value of geoscience programs to determine the right blend of geoscience measurement and engineering controls. Concepts similar to Value of Information (VOI) analysis which is applied to strategic planning can be used to estimate the value of geoscience measurement and pit sequencing at tactical planning and operational timescales. This involves the quantification of resource uncertainty and prediction of how it will affect resource extraction. This paper outlines this process and demonstrates its use to prioritise geoscience at BHP Coal Assets. The value of infill drill programs in enabling operational stability is quantified and compared the value of engineering controls like increased stockpile capacity. This study supports that idea that the application of VOI methods to bulk mining at tactical time horizons has potential to inform geoscience planning and resource engineering not just separately, but as part of a unified strategy for managing resource uncertainty.

Mar 22, 2022

By S Mitra, T Singh, D O’Dea, T Honeyands

Permeability and air flow rate in the bed during iron ore sintering is crucial to controlling the sinter quality and productivity of a sinter plant due to its influence on the flame front speed. In the present work, the permeability of the bed during sintering was analysed by means of measured pressure drop and temperature at multiple points in the bed during sintering. Three different zones were categorised, ie humidified (green) bed, region of maximum resistance (high temperature zone) based on temperature, and sintered bed. Previous work has shown that the maximum pressure drop during sintering was due to several concurrent physico-chemical processes including dehumidification, calcination of fluxes, dehydroxylation of goethite, combustion of coke and melting of granules (>1200°C). To quantify the effect of the different process, sintering experiments were conducted in a milli-pot (diameter 53 mm, height 400 mm) with pressure and temperature measured at same location in bed. The milli-pot was fitted with four equidistant (80 mm apart) taps. Overall, five sections in the milli-pot were analysed for pressure drop at different times during sintering. It was found that in region of maximum resistance, coke combustion and flux calcination were highest contributors with ~35 per cent of the pressure drop when compared to other processes like de-humidification and goethite dehydroxylation which contributed to ~20 per cent and 25 per cent each respectively. The pressure drop contribution of the coke combustion region increased with increasing coke addition rate.

Nov 8, 2021

By K Tanguturi, B Belle, R Balusu

Management of high rates of goaf gas emissions between 4000 and 6000 L/s of methane gas in longwall panels is a challenging issue, particularly in start-up areas of the panels. There is a need for investigation of the effect of various goaf gas drainage concepts and techniques, and development of effective gas drainage strategies for management of high goaf gas emissions in start-up areas of the longwall panels. This paper presents the results of various computational fluid dynamics (CFD) simulations that were carried out to investigate the effect of different goaf gas drainage strategies and combinations for gas management in the start-up area of the longwall panels. Results indicated that the gas (methane) concentration in goaf holes on the tailgate (TG) side vary between 50 and 75 per cent under the simulated field conditions with flat coal seam gradients. The results also indicated that operation of more goaf holes for draining the goaf gas on the TG side results in high ingress of oxygen and further reduction in gas concentration in goaf gas drainage holes. The simulations also included scenarios with goaf gas drainage holes on the maingate (MG) side, TG cut-through seal and near the start-up area. This paper presents the results of various goaf gas drainage strategies and discusses the effect of various combinations in order to develop effective goaf gas drainage strategies for gas management in start-up areas of the longwall panels.CITATION:Tanguturi, K, Balusu, R and Belle, B, 2015. Development of goaf gas drainage strategies for start-up areas of highly gassy longwall panels, in Proceedings The Australian Mine Ventilation Conference, pp 251–258 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 31, 2015

By X Hu, J Björkvall, L Sundqvist Ökvist

The metal production industry is a significant contributor to global CO2 emissions due to the use of fossil fuels such as coal and coke. To mitigate these emissions and meet climate goals, innovative and sustainable technologies are required. Molten salt electrolysis is a promising technology that directly produces metals from their precursor sulfides or oxides using electricity. When combined with renewable electricity and an inert anode, the electrolysis process can be carbon neutral. This paper presents the results of two pilot-scale studies on the electrolytic reduction of metal oxides and sulfides in molten salts. The first study focuses on the electrolytic reduction of chalcopyrite in molten NaCl-KCl salt. The results demonstrate that in situ separation of copper, iron, and sulfur is possible, enabling the extraction of all valuable elements without CO2 emissions. Furthermore, the findings underscore the capability to eliminate impurities like zinc, antimony, arsenic, and mercury from the electrolysis product. The second study investigates the electrolytic reduction of pure/synthetic chemicals of wüstite, hematite, and magnetite, as well as a magnetite-type iron ore in molten NaOH salt. The findings reveal a stepwise reduction of iron oxides from high valence to low valence, ultimately leading to the production of metallic iron electrolytically. Notably, this study underscores the challenges associated with the selection of an economically viable and durable inert anode material for efficient oxygen generation. These results indicate that molten salt electrolysis provides a sustainable and green route for base metal production. The use of this technology has the potential to significantly reduce CO2 emissions in the metal production industry, contributing to achieving climate goals.

Jun 19, 2024

By T D. H McGrath, G Wardell-Johnson, E A. Oraby, W Staunton, A R. Bax, J J. Eksteen

"Gold ores often show significant inter-domain variation with respect to the gravity recoverable gold (GRG) content and the leach behaviour of the non-GRG component. Liberation assessment is extremely difficult for gold due to its malleability and the high sampling errors and poor test reproducibility resulting from gold’s high specific gravity and the low metal concentrations that occur in most gold ores. The use of microscopic techniques for the liberation assessment of gold is also impractical due to the high number of sampling errors and high cost of analysis.Curtin University’s Gold Technology Group has developed an online carbon-in-pulp/carbon-in-leach (CIP/CIL) simulation model called SIMCIL, which has been used since 1999 to model and simulate industrial leach-adsorption circuits. Recently the model has been upgraded to include an integrated liberation-leach modelling (ILLM) approach, which can be used to evaluate the impact of various process parameters (such as grind size, bleed to gravity etc) and circuit configurations on leach-adsorption circuit behaviour and overall plant gold recovery. A new time-efficient ore characterisation methodology has been researched and developed to provide the required liberation-leach data used in the ILLM approach, which is implemented online for the modelling of gold operations. The ILLM characterisation methodology, test work data analysis, interpretation and application of the ILLM test work data are discussed.CITATION:Bax, A R, McGrath, T D H, Eksteen, J J, Staunton, W, Oraby, E A, and Wardell-Johnson, G, 2016. An Integrated Liberation-leach Model and Ore Characterisation Procedure for Gold Ores, in Proceedings The Third AusIMM International Geometallurgy Conference (GeoMet) 2016, pp 315–320 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

Jun 15, 2016

By P J. Sack, L V Danyushevsky

"An EXTENDED ABSTRACT is available for download. A full-length paper was not prepared for this presentation. Regional-scale exploration for sediment-hosted gold deposits is hampered by the challenge of evaluating the fertility of ancient sedimentary sequences that host these deposits. Recent developments in laser ablation inductively coupled plasma mass spectrometry allow for the evaluation of the gold fertility of sedimentary sequences using chemistry of early-formed sedimentary pyrite. We present a case study from the Selwyn basin area of Yukon, Canada, where significant sediment-hosted gold exploration has been ongoing for the last five years. Data from sedimentary pyrite in some Neoproterozoic shales are anomalous in Au and As compared to a global data set of unmineralised sedimentary pyrite. If at least some of the gold and associated trace elements in sediment-hosted gold deposits are derived from recrystallisation of early sedimentary pyrite, it follows that strata containing anomalous sedimentary pyrite should be more prospective. Based on this premise, our data clearly show that Yusezyu Formation Neoproterozoic shales in the Selwyn basin area of Yukon are a fertile source rock for sediment-hosted gold deposits, while pyrite from Nadaleen formation shales are strongly anomalous in Hg and Tl, but not Au. We suggest that the area warrants continued exploration for sediment-hosted gold.CITATION:Sack, P J, Gregory, D D, Large, R R and Danyushevsky, L V, 2015. Using sedimentary pyrite chemistry to inform regional exploration for sediment-hosted gold deposits – a gold fertility case study from the Selwyn basin area, Yukon , in Proceedings PACRIM 2015 Congress, pp 69–76 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

Mar 18, 2015

This paper presents a rationale for selecting appropriate support elements which combine to form a support system to maintain stability in mines subjected to both strainburst and the shaking that occurs from fault slip. The overall approach was developed during the 'case for safety' study undertaken to allow the then Beaconsfield Gold mine (now Tasmania mine) to resume development and production after the 25 April 2006 ground-fall and fatality that received worldwide publicity. Issues of the sometimes competing requirements of support element performance during dynamic loading are discussed and the need for support flexibility is contrasted with the usual high support element stiffness required when these are used to reinforce rock masses. An example is presented to show the steps and technical details required to design each component of a support system to counter the de-stabilising effects of seismicity.

Nov 25, 2010

By N J Welham

A commercial enargite concentrate was mechanically milled in inert and oxidising atmospheres for 10 hours. No substantial effect was observed in either an inert atmosphere or in air other than a broadening and weakening of the diffraction peaks. Milling dry in oxygen or wet in air was dramatic with a significant reaction occurring which formed arsenolite, As2O3 and CuSO4.5H2O, both of which are readily soluble.A small amount of SO2 was also formed. Dissolution in acid left CuS as the major phase implying incomplete oxidation. The small fraction of tennantite in the sample was comparatively resistant to oxidation.

Jan 1, 2001