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Comparative Studies on Balls Versus Spheroidal Tetrahedrons Working Media to Ore Grinding in an Industrial Drum Mill

Sep 13, 2010

By C. R. Austin

IN a recent paper1 the authors presented information on a refinement of the Rohn type of creep test with data on pure iron that exemplified the behavior of the apparatus. The present paper extends that work to nickel and cobalt and to the examination of the comparative high-temperature properties of two widely used commercial alloys. Careful attention has been given to the effect of plastic deformation in decreas-ing creep rate, using the elementary metals iron, nickel and cobalt for purposes of analysis. In any, endeavor to develop new materials for high-temperature service one soon encounters a real problem as to the sort of test to be employed in evaluating the commercial possibilities of the alloys. At one time it was considered satisfactory to determine the tensile strengths at elevated temperatures and to use these values as a criterion for the commercial application of the alloys. More recently the proportional limit has been used as a means of classification. Data obtained from a form of bend test has also shown promise as providing a "merit index" of high-temperature serviceability.2 Koerber and Pomp3 state that since the influence of testing time is small, the high-temperature yield point of steel furnishes sufficiently reliable and concordant values up to about 350° C. (and a maximum of

Jan 1, 1934

By Sushil Bhandari, S. S. Rathore

Controlled drilling and blasting continue to be an important method of block production and for block splitting. Drill and blast technique has disadvantage that sometimes, it produces cracks in uncontrolled manner and also produces micro cracks in the block as well as in remaining rock, if not carefully carried out. Recovery by this method is low compared to other methods. Therefore, attempts have continued to develop controlled growth of crack in desired direction. In this paper a series of tests are described using detonating fuse in marble. Economics of different methods is also compared. In comparison to conventional use when holes are lined with inexpensive cardboard or plastic liners with a slit, the cost and damage is the least and development of crack is in desired direction.

Jan 1, 2002

By M. A. ENCINAS-ROMERO, G. TIBURCIO-MUNIVE, P. GUERRERO-GERMÁN, M. M. SALAZAR-CAMPOY, J. L. Valenzuela-García, L. S. QUIRÓZ-CASTILLO, J. R. PARGA-TORRES

Simultaneous alkaline pressure oxidation and sodium cyanide leaching treatments on a pyritic ore from Mulatos Mine located in Sahuaripa, Sonora, Mexico, were carried out. Mineral characterization, agitated leaching, hot cyanidation under atmospheric pressure conditions, simultaneous moderated pressure oxidation and leaching, and kinetic tests results are shown. The modified variables were temperature, pressure, and cyanide concentration. Characterization indicated that pyrite was the main mineral. Simultaneous pressure oxidation and leaching experiments were conducted in a temperature range of 40 to 80 °C, an oxygen pressure range of 87.5 to 200 psi, and cyanide concentration range of 0.8 to 1.2 weight percent in a 2-L Parr pressure reactor. Dissolution rates of 81 to 86 percent were achieved under the following conditions: 87.5 psi, 80 °C, 0.8 weight percent NaCN and processing time of one hour.

By N. J. Shackleton, N. A. Chapman, V. Malysiak, C. T. O’Connor

In this study, the effect of using conventional crushing and high-pressure grinding rolls (HPGR) in combination with dry or wet milling was investigated using a base-metal sulphide (BMS) sphalerite and a platinum group mineral (PGM) ore to determine how these processes affect the flotation performance. In sphalerite, irrespective of the crushing procedure (HPGR or conventional), dry milling resulted in the highest grades and recoveries of zinc, whereas in PGMs, similar treatment produced the poorest results. The results were investigated further by the effect of factors such as percentage liberation and particle size on the flotation results.

Jan 1, 2012

By Jafar Safarian, Manish Kumar Kar, Ahmad Hassanzadeh, Casper van der Eijk

To minimize the carbon footprint in the industrial valourization of bauxite residue, hydrogen was used as a reducing agent. The current study experimentally investigated hydrogen reduction of bauxite residue-CaO sintered and self-hardened pellets at 1000 °C, along with magnetic separation of these reduced pellets for iron recovery. Calcium was introduced to bauxite residue to form leachable calcium aluminate phases with the existing alumina in bauxite residue. This involved the addition of either CaCO3 or a mixture of CaO and CaCO3 while maintaining the fixed Ca content during pelletization. The former underwent sintering at 1150 °C, while the latter was self-hardened through the cementing effect of CaO in exposure to moisture and air. Both types of pellets were reduced in a thermogravimetry furnace at an elevated temperature under similar conditions. The pellets were characterized by the X-ray diffraction (XRD) method and scanning electron microscope (SEM) coupled with energy dispersive spectroscopy (EDS), and their physical and mechanical properties were measured via standard techniques. During hydrogen reduction, a negligible amount of gehlenite ( Ca2Al2SiO7) was formed in the self-hardened pellets, while this phase dominated in the sintered pellets. Alumina in the bauxite residue converted to mayenite phases during reduction in both the pellet types; however, reduced self-hardened pellets had a higher amount of alumina containing mayenite leachable phase. The two pellets showed similar reduction behaviour, while different chemical, physical, and mechanical properties were observed. The magnetic properties of milled reduced pellets were examined through a Davis Tube magnetic separator in a wet environment under a constant magnetic field of 800 G. Higher iron recovery was observed for the self-hardened reduced (41%) pellets than for the sintered pellets (27%).

Nov 23, 2023

By E Donskoi

In order to develop downstream processing routines for iron ore and to understand the behaviour of the ore during such processing, extensive mineralogical characterisation is required. To determine mineral associations, mineral liberation and grain size distribution, imaging techniques have to be used. There are two main imaging techniques used for the characterisation of iron ore, ie, Optical Image Analysis (OIA) and Scanning Electron Microscopy (SEM). In this article a QEMSCANTM system is used as an example of SEM methodology and results obtained from it are compared against results obtained by the CSIRO ‘Recognition3/Mineral3’ OIA system.Both OIA and QEMSCANTM systems have advantages and drawbacks. Even though the latest QEMSCANTM systems can distinguish between major iron oxides and oxyhydroxides, it is still problematic for QEMSCANTM to distinguish between iron ore minerals very close in oxygen content, eg haematite and hydroheamatite, or between different types of vitreous goethite.QEMSCANTM also can misidentify minerals with close chemical composition, ie haematite as magnetite and vitreous goethite as haematite. In OIA, iron minerals with slight differences in their oxidation or hydration state are more easily and directly recognisable by correlation with their reflectivity. In both methods, the presence of microporosity can result in some misidentification, but in SEM methods misidentifi cations due to microporosity can be critical. Low resolution during QEMSCANTM analysis can significantly affect the textural classifi cation of particle sections.The main conclusion of this study is that, for low iron content ores or tailings, QEMSCANTM can provide much more detailed information on the gangue minerals than OIA. However, for routine characterisation of iron ores with high iron content and containing a variety of iron oxides and oxyhydroxides, OIA is a faster, more cost-effective and more reliable method of iron ore characterisation. A combined approach using both techniques will provide the most detailed understanding of iron ore samples being characterised.

Jul 11, 2011

By M. Evertsson, K. Bhadani, E. Hulthén, M. Bengtsson

"Modelling and simulations for mineral processing plants have been successful in replicating and predicting predefined scenarios of an operating plant. However, there is a need to explore and increase the potential of such simulations to make them attractive for users. One of the tools to increase the attractiveness of the simulations is through applying optimization schemes. Optimization schemes, applied on mineral processing simulations, can identify non-intuitive solutions for a given problem. The problem definition itself is subjective in nature and is dependent on the purpose of the operating plant. The scope of this paper is to demonstrate two optimization schemes: Multi-Objective Optimization (MOO) using a Genetic Algorithm (GA) and Multi-Disciplinary Optimization (MDO) using an Individual Discipline Feasible (IDF) approach. A two stage coarse comminution plant is used as a case plant to demonstrate the applicability of the two optimization schemes. The two schemes are compared based on the problem formulations, types of result and computation time. Results show that the two optimization schemes are suitable in generating solutions to a defined problem and both schemes can be used together to produce complementary results. INTRODUCTION The comminution process for a mineral processing plant consists of multiple crushing and classification stages and aims to produce fine material to liberate ore from the minerals. The modelling and simulation of such processes are well established using static process models (King, 2001; Napier-Munn et al., 1996). A recent development in the dynamic modelling for such processes has shown further increase in fidelity compared to the static process models (Asbjörnsson, 2015). The developed simulations can be utilized to design, operate and control mineral processing plants based on the requirements of users (Bhadani et al., 2017). Typically, the requirements in the operation of the comminution process are conflicting in nature, as for instance, reduction of power draw by process units, maximization of production of fine materials, and increasing utilization of the process units. These conflicting requirements leads to a Multi-Objective Optimization (MOO) problem to operate a mineral processing plant. The MOO problems are normally referred to as non-linear problems and its fundamental understanding with respect to process behaviour is difficult to achieve."

Jan 1, 2018

By F. Wendling, R. C. Nascimento, S. S. Wendling

"The objective of this research is to study the quality of blast-furnace iron ore pellets with binary basicity 1 fired on a pilot scale using the two main firing processes that are presently in use in the world and comparing them. Currently, the great majority of pellet producers use the traveling grate process because of its higher production capacity. In this study, the physical and chemical qualities of the pellet feed, limestone, anthracite and bentonite were determined and the amount of additives for a blast furnace pellet with the defined basicity was calculated. The physical properties of the green and dried pellets were determined accordingly. Produced pellets, after being fired on a pilot scale using traveling grate and grate kiln, were subjected to chemical analysis and physical testing. No significant difference was observed in the metallurgical quality — that is, reducibility index (RI), reducing disintegration index (RDI) and swelling index (SWI) — of the pellets produced by both processes. However, a comparison of cold physical tests — tumble and cold compression strength — shows improved quality of the pellets fired using the grate kiln process.IntroductionThe development of human civilization owes much to iron and steel (Sun et al., 2015). Iron is the most used metal in the world, and it is the main component of steel, which is present in materials for structural engineering, automotive and general industrial applications (Liu et al., 2014). Increased global demand has led to a decrease in the resources of ore with high iron content (Zhang et al., 2015), and currently 95 percent of the iron ore in China needs processing before smelting as its iron (Fe) content is only about 30 percent on average (Liu et al., 2014).Pelletizing is a process to economically agglomerate iron ore pellet feed into pellet form. After balling, green pellets are conveyed to the final step of the manufacturing process (Pena, 1982). The process is a multifaceted one, involving high temperatures, air flow gas turbulence and complex equipment geometry (Larsson et al., 2009). The pellets are fed into blast furnaces, which are now predominantly used in the extraction of iron. Ore processing also requires physical separation, including crushing, grinding and water removal (Sun et al., 2015).The increase in steel consumption favors the exploitation of low-concentration ores and the production of pellets (Halt and Kawatra, 2014). Pellet quality is affected by various factors, such as their physical and chemical characteristics and their temperatures and residence times in the furnace (Halt, Silva and Kawatra, 2015). Different geological settings lead to a wide range of different minerals (Graça et al., 2015).This work aims to generate important information for the pellet industry in the area of physical and metallurgical qualities of the agglomerates obtained by two processes: traveling grate and grate kiln."

Jan 1, 2017

By P. N. Anyalebechi

The effects of solidification rate on the cast microstructures of aluminum alloys 6009 and 6016 have been investigated with directionally cooled laboratory-size ingots, at 0.2-10.1 K/s and 0.4- 23.1 K/s, respectively. These ranges of solidification rate are within those observed in commercial-size ingots. In both alloys, the average dendrite cell size and second phase particle size decreased with increase in average solidification rate and with a decrease in average local solidification time. However, at comparable solidification rates, the dendrite cells and second phase particles are finer in the shorter freezing range alloy 6009 than in the longer freezing range alloy 6016. This is provisionally attributed to the earlier formation of second phase intermetallics at higher temperatures during solidification and to the formation of greater amount of the relatively coarse plate-like ß -phase (Al9Fe2Si4) phases in alloy 6016. In general, in both alloys, the types and relative amounts of the second phase particles in both alloys are independent of solidification rate.

Jan 1, 2006

By R. W. Lai

Cyclic voltammetry (CV), flotation response, evolved-gas analysis (EGA), and X-ray photoelectron spectroscopy (XPS) were employed to evaluate the major differences in the surface property and surface reactivity of coal pyrite and mineral pyrite.

Jan 1, 1989

By N. A. Chapman

The effect of using conventional crushing and HPGR in combination with dry or wet milling was investigated using a base metal sulphide (sphalerite), and a PGM (platinum group minerals) ore in order to determine how these different processes affect the flotation performance. In the case of sphalerite, irrespective of the crushing procedure (HPGR or conventional), dry milling resulted in the highest grades and recoveries of zinc. Conversely, in the case of PGMs, a similar treatment produced the poorest results. The results were investigated further by comparing the relative effects of factors such as percentage liberation, particle size, and surface properties of the samples produced by the different milling procedures as well as the concentrates and tailings obtained from the flotation tests.

Jan 1, 2013

By Khamis Y. Haramy

This paper summarizes ground control studies of longwall panel entry systems in two Western U.S. coal mines. Presented are comparisons of in situ pressure change measurements and assessments of chain pillar and entry behavior under a wide range of cover. Results indicate that no one entry system design is universally applicable, and that site-specific factors need to be considered for panel entry design. Relationships between overburden depth, face advance, and magnitude and location of the forward abutment are discussed for western operations. In addition, analysis indicates that use of yield pillars may reduce or eliminate some stress-related problems that plague longwall panel entry design.

Jan 1, 1989

By C. Pelley, S. Kelebek, T. Katsabanis, B. Nanthakumar

"As part of a larger investigation on generation of fines from mining activities and their effect on downstream operations, ore samples from Onaping area stockpiles of Falconbridge Ltd were studied. Batch flotation tests were conducted on the stockpile samples and fresh ore samples to explore the effect of stockpiling on grade-recovery performance. Head grade and particle size distribution of the samples from stockpiles were adjusted so that the samples compared are similar to each other. In additional tests, fresh ore samples were blended with stockpile samples at various percentages, representing 27.4, 50.2 and 81.5% of stockpile samples.The samples from stockpiles produced inferior nickel grade-recovery curves compared to fresh ore. The poorer grade-recovery performance was attributable to two factors. First, a significant dilution effect was observed due to the nearly complete flotation of pyrrhotite. Secondly, while pyrrhotite from stockpiled ore became highly floatable, the same stockpiling conditions caused nickel losses that were attributable to non-floatability of some pentlandite.In the case of blending, there was generally insignificant difference in the nickel grade-recovery between fresh and blended samples when the blending cases involved 27.4 and 50.2% stockpile samples. However, an increase in pyrrhotite recovery was observed for both blending cases. At 81.5% blending case, degraded grade-recovery was significant primarily due to the nearly complete flotation of pyrrhotite. There was a small, but noticeable amount of nickel loss for this case. However, for lower ratios of blending this loss was negligible.The increase in pyrrhotite recovery was partly attributed to its activation by Cu and Ni ions. Formation of a significant amount of elemental sulphur was also apparent from analysis of stockpiled samples. It can be concluded that pyrrhotite is mildly oxidized under stockpiling conditions while part of the pentlandite undergoes a more severe oxidation."

Jan 1, 2006

By X. M. Zhou, T. Wu, He X. N.

"In order to study the support effect of concrete in the surrounding rock of a metal mine, the concrete and surrounding rock were comparatively studied. Firstly, the general situation of the ultra-kilometer deep shaft in Xincheng, surrounding rock and geological conditions are introduced. Secondly, the experimental scheme of material mechanical properties of surrounding rock and shaft lining concrete based on same standard dimension and shape are examined, and the mechanical tests of rock and concrete based on different shapes and sizes are carried out. The study shows that the compressive strength value and elastic modulus of the rock cube are 1.28 times and 1.78 times that of the cylinder, and the Poisson's ratio is 0.77 times. The dimensional effect law of the concrete cube and cylinder test data is consistent with the rock law. However, the test results of the concrete are less discrete than the rock; the test also shows that the strength and elastic modulus of the concrete lining of the main shaft of the Xincheng are much smaller than the surrounding rock that is also used as the concrete aggregate, which indicates that the support of concrete lining in the surrounding rock shaft behaved weakly. Based on the development of the modern NATM rock support theory, it is suggested that the mechanical test standard of artificial support materials should be unified into the mechanics test standard of natural rock, which will help to improve the accuracy and practicality of scientific calculation of geotechnical engineering.INTRODUCTIONConcrete and rock mass are usually attributed to a class of materials called frictional materials or geotechnical materials, of these two kinds of materials, the first is man-maded and the second is natural. The attentive scholar can find that there are many differences in the test criteria for the mechanical properties of the two kinds of materials among different industries or departments, reflecting the differences in their sources, tradition, and the application thoery of material strength among them.There is a situation wordwide, that there are many testing standards of the same material mechanical parameters such as elastic modulus, compressive strength, etc. The cube with a side length of 150 mm is adopted as a common sample in the architecture department in China, while a cylinder with a diameter of 50 mm and a height of 100 mm is as a standard specimen in geotechnical department.Knowing that mechanical parameter values are strongly affected by the the size, shape of specimen and loading rate etc, that is to say the mechanical parameter values of the same material are completely different when obtained from different test with different standards. However, such a problem has been long neglected in geotechnical engineering."

Jan 1, 2019

By Tiruvengala Padma, Nilesh Naik

Piles are common type of deep foundation elements used for the special bridges, transmission towers, Jetties, and tall structures. Lateral loads on the structures can be due to either earth pressures, wind, waves, impact, moving vehicles and eccentric application of axial loads or in combination of the loads. Hence the lateral capacity of piles plays a major role in determining the pile dimensions. The laterally loaded pile analysis is a soil-structure interaction problem as the lateral capacity of pile depends on the soil strength and stiffness parameters and its reaction to the lateral load on pile. The common approach to determine the lateral load analysis of piles is the Beam on Lateral Springs Method also known as “p-y” method. In this method the pile is modelled as a beam and supporting soil is modelled as lateral springs. This study is focused on the comparison of output obtained from three geotechnical softwares namely FB-MultiPier, L- Pile and Wallap. L-Pile Software is based on Finite Difference Method, Wallap on Horizontal Subgrade Modulus Method and FB MultiPier on Finite Element Method. Pile response in terms of deflection, shear force and bending moments under vertical and horizontal loads from above three software are compared and concluded.

Sep 1, 2022

By Qingchun Yu, Bin Yang, Yong Deng, Heng Xiong, Fei Wang, Minxiu Chen

"Metal aluminum produced by non-electrolysis process received much attention due to its lower energy consumption. In this paper, carbothermic reduction and carbothermic-chlorination of alumina in normal pressure and vacuum were studied. The products were examined by means of XRD, EDS and SEM. During the carbothermic reduction process using carbon reductant in normal pressure, no metal aluminum was found. However, when coal was used as reductant, a mixture containing metallic aluminum, A14C3, and silicon was obtained, but metallic aluminum couldn't be separated from the mixture. During the carbothermic-chlorination process in vacuum, Al404C and Al4C3 were produced by the reaction between alumina and carbon, and Al Ch gas reacted with Al404C and Al4C3 to produce Al Cl gas. Metallic aluminum was produced due to the disproportionation of A!Cl gas and condensed on the collecting plate. Meanwhile, the initial temperature of carbothermic reduction of alumina reduced in vacuum compared with that in normal pressure.IntroductionIndustrial production of primary aluminum is carried out in alumina cell by the so-called Hall- Heroult process, necessitating the use of very high currents of low voltage. The alumina from which metallic aluminum is gained must be chemically pure, otherwise impure metal results. The main drawbacks of the electrolytic production are its very high energy consumption, the release ofperfluorocarbons, and the high specific C02 emissions [1]. During the past years, there were a lot of attempts to produce metallic aluminum by carbothermic reduction of A1203 [2, 3]. Cox [4] determined the vapor pressure over the A1203-C system and performed X-ray diffraction analysis of condensed products. It was demonstrated that an increase in the carbon content in the system leaded to the sequence of transitions: A1203~Al404C~A1zoc~A14C3 ~AI [5]. In any carbothermic reduction process for aluminum, extremely high temperatures (2000 °C ) were required [6]. In spite of considerable effort, the carbothermic reduction of alumina to aluminum remains a formidable technical challenge, due to the high temperatures required, and to the formation of aluminum carbide and oxycarbide byproducts [7]."

Jan 1, 2013

By Qingchun Yu, Bin Yang, Yong Deng, Heng Xiong, Fei Wang, Minxiu Chen

"Metal aluminum produced by non-electrolysis process received much attention due to its lower energy consumption. In this paper, carbothermic reduction and carbothermic-chlorination of alumina in normal pressure and vacuum were studied. The products were examined by means of XRD, EDS and SEM. During the carbothermic reduction process using carbon reductant in normal pressure, no metal aluminum was found. However, when coal was used as reductant, a mixture containing metallic aluminum, A14C3, and silicon was obtained, but metallic aluminum couldn't be separated from the mixture. During the carbothermic-chlorination process in vacuum, Al404C and Al4C3 were produced by the reaction between alumina and carbon, and Al Ch gas reacted with Al404C and Al4C3 to produce Al Cl gas. Metallic aluminum was produced due to the disproportionation of A!Cl gas and condensed on the collecting plate. Meanwhile, the initial temperature of carbothermic reduction of alumina reduced in vacuum compared with that in normal pressure.IntroductionIndustrial production of primary aluminum is carried out in alumina cell by the so-called Hall- Heroult process, necessitating the use of very high currents of low voltage. The alumina from which metallic aluminum is gained must be chemically pure, otherwise impure metal results. The main drawbacks of the electrolytic production are its very high energy consumption, the release ofperfluorocarbons, and the high specific C02 emissions [1]. During the past years, there were a lot of attempts to produce metallic aluminum by carbothermic reduction of A1203 [2, 3]. Cox [4] determined the vapor pressure over the A1203-C system and performed X-ray diffraction analysis of condensed products. It was demonstrated that an increase in the carbon content in the system leaded to the sequence of transitions: A1203~Al404C~A1zoc~A14C3 ~AI [5]. In any carbothermic reduction process for aluminum, extremely high temperatures (2000 °C ) were required [6]. In spite of considerable effort, the carbothermic reduction of alumina to aluminum remains a formidable technical challenge, due to the high temperatures required, and to the formation of aluminum carbide and oxycarbide byproducts [7]."

Jan 1, 2013

By H. -U. Lim, C. -H. Kim

The sixth underground pumped powerhouse cavern is under construction now in Korea. For the stability analysis of the five underground powerhouses, finite element method was used. For this analysis, in-situ rock stresses were measured by overcoring method and horizontal to vertical stress ratio was calculated 1.07-1.32 at four sites. Rock mass strength and elasticity were assumed from intact rock properties. The ratio of elasticity of rock mass was 0.16-0.55 of intact rock core elasticity. In general, elasto-plasticity with Mohr-Coulomb failure criterion was applied and the input cohesion and internal friction angle were approximately 0.12-0.22, 0.6-0.87 of intact rock strength parameters, respectively. Der sechste Untergrund-gepumpt-Powerhouse-Cavern ist jetzt im Bau in Korea. Für die vergan-gene Stabilitätsanalyse des fünf unterirdischen Powerhouses in Gebrauch wurde ein begrenztess Elementsmethode benutzt. Für die Analyse wurden In-Situ Felsenspannungen von overcoring Methode gemessen und Horizontale zu senkrechtem Spannungsverhältnis waren als 1.07-1.32 an vier Stellen kalkuliert. Felsenmassenkraft und Elastizität wurden von unversehrtem Felsenei-gentümern angenommen. Das Verhältnis der Elastizität von Felsenmasse war 0.16-0.55 von un-versehrter Felsenkernelastizität. Im allgemeinen wurde Elasto-Plasticity mit Ausfallskriterium des Mohr-Coulombs verwendet. Die Eingabebindekraft und die innere Reibungswinkel waren unge-fähr 0.12-0.22, 0.6-0.87 von unversehrtem Felsenkraftsparametern, jeweilig. En Coree, la sixieme centrale souterraine de la pompe d'accumulation dans la caverne est en construction. La methode d'element fini a ete utilisee pour analyser la stabilite de cinq dernieres centrales en service. Dans cette analyse, la reaction de la roche sur place etait mesuree par la methode d'overcoring et celle du rapport horizontal-vertical etait calculee de 1.07-1.32 en quatre places. L'intensite et l'elasticite de la masse de roche ont ete estimees de la roche intacte. Quant a l'elastic-ite, sa masse de roche etait 0.16-0.55 fois que celle de la roche intacte. En general, elasto-plasticite avec le critere de defaut Mohr-Coulomb etait utilisee et sa cohesion d'energie et son angle de friction interieure etaient supposees respectivement 0.12-0.22, 0.6-0.87 fois que la parametre de l'intensite de roche intacte.

Jan 1, 2003

By Carla Lupi

Zinc electrowinning from sulfate solutions is the traditional industrial method to produce SHG zinc. Over the past few years several efforts have been done to improve process efficiency in order to reach high productivity with low energy requirement. The latter aim can be pursued both by means of a hard purification of the electrolyte and reducing the anodic voltage. This work is a comparative study of the results obtained in several previous researches on zinc electrowinning from both sulfate and chloride solutions. Zinc electrowinning tests on industrial sulfate solution have been carried out by using Pb alloy anodes and by adding organic depolarizers such as ethanol, acetic acid or ethylene glycol. Experiments on chloride solutions, obtained by purification of zinc exhausted electrolyte, have been performed by using DSA anodes and by testing the effect of additives such as TEACI and TBAC\. Comparing the best results obtained with the two methods it can be highlighted that a high quality zinc is electrowon in both cases with comparable energy requirements.

Jan 1, 2000