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By A. E. Torma

In recent years the copper industry has gained considerable economic stability. An essential part of this industrial wealth is attributable to the successful application of bio-mediated heap and dump leaching techniques in the recovery of copper from low-grade resources. This study evaluated the leachability of a chalcopyrite conlentrate using naturally occurring mixed culture of predominantly Thiobacillusferrooxidans and Thiobacillus thiooxidans. For the effects-of pulp density, the overall reaction rate constant (k) and the order of reaction (n) have been determined to be 1.93 h-1 and 1.36, respectively. Cyclic voltammetric measurements revealed that intermediate reactions are involved in the chalcopyrite oxidation. Using the Price approach, it was shown that the dissolution of chalcopyrite is solid state diffusion controlled.

Jan 1, 1992

Bioleaching of E-Wastes

Sep 13, 2010

By Y. Lv, H. Ye, D. Du

Electrolytic manganese residue (EMR) is a kind of industrial solid waste with high silicon content that contains harmful metal elements such as chromium (Cr), copper (Cu), lead (Pb), cadmium (Cd), nickel (Ni) and cobalt (Co). Developing a highly effective and environmentally friendly process to treat EMR is important, both for the reutilization of metal resources and for environmental sustainability. In this study, the bioleaching of available silicon from EMR using silicate bacteria is investigated, with flask experiments conducted to optimize the parameters in the bioleaching system. For metal ions, the concentrations of manganese (Mn), Co, Ni and Pb in solution were measured to determine the environmental safety effects before and after bioleaching. The results show that the bioleaching rates of available silicon in the slag were mainly affected by the temperature, pH and pulp density. Under the optimal conditions of temperature of 30 °C, pH of 7.0, pulp density of 5 percent, shake flask rotational speed of approximately 210 rpm, particle size of approximately 0.150 mm and leaching time of 16 d, the concentrations of available silicon in the bioleaching system rose to approximately 110 to 140 mg/L. The metals remaining in the residues were mainly bonded in stable fractions, with concentrations lower in the leachate after bioleaching. This study demonstrates that silicate bacteria can be used to increase the contents of available silicon from EMR, and that bioleaching technology can realize the harmless resource utilization of EMR.

By D. Morin

A general study of gold refractory arsenopyrite-pyrite concentrate bioleaching has been carried out including two continuous bioleach testworks at different sizes, namely one at a laboratory scale with a 100 I unit at a 2 kg/d dry solid flowrate and the other at a pilot scale at a 100 kg/d dry solid flowrate. Both tests show a 80% bioleaching of arsenopyrite in about four days of treatment and with the same kinetic. Pyrrhotite is attacked at the earlier stage of the bioleaching but pyrite remains unaffected. The weak potential of oxidation associated with the decomposition of arsenopyrite and the abundance of arsenite leads to a high grade of elemental sulfur in the bioresidue which consumes the major part of the cyanide during the gold recovery. Furthermore. the arsenite and ferrous produced in solution have to be oxidized to obtain a stable precipitate in the waste products and as outlined in previous works of other authors on this subject the addition of iron to obtain a Fe/As molar ratio at least above 3 is necessary. The agitation equipment used in the pilot unit allowed an optimization study calculation for scaling-up the design and power requirements of an industrial installation. For the pretreatment of a gold refractory As high-graded concentrate the reagent cost has the greatest part in the operating cost of the biooxidation step due to the necessary retreatment of the biosolution. In that conditions the power cost is quite marginal. actually it is significant for the treatment of pure pyrite.

Jan 1, 1991

By A. F. Neil, A. S. Bahaj, P. Watkins, P. M. Hyslop, C. E. Kirby, P. A. B. James

The results of initial work indicate that for 3 of the 5 quarry sands bioleaching reduces the iron oxide content to a commercially acceptable 0.035 wt% Fe20 3, although the time taken to achieve this is 14-22 days against a target leach time of 7 day. Subsequent work has identified strains of Aspergillus niger that are more efficient at producing the array of complexing agents for iron and is yielding excellent and rapid reductions in Fe levels. Potentially, bioleaching offers a more environmentally friendly and energy-efficient process for the removal of Fe from glass-making sands than conventional routes but the production of organic acids by fermentation must be achievable with low-cost substrates such as sugar-beet molasses and lactose permeates for bioleaching to offer a commercially viable alternative to treatment with hot mineral acids. Silica sands usually contain three groups of Fe minerals: iron oxyhydroxides, which comprise crystalline types such as goethite and limonite tending to occur as thin, discontinuous coatings and in cracks and crevices on the surface of the quartz; the assemblage of heavy trace minerals, which include ilmenite, rutile, leucoxene, chromite and haematite, commonly present at levels of 0.1 wt% or less as discrete grains or sometimes cemented to the quartz; and clay minerals cemented in pits on the surface of the quartz and in association with weathered, discrete feldspars. The response of the assemblage of iron minerals to short periods of exposure to hot inorganic acids is broadly related to which group they belong to, those that form coatings being accessible to acid and tending to react rapidly whereas the trace minerals are usually resistant and react very slowly, if at all, and the clays are probably digested. The note reports on a preliminary study of the use of microorganisms to develop an alternative clean technology that will give results comparable to those achievable with hot inorganic mineral acids but with more environmentally acceptable procedures. Various fungi and bacteria produce organic acids when grown in certain media. When these acids come into contact with Fe-stained sand grains the iron is removed as soluble complexes. Several strains of Aspergillus niger have been found to produce organic acids from sugar, predominantly citric, gluconic and oxalic acids, their relative yields depending on cultivation medium and conditions. Sand samples were prepared from five quarries in the UK: Levenseat, Lothian; Redhill, Surrey; King's Lynn, Norfolk; Chelford, Cheshire; and Oakamoor, Staffordshire; ranging in iron oxide content from 0.035 to 0.153 wt% Fe203

Jun 18, 1905

By E. G. Noble

The potential for using heterotrophic microorganisms to solubilize manganese from low-grade domestic ores is being assessed at the Reno Research. center, U.S. Bureau of Mines. More than 90 pct of the manganese has been extracted from a variety of oxide ores in shake-flask tests using molasses as a source of .. nutrients for the microorganisms. It has also been demonstrated that high recoveries of manganese can be obtained from a domestic wad ore using column bioleaching. 'l'he isolation and identification of organisms responsible for manganese extraction is discussed, as are the mechanisms responsible for manganese solubilization.

Jan 1, 1991

By H. B. Zhou

The process of bioleaching marmatite using moderately thermophilic bacteria has been studied in this research by comparing marmatite leaching performance of mesophilic bacteria and moderately thermophilic bacteria and valuating the effect of venting capacity on marmatite leaching performance of moderately thermophilic bacteria and the effect of pulp densities on marmatite leaching performance of moderately thermophilic bacteria. The results show that moderately thermophilic bacteria have more advantages over mesophilic bacteria in bioleaching marmatite. Aeration agitation can improve the transfer of O2 and CO2 in solution and promote the growth of bacteria and therefore, enhance the leaching efficiency. With the increase of pulp density, the total leaching amount of valuable metals increased, however, the extraction efficiency decreased due to many rea-sons, like increasing shear force that results in poorly growth condition for bacteria, etc.

Jan 1, 2014

By Z. Y. Lan

Bioleaching of marmatite with various mixed cultures of microorganisms was investigated. The experiments were carried out in shaking flasks with iron-free nutrient and the pulp density of 10% wt/vol at the temperature of 30?. The results show that zinc is preferentially leached before iron. The leaching rate of zinc with the mixed culture of Acidithiobacillus ferrooxidans, Acidithiobacillus thiooxidans and Leptospirillum ferrooxidans is 62% in 18 days. The leaching rate of zinc with the mixed culture of Acidithiobacillus ferrooxidans and Acidithiobacillus thiooxidans is nearly the same as that with the mixed culture of Acidithiobacillus ferrooxidans and Leptospirillum ferrooxidans (45% versus 50%). SEM and EDX analysis of the leaching residues indicate that a solid product layer composed of iron sulfide, elemental sulfur and jarosite accumulates in the mineral surface and becomes a barrier to the dissolution of marmatite. The bioleaching of marmatite follows the shrinking core product layer model. When the product layer increases and becomes insoluble, the leaching rate is controlled by the diffusion through the product layer and slows down. When the product layer decreases or becomes a porous layer, the leaching rate is controlled by chemical reaction and enhanced dramatically.

Jan 1, 2014

By Vijaya Thangavelu

Biological leaching of low-grade nickel laterite is based on a non-traditional leaching of oxide minerals using heterotrophic micro-organisms. The organisms solubilise metals by excreting organic acids; these acids then form complexes with heavy metals. High salinity of water supplies and soils in the vicinity of nickel laterite ore bodies is a major abiotic stress to fungi and represents a major challenge in the application of bioleaching process in-situ. Salinity exposes fungi cells to Na+ toxicity and osmotic stress. This study examined the salt tolerance development of Aspergillus foetidus based on gradual acclimatization of organism, its salt threshold and the salinity effect on its metabolism. The biological leaching of weathered saprolite ore with the resulting halotolerant organism under saline conditions was assessed. It was observed that salinity stress affected the organism?s growth and energy utilization

Jan 1, 2006

By P Tzeferis

An exploratory laboratory work was carried out on microbial leaching of poor non-sulphide nickel ores, not amenable to conventional mineral processing operations. The results have shown that domestic low-grade lateritic ores of limonitic or haematitic type are amenable to bioleaching by fungal strains of Aspergillus sp and Penicillium sp. Maximum nickel and cobalt recoveries achieved were 60 per cent and 50 per cent respectively. Losses of soluble nickel in the fungal biomass were found in the range 3 - 11 per cent. Chemical analysis of the leach liquors showed the presence of significant amounts of citric, oxalic and other organic acids, indicating the role which certain metabolic products of fungal activity may play in the process. Possibilities for future investigations are discussed.

Jan 1, 1997

By Cheryl Devine, Radhakrishnan Mahadevan, Vladimiros G. Papangelakis, Srinath Garg

The microbial-mediated recovery of valuable metals locked in mining wastes presents an economical alternative to conventional hydrometallurgical processes. The present study investigated the bioleaching response of a low-grade nickeliferous pyrrhotite tailings (0.6 wt% Ni) and an upgraded pyrrhotite tailings (1 wt% Ni) produced by Vale Base Metals in the Sudbury Basin of Ontario, with the ultimate aim of maximizing Ni recovery. The initial part of the study focused on the bacterial adaptive evolution protocol, by repeatedly sub-culturing an indigenous culture from an acid mine drainage site on 2% (w/v) pyrrhotite tailings. The results showed that the extent of Ni dissolution is positively correlated with microbial activity. Microbial profiling revealed A. ferroxidans to be the dominant member of the microbial consortium. The enriched culture was used for optimizing the growth medium by varying the concentration of essential growth nutrients. Finally, an aerated biotic and abiotic leach of a 10% (w/v) upgraded pyrrhotite tailings with and without pH control, showed a higher recovery of Ni in the pH controlled experiments. These results demonstrate that a high concentration of the oxidant Fe3+ in solution promotes the dissolution of Ni. Furthermore, the sulphide conversion into So was found to be higher in the pH controlled experiments (32%), relative to the experiment without pH control (10%).

Jan 1, 2015

By E. Krause, V. G. Papangelakis, S. Garg, R. Mahadevan, E. Edwards

"Bioleaching uses iron and sulfur-oxidizing bacteria to extract base metals from sulfide minerals. As bioleaching involves breaking the iron-sulfur bonds by ferric attack, the biologically mediated rate of iron oxidation is recognized to play a key role in influencing the overall kinetics. In this study, we investigate the catalytic ability of an indigenous AMD culture for oxidizing Fe(II) in solution. This culture was subsequently adapted on pyrrhotite tailings (0.6% Ni) by gradually increasing the solids loading. Results from this study show that such an adaptation reduces the initial lag phase in the biotic oxidation of Fe(II), thereby allowing for a higher Ni extraction when compared to experiments with an un-adapted culture at a similar solids loading. The use of adapted cultures also helps to reduce the residence time for bioleaching of Ni from pyrrhotite tailings. INTRODUCTIONAs the world demand for pure base metals grows; the mining industry is increasingly faced with the burden of processing lower grade ores and mining waste streams in order to recover the occluded metal VALUES ((Watling, 2006). The extractive metallurgy of nickel from sulfide minerals focuses on using a combination of mineral processing, pyrometallurgical (smelting) and hydrometallurgical techniques to extract Ni from its ore bodies.Pyrrhotite (Fe1-xS) is commonly found in association with pentlandite and chalcopyrite in sulfidic Ni ores, such as those found in Sudbury, Ontario, and in Russia, e.g. Norilsk. The vast majority of this pyrrhotite needs to be removed using mineral processing techniques, in order to minimize the Fe and S contents of the concentrates that proceed on to smelting. If all pyrrhotite were left in the concentrate, much more slag and SO2 would be produced, and the smelter throughput would be limited. Beneficiation of Ni sulfide ores leads to the rejection of unwanted constituents as mining wastes, which may still contain extractable amounts of Ni (Edgar Peek et al., 2010)."

Jan 1, 2012

By Pierre Ollivier, Dominique Morin

A general study of gold refractory arsenopyrite pyrite concentrate bioleaching has been carried out including two continuous bioleach testworks at different sizes, namely one at a laboratory scale with a 100 1 unit at a 2 kg/d dry solid flowrate and the other at a pilot scale at a 100 kg/d dry solid flowrate. Both tests show a 80% bioleaching of arsenopyrite in about four days of treatment and with the same kinetic. Pyrrhotite is attacked at the earlier stage of the bioleaching but pyrite remains unaffected. The weak potential of oxidation associated with the decomposition of arsenopyrite and the abundance of arsenite leads to a high grade of elemental sulfur in the bioresidue which consumes the major part of the cyanide during the gold recovery, furthermore, the arsenite and ferrous produced in solution have to he oxidized to obtain a stable precipitate in the waste products and as outlined in previous works of other authors on this subject the addition of iron to obtain a Fe/As molar ratio at least above 3 is necessary. The agitation equipment used in the pilot unit allowed an optimisation study calculation for scaling-up the design and power requirements of an industrial installation, For the pretreatment of a gold refractory As high-graded concentrate the reagent cost has the greatest part in the operating cost of the biooxidation step due to the necessary retreatment of the biosolution, In that conditions the power cost is quite marginal, actually it is significant for the treatment of pure pyrite.

Jan 1, 1990

By Yasuo Kudo, Wu, Hayato Sato, Hiroshi Nakazawa, Shouming

"In order to recover copper from a waste nickel condenser powder, bioleaching experiments were carried out using Thiobacillus ferrooxidans in a shaking flask. The content of nickel and copper in the waste nickel condenser powder in this study were 8.0% and 3.5%. X ray analysis showed the peak of barium titanate. In the preliminary study using metal nickel and copper powders , the dissolutions of nickel and especially copper were accelerated with the addition of ferric iron in the bioleaching of nickel and copper powders while not in the absence of ferric iron. Ferric iron oxidizes both metals, and Thiobacillusferrooxidans oxidizes ferrous iron resulting from the oxidation of metals, whereby the dissolutions of metals proceeds. The dissolution rates of nickel and copper increased with increase in the concentration of ferric iron in the bioleaching of the waste nickel condenser powder.1. IntroductionNickel condensers rejected from manufacturing plants are crushed and landfilled. Waste nickel condensers contain nickel and copper and could be considered as nickel and copper ores. Since the capacity of landfills is diminishing, it is required to recycle metals of waste nickel condensers in order to reduce the amount of wastes landfilled. Conventionally, metals in the waste were recovered by dry metallurgy after the incineration.Nickel has been refined by solvent extraction - electrowinning method (SX-EW method). Recently the amount of copper refined by SX-EW method has increased (Takahashi, et al. 1994). This method is cleaner and consumes less energy than conventional methods. Nickel dissolved well in acid solutions, but copper is not. If copper is leached efficiently from a waste nickel condenser powder, SX-EW method will be applied to recover copper from them"

Jan 1, 2000

Bioleaching of Weathered Saprolite - Heavy Metal Adaptation Mechanisms of Aspergillus foetidus Nickel laterite ores remain important to the future supply of Ni and Co as they contain the bulk of known nickel and cobalt reserves (80 per cent and 90 - 95 per cent respectively). Current commercial extractions of Ni and Co from nickel laterite ores are energy intensive and operational costs are high. Microbial leaching of oxide ores has the potential to offer a much needed step-change in the technology for processing laterite ores. Biological leaching of low-grade nickel laterite is based on a non-traditional leaching of oxide minerals using heterotrophic micro-organisms. The organisms solubilise metals by excreting organic acids; these acids then form complexes with heavy metals. Optimisation of the process in in-situ application, however, has been hampered by the toxicity of the heavy metals that are being leached by the organisms. Our recent study has shown that organisms are able to develop tolerance towards heavy metals by adaptation. This study examined the extracellular metal detoxification mechanisms of A. foetidus in 0.2 per cent (wt/v) to 0.7 per cent (wt/v) of weathered saprolite ore. To support our analysis, FTIR, CHNS and microscopy were used to confirm the participation of specific functional groups in the extracellular detoxification process.

Sep 13, 2010

By F Battaglia-Brunet, D. H. Morin, Foucher S. ’

In the mineral-processing field, bioleaching of metal sulphide concentrates is currently operated in very large mechanically agitated tanks. Such bioreactors have considerable requirements in terms of power consumption for mixing, aeration and heat transfer. The use of slurry bubble column, where the particles are suspended by gas motion as well as by liquid upward flow, could be an alternative to achieve bioleaching in more economical conditions. In order to compare these two techniques, a unit of stirred reactors in cascade and a bubble column were comparatively operated at laboratory scale in the bioleaching of a pyrite concentrate. For both pieces of equipment, experiments were performed not only in batch mode but also in continuous conditions.

Jan 1, 2003

By Morin D. H., Battaglia-Brunet F., D'Hugues P.

"In the mineral-processing field, bioleaching of metal sulphide concentrates is currently operated in very large mechanically agitated tanks. Such bioreactors have considerable requirements in terms of power consumption for mixing, aeration and heat transfer. The use of slurry bubble column, where the particles are suspended by gas motion as well as by liquid upward flow, could be an alternative to achieve bioleaching in more economical conditions. In order to compare these two techniques, a unit of stirred reactors in cascade and a bubble column were comparatively operated at laboratory scale in the bioleaching of a pyrite concentrate. For both pieces of equipment, experiments were performed not only in batch mode but also in continuous conditions.Bubble column performances were significantly affected by unpredictable technical difficulties met to maintain continuous feeding in the bubble column and by a significant settling of the heavy solid particles. Nonetheless, theoretical kinetic data, extrapolated from results in batch conditions, could be compared to those obtained in continuous tests, in bubble column and in mechanically agitated reactors. These kinetic data were used to evaluate the influence of reactor design and configuration choice on bioleaching performances."

Jan 1, 2003

By D. Kidd, T. Tucker, L. M. Indergard, S. Davis

"INTRODUCTION The Lisbon Valley Mining Co LLC (LVMC) operates the Lisbon Valley Mine located in SE Utah. The mine includes 3 open pits, 150-acre heap leach pad, and solvent extraction electro winning plant (SX/EW). Approximately 25MM tons of ore has been mined since 2005. The ore is stacked on the leach pad to an average height of 55 feet and occurs as a blend of crushed material (minus 2”) and run-of-mine (minus 24”). The host rocks include Dakota and Burro Canyon Sandstones. Copper occurs finely disseminated in this material at an average grade of 0.46%. Minerology is 63% sulfide, 27% oxide, and 10% insoluble. Total inventory mined through 2016 is approximately 230 MM lbs. METALLURGICAL CONSTRAINTS Copper production is constrained by areas of low permeability ore and geochemical issues, including acid consumption. The intrinsic permeability the ore ranges from 10-2 to 1 Darcy. This permeability does not permit sufficient aeration by natural convection, therefore oxygen transport is largely limited to the mass of oxygen that can remain dissolved in leachates. As a result, greater than 50MM lbs of copper remains in inventory and occurs secondary sulfides, including chalcocite, covellite, and bornite. BIOLEACHING FUNDAMENTALS Due to the higher activation energies of secondary sulfides, notably covellite and bornite, a strong oxidant is needed to remove an electron from the metal-sulfide lattice and release the copper cation into the sulfate solution. This process occurs most efficiently using the strong oxidant ferric iron (Fe3+). Ferrous iron can be oxidized to ferric iron by oxygen via chemical oxidation or biologically; which was measured to occur 500,000 times faster when using microbes versus oxygen.1 The microbes that oxidize ferrous iron (Fe2+) to ferric iron are naturally abundant and will develop biomass when appropriate conditions and nutrients present themselves. Most nutrients are provided by the ore/irrigation (P,N,Mg, Ca & Fe2+) while the others (O2 and CO2) are provided by air. In most cases, oxygen transfer is the rate limiting step during copper sulfide leaching. 1 Lacey & Lawson 1970 FORCED AERATION SYSTEM DESIGN This paper describes LVMC’s efforts to bioleach the remaining inventory by forced aeration. Two basic aeration systems were installed and tested including vertical wells and horizontal piping. Vertical System The vertical system was installed using the mine’s blast hole drilling rig. Wells were constructed using 4” high-density polyethylene (HDPE) connected to 4” polyvinyl chloride (PVC) screens similar to conventional bioventing wells. Ore samples were collected at each well location to characterize the spatial distribution of the remaining inventory along with fines (minus 200 sieve), pH (acid consumption), and iron. A block model of each analyte was developed and mapped in 3D."

Jan 1, 2017

By M. Oliazadeh

The bioleaching of fine low grade copper sulfide ore is described. A sample of ground (> 1 mm) copper ore from Sarcheshmeh, Iran, was subjected to a series of agglomeration procedures and subsequently leached. The best agglomerate was obtained by using lime and sulfuric acid as binders. A column bioleaching test of agglomerated ore was then run for 105 days along with a non-inoculated control column having thymol as bactericide. The results show that about 77.5% of copper was extracted in the bioleaching, whereas the control column achieved only 57% copper leaching.

Jan 1, 2007

By Elmer Pabel Huayna Peraltilla

El proceso de lixiviación es un método para el tratamiento de minerales sulfuros y sulfuros mixtos que consiste en la utilización de un consorcio microbiano acidófilo y una solución rica en cloruro de sodio. En ese sentido, el presente texto destaca el método de la biolixiviación como la alternativa adecuada -en tanto solución ácida (cobre) que contiene el metal en su forma soluble. Dicho proceso se desarrolla en dos etapas: En la primera se usa una solución de cloruro de sodio, el compuesto protector, más un inóculo del consorcio microbiano. La mezcla permite obtener una recuperación de cobre de hasta un 80% basados en pruebas preeliminares. En la segunda etapa, se le agrega un agente oxidante, que no daña a las bacterias, con el fin de disminuir la pasivación del mineral y un inóculo fresco del consorcio y así prolongar la recuperación.

Sep 1, 2013