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By H. P. Kritzinger, T. C. Kingsley

Rotary kilns are used for a variety of mineral processing operations. Hatch makes use of a kiln model developed from first principles to evaluate designs for its clients. This tool has been applied to a variety of pyrometallurgical applications. This paper illustrates the application of numerical optimization techniques in combination with the kiln model in the interrogation of a generic iron-ore reduction process. The fundamental modelling concepts are explained, followed by a description of the optimization approach. The results show how the combination of the two methods, with modern computing power, can generate a large number of viable design and operating candidates.

Jan 1, 2014

By A. Golder, I. Roy

The Jayant opencast operation is one of the largest opencast coal mines in India. Prior to 2008 the mine experienced a number of dragline dump failures, which was a major hindrance in sustaining production. Northern Coalfields Limited (NCL) and the mine management engaged several design, research, and academic institutions to carry out dump slope stability studies, particularly of dragline dumps. BirlaInstitute of Technology prepared a report on the investigations in May 2009. In this paper we review the findings of the report and the measures taken to tackle the safety aspects of dragline dumps.

Jan 2, 2022

By Y. Yang, M. Zhang, X. Xia, S Shi, Z. Shen

A stepwise arrangement of flotation cells is the most common layout of a flotation circuit in the mineral processing industry. In such a design, slurry flows from upstream to downstream by means of gravity, and the middling products are returned to previous stages by pumps. This paper will introduce an alternative solution in which the forced-air and slurry-induced flotation cells are adopted so that all the flotation cells can be placed on the same horizontal platform and no pumps will be needed for middling product transferring. The technology of the forced-air and slurry-induced flotation cell will be described in detail, including unique features, the working principle and the related fundamental problems. The comparison of capital investment, operating cost and metallurgical performance will be made between the conventional stepwise arrangement and the samelevel arrangement technology based on industrial practice. Keywords: Forced-air and slurry-induced flotation cell, same-level arrangement, stepwise

Jan 1, 2020

By S. Kauvosaari, M. Olofsson, O. Haavisto, M. Kosonen, J. Martikainen

The target in grinding circuit operation is usually to maximise the throughput and energy efficiency while keeping the product particle size on an optimal level for downstream operations. Furthermore, feed ore variations in size and hardness need to be compensated in order to stabilise the process. This is a challenging task for any circuit and requires good instrumentation, combined with careful control design. This study investigates the control of a two-stage iron ore grinding circuit with an AG and pebble mill at LKAB Kiruna KA3 concentrator in northern Sweden. A new control approach based on multivariable model predictive control (MPC) is designed, implemented and evaluated for the circuit. Additionally, advanced instrumentation including a volumetric charge measurement for grinding mills is utilised. The MPC control approach starts with step tests that are used to model the effect of manipulated variables (MVs) like feed rate, water addition and primary mill speed on controlled variables (CVs) such as final product particle size, power consumption and volumetric charge of the mills. In the control implementation phase, the models are then utilissed together with current process measurements and known operating limits to predict optimal future changes for the manipulated variables in order to reach the desired process output values. It is shown that the new control approach improves the stability of the circuit and reduces energy consumption. Keywords: Model predictive control, grinding, optimisation

Jan 1, 2020

By Huanhuan SU, Jianqiang Zhang, Zhongyuan Liu, Junwei Ma

The high-sulfur bauxite in Henan Province was used as raw material. The grinding fineness, pH value and collector dosage on its desulfurization performance, and industrial flotation desulfurization process were studied. The best flotation desulfurization conditions were grinding fineness of 75%, pH of 8.5, and collector of 600 g/t. “One coarse, one cleaning and one sweep” closed-circuit flotation was established as the industrial flotation desulfurization process. After the closed circuit test, the sulfur content of aluminum concentrate with the yield of 93% was 0.23%, and the sulfur removal rate was 83.16%, and the sulfur content of tailings (sulfur concentrate) was 15.09%. Keywords：High-sulfur bauxite under coal mines, flotation, desulfurization

Jan 1, 2020

By V. Sheikhzadeh, M. R. Sheikhzadeh, A. Haratian, M. Zare

High Pressure Grinding Roll (HPGR) as an efficient grinding technology plays a major role in mineral processing plants. Investigating the effects of this technology on different parts of mineral processing circuits reveals this technology’s capability. In this paper, HPGR grinding effects on an iron ore beneficiation circuit, in comparison with conventional crushing systems were studied. A representative feed sample was taken from an iron ore beneficiation plant, then crushed to minus 6 mm in a laboratory by two methods: HPGR and cone crusher, and finally a concentrate plant circuit was simulated. Plant simulation was performed by doing laboratory tests consisting of grinding, magnetic separation, flotation and filtration on HPGR and cone crusher products, respectively. According to comminution tests results, in particle sizes smaller than 6 mm, a cone crusher product is coarser than an HPGR product. Also, the Bond ball mill work index of the HPGR product was 10% less than the crusher product. Therefore, based on the Bond formula in applying HPGR, ball mill power consumption decreased by 12%. After ball milling to minus 100 microns, magnetic separation tests results showed that the recovery of the cone crusher circuit output was 90.8% and the product Fe grade was 66.4%. For the HPGR circuit these figures were 87.6% and 67.3%, respectively. Therefore, by using an HPGR, a higher Fe grade of the final concentrate was achieved. A flotation test was then performed on the magnetic separation concentrate, where the results showed that the crusher circuit recovery and the sulfur grade of the product were 96.5% and 0.192%, respectively; whereas the HPGR circuit recovery was 97.2% with a sulfur content of 0.185%. Findings revealed that flotation performance in the HPGR circuit was more efficient than the crusher circuit. Vacuum filtration tests on concentrate produced through the HPGR circuit resulted in a moisture content of 12% that was 2% higher than the crusher circuit’s concentrate in the same condition. Keywords: High pressure grinding roll, power consumption, magnetic separation, flotation, filtration

Jan 1, 2020

By M. Mbonami, R. Pretorius, J. Miller, P. Kyony, B. Nel, N. Mautsa

Challenges due to the formation of stable froth in acid leach systems is common at many copper and Ccbalt producers. Stable froth affects downstream process, critical equipment, and operational parameters. In severe cases the froth present safety and environmental risks and increased operational costs. Solids reports in the pregnant leach solution, accumulates, and clogs launders resulting in a potential costly safety and environmental risk. Solvent extraction is operationally affected by crud formation, organic solvent and extractant losses, reduced mass transfer due to the solids carried downstream. This article reviews the generally inadequate mechanical and hydraulic solutions of froth elimination employed over the years. The recent introduction of a chemically based solution able to eliminate froth problems that can potentially turn around the situation for those who adopt the technology.

Jan 1, 2023

By K. Barani, S. M. S. Ganji

Creatine was used as a lixiviant for gold dissolution from gold ore. The effects of creatine concentration, temperature, leach time, and pH were examined for their influence on extent of gold dissolution. The results show that at a temperature of 75°C and pH 11.5, gold dissolution increased from 51% to 88% on increasing creatine concentration from 25 to 50 g/t. Further increase in creatine concentration showed a negative effect on the gold dissolution. Gold dissolution increased from 47% to 87% by increasing the temperature from 25°C to 55°C, and from 61% to 89% by increasing pH from 10 to 11.5. Under the optimum conditions of solids’ content of 30%, pH 11.5, creatine concentration of 100 g/t, temperature of 75°C, and hydrogen peroxide addition of 2%, about 90% of the gold could be dissolved from the ore after 24 h. A comparison between creatine and cyanide leaching showed that 90% gold dissolution was achieved at a cyanide concentration of 300 g/t, which is three times higher than the creatine concentration under optimal conditions.

Apr 14, 2024

By Y. G. Zhu, G. B. Zheng, X. X. Hu

Reverse flotation by cationic collectors is the classical method to reduce the silicon content in magnesite. But because of the low selectivity, there is a large loss of magnesite in the reverse flotation froth. To improve the efficiency of the collector, a novel collector named BK433 was developed in this paper. In order to determine the performance of the BK433 collector, a systematic experimental study was carried out with a high silicon magnesite in China. The suitable pH environment of slurry was confirmed, the depression effect of different depressants was investigated, and the flotation effect was compared with commonly used traditional collectors. The results show that the BK433 shows remarkable good selectivity and collection ability. After the 4 stages reverse flotation, the SiO2 content decreased from 3.76% to 0.25%, SiO2 impurity removal rate reached 94.69%. Meanwhile, the MgO content increased from 45.06% to 46.73%，the recovery of obtained concentrate (calculated by MgO) was 82.79%. Keywords: Magnesite, Desilicication, Reverse flotation, Collector

Jan 1, 2020

By M. R. MacIver, M. Pawlik, S. Finora, H. Alizadeh

The dispersion of mature fine oil sands tailings (MFT) by the addition of sodium lignosulfonate was studied using contact angle measurements, optical scattering, and particle size measurements. Lignosulfonate caused the release of residual bitumen to the slurry surface and settlement of fines. Dynamic contact angle by captive bubble measurements were carried out on bitumen to determine the effect of the dispersant on the wettability of bitumen. Lignosulfonate caused a change in the aggregation state of the MFT and increased sedimentation of particles, as indicated by optical scattering measurements. Zeta potential measurements indicate that this change was caused by an increase in adsorption of lignosulfonate onto particles, which caused improved settling of the colloid. Ultraviolet Visible (UV) spectrophotometry and organic carbon content measurements showed that only a small amount of the reagent remains in the aqueous phase of the tailings, which is critical for decontamination of recycled water. Keywords: Oil sands tailings, bitumen recovery, dewatering, dispersion, surface chemistry

Jan 1, 2020

By S. Ling, T. Liu, Y. Shang

A new copper-molybdenum flotation technology developed for a certain coppermolybdenum ore is introduced. We achieved copper-molybdenum bulk flotation in lowalkali conditions. Locked-circuit test results showed that the bulk concentrate contained 21.05% Cu and 1.10% Mo, with copper recovery of 87.37% and molybdenum recovery of 77.07%. For the copper–molybdenum separation process of the bulk concentrate, we use a new depressant, BK511, to replace the traditional sodium hydrosulfide. We achieved copper–molybdenum separation through one rougher, nine cleaner, and two scavenger processes. The results of locked-circuit tests showed that the molybdenum concentrate contained 46.19% Mo and 0.75% Cu, with molybdenum recovery of 93.80%; the copper concentrate contained 21.50% Cu and 0.069% Mo, with copper recovery of 99.92%. This new technology overcomes disadvantages of using large amounts of lime, sodium hydrosulfide, and other reagents in traditional copper–molybdenum flotation.

Jan 1, 2023

By A. C. Johnstone

The aim of the study is to determine if pit lakes are a sustainable coal mine closure option in South African. The water balance, chemistry, limnology, and bacterial population of three selected pit lakes were investigated. The lakes are in the three major coal basins of South Africa and are associated with different lithologies and mining methods. The major factors driving the water balance of the pit lakes are direct rainfall, runoff, inflow from old mine workings, and groundwater infiltration, with the major losses being evaporation or discharge onto surface. The study indicated that pit lakes can be designed as ’terminal sinks’ to provide a sustainable mine closure option. The pit lakes sampled have an alkaline pH, and mostly a sodium/calcium sulphate water with total dissolved solids content of less than 3000 mg/l. The phytoplankton and microbiological data indicates that the pit lakes support aquatic life. The study shows that correctly designed pit lakes can be an environmentally sustainable closure option for South Africa’s coal mines. A suggested design manual has been developed to assist mine owners and regulators in developing sustainable coal mine pit lakes as a closure option.

Oct 1, 2021

By F. Rosenblum, K. E. Water, J. A. Finch, S. Moon, Y. H. Tan

Previous work has shown that sulphide self-heating occurs in three distinct stages referred to as Stage A, Stage B and Stage C. In this paper the focus is on the transition from Stage A to Stage B, which occurs at ca. 100OC. Background literature hints that the transition corresponds to the transformation of the rhombic form of elemental sulphur to the more reactive monoclinic form that occurs at 96OC. A test apparatus is modified for adiabatic heating to track the transition. The results support this transformation of sulphur as being key to the transition, and the transition temperature is thus modified to 96OC. Variations in a sample’s response under adiabatic conditions are observed and possible reasons are discussed. Testing in adiabatic mode provides new insights into the sulphide self-heating process that complement the test designed to identify propensity to self-heat. Keywords: Self-heating; Stage A/Stage B; transition; rhombic/monoclinic elemental sulphur; adiabatic heating

Jan 1, 2020

By L. Petzold

The demand for stainless steel is ever-increasing. As an essential element in stainless steel-making process, so is the demand of chromite concentrate. At the same time, the industry proven technologies for beneficiation of chromite are limited. Chromite is only crushed, screened and jigged to produce a concentrate. However, for ultrafine and low-grade material, no satisfactory beneficiation methods for the enrichment of chromite fines exist in industrial operation. This poses a clear challenge for the industry, which Primetals Technologies has addressed with the development of a new beneficiation process. The aim of this process was to enrich low grade chromite tailings to a quality suitable for the smelting process. Required concentrate grades are different over the world, concentrate grades of Cr2O3=40% and lower are found at the Bushveld Complex, South Africa. The target for the present study was a Cr2O3-grade in the area of 49%. Three different chromite tailings with Cr2O3 grades between 16 % and 29 % were part of a study, executed by Primetals Technologies. All three tailing materials were characterised by Mineral Liberation Analysis (MLA). Based on the physical, chemical and mineralogical findings, process flowsheets were developed. The process flowsheets included grinding to ensure a full liberation of the chromite. The liberated material was classified at a cut size of 63 μm to a coarse and fine fraction. Gravity separation and flotation processes were tested with the coarse particle fraction. Due to the limitations of gravity separation with fine particles, only the flotation process is suitable and was tested with the fine fraction < 63 μm. A Design of Experiment (DoE) with six factors, each three levels, was conducted to identify optimal parameters for the fine chromite flotation. Two different collectors were tested: a phosphoric acid ester and a fatty acid type collector. In small scale test work a chromite concentration suitable for the smelting process was achieved. On this basis Primetals Technologies will develop a pilot-scale test program to research recirculation effects and upscale potential of the process. Keywords: Mineral processing, tailings beneficiation, flotation, density separation, process development, chromite

Jan 1, 2020

By A. E. Lewis, J. Du Plessis, J. Chivavava

Current metallurgical processes lack selective and efficient REE recovery from aqueous leach liquors. Antisolvent crystallisation is used to selectively recover pure inorganic salts from aqueous solutions without excessive chemical use in ambient conditions. Yttrium sulfate octahydrate (Y2(SO4)3.8H2O) was used as a representative rare earth salt to investigate the effect of antisolvent selection on the crystal morphology and size distribution of the final crystalline product produced through antisolvent crystallisation. The antisolvents of choice were short length alcohols that are water miscible i.e. methanol, ethanol, 2-propanol and t-butanol. All experimental parameters except the type of antisolvent were kept constant under isothermal conditions. The large reduction in solubility of the salt by the antisolvent creates high supersaturations. This leads to high product yields as observed in this study at > 91%. In general, a variety of morphologies were successfully formed in each individual alcohol including; rods, plates, prismatic cubes and starburst clusters. The powder X-ray diffraction (XRD) analysis indicated that Y2(SO4)3.8H2O was the only species present for all final products. There was a change observed from the starburst and rod structures for the shorter alcohols towards prismatic cubes for the longer alcohols due to different strengths in the solute-antisolvent interaction at the crystal growth faces. The crystal sizes increased with an increase in the alcohol chain length because of the lower supersaturation conditions due to a limit in the mass transfer induced by the bulkier alcohol structure. In conclusion, it has been shown that the particle morphology and size can be greatly affected by the selection of antisolvent even under high supersaturation conditions, contributing to understanding the effect of different antisolvents on the final particle characteristics. The engineering of favoured product characteristics can therefore be achieved by antisolvent crystallisation, presenting a viable alternative process for the recovery of REE. Keywords: Antisolvent crystallisation, rare earth elements, morphology, particle size

Jan 1, 2020

By E. Tabosa, S. Vianna, K. Duffy, W. Valery, B. Andrade, L. Pyle, P. Holtham

Pneumatic flotation cells are high-intensity flotation machines with rapid kinetics, resulting in short residence times. Examples include the Jameson, PneuFlot and ImhoFlot cells. These cells do not use impeller-like mechanical cells. Rather, the air and pulp are mixed in a continuous stream of high fluid velocity through a downcomer or venturi to disperse the air into fine (approximately 0.5 mm) bubbles and maintain particle suspension. Froth wash water is often used to enhance concentrate grade, minimising recovery by entrainment. With the growing application of these types of cells, not only in cleaner stages (their traditional use) but also in pre-flotation and scalping duties, there is a need to predict their performance more accurately for circuit design and optimisation. No widely accepted model for pneumatic flotation cells is available and their metallurgical performance is often scaled up from laboratory and/or pilot plant testing by assuming fixed values for metal recovery, concentrate grade and concentrate percent solids. This paper describes a new approach to simulate pneumatic flotation cell performance and presents case studies demonstrating its applicability. Keywords: Pneumatic flotation, flotation modelling, flotation circuit design, flotation circuit optimisation, Jameson cell

Jan 1, 2020

By D. A. Cowen

Toll and custom treatment of base metal concentrates have been performed for decades as mines and concentrators are developed distant from capital and, energy-intensive smelting and refining facilities. Commercial treatment terms have been developed and refined for over a century, and are negotiated taking into account a complex array of quality and economic factors. Treatment of third-party concentrates in the South African platinum industry is a comparatively recent development, brought about by the opening up of mineral rights and operations being developed that are smaller than the critical size required to sustain capitalization of smelting or refining plant. Published commercial terms have not been demonstrated to reflect the complexities and subtleties of base metal concentrate markets. This paper outlines some key elements and parameter ranges of base metal concentrate treatment contracts, and applies similar principles to typical Merensky and UG2 platinum group element (PGE) concentrates to determine potential value distribution between the mining and treatment parties in tolling arrangements.

Jan 1, 2012

By J. Moema, L. Mampuru, M. Phasha, D. Mkhonto

The global liquified natural gas (LNG) storage market size is projected to reach USD17.5 billion by 2025. Currently, owed to its high toughness, tensile strength, and excellent weldability, the 9% nickel steel is the most used in building infrastructure for cryogenic applications such as the construction of tanks and pipes for storage and transportation of LNG. However, this alloy is not readily available because of its complex production process and high cost. This provides an opportunity for suitable alternative materials to build infrastructure for cryogenic applications. Among strong contenders is the Fe-Mn based alloys, which have sparked global interest due to their desirable properties such as relatively lower density, low cost, high toughness and strength, due to a high manganese (Mn) content. These attractive properties render Fe-Mn based alloys preferred candidates to replace traditional steels in engineering applications in which strengthweight ratio is critical. In response, as a build-up to designing and developing austenitic Fe- Mn alloys, the present study employed density functional theory (DFT) based first-principles computational materials modelling technique to investigate the structural, thermodynamic, and magnetic properties of binary Fe-Mn alloy composition in competing FCC, HCP, and BCC crystal structures. Using this approach, it was possible to unravel the key underlying elastic properties that are directly correlated to experimental tensile strength and high toughness in binary Fe-Mn alloys. Besides successfully validating the existing experimental data, the current predicted properties and the deployed approach will serve as a benchmark from which further alloying required to improve other properties will be conducted.

Mar 4, 2025

By P. F. Dicks, N. J. Shackleton, E. H. W. Theron, V. Malysiak

Flotation is a complex physical chemical process in which flotation reagents play a vital role in valuable minerals recovery and concentrate grades. This study examines the performance of new generation AECI Mining Chemicals (previously named Senmin) collectors. They were developed to enhance the valuable minerals recovery and flotation selectivity by tailoring the collectors to target specific valuable mineral species present in an ore and thus create added value for concentrators treating PGM ores. The case study was conducted on a Platreef ore, where batch flotation tests were performed and the concentrates were mineralogically characterised for PGE and BMS using QEMSCAN. Further batch flotation testwork was conducted on Merensky and UG2 ores from various localities in South Africa to confirm the trends observed for Platreef ore. The results have shown that there is a strong correlation between PGE mineral type and AECI Mining Chemicals collector type - clearly demonstrating that one reagent type does not fit all flotation applications. Keywords: Batch flotation, QEMSCAN, collectors, PGE and BMS

Jan 1, 2020

By D. Weijie, S. Kai, Y. Hu, X. Ning, M. Shiyi, W. Junpeng, Z. Guihong, L. Xianjie

Flotation is one of the most important processes in the copper production industry. The copper grade in the concentrate is a pivotal indicator of the flotation process performance. However, it is difficult to achieve real-time measurement through hardware sensors. Based on the production data provided by an industrial operation, a novel soft sensor based on multi-layer perceptron (MLP) is proposed for effective monitoring of this pivotal indicator. The proposed soft sensor uses the nonnegative garrote (NNG) to perform global variable selection for MLP, while a local search (LS) approach is incorporated to improve the model presented by NNG. Simulation results show that the proposed algorithm has higher prediction accuracy and better model simplicity than other algorithms. Furthermore, the variables selected are consistent with the field experience, and the developed model can provide reference of feedback control for the optimisation of the process. Keywords: Flotation process of copper ore, nonnegative garrote, local search, soft sensor, multi-layer perceptron

Jan 1, 2020