Search Documents

By Frank E. Scott

During the past year interest in the use of hydrazine and hydrazine hydrate as a fuel has increased in the United States; For this reason it was felt to be desirable to obtain information on the explosives properties (if these materials in order that hazards inherent in their manufacture, storage, transportation, and use might be evaluated.

Jan 1, 1949

By M. Kanda, W. D. Bensema, J. W. Adams

Two different techniques were used to make measurements of the absolute value of electromagnetic noise in and above an operating coal mine, McElroy Mine, located near Moundsville, Nest Virginia. The electromagnetic environment created by 300 volt dc and 480 volt ac machinery was measured. In one technique noise was measured over the entire electromagnetic spectrum of interest for brief time periods. The noise was recorded using broadband analog magnetic tape. The noise data was later transformed to give spectral plots. In the other technique, noise amplitudes were recorded at several discrete frequencies for a sufficient length of time to provide amplitude probability distributions. The specific, measured results are given in a number of spectral plots and amplitude probability distribution plots.

Jan 6, 1974

By Jack E. Fraley

In this Bureau of Mines study, sealants containing mineral wool, cement, etc, were sprayed through dry-process equipment that propels dry material pneumatically to the water-adding nozzle. Advantages over slurry applications include no mixing, no extensive cleanup, and freedom from hardened cement in equipment should power be lost. Sealants with large mineral wool nodules (>l-inch) were sprayable at rates to 900 square feet per hour for 1/2-inch thickness with little dust and smooth material flow through equipment, but they were weak for mine use, Materials containing small wool nodules (1/4-inch) were stronger but tended to plug lines because the nodules were inadequately separated in the shredder. Increasing the dedusting oil also increased line plugging by holding the nodules together in larger lumps. Best results were obtained using a 3/4-inch-nodule wool with cement binder, which provided both smooth flow through the machine and adequate strength.

Jan 1, 1977

By M. B. Shirts

Numerous alternative processes have been proposed as being potentially more economical or less polluting than the traditional smelting of copper sulfide concentrates. One such process as recently developed in the laboratory by the Bureau of Mines is composed of a two-stage fluid-bed, oxidation-reduction roasting followed by ammoniacal leaching, solvent extraction, and electrowinning. A copper-leaching recovery of 97.4 percent was obtained, and electrolysis of the acid strip solution deposited metal assaying 99.99 percent copper. The roaster gases contain over 95 percent of the sulfur at a concentration of 12 percent which is better suited for acid making or elemental sulfur production than conventional smelter gas. When considering byproduct recovery, a preliminary estimate indicates copper production costs are com-parable to the conventional smelters.

Jan 1, 1975

By R. H. Lien

The Bureau of Mines investigated a roast-leach process for recovering a marketable lithium product from a montmorillonite-type clay deposit located on the Nevada-Oregon border. The clay sample treated in the investigation contained 0.6 wt pct Li. The lithium recovery process consisted of several unit operations. The lithium silicate compounds in the clay were converted to Li2SO4 by roasting a pelletized mixture of clay, limestone, and gypsum at 900° C in a direct-gas-fired rotary roaster. Water--leaching the calcine at 40 pct solids extracted the Li2SO4. Lithium recovery from the leach solution involved concentrating the solution by evaporation, adding Na2CO3 to the concentrated solution to precipitate Li2CO3 , and filtering the slurry to obtain the product. The product filtrate was recycled to the evaporator following a crystallization step. About 80 pct of the lithium in the clay was recovered as 99-pct-pure Li2CO3. Process operating costs were estimated at $2.12/lb Li2CO3 produced; the current Li2CO3 selling price is $1.48/lb. Raw materials. accounted for 30 pct of the total operating cost.

Jan 1, 1985

By R. L. Bolmer

Driving long development raises probably is one of the most hazardous and expensive operations in underground mining. The safe handling of men and materials becomes more difficult and more time consuming in the higher sections of the raise. The efficient ventilation of these sections often is a major problem. This information circular describes a unique method by which Resurrection Mining Co, safely and efficiently completed a 622-foot vertical raise at its Irene shaft near Leadville, Colo. The method used by the company involved driving a raw, 6-foot-diameter ventilation raise and emergency escapeway, using a work cage that was suspended on a hoisting rope extended down a small-diameter drill hole. Although the method was new and experimental, the raise was completed in record time. Overall costs were less than they would have been with conventional methods. The company's initial experience suggested improvements both in design and operating technique that should prove of value to others who contemplate using the cage method of raising

Jan 1, 1958

By F. E. Joyce

The Bureau of Mines studied copper-nickel minerals (mainly sulfides) of the Duluth Gabbro Complex in north-eastern Minnesota to determine their response to selective high-temperature sulfatization techniques. The gabbro, containing 0.44 percent copper and 0.13 percent nickel, was ground to minus 325 mesh and sulfatized in a heated, rotating, stainless steel bench-scale retort. Tests demonstrated that over 95 percent of the copper and 80 percent of the nickel can be converted to water-soluble sulfates, depending upon the roasting conditions employed. Yield equations were developed using regression analysis for predicting the extraction of copper and nickel between the temperature limits of 520° to 670° C, the roasting time limits of 3 to 7 hours, and S02 limits of 10 to 40 percent in S02-air mixtures.

Jan 1, 1971

By Maureen M. Foss

Underground coal mining is hazardous due to changing geological conditions. One geophysical method showing promise for in-seam hazard detection is ground-penetrating radar (GPR). The Bureau of Mines recently completed preliminary studies to demonstrate the feasibility of using GPR for in-seam hazard detection. Investigations included air and coal tests for the purpose of checking equipment accuracy, coal penetration, and other factors such as the effects of receiver orientation. Further investigations involved using both a short pulse and a new prototype synthetic-pulse system to locate a clay vein in a coal seam using trans-illumination. Data were gathered on multiple travel paths, and a back projection processing technique was then used to create a tomographic image using the calculated velocities. A computer model of the same coal seam was subsequently processed using the same tomographic tech-nique, and the results were compared with those of the actual data. Analysis of the tomographic images shows the presence of the clay vein, although its boundaries are unclear due to the tomography method used. Results of these preliminary studies show that GPR is feasible for use in in-seam hazard detection and point the direction that future research should take. A need has been shown for research involving more sophisticated tomography techniques, transmission studies on thicker coal seams, and reflection studies using the synthetic-pulse system.

Jan 1, 1987

By G. W. Birge, D. E. Wolfson, J. G. Walters

Seventeen samples were carbonized by the BM -AGA pilot - plant test method and in industrial ovens . Chemical and physical properties of the samples were determined , and the physical properties of the cokes prepared by the two methods were compared . Since the capacity of the plants from which these samples were obtained is about 30 percent of the 1959 total for the United States , the data given in this report are indicative of the chemical and physical properties of blends used to produce industrial cokes and the acceptable chemical and physical properties of the resultant coke .

Jan 1, 1964

By E. G. Baglin

The Bureau of Mines devised a procedure for selectively extracting platinum-group metals (PGM) and gold from Stillwater Complex flotation concentrate. The Stillwater Complex is the only major U.S. PGM resource. Development of a suitable extraction technique will contribute to its exploitation. The concentrate was roasted at 1,050° C to convert host base-metal sulfides to oxides and the PGM from sulfide minerals to their elemental states. The roasted concentrate was preleached with dilute sulfuric acid to remove easily soluble gangue minerals. After pre-leaching, the concentrate was slurried with 6M HCI and leached at ambient temperature and pressure with a strong-oxidizing agent. Hydrogen peroxide, chlorine, sodium hypochlorite, nitric acid, and a persulfate salt were the oxidants investigated. The two-stage leaching scheme ex-tracted up to 97 pct of the platinum, 92 pct of the palladium, and 99 pct of the gold from the roasted concentrate. The base metals were not solubilized and reported to the residue. No attempt was made to devise a procedure to recover the copper and nickel because they comprise less than 5 pct of the value of the concentrate. Viable techniques for recovering the precious metals from the pregnant solution were sulfide precipitation, cementation with nickel, or adsorption on activated carbon.

Jan 1, 1985

By Seth T. Reese

THE INJURY DATA and experience at coke ovens in the United States for 1952 are presented in this bulletin under the following general sections: (A) General injury experience: Tables 1 to 9: Contain current and comparable data on operating statistics, number and classification of injuries, frequency rates, and accident agencies involved in causing injuries. Data are given for the industry as a whole, for each type of oven, and for the States in which coke is manufactured. (B) Selected injury experience: Tables 10 to 15: Contain comparable injury data in the coking industry covering 5- and 10-year periods on the number of injuries, accident agencies, and severity of injuries. (C) Historic injury experience: Tables 16 to 19: Contain data on the number of injuries, frequency rates, and employment at coke ovens from the earliest records through 1952, Operating statistics from 1929 through 1952 are given in table 19.

Jan 1, 1955

By F. J. Palumbo

An electronic color-sorting machine was tested for recovering colorless glass concentrates from mixed glass products. The tests were made using glass recovered from unincinerated (raw) urban refuse and residues resulting from the incineration of refuse. The results of the study revealed that concentrates analyzing about 86 percent colorless glass could be recovered from mixed unincinerated glass containing 54 percent colorless glass material. Recovery of the colorless glass was about 62 percent. Color sorting the incinerated glass was somewhat more difficult. Multiple-stage processing was required to recover 59 percent of the colorless glass material in a product analyzing 89 percent colorless glass. The feed material analyzed 41 percent colorless glass.

Jan 1, 1971

By G. H. Keith

A vanadium-base alloy consisting of the following elements in weight-percent--molybdenum, 20; titanium, 10; carbon, 0.1; silicon, 0.5; and yttrium, 0.5--had exceptionally high strength at temperatures up to 1,200° C. This alloy was capable of fabrication to sheet of ~ 1 mm thickness by a combination of hot swaging and hot and warm rolling. In the warm-rolled condition at ambient temperature, its ultimate tensile strength was 1,205 MN/m2. The strength at 1,200° C was 150 MN/m2. Within the temperature range of 25° to 1,200° C, the ductility of the alloy as measured by elongation increased from 4 to >90 percent. Strengthening was achieved by both solid-solution and dispersed-phase mechanisms. Alloys of 20 percent molybdenum and 10 percent titanium were stronger than the other molybdenum-titanium alloy compositions tested. Strength was increased 15 percent in the temperature range of 25° to 800° C, with no accompanying loss in ductility, by the addition of 0.5 percent silicon. Workability was improved by additions of 0.25 and 0.5 percent yttrium.

Jan 1, 1970

By FRANCIS FEEHAN

Safety first is no longer merely a motto ; in some industries and in some parts of the mining industry it is an accomplished fact . In connection with the National Safety Competition of 1928 in which 284 mines and quarries participated , 42 plants were operated without a single lost - time accident . The winning company in the bituminous group had an accident severity rate of 0.053 per thousand man hours of exposure . Excellent safety records of various kinds are becoming more and more frequent , and the indication is that in reality safety is first in many mines and qquuaarrrriieess .. The safety achievements in the Stewart mine of W. J. Rainey , Inc. , are unusual even among mines winning awards in the competition .

Apr 1, 1930

By C. G. Storm

Permissible explosives are those that have passed the tests pre- scribed by the Bureau of Mines for explosives intended for use in coal mines, and are therefore recommended by the bureau as suitable for this class of work when used under the prescribed conditions. The tests for permissible explosives and the conditions prescribed for their use are described in Miners' Circular 6 of the Bureau of Mines. Up to June 1, 1915, 168 explosives had been classed as per- missible explosives; 133 of them were then on the bureau's "per- missible list" and 35 had been withdrawn by the manufacturers. In addition to the required physical tests, each explosive is sub- jected to a complete chemical examination in order that its exact composition may be known and also that the composition of future samples of the same explosive collected in the field may be compared with that of the sample which originally passed the bureau's tests, for by such comparison it may be possible to ascertain whether or not the explosive as supplied to the miner is still "permissible." This bulletin is published primarily for the purpose of informing manufacturers of such explosives as to the methods used by the Bureau of Mines in the analysis of samples received for tests to determine their permissibility. Such information may be of value in cases of possible controversy over the results obtained in the analysis of a field sample as compared with those obtained in ana- lyzing the sample originally tested by the bureau. Also, a descrip- tion of the methods used by the Bureau of Mines in the analysis of explosives should be of assistance to the many chemists engaged in similar analytical work.

Jan 1, 1916

By H. B. Humphrey, F. E. Cash

The following information on accidents in Alabama during 1930 was compiled from data obtained from the companies represented in a course on accident prevention given by the United States Bureau of Mines in Birmingham. These mines produced nearly three-quarters of the tonnage of that State for the year, and included most of the larger operations in the district. The figures are probably representative of the mines which are doing recognized safety work, and are better than the average for all the mines in Alabama. Table 1 lists the days lost in accordance with the weights given to fatalities and permanent disabilities, part and total, which is the scale used in the National Safety Com¬ petition for Mines, conducted by this bureau. By way of explanation, temporary disabilities are weighted according to actual number of calendar days of disability, including Sundays and holidays — that is, all days are counted except the day of accident and day of employee's ability to return to duty. Hernia is classed as a temporary disability to be charged with the actual number of calendar days during which the employee was unable to work. Table 2 gives the number of accidents and the days lost from each cause at 45 coal mines and 7 iron ore mines, also the average frequency and severity rates.

Aug 1, 1931

By Edwin S. Secor

The Federal Bureau of Mines conducted a field survey of 153 bituminous coal strip and auger mines to estimate coal recovery from surface mines in the Eastern United States. Recovery was calculated from field data by measuring coal losses resulting from mining coal and leaving barriers. Mean total recovery for strip mining in States east of the Mississippi River was 83.0 percent and ranged from 72.3 percent for Tennessee to 91.3 percent for Maryland. Mining losses and barrier losses were 10.1 and 7.7 percent, with standard deviations of 4.8 and 10.4 percent, respectively, indicating that barrier losses, although less than mining losses, were more variable. Mean total coal recovery varied only slightly for the two regions studied; 82.7 percent for Appalachia and 84.3 for the Midwest. Total recovery grouped by mining method--contour, area, and mountaintop removal--was 79.8,84.7, and 85.3 percent, respectively. Mean auger recovery was 35.9 percent; of the total average loss of 64.1 percent, over one-half resulted from design limitations while the remainder was attributed to operating losses. The wide recovery range at individual mines indicates the variability of the eastern surface coal mining industry. Because of this, care should be exercised in applying the results of this report to reserve estimates other than those of a general nature.

Jan 1, 1977

The United States has not begun commercial operations to tap its largest poten-tial sources of oil supply - oil shale and coal. The reason is that domestic petrol-eum has been plentiful in the past and liquid products probably could be produced from it at the lowest cost. In view of the ever-increasing need for petroleum in the United States, the critical international situation threatening foreign supplies, the growing demands for steel, and the heavy costs to industry of constantly discovering and developing new oil fields, it is believed that the prompt development of a synthetic fuel industry based on oil shale and coal is not only requisite to safeguard our oil supply but is an economically sound course for the foreseeable future. To neglect its development is to close our eyes and minds to our own resources at a time when they are needed critically. It also is apparent now that neither the Government nor industry would be taking any considerable economic risk in starting the initial plants, especially as measured against their potential value in meeting critical oil and chemical demands and in building a new industry in the West.

Jan 1, 1951

By James J. Olson

The Bureau of Mines recorded both particle accelerations and velocities from one-stick and production blasts at Eagle-Picher Industries' Shullsburg mine, Shullsburg, Wis., to test the effectiveness of square root scaling in grouping underground blast vibrations and to determine the effects of rock type and mine geometry on blast vibrations. Although the charge weights of subsequent delay periods sometimes exceeded the charge weight of the zero-delay period, both acceleration and velocity records showed that the zero-delay portion of the Shullsburg production blasts produced the highest vibration amplitudes. Because of the restricted range of charge weights in the Shullsburg experiments, no statistical determination of an appropriate scaling factor could be made. However, the square root scaled peak particle velocity data from the Shullsburg production blasts grouped well within the approximate band-width of vibration data obtained by the Bureau from quarry blasts in many different rock types. This indicates that scaling by some factor, perhaps the square root or cube root of the charge weight, may be an effective way to group and study vibration data from underground blasts. Further research is needed to determine which scaling factor is best for underground blasting.

Jan 1, 1970

By David E. Siskind

The Bureau of Mines has studied the fracturing and associated damage occurring in the vicinity of blastholes from five shots fired in the shale pillars in the White Pine copper mine, White Pine, Mich. Four types of explosives (AN-FO, commercial extra dynamite, ammonia gelatin dynamite, and a low-density, low-velocity permissible) were used. Cores were taken from the blast region and examined by ultrasonic and petrographic techniques. Pulse wave velocities were measured across the core diameters, and thin sections showing cracks and changes in lithology were examined in an attempt to establish zones of damage. Cores from the blast regions and areas near pillar free faces were found to have abnormally low pulse velocities. Petrographic study of the thin sections showed that the negative velocity anomalies were caused by cracks in the cores. Crushing and extensive fracturing prevented meaningful measurements on core fragments from the immediate blast vicinities. Compositional, changes and other rock nonuniformities, such as joints and preexisting fractures, tended to mask detailed damage differences among the four explosives; however, the two most energetic explosives (extra dynamite and ammonia gelatin dynamite) produced damage zones two to three times as large as the AN-FO and low-velocity permissible explosives.

Jan 1, 1973