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By M. Maeda, H. Sasaki

"Precious metals such as platinum, palladium, and rhodium are commonly used for automotive catalyst converters. To recover these metals with lower environmental load and cost, exposure to zinc vapor was proposed as a pretreatment prior to acid leaching. Alloying with zinc is expected to enhance dissolution of precious metals and reduce the amount of toxic chemical agents required for the leaching. This study examined the effect of the alloying pretreatment using model catalysts. Catalysts were immersed in leaching solutions for a predefined time with or without zinc vapor pretreatment, and the amount of dissolved metals was then evaluated. INTRODUCTIONAutomotive catalysts account for large portions of the world consumption of platinum (Pt), palladium (Pd), and rhodium (Rh) (Butler, J., 2011). Because of their limited production and high prices, recovery of the precious metals from spent catalysts is obviously an important issue. A representative structure of an automotive catalytic converter can be described as a monolithic ceramic support with a honeycomb structure which is coated with porous oxides such as those of aluminum (Al2O3), cerium (CeO2), and zirconium (ZrO2) (Heck & Farrauto, 2001; Matsumoto & Shinjoh, 2007). Small particles of precious metals, originally several nanometers or less, adhere to the oxides.Typical recovery processes for precious metals from scraps are shown in Figure 1 (a)-(c) (Habashi, 1997; Yoo, 1998; Shibata & Okuda, 2002). Precious metals can be recovered by using non-ferrous smelters as Figure 1 (a) shows. Smelted along with metals such as copper (Cu), precious metals and ceramics in the scraps are absorbed into the metal phase and slag phase, respectively. Because the metals separate from Cu as anode slime in successive electro-refining, such a process can recover precious metals as co-products of Cu. However, in order to prevent negative effects on the principal process, a specialized procedure is needed. Figure 1 (b) is a specialized approach in which scraps are melted at elevated temperature with Cu called the Rose process. Here Cu works as a collector metal, and the absorbed precious metals are then concentrated by oxidation of Cu. Such a process can separate precious metals from ceramics constituting catalyst converters. Smelting at high temperature, however, requires extensive equipment as well as a high amount of energy. On the other hand, hydrometallurgical processes may be effective to separate precious metals from ceramics into an aqueous solution, because chemical agents can act on these metals selectively (Figure 1 (c)). Leaching of precious metals, however, requires strong acid and oxidizing agents because of their corrosion resistance; this makes liquid waste disposal and the large environmental load controversial. To solve the problem, a metal vapor pretreatment was proposed (Okabe, Yamamoto, Kayanuma, & Maeda, 2003a, 2003b; Kayanuma, Okabe, Mitsuda, & Maeda., 2004; Kayanuma, Okabe, & Maeda, 2004; Itoh, Kayanuma, Miyake, Kimura, & Maeda, 2005). A flow diagram of the process using zinc (Zn) vapor is shown by Fig. 1(d). Exposed to Zn vapor, precious metals are expected to form alloys which dissolve more easily than pure precious metals, thus reducing the use of chemical agents and environmental load involved with successive leaching. In previous research (Sasaki, Miyaki, & Maeda, 2010; Sasaki & Maeda, 2010, 2012), dissolutions of precious metal alloys formed by Zn vapor treatment were examined in hydrochloric acid (HCl) using an electrochemical method, and it was confirmed that these metals dissolved at higher rates from the alloys than from their pure states (Figure 2). In this study, the availability of the alloying pretreatment was demonstrated by testing on model catalysts in leaching solutions."

Jan 1, 2012

By J. Budac, R. Kofluk, S. Mankasingh

Stainless steels such as 316L or 304 are normally relatively resistant to attack by nitric acid. However research at Sherritt International’s Fort Saskatchewan Operation reveals that when the stainless steel is immersed in an aqueous system in which nitric acid is used to dissolve metals such as cobalt or nickel, the steel can be seriously corroded. Sherritt is patenting a simple process for arresting the corrosion via the use of copper. This process is expected to substantially eliminate corrosion in processes where nitric acid is used to dissolve metals attached to a stainless steel substrate.

Jan 1, 2014

By N. R. Thornton

This paper discusses the rapid growth in the application of instrumentation for metallurgical process control. It covers such methods as ultrasonics, pulp density measurements, on-stream X-ray analysis and reagent control, as well as the expanding use of computer control and data acquisition.

Jan 1, 1971

By M. Fairclough, B. Moldovan

Insights into uranium mining projects of the future can be gained by a careful statistical analysis of past and present deposits, as well as an examination of recent trends for uranium resource evaluation and primary uranium production. The International Atomic Energy Agency (IAEA) provides the necessary data and corresponding mechanisms as inputs for methodologies that enable strategic and scientific evaluations of long-term security of supply uranium required to sustain the demand for nuclear fuel. Sustainability of the uranium mining industry and subsequently new uranium mines of the future requires innovation and expertise to lower operating costs, maintain or improve uranium recovery while meeting the requirements of stakeholders in regard to protection of the environment and safety of the workers and general public.

Jan 1, 2020

By J. E. Dutrizac

Mercury balances have been obtained for the flotation circuits at Pamour Porcupine Mines, Timmins, Ontario, and at Brunswick Mining and Smelting Corporation, Bathurst, New Brunswick. The mineral form of mercury in both deposits has been ascertained. At Pamour Porcupine, the mercury is approximately evenly divided among sphalerite, native silverelectrum and tetrahedrite-tennantite; at Brunswick Mining, this element is contained mostly in the sphalerite, although tetrahedrite (and possibly pyrite) also contains minor quantities.

Jan 1, 1979

By John A. Hudson, Xia-Ting Feng, Joseph S. Y. Wang

Evolution over decades and progress over last five years have been made in many topics of interests to rock mechanics, geosciences, physics, and multi-disciplinary interactions in underground research laboratories and development facilities, as well as in underground energy recoveries and environmental assessments. Rock mechanics and geotechnical engineering advances are associated with quantifications of disturbed/damaged zones and rock alternation and bursting processes and creation of underground spaces and accesses associated with deepening of shafts and lengthening of tunnels. Geophysics and earth sciences advances are associated with continuing collections of seismic, electromagnetic, and gravitational data and conducting various thermal, hydrological, mechanical, chemical, and biological investigations, both separately, simultaneously, and in different coupled ways. Astroparticle and underground physics advances are associated with many long term experiments to detect rare events and needs for increasing larger and deeper halls to accommodate next generation detectors, shielings, and isolations. There are also increasing interesting in underground settings to explore multidisciplinary and inter-disciplinary sciences and technologies. Energy and environmental sciences and assessments have evolved from traditional oil and gas focuses to recent activities associated with green resources and alternative recovery/disposal strategies. The evolution and progress of these interdependent and related fields are discussed in this quadrennial Congress.

Jan 1, 2015

By S. P. Lowe

Flotation testing of Flin Flon ore was started in the Denver laboratory of Complex Ores Recoveries Co. in March, 1926. There had been a considerable amount of flotation testing previously which had shown possibilities of success, and it was felt that, with the increased knowledge of flotation and the comparatively new reagents then available, flotation held out the best prospects for a successful commercial treatment of this ore. There remained available for this experimental work a small amount of the rejects from a thorough sampling of the mine and some ore from the mine dump.

Jan 1, 1930

By H. Abdollahi

Cold rolling is one of the most important techniques in metal forming since the cold rolling products are almost finished product, The product quality of this process is widely influenced by friction in the roll gap; therefore, controlling the friction and other parameters affecting the cold rolling is very important in order to have a product with high quality, Among the cold rolling parameters, the pressure distribution or friction hill within the roll gap is known as the most significant one, In this study, a new software (Matroll), is introduced which can determine the coefficient of friction (COF) and plot the friction hills for an industrial mill, Besides, based on rolling equations, it offers about 25 rolling parameters as outputs. To verify the software operation, the real industrial rolling data was used as inputs, The results (outputs) are in good agreements with the findings of other researchers, The COF values are very reasonable, The friction hill shows that COF is not constant over the whole arc of contact.

Jan 1, 2005

By Getu F. Biftu

There is general agreement among scientists that global surface temperatures have been increasing during the past decades. The increase in temperature is postulated to be the result of either an increase in greenhouse gases emission or climate variability (i.e., due to variations in sun or volcanic activity or El Nino and La Nina events) during past decades and may continue to increase. The effects of a predicted rise in the Earth?s surface temperature include an increase in average global evaporation and increase or decrease in precipitation (Bloomfield, 1992; Mann et al., 1991; Vinnikov et al., 1990; Gan 1995; Zhang et al., 2000a). The general circulation models (GCMs) project a global warming due to greenhouse effects of 1.5-4.5°C by the mid 2050s, with the most pronounced changes taking place in northern latitudes (Nicholls et al., 1996). However, similar predictions at a watershed scale or even a regional scale using GCMs are mot possible yet (Arnell et. al., 1996; Georgievskii et. al., 1996; Zhang et al., 2000a). Detection of historic trends, changes and variability in climatic variables is another indirect means of understanding potential future changes or variability at regional and local scales. The main objective of this paper is to review studies related to climatic change or variability and associated hydrologic changes at a regional scale and local scale, particularly those studies applicable to the Oil Sands Region (OSR) of Alberta. This paper identifies gaps in our current understanding of the hydrologic processes that may be affected by climate change; it discusses potential implications to developments in the OSR; and it explores mitigation opportunities including several that have already been implemented.

May 1, 2004

By H. Aminian

Gold powders have many important industrial applications. In this paper the available processes for the preparation of gold nano and micron sized powders are described. The attention has been given to hydrometallurgy route and the recent works and achievements in controlling the powder morphology are highlighted.

Jan 1, 2011

The teaching of geophysics in Canada at the present time presents a variety of approaches to the subject, and the different paths adopted imply, in turn, an uncertainty in the minds of some educators as to the role this science is to play in the future progress of geology, and a hesitancy to commit themselves to foster its development. The pedagogical attitudes vary from a whole-hearted acknowledgment that the science of geophysics is fundamental to the understanding of terrestrial phenomena (including, of course, geological processes) to a hesitant immersion of the toe to test the water's temperature (which is, of course, essentially a geophysical experiment) before deciding whether or not the time is ripe for total immersion. The present discussion has been organized in the hope that it will help to clarify the roads to geophysics and assist educators in making a more understanding choice of the best paths for them to follow, according to their particular requirements and objectives. Before proceeding further, however, it is necessary to define the term geophysics and circumscribe the field it covers. In the first place, it should be emphasized that geophysics is NOT confined to the art of geophysical prospecting. The popularization of geophysics has unfortunately engendered a general misconception of the word, and consequently a tendency to ignore the wider meaning of the term. Etymologically, geophysics means the physics of the earth. It is so understood by the International Union of Geodesy and Geophysics and the various geophysical societies which adhere thereto. To them, geophysical prospecting is but a very small field indeed, which they consider had best be left to engineering and prospecting organizations.

Jan 1, 1951

By Saba Gharedash

In this study the results of a series of numerical simulations which are conducted for one of the tunnels of the Mashhad metro line 2 project are presented to evaluate the role of tunnel face support pressure and soil strength parameters on deformation of tunnel lining and face deformation. To achieve this goal, comparative numerical simulations of a mechanized tunnel advance in soft non- homogeneous soil on top of the ground water table and beneath the building are conducted and sensitivity analysis is performed. Development of a step by step tunnel construction process is modeled using a three dimensional finite difference model (FLAC3D) taking into account all the relevant components of shield tunneling. In order to understand the mechanism of the effects of a variety of support pressures on face deformation and lining stresses, numerical simulations are conducted. It is found that the use of different face supports causes a considerable influence on the forces of tunnel lining. In addition, it is revealed that building weight help to change the stress paths and the stress distributions in the tunnel lining.

Aug 1, 2013

By A. H. Lang

THE recent production of important quantities of high-grade muscovite at the Purdy mine, near Eau Claire, Ontario, bas brought that district into prominence and bas added another strategic mineral to the list of Canadian products. The discoveries are thirteen miles west of Mattawa and about two miles north of the Trans-Canada highway and the Canadian Pacific railway. HISTORY Clear mica of low power factor is in considerable demand in Canada and in the United States for war purposes such as radio and telephone condensers, aircraft spark-plugs, radio tubes, and transformers. Some muscovite (white mica) bas been produced in North Carolina and New Hampshire, but the United States trade bas depended largely on importations of muscovite from India and of phlogopite (amber mica) from Madagascar. For many years Canada bas been a substantial producer of phlogopite, but was unable to compete extensively in the United States with importations from abroad. Canadian production of muscovite bas been negligible as no important deposits were known. Ever since the construction of the Canadian Pacific railway, attempts have been made from time to time to mine the pegmatite dykes in and near the Eau Claire area, but, although some feldspar has been mined, no appreciable muscovite was produced. Lace in 1941, J. Purdy and H. MacDonald discovered a dyke containing large crystals of high-grade muscovite from which they are reported to have sold $700 worth of mica. They recorded claims 35974 and 35975 in December, 1941, and claim 36095 in May, 1942.

Jan 1, 1943

By M. Aushouri, S. H. Mansouri, N. Aminizadeh

A thermo-chemical model of the Peirce-Smith copper converter in blowing the copper stage has been developed to predict the molten temperature. The key assumption of the model was that white metal and gas phases in the converter were in thermal and chemical equilibrium. In this model, the chemical reaction of white metal and oxygen was accomplished completely. So long as sulfur existed in the bath, the generation of Cu2O was frozen. The reaction rate was considered to be constant and controlled by the reacted sulfur. The converter temperature was calculated by heat balances over time. The model was validated by a detailed comparison with measured industrial data. A good agreement was obtained. The converter temperature depended on process parameters such as oxygen efficiency, molten emissivity and oxygen enrichment.

Jan 1, 2007

By Jian-bin Xie, Lin-fang Shen, Zhi-liang Wang

"In order to research temperature field for construction of connecting passage in Metro using artificial freezing method, the finite difference software FLAC3D is employed to numerically simulate construction process of connecting passage. During construction, the overall distribution of temperature field around connecting passage, the relationship between soil temperature and freezing time, the distribution and variation for the thickness of freezing wall are studied from the perspective of numerical analysis. The results show as follows: after 55 days’ freezing, the soil temperature surrounding connecting passage is about -24 oC ~ -28 oC, and the minimum thickness of freezing wall is about 4.0m, which is larger than the design value 3.1m. So construction conditions have satisfied to the excavation of connecting passage and pumping station. During the excavation of connecting passage, soil temperature has almost no obvious change and the thickness of freezing wall remains constant mainly. After 45 days’ normal thawing, the temperature of freezing wall rises 12 oC approximately. And the soil temperature rises faster at the beginning of the normal thawing stage. In the whole process of construction, the frozen area is about 5m outside the edge of connecting passage, and the cooling area is about 10m outside the edge of connecting passage. INTRODUCTIONThe first recorded application of the artificial freezing method is on a mineshaft project in 1862, and it has been widely used in foundation pit engineering, subway tunnels, mine shaft engineering and so on (Wang Zhiliang, 2010; Zhang Juanxia, 2012; Qiu Fan, 2007; Zhou Xiaomin, 1999). This method has many advantages of enhancing soil strength; decreasing permeability and adopting various unstable soils (silt clay, sand, gravel, etc.). It has been applied successfully in metro engineering construction in Beijing, Shanghai and Nanjing. According to incomplete statistics, the construction of connecting passage using artificial freezing method accounted for 98% in Shanghai metro (Qiu Fan, 2007)."

Jan 1, 2015

By D. Mills, W. J. Brantina

"Mechanical and magnetic characteristics of ferromagnetic materials were investigated by a pulsed ultra-sonic technique. Two instruments, the Ultrasonic Attenuation Comparator (Sperry) and the standard type Reflectoscope (Sperry) were used for measurements of the attenuation of the ultrasonic pulse. The effects of elastic tensile and compressive stresses on the attenuation of annealed and cold worked material are described. In addition, the effects of plastic de-formation, relaxation and aging processes and different ultrasonic test frequencies are reported. The results for Armco iron, SAE 1020 steel, SAE 4340 steel and AISI 420 stainless steel are shown. Under the test conditions, the attenuation was found to be largely a sum of two components; a ""dislocation"" component associated with the losses accompanying the oscillations of dislocation line segments and a ""ferromagnetic"" component associated with the microeddy currents generated by magnetic domain wall oscillations. Either of these components might be dominant depending on the nature of the particular specimen and the test conditions. Finally, the possibilities of using ultrasonics in residual stress determinations, in fatigue studies and in the study of the ductile-brittle transition in ferrous materials, are briefly discussed."

Jan 1, 1960

By M. Ye. Shulgina, M. L. Bolotin, S. A. Prokopev, Ye. S. Prokopev

Iron ores concentration at Russia’s operations is carried out using conventional flow sheets. They comprise the two-four stage grinding followed by one-two stage magnetic separation. This results in the maximum recovery of magnetite to concentrate and the tailings generation. The final concentrate is generated only during the last stage of magnetic separation. Technologically, this flow sheet layout is not effective at recovering the liberated magnetite grains during grinding to the resulting concentrate. Advanced models of magnetic separators do not allow for the selective separation of the tailings and the portion of the resulting iron ore concentrate. Magnetic product which is the ore mixture of the liberated magnetite grains, high grade and low grade intergrowths is directed to the next grinding stage. In this case, regrinding of the liberated magnetite occurs. In addition, the performance of hydrocyclones during classification in closed grinding circuits is poor. Their classification efficiency does not provide the material separation in accordance with the size. In this case, simultaneous separation in accordance with the density occurs. The quartz particles with the size of 300 mm have similar velocity and trajectory like the particles of magnetite with the size of 60 mm. As a result, light and coarser intergrowths report to the overflow and free heavy magnetite grains report to underflow and return to regrinding (“the density effect”). This resulted in a significant increase of a mill circulating load, the decrease in the feed throughput and higher power consumption. In this connection, the development of iron ore concentrate stage recovery with the focus on gradual liberation of the intergrowths is getting much attention. Gravity concentration technique, particularly, spiral separation is effective at solving the problem of stage recovery not only the dump waste product but also high grade magnetite concentrates at the early concentration stages. This can be attributed to a significant difference in magnetite (4.9-5.2 g/cm3) and host minerals (quartz 2.7 g/cm3) densities, which is the principal during gravity concentration. The test work on concentration of various products samples from current operations (the mills discharges, concentrates from various stages of wet magnetic separation and cyclones underflows) was carried out. Spiral separators SV-500 and ShV-500 manufactured by Spirit LLC were used for the test work. High grade iron ore concentrate (69.05% Fe) was generated during primary wet magnetic separation concentrate concentration using a spiral separator. During the concentration of mills discharges the content of iron in the resulting concentrates and middlings of wet magnetic separation II stage was 64.5% and 64.6%, respectively. The recovery of iron to the concentrates of spiral separation was 33.6-42.0%. The studies presented demonstrate that by using spiral separation for iron-bearing ores concentration, you can separate magnetite liberated grains at the early concentration stages, decrease their regrinding and circulating loads in grinding circuits. This process is able to improve the overall recovery and economics of iron ores concentration process.

Jan 1, 2016

By G. Barrasso

REACH was proposed by the EU Commission in October 2003 and stands for the Registration Evaluation, Authorisation and Restriction of Chemicals. It requires that all substances identified as persistent, bio-accumulative and toxic, whether the risk of those chemicals being released is real or perceived, require registration prior to them being allowed to be imported into the European Union. An internal investigation by the metals industry indicates that almost all primary raw materials streams would be classified as hazardous due to the potential health or environmental hazard properties of one or more of their ingredients. REACH uses a wide definition for chemicals and metals and as such its implications greatly impact the entire supply chain of the metals industry. The process of registration would require the producer/ importer to produce a dossier. Initiatives along the same lines as the EU REACH are also coming up in other parts of the world. REACH requires registration of at least four substances manufactured by the aluminium industry: aluminium metal, including powder, aluminium oxide, and aluminium hydroxide. The proposed legislation permits the affected companies to band together to form a consortium to develop certain aspects of the registration application. The aluminium industry has established a consortium and testing is currently underway.

Jan 1, 2006

By Shigeomi Nishigaki

This paper presents quantitative indexes to evaluate operator?s bearing, difficulty in a task, and machine operability when an operator remotely controls a backhoe, and reports the use cases. The quantitative indexes would give her/him the opportunity to reflect on her/his works, and enable us to gain in-depth insight into the teleoperation, and furthermore give us with promising hints to improve it.

Aug 1, 2013

By K. Ihara, R. Akiyoshi, Y. Takaki, S. Kang, H. Shishido

"Tensile tests and scanning electron microscopy-electron backscattered diffraction (SEM-EBSD) analysis were performed in an Al-Mg-Si alloy to clarify the effect of annealing and cold-rolling reduction on the texture formation. The hot-rolled specimens were cold-rolled with the reduction of 58-75%(CR1), followed by annealing at 773 K for 5 min(IA). The secondary cold-rolling(CR2)for the IA specimens with the reduction of 33–66%, followed by the solution heat treatment(ST), were performed. Focusing on the CR1 and CR2 specimens, the average r-values increased with higher primary and lower secondary cold-rolling reduction, respectively. This was considered to be due to the increase of r-values measured in the direction of 45 degree with respect to rolling direction, caused by the formation of the ß-fiber components (Brass {011}<211>, Copper {112}<111> and S {123}<634>) with high density. Based on the texture analysis of annealed specimens it was suggested that the high density of the ß-fiber components after IA and the small amount of stored strain energy of CR2 introduced by the lower cold-rolling reduction remained the ?-fiber components even after solution treatment.INTRODUCTION Al-Mg-Si alloys have been applied to automobile body applications, due to their excellent paint-bake hardening (age-hardening) and corrosion resistance compared to other aluminum alloy. On the other hand, the mechanical properties and deep drawability of Al-Mg-Si alloys are inferior to those of steels. Thus, it is important to improve the mechanical properties and deep drawability in order to expand the application components. One of the best methods to improve the deep drawability is to increase the Lankford coefficient (r-value). Previous studies reported that the increase of the average r-value ( ) improves the deep drawability. The relationship between the r-value and texture of the alloy is also well known. Inoue et al. reported that the ß-fiber components, such as Brass ({011}<211>), Copper ({112}<111>) and S ({123}<634>), increase the r-value measured in the direction of 45o with respect to the rolling direction. r"

Jan 1, 2018