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By B. Courtaud, L. Donati, V. Weigel

As a growing mining company, ERAMET is looking for new positions in the strategic metals market. In this context, the Gabonese Maboumine pyrochlore deposit is currently being studied for the recovery of niobium, tantalum, rare earths and uranium. This ore shows mineralogical and chemical characteristics that make it challenging to process by existing practices, from both technical and economic points of view. ERAMET has developed since 2008 an innovative hydrometallurgical process, which has been successfully operated at a pilot plant scale (more than 35 weeks in continuous). The upstream part of the process aims to dissolve valuable elements in sulphuric acid. The first step is dedicated to dissolve the ore matrix, leaving the pyrochlore unleached. The second step consists in chemically breaking down pyrochlores in order to form soluble species of the valuable elements. After dissolution, the valuable elements are separated into different flows: niobium and tantalum are recovered and transformed as commercial ferroniobium on one side, and rare earths and uranium remain in the solution to be recovered in the downstream part of the process. The main goal of this paper is to discuss the upstream part of the process, which has given successful results.

Jan 1, 2014

By A. Aubin, H. Yang, G. Zaluski

The Athabasca Basin of northern Saskatchewan and Alberta is an exceptionally rich metallogenic region, hosting more than 2.8 B lb U3O8, of which over 927 M lb U3O8 have been mined out since extraction first started in the late 1970’s. A detailed compilation of several empirical features of 85 deposits located within the basin was conducted in order to understand the distribution and variability of the geological characteristics of the mineralization and its associated alteration. A new empirical classification was devised based on four parameters: 1) geometry of the mineralization (dimensions and relation to the unconformity surface), 2) size, grade and metallurgical complexity of the mineralization, 3) lithostructural setting, and 4) extent and nature of associated alteration haloes. This compilation defines the footprint characteristics of the Athabasca Basin deposits, which guides decision-making processes from early exploration and discovery to resource expansion and extraction.

Jan 1, 2020

By A. Pearson, F. A. Auld, S. O. Colbeck

"""The theory of buckling of shafts and Steel tunnel-linings"" was published by E. Amstutz in 1970 and commented on by S. Jacobsen in 1974. The authors have revised and enhanced Amstutz’s work to address Jacobsen's comments on its limitations and to extend its validity over a wider range of pipe/shaft geometries, including those commonly found in deep mine access shafts. The author has looked at Amstutz’s assessment of strengthening with flexible shear anchorages and adapted the theory of non-linear shear deformation response of bolts to develop a method of assessing increased buckling capacity utilising the full plastic shear capacity of studs. INTRODUCTION “Amstutz Buckling” refers to the buckling of pipe embedded in concrete under external uniform pressure. In terms of a mining environment, this relates directly to the design of a watertight shaft. This load case will commonly occur where a main shaft is cast against a geostatically stable primary liner and the only load applied to the final shaft is that of a uniform ground water load. Ernst Amstutz wrote his first paper on buckling of pressure-shaft steel linings in 1950 and subsequently improved his theory (Amstutz, 1970), which was then widely adopted for use within the industry. Years later, an alternative approach (Jacobsen, 1974) was proposed. Within his paper Jacobsen critiques Amstutz work, identifying some mathematical inconsistencies and highlighting limitations of the theory imposed by approximations adopted by Amstutz. Despite these limitations Amstutz work has still been used as the favoured design theory for use in the mining industry. In reviewing this body of work the author realised that with the advent of readily available computing software it was possible to adopt an iterative approach using Amstutz approximate formulae to find a solution to the original precise formulae, thus eliminating the limitations highlighted by Jacobsen The shear deformation to load characteristics of bolts has long been established (Crawford & Kulak 1968) and used for the plastic design of bolted connections in shear. This relationship is directly transferable to the design of shear studs, typical properties are well known, and actual values easily established in simple lab tests. The author has taken this relationship and modified Amstutz theory (Amstutz, 1970) for shear anchored strengthened liner buckling, to give a more efficient solution, using readily available material properties."

Jan 1, 2019

By Mohamad Kharseh

There is general acceptance that climate change, which is the most important challenge facing humanity, is anthropogenic and attributed to fossil fuel consumption. Therefore, improving the performance of our existing energy systems and deploy more renewable energy resources is an urgent issue to be addressed. Geothermal refers to existing of heat energy in deep rock and sedimentary basins. This energy can be used to drive a power turbine to generate electricity. Traditionally, geothermal has been exploited in places with the plentiful hot water at relatively shallow depth. In the light of fact that ground temperature increases with the depth everywhere on the Earth, engineered geothermal systems (EGS) can be installed in any place to exploit the geothermal in generating energy. Unfortunately, the high exploration and drilling costs of boreholes is the main barrier to commerciality of EGS worldwide. In addition, there are technical problems associated with drilling big depth. In oil producing countries such problems can be addressed by utilizing whether active or abandoned oil or gas wells and, consequently, EGS can produce power at profit. The current study presents an analysis of a binary geothermal power generation system for commercial electricity generation in Qatar. For this purpose, two binary cycles are assumed the main difference between them is that the first one is air cooled while the other will be water cooled. The performance of the two cycles and the possibility of improvement has been shown. Economic analysis the power plant shows that the levelized costs of electricity is 3.6US¢/kWh and the pay-back time is less than 8 years.

Aug 1, 2013

Iron control and iron residue management and disposal are significant issues in all zinc production processes. This paper briefly reviews the most important primary zinc production routes and discusses the challenges posed by iron control in each of them. The technologies and strategies that have proven successful in controlling and managing iron are discussed. SNC-Lavalin's experience in designing and commissioning zinc plants provides a unique perspective from which to review this aspect of zinc production.

Jan 1, 2006

By S. C. Radopoulou

Pavement condition assessment is an indispensable constituent in maintaining roadway infrastructure. Current practices for pavement condition assessment are labor intensive which introduce subjectivity in pavement rating and are time consuming. Automated methods rely on full 3D reconstruction of the pavement surface which introduces high equipment and computation costs. This paper presents a methodology for detection of patch type distresses in asphalt pavement images. This method uses filtering and histogram equalization for clearing and enhancing the image accordingly. It continues by applying the morphological process of closing, along with some rules based on the characteristics of a patch when captured in an image, to finally detect the area it occupies. Criteria for area, length, and width of a patch as seen in an image are taken into account to decide whether a probable patch is actually a patch. The method has been implemented in C#. The preliminary experiments demonstrate it produces promising recognition results

Aug 1, 2013

By M. D. Griffith

"Ventilation models are a vital tool to ensure ventilation designs can provide airflow to all work areas in a mine. Airway resistance and variations in natural ventilation pressures will affect simulated airflow and heat distribution through a mine. Validating ventilation model resistances and pressures to the exact underground conditions can be difficult and the variances can contribute to significantly different simulation results depending on the structure of the ventilation design. The study will use sensitivity analysis to explore examples of variability of simulated airflow due to small resistance, heat and natural ventilation changes and thereby help the user identify both trustworthy and potentially unreliable parts of a mine ventilation model. INTRODUCTION Mine ventilation network modeling is a vital tool for ventilation professionals and has become increasingly relied upon during the design and operation phase of mine ventilation systems. However, they provide only an approximation of reality, and caution must always be exercised when drawing conclusions or making decisions based on simulated data. Ventilation modelling should be performed by persons with a sound fundamental knowledge of ventilation and ideally should be validated with field data, but in large mines, or mines which are yet to be mined, accurate input of the simulation variables can be difficult, and errors and inaccuracies may be difficult or impossible to avoid. This study discusses and investigates the sensitivity of the mine ventilation simulation results to input errors. In addition, there are limitations to what steady-state airflow and heat simulations can model, regardless of the accuracy of the model inputs. In some situations, steady-state solvers cannot capture the dynamic changing behavior of a ventilation system. This study will also describe and apply techniques to analyze the natural variability of mine conditions on ventilation models. The consequences of poor accuracy in some parts of a mine model may impact on the health and safety criteria of ventilation designs. For example, if an airway is required to flow in a particular direction and quantity, then despite a ventilation model showing correctly designed conditions, small errors in input values may result in incorrect prediction of the direction or quantity of airflow. This may create unexpected buildup of heat or gases during operational activities, causing safety issues or operational delays. The ability to know which parts of a mine ventilation model have increased potential for poor simulation results will allow engineers to consider the ventilation design and make changes if required to better guarantee the required design flows."

Jan 1, 2019

By Paul Hammond

Abstract The Allard Lake ilmenite deposits, which are currently being developed on a large scale, occur as a series of dykes or lenticular, flat-lying bodies within the northeastern part of a large, oval shaped anorthosire mass of Precarnbrian age which lies with its long axis paralleling the gulf of St. Lawrence. The Lac Tio deposit, discovered by Kennco Explorations, Limited, in 1946, is the largest body of titanium ore of its type now known in the world. It contains upwards of 112,000,000 short tons of ilmenite ore averaging 32 per cent TiO2 and 36 per cent Fe. The ore is an aggregate of ilmenite with oriented microscopic blades of hematite. The deposits appear to be high temperature, late magmatic injections containing only a small amount of volatiles, and bear a genetic relationship to the anorthosite rocks in which they occur. * * * Introduction Recent developments on the ilmenite deposits in the Allard Lake district of Quebec indicate the probability of a major industry, and one which may make Canada the world's greatest producer of titanium pigments and, ultimately, of titanium metal. The presence of ilmenite in this district was first reported by the Quebec Department of Mines following a reconnaissance shore-line geological survey in the year 1941. The ensuing report by Retty describes the occurrence of a number of small ilmenite lenses about the shore of Allard lake and' along two smaller lakes in the vicinity. These showings were later staked by Toronto and Montreal interests who carried out a certain amount of development work, and were described in more detail by Longley for the Quebec Department of Mines. The claim groups were later optioned by Kennco Explorations, Limited, Canadian subsidiary of Kennecott Copper. None of the deposits in themselves constituted a sufficiently large body of ore to warrant the major construction expenditures necessary for their exploitation on a profitable basis. The surrounding anorthosite areas, however, were considered favourable for the possible occurrence of other ilmenite deposits

Jan 1, 1949

By M. Sengupta

International trade in minerals plays a very important role in the economic growth of many nations. Several less developed countries a1•e heavily dependent on their mineral exports for earning foreign exchange, which is needed for industrialization. Mineral exporting nations experience many problems in international mineral markets; the most important are tariff barriers, deteriorating terms of trade, instability in metal prices, etc. The formation of international mineral cartels to raise prices can be successful only to a limited extent and only for a short period of time.

Jan 1, 1976

By E. Vesely, A. Saxena

"SAG mill liners are designed for protecting the mill shell and providing lifting power for ore charge and grinding media. Due to the impacts from the charge and the grinding media, the liner experiences dimple, plastic deformation, strain hardening, fatigue, peening and final failure. Because of the collisional environment directly measuring such dynamical loads is extremely difficult if not impossible. In this study we tried to evaluate the liner failure risk by simulating the collisions of solid particles with mill liner using Discrete Element Method (DEM). DEM simulation has been proved to be a very useful tool in evaluation of granular flow and its impacts on the solid structure. But there are certain limits in DEM coherently, such as the number of solid elements, the computer runtime, etc. Here we first present the general feature of the particle-liner collision in terms of impact force and collision energy. Then the effects of parameter selection is discussed. Our simulations show the fatal collisional event of huge impact force is very rare and the collisional events of low impact is much more frequent. The fatal event may contribute most to the liner failure. The rarity of the fatal events may be missed in a short runtime simulation. This technical challenge combined with lacking of criterion to evaluate varying impact loads in fatigue problems may further complicate the evaluation. Should we use the largest impact force alone or we should use the more frequent events is an open question and requires more effort. In order to evaluate the quality of liner design, we proposed a relative comparison method. In the end we show the implication and application of this method in liner optimization by a work example. In particular, the effects of the charge level of grinding balls and their size on the operation performance is presented.INTRODUCTION Grinding is one of the most important and expensive steps of mineral processing. A variety of grinding mills such as rod mills, ball mills, semi-autogenous (SAG) mills and autogenous (AG) mills are being utilized for comminution of mineral ores (Gupta & Yan, 2016). Up to today, SAG mills and AG mills have been widely used to reduce operation costs and increase throughput. In an AG mill, a rotating drum throws larger rocks of ore in a cascading motion which causes impact breakage of larger rocks and compressive grinding of finer particles. Unlike AG mills, SAG mills use steel grinding balls to break ores of size quite small such that they cannot be easily broken in AG mill. SAG mill liners are designed for protecting the mill shell and providing lifting power for ore charge and grinding media. Due to the impacts from the charge and the grinding media, the liner experiences dimple, plastic deformation, strain hardening, fatigue, peening and final failure. Quality and performance of SAG mill liners play a fundamental role to enhance efficiency of grinding mills, because failure of liners is the major cause for unexpected breakdown (Banisi, Hadizadeh, Mahmoudabadi, & Eilkhany, 2006)."

Jan 1, 2019

By S. Beitler

The availability of renewable energy does not meet the demands of consumption. Hence, fossil fuels will continue to be an important energy source, and coal promises to cover the requirements for the coming decades. Because of its high energy content, deep lying bituminous coal and anthracite are important for energy generation. One trend in the future of coal mining is thin seam mining, because thick seams more and more have been exploited. A well-known and approved longwall mining method for thin seams is plowing which has big advantages compared to a shearer because of its compact design. The extraction of those thinner coal seams will become more and more important in coal industry and therefore the plow will receive more attention in future. Most approaches in longwall automation are focused on the shearer and need a more or less intelligent exploitation machine. Therefore those approaches cannot be used for the plow technology. The authors introduce a shield-data-based horizon control (SDHC). The developed approach integrates the shield data provided by the roof support and process monitoring into the horizon control process to keep the plow in seam even if the seam trend changes. This control concept can be used for the shearer as well as for the plow. The basic idea of SDHC for plow application will be introduced in this paper and first simulation results will be shown.

Aug 1, 2013

By Haipeng Li, Jacob Masliyah, Barun Gorain, Jian Huang, Qingxia Liu, Zhenghe Xu, AuTec Innovative Extractive Solutions Ltd.

"Froth flotation is widely used to selectively separate one or more minerals from an ore over a wide range of particle sizes with high efficiency. Bubble–particle attachment is one of the most critical steps in flotation. The objective of this project is to demonstrate the need for an innovative dual bubble generator to improve flotation efficiency. This dual bubble generator was designed to generate two different sizes (micron size and typical flotation size) bubbles. The micron size bubbles generated on the crevices of particle surfaces in venturi type of cavitation tubes enhanced the attachment of fine particles to the bubbles in conventional flotation systems. They also acted as a secondary collector, which has the potential to reduce operation cost and improve flotation recovery. The dual bubble generator was evaluated for a double refractory gold ore with 3g/t Au, 1.5 wt% TCM (total carbonaceous matter) and 0.7 wt% sulfides. The results were compared with those obtained using a commercial bubble generator. Compared with the commercial bubble generator, the dual bubble generator showed not only a higher gold recovery, but also an improved separation efficiency, demonstrating the potential of dual bubble generator in fine particle flotation.INTRODUCTIONFroth flotation has been widely used in mineral processing and waste water treatment. However, flotation has been proven inefficient for fine particle recovery although it becomes increasingly inevitable to process fine particles with the depletion of easy processing ores. The critical problem of fine particle flotation is the low attachment of fine particles to flotation size bubbles due to their low collision rate. Based on a commonly acceptable flotation model given by R =F*[Pc*Pa*(1-Pd)], the probability of bubble–particle collision (Pc), attachment (Pa) and particles detachment from air bubbles (Pd) collectively determines fine particle recovery (R) (Yoon and Luttrell, 1986). Since Pc = (3Dp/Db) where Dp and Db are diameters of particles and bubbles, respectively, bubble size and particle size impact the bubble-particle collision in opposite directions. It is evident that the probability of bubble–particle collision decreases with decreasing the size of particles, leading to a low recovery of fine particles. In this case, reducing the bubble size and/or increasing the apparent size of particles by fine particle aggregation are clear means to improve fine particle recovery."

Jan 1, 2016

By W. J. D. Stone

"For several years, the existence of a deposit of barite (BaS04) near Brookfield, Nova Scotia, has been known. A very large deposit of strontium (SrS04) near Sydney, Cape Breton, is a more recent discovery. Cape Chemical Syndicate has been formed to work the deposits. A five-million-dollar integrated mineral processing and chemical plant is planned for Sydney to produce various compounds of barium and strontium. The mineral processing plant includes the Jones Wet Magnetic Separator and will produce high-purity barite and celestite. These products will be processed further in the fine grinding plant and the chemical plant. The general project is described, covering the deposits, processing and markets."

Jan 1, 1969

By D. Gagnon, B. Dubreuil, J. -M. Lalancette, D. Lemieux

"The pilot scale extraction of gold with a brine of sodium chloride and bromide at 30 ºC, in an atmosphere of halogens at atmospheric pressure, leads to gold chloride with 95% gold recovery. The use of dilute hypohalites (1 – 3%) instead of free halogens, which is strong enough to oxidize hypobromite into bromine, simplifies the recycling of halogens by electrolysis. With the recycling of water and brine, the regeneration of hypohalites and with a barren solid that is inert and stable. The Nichromet Extraction technology is a green process where the protection of the environment does not preclude profitability.INTRODUCTIONThe use of chlorides for the extraction of gold predates the discovery of chlorine by Scheele in 1774. In the Plattner chlorination process (Christy, 1888) sodium chloride and copper salt were used to promote gold recovery by amalgamation with variable results. The introduction of the cyanide technology in 1889 has led to a general use of this method for gold recovery. In the last decades, a return to chlorine in extractive processes has been noted (Ferron, Fleming, O’Kane and Dreisinger, 2002), mostly because of environmental pressure for non-cyanide technologies.This paper describes a closed circuit proprietary approach (Lalancette, 2009) developed and piloted by Nichromet Extraction Inc. for the extraction of precious metals with recycled mixed halogens; chlorine and bromine from hypohalites. DESCRIPTION OF THE PROCESSThe attack of gold by halogens can vary significantly. The rate of reaction is substantially higher with bromine (Br2) than with chlorine (Cl2), by a factor of more than five, although the oxidation potential of Cl2 is higher than Br2, as shown in Equation 1a and Equation 1b (Latimer, 1952)."

Jan 1, 2012

By E. Swartzman

"DURING 1951, experimental cleaning studies on both fines and larger sizes of certain Canadian coals were conducted on a relatively large scale in two pilot plants in the United States, large enough to be considered as small commercial units, and in one commercial plant in Canada.One of the pilot plants was a wet washer of a type which apparently has never been .used in Canada, nor has any Canadian coal been tested in it before. In the other pilot plant and in the commercial plant, dry cleaning equipment was used. The commercial plant is the first of its kind to be employed in Canada, and this type is used only to a limited extent in the United States.Fine-Coal Cleaning ExperimentsTest PlantsHydrotator and Hydrotator-Classifier combination pilot-plant with a capacity of about twenty tons per hour. This is a classifier type washer adapted for cleaning fine coal as well as certain intermediate sizes. The Hydrotator deals with that portion of a coal retained on approximately a 24-mesh Tyler sieve, whereas the Hydrotator-Classifier deals with the minus 24-mesh fines."

Jan 1, 1952

By L. E. Puddington, A. L. Mular

"Since the inception of spherical agglomeration, few investigations to exploit commercially the technique in the metallurgical field have been conducted. Of these, none appear to have been carried sufficiently far to demonstrate commercial feasibility.This paper describes a continuous agglomeration-separation process that can rapidly handle large tonnages of ore material. A small pilot plant de-signed from information obtained with the semi-batch unit described herein is currently in operation.In the absence of a reagent recovery system or cheap reagents, the process is probably not economically attractive for many common ores. However, for iron ores, the fuel content of the agglomerates can be used in a subsequent step such as direct reduction."

Jan 1, 1968

By Gilles Bonin

Structures and serpentinization patterns in the Thetford Mines peridotites are important characteristics indicating the necessary geological conditions which led to the development of chrysotile orebodies in Early Ordovician limes. These structures and serpentinization patterns are reviewed in this paper using the geology of LAB Chrysotile orebodies as a model. Structural aspects include parallel and transverse faults, parallel and transverse granite slabs, and orebodies, some of which trend clearly north-westward parallel to the accretionarymovement. Serpentinization patterns in the peridotite belt, particularly in the harzburgite, include primary pervasive mass serpentinization and secondary complete serpentinization. Listwaenites layers appeared along some faults and along some granite slabs as a result of hydrothermal alteration of the serpentine, following the emplacement of the devonian plutons to the south. These plutons as we/1 as other important lineaments, align with the structural pattern of Thetford Mines ophiolites. It is believed that these plutons are part of a heavy magma tic corridor resembling the Pilote-Mont-Louis corridor in the Gaspe (Doyon and Berger, 1997), and the Buchans' structure in Newfoundland (Hutchinson, 1984), both intersecting the Brompton-Baie Verte line.

Jan 1, 2001

By D. J. Scarpato

"Slope construction in shale can present some interesting challenges for geotechnical design engineers and contractors alike. There are challenges that can be expected and designed-for; however, all too frequently, such challenges manifest themselves as “surprises” in the field. Common constructability challenges can include those such as drill hole deviation during drilling for controlled blasting; and, excavation slope instability arising from inconsistent perimeter control drilling. Drill hole deviation results from the cumulative effects from both drilling mechanics and rock mass conditions. Once a hole has initiated the deviation trajectory, it is difficult to rectify drill steel position. Although such challenges are not necessarily unique to shale, they are often exacerbated by weak, weathered and transversely isotropic nature of bedrock conditions. All too often, the working assumption is that shale is “soft” and easily excavatable; however, this blanket assumption can prove to be costly. This paper is intended to provide design professionals and contractors with the practical considerations needed to avoid the “surprises” associated with drill hole deviation, and minimize the potential for costly claims.INTRODUCTIONFor all the slopes that have been excavated worldwide, and for such advancements in excavation technology and field characterization, one might be tempted to believe that the industry almost has slope development down to a science. This is frequently not the case, especially for weak/weathered and anisotropic bedrock. Excavation contractors are still pushed to the limits of what their technology can achieve, and engineers are all too often called to the field during construction, to make potentially risky onthe- fly decisions relative to excavatability, short and long-term slope stability, and project safety. Although there have been a host of other research papers and journal articles that have been written on the subject of deviation over the past 30 years (Brown, Geen, Sinha, 1981), the problems associated with drill hole deviation are still all too frequent. This fact is especially true for civil engineering surface excavations in bedrock."

Jan 1, 2015

By T. S. Smith, C. C. Rennie

"THE LEAD-ZINC and tungsten mines of Canadian Exploration Ltd are on Iron Mountain, 8 miles south of Salmo, B.C., in the Nelson mining division. Relative location of the mines is shown on the general plan.First recorded lead production was in 1908 from surface outcrops. Small amounts of high lead ore were mined intermittently until 1926. No major lead-zinc production occurred until 1949 when outcroppings on the south side of the mountain were mined and diamond drilling began to prove the existence of a large replacement orebody. Lead-zinc ore has been mined continuously from the Jersey orebodies since March 1949, with monthly tonnage as high as 50,000 tons per month, but currently averaging 30,000 tons per month.Schee1ite-bearing tungsten ore was found in 1942 by H. Lakes in an old adit and open cuts at the north end of the Emerald tungsten orebody. The Emerald tungsten mine was developed by the Federal Government as a Wartime Metals project and operated for eight weeks in the fall of 1943, when the poor demand for tungsten closed the mine. Canadian Exploration Ltd. purchased the mine in 1947 and mined in excess of 100,000 tons in 1947-48 until the demand for tungsten dropped again and interest was centred on lead-zinc. The Federal Government repurchased and reopened the Emerald Mine in 195 L and built a new concentrator. The mine and mill were sold back to Canadian Exploration Ltd. in 1952.Regional Geology and IntrusivesThe host rock for both the lead-zinc and tungsten mineralization is the Laib formation of Lower Cambrian age, which consists of 400 feet of crystalline limestone underlain by beds of argillite, and argillaceous limestone locally altered to ""skarn"" or ""tactite"". The Laib limestone is overlain by black argillite and underlain by the Reno quartzite of Pre- cambrian age. Repetition of folded beds has allowed the interpretation of the large isoclinal fold which repeats the limestone (see general cross-section). Dolomitization and the associated lead-zinc ore have been found only in the right-side-up limestone and are not known in the overturned limestone.Two elongated stocks of granite cut the sediments. The Emerald stock outcrops along the east side of the Emerald tungsten mine and again west of the Jersey workings, while the Dodger stock outcrops only at the north end of the Iron Mountain. The shape and attitude of these bodies are believed to have been governed partly by pre-granite faulting and partly by pre-granite folding of the sediments. Although some forceful intrusion may have occurred the detailed granite surface indicates a gentle stoping emplacement."

Jan 1, 1949

By I. Soosaiprakasam

This work investigated inhibition performance of copper carbonate (CuCO3), which is less toxic than conventional heavy-metal corrosion inhibitors in amine treating plants, The investigation was experimentally carried out in a bench-scale electrochemical corrosion cell under an atmospheric pressure, The inhibition performance of CuCO3 in an aqueous solution of monoethanolamine (MEA) was examined under a wide range of operating conditions and reported as a function of process parameters including inhibitor concentration, temperature and solution velocity, The results show that CuCO3 functions as an anodic inhibitor. The addition of CuCO3 decreases corrosion rate of carbon steel but might induce pitting corrosion/

Jan 1, 2005