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By M. S. Badollet

"DURING the past five years, production of asbestos fibers has increased in all countries that list asbestos as one of their mineral resources. Despite the many small mines that have been opened in Canada, United States, Mexico, South America, Italy, South Africa, Australia, Yugoslavia, and Rhodesia, the supply still does not meet the demand. It is estimated that total 1952 world production of asbestos fibers of all varieties approximated 1,600,000 tons, with Canada supplying 966,382 tons (I), or 60 per cent of all fiber mined.Asbestos fiber brokers continually are offering odd-lot samples of chrysotile, amosite, crocidolite, tremolite, and anthophyllite fibers to manufacturers, •quoting fantastic prices for tonnages •varying from just a few to 50 or more in a month. In many cases, the samples are not properly graded and contain quantities of rock impurities and finely ground dust.When vendors submit samples of asbestos fibers, the manufacturer should consider• them in terms of price, quality, quantity, and as possible substitutes for fibers currently used in his products.Grading of these odd-lot fibers in most cases has been poorly done, with resultant non-uniform fiber lengths. In some instances, a number of miscellaneous lots of fibers have been .blended for sale. This blending produces a fiber that is difficult for the manufacturer to accept as a substitute for the well-standardized Canadian fibers."

Jan 1, 1953

By Vladislava A. Ignatkina, Fillip O. Milovich, Vladimir A. Bocharov

"Complex research of flotation concentrates of monomineral fractions of chalcopyrite, sphalerite, galena, pyrite, pyrrhotite included methods of adsorption of collectors, surface compounds by IR ATR, and surface films of flotoreagents by TEM. They revealed that the proportion of the parts of thionocarbamate (TC) and dithiophosphate had an effect on the adsorption rate of the components of minerals, on the presence of characteristic bands, and, what is an important, visualized surface film of organic flotation reagents on the particles of concentrates by TEM. The predominance of thionocarbamate in a composition selectively increases the adsorption rate constant of the components and recovery of chalcopyrite compared with sphalerite and galena. The highest flotation rate using TC is characteristic for chalcopyrite (0.62 min- 1) in case of individual use, and it's in combination with butyl xanthate (25% butyl xanthate or 3:1) 0.89 min-1 too. We studied the ternary blend - dithiophosphate: thionocarbamates: butyl xanthate. The increase of the proportion of butyl xanthate in combination reduces the contrast of the flotation rate among all sulfides.Practice flotation of refractory sulfide copper-zinc ores of the Urals (content sulfide iron - 75- 95%) confirmed that the use of a combination of selective collectors increases selective recovery of copper sulfide minerals up to 50% at the first fraction that is the conditioned copper concentrate. New selective sulfhydryl collectors resulted in high levels of recovery of copper into a concentrate - more than 90% - against 70-72% (butyl xanthate) from copper-pyrite ore. Low floatability of iron sulfides has been obtained by selective sulfhydryl collectors. Using weak selective sulfhydryl collectors can reduce pH into collective or selective flotation from pH 10-10.5 to pH = 7.2-7.5, which improves the quality of individual concentrates of nonferrous metals and their recovery. The same is true for polymetalic sulfide ore. The volume of gold recovery also increased."

Jan 1, 2016

By Norman B. Davis

THE ceramic group of industries is comprised of those engaged in the manufacture of cement, glass, artificial abrasives, whiteware, including earthenware, stoneware, porcelain tableware, porcelain sanitary ware, electrical porcelain, floor and wall tile, porcelain enamel on metals, refractories of all kinds, sewer-pipe and structural clay products, such as terra cotta, brick, and hollow tile. The various sub-divisions of the industry produce a wide range of articles on which we depend for our creature comforts from day to day, perhaps to a greater extent than we generally realize. The industry, in turn, depends on a great number of minerals, and chemical products derived from minerals, and it is the object of this brief paper to present a list of these with notes indicating the particular applications. In order to bring home the importance of the industry to your daily life, stop and consider the many things around you accepted as a matter of course. Cement provides the smooth surfaces of many of our highways, city streets, and sidewalks. It enters into nearly all types of construction, alone or in combination with other clay products. Glass we hardly appreciate because we can see through it so easily, but it is there to serve us in windows, doors, and other light-transmitting structures. Glass is the universal means of transporting liquids and beverages, our beverages are usually served in it, and, with the recent development in fine spun glass textiles, there is a possibility of glass clothing in the future. Chinaware, a general term for table dishes, may be earthenware (not vitrified), semi-porcelain, or bone china, but it is before us three or more times a day ?and we seldom think of the minerals that have made these products possible. Floor tile, wall tile, and other ceramic specialties for interior and exterior use and decoration please the eye and provide sanitary surroundings.

Jan 1, 1938

By Peter N. Calder

The orientation of planes of inherent weakness (joints) with reference to an excavation in rock is the critical factor determining stability. The purely frictional 'residual' strength remaining following the breakdown of initial cohesion is the only strength which can be counted on to resist sliding for the long term. A simple method of resolving driving and resisting forces in three dimensions along joint intersections 'undercut' by the excavation is presented. Contrary to the case of slope failure in soils, it is shown how significant changes in the slope angle sometimes have no effect on the degree of stability pre-sent in rock slopes. Wall control by reorientation of the slope, the use of cable bolts and water diversion are briefly discussed.

Jan 1, 1970

By J. F. Liu, L. Chen, C. P. Wang

"Calcite-cemented joints abound in the rock masses of Beishan area, which is the most potential area for the high-level radioactive waste (HLW) disposal of China. The mechanical properties of Beishan granite containing a calcite-cemented joint with a dip angle of 82° was investigated under uniaxial compression and the acoustic emission (AE) characteristics were also studied in this paper. Compared to intact granite, the calcite-cemented joint caused a decrease more than 50% in uniaxial compressive strength and a decrease more than 90% in shear strength. The Young’s modulus was also decreased, while the circumferential deformation of jointed granite was sharply increased. The AE monitoring system successfully recorded the process of micro-crack development and the results indicated that the risk of rock-burst could be reduced due to the appearance of calcite-cemented joint.INTRODUCTIONThe properties of jointed rocks differ considerably from that of intact rock. Due to the difficulties in specimen preparation, analogue experiments with artificially prefabricated fractures are often used to study the mechanical behavior of jointed rock (Chen et al. 2012; Kulatilake et al. 2001; Singh et al. 2001). However, natural joints are not quite similar to the artificial fractures and it is necessary to investigate the mechanical behavior of jointed rocks. Xie et al. 2011 studied the mechanical properties of marbles with natural joints by uniaxial compression tests and found that the uniaxial compressive strength of jointed rock is greatly decreased. With the unaxial compression tests, Jacobsson 2005, 2007 tested the intact and jointed granites, which were taken from the potential site for high-level radioactive waste (HLW) disposal of Sweden. However, no significant difference in strength or modulus was found. The above research results are inconsistent and it indicates the complexity of the mechanical properties of natural joints."

Jan 1, 2015

By Deepak Bhadouriya, Saurabh Singh, Aditya Raj Suman

"An experimental study of chemically enhanced filtration and dewatering of fine coal slurry with and without additives was carried out. The experiment involved determination of effect of slurry concentration, additives (cationic, anionic and nonionic), filter area, filtration velocity, particle size and cake resistance on dewatering and filtration using vacuum filtration cell. Finally, the rate of filtration and dewatering and optimum amount of additives used were determined under suitable filtration condition. Overall, it was found that the filtration and dewatering characteristics were enhanced by increased slurry concentration, larger filter area and larger particle size. In addition of additives, the kerosene was found to be best for enhancing the filtration which yielded cake moisture reductions of approximately 17% by weight. At optimum dosages, the final cake moisture contents were reduced by 3.6% and 5.8% by weight using the appropriate surfactant and flocculent, respectively.INTRODUCTIONFor India, it is estimated that coal constitute a principal source of energy for the next several decades. It is majorly used at thermal power plants to generate electricity and also to a great extent in steel and cement industry. It has been observed that its consumption is increasing so as to meet the energy requirements of the country. It has been found that in a coal preparation plant; approximately 20-25 percent coal is of the mined coal of the range below minus 0.5 mm (28 meshes). Generally, this fine fraction is discarded due to its high cost of processing and further utilisatisation is very minimal. But with ongoing research and development for advanced clean coal technology, various new techniques have been evolved to maximize the utilization of available coal. In recent time technologies such as column flotation, cleaning of fine size coal to lower the ash content and low pyretic sulfur is feasible at high recovery value. But in various researches it is found that one of the biggest hurdles in utilization of fine coal cleaning technology by the coal industry is the economic dewatering of the fine clean coal product. Thus, until an economical and practical solution to dewatering of fine clean coal is achieved, the efforts devoted to developing fine clean coal technology will be wasted. In this paper an effort toward enhancing and developing the optimum technique of dewatering and filtration of fine coal slurry has been made."

Jan 1, 2016

By D. M. Baird

"THE Island of Newfoundland lies on the extreme eastern edge of the continent of North America and at the extreme northeastern end of the Appalachian geological province. Its belonging to the Appalachian province is shown in the geological history of the region and in the rock types and structures.Geosynclinal sedimentation in early and middle Palaeozoic times was interrupted by Taconic and, more profoundly, by Acadian, mountain building activity. Mid-Palaeo-zoic intrusions range from masses of serpentinized ultrabasic rocks to granite batholiths. A Carboniferous overlay of continental and shallow, drying sea types covers the earlier developed complex. Local basins in these times were filled with products of the erosion of tl1e earlier rocks, and, locally, grew the right kind of vegetation to make thin, discontinuons seams and pockets of coal. Post-early Pennsylvanian history is one of erosion and pene-planation with renewal of movement along many of the older fault systems."

Jan 1, 1960

By M. M. Holgate

"Porosity neutron deflection scales can be derived more easily by cumulative correlation than by the conventional method of plotting corresponding points on a graph. The micro-log can be used as a porosity datum for the neutron log by transforming the permeability cut-off it shows to a porosity cut-off by a permeability-porosity function obtained from core analysis. Porosity footage values calculated in this manner from the neutron log are within 20 per cent of core analysis values."

Jan 1, 1960

By Albert G. Zima

THE conservation of strategic materials during war rime gives rise to many problems not commonly encountered in times of peace. During normal times, when world trade is unrestricted, we are apt to become lavish to a point of extravagance in our use of those materials which, during rime of war, become scarce owing to inadequate transportation and production facilities or because the enemy may be in position to control sources of supply. It becomes necessary, then, to enforce rationing of available sup-plies, and in some cases, where such supplies are wholly inadequate, we find we must resort to the use of substitute materials. We are now confronted with such a problem to an extent never before experienced, with the result that many of the commodities upon which our civilization depended are now either shut off completely or, because of the heavy demand occasioned by war production, are not available in sufficient quantities to meet requirements predicated on peace-time standards and manufacturing methods. It has become necessary, therefore, to make many changes, some of them very drastic indeed, to enable us to carry on our war effort effectively. This? discussion will deal briefly with one phase of this problem, namely, the conservation of alloys required in the making of steels necessary for war production. In line with a request from the War Production Board, the Technical Committee on Alloy Steels of the American Iron and Steel Institute made a study of experimental steels embodying the !east amount of alloying constituents, with the objective in mind of substituting these steels wherever possible for the standard alloy steels used heretofore. This study embraced the following phases: (1) The availability of silicon and manganese; (2) The average quantity of alloying elements recoverable from scrap; (3) The effect of increases in manganese and silicon contents on the general properties of steel; ( 4) The elements and ranges of elements which might be used to duplicate the hardenability of the steels now in use; (5) The effect of combining several elements in small quantities upon the properties of steel at various hardness and strength levels; (6) A determination as to whether or not the steels selected would suffice for general application. Working on this basis, the Committee arranged for the manufacture of several heats of steels containing various combinations of different amounts of such elements as silicon, manganese, chromium, nickel, and molybdenum. The steels thus produced were compared by hardenability tests.

Jan 1, 1943

By B. Tiryaki, M. Ayhan, O. Z. Hekimoglu

Coal shearers are one of the major sources of dust and fines in underground coal mines. Despite considerable research investigations, no comprehensive in situ investigations coupled with extensive laboratory studies on the effects of drum design on generation of dust and fines have been found. It may be for this reason that many major shearer drum manufacturers persistently employ a certain drum-lacing pattern on current coal shearers, which is believed to cause excessive dust and fines in coal mines. This paper shows how respirable dust and fines are minimized under near-identical conditions when the drum lacing pattern was changed from a triple-tracking to a single tracking arrangement. A series of laboratory trials simulating in full scale the practical cutting action of tools was followed by extensive long-term underground trials during production operations in OAL (Cayirhan) Lignite mine in Turkey. The results are presented and discussed, and recommendations for proper drum-lacing in terms of respirable dust and fines are made.

Jan 1, 2002

By Toivo Toivanen

The paper begins with a brief history of the nickel industry in Finland, and then deals with the introduction of the flash smelting process. The main part of the paper is devoted to nickel refining, which is studied under four main headings -grinding, leaching, electrolyte precipitation, and nickel electrowinning. Flowsheets are illustrated, and the equipment used is described. Analyses of the material in the various stages, from concentrate to high-grade nickel matte, are also presented. N ICKEL made its appearance in the Finnish mining industry forty years ago, when a nickel deposit was discovered at Petsamo in Lapland. Mond Nickel Co. received the concession for this deposit from the Finnish Government, and the Petsamon Nikkeli Company constructed a mine and a nickel smelter (1), the completion of which was prevented by the 1939 Winter War. The mine and smelter were, however, completed soon afterwards in spite of World War II,

Jan 1, 1964

By A. Shakoor, T. P. Gautam

The long-term slaking behavior of clay-bearing rocks in the field can be quite different than the short-term slaking behavior in the laboratory. To assess this difference, 12 replicate samples of each of 20 clay-bearing rocks, including 5 claystones, 5 mudstones, 5 siltstones, and 5 shales, were exposed to natural climatic conditions for 12 months. After each month of exposure, one replicate sample of each rock was removed from natural exposure and its grain size distribution was determined. Disintegration ratio (DR), defined as the ratio of the area under the grain size distribution curve of the slaked material for a given rock to the total area encompassing all grain size distribution curves of the tested samples, was used to quantify the amount of disintegration under natural climatic conditions. DR values of naturally exposed samples were then compared with the corresponding values of second-cycle slake durability index (Id2) determined in the laboratory. The relationship between Id2 and DR after, 1 month of exposure, exhibits an R2 value of 0.65 but the relationship deteriorates when DR values for 6 and 12 months of exposure are used, with R2 values of 0.63 and 0.25, respectively. However, when DR values for laboratory samples, computed from grain size distributions of slaked material after second cycle, are compared with DR values of naturally exposed samples for the three periods of exposure, the relationship improves with the corresponding R2 values being 0.61, 0.71, and 0.41. These results suggest that DR may be a better parameter for assessing the long-term disintegration behavior of clay-bearing rocks than Id2.

Jan 1, 2015

By F. Dubuc

"The Adams Mine of Jones & Laughlin Steel Corporation is situated on the Boston Township iron range near Kirkland Lake, Ontario. Eight different orebodies have been outlined, with a total open-pit crude tonnage of. about 100,000,000 tons or the equivalent of 30,000,000 tons of concentrate. The ore consists of fine-grained, well-bedded Early Precambrian iron-formation composed essentially of alternating layers of chert and magnetite. Grade averages about 22 per cent magnetic Fe.The iron range varies in width from 3,000 to 4,000 feet and is made up of several horizons of iron-formation, cherty ""quartzite"" and volcanic rocks. The latter consist mostly of basic lava flows and minor amounts of tuff. Dips are rarely Jess than 50 degrees, and the range is believed to represent an overturned limb of a major synclinal structure. Dykes of syenite and lam prophyre, along with local younger diabase, intrude the rocks of the iron range."

Jan 1, 1966

By M. M. C. Lima, L. C. S. Solimani, M. A. Quintela

Galvanized steel scrap is recycled to B OF converters where zinc escapes from the bath and is captured by the gas control system, appearing in BOF sludge. As BOF sludge contain high iron content, it could be recycled, but due to its zinc content, it is disposed in landfills. In this study techniques were evaluated for zinc layer removal from scrap by sulfuric acid leaching. The effects of coating weight, temperature, time and sulfuric acid concentration were evaluated for three different galvanized scrap. The results showed that the behavior of each galvanized scrap was different. Nevertheless zinc removal efficiency was more than 80% with low dissolved iron in the leached solution.

Jan 1, 2011

By D. J. Xue

Four kinds of coal-rock combination were subjected to three kinds of stress waves in the SHPB numerical simulation. The wave propagation and the changes of the strain energy in the coal-rock combination during the dynamic impact process were recorded as well as the contact force. The dynamic response law of coal-rock combination was obtained. It was found that the coal had better reflectivity than the rock because of coal with larger impedance. In contrast the rock had better transmissivity. As the crest value of the incident wave increased, the increment in the crest value of the transmitted wave weakened in the coal-coal group, coal-rock group and rock-coal group, in contrast, the increment in the rock-rock group increased.

Aug 1, 2013

By A. Aftabi

Abstract-To evaluate geochemical aspects of sheared zones, 35 samples of granitoid rocks from an area of shearing >5 km2 at Derehamzeh, Iran were studied geochemically. Relatively unaltered samples within the shear-zone area average 38 ppm Cu, 1.45 ppm Mo, 4.6 ppb Au, 0.21 ppm Ag, <1 ppm Re, 46 ppm Zn, 28.5 ppm Pb, and 0.34% S. Bleached, hydrothermally-altered samples are anomalous in Cu (>896 ppm), Au(>59.5 ppb), Ag(>24.4 ppm), Re(>1.28 ppm), Zn (>164 ppm), Pb (>218 ppm), and S(>0.9%). Some samples from bleached sheared zones that are highly anomalous in Cu (5000 ppm), Mo(23 ppm), Ag(74 ppm), and Au(200 ppb) are characterized by a typical sericitic alteration assemblage consisting of sericite, pyrite, chalcopyrite, and granular quartz. The main anomalous zone extends over about 0.4 km2 in the southern part of the area. The strong Cu- Mo-Au-Ag association in the sericitic shear zones suggests a possible relationship to porphyry copper mineralization, similar to that found in northern Chile. Further studies on drill-core samples in the southern sericitized shear zones are required to determine if more extensive porphyry-type sulfide mineralization is present.

Jan 1, 1997

By Namavari. H., M. Ashouri, M. R. Sarhadi, S. H. Mansouri, A. Sarrafi

The splash phenomenon and its effective parameters in metallurgical converters have been studied thoroughly for decades. The detailed studies of processes such as tuyere blockage, wave formation during air injection, entrapped phases, and also processes which control the formation of bubbles in viscous fluids are not feasible yet. In this research, we have used a converter-shaped vessel made of flexi-glass. Water and oil have been used as matte and slag phases respectively. The effective operational factors responsible for creation of splashing have been studied such as air flow rate, tuyere angles, depth of tuyere submergence, tuyere blockage, density and viscosity of liquids, liquids heights, etc. The results have been found as follows: the amount of splashing increases slowly as air flow rate increases. However, as the air flow rate reaches a critical value (depending on the physical specification of converter) the amount of splashing rises sharply, because the flow of air inside the liquid changes from bubbling into a jet stream; and most of the splashed materials are in the form of filaments instead of droplets. Changing tuyere angle from horizontal towards vertical position will increase the turbulence level on the fluid surface and causes an increase in the amount of splashing. The effect of tuyere submergence is related to the converter opening angle. As the converter opening angle is shifted towards the hood position, the amount of tuyere submergence and splashing will increase. As density of the liquid increases, the number of droplets splashing increases with a decrease in drop size. Therefore, the total amount of splashing decreases. However, as viscosity of the liquid increases, the splashing material increases due to the changes in the splashed material from droplet shape into filament form. The height of liquid inside the converter, depending on the relative height of heavy phase and light phase, is an important parameter regarding splashing. As the relative height of heavy phase to light phase increases the splashing will decrease. The tuyere blockage will cause the pressure in the inlet manifold to increase; and in real cases will increase the splashing. Finally, we have development a model based on dimensional analysis to relate the above parameters in order to calculate the amount of splashed material.

Jan 1, 2007

By V. G. Papangelakis, A. Dani

"Alkaline pressure oxidation, particularly in the presence of trona as additive, can be used to oxidize high carbonate refractory gold ores as it prevents the formation of CO2 in the autoclave. However, the presence of silica in the ore can lead to the encapsulation of pyrite due to the solubility of silica in alkaline solutions and its subsequent reprecipitation on the reacting pyrite surface, leading to the formation of a passive layer. This fundamental study investigates the chemical composition and thickness of the passive layer on a rotating pyrite disk using XPS and SEM, as a function of process conditions at 230°C, in an aqueous slurry containing silica sand, sodium carbonate and calcium carbonate under 100 psi of oxygen overpressure.INTRODUCTIONAlkaline pressure oxidation (POX) has been used successfully to treat high carbonate refractory gold ores, which contain carbonates in addition to sulphides, most notably at Mercur and Goldstrike mines operated by Barrick Gold. There are several advantages to using alkaline POX over its acid counterpart, especially due to high carbonate content. First, it eliminates the production of CO2 in the autoclave without resorting to pre-acidification, which allows for high oxygen utilization. Second, alkaline POX suppresses the formation of elemental sulphur and intermediate sulphur oxyanions (such as thiosulphates and dithionates), which reduce gold recovery. Third, the use of sodium hydroxide or salts prevents the formation of anhydrite scale by forming soluble sodium sulphate. Other advantages are the use of cheaper materials of construction and the formation of non-acidic residue that do not require further treatment prior to cyanidation (Thomas, 2005).Sodium carbonate in particular is a promising reagent for alkaline POX because it was shown to significantly accelerate the kinetics of pyrite oxidation by molecular oxygen, when compared to other reagents such as sodium hydroxide, sodium borate and calcium hydroxide. This has been attributed to the following factors: a) the faster oxidation kinetics of Fe2+-CO3 complexes compared to Fe2+ oxidation, b) the buffering effect of carbonate ions on the acidic pyrite surface, and c) the increased solubility of oxidizing Fe(III) species due to carbonate complexation (Caldeira, 2010)."

Jan 1, 2012

By P. Talonen

Since the last Iron Control in Hydrometallurgy Symposium in Montreal in 1996, the Kokkola zinc plant has increased its capacity from 175,000 t/y to 280,000 t/y by installing an atmospheric concentrate leaching process, which has also affected iron control in the leaching circuit. Major changes have been made at the jarosite residue pond; a subterranean plastic wall reinforced with bentonite and cement has been built around the pond. A new water collecting system that is used for groundwater level control in the pond area was installed. With these two investments in the pond area, it is now possible to prevent any seepage flow from the pond into the surrounding environment. Water pumped from the residue pond is treated in the water treatment plant. This paper describes the behavior of iron in Kokkola&apos;s current leaching processes. The treatment of the jarosite, the improvements to the residue pond and the water treatment process are also described.

Jan 1, 2006

By A. Aftabi

To evaluate geochemical aspects of sheared zones, 35 samples of granitoid rocks from an area of shearing >5 km2at Derehamzeh, Iran were studied geochemically. Relatively unaltered samples within the shear-zone area average 38 ppm Cu, 1.45 ppm Mo, 4.6 ppb Au, 0.21 ppm Ag, <1ppm Re, 46 ppm Zn, 28.5 ppm Pb, and 0.34% S. Bleached, hydrothermally-altered samples areanomalous in Cu (>896 ppm), Au(>59.5 ppb), Ag(>24.4 ppm), Re(>1.28 ppm), Zn (>164 ppm), Pb(>218 ppm), and S(>0.9%). Some samples from bleached sheared zones that are highly anomalous in Cu (5000 ppm), Mo(23 ppm), Ag(74 ppm), and Au(200 ppb) are characterized by a typical sericitic alteration assemblage consisting of sericite, pyrite, chalcopyrite, and granular quartz. The main anomalous zone extends over about 0.4 km2in the southern part of the area. The strong Cu-Mo-Au-Ag association in the sericitic shear zones suggests a possible relationship to porphyry cop-per mineralization, similar to that found in northern Chile. Further studies on drill-core samples in the southern sericitized shear zones are required to determine if more extensive porphyry-type sul?de mineralization is present.

Jan 1, 1997