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By M. Kozlowski, I. Candy, S. Kashani-Nejad

The production of ferronickel and matte from nickel laterite ores is dominated by the Rotary Kiln, Electric Furnace (RKEF) process. Over time, major improvements have been made to kiln operation. In particular, kilns are now required to perform substantial amounts of reduction of the metallic oxides, thereby reducing the load on the electric furnace and substituting less expensive fossil fuel for electrical energy. To the basic refractory lined cylinder have been added: internal features such as dams and lifters, aimed at changing residence times in different sections of the kiln and enhancing gas/solids interaction, on-board fans to introduce tertiary air and on-board scoop mechanisms to allow reductant coal additions to be made at advantageous locations along the kiln. Many of these advances in design have been made on a trial and error basis and by 'borrowing' technology from related kiln processes, supplemented by proprietary modeling to various levels of sophistication. This paper presents a conceptual review of modeling components for the development of a computational model for granular material flow, combustion and heat and mass transfer in a nickel laterite kiln. These components include: granular material flow and segregation models for the simulation of bed motion, heat transfer models that simulate heat transfer by turbulent diffusion and radiation and the distribution of this thermal energy within the bed, and fluid flow models for the prediction of combustion aerodynamics.

Jan 1, 2005

By J. -F. Lepage, M. A. Tomlinson, K. K. Murray

"The Éléonore mine, located in the James Bay region of Northern Quebec, generates a gold bearing flotation concentrate rich in pyrrhotite. Direct leaching of the finely ground concentrate results in high cyanide consumptions and poor recoveries, so effective pre-treatment to passivate the pyrrhotite is required before leaching. Following a number of process upsets at the mine, test work was performed to better understand the requirements for passivation so a more effective operational strategy could be implemented. This paper outlines the testing and implementation of the new strategy at Éléonore.ÉLÉONORE CONCENTRATOR The Éléonore mine is located 800 km north of Montreal, in the James Bay Region of Quebec, Canada. The ore, containing gold disseminated in sulfide minerals and free fine gold in silicate gangue, is crushed in a two-stage crusher plant before being ground in a single 9,000 kW ball mill. The ball mill is in closed circuit, with about 25% of the cyclone underflow passing through a gravity plant with two, 48” Knelson concentrators. Gold recovery in the gravity circuit varies between 15 and 20%, with gravity concentrate leached daily in an Acacia intensive leach reactor. Cyclone overflow, at a target P80 of 65 microns, flows to the flotation plant where the gold bearing sulfide minerals, mainly pyrrhotite and arsenopyrite, are recovered to concentrate with a mass pull of about 5%. The flotation concentrate, typically containing between 80 and 120 g/t of gold, is thickened and finely ground using a 1500 kW Isa Mill. The finely ground concentrate is diluted, to generate a slurry with about 32% solids by weight, before feeding the leach plant. Initially the concentrate slurry is pre-treated with oxygen and lead nitrate, to passivate the sulphide minerals before cyanide is added for gold dissolution. Gold is recovered from the leached slurry using carbon-in-pulp (CIP). The flotation tailings are also thickened and gold is recovered in a dedicated leach-CIP plant."

Jan 1, 2017

By Tassos Grammatikopoulos, Vladimiros Papangelakis, Douglass Duffy, Cheryl Washer, Srinath Garg

Flotation operations in Sudbury, Ontario, seeking to separate pentlandite and chalcopyrite from mixed sulphide deposits, produce pyrrhotite tailings that have been disposed of in tailings ponds for over 50 years. These reactive tailings are viewed as waste, despite containing ~0.8 wt% Ni, and represent an environmental liability because of their acid mine drainage (AMD) potential. Given the large quantities of pyrrhotite currently stored in Sudbury, and declining ore grades elsewhere, these tailings have shifted from being viewed as a waste to a potential resource. Recent advances in the bioleaching of low-grade sulphide ores have raised the prospect of bioleaching as a potential low-cost processing option. However optimization of this proposed process requires a thorough understanding of the mineralogy of the pyrrhotite tailings that would be leached. The work presented here addresses the characterization of two distinct Sudbury pyrrhotite tailings, namely from the Vale and Glencore operations, using electron microprobe, XRD and QEMSCAN analysis. Particular focus is given to how the mineralogy may affect bioleaching as a processing option, through the deportment of nickel and the various phases present

Jan 1, 2015

By George P. Demopoulos, Yan Zeng, Zhibao Li

Precipitated silica is marketed with a rising demand as reinforcing filler in the rubber industry and as a potential raw material for the synthesis of lithium-ion battery electrodes. Due to an awareness of the environmental impact of the existing processes for the production of precipitated silica, a green and sustainable process was proposed by using sodium bicarbonate (NaHCO3) as an alternative to sulfuric or hydrochloric acid in the precipitation reaction with sodium silicates. The use of NaHCO3 allows for better control of the supersaturation and pH to form silica with desired quality. Additionally, Na2CO3 solution as the process by-product is recyclable because it could be recovered to produce NaHCO3 by absorbing CO2. The solubility of sodium metasilicate nonahydrate (Na2SiO3·9H2O) in the Na-CO3-HCO3-OH-H2O system was measured using a dynamic method in the temperature range from 288.15 to 308.15 K. It is found that the solubility of Na2SiO3·9H2O decreases with increasing concentration of either Na2CO3 or NaOH over the investigated concentration range. With the aid of the OLI platform, a chemical model for the Na2SiO3-Na-CO3-HCO3-OH system was established with newly obtained interaction parameters of the Bromley-Zemaitis model by regression of experimental solubility data. The new model predicted the solubility of Na2SiO3·9H2O in multi-component systems with good agreement and was used to conduct a preliminary feasibility study of the new process.

Jan 1, 2015

By E. Uzun

"In this study, H2SO4 and HCl leaching behaviour of an ore sample containing 1.87% of Ni, obtained from the Karaçam (Eskisehir-Turkey) lateritic deposit that started operation recently was investigated. Acid concentration, temperature and reaction time were investigated as variables by comparative leaching tests and the optimum leaching conditions were selected on teh basis of Ni, Fe, Co and Mg behaviour. For H2SO4 leaching, optimum leach parameters were 95°C, a 12 normal H2SO4 concentration and 90 minutes of reaction time, and under these conditions Ni and Fe dissolutions were 97.6% and 95.4% respectively. On the other hand, 70°C, an 8 normal HCl concentration and a reaction time of 90 minutes were found to be the optimum parameters for HCl leaching, and Ni and Fe dissolutions found were 97.1% and 97.8%, respectively.INTRODUCTION Today, nickel and various nickel compounds are obtained from sulphide and lateritic nickel ores (Moskalyk & Alfantazi, 2002). Even though about 72% of the world's nickel reserves constitute lateritic ores, only about 42% of nickel is produced from these ores. The decrease in production from sulphide deposits, on the other hand, and increases in the use of nickel in the iron and steel, and battery production sectors, and especially the production of nickel cast irons in recent years, have accelerated the importance of making use of lateritic deposits (Luo et. al., 2010; Chang et. al., 2010). In the beneficiation of sulphide nickel ores, mostly pyrometallurgical methods are used. On the other hand, about 39% of lateritic ores are beneficiated by pyrometallurgical, and 61% are beneficiated by hydrometallurgical methods (USGS, 2009). In laterite beneficiation, the ore properties are of significance; that is to say, limonitic ores are eneficiated by high pressure acid leaching or via the Caron process, nontronitic ores are beneficiated by high pressure acid leaching or heat treatment (smelting), and ores containing serpentine by pyrometallurgical methods (Berezowsky, 2004; McDonald & Whittington, 2008a; Dreisinger et. al., 2015)."

Jan 1, 2017

By M. Nusheh, C. Bumby, A-H. Puichaud

"Vanadium-bearing titanomagnetite ironsand deposits occur along a 480 km stretch of the west coast of New Zealand. In the present study, the leaching behaviour of NZ ironsand was investigated in hydrochloric acid (2–10 M) solution at 50–80°C for 2 h. The resulting leaching liquors exhibited Fe/V ratios in the range 150–180. The distribution of trace element contaminants between solution and solid residue was investigated, and processing conditions have been determined for rapid and efficient dissolution of Fe, Ti and V into the leaching solution. In addition, mineralogical analysis of raw ironsand and leached residues was performed in order to study the leaching mechanism. Samples were characterized by scanning electron microscopy, energy dispersive X-ray spectroscopy (EDX), X-ray fluorescence spectroscopy, qualitative and quantitative X-ray diffraction and inductively coupled plasma mass spectrometry (ICP). Results indicate that the dominant dissolution process follows shrinking particle mechanism. However, ironsand particles containing ex-solution lamellae exhibited a different leaching behaviour compared to homogenous titanomagnetite particles.INTRODUCTION Titanomagnetite ironsand (blacksand) forms Quaternary onshore beach and dune deposits and offshore marine deposits (Figure 1) along 480 km of coastline from Kaipara Harbour south to Wanganui on the west coast of the North Island (Christie, 2016). It attracted the attention of scientists from the earliest times (Galbreath, 1998). The principal minerals in ironsand are titanomagnetite (TTM), ilmenite, quartz and ferromagnesian minerals such as augite, hornblende, diopside, and olivine with smaller amounts of rutile and apatite (Mauk, 2016).Several large ironsand deposits have been discovered and exploited since the late 1960’s. The Waikato North Head and Taharoa mines are currently operating and they have a 2015 measured resource of 400 million tonnes in total and provide over 2 million tonnes of concentrate per year by simple cost effective magnetic separation process (Christie, 2016; Christie & Brathwaite, 1997). The concentrate contains not only 7–8% TiO2 and 56–60% SFe, but also 0.3–0.6% V2O5, is both a valuable titanium mineral and a source of vanadium. All the production is used for steelmaking industries. The other potential for utilizing more of this resource without requirement of integration into an iron and steel producing plant is to develop a hydrometallurgical route with advantages of higher efficiency along with lower emissions. Currently, there is no existing commercial process capable of extracting all three of these elements as industrial-grade commodity products. Acid leaching of TTM concentrate with higher degrees of recovery and selectivity is a key step in any possible hydrometallurgical route."

Jan 1, 2017

By Taisuke Sakakibara, Shinya Suzuki, Tatsuya Kato, Chiharu Tokoro, Kenichi Muto

Surface complexation using a diffuse layer model were constructed for arsenic (As(V)), zinc (Zn(II)) and silicate (Si(IV)) for aluminum hydroxide in the co-precipitation process. From experimental investigations using isotherms, zeta potential measurement and XRD analysis, it was confirmed that co-precipitation involved not only surface complexation but also surface precipitation. However, surface complexation was major mechanism for As(V), Zn(II) and Si(IV) removal under the target removal level of the Japanese effluent standard. In surface complexation modeling, exchange capacity of aluminum hydroxide was determined from specific surface area obtained from experimental measurement and site density obtained from reference. Surface complexation coefficients were determined by fitting the removal property and sorption isotherm obtained from co-precipitation experiments. These parameters were in agreement with the numerical parameters found by Karamalidis and Dzombak (2010) who reported a database of adsorption equilibrium constants for gibbsite. The surface complexation models constructed in this study were applied to neutralization process of an actual AMD treatment. Our model could successfully represent the pH edges for As(V), Zn(II) and Si(IV) in the neutralization of AMD.

Jan 1, 2015

By G. K. Lee, E. R. Mitchell

Designers of combustion processes may select aerodynamic conditions which produce only superfine fly ash. Although it is not usually anticipated that this will create a problem, such as has been found to agglomerate in high-velocity gas streams, to plug mechanical dust separators in a short time, and to contribute to atmospheric pollution. The problem is a fundamental one, and may be approached in several ways. The authors, in the course of their combustion research program, had occasion to examine the agglomeration of ash, ranging from sub-micron to 17 microns in size, produced in a (coal and oil) dual-fuel-fired steam generator. Several theories, supported by extensive laboratory studies, have provided some understanding of a probable mechanism of agglomeration. As a result, certain precautions are suggested in the design and selection of combustion processes and equipment.

Jan 1, 1962

By L. E. Djingheuzian

IN 1953, Lewis (1) published an article which brought forth a great amount of discussion by grinding engineers. In his contribution to discussion the present writer (2) suggested that, for the most efficient performance of a ball mill, there must be a .definite relationship between Cn, per cent critical speed, and V p, per cent mill volume occupied by the ball charge. Later, he ( 3) was able to publish some grinding data from Wright-Hargreaves milly which appeared to bear out this contention. It is with this view to establishing a fundamental relationship between Cn and Vp that the idea of this Forum was conceived. Accordingly, a questionnaire was prepared and copies of it were mailed to over eighty Canadian mill operators. This questionnaire did not include a question on dilution on the assumption that each mill operator was using the most efficient dilution for his operation, nor was a question on efficiency of classification included since it was thought that the inclusion of efficiency of dassification in the questionnaire at this preliminary stage might render the forum discussion,. while everybody was trying to find his bearings, too unwieldy. However, it is evident that, as discussions develop, this forum will have to define a uniform method for establishing most efficient classification in grinding circuits

Jan 1, 1957

By Geoff Goodyear

UHNL Corporate Profile ? Providing Helicopter Services since 1963 ? A Newfoundland Company head-quartered in Goose Bay, Labrador ? Operations, while primarily Atlantic Canadian, extend across Canada, the Arctic, Greenland ? 16 aircraft, all single engine / VFR Typical Industry Mission Profiles & Work Environments ? Types of missions include: ? Air Taxi & Executive Transport ? Mineral Exploration ? Forest Fire Suppression ? Medivac ? Wildlife Management & Research ? High Angle Rescue and Ice Blasting ? External Load & Long Line ? Mountainous Terrain Operations ? Aerial Application ? Power line Patrols & Construction The Helicopter ? Essentially the same aerodynamic principals as fixed wing but with some mechanical variations on the theme

May 1, 2001

By A. E. Hilder

Introductory The following pages present the results of field investigations, laboratory and commercial tests, drilling, surveying, and preliminary development of the refractory clays which have been discovered recently in the township of Kipling, at the foot of Long rapids on the west side of the Mattagami river about 57 miles north of Kapuskasing and approximately 7 miles north of Smoky Falls, the terminus of the privately owned railway operated by the Spruce Falls Power and Paper Company, Kapuskasing (see Figure 1). Investigations on the clays of northern Ontario have been carried on over a period of seven years by officers of the Ontario Department of Mines, and I am indebted to the information published by that Department in reports by W. S. Dyer and A. R. Crozier, as well as?by Professor R. J. Montgomery, of the Ceramic Department, University of Toronto. It was, in large measure, the data given in the 37th, 38th, and 42nd Annual Reports of the Ontario Department of Mines that led me to make a personal investigation of the Mattagami River clays, with the result that we now have a commercial undertaking that will develop eventually into an industry of considerable importance in supplying the central manufacturing districts of Canada with refractories that heretofore have been largely imported from the United States. An extract from the 42nd Annual Report of the Department, Part III, 1933, page 75, reads as follows: "As for the refractory clay, the deposits are undoubtedly very large, but what is urgently needed is a deposit near the railway under sufficiently shallow overburden for recovery by stripping'. Having previously made an investigation of the clays adjacent to the Temiskaming and Northern Ontario railway, and these clays proving unsuitable, I turned my attention to the outcrops of refractory clays on the Mattagami river, first reported by Keele in 1919. This area offered possibilities within the economically permissible distance from rail transportation.

Jan 1, 1935

By T. H. Etsell, P. Kerr

Over the past 50 years, there have been a number of geological, mineralogical and metallurgical studies carried out on the Clear Hills ironstone deposits in northern Alberta, Canada. Due to the low grade and complex mineralogy, previous metallurgical studies have achieved limited success. After rejecting some of the more ‘conventional’ techniques for iron ore beneficiation, the authors chose to investigate the grain enlargement/iron segregation process for the beneficiation of the Clear Hills ironstone. The segregation reactions for iron have not been explored in as much detail as they have for copper and nickel. Iron segregation roasting involves the addition of a carbonaceous reductant and a chloride transport agent to an iron oxide ore, and heating the mixture to an appropriate temperature. The benefit of this process is that it allows ores in which the value minerals are intimately associated with gangue minerals to be processed in circumstances where conventional iron ore processing techniques are not suitable or capable of upgrading the material. As iron is one of the few elements that can be transported through this process, a clean high purity metallic concentrate can be achieved.Through the use of crucible testing followed by Davis tube magnetic separation, scanning electron microscopy, X-ray diffraction and atomic absorption spectroscopy analysis, characterization of the reaction products has been made with an improved understanding of the reaction mechanism.

Jan 1, 2015

By M. Kreuh

Crystalline Mg(OH)Cl and amorphous Mg2(OH)3C1 were successfully isolated from a hydrolyzed molten salt electrolyte sample in this work, It was found that the chemical form and crystallinity of the hydroxylchloride were controlled by the cooling rate of the molten sample when it was taken. Crystalline Mg(OH)Cl could only be obtained by cooling the molten electrolyte sample at a rate not faster than 0.6 °C/min, Upon more rapid cooling, the hydroxylchloride species precipitated as Mg2(OH)3Cl, The behavior of these solid hydroxylchlorides when contacted with fresh and non-hydrolyzed molten electrolyte at 550°C was also examined, It was found that the Mg(OH)Cl rapidly dissolved in the hot electrolyte and did not decompose into MgO at that temperature as would be expected from the literature, The dissolution rate of solid Mg2(OH)3Cl was found to be so slow by comparison that it resulted in the complete decomposition into MgO which thereafter was incorporated into the electrolyte as a suspended solid phase rather than dissolution.

Jan 1, 2004

ABSTRACT Inco’s Iron Ore Recovery Plant was operated by Inco from 1955 to 1980 near Sudbury, Ontario. As exposures to specific nickel substances have been associated with adverse respiratory endpoints it is important to understand processes giving rise to such substances. This manuscript discusses the process and equipment, the propensity for aerosol formation, and operational procedures used by Inco in roasting a pyrrhotite concentrate, reducing the nickel in the formed oxide, leaching the nickel in ammoniacal solution, purifying the resulting solution, making green or black NiO, and producing iron oxide pellets. Industrial hygiene measurements are also reported.

Jan 1, 2013

By Gheorghe Marin, Franco Chiesa, David Levasseur, Bernard Duchesne

Over the past 20 years, pressure die casting has evolved to a point where structural parts can now be produced by this process. This has been made possible by the development of vacuum die casting and by the development of die-castable, low iron content alloys. This resulted in the production of low porosity, weldable die-cast parts on which heat treatment may be applied. In the present paper, the influence porosities on the tensile properties of as-cast A360 tensile test bars was evaluated. This was done by casting 24 clusters, comprising three 6mm diameter test bars each, in a 280T cold chamber pressure die casting machine after a steady dynamic equilibrium had been reached. Modeling of filling allowed to explain the differences in porosity observed in the 3 samples of a same cluster while the results of solidification modeling were related to the microstructure. Tensile samples were radiographed on a real time X-cube apparatus and separated into 2 lots: samples where no porosity defect were visible and samples with visible defects. By measuring the tensile properties of the 2 lots it was possible to quantify the drop in tensile properties brought about by porosity, which is the most common defect observed in pressure die-cast parts.

Jan 1, 2015

By K. C. Corin, Z. G. Song, J. G. Wiese

In the present study the effect of using different grinding media, viz, ceramic balls, forged steel balls, 15% Cr steel balls, stainless steel and mixture of stainless steel and 15% Cr steel balls (50:50) on the flotation performance of a Platinum Group Mineral (PGM) UG2 ore was investigated. Test work was conducted using a laboratory scale horizontal tumbling mill and a batch flotation cell. Power draw to achieve a specific P80 was determined for each media type. Changes in flotation behaviour were evaluated in terms of particle size distribution, water recovery, solid recovery and valuable mineral recovery. pH, Eh and DO levels were also measured. Grinding products of five different media produced similar solids and water recovery, which is indicative of the froth characteristics, but the grades and recoveries of PGE and chromite were different. The product obtained when using ceramic media showed the best flotation performance, producing the highest PGE recovery and the lowest Cr2O3 recovery. The products obtained when using stainless steel balls (SS) produced the lowest PGE recovery and highest Cr2O3 grade and recovery. The paper proposes possible reasons to explain these observations which may have significant importance for the operation of a PGM concentrator.

Jan 1, 2015

By W. P. Campbell

Introduction OWING to the necessity of curtailing the length of this paper, nothing like an exhaustive treatment of the subject will be attempted. Instead, merely a few aspects will be considered, viz., water trouble in wells, sampling of waters, analysis, methods of reporting analysis, and the comparison of a few typical waters. The waters discussed will not be confined to those occurring in areas where oil or gas has already been found, but will include samples from areas in which drilling is being carried on in the hope that oil or gas may be found, i.e., from unproved fields. The Water Problem The problem of dealing with water encountered in oil and gas producing areas has engaged the attention of petroleum engineers from the early days of the industry. Water was not always considered a menace to oil sands; indeed, a certain amount of it was considered beneficial in some areas, but if such exist today they are very exceptional. In some fields, the problem is more acute than in others, and at times has baffled all attempts to solve it satisfactorily. Wells have been brought-in with promise of good production, but after a brief period have 'gone to water'. Whether ?it has always been a case of poor engineering in the form of unsuccessful water shut-off of 'top' or 'bottom' water, or because 'edge' water was present and water and oil were in such close contact it was impossible to remove the one without the other, is hard to say.

Jan 1, 1929

By Louise Corriveau, Bronwyn Azar, Valerie A. Jackson, Luke Ootes, Jeff Harris

We use the results of new bedrock mapping, combined with geochemical point data and airborne radiometric data (in particular equivalent uranium concentrations) to help determine which geological units in the Paleoproterozoic Great Bear magmatic zone (GBmz) contain elevated uranium. The data collectively indicate that the highest primary uranium concentrations are in equigranular granites and subvolcanic/volcanic porphyries. Notably, these rocks host the majority of known uranium-bearing deposits and/or prospects in the GBmz. We speculate that the uranium in these deposits/prospects was derived from nearby, uranium-enriched rocks and was mobilized by much younger, circulating hydrothermal fluids. Sedimentary rocks of the Thelon and Dismal Lakes groups unconformably overlie the GBmz and are known to host unconformity-type and sandstone-hosted uranium prospects. Most likely, the uraniumenriched rocks of the GBmz acted as a uranium donor to these overlying sedimentary basins. The method of investigation employed in this study may be applicable to other ‘granitic’ terrains in order to identify regions with favourable rocks for uranium exploration.

Jan 1, 2013

By Stephen B. Hearn

The SLon Vertical Ring and Pulsating High Gradient Magnetic Separator was developed to overcome multiple disadvantages associated with traditional horizontal type Wet High Intensity Magnetic Separators (WHIMS) which have been in service for many decades for recovering iron ore and other minerals. Proven successful, with hundreds of units now upgrading low-grade iron ores and maximizing recovery of fines throughout China, the technology is now being tested in the Western world. This paper will discuss the drawbacks of traditional WHIMS, explain the operation of the SLon, and illustrate its practical use in processing hematite ores.

May 1, 2007

By Oliver C. Ralston

DURING the development of froth flotation for the treatment of sulphide ores, a certain amount of information was collected about a few of the nonmetallic minerals, and occasionally the gangue minerals in the sulphide ores showed an embarrassing tendency to float. However, for many years efforts were expended to develop reagents that would cause wetting and depression of these minerals. Among the nonmetallics, the minerals sulphur, graphite, and talc probably should be classified as 'natural floaters', and perhaps sericite. They respond to almost any type of flotation reagent, and their beneficiation by flotation had been attempted years ago. Flotation of sulphur is now common practice, and graphite was concentrated during the World War in many mills, most of which have now closed down. A talc mill has just been constructed, and another may soon be erected. Second to the 'natural floaters' come the 'easy floaters', cassiterite, fluorite, barite, mica, colloidal gangue, and paper pulp from white water of paper mills. That these materials responded to some of the early flotation reagents, as oleic acid, has long been known; occasional references to their behaviour are found in the very early flotation literature and in that of today. In general, however, nonmetallic minerals, valued at $2.00 to $15.00 per ton, have for a long time been regarded as cheap products and not worth much beneficiation. Consequently, only high-grade natural deposits suitable for direct mining and sale have been gouged out. Furthermore, the mining of these minerals has too frequently been in the hands of 'super-practical' men-men of no technical or other training, willing to work for a very low compensation. From the social standpoint, nonmetallics has been the field for small, untrained enterprisers with little money to spend on plant or equipment. But times have been changing. The impact of technically trained men on the old industry has revealed appalling losses and inefficien-cies and proved the value of processing materials discarded or avoided by the old regime.

Jan 1, 1937