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Physical/Chemical Treatment of Mercury-Contaminated Wastes from Former Chlorine-Alkali Electrolysis Plants - Application of Flotation Technologies in Soil Washing Plants

Sep 13, 2010

By B Xiao, J Yang, H Chen

"An EXTENDED ABSTRACT is available for download. A full-length paper was not prepared for this presentation. The Tuwu-Yandong Cu deposit, located in the East Tianshan mountains in the eastern section of the Central Asian Orogenic Belt, is the largest and economically most important porphyry Cu deposit in Xinjiang, China. It contains ~3 Mt of copper at an average grade of 0.46 per cent Cu and 0.2 g/t Au, with significant amounts of Mo and Ag. The deposit is mainly hosted in the Carboniferous Qi’eshan Group and plagiogranite porphyry, and is controlled by faults that are east–west-, north-west- and north-east-trending. Ore minerals in the Tuwu-Yandong deposit are dominated by pyrite, chalcopyrite and molybdenite, with minor bornite, chalcocite, magnetite, sphalerite and galena. Gangue minerals are mainly composed of quartz, sericite, chlorite, epidote, anhydrite, gypsum, muscovite, biotite, phosphorite, sphene, dolomite, actinolite, barite, albite and calcite. Based on the megascopic and microscopic textural relationships and mineral assemblages, five stages of hydrothermal alteration and hypogene mineralisation are recognized in the Tuwu-Yandong Cu deposit: the potassic stage, propylitic stage, phyllic stage, late veins stage and supergene stage. Most of the copper was deposited during the phyllic stage, along with less molybdenite.CITATION:Xiao, B, Chen, H, Wang, Y and Yang, J, 2015. Geology, mineralisation and alteration of the Tuwu-Yandong porphyry Cu deposit, north-west China, in Proceedings PACRIM 2015 Congress, pp 641–644 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

Mar 18, 2015

By Daniel L. Ng

This Bureau of Mines report describes the results of scanning electron microscopic (SEM) studies of the combustion residues of carbonaceous dust particles resulting from explosions and thermal ignitions in laboratory and full-scale mine tests. The dusts studied varied widely in rank and volatility: Pittsburgh seam bituminous coal (35% volatility), Pocahontas seam bituminous coal (16% volatility), anthracite (7% volatility), graphite, and diamond. The most systematic explosion studies were performed in an 8-L chamber with narrow size distributions of Pittsburgh coal dust with surface mean diameters of 2, 22, and 84 pm. Experiments were conducted mainly in air, with some data obtained in 50% 02. Observations of the bituminous coal explosion residues showed particles with rounded edges, particles with blowholes, and some cenospheres. The lower volatility dust residues showed fewer changes from the original, unburned dust. In addition to the experimental studies, results of SEM observations of residues from a mine explosion disaster are reported. Comparison of such residues with those from the laboratory and experimental mine explosions can help investigators determine the extent of dust participation in the disaster and in identifying the possible ignition sources.

Jan 1, 1983

By M. C. Bétournay

Hydrogen fuel cells are a known technology, having been applied to stationary (e.g. equipment, buildings, and power plants) and vehicle applications (e.g. transit buses and space shuttles). There is currently a growing need to provide alternate power systems to diesel fuel for underground mining vehicles to improve underground air quality and reduce production costs and greenhouse gas emissions. To date, however, fuel cells have not been exposed to underground mine air and physical conditions. A testing program was carried out to provide information on the vulnerabilities of fuel cells as part of a number of proof-of-concept projects to apply hydrogen power to underground mining vehicles. The fuel cell type of choice for the industry, the proton exchange membrane, would function at the range of surface operations, and use hydrogen that is stored under low pressure and risk. A small fuel cell stack was tested in a cooperative project between CANMET, the Fuelcell Propulsion Institute, Inco, the Ontario Ministry of Labour, Sandia National laboratories, and H-Power. This article will review the tests carried out to measure the effects from high humidity, mineral dust, diesel emission gasses and diesel particulate matter, as well as from shock and vibration provided to the unit in underground conditions at Inco?s 175 Orebody minesite and Stobie mine. The test results provided will show that the unit was not affected by the underground conditions; physically and electrically, the unit performed without any reduction in operation or adverse effects imposed

May 1, 2005

By G. Bonnell, W. Lidkea, M. C. Bétournay, E. Edwardson

"Hydrogen fuel cells are a known technology, having been applied to stationary (e.g equipment, buildings, and power plants) and vehicle applications (e.g transit buses and space shuttles). There is currently a growing need to provide alternate power systems to diesel fuel for underground mining vehicles to improve underground air quality and reduce production costs and greenhouse gas emissions.To date, however, fuel cells have not been exposed to underground mine air and physical conditions. A testing program was carried out to provide information on the vulnerabilities of fuel cells as part of a number of proof-of-concept projects to apply hydrogen power to underground mining vehicles. The fuel cell type of choice for the industry, the proton exchange membrane, would function at the range of temperatures encountered in underground and surface operations, and use hydrogen that is stored under low pressure and risk.A small fuel cell stack was tested in a cooperative project between CANMET, the Fuelcell Propulsion Institute, Inco, the Ontario Ministry of Labour, Sandia National laboratories, and H-Power. This article will review the tests carried out to measure the effects from high humidity, mineral dust, diesel emission gasses and diesel particulate matter, as well as from shock and vibration provided to the unit in underground conditions at Inco’s 175 Orebody minesite and Stobie mine. The test results provided will show that the unit was not affected by the underground conditions; physically and electrically, the unit performed without any reduction in operation or adverse effects imposed."

Jan 1, 2005

By D. A. Reynolds

A few studies on the relationship of the fusion temperature of the ash on coke to that of the corresponding coal have been made on commercial high-temperature cokes. H. J. Rose3/ in 1921 compared the fusion temperatures of the ashes of 10 coals and the cokes produced from them and concluded that they were in such hose agreement that either figure could be used. More recently, Quarfort4/ found that the ash of coke fused at a somewhat lower temperature than that of the original coal. As the ash of a coal and that off tie coke produced therefrom have the same origin their chemical composition should be identical, provided that carbonization has not altered the inorganic, or ash-forming, constituents of the coal, and such alteration seems highly improbable. However, it has been shown5/ that coke is liable to contamination by iron during crushing and grinding preparatory to sampling. Pieters6/ found that coke ash was contaminated in this manner up to 0.4 percent. Extraneous iron would lower the ash-fusion temperature because such iron may form ferrous silicate, which is readily fusible.7/ These results provide a basis for the prediction that the ash of coke will fuse at a lower temperature than that of the corresponding coal, especially if the fine grinding of the coke was done by rubbing -surfaces of iron, as in a disk pulverizer or bucking plate.

Jan 1, 1940

A method for the detection and analysis of tin in cassiterite ores is discussed. An empirical relationship was established between the tin content of an ore sample and the percentage absorption that this sample produced in a Mossbauer experiment. The time taken to complete an assay with this method is much less than with any of the methods currently in use. The equipment can be adapted readily for use in the field.

Jan 1, 1969

By David J. Lowell

The gold content of porphyry copper deposits ranges from less than 0.05 g/t to more than I g/t ((0.0017 to 0.035 oz per st) and the average is about 0.05 g/t (0.0017 oz per st) gold. Perhaps the highest grade mineralization found near a porphyry cop¬per deposit is the Ok Tedi Gold Cap ore body whose grade falls in the 2 to 3 g/t (0.07 to 0.1 oz per st) range. It is difficult to define a gold-rich por¬phyry copper deposit. All porphyry copper ore bodies contain some gold, but there seems to be a fairly sharp break in the gold content at about 0.1 g/t (0.003 oz per st) gold. There is also a problem in identifying dis¬seminated gold deposits that may have an indirect relationship to porphyry copper systems. This relationship is clear cut in deposits such as the Ok Tedi Gold Cap, the El Hueso deposit, the Fortitude and West de¬posits at Battle Mountain, NV, and the Sur¬prise deposit at Ely, NV. There are many other bulk disseminated, epithermal-type gold deposits - McCoy, NV, for example - that might be related to a porphyry system but where this relationship is remains very uncertain. In such places as the Goldfields and Tonapah district in Ne¬vada and in the El Indio, Chile district, there may be a vertically stacked ore deposit rela¬tionship between near surface epithermal deposits and disseminated molybdenite and chalcopyrite enargite mineralization at depth that may represent a deep porphyry system. This, however, has not been positively demonstrated. Most of the bulk epithermal gold deposits are probably not related to porphyry copper systems. Exceptions would probably be Ok Tedi, El Indio, El Hueso, Battle Mountain, and Lepanto where vertical or lateral zoning relationships are more apparent. This author believes that porphyry copper systems are related to a relatively unique type of intrusion that is probably distinct from, for example, the McCoy intrusivebody. For that reason, deposits such as McCoy, Chimney Creek, and the like will not be included in the definition of gold-rich por¬phyry copper deposits for this article. The interpretation of the origin of several of the deposits previously mentioned are subject to an unusual amount of contro¬versy. For example, geologists seem to be equally divided about the presence of a porphyry copper deposit below the El Indio deposit. Geologic setting Continental vs. island arc Several geologists have speculated that the gold-rich, moly-poor, porphyries are

Jan 1, 1989

By G. B. Clark

One portion of this project was to test a blast shield and to design some features for a novel tunneling method termed the Automated Drill and Blast System (ADBS). The ADBS tunneling concept was developed for the design of an excavation system of greater efficiency than conventional drill, blast, and muck (DBM) systems by minimizing the down time and approaching the non-cyclic efficiency of continuous tunneling by means of small charge blasting. Small charge blasting uses simultaneously detonated, small light charges (less than 200 grams per hole) in four to eight shallow (24 to 36 in. deep) holes usually in a line. Limitation of the total explosive per blast reduced air blast overpressure, fly rock velocity, vibration, and noise. Thus, shielded equipment can remain at the face and a tunnel shield permits support personnel to work outby the shield at all times. The ADBS equipment will be composed of five components: (1) a chassis, upon which is mounted automated mucking equipment, and a frame which carries (2) the hydraulic drill(s), (3) load/blast system(s), and (4) control cab(s). The blast shield may have its own mounting. Ventilation, horizontal, and vertical alignment controls are incorporated in the system. The blast sheild, which protects personnel outby the advance equipment from air blast overpressure, fly rock, and gases, was tested with full scale small charge blasting. A blast shield was designed, fabricated, and tested under conditions anticipated for a working model. The shield was designed to expand to fit the tunnel shape, to seal itself to the tunnel periphery, and to contain air blast, fly rock, and gaseous explosion products. In addition, the shield, which was lined on the inby side with rubber belting, reduced the blast noise level outby the shield to 113 dBA or less, which is very near permissible levels. The test results show conclusively that the shield concept is viable. Based partially on the shield tests, a blast resistant control cab was designed to be located on the equipment chassis inby the blast shield to protect operators during blasting, and to contain all the controls necessary for system operation and safety. The economics of tunnel driving using the ADBS were compared with those of DBM. Four rock types, which determine advance rate, and four cost categories were examined. The results of this analysis are as follows: 1. ADBS advance rate is faster because equipment remains at the face and operation procedes semi-continuously. 2. ADBS bit and explosive cost (which accounts for 4%o of the total advance cost) is higher than for DBM. 3. ADBS equipment cost, on a per foot basis, is lower than for DBM. 4. Due to a reduced labor force, ADBS labor cost is lower than for DBM. 5. Because of the overbreak reduction due to controlled blasting, ADBS tunnel support cost is lower than for DBM. 6. On a per foot basis, total ADBS advance cost is from 17% to 20% lower than for DBM, depending on tunnel diameter and rock type. The small charge method greatly reduces ground vibration, increases personnel safety by limiting excessive fracture, and decreases tunnel support requirements by reducing overbreak. The overall analysis, tests, and results to date show that the Automated Drill and Blast System may be developed into a viable tunnel excavation method. The method also may be adapted to use in the mining of ore. For some types of mining operations, the cyclic nature of conventional drill and blast methods may not be a disadvantage, either where the drilling and mucking may proceed simultaneously or where the operations are carried out in adjacent working faces. The proposed method would find application where continuous methods of excavation are desirable.

Jan 1, 1979

By W. D. Bensema

Two different techniques were used to make measurements of the absolute value of electromagnetic noise in an operating coal mine, Itmann No. 3 Mine, located near Mullens, West Virginia. The electromagnetic environment created by 250-volt-dc and 550-and 950-volt-ac machinery in two longwall panels was measured and is reported. One technique measures noise over the entire electromagnetic spectrum of interest for brief time periods. It is recorded using broadband analog magnetic tape, and the noise data is later transformed to give spectral plots. The other technique records noise amplitudes at several discrete frequencies for a sufficient amount of time to provide amplitude probability distributions. The specific, measured results are given in a number of spectral plots and amplitude probability distribution plots.

Jan 1, 1974

By Virgil Miller

Bureau of Mines Reports of Investigations 3244, 3245, 3246 and 3264 give data of detailed studies on smelting in the lead blast furnace handling zinciferous charges at Trail, B. C. The present paper gives more on analyses of the gases leaving the top of the charge and on accretions formed on the walls of the blast furnace. New data are presented to show the effect of the temperatures at the tuyere zone on the lead content of the slags made. The greater part of this paper, however, deals with a much debated subject, namely air used in lead blast furnaces. Original data are presented to show the effects on smelting lead 'products when air is supplied to a lead blast furnace under volume versus under pressure control.

Jan 1, 1940

By Virgil Miller

Bureau of Mines Reports of Investigations 3244, 3245, 3246 and 3264 give data of detailed studies on smelting in the lead "blast furnace handling zinciferous charges at Trail, B. C. The present paper gives more on analyses of the gases leaving the top of the charge and on accretions formed on the walls of the blast furnace. New data are presented to show the effect of the temperatures at the tuyere zone on the lead content of the slags made. The greater part of this paper, however, deals with a much debated subject, namely air used in lead blast furnaces. Original data are presented to show the effects on smelting lead 'products when air is supplied to a lead blast furnace under volume versus under pressure control.

Jan 1, 1940

By S. V. Burr

"A 28-year study of cross folds leads to the conclusion that the northwest-southeast folds recognized in many areas of North America are part of a regional pattern. Detailed examination of over 650 geological maps and reports of Ontario indicates that this folding can be traced across the province. Evidence is presented that this fold pattern played an important part in determining the pattern and scale of intrusion, that its recognition in the field can aid in defining stratigraphy, folding and faulting, and that it may have played an important role in channeling hydrothermal or magmatic mineralization. IntroductionThe concept of regional cross folding in Ontario is not new. W.H. Gross (1955) discussed regional cross folds in the Archean of Northwestern Ontario, and A.M. Goodwin (1961) referred to regional cross folds in the Archean of Ontario and Quebec. However, the interpretation in this paper is new.The writer saw a cross fold for the first time, underground, at Little Long Lac Gold Mines in Geraldton, Ontario, in 1951. This recalled the ""transverse folds"" on E.R. Faribault's classical maps of Nova Scotia, published by the Geological Survey around the turn of the century; M.E. Hurst's cross fold(s) at Timmins, Ontario (Figure I); and the cross folds mapped by A.W. Jolliffe in the Yellowknife area of the Northwest Territories. All these mapped cross folds had one thing in common with the fold at Little Long Lac: A northwest-southeast axial trend. Were such cross folds of purely local extent, or might they be indicative of a widespread regional fold pattern? If so, has such folding any significance for mineral exploration or potential?By 1959, based on a study of about 1000 Canadian geological maps and reports, including 291 in Ontario, the writer reached the conclusion that cross folding trending northwest-southeast is so widespread as to constitute a pattern of folding, and that such cross folding should produce changes in plunge along pre-existing greenstone fold belts."

Jan 1, 1980

The following brief paper is intended, to apply to the concentration of the silver-lead ores at Broken Hill, New South Wales, generally, but more particularly to the process as applied to the ores in the Block 10 mine. The attached plans are similar inmany respects to those prepared, recently for the Block 10 company.Most of the information here given is already well known to those members who are conversant with the concentration practices of this field, but it is the writer's object to give just a few of those figures which he found difficult to obtain when first engaging in practical work. At that time no text-books were at hand from which it was possible to get sufficient details for practical working purposes.It is first supposed that the mine has been thoroughly explored and has been found to contain a lbde sufficient in size ·and quality to warrant the erection of a concentrating plant. The points then to determine are:-(1.) The quantity and cost of water available for steam-making and ore-dressing purposes.(2.) The most convenient site for the mill.

Jan 1, 1904

By J. H. Archibald

"IntroductionShot-saws are used for sawing rock throughout the dimension stone industry especially in granite quarry mills. Shot-saws, as currently designed, have an inherent wear problem which leads to slow cutting rates and repetitive blade changes which consumes much time. Because the saw blades are made from steel the abrasive shot used with them is limited to a certain hardness which effects the over-all efficiency of the sawing operation. Suggestions are made toward optimization of blade design and the sawing process. Blade DesignA common steel blade design is shown in Figure I. Note the perforations in the blade. These perforations or holes in the blade serve two or three purposes. The most obvious reason is to allow the abrasive shot a pocket in which to collect at the bottom of the blade, so that it can be distributed from these pockets into the cutting zone underneath the blade. The abrasive is fed to the saw in a slurry and usually comes in from the top. The blade must then cut a kerf wider than itself in order that the abrasive grains have a path leading from the top of the blade, down along its sides, and finally reaching the pockets and cutting zones. This circuitous path followed by the abrasive leads to side wear on the blades and high friction which can lead to blade buckling in severe cases. However, the fluidized path of the abrasives down the sides of the blade serves another purpose which is a positive gain if conditions are properly controlled. The abrasive slurry interacts with the perforations of the blade, the blade itself and the rock. This gap and the perforations in the blade, which are fluid filled, are sites of constant shearing motion. Eddy currents form in these gaps and pockets which tend to stabilize the blade by setting up balanced hydrodynamic forces which otherwise might not form in a non-perforated blade. A stable blade produces a more uniform cut in the rock. The third and final reason for the perforations are to allow the blade to wear in such a fashion that new pockets are always being formed and, consequently, new cutting surfaces between these pockets are also formed."

Jan 1, 1993

By Ferron A. Olson

Natural bornite (Cu5FeS4) leached in ferric chloride or in sulfuric or hydrochloric acid solutions with oxygen showed several differences. In ferric chloride 80 of the copper was leached in two stages. The first (30 copper removal) requiring one minute was controlled by mixed kinetics (liquid ferric ion diffusion and chemical surface reaction). The second was controlled by formation of a surface sulfur layer and then diffusion through the sulfur. With oxygen in sulfuric acid reaction was slow and only the first stage was studied. Copper removal had an induction period. The bornite structure disappeared at 12% copper removal (also found with ferric chloride) and covellite formed on the surface with a species inside the particles having an x-ray structure similar to CuFeS2 but with composition Cu3FeS4 (also with ferric chloride). Copper removal was controlled by iron dissolution. Surface iron vacancies filled with Cu+ to give CuS while interior copper dissolution produced Cu3FeS4. Preliminary results with oxygen and hydrochloric acid showed 80% copper removal and sulfur as end products (similar to ferric chloride).

Jan 1, 1982

By G. B. Amicucci

Golden Sunlight Mines Inc. operates an open-pit gold mine and cyanidation plant about 11km (7 miles) northeast of Whitehall, MT. Golden Sunlight is a subsidiary of Placer Dome US Inc. Mining is accomplished with conventional open pit drilling, blasting and hauling methods. The mining rate is about 102 kt/d (113,000 stpd). Gold occurs as fine-grained disseminations in a pipe-shaped breccia and in immediately adjacent country rock. The ore body is low grade, averaging 2 g/t (0.059 oz per st) of gold. The metallurgical plant uses conventional carbon-in-pulp (CIP) technology. Daily throughput averages 6.5 kt (7000 st). Recoveries are enhanced through a sand tailing retreatment facility while a preaeration process reduces operating costs. The low grade ore dictates that maximum mill throughput at the desired grind size be maintained. Therefore, in October 1988, an Armco Autometrics (now Denver Autometrics) particle size monitor (PSM) 400 was commissioned. The PSM 400 is an on-line instrument. It measures particle size and percent solids in a slurry stream. The PSM pulls its own sample, deareates the sample and passes it through diametrically opposed ultrasonic sensors. The unit uses ultrasonic sound to measure the deareated slurry stream's particle size and percent solids.

Jan 1, 1991

The Northland region of New Zealand has a complex geological history which has long been the subject of considerable controversy. Small mineral deposits have been discovered in the past, and some have been mined. Except for aggregates and very high quality china clay, mining is virtually nonexistent at present. Mercury mining is proposed from small deposits in the Kaeo area. Intensive exploration for epithermal precious metals deposits in the past seven years, combined with some recent geological mapping undertaken by the Geological Survey and University thesis students has added greatly to an understanding of Northland's geology. Mapping of the Whangaroa-Kaikohe map sheet at a scale of 1:100 000 by Brown and Laurenson Limited has enabled new geological information to be collated for the first time since 1961, when the last geological map was published. The 'Northland Allochthon' is now observed to be a series of four or more thrust sheets each containing predictable formations. High angle faulting contemporaneous with overthrusting has modified the thrust sheets, and established a series of horsts and grabens. The Pirau Fault is considered to be a major earth fracture.

Jan 1, 1987

By F. Hassan, M. A. Arafa

At El-Gedida iron ore deposits there is a block of about 30million tons neglected due to its higher sulfur content due to the presence of barite gangue minerals. From this bluk by magnetic separation dual concentrates of high grade iron concentrate (~65%Fe and total Sulfur of 0.26%) and the second concentrate is barite of (60.87% BaO and total impurities of less than 3%).

Jan 1, 1999

By Bengt H. Fellenius

THIS PAPER deals with the analysis of results from axial testing of vertical single piles, i.e. the most common field test per-formed. Despite the numerous tests which have been carried out and the many Papers which have reported on such tests and the analysis thereof, the understanding of pile test loading in current engineering practice leaves much to be de-sired. The reason for this is that the engineers have concerned themselves with mainly only one question: "Does the pile have a certain least capacity?", finding little of practical value in analysing the actual capacity and the pile-soil interaction. This Paper aims to show that engineering value can be gained from elaborating on a pile test ? during the actual testing in the Held, as well as in the analysis of the results. The first portion of the notes make use of an earlier Paper by the author (Fellenius. 1975). However, additional views and recent literature have been incorporated.

Jan 1, 1988