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By Denise Crocce Romano Espinosa

The recycling of waste of electric and electronic equipment (WEEE) is one of the main modern challenges. Among the variety of WEEE, batteries can be set apart due to their composition and their growing demand along with portable devices. The objective of this work is to characterize the thermal behavior of a sample of mixed types of batteries using a thermobalance (TGA). The results of tests showed that Cd evaporated up to 800ºC, Zn evaporation occurred mainly above 900ºC and manganese oxides were pre-reduced to MnO at temperatures above 900ºC.

Jan 1, 2009

By Hani Henein

Recent innovations in atomization of molten metals have occurred in the area of single fluid atomization. Impulse Atomization (IA), one of the single fluid techniques, provides unique capabilities to study different regimes of atomization in a controlled environment. By changing processing variables, a mono-dispersed distribution of droplets above one millimeter in diameter can be produced. This is accomplished through proper characterization of the forces influencing the process and in particular the flow of melt through the orifice. This paper will discuss the approach and illustrate results with molten aluminum and cobalt.

Jan 1, 2006

By Lijuan Chen

During the detoxification of chromium-containing slag by Achromobacter sp. CH-1, anionic surfactant Sodium Dodecyl Sulphate(SDS) and its mixed systems with different Tween surfactants(Tween 20, Tween 60 and Tween 80) were used to promote the interaction between the bacteria and the chromiumcontaining slag and the rate of acid-soluble Cr( ? ) leached from the slag. The effects were evaluated by the surface tension, the pH of the leaching solution and the leaching rate of total Cr( ? ) from the slag. The results showed that the surfactants systems improved Cr(VI) leaching and its detoxification of chromium-containing slag. The mixed surfactants of SDS combined with Tween surfactant revealed better effectiveness of detoxification than SDS only. When the mass ratio of SDS to Tween 80 was 1:1, the rate of Cr( ? ) leached from the slag increased by 12%.

Jan 1, 2009

By Jacques J. Eksteen

Any effort to improve the metallurgical control of industrial furnaces employed in the primary extraction of high carbon ferroalloys are bound to fail unless the variability of the melt is not fully accounted for. A number of sampling campaigns were performed on both 3phase AC submerged arc and single phase DC open arc furnaces at different smelter sites in South Africa where High Carbon Ferrochrome is produced. It was found that the heterogeneity between multiple samples during a single taps were much higher that for heterogeneity found within a sample. Moreover, this heterogeneity (as quantified by the relative standard deviation per tap) varied with the operating conditions of the furnace, the element monitored and the type of furnace. A relationship was found between the relative standard deviation of certain elements and the degree of subcooling of the melt.

Jan 1, 2006

By Burcu Ertug, Necip Ünlü

"On average, one out of two glass bottles coming on to the market is provided by recycling processes in Europe. Glass recycling has been started by the early of 1970s in Turkey, and the recycling amount has been reached to 70 thousand tons recently, while 4.2 million tons which represents only 25 percent of total glass manufactured, is the amount of glass collected annually for recycling in the world. The glass recycle process basically involves collecting, sorting, then crushing and grinding after which glass cullet is produced as the secondary raw material. Removing of the contaminants from the glass cullet, and then melting are the next steps. In this study, recent developments of 100% recyclable without any deterioration in quality, and never decomposable glass, are discussed detailed in terms of glass production processes.1.IntroductionIn many countries, waste glass constitutes a large proportion of solid wastes, and recycling the glass is a major environmental problem all over the world [1]. Among the diverse types of waste, glass is one of the most valuable recycling materials because it can be revived and recycled completely and hardly decomposes [2]. Between 80% and 85% of the mass output from the worldwide glass industry is either in the form of containers for the food, beverage, and pharmaceutical industries, or flat glass for building construction or for motor vehicle manufacture. Other product segments, whilst only constituting about 15% of the mass output, produce high value technical and consumer products by comparison with container and flat glass [3].In the present study, the recycling of Liquid Crystal Display (LCD), Cathode Ray Tubes (CRT) and Printed Circuit Boards (PCB) were examined. The production of glasses and glass-ceramics from glass cullet, synthesis of different compounds from recycled glass were other subjects of interest. The use of recycled glass for construction industry and using glass as aggregate were emphasized. Finally the recovery of glass fibers were investigated."

Jan 1, 2012

By P. J. Mackey, J. B. See, D. G. C. Robertson

The production of iron and steel and non-ferrous metals by pyrometallurgical processes will remain a critical element in meeting the demand for materials in both developed and developing nations. Given the important need to reduce and minimise greenhouse gas emissions the technological focus of future pyrometallurgical R&D by universities and industry alike must concentrate on sustainability issues such as improved energy efficiency, recycling and waste minimization. Continued efforts are also needed on process optimization and new process development with a view to reducing capital and operating costs of the new large “mega” plants. Using the academic and industrial backgrounds of the authors, the present paper reviews the current status of R&D in pyrometallurgy in university departments with a particular emphasis on sustainability issues. The role of industry and government laboratories is also reviewed although primarily for developed countries. The paper also includes comments and suggestions on the future requirements for education and R&D in pyrometallurgy in developed countries to maximise sustainability. It is also suggested that future R&D in pyrometallurgy will be even more concentrated in developing countries – most notably China.

Jan 1, 2014

By Thomas Prietl

The use of gas stirring systems through the furnace bottom is common for anode and holding furnaces in the copper industry The first implementation of a gas stirring COP KIN® system in a Peirce-Smith converter was performed at the New Boliden smelter, Rönnskar, Sweden. In addition to other benefits, a decrease in process time and a decrease of the oxygen content in the blister copper were observed. To determine the effects of the gas stirring system and the process endpoint, an optical production control ?Semtech OPC system? was used. The light emission of the converter flame as an optical process parameter provides qualitative on-line process information, and is also used for endpoint determination of the slag making process, on-line control of iron content in white metal, quality control of slag etc. The results, benefits and risks of using the COP KIN® and OPC system for a Peirce-Smith converter are reported.

Jan 1, 2005

By F. Kavicka

An original application of ANSYS simulated the forming of the temperature field of a massive casting from ductile cast-iron during the application various methods of its cooling using chills. The numerical model managed to optimize more than one method of cooling but, in addition to that, provided serious results for the successive model of structural and chemical heterogeneity, and so it also contributes to influencing the pouring structure. The file containing the acquired results from both models brings new and, simultaneously, remarkable findings of causal relationships between the structural and chemical heterogeneity and the local solidification time in any point of the casting. The determined relations therefore enable the prediction of the face density of the spheroids of graphite in dependence on the local solidification time. The calculated temperature field of 500x500x1000 mm casting of ductile cast-iron with various methods of cooling has successfully been compared with temperatures obtained experimentally. Acknowledgments. This analysis was conducted using a program devised within the framework of the GA CR projects (No.106/04/1334, No. 106/04/1006 and No. 106/04/094), of the COSTAPOMAT-OC526.10, MPO/FI-IM/021, EUREKA No.2716 COOP and KONTAKT 14/ 2005/06.

Jan 1, 2006

By M. Hochenhofer

Due to economic aspects and environmental regulations recycling of slag and waste from ferroalloy production became a very important issue for the companies during the last years. The treatment of slag depends prior on the composition, especially on their content of valuable metals and impurities. The final aim should be a total re-use of these materials in the industry e.g. cement industry, pig-iron production etc.. Therefore, to reach the required physical and chemical properties for a further use, possibilities of a metallurgical treatment have been investigated. The conditioning of slag with a high V-, Mo- and P-content via reducing metal bath showed to be one alternative. To determine the optimal process parameters, practical investigations with different slag compositions and thermodynamic calculations were carried out.

Jan 1, 2006

By Tiebao Yang

In high pressure die casting processes, a die plays a critical role in removing heat from the molten metal during the cavity filling and solidification stages. Proper control of die temperature is essential for producing superior quality components and yielding high production rates. This paper proposes a local temperature control scheme for die thermal management based on a computerized intelligent real-time monitoring and control system (IRMCS). In this scheme, cooling water lines are controlled by a pump and solenoid valves. A controller is designed according to the law of die temperature fluctuations. The results obtained from the experiments carried out on a laboratory die casting process simulator indicate that the controller can limit the local die insert temperatures in a given band. Hence, the desired thermal pattern of the die insert becomes achievable.

Jan 1, 2006

By Sutham Niyomwas

Keywords: Al2O3-SiCW, Ceramic Matrix Composite, Carbothermal Reduction, Kaolin The formations of Al2O3-SiCw composite have been obtained in situ by carbothermal reduction of a mixture of kaolin and activated carbon. The reaction temperature was controlled at between 1400°C to 1600°C. The synthesized products were mixtures of alumina and silicon carbide in the form of whiskers. The effects of milling time of precursors and reaction temperature are presented. XRD and SEM analyses indicate complete reaction of precursors to yield Al2O3-SiC as product powders, with the SiC having porous and whisker morphology.

Jan 1, 2005

By Dongok Kim

Regardless of the advantages of the Friction Stir Process (FSP), for age-hardened aluminum alloys, the mechanical properties such as hardness in the stir zone decreased after FSP due to the growth or dissolution of strengthening precipitates. Here, as a new technique, FSP was introduced to alloy copper nanopowders in Al7075 T651. Mechanical properties of copper nanopowder- alloyed Al7075 T651 together with micro and nanostructures were compared with those of as-FSPed Al7075 T651 using SEM, TEM, and Vickers hardness testing to understand structure-property relationships. It was observed that Vickers hardness of the stir zone in copper nanopowder alloyed Al7075 T651 increased by 20% compared to that of the heat affected zone, while the as-FSPed samples did not show a noticeable increase in hardness in the same zone. Xray mapping showed traces of copper nanopowder after the process. TEM is being used to verify if there was CuAl2 formed in the copper alloyed sample.

Jan 1, 2006

By Emma Arakelova

?2?2 (98 %) vapour passed through a reactor at 25Pa where a Zn? target was placed at 273K- 373?. Experiments were carried out on a flow- type vacuum device. ?2?2 decomposition on Zn? surface accompanied by formation of a Zn-containing volatile complex which transferred to the gas phase, and Zn? deposited on a substrate at condensation. As the substrate, five sequentially located quartz cylinders were used at 293K- 423 K (?n). Decomposition of the Zn-containing complex on quartz substrates carried out as a first- order reaction. ?The complex decomposition constant (??) increased with the substrate temperature (?n=293 K, ??=7.05 sec-1;?n = 373 K, ?? = 87 sec-1;?n = 423 K, ?? =158 sec-1). ?The complex decomposition constant did not practically vary when the target temperature increased; the complex formation rate increased slightly.

Jan 1, 2006

By Han Yi

The coarse indium ingots produced by Shaoguan smelter contained a lot of impurities. In order to produce the high pure indium with the purity more than 99.99%, the appropriate refining processes were designed and the practice of combined application of Glycerin-KI process and electrolysis in Shaoguan smelter was introduced.

Jan 1, 2005

The purpose of this study was to investigate the immobilization as a host for metallic pollutants (Cr, Cu, Pb, and Zn) by ettringite phase. Ettringite phase is produced through hydration reaction of calcium aluminate with gypsum. From the XRD patterns, it is known that the distance between spaces in 010 planes in ettringite crystal increase with an increase of ionic radius of heavy metal except Pb; no big difference is shown. For this reason, the d-value of 010 planes in ettringite crystal increased with the substitution of Cr, Cu and Zn having a big Al ironic radius. But in case of Pb, because the substitution occurred at calcium site, it does not influence to increase d-value of 010 planes.

Jan 1, 2006

By Fanke Meng

Electrolyzing oxides of titanium, aluminum and niobium could prepare high-Nb bearing TiAl alloy (Ti-45Al-9Nb) at 1500°C. The chosen electrolysis voltage is 3.5V, which is lower than reducing voltage (~4.7V) of electrolyte CaF2, but higher than that of titanium, aluminum and niobium oxides. The investigation shows that compared with traditional methods, this method for preparing high-Nb bearing TiAl alloy is of many advantages such as few steps, friendly environment, low energy consumption, low cost and high current efficiency.

Jan 1, 2009

By Alex Del Castillo

The mineral processing industry has followed the development of database control systems, and various systems have been installed in existing and new plants. The goal is to improve product quality, raise productivity and lower production costs. Improvements in different units for mineral .processing .have been applied. This has led to increasing information for the operators. To support the operators and for an easy overview of the process, a complete concept for an integrated process-control system is required. This paper describes the plant-wide [process control system for the Collahuasi copper project located in northern Chile. The total investment for the project was $1,700,000,000 and included a port area and two copper processing plants, an oxide plant with a cathode production of 50 tons per year and a sulfide plant with a concentrate production of 330 kilotons per year. The main characteristics of the plant-wide process control system include a 200- kilometer long redundant control network and a 24-kilometer long redundant serial network providing coverage for the entire plant. The plants are located around 4,700 meters above sea level, serial communication lids allow the integration of over 2,700 SCADA data units, and the system handles over 7,500 physical signals plus the SCADA data integration. The main equipment consists of 39 different sized controllers, 16 operator stations, 5 engineering stations, 2 information management systems and 4 X- terminals. The project management, control configuration, factory acceptance test, system integration test, training, commissioning and start-up were carried out in close cooperation with the customer. The result was completely satisfactory for the customer.

Jan 1, 1999

By Frank R. Field, Randolph E. Kirchain, Elisa Alonso

"There are a number of environmental incentives for increasing recycling, including the reduction of waste, energy and resource use. Recycling can also be advantageous for manufacturing firms in both the short and long term. Secondary material can substitute for primary material, potentially dampening primary material price increases and reducing the pressure for greater primary extraction. This paper examines the potential for and dynamics of recycling for the case of platinum using a dynamic, behavioral simulation model of the primary and secondary markets. Since the secondary supply of platinum depends on a supply chain separate from primary extraction, recycling can diversify the risks of primary supply instabilities. Over time, recycling can cut primary consumption, reduce overall costs to firms, and possibly reduce the impact of price fluctuations upon firms.IntroductionThe benefits of recycling, from the perspective of the environment, are many, and the environmental benefits of increased recycling are considered a step towards increased sustainability [1, 2]. Life cycle assessments indicate that obtaining materials from secondary sources generally requires less energy and has fewer environmental impacts than extraction and refining of primary materials [3]. Analyses of materials flows show that, in addition to landfill volume reduction, recycling reduces primary material consumption, affecting long term materials scarcity [4, 5].The benefits of recycling are not limited to the environmental. Firms can benefit from the lower energy costs of recycling, especially that of metals whose primary extraction and refining are particularly energy-intensive (e.g., aluminum). The routine participation by firms in secondary materials markets (e.g., www.recycle.net) shows that this advantage has not gone unnoticed.Recycling can also benefit firms whose costs can be significantly affected by changes in material prices resulting from material shortages and material scarcity, with potentially permanent effects upon firms [6-8]. This paper focuses on the impact of recycling in the face of platinum scarcity for supply chain downstream firms."

Jan 1, 2008

By Sergio N. Monteiro

Jute fiber reinforced polymer composites are among the most investigated and applied natural composites. In this past decade the mechanical properties of these composites has been assessed for various types of test conditions. However, the reported results correspond mainly to short-cut jute fiber composites, which do not present the highest mechanical strength as compared to continuous fibers of the same kind. In order to complement these results, the present work evaluated the mechanical behavior, by means of flexural tests, of polyester matrix composites reinforced with continuous jute fibers. Bend tests were conducted in standard specimens with up to 40% of jute. Fracture analysis by SEM displayed the rupture mechanisms. The results showed an improvement in some flexural properties with incorporation of jute fiber. However, a low fiber/matrix interfacial stress was responsible for limitation in the values attained by some properties.

Jan 1, 2010

By Toshiyuki Kawai

Copper concentrate smelting directly in P-S converters was started at Onahama Smelter in 1983. Thereafter, the tonnage of concentrate smelted through the P-S converters increased, such that by 2002, it equaled the tonnage smelted through the reverberatory furnaces. In 2003, 56% of the total copper concentrates treated at Onahama Smelter were processed directly through the P-S converters. Technical improvements are reviewed and advantages of direct smelting in P-S converters are reported.

Jan 1, 2005