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By S. Potgieter-Vermaak, T. T. Chiweshe, W. Purcell

The advantage of using ammonium phosphate salt as flux is the selective precipitation of chromium(III) compounds, which are considered nontoxic and environmentally friendly. The technique in this paper is determined to have potential to be applied in the metallurgical industry, where it can be used in the beneficiation of chromite mineral ores. The higher chromium contents of chromite ores often require furnaces to run at higher temperatures of above 1,300 °C, which can cause shutdown of the ore processing plant and accumulation of the sticky chrome compounds — including toxic chromium(VI) waste — which are generated as byproducts. The other advantage of this technique is its low to moderate energy consumption compared to existing techniques.

By Peter N. Yanker

The two types of dryers used in the drying of copper concentrates are the rotary dryer and the spray dryer. The rotary dryer has until recent history been the traditional drying method used, Although spray dryers have been used in the chemical field for many years it is only recently that they have been accepted for drying of copper concentrates. The comparison made here will apply in a narrower sense to the drying of copper concentrates as fed into the reverbatory furnaces of the Smelter. To compare a rotary dryer and a spray dryer, which are two totally different methods and pieces of equipment, it is best to view them as systems each made up of certain elements

Jan 1, 1976

By Joel L. Morrison

The preparation of coal-water slurry fuel (CWSF) has the potential to be a commercially viable technology for the coal industry. The technology base required to prepare stable CWSF using grinding circuits has been developed over the past decade and is now being applied to the preparation of CWSF from wet coal fines which are generated during coal beneficiation. When preparing CWSF, the optimum CWSF formulation must be determined to ensure that the fuel will be stable while having acceptable atomization and combustion properties, and the production run must be monitored closely to ensure that the CWSF quality is maintained. This paper describes the CWSF formulation process, CWSF preparation circuits, and some of typical problems encountered in, and solutions to, the transportation and storage of CWSF.

Jan 1, 1993

By J. Kennedy

Rare Earths: Understanding The United States complete failure of status and relevance in Rare Earth Oxides, Elements and Alloys. Although rare earth oxides are strategic and critical in their own right, elements and alloys are even more important for the development of "Green Technologies" and advanced weapons systems. America does not have an active domestic source of rare earth oxides. America does not have any Heavy Rare Earth Elemental or Alloy capabilities. The magnitude of this failure continues to become more apparent as the manufacture of REO based electronics and magnetic components moves eastward towards China. China has succeeded in outmaneuvering The United States and the world in its quest to control the Rare Earth Oxides, Elements and Alloys, and the many industries dependent upon REO. What can be done?

Jan 1, 2010

By R. Bishop, J. Baggett, J. Monsalve, J. Hole, N. Ripepi, A. Abassi

This work focuses on the operational and safety issues associated with karst voids in large opening underground mines. Issues include water inrush, structural instability, and engineering uncertainty in these environments. Coupled with the fracturing prevalent in folded sedimentary rocks, karsts are complex and challenging ground control risks. Traditional methods of predicting karst locations, such as probe drilling, are impeded by the inconsistent spatial distribution and variable sizes of the features. Ground penetrating radar (GPR) is a geophysical technique that transmits radio waves into a medium and subsequently detects reflected waves via a receiver. The travel time and energy of received signals are then processed and interpreted. The difference in material properties between limestone and open karsts causes strong reflections. GPR is frequently used as a geophysical surveying technique in several industries, however there is a lack of published research on underground mining GPR applications. The purpose of this work is to prove the viability of GPR in underground stone mines for karst detection, and to discuss the importance of karst detection ahead of mining. INTRODUCTION The Mine Safety and Health Administration (MSHA) currently lists 116 active underground stone mines in the United States, the vast majority of which extract limestone for crushed stone products. These limestone mines have the potential to encounter karst voids at some point in their operation, as most karstic regions of the United States develop in limestone rock masses (Kuniansky, Weary, & Kaufmann, 2016). Karsts, the cavities formed by the dissolution of carbonate rock, have long plagued the mining and tunneling industries, as well as been a hindrance on the Earth’s surface, producing sinkholes and ruining otherwise valuable land for construction and public use. The impact of karsts on the Gavarres tunnel in Spain is well documented by Alija et al; constant instability conditions, material spills into the tunnel, and unexpected cavities seriously delayed the project deadlines and “were not foreseen in the design” (Alija, Torrijo, & Qunita-Ferreira, 2013). At the water supply project in Sohngua River, China, Bin et al detail the presence of both water and sediment filled karsts which are sources of disastrous conditions at this tunnel (Bin, et al., 2017). A hydrological tunnel in Lebanon encountered numerous massive karsts in the tunneling path which required remediation via friction anchors, rockbolts, welded wire fabric, channel steel arch segments, invert steel beams, and shotcrete (Leech, Jaoude, & Ghanem, 2008). From a design standpoint, rock mass classification schemes, such as the RMR from Bieniawski and the Q-system from Barton, are not able to represent the true nature of a karstified carbonate rock mass, and therefore complex case-by-case analyses of underground conditions are necessary (Andriani & Parise, 2017).

Jan 1, 2019

By Robert R. Unterberger

The purpose of this paper is to summarize the research of the past sixteen years on three distinct methods of probing into solid rock. The first method is to use radar of the appropriate frequency. The second method is to use sonar. The third method is of recent vintage and uses techniques of nonlinear sonar also known as parametric sonar. The first two concepts, that of radar and sonar, are common to most people. Very few have heard of nonlinear sonar. Each of the probing techniques were investigated in order to overcome deficiencies in the former technique. Each has its advantages and disadvantages. It should be emphasized that all of these techniques for probing (or seeing) into rock are used in mines, and generally speaking not from the surface. Only in very special cases, such as certain very dry parts of Egypt or Peru, or, for example, the surface of the moon, will these probing techniques work from the surface. The reason for the development of these probing techniques has been to alert miners to possible hazards ahead of mining. Such hazards may be (1) old (unknown) boreholes connected with high pressure water zones above, (2) fractures that might connect to the Gulf of Mexico above the mine, (3) water-filled fractures that threaten the safety of miners, or (4) the discovery of dry faults ahead that can disrupt the planning of future operations.

Jan 1, 1983

By J. Marsden

Lift height, overall heap height and climate all play an important role in determining precious metals leaching rates, recoveries, operating costs and capital cost requirements for heap leaching operations. The effects of these factors are not easy to predict from testwork, and this can result in unexpected delays in metal production, lower recoveries than expected and higher capital and operating costs than necessary. This paper investigates the economic impact of lift height, overall heap height and climate on heap leaching and provides criteria to assist in the design and operation of leaching facilities. Descriptions of three heap leach operations in the western USA are provided to support the discussions and conclusions.

Jan 1, 1995

By T. BACHMANN, G. SHAPLAND, E. Amini, N. BEATON, M. BECERRA

Process plant modeling in the computer environment has been developed over the past 40 years by implementing the comminution models formed by the Julius Kruttschnitt Mineral Research Centre, University of Queensland, in the early 1970s. The models for the other processes in a mine value chain, such as blast fragmentation and flotation, were continuously developed and improved in parallel as well. Other research and commercial entities have also developed process modeling methodologies in the computer environment, which evolved as specialized commercial software or through equations set up in Excel spreadsheets. These were performed on a local computer, in thousands of simulations over a long period of time due to hardware limitations and the lack of a fully automated process. This limits the application of detailed process simulations for scale-up and strategic planning analysis, as they require many simulations to cover all possible scenarios which would take a lifetime when using local computers. The Integrated Extraction Simulator (IES), as the next generation of cloud-based software package, has made it possible to run simulations on the entire operation value chain in the same platform, including drilling and blasting, crushing, grinding, flotation, and other downstream process and material-handling units. This capability has allowed IES to handle multivariable simulations across the mine value chain, including pre-concentration and in-pit size reduction, and modify the process simultaneously.

By B. E. Davis

A problem that has continued to plague the Florida phosphate industry is the loss of coarse phosphate in the flotation circuit. Attempts to remedy this problem such as floating the coarse material (plus 425 µ m) in a separate circuit have resulted in limited success, but recovery is still not optimum. The Bureau of Mines is investigating ways to improve the recovery of coarse phosphate through improvements in the conditioning step. Studies to optimize conditioning parameters such as agitation energy, conditioning time, conditioner solids, and residual clay content have resulted in improved P2O5 recovery. Optimizing these and other conditioning parameters resulted in a rougher concentrate grading 30 pct P2O5 with a P2O5 recovery of 97 pct.

Jan 1, 1993

By D. L. Shenck

The Navajo Mine is exclusively a multiple seam surface coal mine located in the northwest corner of New Mexico, and entirely on the Navajo Indian Reservation (Figure 1). It is owned and operated by the Broken Hill Propriety Co., Ltd. of Melbourne, Australia. The mine began production in January 1963 with a long term fuel supply agreement with the Four Corners Power Plant. The 2175 MW nominal generating capacity of the Four Corners Power Plant consumes 8-8.5 mm tons of coal annually. With estimated reserves totaling 1.1 billion tons of strippable coal, only one third is presently committed to the generating station. As development has continued over the years, mining operations have advanced into more complex geologic areas to satisfy the utilities demand for coal.

Jan 1, 1990

By John W. Leonard

The typical tunnel boring machine in use on today's tunnel project uses 15'2-inch diameter cutters at a nominal load of 45 kips per cutter. The cutterhead rotates at a speed of 120 over D revolutions per minute where D is the cutterhead diameter in feet. The typical machine operates about 50 percent of the time. Delivery of a new machine takes 12 to 15 months. The TBM is a specialized tool and not applicable to all jobs. There is a range of job conditions that limit the economic use of a TBM. The machine should provide a thrust per cutter at least twice the compressive strength of rock in psi and up to three times the rock strength is required if in "granitic rocks." The rock strength in psi must be at least three times the cover above the tunnel in feet or the machine may stick. For example, 2,500 feet of cover requires at least 7,500 psi rock to avoid problems. When the RQD's over a significant distance of the project are less than 50, the TBM becomes support-bound. When a large percentage of the time is spent waiting while the ground is supported, the TBM cannot perform well (See Figure 1). This problem increased inversely with tunnel diameter. We are finding that increasing the RPM's does not significantly increase progress. The increased RPM results in a substantial decrease in cutter penetration. The explanation for this decrease appears to be vibration, cutterhead drag, or lack of stiffness in the cutterhead (See Figure 2).

Jan 1, 1981

By R. M. LaDouceur, C. A. Young, W. Nicholas

"Salicyl hydroxamic acid (SHA) adsorption on two rare earth oxides, lanthanum and yttrium, was studied. Adsorption at both surfaces occurred in two stages. Initially, the monovalent anionic collector appears to adsorb significantly and instantaneously in stage one and then becomes sluggish in stage two presumably because the initial stage passivated the surface. By comparison, adsorption during the sluggish second stage with lanthanum oxide did not stop but with yttrium oxide essentially stopped. Surface monolayer formation could not be observed in either of the two cases. Both stages appear to be due to multilayer formation of a surface precipitate as proven by Raman Spectroscopy for lanthanum oxide but inferred for yttrium oxide. Unlike the use of octyl hydroxamate as stated in the literature, increasing temperatures do not increase adsorption such that flotation of rare earths with SHA may be performed at room temperature leading to improved recoveries as well as significant energy savings. INTRODUCTION Rare Earth Elements (REEs) are comprised of the 15 lanthanides along with scandium and yttrium. The REEs with lower atomic numbers are relatively more abundant and are categorized as light REEs. On the contrary, the REEs with high atomic numbers are less abundant and referred to as heavy REEs. They are not really “rare” and, in fact, some of them are quite abundant in the Earth’s crust; it’s just that they “rarely” exist in concentrated deposits but rather are found dilute and practically everywhere. REEs share very similar physico-chemical properties but, because many of these properties are unique, they have gained enormous importance in recent times making several critical and strategic pending their use. For example, REEs have found extensive application in phosphor coatings, magnetics, and automobile cracking catalysts. Early technology was not advanced enough to produce commodity level production of the REEs and can be attributed to REE-bearing ores containing many rare earth minerals (REMs), not just one. In this regard, there are numerous REMs but bastnaesite, xenotime and monazite are considered to be the most common. Bastnaesite is a fluorocarbonate whereas the other two are phosphates. The separation of the individual REE-bearing minerals from the ores is not an easy task since they also exhibit very similar properties. Consequently, when flotation is used, it is done to produce bulk REM concentrates. For REM flotation, it is well established that octyl hydroxamate is more selective than fatty acid collectors (Pradip and Fuerstenau, 1983 and 1991). Liu et al. (2006) indicated that hydroxamates are the most common collectors for REMs. Pavez et al. (1996) studied the adsorption of oleic fatty acid and octyl hydroxamate on REM surfaces. Cui et al. (2012) studied the interaction of octyl hydroxamate with various REMs surfaces using various spectroscopic techniques such as XPS, FT-IR and Raman along with electron microscopy and concluded that such techniques offer ample information to establish adsorption mechanisms. Ren et al. (1997) studied napthalenic hydroxamic acid as a unique collector for flotation of REMs from bastnaesite ore and indicated that more selective collectors were needed. From these studies, it is clear that the quest of more selective collectors is essential but understanding how they adsorb at mineral surfaces is prerequisite to improving flotation performance."

Jan 1, 2016

By C. Sun

With complex component, higher salt content, low biodegradability, DSD acid oxidation wastewater could not be efficiently dealt with traditional methods. It is pointed that the coal water slurry could be made with DSD acid oxidation wastewater of different concentration and the density of coal water slurry could be up to 70%, while its viscosity is only 850~930 mPa?s. The coal water slurry could be perfectly jetted and burnt under different conditions. The higher density the DSD acid oxidation wastewater has, the better properties the coal water slurry have. The pollution components and characteristic group of DSD acid oxidation wastewater are similar to the additives of coal water slurry, so it could be used as a kind of usable additive of water coal slurry. It is so reasonable and feasible to make coal water slurry with DSD acid oxidation wastewater that the pollution of DSD acid oxidation wastewater can be solved completely.

Feb 23, 2014

By William C. Peters

The frustration encountered by exploration crews in connection with land acquisition could be graphed to show a correlation with the natural law that everything tends to become more so. Figure I shows a rather common, situation. The combinations of ingredients are almost limitless and the resulting brew is often poisonous to an exploration man. A single step, that of taking a series of deep soil samples is often delayed until some sense can be made from "floating" unpatented claims which are obscure in orientation as well as position, placer claims overlapping lode claims, location posts with empty Prince Albert cans, and claims with no apparent assessment work for ten years. Add to this some patented claims with¬out monuments, a state or federal withdrawal area which may or may not invalidate pre-existing claims, a loosely defined tunnel site, and some ranchers who understandably resent the separation of surface rights from mineral rights. The picture is familiar to exploration men. One approach to such problems is to ignore them until someone voices an objection -- but then an even more chaotic situation is likely to develop. Another practice is to stake new claims to cover all ground that is "open" at first glance and then find out if there are conflicts so that the new claims can be adjusted accordingly.

Jan 1, 1970

By Robert D. Coale

This paper will describe the copper concentrate slurry pipeline and pumping system between the concentrator and the port at Bougainville Copper Ltd. The operations of Bougainville Copper Ltd. are located on the island of Bougainville in the South Pacific. Geographically, it is the northernmost island of the Solomon Group but, politically, it is part of Papua New Guinea. Papua New Guinea is a United Nations Trust territory administered by Australia, having recently been given self-government, with independence scheduled for December 1974. (Fig. 1). The island is approximately 130 miles long by 30 miles wide, with the Crown Prince mountain range forming a spine along its length. The mountains in place are over 8,000 feet high with the mine located on the western flank at an elevation of 2,200 feet. Exploration on Bougainville for copper by Conzinc Riotinto of Australia (CRA) began in 1963 and by 1968, through geophysical, geochemical and diamond drilling methods, an orebody containing nearly one billion tons of ore grading approximately 0.48% Cu. and sane gold had been outlined. Bougainville Copper Ltd., the company operating the mine, is 53.6% wined by CRA, 20% mined by the government of Papua New Guinea with the public Folding the remainder of the shares. The first copper concentrate was produced in early 1972, with production for the first full year, 1973 being:

Jan 1, 1974

By R. K. Steinhorst

Multivariate cluster analysis, MANOVA, canonical analysis, and discriminant analysis of hydrochemistry data were used to investigate the directions of ground water movement in basalts in the vicinity of the Hanford Reservation, Washington. The statistical analyses indicate that the hydrochemistry of the ground waters in these basalt formations is distinctly different on each side of the Columbia River. This suggests that the river is a ground water divide or that the river is roughly coincident with a hydrogeologic barrier boundary. The statistical procedures used in this study constitute a quantitative means for differentiating ground waters according to hydrochemistry.

Jan 1, 1990

By R. K. Clifford

The formation of elemental sulfur on the surface of sphalerite in aqueous systems was investigated. Hallimond tube flotation tests showed that unoxidized sphalerite did not float well without a collector. Flotation recoveries of greater than 95 percent were obtained without the use of a collector or frother after the sphalerite had been reacted with oxygen under pressure and water at pH 2.8 at room temperature. High flotation recoveries also resulted when sphalerite was reacted in acidic solutions in the presence of platinum sponge, titanium sponge, 316 stainless steel, copper turnings, or [10-5M++]. Conditions which produced high flotation recoveries of sphalerite yielded contact angles of 37° to 40° and also produced elemental sulfur. The increase in elemental sulfur on the surface of sphalerite was detected by elemental sulfur extraction with petroleum ether, electron spectroscopy for chemical analysis (ESCA), and the electron beam microprobe. The quantity of elemental sulfur formed was insufficient to be detected by infrared or Raman spectroscopy, or by the optical microscope or by the scanning electron microscope. An electrochemical type reaction for the production of elemental sulfur in acidic solutions was proposed. The cathodic reduction of oxygen was the slow step which needed to be catalyzed. A chemical type reaction which produced H2S rather than elemental sulfur was evident in non-oxidizing conditions.

Jan 1, 1974

By Julián M. Ortiz, Antoine Caté, Oy Leuangthong, Ilkay S. Cevik

Mineral resource classification relies on the expert assessment of a qualified person (QP) to determine which blocks of a 3D mineral resource model are classified as measured, indicated, or inferred. The decision is often based on a combination of quantitative parameters related to the estimation process and qualitative decisions based on previous experience or preconceptions not captured in the numerical model. As such, the procedure is subject to inconsistency, that is, blocks with similar qualities may end up in different categories, mainly due to the subjective nature of the approach. In this paper, we present a methodology to assist the qualified person in this task by clustering blocks with similar parameters and then classifying them into categories in a consistent and automatic manner that only requires the specification of a few hyper-parameters. The result is a consistent classification into resource categories comparable to the result of a classification done by a qualified person but fully consistent and generated in a short time frame. The procedure begins with repeatedly sub-sampling the block model to determine a distance matrix using an unsupervised random forest approach and then clustering the blocks using the associated distance matrix. Then, all the blocks in the model are classified using a supervised random forest approach, which gives a probability of belonging to each class. The initial class can be determined from the class probabilities. Support vector classification with a radial basis function kernel is utilized to smooth the boundaries between classes and define the final classification. An approach to tune the hyper-parameters of smoothing is provided. The methodology is demonstrated with two examples from two gold deposits. Results are comparable to the classification done by the project qualified person using conventional methods.

Aug 17, 2021

By Paul W. Johnson

Chemical mining is the in situ extraction of metals from ores located within the confines of a mine (broken or fractured ore, stope fill, caved material, ores in permeable zones) or in dumps, prepared ore heaps, slag heaps, and tailing ponds on the surface. These materials represent an enormous, untapped, potential source of all types of metals. The field of chemical mining, now in its infancy, encompasses the preparation of ore for subsequent in-place leaching, the flow of solutions and ionic species through rock masses and within rock pores, the leaching of minerals with inexpensive and regenerable lixiviants under prevailing conditions of the in-place environment, the generation and regeneration of such solutions, and the recovery of metals or metal compounds from the metal-bearing liquors. It is not inconceivable that eventually our ore reserves will consist largely of low-grade, refractory, and inaccessible new deposits and low-grade zones near previously worked deposits, caved and gob-filled stopes, waste dumps, tailing ponds, and slag-heaps. Chemical mining promises economic recovery from these types of deposits. Before it can come of age, however, a much better understanding is needed concerning its chemical and physical aspects.

Jan 1, 1967

By Loic Galisson

"Urban tunneling projects are usually extensively monitored. Most of the instruments used rely on benchmarks providing a sustainable datum throughout the life of the project. The monitoring program also is based on a predicted model of deformation induced by specific construction methods. Events can interfere with those assumptions and eventually alter the stability of these datum. In addition, the anticipated ground conditions and hence the theoretical deformation model often differ from reality. Satellite Radar Interferometry provides useful information to overcome the weakness of the hypothesis made before construction. It is also a powerful tool to ensure the continuity of the monitoring program throughout the life of the project, accurately describing the true effect of the project on the surrounding environment. This paper emphasizes the benefits and limitations of this technique for urban tunneling applications, illustrated by examples of major tunneling projects around the world. MONITORING URBAN TUNNEL PROJECTS Why Monitoring? Retrofitting existing tunnels or constructing new tunnels – including access and retrieval shafts, portals and cross passages – implies an alteration of the neighboring soil structure. Excavating, dewatering, grouting, loading tie backs, etc. artificially modifies the natural equilibrium of the pore-water pressure, of the water table level and of soil stability. In many cases, the effects are immediate: ground loss, deformation of utilities, settlements of buildings, and distortion of infrastructure are a few examples resulting from construction activity.Instrumentation and Monitoring Scope To control and mitigate the risks of damage associated with the above effects, tunnel projects usually include an instrumentation and monitoring program. Depending on the level of geotechnical, structural and environmental risk, the magnitude of this program varies. Projects with a low exposure to risk may restrain the program to conventional methods such as limited topographical surveys and intermittent manual readings of geotechnical instruments. On the other hand, iconic projects with high risk or with controversial history may implement complex and extensive instrumentation plans, involving highly technical solutions such as Automated Motorized Total Stations (AMTS – see opposite Picture 1), Multi-Point Borehole Extensometers (MPBX), In-Place Inclinometers (IPI) and a wide series of fully automated geotechnical, structural and environmental sensors. In this case, all the devices are usually connected to field data loggers collecting raw data around the clock at frequencies ranging from days to seconds, depending on the sensors."

Jan 1, 2016