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By R. J. Kuczynski

The U.S. Bureau of Mines operated a 2,000-g (4.4-lb) batch process development unit for recovering platinum-group metals (PGM) from automobile catalysts. Virgin monolith, used pellet, and used monolith catalyst samples were tested. Leaching twice with 1-pct sodium cyanide (NaCN) solution at 1600 C for 1 h dissolved more than 95 pct of the PGM from virgin catalysts and more than 90 pct from used pellet catalysts. More than 85 pct of the PGM was dissolved from used monolith catalysts when a third autoclave step was added. Solid PGM concentrates containing more than 99.8 pct of the dissolved PGM and analyzing greater than 70 pct PGM were recovered by heating the pregnant leach solutions from virgin catalysts to 2500 C and used catalyst to 2750 C for 1 h. The solution after heating contained less than 0.2 ppm. total cyanide. The virgin residues passed the EPA Extraction Procedure Toxicity Test (EP Tox Test), the EPA Toxicity Characteristic Leaching Procedure (TCLP), and the California Waste Extraction Test (WET) for all elements except Ba. Adding sodium sulfate (Na2S04) to the virgin leach residues reduced the amount of Ba dissolved to an acceptable level. The used leach residues passed the EP Tox Test for all elements but failed the WET and TCLP for Pb.

Jan 1, 2010

By Charles D. Litton

This U.S. Bureau of Mines report details the results of a series of large-scale experiments where small coal fires were used to ignite the conveyor belt at air velocities ranging from 0.76 to 6.1 m/s. In the tests, electrical strip heaters imbedded within a pile of coal were used to heat the coal to a point of flaming ignition. The flaming coal subsequently ignited the conveyor belt located approximately 5 to 10 cm above the coal pile. During the tests, temperature, CO, and smoke levels were continuously measured in order to determine both alarm time and level as the fire intensity progressed through the stages of smoldering coal, flaming coal, and flaming coal plus flaming belt. Analysis of the data leads to certain conditions of air velocity and sensor alarm levels that are required for early detection of conveyor belt entry fires. Two nomographs are presented, which define sensor alarm levels and sensor spacings as a function of belt entry cross-sectional area and belt entry air velocity.

Jan 1, 2010

By H. D. Jacobs

The Federal Bureau of Mines, as part of a program to insure future raw material needs for the iron and steel industry, undertook research to beneficiate the oxidized taconites from the western Mesabi range in Minnesota. The data presented were obtained by applying the Bureau-developed selective-flocculation/cationic-flotation process to the second of three oxidized taconite samples. These three samples are representative of an estimated 10 billion tons of ore analyzing 30 to 40 pct iron. The experimental work was performed in a 900-lb/hr pilot plant. Treating the ore sample (36.1 pct Fe) with the Bureau's process produced commercially acceptable concentrates averaging 63.5 pct Fe and 4.3 pct SiO2, with an average iron recovery of 84.6 pct.

Jan 1, 1980

By H. F. Yancey

Traditionally the Pacific Northwest has relied on hydroelectric power, which has been both abundant and cheap. However, comparatively few hydroelectric sites capable of providing low-cost power remain, therefore the need for supplemental thermal generation, perhaps within the next decade, is generally recognized. Based on the present cost and availability of competing fuels, coal seems to be the logical choice for projected thermal power plants. Power companies and public utilities have become interested in establishing reserves of coal for future use. One deposit explored in 1958-59 lies in southern Thurston and northern Lewis Counties, Wash., near Centralia. Drilling, totaling 22,700 feet, proved the existence of 70 million tons of strippable coal--an ample reserve for the projected power plant. The coal, like most others and particularly those of Washington and Oregon, when mined in full seam section by mechanical methods, would require cleaning to make it suitable for use. The amount and nature of the impurities in this coal dictated a thorough investigation of its cleaning characteristics to establish economic factors and to insure proper preparation-plant design. Therefore, arrangements were made through a cooperative agreement to conduct such work at the Seattle Coal Research Laboratory of the Bureau of Mines. This report describes that investigation. The results are of interest primarily in connection with the utilization of this particular deposit, but some of the information developed is applicable to other deposits of low-rank coals in the West, because the impurities in these coals differ greatly in behavior from those generally associated with the higher rank coals of the Appalachian field.

Jan 1, 1961

By Raja V. Ramani, Wilson Miola

"The potential health effects of quartz-bearing airborne dust in mine and mill atmospheres point to the need for the quantification of quartz content in the source material for determining the source-sink relationships and for choosing applicable control measures. While a standard method exists from a regulatory point of view for the sampling of coal mine atmospheres for determining (i) respirable dust concentrations and (ii) the amount of quartz in the samples, there is no generally accepted standard method for quartz analysis in bulk samples of coal and host rocks. Generally, the bulk sample is reduced to a powder for producing quartz analysis samples. Extensive controls arc necessary to ensure representativeness of the analysis samples when these are very minute fractions of the bulk samples. Since the amount of analysis sample is not limited, alternative methods for quartz analysis may also be tried. It is, however, necessary to adopt a procedure which will satisfy several statistical requirements to guarantee representativeness of the quartz analysis samples.In this paper, the important factors in the preparation of quartz analysis samples from the host rocks and bulk samples are discussed. The method developed to prepare the analysis samples is outlined. The results of application of the procedures are presented. The procedure developed for quartz analysis sample preparation is based on sound statistical foundations. The procedure has been validated for reproducibility and homogeneity.The current methods used for quartz analysis in powders are the P-7 infrared spectrometry and quantitative X-Ray Diffraction (XRD). Both have similar restrictions concerning the sample characteristics and operational problems, which arc intrinsic to radiation beams, device geometry, mechanics and controls of the radiation behavior. Although improvements can be made in the spectrometers and diffractometers, some of the most important steps are the procedures for analysis sample preparation from bulk samples and for calibration of the instruments. The sample preparation process is often referred to as one of grinding and sizing the bulk sample to generate the powder for the scanning devices. The particle sizes are referred to and their influence emphasized but the representativeness of the sample is assumed. Assuring sample representativeness during the sample preparation procedures is critical.For the sampling of airborne respirable dust in coal mines, the collection devices, the collection procedures and the analysis procedures are defined. This is not true for bulk samples where weights must be reduced thousands of times to generate the analysis samples for the scanning devices. The specifications to be developed may include bulk sample amount, sample reduction procedures, sample particle size distribution and sample amounts. However, the common problem of insufficient sample amount which is often encountered with mine airborne dust samples need not exist for bulk samples. Further, the same bulk sample can yield analysis samples for several experiments. The latter, of course, requires sample homogeneity.Three concepts are important in the selection of any procedure for sample preparation and analysis. These arc accuracy, reproducibility and representativeness. The adopted procedure has to guarantee a homogeneous sample representative of the population, a defined level of accuracy and reproducibility. Important statistical concepts are embedded in these requirements, particularly with respect to estimation and dispersion errors. Accuracy and reproducibility are totally different though not independent concepts. Estimation is related to accuracy and the true value. Dispersion is related to reproducibility and is measured by the classical statistical standard deviation of the distribution of a series of measurements or analysis performed over the same lot or analysis sample. The dispersion variance (or dispersion error) does not tell a"

Mar 1, 1992

By A. Viksne

A series of tests were conducted by the Bureau of Mines to determine the best means of reducing noise generated by the detonating cord that is utilized for trunklines in quarry blasting. Ten different types of detonating cord were tested and evaluated for their acoustic qualities. The results of the investigation showed that noise levels produced by "low-core-load-per-foot" detonating cord "not covered" were lower than those produced by "high-core-load-per-foot" detonating cord covered with 6 inches of unconsolidated material.

Jan 1, 1972

By F. P. Haver

The Bureau of Mines is developing a leach-electrolysis procedure to produce Special High Grade (SHG) zinc from sulfide concentrate without the generation of sulfur oxide gases. Chlorine-oxygen leaching of the concentrate yields zinc chloride (ZnCI2) which, after purification, is electrolyzed in a fused-salt cell to obtain molten zinc metal and chlorine gas for recycle. This paper describes a laboratory-scale investigation made to develop a procedure for electrowinning zinc metal from ZnC12. Zinc chloride by itself is not a suitable electrolyte because it fumes badly above its melting point and is a poor conductor of electricity. Other salts therefore must be added to prevent fuming and improve the conductivity. Optimum results were obtained with a KC1-LiCl-ZnCl2 bath at 500° C, using a current density of 5 amp/in2 and an electrode spacing of 0.5 inch. Under these conditions, SHG zinc was produced at a current efficiency of 94.3 pct and an energy requirement of 1.16 kwhr/lb. Fused-salt electrowinning eliminates the need to handle and melt cathodes and increases the production of metal per unit cell volume through the use of higher current densities than are possible with aqueous electrolysis.

Jan 1, 1976

By R. H. Storch

This report describes work done as part of a Bureau of Mines program to appraise the titanium-mineral resources of Idaho. The work included both field reconnaissance and a spot churn-drilling program. Much general information was available, as a result of earlier work done under the Western Radioactive Minerals Exploration Program conducted between 1950 and 1954 by the Bureau of Mines for the United States Atomic Energy Commission. This particular exploration provided data as to the quantity of ilmenite (TiFe03) and accessory black-sand mineral concentrates in a number of placer deposits; however, at that time no tests were made to ascertain if the ilmenite was of marketable grade. The spot churn drilling was begun in the Gold Fork area of Long Valley, Valley County, Idaho (fig. 1), in August 1956 and was completed during October of the same year. Eleven holes (designated as the GF series on fig. 2) 35 to 45 feet in depth, aggregating 425 feet, were completed during this period. Data from other exploration drilling in 1951 was used in this report. The 13 holes in the G series shown in figure 2 were drilled by the Bureau of Mines for the United States Atomic Energy Commission; the 7 holes of the DH series were drilled by the Bureau of Reclamation. The 20 holes, ranging from 16 to 140 feet in depth, totaled 1,625 feet. The combined number of all samples recovered was 422. Those taken in 1956 were composited for each drill hole and sent to the Bureau of Mines laboratory in Albany, Oreg., for analyses.

Jan 1, 1958

By J. Burlin Johnson

This report describes an investigation of the relationship between crater dimensions formed in laboratory blasting experiments and the mechanical properties of the material cratered. Scaled field data have been included when available. The results show that tensile strength and possibly other mechanical properties may be useful in predicting maximum crater dimensions.

Jan 1, 1963

By Gary P. Sames

The Bureau of Mines recently initiated a study of geologic features that contribute to roof instability in western U.S. underground coal mines. The purpose of the study is to provide information for use in ground control planning and safety hazard reduction in that region, where mining activity has been increasing. Hazardous geologic conditions were surveyed in selected underground coal mines in Utah and Colorado, and both depositional and structural features were identified as potential ground hazards. Although the conditions found do not differ in kind from hazardous geologic conditions in the Eastern United States, they do differ in intensity of occurrence and relative importance. Three depositional features dominate where unstable roof occurs in western underground coal mines: paleochannel deposits, crevasse splay deposits, and flood basin deposits. Three structural features identified as hazardous, but not so widespread or common as the depositional hazards, are faulting, jointing, and igneous intrusions. This survey establishes a foundation for future studies aimed at reducing and preventing ground control accidents in western coal mines.

Jan 1, 1988

By G. R. Hopkins, A. B. Coons

A survey of the petroleum pipe lines by the Bureau of Mines as of May 1, 1923, shows that on that date there was a total of slightly more than 90,000 miles of pipe lines in the United States, having a capacity of approximately 15,750,000 barrels, which is equivalent to one-fourth of the nation's average production for one month. These lines varied in diameter from 2 to 16 inches, the weighted average being 6 inches. The total pipe-line milenge was about equally divided between trunk lines and gathering lines, though the capacity of the former was about four times that of the latter. This was due, of course, to the difference in average diameter, that for the former being 7.4 inches as compared with 3.7 inches for the latter. The common size for trunk lines was 8 inches, and for gathering lines 2 inches. Oklahora, with 19,180 miles of pipe lines, is the leading State in total mileage, with Texas second and Pennsylvania third. From point of trunk lines alone Texas is considerably ahead of any of the other States, a position which it owes to its size and to the growth in the rovement to its Gulf ports. Cali- fornia, though the leading State from point of production, ranks only seventh in pipe-line mileage. This is due to the fortunate location of the Los Angeles Basin fields, some of which are within sight of the refineries to which their oil is delivered or of the port of San Pedro through which their oil is shipped. The last survey of this nature, made in the spring of 1924 by the U. S. Geological Survey, recorded a total mileage of nearly 83,000 with a capacity of approximately 14,450,000 barrels. This indicates an increase of 9 per cent in both mileage and capacity during the two years.

Jan 1, 1927

By Lowell L. Patten

The Federal Bureau of Mines participated with the National Aeronautics and Space Administration and Martin Marietta Aerospace in developing, building, and testing a portable X-ray fluorescence spectrometer for use as an analyzer in mineral-resource investigative work. The prototype battery-powered spectrometer, measuring I1 by 12 by 5 inches and weighing only about 15 pounds, was designed specifically for field use. The spectrometer has two gas-proportional counters and two radioactive sources, 109Cd and 55Fe. Preliminary field and laboratory tests on rock specimens and rock pulps have demonstrated the capability of the spectrometer to detect 33 elements, to date. Characteristics of the system present some limitations, however, and further improvements are recommended.

Jan 1, 1982

By H. C. Miller

The removal of the mud sheaths that are deposited against the faces of productive oil sands during rotary drilling is one of the important problems confronting operators, especially in semidepleted fields where formation pressures are low. Unless the mud sheaths behind the perforated oil strings and, liners are removed and the sands exposed, oil cannot enter the wells. Consequently much oil that otherwise eight be produced from low-pressure sands is trapped and never recovered. Various types of perforation washers, down swabs, and agitators are used at present for breaking down the mud sheaths and. removing the disintegrated clay particles from wells after the perforated pipes have been inserted. Mechanical methods for removing mud sheaths are quite satisfactory, but prompted by tie request of certain operators in the California oil fields Bureau of Mines engineers have conducted a series of laboratory tests with the view of developing a chemical method for removing mud sheaths in oil wells that will be applicable to field conditions.

Jan 1, 1934

By E. J. Lintner

This paper is one of a series being prepared by the United States Bureau of Mines describing clay mining and crushing methods and costs at various operations throughout the United States. These papers are designed to disseminate technical information regarding methods used. The cost tabulations represent local operating expenditures only and not total production costs. It is recognized that publication of total production costs might, in many instances, cause embarrassment to the individual operator as well as to the industry as a whole. On the other hand, operating costs are essential to a technical discussion and study of the methods employed. The attention of the reader is specifically called to this differentiation in order that no misunderstanding of the scope of the cost tabulations may ensue. The author wishes to acknowledge the assistance of the following persons: L. W. Camp, general manager; S. Cooper, plant superintendent; and W. R. Riel, office manager.

Jan 1, 1936

By G. W. Birge, D. E. Wolfson, J. H. Lynch

This report presents all available 900 ° C BM- AGA carbonization and related data for coals from the principal beds of the southwest Virginia field in a form which permits ready comparison of product yields and properties of coals and cokes . Thirty- one channel samples from Buchanan , Dickenson , Russell , Tazewell , and Wise Counties were carbonized at 900 ° C in an 18 - inch - diameter retort . Blending properties of 10 of the coals were studied , and expansion of most of the coals and blends was measured in the Bureau of Mines sole - heated oven . Ash Most of the samples were chemically suitable for metallurgical use in coking blends , and their coking properties generally were satisfactory . content exceeded 10 percent in only three samples , and none of the coals contained more than 1.5 percent sulfur . Dry , mineral - matter - free fixed - carbon content of the coals ranged from 62.1 to 77.5 percent . Expansion behavior varied widely , ranging from 16.8 percent expansion to 27.6 percent contraction .

Jan 1, 1964

By Donald F. Reed

The bauxite deposits of Tippah and Benton Counties in northeastern Mississippi were developed by drilling as a part of the investigation by the Bureau of Mines of the domestic sources of supply of aluminum. The primary purpose of investigations of this nature was to provide essential information to the war agencies of the United States Government and to assist owners and operators of mining properties in the production of minerals vital to the prosecution of the war. These reports are based upon the field work of the Bureau of Mines and upon data made available to the Department from other

Jan 1, 1948

By C. E. Jordan

The Bureau of Mines is conducting research into the pneumatic recovery of coarse mica and has used this method to produce mica concentrates that contain more than 90 percent mica. This research is being carried out pursuant to the Bureau's objective to develop technology that will help maintain an adequate supply of minerals and metals to meet national economic and strategic needs. Researchers used a Bureau-designed system of crushers, screens, and zig-zag air classifiers to concentrate coarse liberated mica particles from mica-bearing materials. This pneumatic system was used to concentrate four mica ores from Arizona, North Carolina, and South Dakota and three waste tailings from Alabama, Georgia, and South Dakota. Using these samples, it was demonstrated that plus 65-mesh size mica can be effectively recovered by the pneumatic method. Not only were the concentrates high in mica content; it was also demonstrated that this method can be used to recover up to 78 percent of the mica that was originally contained in the samples. Because it is a dry concentration method, the pneumatic beneficiation technique may be advantageous in areas where water resources are limited.

Jan 1, 1980

By William A. Vogely

HIGH ACTIVITY, continuing the substantial recovery from the slump of 1954, characterized the domestic nonfuels-mining industries during 1956 Income generated in producing nonfuel minerals and mineral products3 increased 9 percent over 1955 as compared with a 6-percent increase for all industries. Thus, the 1956 performance of the mineral industries, while not as dramatic as the 27-percent increase obtained in 1955, continued to exceed the gains of the total economy. Other measures of mineral activity strengthen this conclusion. The index of physical volume of mineral production, presented for the first time as an integral part of this review, reflects significant gains in all major sectors during 1956; and, although the overall increase was diminished somewhat by the steel and iron-ore strike in July 1956, the all-mineral index (including fuels) reached a new high.

Jan 1, 1958

By Ronald S. Conti

This U.S. Bureau of Mines report discusses the results of research conducted in the Bureau's experimental mine at Lake Lynn Laboratory on the response of fire sensors to simulated mine fires, which included (1) a slowly developing coal-conveyor belt fire, (2) a rapidly burning liquid fuel-belt fire, and (3) a liquid fuel-belt fire in the presence of diesel exhaust. During these tests, several mine fire sensors were evaluated with respect to sensor placement, spacing, and type. The data indicate that smoke sensors alarm several minutes before CO sensors do; and that, in the presence of diesel exhaust, a prototype diesel-discriminating smoke sensor can successfully function without being sensitive to the diesel contaminants. The vertical placement of sensors in the entry near the fire was also shown to be critical in terms of alarm times. Additional data showed that variations exist in response time and level of response for two brands of electrochemical CO sensor. Results also indicate that early detection of fires will improve the probability of miners' escape, because of reduced smoke concentrations during the incipient stages of the fire.

Jan 1, 2010

By Graham W. Marks, Clyde A. Bridger

"INTRODUCTION An electrolytic process for the preparation of metallic cobalt has been developed recently in the Bureau of Mines Experimental Station at Boulder City, Nev. Chemical analysis shows this cobalt to contain impurities in small percentages, chief of which is nickel. It is desirable to be able to determine these impurities spectrographically. This report is concerned with a procedure for the spectrochemical determination of nickel in cobalt.Previous spectrographic work on cobalt was done by Breckpot and Mevis,/ who used the method of homologous pairs of lines. However, it was felt that a more detailed investigation was needed, employing the method of internal standards.ACKNOWLEDGMENTWe are indebted to B. G. Knickerbockor and his staff at the Boulder City, Nev., station of the Federal Bureau of Mines for their cooperation, and particularly to Richard W. Lewis and Robert G. Sanderson, who prepared nickel-free electrolytic cobalt for us."

Feb 1, 1948