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By D. J. Allan, W. R. Wilson

For conventional aerospace aluminium alloys of the 2000 (copper) and 7000 (zinc, magnesium) series the recycling of process scrap from both metal suppliers and aircraft manufacturers is a well-established, worldwide industry. The recent introduction of a new family of alloys that incorporates lithium has posed a new challenge to the recycling industry owing to the high cost of lithium, its high reactivity to the atmosphere and to refractories and its absence from the specifications of all other registered alloys. Various process options for recycling have been identified, but vacuum distillation has been selected as the most cost-effective and technically feasible solution. Experimental work established that the separation of Li from AI-Li scrap is feasible and an industrial process has been designed. The economics of Li recovery are very sensitive to the AI-Li content of the feed material. Owing to the design of aerospace vehicle manufacturing plants it is expected that the swarf will be mixed with other alloys. A method of enriching this feed has been developed that is based on the control of swarf morphology by thermal and mechanical treatments as a precursor to eddy-current separation. After eddy-current separation and vacuum distillation small proportions of Li are retained in the AI residue. The effects of this on the properties of conventional AI-Si shape-casting alloys were investigated and safe threshold levels have been established.

Jan 4, 1993

By M J. Thomson, P T. Burgin

The economic growth of Hong Kong and adjacent territories in Southern China is, to a considerable extent, dependant on air transportation, but the present Kai Tak Airport is incapable of expansion to meet future needs. After years of study, agreement was reached to build a new airport on the island of Chek Lap Kok, some 34 km remote from Hong Kong, with an ultimate capacity of 87M passengers and 8.9 Ml of cargo per annum. Apart from the building of the airport and its associated infrastructure (including a new town), other similar massive construction works have been necessary in the form of land reclamation from the sea and existing outer lying islands. The construction of bridges, tunnels, railways and highways are also an integral part of the project. The paper provides a broad overview of the concepts of the scheme (called The Airport Core Programme) and highlights some of the major operations and equipment being used in the projects, whose cost at 1992 prices was reckoned to he Hong Kong (HR)$l63hn.

Jan 7, 1997

By J A. Hacked

This paper explores the potential to exploit controls over the outputs of the primary blasting operation, arising from the performance consistency benefits gained in using modern bulk emulsion explosives technology. The former, allied with the latest powerful blast predictive software and measuring tools, offers the user the opportunity to apply control over both cost and performance, which has not been possible in the past.

Jan 12, 1997

By Zhengya Lu, F. Lawson

The surface tensions of lead and lead alloys with very low concentrations of silver, tin and copper were measured by the sessile-drop method. The enrichment of silver and tin in the surface of liquid lead alloys at temperatures close to the freezing-point of lead was confirmed, which may explain the unusual behaviour of small amounts of silver and tin in lead bulllion during the sulphur-drossing step of the refining process. From the limited data available copper also appears to concentrate at the surface of the liquid alloy

Dec 1, 1991

By R. E. T. Hill

"A laboratory study was undertaken to determine the condensed equilibrium phase relations at 600°C in that portion of the quaternary Fe-Ni-Cu-S system which lies in the neighbourhood of the monosulphide solid solution (MSS). The study sought to determine to w hat extent copper affects the temperatures of stability and compositions of iron-nickel sulphides in bulk compositions similar to those of massive Fe-Ni-Cu ores. Experimental data, including stable phase assemblages and phase compositions, are presented.In the quaternary system at 600°C MSS forms stable phase assemblages with pentlandite, chalcopyrite solid solution, pyrite and vaesite. Over the range of bulk compositions displayed by natural ores copper as well as metal/sulphur ratio have a significant effect on the thermal stability of pyrite and pentlandite. Errors therefore accompany the widespread practice of ignoring copper or chalcopyrite when the mineralogical and compositional changes that have accompanied the initial cooling of primary magmatic sulphides or their subsequent homogenization during isochemical metamorphism are being deciphered. These errors are most significant for ores the bulk compositions of which lie tow ard the sulphur-deficient side of the cupriferous MSS. Temperatures as much as 300°C above the copper-absent value are possible for the interpreted upper stability limits of pentlandite in these ores.The experimental data show that up to 2.0 at% copper can occur in pentlandite stable at 600°C in a bulk composition equivalent to natural magmatic ores. This is equivalent to nearly 10 vol% chalcopyrite. Pentlandite contains more copper than coexisting MSS and the copper content of both phases increases with increasing iron."

Jan 1, 1984

By M. Dobias, N. Mayor, J. Lillo, A. Gonzalez, R. Lunar, R. Oyarzun

The central domain of the Spanish Central System contains a series of Ba-(F)-(base metal sulphide) hydrothermal vein deposits that are hosted by adamellitic granitoids. Fluid inclusion and sulphur isotope data suggest that the mineralisation was formed by low-salinity hydrothermal solutions that incorporated fluids, metals and sulphur from a magmatic source. Mineralisation occurred in two main stages; a first stage of open-space filling with quartz-Ba-(F)-(base metals) ; and a second stage of brecciation and deposition of quartz-barite. The two mineralising events can be clearly related to two tectonic episodes of late Variscan age that involved extension along east-west trends followed by ductile transcurrent movements along northeast-southwest trends.

Jan 4, 1992

The following procedure was used to determine cut-off grades: define the orebody profile; plan the stope layout and quantify the work involved; formulate equipment-performance norms; calculate unit costs; input process recoveries and metal prices; and calculate the cut-off grade. Use of the method is illustrated using data from a copper mining complex in India. Results from the study led to the following conclusions for underground mines in general. Cut-off dependent costs vary significantly with the stoping method employed, orebody thickness, the degree of mechanisation and the working efficiencies of the workforce and equipment. This applies even within the same deposit. Sub-level stoping and its variants can be operated at a lower cut-off grade than cut-and-fill and its variants. Thinner orebodies affect cut-off grades adversely, but with thinner orebodies very little further reduction in cut-off grade can be achieved once a certain minimum width has been exceeded. For the same stoping method and in the same mine the cut-off grade varies with the degree of mechanisation. Labour-intensive methods require higher cut-off grades. An allowance for working efficiency should be made when calculating cut-off grades. Higher process recoveries allow a significant lowering of cut-off grades

Jul 1, 1996

By R. Macleod, G. G. Bursey, T. R. C. Aston, J. E. Gale

In 1991 the problems of water inflow at the mine were addressed by a three-phase study. A three-dimensional finite-element computer code, CFEST (Coupled Fluid, Energy and Solute Transport), was used to model the system of groundwater flow around the mine, allowing assessment of the nature of the hydrological regime and of the various recharge mechanisms and sources of inflow. A regional (111 km2) model was used to simulate conditions of low to average mine inflow and provide boundary conditions for the subsequent local (16.8 km2) model. The regional model produced inflows of 0.26 m3/s and the local model 0.25 m3/s. With the use of constant head conditions to simulate a saturated flood plain along the Gays River and on doubling the rate of surface recharge, the local model produced a maximum mine inflow of 0.255 m3/s, in contrast to a measured peak mine inflow of 0.37 m3/s. The discrepancy suggests that during periods of high river level surface water gains access to features with high permeability, such as sinkholes, that may be connected directly or indirectly to the mine workings. Improved simulation of high inflow conditions can probably be achieved by determining the hydraulic conductivity of the river-bed and flood-plain sediments and modelling known sinkholes as discrete units. Possibilities for controlling the amount of inflow to the mine include sealing the flood plain with dykes, checking regularly for new sinkholes, which should be filled and capped, maintaining adequate mine drainage, and monitoring well levels and pressures on a continuous basis.

Jan 12, 1993

By D G. Jefferies

This paper covers National Grid's role in the electricity market, the growth of competition in both generation and supply in that market, and the resulting impact on fuel usage, prices and the environment. It also considers other, external influencing factors on the electricity supply industry, as well as the growing trend towards globalization.

Jan 12, 1997

By R. J. Bridges

Mining operations on the Witwatersrand are conducted for the most part in rocks of highly quartzitic character. They comprise the following types: Conglomerates, grits, and quartzites, to which on the Far East Rand must be added fine-grained quartzitic shales and shales. In addition, vein quartz occurring as small veins, veinlets and fissure fillings, and igneous rocks forming dykes, must be mentioned, although they constitute only a small percentage of the rock broken. The following is an account of the character and mineralogical composition of the various types.

Jan 1, 1947

By L. T. Matthews, C. E. Loo

During sintering, porous ore particles are easily assimilated by liquid melt. Two simple models of the process are considered: the dissolution of a solid by a liquid and the penetration of a liquid into a porous solid. Laboratory sintering studies covering a range of experimental conditions were undertaken to characterise the assimilation of large particles of ore and flux by melts formed from different mixes of fines. For ores, the process appeared to be complicated by the detachment of fines from the ore surface prior to melt formation, according to the mass of adhering fines and surface roughness of the particle. This delayed the onset of assimilation and sometimes reduced it, although melt penetration was fast and effective. Studies using different temperature profiles suggested that the assimilation of haematite was controlled by the transport of Fe2O3 away from the surface of ore particles. The assimilation of limestone depended more on thermal conditions than on the three magnesia-bearing minerals considered. Changing the composition of the initial melt significantly altered the extent of assimilation of ores and limestone, but again had a less marked effect on the magnesia-bearing fluxes.

Jan 8, 1992

By D. Newman

Mineral production in the Highlands and Islands of Scotland during the last ten years has been confined to the sporadic production of industrial minerals—for example marble, anorthosite, limestone, talc and silica. From 1962 onwards there has been an upsurge in mineral exploration in the Highlands, increasing in tempo from 1966 onwards due to the efforts of the Institute of Geological Sciences, the Highlands and Islands Development Board, and private and public companies. Geological, chemical and economic aspects of some of the more interesting mineral prospects are discussed: these include anorthosite, feldspar, magnetite, quartzite and brucite marble. Reference is made to a geochemical survey undertaken in the Rosehall district of Sutherland, the results obtained being summarised. Problems that affect the future of mineral exploration in the Highlands are stated.

Dec 1, 1971

By D. G. Skinner, J. H. Griffiths, F. T. Williams, A. G. Withers

"The absence of homogeneity, in dust-clouds underground indicates the use of a method in which the volume of air sampled is an appreciable proportion of the total volume under consideration. Of the available methods, only the impinger and gravimetric techniques seem to comply with this requirement. In practice, greater efficiency of collection of the smaller particles is possible by the use of a gravimetric filter than with the impinger. For this reason if, as seems desirable, a standard method of sampling be sought, the adoption of a gravimetric technique is to be recommended.Provided that the amount of dust collected is reasonably large, the paper filter would seem to be preferable to the solid crystal type of filter on account of its greater convenience in use.Alternative methods of sampling are desirable to cover the wide range of practical conditions."

Jan 1, 1947

By D. R. Hudson, M. J. Donaldson

"Study of gravity concentrates from the gold-recovery circuit of the Kambalda nickel mill has enabled an assessment to be made of the nature, relative abundance and compositional variability of platinum group element (PGE) minerals and other associated heavy minerals that are present in the Kambalda nickel deposits. The major platinum minerals are sperrylite, PtAs2, and nioncheite, (Pt. Pd, Ni)(Te, Bi)2, and the major palladium minerals are sudburvite, (Pd, Pt, Ni)(Sb, Te, Bi), stibiopalladinite, Pd6Sb2, and palladoarsenide, Pd2 (As, Sb), together with a palladium antimonide and a palladium arsenide that have not been fully characterized. Palladian melonites, which contain up to 10 wt% Pd, and palladian nickeline are also important PGE hosts. Sperrylite and sudburyite are by far the most abundant discrete minerals in the gravity concentrates.Gold occurs as argentian, cuprian and nickeloan—cuprian gold, and as the tellurides calaverite, petzite and auriferous hessite. Silver is present in petzite, hessite and volynskite. Other rare phases contained in the gravity concentrates include native bismuth, altaite, frohbergite, breithauptite, gersdorffite, parkerite, scheelite, tantalite, cassiterite, rutile, bunsenite, gahnite, barite and uvarovite.Descriptions of in-situ occurrences of PGE minerals at Kambalda are rare. Michenerite, PdBiTe, and testibiopalladite, PdSbTe, have been described from a telluride-rich quartz-carbonate vein that intersects massive sulphide ore in Lunnon Shoot. Moncheite has been observed in chalcopyrite-rich stringers, and sudburyite occurs as inclusions in nickeline in a quartz- carbonate veinlet. No discrete PGE minerals have been found within the massive and matrix ore zones in the Kambalda ore- shoots, and the geochemical distribution of PGE suggests that the formation of discrete PGE phases may be related to post- magmatic processes—in particular, metamorphic segregation of sulphides, and the interaction of the ore sulphides, containing PGE in solid solution, with younger hydrothermal fluids. This has led to local redistribution of the PGE, with concentration in footwall stringers and veins, and in reaction zones."

Jan 1, 1984

By C G. Wall, T S. Daltaban

Three quarters of recent increases in world oil reserve estimates since 1990 have been attributed lo ‘better reservoir management' rather than to new discoveries. For the United Kingdom Continental Shelf (IJKCS), the Department of Trade and Industry (DTI) has on 2.2 bn barrels of extra oil protection through effective reservoir management of existing producing reservoirs. Past practise has been to manage petroleum exploitation on a departmental basis, with exploration assessing and ranking prospects, reservoir engineering assessing development plans and production facilities implementing plans. Any reservations necessary might involve restarting the project evaluation from scratch. Current practice is to manage an operation through asset management teams involving all disciplines. It is hoped that this approach will not only eliminate fruitless directions of effort, but the quality of work in each discipline will benefit from interaction. That is, the result of a team effort is greater than the sum of individual efforts. To date, this is most apparent with the interaction between geology, reservoir geophysics and reservoir engineering through reservoir characterization. This is the current area of greatest effort, with improved geophysical technology and computer power leading to more and more detailed and complex simulation models. The equally important interaction of reservoir engineering and production and facilities engineering applied to fields in decline has not yet achieved the prominence that it deserves. Establishing priorities in reservoir management requires the very critical evaluation of the relative value of objectives. The fact that something can be done (3-D seismic, 4-D seismic, multilateral wells, or three phase multi-layer well test analyses etc) is not a good reason for doing it. Reservoir management should he a study of value added versus cost for any activity possible or proposed. Both in the areas of reservoir data acquisition and of assessing opportunities in the period of production decline, it is likely that expert systems will need to be developed with the associated base of experience, understanding and know ledge. A n other area for the future is the elusive target of ‘enhanced ’ oil recovery, as distinct from ‘improved’ oil recovery. The most likely route forward here is the incessant scrutiny of reservoir regions and units within fields for their suitability for pilot schemes for advanced recovery techniques implemented at a favourable time. Finally, the reduction of costs, the maintenance of low. but viable rates of production and the threat of abandonment costs will increase reserves. An increase which may have appeared insignificant in the past is now more valuable.

Jan 11, 1996

By S. G. Tsimas, A. K. Moutsatsou, S. G. Tsivilis, G. K. Parissakis

(NH4)2SO4 can be used with success as a leachant to remove gypsum contained in celestite ores. The process, which is applied before flotation, provides an upgraded feed and problems related to the simultaneous flotation of CaCO3 and SrSO4 are reduced. The process is independent of the gypsum content of the feed so that each leaching stage decreases the gypsum content by almost 50%. The use of (NH4)2SO4 has an insignificant effect on the co-leaching of SrSO4 (0.45 wt.%) at each stage

Jun 13, 1905

By M. J. Russell, W. E. Stephens, D. B. Mohamad, A. B. MacKenzie

Redox front processes in rocks are important in the context of both radioactive waste disposal and the development of orebodies. Results are presented from a study of the distribution of uranium and thorium and the natural decay series equilibrium about redox fronts in a granite at the Criffel pluton and Craignair quarry, Dalbeattie in southwest Scotland. The results are considered in the context of large scale uranium aqueous transport in the region and compared with those from a previous study of highly developed redox fronts at Pocos de Caldas, Brazil. Results show that the Criffel pluton has experienced a recent and rapid removal of uranium from the uppermost section of the granite whereas thorium has remained relatively immobile. The radium and uranium distributions indicate that diffusion processes probably control the distribution of radionuclides about the front. These processes are similar to those observed at Pocos de Caldas. The trends of concentration and activity ratio about the Dalbeattie redox front are less pronounced than those at Pocos de Caldas owing to the shorter time available for the process and the lower intensity of weathering at Dalbeattie.

Jan 12, 1992

By J. Drzymala, K. L. Wolters, T. Chmielewski, T. D. Wheelock, D. H. Birlingmair

Microflotation tests were conducted with a modified Hallimond tube equipped with a fritted glass disk and magnetic stirrer to determine whether the results would support an equation that predicts a linear relationship between particle size and the reciprocal of particle density in water for a specified flotation recovery in a given time. Data obtained with the tube for either hydrophilic or hydrophobic solids fit the equation satisfactorily. It was also shown that the natural flotability of molybdenite is somewhat less than that of elemental sulphur and that sodium dithionite is a good depressant for sulphurised pyrite. In addition, it was found that the untreated pyrite and galena used in the study were hydrophilic and did not float by particle-bubble attachment.

Jan 4, 1992

By A Misra

In pursuit of solving the development rate problem the coal industry has investigated various development systems. While all the systems may improve the development rate they may not necessarily he cost effective. This paper carries out an economic analysis by developing cost models for present and future development systems for retreating longwall faces with particular reference to Australian longwalls. A critical cost analysis of various development systems is presented by taking into consideration all the costs associated with development systems. The costs have been divided into equipment, face and panel services, belt and structure, wages, roof and rib support, ventilation, consumables, power and maintenance. The annualised cost of various equipment has been obtained on the basis of depreciation rates prescribed by the Australian Taxation Office.

Jan 11, 1996

By M. W. Davies, P. N. Smith

The activity of MnO has been measured in the system CaF2-MnO at 1773 and 1873 K and in the system CaF2-CaO-MnO at 1773 K by the method of equilibration with platinum. Large positive deviations from ideal solution laws have been found, but these became less as the lime content rose. The loss of a volatile component made activity measurements impossible in the CaF2-AI203-MnO system, but the boundaries of a two-liquid region have been measured at 1773 K.

Dec 1, 1971