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By A. Kurkov

Flotation process is based on the formation of primary collector-based supramolecular associates at the mineral surface and within the pulp. Supra molecular chemistry allows studying within a common framework, all kinds of molecular associates, from dimers to large assemblies, resulting from spontaneous association of a large number of interacting components of the flotation system, where the collective action of non covalent bonds can have an important role. Self-organization of supra molecular assemblies in the flotation process can be controlled by modifying the chemical structure of the collector, the nature and arrangement of functional group in it, by introducing secondary agents (SA) into the process, to adjust the interaction between the collector and the surface and to control the hydrophobicity of the adsorption bed. This offers broad opportunities to build supramolecular assemblies to improve the efficiency of flotation. Besides, the more complex is the system, the weaker are the interactions, that determine its behavior. This powerful factor still is not employed deliberately to control the flotation process. Organophosphorus compounds (OPC) - dialkyl phosphoric acids whose radicals contain ethoxylated groups ? are considered as nanocompounds, that can be used in building supramolecular assemblies. The presence in an OPC molecule of functional groups (P=O, P (O) O-, P (O) OH), ethoxylated groups, and aromatic rings is the basis for the formation of stable supramolecular associates. Gross formula: C54H94KO16P. Molecular weight is 1069.39. Phosphoryl anion has a regular tetrahedral structure with the angle of 109.5°. Lengths of -P-O- bonds in a PN molecule are 1.7345Å; length of the hydrocarbonic radical C42-C72 = 33.942Å. In an alkaline environment, PN is in the form of the anion, in an acidic environment ? in the form of the polycation due to protonation of the oxygen in the EO group. Chem Office software suite was used to generate three-dimensional images of an OPC molecule in acidic and alkaline environments, to reveal the OPC geometry (bond lengths, valence angles, aliphatic radical length), to identify the collector's binding sites with the mineral surface, to find the most stable and energy-efficient molecular conformations of an OPC molecule and its complexes with minerals under various conditions. Mechanisms of interaction between OPCs and the mineral surfaces are different. In ores whose minerals are dominated by ionic bonds (fluorite), the interaction mainly involves the anionic form of the collector; in ores, whose minerals are dominated by covalent bonds - the oxygen of the phosphoryl group (donor-acceptor interaction) and the oxygen of the ethoxylated groups. This difference is responsible for the formation of spatial associates with different surface layer structures. Introduction of supramolecular chemistry concepts into the analysis of flotation phenomena and mechanisms can become an effective tool for better understanding the flotation process and offers new means of consistently improving its effectiveness.

Sep 1, 2012

By Anatoly Usov

The detailed researches of a broad circle of problems connected to development of the electric pulse method destruction materials (EPD) of a various nature and area of use are executed. The electrical and power characteristics of process, physical fundamentals of selectivity of a breakdown and destruction are investigated, the device of electric pulse (EP) disaggregation and ?omminution of materials are developed, the technological efficiency of disintegration of industrial minerals estimated. Due to its technological advantages, the EPD could have a great potential in minerals mining and processing technologies. Low specific power and weight-and-size characteristics of EP installations based on the existing out-of-date electric equipment are at present the main reasons hindering the effective application of the method in mining and processing technologies. The main studies carried out in Russia in the field of electro technical equipment development for EP technology are presented. The pulse capacitors service life affects greatly the economic efficiency of the process because the capacitors cost accounts for a considerable, and in some cases, the most part of the operational costs. Determined and analyzed in the study are the ways which could significantly improve the specific characteristics of high voltage pulse generators (VPG), such as to use of high-frequency voltage transformation to develop a charger; to use pulse transformers (PT) with iron magnetic circuits made of materials characterized by high magnetic permeability, in pulse generating circuits; as well as to use special ways which could produce voltage pulses with a short front. The experiments have proved the possibility to adapt these technological solutions for EP devices, and a further strategy of the EP technologies development and application has been suggested on this base. Keywords: electric pulse disaggregation, electric pulse installation, charger battery, high voltage pulse generator

Sep 1, 2012

By Svetlana Krashenina, Nebojsa Petrovic, Oscar Lopez

"As easily mined gold deposits are becoming increasingly rare, gold producers are turning to the processing of ores with polymetallic and copper mineralization. These base metals can create metallurgical and waste handling/disposal challenges, which can render the project uneconomic. Base metals such as copper compete for the cyanide reagent used to extract gold, necessitating the need to increase cyanide volumes and consequently, cyanide consumption costs. Copper will also stabilize in tailings water as weak acid dissociable cyanide, a form that is both difficult and costly to destruct. SART (sulphidization-acidification-recycling-thickening) process technology can be applied to remove base metal interferences in gold projects. SART breaks the copper-cyanide complex and precipitates the copper as a saleable copper sulphide concentrate. With the copper removed, the cyanide can be regenerated as free cyanide for recycle to the gold recovery process. This improves cyanide utilization efficiency and mitigates copper presence in tailings. Additionally, copper recovery generates an incremental revenue source to further improve project economics. Engineering Dobersek GmbH together with BioteQ developed a SART and AVR testing program to recover cyanide and maximize operational efficiencies at a gold processing plant in Kazakhstan with high cyanide consumption in the leach circuit. Results from on-site testing demonstrated that up to 99.98% of copper can be removed and precipitated as copper sulphide and 60-90% of cyanide can be recovered from the AVR and recycled for leaching, reducing total overall cyanide use. This paper provides an overview of the testing methodology and results together with a discussion on the potential of SART to improve gold production operations to deliver both environmental and economic benefits."

Jan 1, 2014

By Markus A. Reuter, Antoinette van Schaik

"INTRODUCTIONGoods and products, such as passenger vehicles, are manufactured by using a wide spectrum of different raw materials to meet highest consumer requirements during use. Due to the time-varying composition and complexity of multi-component products such as cars, recycling is complicated. It involves a network of interconnected processes and material and energy flows. Improving the efficiency of the material cycle of the car to comply with the recycling targets as imposed by EU legislation, requires insight into all aspects influencing the closing of the material cycle (dynamics, technology, economy, legislation, etc.) and their mutual relation. In order to define the link between recycling end-of-life products, their changing composition and design a dynamic model was developed for the resource cycle of cars. The model integrates the optimisation of the material cycle with the dynamic behaviour of recycling systems."

Jan 1, 2003

By Gauti Asbjörnsson

Material handling is an essential part of the aggregate and mining industries. Mixing and blending of granular material can affect the grading and particle size distribution of the material leaving the system. Segregation and variability can cause problems in the downstream process while insufficient capacity will disturb upstream processes. Process plants utilize surge bins for handling recycle streams of material and act as a buffer for the process. The flow through the surge bin is usually controlled by a simple PID controller or PID controller in combinations with a plant-wide controller. Even though the surge bins play an important role of smoothening out the plant and creating a steady operating condition they are seldom included in plant simulations. This can lead to a number of problems in the form of decreased plant capacity, plant lockdown, and even operation units malfunctioning. The main objective of this study is to investigate the dynamic behavior in surge bins and develop a model more suitable for representing this behavior, which can occur during operation, for dynamic simulations. The proposed model adopts vertical layers which allow for flows between segments depending on the level of neighboring segments. This enables both the representing of segregation within the system and gives an indication on the effects from different inlet- and outlet placements. The proposed model was developed in MATLAB/Simulink and validated against an actual bin with the total capacity of 660 m3 in platinum ore application. With the new bin model significantly higher fidelity and more accurate dynamic, simulation results were achieved. Keywords: dynamic simulation, modeling, segregation, material handling, MATLAB/Simulink

Sep 1, 2012

By T. C. Sun

Two wasted activated sludges (WAS), from an industrial wastewater treatment and a sewage treatment plant respectively, and 7 collectors are used to investigate the feasibility of air flotation thickening of WAS by adding the collectors used in mineral processing. The collectors experimented include straight chain fat acids with different chain length, sodium oleate, alkyl sodium sulphonate, sodium dedecylsulfonate, and dodecylamine. The results show that the thickening efficiency varied depending on different collectors. Of the collectors experimented, dodecanoic acid and dodecylamine are best collector for thickening both sludges.

Jan 1, 2014

By Ray Everson, Henry Kasaini

"Adsorption of Pd (II) anions on the surface of activated carbon (Norit 0.8) occurred at high proton concentration (0.01 – 2.5M, HCl) in the feed and averaged 27 mg/g. The adsorption process was interpreted in terms of surface ionisation and adsorption model. Enthalpy of adsorption averaged 0.4 kJ/mole indicative of an instantaneous physical adsorption process. We found that the Toth isotherm fit the adsorption data fairly accurately. A combination of the Langmuir and Freundlich equations yields an effective three-parameter Toth equation (1) which is frequently used to describe adsorption on heterogeneous surfaces.Figure 1 shows the comparison between experimental results and the model isotherms. We found that Langmuir isotherms underestimated the adsorption capacity on the porous surface while the Freundlich isotherm overestimated adsorption. Furthermore, the surface coverage at equilibrium was well described by both the Langmuir and Toth isotherms. But, Freundlich isotherm predicted a surface fraction coverage that was higher than unit. Based on better prediction of surface coverage and a reasonable fit to adsorption data, we concluded that the Toth isotherm best described the adsorption data of palladium. The adsorption process was limited by mass transfer resistance through the external film. We estimated the rate constant from equation (2), where e, ?b, and rp are porosity, fluid density and particle radius, respectively"

Jan 1, 2003

By Kaiwen Liu

Activated carbon is widely used in the removal of organic and/or inorganic contaminants from waste water due to its high surface area, porous structure, and specific surface reactivity. However, in practical applications, it is difficult to recover the activated carbon completely by screening or classification. In this project,we prepared a magnetic form of activated carbon (magnetic activated carbon or M-AC) by precipitation of iron oxides on the surface of activated carbon. The M-AC can be easily separated from effluents by applying an external magnetic field, thus it can be recycled and regenerated for reuse. M-AC was characterized by X-ray diffraction (XRD), specific surface area measurement, and scanning electron microscope (SEM).XRD results show that the major phase of coated iron oxides on activated carbon is magnetite (Fe3O4). The specific surface area of activated carbon was found to be reduced after the impregnation of magnetite particles on the surface. The SEM micrograph shows the aggregation of the iron oxides on the surface of activated carbon. M-ACwas found effective in removing DETA (diethylenetriamine) species and metal ions from solutions. Cu (II) with initial concentrations from 5 ppm to25 ppm in solution is removed by more than 99% with the addition of 0.1 wt.%ofM-AC. For the removal of 25 ppm DETA species from solution, an addition of 0.5 wt.% of M-AC is required due to the larger size of the DETA molecule. Moreover, M-AC showed a good loadingproperty for nickel and gold ions from solutions. M-ACshows a better adsorption capacityover activated carbon and its potential applications in carbon-in-pulp for gold leaching and waste water treatment. Keywords: magnetic activated carbon (M-AC),diethylenetriamine (DETA),metal ion,adsorption

Sep 1, 2012

By M. Schneider, J. Regler, Th. Neesse, AKW A. + V GmbH & Co., J. Dueck, F. Donhauser

"In practice the advantages of high-quality hydrocyclone separation are often reduced due to varying feed suspension properties, solids concentrations and particle size distributions. Therefore, a new control system for a battery of hydrocyclones with a nominal diameter of 150 mm was developed for bentonite slurry regeneration associated with tunnel excavation using bentonite slurry as a transport aid and lubricant.As can be seen from Fig. 1, the hydrocyclone battery has been modified for regulation purpose. The battery was manufactured with an overflow collector as a closed pressure chamber (1) with a discharge pipe (2) where the throttling valve (3) was installed.With increased stepwise throttling of the overflow, the volume split is changed with the effect that the solids discharge in the underflow is increased. To stabilize the total throughput, the feed pump speed is simultaneously increased so that the pressure drop ?p across the hydrocyclones (9) remains approximately constant. However, this causes the increasing pressure inside the hydrocyclones, which results in a further intensification of the underflow discharge. After the detection of the break through of the air core (transition state) by the capacitive sensor (4), the throttle valve is shortly opened, and a new regulation interval can start again. The control concept is focused on maintaining the optimum operating state, characterized by the underflow discharge shape at the transition state between rope and umbrella discharge."

Jan 1, 2003

By A. Güney

Currently, recycling technologies use relatively homogeneous plastics because hand-sorting waste feed is too expensive. Many promising technologies for separating mixed thermoplastics are being investigated, but they are still uneconomical and unreliable. Burning plastics for recycling is not used because of poisonous gases released when their burning. PET and PVC cannot be separated using conventional gravity separation techniques because their specific gravities overlap; PET density changes from 1.33 g/cc to 1.37 g/cc and PVC density is between 1.32 g/cc and 1.37 g/cc. For this reason, plastic recycling needs new techniques. Among these techniques froth flotation, also used in mineral processing, can be useful for its cost and simplicity. In this method, a plastic is selected from mixture, tried to regain its natural property, hydrophobicity. In this study the experiments were applied by using plasticizer reagents to make the selected plastics hydrophobic and us-ing NaOH to render the other hydrophilic. Post-consumed PET and PVC are evaluated by concerning the effects of selected parameters (particle size, concentration of plasticizer reagent, amount of NaOH, conditioning time and the effect of conditioning temperature). At the end of the experiments, optimum parameters for selective flotation of PET from PVC was found as particle size of -4.76 + 3.36 mm, NaOH amount of 30 kg/t, conditioning temperature of 75°C, conditioning time of 30 minutes, reagent amount of 300 mg/L. Consequently, PET was re-covered with 99.7% purity and 57% efficiency.

Jan 1, 2014

By Ben Murphy, Alejandro Yanez, Tatu Miettinen

"Flotation using large volume cells has grown in importance during recent years, particularly given the increasing demand for minerals whilst ore grades are decreasing. Outotec introduced the TankCell® e300 in 2007 to enable concentrator plants to process these higher tonnages. From the beginning, TankCell® e300s with FloatForce® mixing mechanisms have demonstrated good metallurgical performance with decreased operating costs and high availability. This paper deals with specific engineering challenges that need to be considered when installing these units rather than giving examples of performance. Today there are over 100 TankCell® e300s operational worldwide. As more of these units are installed new technical challenges are encountered and solutions developed to maximize their productivity. Lessons have been learnt by operators, engineering companies and the cell manufacturers on how best to design and layout these cells in modern concentrators to ensure smooth transition from design to installation to operation. This paper presents information on important design considerations and learning that has been obtained through the design, installation and commissioning of the TankCell e300 around the world. Areas pertaining to cells layout such as feed and discharge arrangements along with items of metallurgical concern such as sampling, reagent addition and the potential benefits of installing a variable speed drive on the motor will be covered in depth."

Jan 1, 2014

By Z. Chen

This study is concerned with the behavior of bubble clusters in a well-controlled turbulent flow. We used a specially designed cell where the bubble aggregates could be formed and exposed to breakage by a rotating impeller. The effects of impeller speed and the concentration of collector on cluster behavior were studied. It was found that the size of the clusters increases with the concentration of collector used. We also found that although the clusters could easily be destroyed under the action of impeller, they could reform, especially at lower impeller speeds. It was observed that the size of the bubbles arriving into the impeller region in the absence of particles before breakage was considerably higher than the size of the clusters formed at the same impeller speed. It appears that both cluster breakage and re-formation take place simultaneously, and the extent of formation and regrowth is mainly determined by the hydrophobicity of the particles and the impeller speed.

Sep 1, 2012

By Lokesh K. Thakur, Peter Radziszewski

"For the cases tested (11 mills with 15 operating conditions), the Bond abrasion test steel media wear rate prediction gives an overall error of 73% and a standard deviation of 192.5%. However, total steel media wear in a given mill (ball or SAG) grinding process is a product of three recognised wear mechanisms -- impact, abrasion, and corrosion. A total media wear model can be defined on the assumption that the effect of each wear mechanism can be independently determined which allows for a total media wear model to be defined as the summation of the wear result of each mechanism (eqn. 1). It is assumed that impact and abrasive media wear is a function of the energy dissipated in impact and abrasion as estimated by a DEM charge motion simulation. Corrosive media wear is assumed to be a function of the media surface area present in a mill.The 3 initial tests developed (steel abrasion wheel, corrosion batch mill, impact chamber) coupled with the impact and abrasion energy spectra from a DEM charge motion simulation produced total steel wear rate results for the same cases as the Bond abrasion test giving an overall error of 0% and a standard deviation of 66.1%. However, if one were to consider the general observation that wear is proportional to energy and maintain the assumption that corrosion is proportional to media surface area then one would realize that the total media wear eqn. (1) can be reduced to eqn. (2). As this is a linear equation and one has, for the same mill, media wear and operating data for three different operating cases, one obtains three equations with three unknowns. This defines a simple matrix manipulation to determine the constants k1, k2 and k3. From the previous data set, we had 6 identical mills grinding the same ore but having different worn liner profiles and charge volume which provided the opportunity to average out the ki values over 20 combinations of 3 cases. With the determined ki values, it was possible to determine a second estimate of the contributions of impact, abrasion and corrosion to total media wear giving an overall error of 0% and a standard deviation of 56%."

Jan 1, 2003

By V. A. Ignatkina, V. A. Bocharov, T. I. Yushina, I. M. Petrov, A. A. Kayumov

"The purpose of this research was aimed at increasing recovery of metals from rebellious sulfide polymetallic ores of nonferrous and rare metal deposits. The ores under consideration have common processing features, including textural and structural complex characteristics, irregularity of impregnation and wide range of grain size, up to nanoparticle size, variable complex mineral composition, low content of precious metals etc. This all predetermines the need for advanced processing schemes with deep selective liberation and separation of minerals with intercycle release into rough concentrate and fractional products with the use of multi-stage cycles of individual dressing, based on an optimum combination of various integrated beneficiation and hydrometallurgical processes. The application of existing standard processes does not enable the production of high-grade selective concentrates without reducing the recovery rate due to incomplete separation of fine mineral intergrowths and overgrinding of brittle ore and rock minerals.The combined beneficiation processes for such type of resources, aimed at increasing recovery of nonferrous, rare, and precious metals are based on flotation methods in combination with gravity concentration to produce rich rough collective or selective concentrates, comprising readily floatable mineral fractions. At the same time, hardly recoverable and non-separable mineral associations are released into separate concentrated products for following dressing by individual processes. The proposed combined process provides for successive selective liberation of minerals with release of rich readily recoverable mineral fractions at the preparation and ore beneficiation stages. The hardly recoverable mineral associations shall be released in subsequent operations with the use of dressing, based on a combination of beneficiation and pyro- and hydrometallurgical methods."

Jan 1, 2018

By Chuanyao Sun, Yang Yu, Zhen Guo Song, Wei. Ming’An

"Carbonate minerals are very important mineral source of extracting metal, radioactive element and rare earth elements. Furthermore,some carbonate minerals, such as calcite and dolomite, are common and important components of sediments and sedimentary rocks. Many flotation processes involve the separation of valuable minerals with carbonate minerals. So it is of great significance to the flotation theory and industrial practice to investigate the flotation behaviors of carbonate minerals. As regulators, metal ions play a major role in minerals flotation. The study of influence law of metal ions on minerals flotation is helpful to eliminate or utilize the effect of metal ions. In this study, calcite and smithsonite laboratory scale flotation, surface analysis and zeta potential determination in the presence of Fe(II) ion were performed to investigate the effect of Fe(II) on carbonate flotation. The results show that Fe(?) depresses the flotation of calcite and smithsonite. The depression effect of Fe species on calcite and calamine flotation can be improved with the increase of Fe(?) concentration. The zeta potential measurements and surface analysis show the existence of iron hydroxide products on mineral surface, which may be link to carbonate site instead of exchanging with calcium on the mineral surface. Fe species on the mineral surface inhibit the interaction between the reagents and calcite/smithsonite through the formation of surface precipitation coating on the calcite/smithsonite surface when the Fe(?) concentration is higher."

Jan 1, 2014

By Masakazu Niinae, Tasuma Suzuki, Mai Moribe, Yohhei Okabe

Bench-scale electrokinetic experiments were performed to elucidate the electrokinetic remediation mechanisms of arsenate from artificially contaminated kaolinite. The electrokinetic experiments in which a constant voltage was applied demonstrated that high soil pH favored arsenate remediation with respect to both the remediation time and electricity consumption. It was also demonstrated that applying a pulse voltage (1 hour ON, 1 hour OFF) significantly improved the electricity consumption efficiency when the soil pH was maintained at the initial value during the experiments; this trend was not observed when the soil pH was gradually increased from the cathode side. These electrokinetic experimental results indicate that the remediation rate-limiting step varied with soil pH. When the soil pH was maintained at the initial value of 7.2 during the experiments, arsenate desorption was the remediation rate-limiting step rather than the migration of dissolved arsenate toward the anode. Conversely, when the cathode pH was not controlled and the soil pH was correspondingly increased gradually from the cathode side, the migration of hydroxyl and desorbed arsenate ions toward the anode played a more important role in the control of the overall remediation efficiency.

Jan 1, 2014

By Valentine Chanturiya1

We have developed a classification of geochemical barriers according to their origin, i.e. natural and artificial, and according to methods and areas of application. There has been an examination of the interaction between different classes of geochemical barriers with sulfate solutions containing nickel, copper and iron. As natural barriers, carbonates (calcite and dolomites) were used. For artificial barriers, a mixture of serpentine and carbonatite, thermo-activated copper-nickel dressing tailings, and a magnesium-containing sorbent based on brucite was used. Keywords: geochemical barriers, physical-chemical geotechnologies, treatment of natural and waste water, recovery of nonferrous metals

Sep 1, 2012

By Christopher M. Rule, Martyn P. Hay

"A methodology was developed in the mid-1980’s to predict plant performance from standard laboratory flotation tests. The methodology incorporates a flotation simulation program “SUPASIM” which translates flotation performance from bench-scale tests to full-scale plant. The technique is based on a simple, empirical kinetics model, and is tailored for use by the practical metallurgist. Kelsall’s unmodified equation incorporating two rate terms describing slow and fast floating components is used as the basis of the method. The flotation behaviour of an ore is described by a set of numbers, which can be compared in the evaluation of ore types, mineralogy and operating conditions. In so doing a precise relationship is developed between metallurgical performance in terms of grade and recovery and flotation kinetics.To date the performance of more than 20 flotation plants has been predicted, encompassing copper, lead, zinc, nickel, phosphate, pyrite, graphite, cassiterite, platinum and various slags. In three cases, plants have treated more than one type of ore. The method has successfully been used to predict and design four flotation plants using data generated from bench-scale laboratory flotation testwork. All have since been commissioned, and have performed as predicted. In the last year alone it has been used to drive flowsheet development for at least seven new plants in South Africa and the Americas. It is also being used to assist in the optimisation of existing operating plants."

Jan 1, 2003

The flotation of nickel sulphide minerals is normally difficult in the presence of serpentine minerals due to the coating of serpentine particles on the nickel mineral surface. To improve the flotation, dispersants such as polyphosphate and carboxy methyl cellulose are normally used to remove the slime coating. However, in the flotation using high ionic strength process water, these dispersants are invalid due to their ionic nature. In this study, a new type of non-ionic dispersants, Pluronic triblock copolymers were examined with an objective of improving the flotation of ultrafine pentlandite (a nickel sulphide mineral) in the presence of lizardite (a serpentine mineral) in saline water. Three Pluronic triblock copolymers varying in solubility and hydrophile-lipophile balance (HLB) values were studied by flotation tests, settling tests and froth measurement. It was found that two of the copolymers improved pentlandite flotation against lizardite, and one copolymer deteriorated the flotation. The effect of Pluronic triblock copolymers on the flotation was actually linked to their dispersibility and foamability, which were governed by their physical properties. The two copolymers with a higher solubility or HLB value produced more stable mineral suspensions and more stable froth in the flotation resulting in better nickel grade and recovery in both rougher and cleaner flotation. Keywords: ultrafine particle, flotation, slime coating, dispersion, saline water, triblock copolymers

Sep 1, 2012

By S. Martins

The aim of this work is to compare three different results of charge motion in a modified 5ft diameter lab mill and to identify differences and similarities in these results. The lab mill is modified from tumbling a ball charge to tumbling a charge of disks. This modification replicates 2D motion. This 2D condition is measured using an instrumented disk (iDisk) and analysed using a video imaging system. The iDisk is equipped with a 3D accelerometer array and rotation rate sensors. With the help of a video system, some measured quantities are also determined externally. The results of these three predictions or measurements are presented. A discussion is included.

Jan 1, 2014