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By C. Arson

We modeled mode I fracture in shale with an equivalent damage zone (CDM), a cohesive zone (CZM) and discontinuous enrichment functions (XFEM). In the Differential Stress Induced Damage model (DSID model) used in the continuum approach the total work input is equal to the sum of the energy released by crack debonding, the energy dissipated by crack opening, and the elastic strain energy stored in the bulk outside of the damage zone. In CZM and XFEM, the overall stiffness of the rock mass in the process zone drops as soon as the fracture starts propagating (unstable fracture propagation), whereas rock elastic properties in the CDM equivalent damage zone evolve smoothly with the displacement imposed at the boundary of the domain. In the CZM and XFEM, fracture propagation stabilizes after a turning point: this point coincides with damage initiation in the DSID model. As a result, the total energy of the rock mass calculated with CDM is about twice as large as in CZM and XFEM. The relative energy components of the rock mass are in the same order of magnitude and follow the same trends in the three models. This numerical study compares the evolution of dissipated energy potentials during mode I fracture propagation, and is expected to provide a basis to predict the amount of energy released by discrete fracture growth vs. damage propagation in the fracture process zone.

Jan 1, 2015

By D. F. Sherwin

"THE AREA which is described in this paper (Fig. 1) includes the continental margin of eastern Canada extending from the Gulf of Maine to the north edge of the Grand Banks, which, including the continental shelf, slope and rise, comprises an area of about 600,000 square miles. The paper is intended to give a background of the geological setting of this region in the context of its ultimate potential for oil and gas reserves in close proximity to the Nova Scotia energy market.HISTORY OF EXPLORATIONThe history of geological exploration of this area really began in 1878, when U.S. fishing boats brought back samples of rock recovered in trawls from their expeditions to the long-famous fishing banks off Canada's East Coast. Tertiary and Cretaceous fossils recovered from these samples indicated that the eastern Canadian continental shelf was actually the submerged northern extension of the Atlantic Coastal Plain."

Jan 1, 1972

By J. Shahabpour

"Many porphyry copper deposits of the Kerman copper province in central Iran are associated with a consistent structurally con-trolled main drainage pattern, which is shown in this paper to be a useful regional prospecting tool in the search for new deposits. The main drainage trends also generally allow the distiction of high-grade (>0.2% Cu) from low-grade (<0.2% Cu) deposits. Topographic maps1:50 000 or geologic maps 1:100 000 have been found suitable for identification of promising drainages.IntroductionTrends of the main drainage systems transecting the high-grade porphyry copper deposits of the Kerman Region in Iran coincide with Quaternary age regional faults and fractures. Observation of such drainage trends can expedite regional evaluation prior to field examination. Thirty deposits located in the Kerman Region (Fig. 1) have been studied to identify common features that can be used for exploration purposes, especially for the first stage of regional exploration. A variety of field criteria are available for subsequent rapid field checking prior to trenching and more costly methods such as drilling, etc.Characteristic geomorphic features have been considered as aids in mineral exploration by many authors (e.g., Faniran, 1971; Piotrovski and Lubkashov, 1976; Verstappen, 1983). Clark et al. (1967) indicated the relationship between geomorphology and the supergene enrichment of copper in Atacama Desert, Chile, and correlated three periods of supergene enrichment with three periods of pediment disection. Seeland (1978) used fluvial drainage patterns for uranium and hydrocarbon exploration in the Wind River basin, Wyoming. Postolenko and Konopleva (1973) used the reconstruction of ancient valley systems for exploration of gold placers"

Jan 1, 1996

By Jayesh B. Patel, Zhongyun Fan, Hu-Tian Li

"Melt conditioned direct-chill (MC-DC) casting is a novel technology which combines vertical direct-chill (DC) casting with a high shear device directly immersed in the sump for in situ microstructural control. In this paper, the solidification mechanism of DC casting under varying conditions is discussed. The temperature profiles in the sump were measured under the steady state casting conditions by using sacrificing thermocouples. Detailed comparisons of the derived thermal condition are made. The individual role of grain refiner additions, natural thermosolutal convection and forced convection in the sump and the interplay of these factors in determining the solidification structures of DC cast billets are discussed. The MC-DC casting technology can be used to control microstructural constituents and casting defects in DC cast billets/ingots by in situ manipulating of the thermal and fluid flow conditions.INTRODUCTION Direct-chill (DC) casting of aluminium, has been the essential commercial process for producing feedstock suitable for subsequent processing, such as extrusion, rolling or forging. Fine and equiaxed grain structures in the as-cast billets/ingots are required to enable a fine and uniform distribution of second phase particles and microporosity. This leads to higher productivity, more cost-effective homogenisation and more efficient downstream thermomechanical processing. The addition of chemical inoculants has been the standard industrial operation prior to casting for grain refinement of Al alloys. However, it has been established that less than 1% of the grain refiner particles added actually act as heterogeneous nuclei to refine the grain structures, showing a very low grain refining efficiency (Greer, Bunn, Tronche, Evans, & Bristow, 2000). Moreover, the remaining particles from the grain refiner addition in the final casting may cause surface defects during downstream processing. A major issue of the metallurgical quality of large sized ingots/billets is the non-uniformity of microstructures even with chemical grain refiner additions. This is due to the fact that the grain structure formed in the different zones of the billet depends on the local chemical composition and local cooling rate. The local cooling rate can vary from 0.4~1 K/s at the centre of the billet to around 10–20 K/s at its surface zone (Nadella, Eskin, Du, & Katgerman, 2008). The large thermal gradient along radial direction between billet surface and interior of the melt during conventional DC casting induces thermal stress and cold cracking even with grain refiner addition. Therefore the control of casting defects, such as macrosegregation, porosity, cold/hot cracking and distortion of the billets/slabs, etc., is still challenging in industry, causing high scrap rate of DC cast ingots/billets even with grain refiner addition."

Jan 1, 2018

To determine the optimal circuit configuration for gravity gold recovery consideration should be given to a range of factors in addition to the efficiency of the gravity circuit, including capital costs, ease of operation and impact on comminution. The most common gravity gold circuits utilise a centrifugal concentrator treating a portion of the hydrocyclone underflow. This paper will examine this option and alternative circuit configurations to illustrate the effect of various gravity circuit feed and tailings configurations on the equipment sizing, capital costs, operating costs, water balance, comminution efficiency and gravity gold recovery. The optimum circuit configuration can provide reduced capital and operating costs, maximise gravity gold recovery and improve comminution efficiency.

Jan 1, 2011

By Victor F. Hollister

Elemental sulphur occurs as aformational sedimentary deposit in Upper Devonian Wabamun evaporites near Coronation, Alberta. The deposit developed in a stratigraphic jacies-change lrap; it is assumed that petroleum reacted with anhydrite to form sulphur, calcite, hydrogen sulphide and other reaction products. The deposit contains about 362,800 tonnes of sulphur and lies at a depth of 1200 m. The Coronation deposit is expected to be geologically typical of such other native sulphur deposits as may be found in Wabamun Group sediments. Widespread sour gas sulphur production f rom the Wabamun suggests the possibility that additional native sulphur deposits will ·be found.

Jan 1, 1984

By T. L. Tanton

"The New Helen mine is 12 miles east of Michipicoten harbour on lake Superior. It is 2 miles east of Wawa station, on the Algoma Central railway, with which it is connected by a spur line railway and a highway.The mine was discovered by Ben Boyer in 1898 during the gold rush near Wawa lake, Ontario. The original discovery was of solid hematite ore extending to a height of 100 feet on a hill rising abruptly on the east side of Boyer lake. The property was acquired by the Algoma Steel Corporation and mining was commenced in 1899. The first iron ore was shipped in 1900. The mine was operated until 1918 when the hematite became exhausted at a depth of 800 feet below Boyer Lake level.Drilling at the Helen mine, after 1910, revealed a large body of siderite both below and to the east of the hematite. By 1913, the body was known to be about 200 feet wide, 3,000 feet long, and at least 2,200 feet deep. In this there was estimated to be 100,000,000 tons of proved and probable siderite ore. An adit was driven into this body in 1917, and in 1918 work was suspended. In 1937 the Algoma Steel Corporation proceeded with the development of the New Helen mine by open-cut mining, and the beneficiation of the ore by sintering. Production commenced in 1939 and has since been maintained at the rate of approximately 500,000 tons a year.From 1900 to 1918, inclusive, the total production from the Helen mine was 2,823,369 tons of hematite ore and 51,930 tons of pyrite. From 1939 to the end of 1945 the total production from the New Helen mine was 3,921,455 gross tons of siderite ore.GEOLOGYThe Helen property is underlain by rocks of Precambrian age. For general description, and a statement on the structure of the iron deposits, the map-units are those shown in Fig. 1.The oldest rocks occur in a complex that lies north and south of an east-west trending zone, 1 ½ miles long and ¼ mile wide, in which the iron deposits occur. That part of the complex lying south of the iron deposits includes small masses of altered conglomerate and slate, and greenstones and pyroclastics. Other fairly abundant rocks are sericitic, chloritic, ottrelitic, and carbonatized schists of doubtful origin, and almost massive metamorphic rocks in which a development of carbonate, ottrelite, quartz, and other minerals has obscured a pre-existing schistose structure. Felsite and quartz porphyry are· prominently exposed south of the iron deposits."

Jan 1, 1954

By T. R. Madhavan

The development of contact angles on highly polished ?uraninite surfaces, using sodium oleate and dodecyl ammonium acetate as collectors, has been studied at different collector and hydrogen ion concentrations. It was found that sodium oleate in acidic media (up to a neutral: PH) and dodecyl ammonium acetate in neutral and alkaline media give good contact angles. It appears that the combined forms of these collectors, viz., oleic acid and free amine, are more important in effecting contact. W ITH the emergence of uranium as a strategic metal in the last fifteen years, considerable effort has been directed toward the commercial recovery of uranium from its ores. This has resulted in the development of a uranium technology. It is only in recent years, However, that fundamental data regarding the floatability and surface properties of uraninite and ?pitchblende have been elucidated by different methods. Contact-angle measurement is one of the important tools for tl1e evaluation of the conditions of floatability

Jan 1, 1964

By A. M. Martinez, L. Melis, R. C. Peláez, L. G. Garcia

Orovalle Minerals S. L. operates a copper/gold mine in the Asturias region of northern Spain, with the operation dating back to December 1997. The feed to the El Valle mill, consisting of oxide/sulphide (skarn) mineralization, is highly variable, even on a shift by shift basis and presents challenges to the mill operating staff on a daily basis. The mineralogical characteristics of the ore are quite complex with copper present as native copper and sulphides as well as copper minerals with deleterious elements. Gold is present as native gold and electrum. The mill circuit includes SAG/ball mill grinding, gravity recovery of native copper and gold, flotation of copper concentrate, carbon-in-leach gold recovery and SO2/air cyanide destruction. The paper will provide a description of the different unit operations and present operating data of the mill operation.

Jan 1, 2019

By A. E. Wraith, J. Protheroe Jones, P. J. Mackey

INTRODUCTION When Victoria became queen in 1837, that technical wonder of the 19th century—electricity— had progressed from being an exciting physical curiosity and was now a field of intense scientific investigation, invention and application. Its role in electrochemistry had been brilliantly quantified by Faraday in 1833–1834, and his earlier discoveries in electro-magnetism were to lay the foundations of electricity generation and the electric motor. In this age of electrical experiment, silver electro-plating emerged as a popular decorative art, at first using batteries to provide the deposition current, superseded by dynamos in the early 1840s. The decorative chemical and electroplating of precious metals was largely pioneered in England by the firm of G.R. Elkington and Co., founded in Birmingham by George Richards Elkington (1801–1865) in 1832, and protected by a series of patents which helped the company establish a leading position in the new field of ‘electrometallurgy’. In the same decade, the technique of electrotyping emerged, the first application of electro- forming by electrolytic deposition. Simultaneously invented by Spenser in England and Jakobi in Russia, but generally claimed for Jakobi, electrotyping involved plating a thick copper layer on to an electrically conducting mould wall embossed or incised with a pattern or profile which would consequently be replicated on the copper deposit—essentially a method of casting by electro-deposition with the mould wall as cathode. Woolrich’s invention of the low voltage magneto-dynamo in 1842 eliminated the need for batteries as a continuous source of deposition power, opening up the possibility of making more massive electroplated deposits, and by the mid-point of Victoria’s reign in 1869, the work of Wilde, Wheatstone and Siemens had produced the self-excited electro-dynamo, capable of higher voltages and yet greater deposition power. In this early Victorian period copper was extracted and refined by methods which had developed step-by-step over many decades. Only relatively rich copper ores containing more than, say, 6% Cu were economically useful, and the final copper product was far from pure. Copper production in Britain was located principally in the Swansea area of South Wales, based upon the ‘Welsh process’ of reverberatory batch smelting and refining, using locally mined coal and ore imported from Cornwall and elsewhere. Silver was an important by-product. Much of the output was exported and South Wales remained a principal supplier to the world copper market until the 1890s. It was here at Pembrey, a few miles west of Llanelli, that a new primary copper smelter was stablished in 1849 under the name Mason and Elkington, arguably to supply the Elkington company’s market for electrotype products.

Jan 1, 2019

By C. J. Li, J. L. Feng

In the present study we focuses on developing the poroelasticity model that deals with adsorptioninduced permeability change mostly occurred in porous media constituted several phases such as coal. The underlying pressure induced by adsorption is obtained by Virial expansion form, which is substantially founded on statistical physics. The corresponding thermodynamic pressure applying on the pore surface is then used to detail the pore pressure and further to evaluate the macroscopic volumetric strain and the porosity. In the process of physical adsorption, the adsorbed phase is in thermodynamic equilibrium with the gas phase regardless of pore size, and the corresponding chemical potentials are all equal. The relationship between surface strain and volumetric strain is derived under infinitesimal deformation conditions to gain an explicit formulation of pore surface area with respect to volumetric strain and porosity. After the formulation of surface stress modified by the Langmuir isothermal adsorption is derived, the differential micromechanical constitutive equations of porous media are obtained. By supposing that the ratio of current permeability to initial is equal to the cubic ratio of current porosity to initial porosity, the differential equations for permeability change is consequently derived. The numerical simulations by the present model for permeability change of coal induced by adsorption of CO2 and CH4, respectively, are presented under confined stress conditions. The predictions from the model are good in agreement with the experimental data of sorption-induced permeability change of coals in the literature.

Jan 1, 2015

By Larry A. Morris

The environmental impacts of industrial activities have become very serious concerns of the public over the past few decades. Not surprisingly, governments have responded with legislation and regulations to force industry to operate in a more environmentally responsible manner and, more recently, have prompted industry to initiate voluntary measures in response to specific environmental issues. The concept of Product Stewardship has evolved as a system or vehicle for the industrial sector to demonstrate an active concern about the environmental impact of their products, services and processes.

Jan 1, 1996

"One of the corporate values mentioned by many companies deals with respect for people. This paper discusses one aspect of this value, namely, the need for clarity of accountabilities and authorities. The job of the manager in achieving this goal is analyzed and the benefits of enhancing the manager-employee conversation outlined. IntroductionCorporate values usually refer to the standards of behaviour that the leaders of the organization expect of all employees, including themselves, in carrying out their duties. Terms such as integrity, respect for the individual, continuous improvement, continuous learning, teamwork, speed, and innovation are quite common. The company-specific values are typically developed by the top executives of the company, and then tested with a broader group of employees. Where the process works, employees have a good understanding of what behaviour is expected of them in doing their work, in making difficult decisions, and in interacting with others.Having spent considerable time in his career investigating and studying the management systems at over 50 of the most successful companies in Canada, the United States, Europe and Japan, the author has had the opportunity to visit organizations such as Hewlett-Packard, 3M, Xerox, Intel, Toyota, NEC, Komatsu, British Airways, and Eastman Chemical. These experiences, together with the work of many other researchers, including the work of Dr. Elliott Jacques, have helped significantly to form the thoughts expressed below.Rather than reviewing the creation of corporate values and their deployment through the organization, these remarks focus on issues over which managers and employees have some control. The value in which managers can have significant impact deals with people and the respect shown them in the workplace. The component of respect to be emphasized is to be clear about expectations or accountabilities for oneself and the people who report to you, and to ensure that personal authority matches those expectations."

Jan 1, 1999

By M. J. Young, C. A. Aird

"The Gem molybdenum prospect is situated at the head-waters of Clear creek, between the Fraser river and Harrison lake, about 30 miles north of• Harrison Hot Springs, B.C. Clear creek follows a deeply eroded fault zone southwesterly through the center of the claim group. Elevations range from 2,000 feet in the creek bed up the steep slopes flanking the creek to a height of 5,500 feet. The property lies within an area underlain by schists and gneisses which strike from north to west in a broad fold plunging steeply to the northeast. This metamorphic complex has been invaded by numerous bodies of grano-diorite, much of which is gneissic. A granite plug, roughly 2,400 by 4,000 feet in size, has intruded this broad fold just west of Clear creek and encloses a circular breccia pipe 1,500 feet in diameter. In the breccia pipe, fragments of metamorphic rocks, granite and quartz monzonite porphyry are firmly cemented in a matrix of quartz monzonite porphyry. All the above rocks are cut by numerous fractures filled by vuggy quartz veins, many of which contain molybdenite. Attentien was first drawn to the area by a quartz vein, 18 inches in width, known as the Gem vein, which consists of several laminated bands of quartz and molybdenite. Since 1964, exploration efforts have been directed toward attempting to outline a large, low-grade type of molybdenum deposit."

Jan 1, 1969

By ByongPil Lee, Changkyu Lee, Jin Gyun Park, Hyung Sub Eom, Sung-Koo Jo, Jae-Young Lee, Gilsoo Han

"A new hydrometallurgical process for nickel extraction from a low grade laterite ore such as limonite has been developed by RIST and POSCO. This POSCO Nickel Extraction Process (PosNEP) consists of five main processes: ore reduction using hydrogen as a reductant; acid leaching at atmospheric pressure and temperature; cementation by the use of reduced-ore seed; production of the main product such as ferronickel or a high purity nickel compound; and production of by-products such as cobalt and iron in the forms of cobalt sulfate and iron oxide. In addition, hydrogen produced in acid leaching and hydrochloric acid regenerated in pyrohydrolysis for iron oxide production can be reused in the process, which makes PosNEP more cost-effective. The performance of PosNEP has been proven through pilot tests, showing that this process is economically and technically viable. In this paper, basic concepts and detailed test results of PosNEP are shown.INTRODUCTIONNickel has been extracted from two types of ore, sulfide and oxide ore. Nickel and cobalt usually occur together in the ores. The principal ore mineral of the sulfide is pentlandite, (Ni,Fe)9S8, which is easily beneficiated to produce sulfide concentrates(Moats & Davenport, 2014). These concentrates are usually treated by smelting and converting to make a matte. The produced matte is then purified through either hydrometallurgical or pyrometallurgical processes to produce high-purity nickel. In general, this process for sulfide ore has been known as a more cost-effective process than that for oxide ore.The oxide ore is laterite comprised of two different ore types, saprolite and limonite. The main nickel-bearing mineral of saprolite is nickeliferrous garnierite,(Mg,Ni)6Si4O10(OH)8, and that of limonite is nickeliferrous goethite (Fe,Ni)O·OH ore (Moats & Davenport, 2014). Since the saprolite has high contents of nickel and slag formers (MgO and SiO2) and a low content of iron, it tends to be treated by a pyrometallurgical smelting process such as calcination and electric furnace techniques to produce ferronickel for use in stainless steel. In this process, the cobalt in the ferronickel does not have any economic value."

Jan 1, 2017

By D. L. Johnston

"The avenues and degree of participation by aboriginals in the Canadian minerals industry have changed significantly during the thirty years of the author&apos;s career in that industry.The typical 1950s cycle of mineral industry involvement of a local non-Europeanized aboriginal was as an individual employee. The employment relationship would begin with the best of intentions by both parties of permanence and terminate when the pioneering employee was unable to reconcile the attendance behaviour required by the employer and the social-sharing behaviour demanded by family and friends.Cominco Ltd. has been a mine operator and developer in the North since the 1920s. Cominco&apos;s early experiences with employment of non-Europeanized natives at the Con Mine in Yellowknife, Northwest Territories from 1938 to 1986 was a negative experience from both the employee and employer ends. A series of classic failures in employment of individual aboriginals was a large part of the history. A few Metis or natives from other areas were the permanent aboriginal employees at Con (2010). Racial prejudice was overt on the street in Yellowknife and, it can be assumed, in the workplace, as well.The history of aboriginal employment at the Pine Point, Northwest Territories operation (1964 to 1988) was somewhat better but also frustrating. The mine was equidistant (80 km) from the Dene communities of the Hay River Indian Reserve and Fort Resolution, both on Great Slave Lake. Despite a large aboriginal presence and many well-intentioned efforts, employment of aboriginals at Pine Point never got much beyond ten per cent. These would have been half local and half northern prairie aboriginals. One continuing success story was the railcar loading and covering crew led by Ed McKay, a local aboriginal. This predominantly aboriginal crew did its own recruiting and several are on Cominco pension."

Jan 1, 1995

By J. Keith Haddock

"The Luscar Mine is a metallurgical coal mine located in the foothills of the Canadian Rockies, 41 km southeast of Hinton, Alberta. The mine is operated by Cardinal River Coals Ltd., a 50/50 joint venture between Luscar Ltd. and Consolidation Coal Company of Canada. The mine produces a high quality medium volatile metallurgical coal which is sold on the export market principally to Japan and South Korea. Operations consist of a surface mine with capacity to produce 3.0 million tonnes per year and an underground mine which is currently mothballed due to market conditions.GeologyBedrock units within the Luscar minesite are of Devonian to Upper Cretaceous age. The commercial coal measures in the area are, however, confined within the Lower Luscar Formation. The Luscar Formation consists of a 460-metre thick sequence of interbedded sandstones, shales and coal seams. The sequence is primarily deltaic in origin, and is bounded to the north and south at the Luscar mine by tectonically induced thrust faulting.The only mineable coal seam at Luscar is referred to locally as the Jewel seam. Average thickness of this coal measure is usually 10.5 m to 14 m, although in some areas folding and faulting has produced ""pods"" of coal from 15 m to over 40 m thick while in others the structural deformation has thinned the coal to 3.0 m to 4.6 m. Waste within the Jewel seam seldom exceeds a metre of shale, carbonaceous shale or infrequent sandstone stringers.Reserves and Coal QualityProven surface mineable reserves, based on pit scheduling through 1996, are 50.8 million raw tonnes. An additional 19.2 million raw tonnes are contained in possible extensions to the present planned operations. These surface mineable reserves are considered to be those reserves within 155 m of the surface. Underground reserves, located within 770 m of the surface show that 25.7 million raw tonnes have been proven to date in additon to 27 .5 million indicated and 260 miIJion inferred.Coal specification at Luscar Mine is as follows:"

Jan 1, 1985

By Gordon E. Agar

"The effectiveness of two this compounds for copper sulphide depression in molybdenite flotation has been examined with batch bench scale tests.Both thioglycollate and trithiocarbonate proved to be good depressants producing results similar to those f or cyanide and hydrosulphide. Ferrocyanide was ineffective on the samplematerial tested.The depressing effect of thioglycollate was readily reversed by an addition of xanthate.IntroductionThe separation of molybdenite from copper sulphide minerals has been practised for a long time(1,2). The predominant scheme is to depress the copper sulphides while capitalizing on the ready floatability of molybdenite to effect the separation. There are many recipes for depressing the copper minerals(3), among them the addition of sodium cyanide, particularly if the copper is present primarily as chalcopyrite; some form of sulphide whether as sodium sulphide, sodium hydrosulphide or phosphorous pentasulphide when there is a mixture of copper sulphides such as bornite, chalcocite and chalcopyrite; potassium ferro cyanide may be used when chalcocite is the principal copper sulphide; peroxide or hypochlorite; as well as heating in the presence of lime. There are different mechanisms by which these reagent s depress the copper sulphides. Sodium cyanide and the sulphide-producing compounds apparently reduce the potential of the copper sulphides to the point where they ar e rendered unfloatable by xanthates . Another study(4) showed that after cyanide addition, chalcopyrite was rendered un floatabl e until the REDOX potential (measured with a gold electrode with a saturated calomel reference) had become more positive than -250 mY. If the chalcopyrite pulp was conditioned after the cyanide addition the REDOX potential increased slowly, whereas if air was introduced during the conditioning the potential r ose much more rapidly. The difference in time to reach the desired level of - 250 mV was as much as 20 minutes&apos; 25 minutes being required when air was absent but less than 5 minutes when air was admitted . These observation s demonstrate some of the problems encountered when using cyanide to depress sulphides such as chalcopyrite . The system adjusts to counteract the depressing effect of the additive. To overcome this tendency it is necessary to either add an overdose at the beginning or to more or less continuously add the regulating reagent. In this study cyanide solution was added under automatic control to maintain a specified REDOX potential."

Jan 1, 1984

By J. R. Parga T., P. J. Valenzuela G., L. S. Quiroz C., P. Guerrero G., J. L. Valenzuela G.

"Pressure oxidation is a hydrometallurgical pre-treatment process used for refractory auriferous sulfide ores. In the work reported here, a refractory pyrite ore sample from the Mulatos mine, Sonora, Mexico was characterized. The sample was subjected to atmospheric cyanidation, and simultaneous pressure oxidation and cyanidation under different conditions of temperature and pressure. The mineral characterization showed that pyrite is the main species in the sample. The gold extraction tests were carried out in an 1-litre Parr pressure vessel at a temperature range of 90-120 °C, a pressure range of 87.5–150 psi (using oxygen), and a cyanide concentration range of 0.8-1.2 %wt. The gold extraction results showed that diffusion through product layer is the rate controlling step.INTRODUCTIONIn hydrometallurgical precious metals extraction, the most commonly used process is sodium cyanide leaching, as shown in the next reactions involving gold and silver (Fleming, 1992; Marsden & House, 2006):4Au(s) + 8CN- (aq) + 2H2O(l) + O2(g) ? 4Au(CN)2 -(aq) + 4OH- (aq) (1)4Ag(s) + 8CN- (aq) + 2H2O(l) + O2(g) ? 4Ag(CN)2 (aq) + 4OH- (aq) (2)“Refractory” auriferous ores or concentrates often contain gold and silver locked inside other sulfide phases such as pyrite. This renders cyanidation ineffective, so oxidative pre-treatments are used in order to convert the sulfide minerals into porous oxide minerals and make cyanidation work more efficiently. Reaction (3) shows the oxidation of pyrite in alkaline media and the formation of the porous oxide (Koslides & Ciminelli, 1992):2FeS2 (s) + 15/2 O2 (g) + 8H- (aq) ? Fe2O3 (s) + 4SO4 2- (aq) +4H2O(l) (3)A process of simultaneous chemical pressure oxidation and cyanide leaching for a flotation concentrate produced in the mine of Bacís, Durango, in Mexico, gave good results (Parga et al., 2007). In the study presented here, it was intended to use this treatment for a refractory pyrite mineral from the Mulatos mine in Sahuaripa, Sonora, Mexico, modifying variables such as pressure, temperature and cyanide concentration to find the best conditions for oxidation and leaching."

Jan 1, 2012

By P. Tarassoff

Extractive metallurgy is concerned with the winning of metals from their ores and concentrates. It is therefore not unexpected that extractive metallurgy in Canada has always been closely linked with mining. The discovery and exploitation of new orebodies has provided the impetus for the building of many of our smelters and refineries - past and present - and for the development of new metal extraction processes. The purpose of this paper is to provide a brief overview of those early metallurgical developments, and to highlight the continuing expansion and diversification of the Canadian metallurgical industry.

Jan 1, 1999