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By Manqiu Xu, Songtao Yang, Zongfu Dai, Robert Pelton

Five years ago, VALE Base Metals (then INCO), approached Pelton's group at McMaster and described a challenging mineral separations problem. The McMaster group has a strong track record in colloids, polymers, and chemical additives for papermaking; however, they had no experience in mineral processing. They proposed employing hydrophobic nanoparticles to replace conventional low molecular weight, water-soluble flotation collectors. Over the last five years, Vale, together with the Ontario Government (OCE) have funded two graduate students at McMaster who have worked closely with flotation experts at Vale. Experiments involving both very clean model mineral suspensions at McMaster and complex ores at Vale, have shown that hydrophobic nanoparticles do indeed function as collectors. Key nanoparticle properties and mechanisms have been identified and the technology has been protected in patent applications. Efforts to commercialize the technology are on-going. We believe that this project is a good case study demonstrating the advantages of industry-university collaboration and the use of outside experts, who may come up with novel solutions to complex problems.

Jan 1, 2011

Uranium mining remains controversial in many parts of the world, especially in a post-Fukushima context, and often in areas with significant uranium resources. Although nuclear proponents point to the relatively low carbon intensity of nuclear power compared to fossil fuels, opponents argue that this will be eroded in the future as ore grades decline and energy and greenhouse gas emissions (GGEs) intensity increases as a result. Invariably both sides fail to make use of the increasingly available data reported by existing uranium mines through sustainability reporting ? allowing a comprehensive assessment of recent trends in the energy and GGEs intensity of uranium production, as well as combining this with reported mineral resources to allow more comprehensive modelling of future energy and GGEs intensity. In this study, detailed data is reported for numerous uranium mines around the world, including production, energy and GGEs intensity and reported mineral resources. An important aspect included ? arguably unique and never before published ? is the relationship between ore grade and recovery, which is crucial in future projections of uranium mining. Overall, the paper shows the importance of continuing to improve reporting by the uranium sector as well as the ability to analyse key trends and future projections in energy and GGEs intensity of uranium production.

Aug 1, 2013

"An unparalleled growth in the Canadian coal industry in 1970 coincided with increasing awareness by Canadians of their environment and their geography with its accompanying transportation factors. R and D on coal moved with greater emphasis toward solving problems in these areas as well as continuing with strong interest in coal preparation, carbonization, combustion, ""weathering'', spontaneous ignition, storage, exploration and geology. Long-range ""basic"" research was not forgotten in that work continued on coal-based carbons, coal chemistry and agrobiological uses for coal. This paper reviews the status of these many areas of coal research at the beginning of the seventies and takes note of some of the more significant legislation and projects brought to the author's attention. No attempt is made to itemize or to describe in detail all the worthwhile projects, many of which are reported elsewhere."

Jan 1, 1971

By M. Jahazi, J. Gholipour

Design and manufacturing of parts using hydroforming process require knowledge about material behaviour and tribological effects during hydroforming. Lubrication is one of the key issues in successfully hydroform the tubes. A Ni-based super alloy tube with 50.8 mm (2 inches) outer diameter and 0.9 mm (0.035 inches) thickness is considered for this research to study the effect of lubricants on the formability of the tubes. Hydroforming of a hollow compressor blade is considered for this project. A combination of press forming and hydroforming is employed to produce the part. LS-DYNA, an explicit dynamic finite element code, is used to model the experiments. Different lubricants are modeled using different coefficient of friction in the model. Predicted results for strain distribution at a critical section of the tube are extracted for each case to evaluate the effect of different lubricants on the process.

Jan 1, 2006

By A. Galibois, H. Monette, J. L. Collins

This paper deals with the problem of caving, which occurs in varying degrees in blast holes before loading. It is shown that the distribution of the amount of caving in materials may be described by a gamma density function. A decision model to determine the optimal depth of over-drilling 'in order to minimize the expected additional cost per hole is described. Two different policies are discussed. In addition, charts which permit the mine operator to realize significant savings have been drawn for different actual situations.

Jan 1, 1971

By Eric Poulin, Anthony Clapperton, Jocelyn Bouchard, Jaime Cristobal Rojas-Montes, Benjamin Legare

"Several grinding mill dynamic simulators have been developed in the last half-century. However, complete circuit simulations are mainly limited to academic investigations, and on-site applications for advanced control or real-time optimization are scarce. One particular issue that has certainly curbed a more widespread use is the time and efforts required for model calibration. This paper illustrates this challenge and presents a calibration method based on dynamic simulation using industrial data and laboratory testwork. The simulator models discussed originate from the work of Austin and Luckie (1972) for grinding mills, and Plitt (1976) for hydrocyclones. A two-stage approach based on a least squares minimization allows determining calibration parameters values. Firstly, laboratory testwork are required for characterizing breakage coefficients of the ore. Secondly, step change responses and their simulation— effect of ore and water feed rates on output flow rates and size distributions—allows identifying transport/mixing conditions. Simulation results are in agreement with actual process responses to variations of feed conditions obtained from a plant survey.INTRODUCTIONDynamic models for grinding circuits has been intensively studied since the 1970's notably by Austin and Luckie (1972b), Klimpel and Austin (1984), Rogovin and Hogg (1988), Napier-Munn et al. (1996), Liu and Spencer (2004), and King (2012) among others. The resulting models primarily serve in simulation applications for process equipment sizing, which incidentally also helps developing a better understanding of comminution operations. An obstacle curbing a more widespread and targeted use of grinding simulation for process control and optimization purposes is the time and efforts required for dynamic model calibration. It remains a cumbersome task that is typically not well detailed in technical papers. This could explain why dynamic process simulators are mainly confined to academic applications."

Jan 1, 2016

By J. A. Morgan, P. M. Dimmell

Abstract - The Aubry pegmatites are located on the Seymour Lake property, 15 km north of Lake Nipigon in northwestern Ontario. The property lies within the Caribou Lake-Marshall Lake greenstone belt along the English River-Wabigoon subprovince boundary of the Superior province of the Canadian Shield. The property was optioned in March 2001 by Linear Resources (now Linear Gold Corp.), who carried out gridding, prospecting, geological mapping, soil and lithogeochemical sampling, trenching, channel sampling, and a total of 1,866 m of diamond drilling in 32 holes. The Aubry pegmatites are classified by Breaks et al. (2003) as complex type, spodumene-subtype, lithium-cesium-tantalum pegmatites (Cerný, 1989). These pegmatites generally form under high-pressure-low-temperature conditions, display complex internal zoning, have relatively low Nb/Ta ratios in the ore-forming assemblages, and contain significantly elevated tantalum values (Cerný, 1989). Other examples of spodumene-subtype pegmatites include the formerly producing Hugo pegmatite in South Dakota, and the currently producing Greenbushes pegmatite in Australia. The Aubry pegmatites occur as an undulating system of stacked sheets that dip moderately to steeply eastward over a 1-km strike length. The main portion of the North Aubry pegmatite ranges in true thickness from 10 to 28 m over a strike length of 125 m, whereas the thickest portion of the South Aubry has an estimated true thickness of 15 to 16 m over a minimum strike length of 95 m. The North Aubry pegmatite remains open downdip and along strike to the north, whereas the South Aubry pegmatite remains open downdip and along strike in both directions. The Aubry pegmatites are among the most highly evolved in Ontario, with the southern end of the North Aubry (trench 5/6 area) being the most highly fractionated (Breaks et al., 2002). Channel samples from the trench NA-5 area of the North Aubry pegmatite produced values up to 2.49 wt.% Ta2O5 over 4 m. Coarse manganotantalite crystals, up to 5 cm in diameter, from this trench contain up to 84.9 wt.% Ta2O5 (Breaks et al., 2002). Drill hole SL02-31 in the trench NA-6 area gave values of 0.046 wt.% Ta2O5 over 17.7 m, including 1 m @ 0.464 wt.% Ta2O5. Further exploration will focus on defining the grade of the North Aubry zone, extending and defining both known pegmatites, and identifying additional Ta-rich zones within them. Lithogeochemical and enzyme leach soil geochemical data suggest the presence of multiple undiscovered pegmatites on the property.

Jan 1, 2005

By G. Bonnivard

"A complete laboratory process for the treatment of lateritic ores containing a high proportion of iron, as well as chrome and alumina, has been established. The ores treated originate from the tropical zones and result from superficial climatic alteration. According to recent estimates, the known reserves of such ores reach many billions of tons, thus representing huge potential reserves for the elements they contain.The process used is based on the alkaline roasting of pelletized ore in the presence of sodium carbonate. This treatment results in the separate recovery of pellets of upgraded iron ore, pure chrome oxide and hydrated alumina. The research described in the paper aims at determining the best experimental conditions for obtaining the highest extraction of the required oxide from this type of ore."

Jan 1, 1967

By V. F. Hollister

Four conditions are commonly accepted as being needed for the development of native sulphur deposits in sedimentary rocks : (1) ample sulphate-bearing evaporite, normally anhydritic; (2) proximity to petroleum deposits; (3) a hydrodynamic system of communication between these two; (4) a stratigraphic or structural trap to prevent escape of the sulphur and sulphur -bearing reaction products. When any of these requisites are absent, apparently no significant residual bio-epigenetic sulphur deposit will form. These requirements are, however, satisfied in some areas, which include both the Triassic and Devonian evaporites of northeastern British Columbia.

Jan 1, 1977

By François Robert, Steve Green, Tyson Birkett, Dan Richardson

Abstract -Detailed sampling using a portable diamond drill, and interlaboratory comparison of selected samples have been combined with statistical studies of truncated populations to establish the gold content of several outcrops in the Val d'Or area. The outcrops chosen are non-mineralized. The background gold concentration in the rocks of the region is 5 ppb or Jess. Gold is distributed relatively homogeneously within the outcrops studied except for slightly increased concentrations within quartz-tourmaline veinlets. Three samples, of which 20 grams of powder are analyzed for each, can adequately determine the gold concentration of a structurally simple outcrop in the Val d'Or area.

Jan 1, 1992

By DONALD E. BARNETT

Since the days of early settlement ew Brunswick has produced a variety of industrial minerals but it is perhaps only the recent discoveries of significant reserves of potash that have elevated the meaning of industrial minerals in their contribution to the provincial economy. With potash production commencing in July 1983, the role of industrial minerals will increase significantly to the value of mineral production in the province.

Jan 1, 1984

By Michael S. Moats, Prashant Bagri

"In recent years with increasing concerns about energy consumption in hydrometallurgical processing, there is an ongoing attempt to use Catalytic Titanium Anodes (CTAs) for copper electrowinning. For this work, anodes with IrO2 - Ta2O5 coatings were prepared in the laboratory with the same total coating loading but varying the number of layers by changing the speed of withdrawal in dip coating. A second set of CTAs were fabricated on niobium, Ti Grade 1, Ti Grade 7 and Ti Grade 36 metal substrates. All the anodes prepared in the laboratory were characterized using standard electrochemical techniques and subjected to accelerated life testing. It was found that the coating would not adhere to the niobium substrate, the grade of titanium had a minimal to no effect on the life of the anode, and it is observed that as the coating speed slows, there is an increase in the electrochemically active surface area of the coating which seems to directly contribute to an increase in the Tafel slope of the anodes. There was inconclusive evidence on the effect of coating speed on anode lifetime.INTRODUCTIONLarge scale hydrometallurgical extraction of copper has become widely practiced over the last 40+ years. The hydrometallurgical route entails leaching, solvent extraction and electrowinning. With the increasing desire to process refractory sulphides like enargite and chalcopyrite through the hydrometallurgical route, use of hydro-processing of copper is expected to remain high.In conventional electrowinning, copper is deposited on the cathode and an inert anode is used for oxygen evolution. Presently, the most common anode material is rolled lead-calcium-tin and the cathode is 316L stainless steel (Robinson et al., 2013). This lead alloy is fairly inexpensive and is robust, providing lifetimes typically of 4+ years. The main drawbacks of lead alloys are their relatively high oxygen evolution overpotential, the need for cobalt in the electrolyte to reduce their corrosion, the contamination of cathode product by lead, and the generation of harzardous by-products (Hiskey, 1999)."

Jan 1, 2016

By F. Tanaka

Copper losses to discard slag have long impacted on the profitability of copper smelters. Businesses based on the treatment of secondary materials have also revealed that copper losses are indices of precious-metals losses. Many custom smelters are thus required to obtain more reliable controls for reducing copper losses than ever before. Mitsubishi Materials Corp. has cooperated with academic research institutes in conducting research projects on the pyrometallurgical fundamentals of copper smelting systems, including mutual evaluation of magnetite behavior between synthetic and industrial slags. The state-of-the-art pyrometallurgy has subsequently been introduced to Naoshima smelter for controlling the Mitsubishi process. The revised controls function successfully and the operational results demonstrate that avoiding the discharge of solid magnetite from the S-furnace is quite effective to reduce copper losses. Magnetite behavior has been controlled over the Mitsubishi process so as to reduce copper losses while satisfying the needs of recycling businesses growing in Japan. In-situ estimation of magnetite behavior using the absorbed heat from the melts to cooling water will also be discussed.

Jan 1, 2007

By R. MacRosty

The demand to increase production levels in smelting furnaces has driven the increase in the power levels. Consequently, greater cooling capacity of the furnace shell has been necessary, resulting in the widespread use of water-cooled elements to protect the refractory linings. Since water ingress into the furnace is an explosion hazard, monitoring and maintenance of the water-cooled elements is of key importance. Some of Hatch's recent research and development efforts have been focused on methods to provide an increased level of monitoring of water-cooled furnace elements; this paper focuses on two technologies developed for this purpose. The first involves the installation of a fibre optic temperature sensor in a water-cooled tapblock. The sensor is capable of providing high accuracy temperature measurements with a fine spatial resolution throughout the tapblock. Hatch has already developed a diagnostic system that uses multivariate statistical analysis to interpret the large quantities of data generated by the sensor. A second technology under development is concerned with enhancing the operating integrity and safety through detection of leaks in the water circuits. A successful leak detection strategy requires minimal maintenance and the ability to detect minute leaks. An instrument that meets these criteria has been investigated and is currently under development. This paper focuses on the technology and results from the test work that has been completed to date.

Jan 1, 2007

By A. S. Knight

THE breaking and handling of ore is obviously the most important consideration when the layout of a new mine is contemplated. The problem must be attacked with due regard to the claim area of the property, the dip of the orebody, the anticipated percentage of payability, the width of the reef, and the amount of dislocation anticipated by dykes, faults, or sills. Among these, as far as East Geduld is concerned, the three most important items are: Area. 2,640.5 claims. Average dip 12° (from flat to 35°) Average channel width 36 inches. We are fortunate on the Witwatersrand in 'chat there is usually sufficient information available from surrounding properties to determine, within narrow limits, the factors mentioned above. With this information avail-able, the choice of layout is not limited, and it will be found that on the Witwatersrand each group has developed its own technique to suit its individual requirements. On East Geduld, the layout of the property for handling ore is known as the endless-rope haulage system. Following is a brief description of the general principles followed.

Jan 1, 1942

By J. I. Gazzarri

A model of solid oxide fuel cell AC impedance behaviour has been developed and is used to simulate the frequency response of a single cell with and without mechanical damage. The results indicate that the presence of mechanically induced damage within the components of a solid oxide fuel cell can be detected by comparing the frequency response of the undamaged cell with that of a cell in which in-plane cracking or delamination has occurred. The presence of such defects manifests itself as a new semicircle in the Nyquist impedance diagram of the full cell. A parametric study reveals the resolution capabilities of the method in terms of the geometrical characteristics of the defects.

Jan 1, 2005

By A. Quilodran, B. Jakovljevic, T. McCallum, P. Wong

"Rare earth separation by solvent extraction (SX) requires multiple separation plants each consisting of many extract, scrub, and strip stages to separate the individual metals. SX modeling advances have brought benefits to circuit design and process optimization by quickly narrowing test conditions without the need for exhaustive laboratory studies. Modeling can be used to optimize circuit configuration, O/A ratios, and acidities, which allows for CAPEX and OPEX savings. A comparison between pilot plant data and the results expected from modeling is presented for rare earth separations with CYANEX® 572.INTRODUCTIONRare earth separations can be difficult due to limited separation between the elements (Xie, Zhang, Dreisinger, & Doyle, 2014). This requires relatively complex solvent extraction circuits utilizing multiple extract, scrub, and strip stages as well as multiple SX configurations to achieve the desired metal purities. Designing rare earth circuits can be complex, and significant time and testing may be necessary to determine the required staging and optimal conditions.Circuit modeling for rare earth separations has been introduced to the industry using CYANEX® 572 extractant (Soderstrom, McCallum, Jakovljevic, & Quilodran, 2014). CYANEX® 572 is an acidic organophosphorus extractant formulation which has a weaker ligand-metal complex strength than that of the traditionally used phosphonic acid extractants. This allows efficient extraction while requiring a significantly lower acid concentration for stripping (Wang, Li, Zhao, Dong, & Sun, 2015). The reduced acid requirement in strip is expected to provide OPEX savings.The modeling can be utilized to quickly determine the required acidity and organic/aqueous (O/A) ratio for a given separation. It is also expected to reduce CAPEX requirements as optimal staging can be determined, and implemented.CYANEX® 572, combined with modeling, was utilized to produce a purified dysprosium (Dy) stream. To achieve this separation, multiple SX circuits were designed and operational conditions specified to separate Dy from the mixed rare earth chloride feed."

Jan 1, 2016

By A. O. Dufresne

A Step which, it is believed, will prove extremely beneficial to the Quebec asbestos-mining industry was taken during 1931, when the asbestos mine operators of the Province assembled to work out a uniform method of naming the products of their mines. The outcome of several meetings was the drawing-up of a classification which defined, limited, and designated anew the numerous grades of asbestos marketed. It entailed no drastic departure from the existing processes of grading, nor any revolutionary changes in methods of testing, but aimed rather to perfect existing methods. The classification proposed has been accepted by all operators in the Province, who, from January first of this year, began introducing the new nomenclature. Unless one is conversant with the properties and mode of occurrence of chrysotile asbestos, with the unique milling methods devised for its recovery, and with the history of the development of their technique, he may not readily understand the basis of the new classification. For information on these and other data concerning the industry, the reader is referred to a recent publication, Chrysotile Asbestos in (Canada, by James Gordon Ross, issued by the Mines. Branch of the Department of Mines, Ottawa. The object of this paper is to present briefly some of the phases in the evolution of the classification of Canadian chrysotile asbestos, in the hope that the recent effort to standardize the marketable products of one of Canada's most important non-metallic mineral industries will open a field for discussion, fruitful in new ideas and constructive suggestions. The necessity for the grading of asbestos results fundamentally from the fact that the price per ton depends on the length of fibre. At all times in the history of the industry, the very limited available supply of the longer grades, as well as the requirements of the trade, have caused relatively very high prices to be paid for fibre over half an inch in length, while for the shorter grades the price decreases rapidly, and at a rate which bears no proportionate relation to the length of fibre.

Jan 1, 1932

By K. G. Baxter, D. G. Dixon

The Sepon process plant utilises an autoclave to oxidize a flotation concentrate containing pyrite, residual copper minerals, and sulphur. The concentrate is produced from the residue of a preceding atmospheric copper leaching circuit. The function of the autoclave is to provide iron and acid for that atmospheric copper leaching circuit. The key issues in the operation of the autoclave are to maximise the production of acid and ferric ions and to avoid scaling issues related to sulphur balling in the autoclave. Scale control in the autoclave was examined using various dispersants and residue recycle without success. Operation of the autoclave at high temperature and high acidity addressed the scale issue through rapid oxidation of the sulphur and produced a ferric sulphate precipitate in the residue that could be re-leached to provide ferric iron. This paper presents the development steps followed, through batch and continuous piloting that resulted in an autoclave circuit design that addressed the above process requirements. Following definition of the process design basis, modelling of the autoclave operation was carried out to assist with engineering design. The model included thermodynamics and kinetics of oxidation of pyrite, elemental sulphur and covellite and also considered gas/liquid mixing, oxygen solubility as a function of temperature and solution composition, ferrous to ferric oxidation, gangue reactions with acid and precipitation/re-dissolution of basic ferric sulphate and alunite.

Jan 1, 2004

By Z. D. Hora

Sand and gravel resources of the southern coastal region of British Columbia may be linked to various episodes of Wisconsin glaciation. During Wisconsin and probably earlier times, the Fraser Lowland and coastal areas were subjected to repeated glaciations separated by non-glacial intervals. Each major glaciation was accompanied by isostatic and eustatic changes in sea level up to 200 m or more. As a result, the Lowland was covered by the sea during much of Quaternary time. Because the Fraser Lowland is surrounded on two sides by high mountain ranges, glaciers terminated in the sea during their maximum advance. Therefore, meltwaters released during deglaciation, together wit h retreating glacier ice, could produce widespread and extensive sand and gravel deposits both along the coast and throughout the Fraser Lowland and adjacent areas.

Jan 1, 1984