Search Documents

By L. R. Hougen

The Falconbridge Matte Leach Process yields high-purity nickel chloride by selectively dissolving nickel from copper-nickel converter matte with hydrochloric acid , purifying the solution by solvent extraction and crystallizing NiCl2 4H2O by further acidifying the purified leach liquor. In the Kristiansand Matte Leach Plant, a granular oxide is produced by high-temperature hydrolysis of the nickel chloride for subsequent reduction to a high-purity granular metal product, designated NICKEL 98. This paper describes the investigation of on alternate route to processing nickel chloride in which high-quality cathode nickel is produced by electrowinning from all- chloride electrolyte. The investigation was made in a pilot circuit containing two production-size electrowinning tanks operated in conjunction with the commercial-scale leach plant.

Jan 1, 1977

By M. A. Perras, H. A. Kasani, G. Walton

The development of an underground repository for the storage of spent nuclear fuel relies on a multi-barrier system to isolate the used fuel from the environment – ultimately, the biosphere. These barriers include engineered copper and steal canisters, dense bentonite, and the natural rock as well. In order to reduce the potential flow pathway along the excavation induced damage zone, various slots perpendicular to the excavation axis have been proposed. These slots are called cut-off seals and generally are filled with bentonite as it has high swelling potential and very low permeability. Many different geometries have been proposed, but clear guidelines on the selection of the optimum geometry have yet to be developed. In order to assess the optimum geometry, three shapes have been selected for this numerical study, including a trapezoid, a triangle, and a thin rectangular slot. The cut-offs were modelled for a conceptual shaft constructed in the Queenston Formation from Ontario over a stress to strength ratio that has been found at many underground research laboratories. It was found that the excavation of a triangular and thin slot cut-off had the smallest increase in the damage as quantified based on the extensile volumetric strain within the plastic yield zone. Both shapes showed an increase in the damaged zone by 13 cm at a stress to strength ratio of 2.75. The trapezoidal cut-off damage zone increased by 20 cm at the same stress to strength ratio. Further study is required to better define the optimum cut-off shape for wider variety of conditions and other geological formations.

Jan 1, 2020

By G. Lodewijks

This paper explores the savings that can be achieved in the energy consumption of belt conveyors used in mines by changing the conveyor components, the operational parameters of the system or the belt properties. First the concept of energy savings is introduced by looking at the energy consumption of belt conveyors from a theoretical point of view. Also methods for the calculation of the power consumption of a belt conveyor and the associated emissions are presented. Two case studies are presented in which the effects of the change of the operational parameters of the system, in this case the belt speed, and the belt properties, in this case the application of aramid products in the belt, are presented.

Aug 1, 2013

By S Sokhanvaran

Electrodeposition of silicon from a cryolite based electrolyte at a relatively low temperature (1000°C) is a promising approach to generate high purity silicon. In order to obtain fundamental data pertaining to electrowinning of silicon from Cryolite?SiO2 melts, density and electrical conductivity measurements were made. A range of temperatures and SiO2 contents was studied for each property. It was found that while density has an inverse relationship with temperature, the dependence for electrical conductivity is direct. Increasing silica content up to the saturation limit (~ 5 wt%) increases the density whereas further increase in SiO2, lowers the melt density. On the other hand, the conductivity is lower for the melts with greater SiO2 content, at any temperature.

Jan 1, 2011

By Gordon T. McKenna

"Syncrude Canada Ltd. is developing new concepts in lease-closure landscape design for its Oil Sands Leases 17 and 22 in northeastern Alberta. Closure planning is becoming an integral part of the planning cycles and of the lease operation. By incorporating closure planning into the day-to-day operation, the company will achieve acceptable lease closure in an economical manner. Ultimately, Syncrude will achieve lower operating costs through innovation in mine planning and a reduction in residual liabilities.New concepts being evaluated for lease-closure landscape design include: designing for closure, use of landforms and natural analogs, self-armouring bouldery ground, robustness in design, landform grading, terrain analysis of reclaimed land, geotechnical hazard assessments, choices in closure design timeframes, passive maintenance, determining post-closure monitoring goals, engineering tailings, engineering other substrates, use of test plots and field demonstrations, geomorphologic monitoring of reclaimed lands, defining closure goals, and visiting other mines. These concepts are being formalized under the new discipline of Landscape Engineering."

Jan 1, 1996

By Wm. D. Jr. Sheldon

THIS paper presents practical data to aid in the selection of a mine ventilating fan, and outlines considerations to be made to ensure satisfactory operation and optimum efficiency of the fan. Much has been published on the general subject of mine ventilation, but the writer has found few specific data on factors and considerations which govern the selection of a fan-data which should be available to the operator if his fan is to give satisfactory service within the range of the high-efficiency portion of its performance curve and deliver the specified air capacity when operating against the anticipated range of resistance of the mine. The total quantity of fresh air furnished by the ventilation system must be adequate to provide, and to ensure at all times, safe and healthful working conditions in the mine. It is assumed that the mine operator is able to determine the air quantities required for the various parts of the mine.

Jan 1, 1941

By S. Hunt, S. Jayasekera, J. Kyle, N. Perera, K. Stone

A preliminary investigation has been conducted to determine the conditions for the precipitation of phosphate from the liquor produced after a hydrochloric acid pre-leach and rare-earth recovery from a rare earth containing fluorapatite concentrate from the Nolans rare earth deposit in the Northern Territory of Australia. The results show that at 50oC the phosphate can be precipitated in two stages using limestone to produce a Stage 1 precipitate containing most of the impurities including iron (94%), aluminium (92%), fluoride (98%), uranium (84%) and thorium (94%), followed by a relatively pure Stage 2 dicalcium phosphate precipitate (DCP) containing only 0.05% Fe, 0.05% Al, 0.1% F, 0.01% U, and <0.01% Th. The initial Stage 1 precipitate contained about 25% of the phosphate while the remaining 75% reported to the Stage 2 phosphate precipitate. Depending on the required radioactivity specifications, the amount of phosphate in the Stage 1 precipitate could be reduced. Reagent requirements were 11.4 kg limestone (as pure CaCO3) per cubic metre of solution for the Stage 1 precipitate and 39.7 kg limestone (as pure CaCO3) per cubic metre for Stage 2. The analysis of radionuclide balance indicated that radionuclides deported mainly to the final filtrate (86.4%) compared to Stage 1 precipitate (5.4%) and Stage 2 precipitate (8.2%). Settling and pressure filtration tests indicated the precipitates were both readily settled and filtered. The final moisture contents of the Stage 1 and Stage 2 precipitates were 62.5% and 49.3%, respectively.

Jan 1, 2014

By B. Fang

Electrochemical behavior of an X-80 pipeline steel, including frequency-sweep electrochemical-impedance spectroscopy (EIS), time-sweep EIS at a constant frequency and open-circuit potential (OCP) monitor, was investigated using four-point bending specimens subjected to a stress-corrosion cracking (SCC) test in a near-neutral pH environment, The capacitive loop became smaller with test duration, revealing an increase in the corrosion rate, The resistance obtained in the constant-frequency EIS test showed two regions, of which the region with a remarkable decrease in resistance transformed into a region of slow decrease, whereas the capacitance increased with test time indicating that iron dissolution was fast at first, and then a corrosion product or film formed and covered the surface, leading to the pitting formation.

Jan 1, 2005

By L. R. Fyffe, D. R. Lentz, S. H. Mcclenaghan

"Abstract - The Eel River area in the southwestern Miramichi terrane of New Brunswick contains a complete calc-alkaline suite of volcanic rocks that are interlayered with intervals of sedimentary and polylithic fragmental rocks, and are overlain by a thick sedimentary sequence. This package, collectively referred to as the Meductic Group, was deposited in a submerged volcanic arc setting interpreted to be part of the Popelogan arc. Rifting of this arc led to the development of the Tetagouche-Exploits back-arc basin, and formation of volcanogenic massive sulfide deposits in bimodal volcanic rocks of the Bathurst Mining Camp in the northeastern Miramichi Terrane. Unlike the Bathurst Mining Camp, volcanic rocks in the southeastern Miramichi Highlands form a continuous calc-alkaline suite characterized by increasing Zr/TiO2 with increasing SiO2, in part resulting from progressive coupled assimilation and fractional crystallization of nested magma systems. Slumping of semi-consolidated volcanic and sedimentary rocks in topographically unstable areas resulted in numerous slumps and debris flows that are preserved throughout the Eel River area. In the early 1990s, the discovery of a large sulfide clast in a road cut along the Benton road sparked interest in the volcanogenic massive sulfide potential of the Eel River area. Subsequent drilling intersected smaller fragments, one clast of which graded 16.7% Zn, 5.6% Pb, 90 ppm Ag, and 220 ppb Au. The intersection of thin lenses of stratiform sulfides in another drillhole indicates favorable conditions for the preservation of massive sulfides. Their subsequent incorporation into synvolcanic debris flows resulted in the transport and deposition of sulfide clasts from hydrothermal vents to more distal locations. Similar to the Buchans deposits of Newfoundland, tracing these debris flows back to their source would be beneficial from an exploration perspective. Approximately 15 km to the southwest of the Eel River area, gold-bearing base metal sulfide clasts (11.1% Zn, 6.13% Pb, 0.19% Cu, 108 ppm Ag, and 1100 ppb Au) occur within intermediate-composition volcanic rocks at Monument Brook in eastern Maine. Sommaire - Le secteur d’Eel River dans le sud-ouest de la terrane de Miramichi au Nouveau Brunswick contient une séquence complète de roches volcaniques calco-alcalines interstratifiées avec des roches sédimentaires et fragmentaires polylithologiques, sous une épaisse couverture sédimentaire. Cet assemblage constitue le Groupe de Meductic, et a été déposé dans un environnement d’arc insulaire interprété comme une partie de l’arc de Popelogan. Le rifting de cet arc à mené au développement du bassin d’arrière-arc de Tetagouche-Exploits, et à la formation de gisements de sulfures massifs volcanogènes dans les roches volcaniques bimodales du Camp Minier de Bathurst dans le nord-est de la terrane de Miramichi. Contrairement au Camp Minier de Bathurst, les roches volcaniques des hautes terres du sud-est de Miramichi constituent une suite calco-alcaline continue caractérisée par un accroissement du rapport Zr/TiO2 à des valeurs croissantes de SiO2, résultant en partie de l’assimilation progressive et de la cristallisation fractionnée de systèmes magmatiques superposés. L’effondrement de roches volcaniques et sédimentaires semi-consolidées dans des secteurs topographiquement instables est à l’origine des nombreux slumps et coulées de débris qui sont préservés dans le secteur d’Eel River. Au début des années 1990, la découverte d’un large claste de sulfures le long de la route Benton provoqué un intérêt pour le potentiel en gisements de sulfures massifs volcanogènes dans les secteur d’Eel River. Des forages ont par la suite recoupé des fragments plus petits, dont un claste qui a retourné des teneurs de 16.7% Zn, 5.6% Pb, 90 ppm Ag et 220 ppb Au. Le recoupement de minces lentilles de sulfures stratiformes dans un autre forage indique des conditions propices à la préservation des sulfures massifs."

Jan 1, 2006

Arsenic bearing minerals such as enargite (Cu3AsS4) and tennantite (Cu12As4S13), which may associate with major copper minerals such as chalcopyrite (CuFeS2), chalcocite (Cu2S) and bomite (Cu2FeS4), usually report to the copper concentrate in conventional flotation due to their similar flotation properties. Arsenic in a copper concentrate causes environmental problems and also problems in the subsequent pyrometallurgical process. Voltammetric studies were carried out to investigate the oxidation characteristics of enargite, tennantite, chalcopyrite, chalcocite and bomite. Contact angle measurements and micro-flotation tests were conducted to examine the flotation characteristics of enargite and chalcopyrite under controlled pulp potentials. Selective flotation of enargite from chalcopyrite under varied pulp potentials was conducted to investigate the feasibility of arsenic removal from a copper concentrate. The test results indicate that the non-arsenic bearing copper minerals ( chalcopyrite, chalcocite and bornite) were easier to oxidise than arsenic bearing minerals ( enargite and tennantite) in an alkaline solution. Enargite floated well at a potential as high as +0.45 V vs. SCE while chalcopyrite was completely depressed at a potential higher than +0.43 V vs. SCE. Selective flotation revealed that enargite can be successfully removed from chalcopyrite through controlling the pulp potential at +0.30 ~ +0.50 V vs. SCE.

Jan 1, 2007

By W. Mueller, M. Rocheleau, E. Dimroth

The paleogeographic evolution of the Abitibi Belt is subdivided into three phases, namely: 1) a phase of the growth of a submarine volcanic chain, 2) a phase of the emergence and growth of volcanic islands and 3) a phase of uplif t and erosion of volcanic islands. Isostatic calculations suggest that the volcanic sequence in the south of the Abitibi Belt rests on oceanic basement or on the mantle; the volcanic sequence in the north of the belt rests on about 13-14 km of tonalitic basement. 10-15 km of plutonic material accreted to the volcanic islands during paleogeographic phases 1 and 2, and caused the uplif t during paleogeographic phase 3.

Jan 1, 1984

By D. E. Macdonald

"Approximately 2.0 million tonnes of phosphate rock is imported from the U.S. to Alberta annually and is used in the production of agricultural fertilizers. No phosphate rock is presently mined in Canada, although sources of igneous phosphate have been mined in the past. Sedimentary phosphate rock is found in nine geological units within the Cordilleran Foothills and Front Ranges region of Alberta. The Devonian-Mississippian Exshaw Formation, Permo-Pennsylvanian Rocky Mountain Supergroup, and the Jurassic Fernie Formation have the best potential f or future development. Most of the phosphate rock in Alberta is of low grade and lies within restricted land use areas. The best over-all resource potential lies in the Fernie basin area of southeastern British Columbia, in the Fernie Formation. The possibility of deep phosphate rock deposits in the plains region should be examined.Phosphate rock is mined in Idaho, Utah, Montana and Florida, and is shipped to Canadian fertilizer plants for processing. Raw phosphate rock is acidified, usually with sulphuric acid, by a wet process. Varying amounts of ammonia are added, and the fertilizer is pelletized. Future research, in western Canada, is needed in the beneficiating of low-grade ores and in the area of in situ mining. At the present time, phosphate rock sells for around US$50Itonne, and Alberta fertilizer companies probably pay in the range of C$7D-$85Itonne for U.S. phosphate rock delivered to the plant. Environmental concerns about phosphate rock processing are centred around gypsum tailing ponds, and radioactive wastes.U.S. supplies of phosphate rock are secure until the year 2000; however, by this time, the richer deposits in the U.S. may be exhausted. Alternate deposits, such as the ones in Alberta and British Columbia, might then be considered. Phosphate byproducts, such as uranium, vanadium, fluorine and rare earth elements, may help in making the processing of low-grade Canadian phosphates economically feasible."

Jan 1, 1988

By John Canterford

Quay Magnesium Limited (QMG) listed on the Australian Stock Exchange in late September 2004 having raised approximately A$30 million with the object of designing, constructing, commissioning and operating a 15,000 t/a magnesium alloy production facility in Nanjing, China, Site construction commenced in February 2005 with installation of all major components completed by the end of October 2005, Hot commissioning was simultaneously commenced with the final stages of installation, leading to the first stage of continuous ingot casting by mid November 2005, Since that time ramp-up to the name plate capacity has been undertaken, This presentation highlights some of the more significant technical and logistical hurdles that have had to be overcome in order to meet the high quality product specifications required by a range of QMG customers.

Jan 1, 2006

By M. Rizwan

Mine workings are progressing to greater depths as shallow mineral resources are being depleted, and civil engineering projects are nowadays being developed at substantial depths. The threat to tunnel stability posed by rockburst events has increased as a result of these high stress environments. Rockbursts are violent events capable of mobilizing large volumes of rock. In addition to the threat to safety and equipment, rockburst damage can significantly impact on operations, and cause loss of mining production, often the largest cost component of such events. Rehabilitation of such damage requires significant effort and resources. Tunnel walls and roof are usually well supported, but the installation of rock support in the floor is uncommon, particularly in mining environments. In the absence of rock support, floors of the excavations are vulnerable to rockburst damage. New concepts for containing damage of excavation floors by dissipation of the large transient forces using simple techniques or preselected and designed elements of sacrificial floor systems are presented. Two approaches to calculate the demand are presented: estimating load demand by assuming displacement levels and a response modification factor; and using a limit displacement approach to calculate elastic stiffness of the selected elements of the sacrificial support system. The proposed conceptual support systems have the capability of dissipating rockburst energy while retaining sufficient serviceability. It is considered that the concepts presented, for discussion, in this paper are logical and developable into practicable and economic solutions for tunnel floor support in rockbursting environments.

Jan 1, 2015

By J. A. Finch

For base metal sulphides, iron rejection starts in mineral processing. This review focuses on the changes in plant practice specifically to improve iron sulphide rejection by controlling contaminant ion effects and discusses selected innovations in mineral processing that can be expected to play a role in iron control. One change to control contaminant ions is size reduction (the use of stage grinding and inert stirred milling) and another is system chemistry (order of reagent addition and exploitation of the flexibility of sulphoxy species). Plant examples illustrate the successes, and indicate that there are several options available. The general innovations consider the new tools for measuring gas dispersion properties and quantifying froth characteristics from images. Examples of their application to improve concentrate quality illustrate the potential. Other innovations adapt geostatistics to model variations in ore flotation response to provide feed forward control and rigorously apply the statistical experimental methodology in plant test work. An example from one concentrator shows that significant improvements to reduce the iron content of concentrates can be achieved by applying these basic principles.

Jan 1, 2006

By B. Zeifert, C. Martínez-Morales, A. Romero-Serrano, A. Pineda-Rivera, H. Martínez-Gutiérrez, G. Diaz-Sandi

In this work, the effects of CaO/SiO2 ratio and the FeSO4 and FeS2 contents on the stability of the mineralogical species in chromium-based slags were studied. The chemical stability was evaluated by leaching with an acid solution. The main Cr-compounds in slags with FeSO4 and CaO/SiO2=1 were FeCr2O4 and Ca3Cr2Si3O12, while Cr3S4 predominated in slags with FeS2. The slags with CaO/SiO2=2 mainly contained CaCr2O4. The highest Cr concentration levels in the leaching liquors corresponded to slags with CaO/SiO2= 2, and the lowest Cr concentration corresponded to slags with high FeSO4 or FeS2, owing to the stable binding of chromium in the compounds FeCr2O4, Cr3S4 and FeS•Cr2O3.

Jan 1, 2011

By T. Alan O'Hara

"The decision to invest capital in developing a mine and constructing a mineral processing plant and services is usually made after a feasibility study shows &apos;that the estimated future cash flow from mine operations will yield an adequate return on the estimated capital expenditures.The actual return on investment may differ substantially from that estimated in the feasibility study, because of the probabilities of errors in estimating capital costs, ore reserves, operating costs, mineral revenue and operating productivity. This paper outlines the R.S.S. (root sum of squares) risk analysis procedure of computing the overall probability of the actual project D.C.F. (rate of discounted cash flow), differing from that estimated in the feasibility study.Variation in Project D.C.F.It is assumed that a feasibility study of the project has been completed which has defined the estimated values for all the project parameters, such as ore reserve tons and grade, capital cost, concentrate recovery, metal revenue, daily milling capacity and operating costs.The financial analysis of the mining project will have determined that the cumulative cash flow will yield an expected D.C.F. on the capital cost if all project parameters attain the estimated values. If, however, the actual value of any parameter varies from that estimated, the actual project D.C.F. will vary from the estimated D.C.F. Risk analysis methods attempt to determine the overall effect of probable variations in the estimated values of all project parameters on the D.C.F. of the mining project. This overall effect is expressed as a probability profile, which shows the likelihood of actual D.C.F. values greater or less than that estimated.Thus, a completed risk analysis of a mine project, with an expected D.C.F. of 15.51%, would display the characteristics shown in the preceding diagram."

Jan 1, 1982

By L. C. S. Dharmasiri, S. M. Shin, A. Senaputra, J. S. Sohn, K. H. Park, J. Avraamides

Reducing agents can be applied to leach metal values from natural and secondary resources such as laterite ores and deep sea manganese nodules and recycled materials such as spent batteries / catalysts which contain high-valent metal oxides of manganese, cobalt and iron. Selective leaching of some metals can be achieved by selecting conditions to control the saturated solubility and dissolution rates of metals from oxides or mixed metal/oxide matrices. The leaching results are rationalized on the basis of chemical species, Eh-pH diagrams and heterogeneous kinetic models. The role of reducing agents such as hydrogen peroxide, sulfur dioxide and iron(II) sulphate, in acid, alkali and in the presence of complexing ligands such as ammonia for the improvement of the leaching of metal oxides and metals is discussed. Previous studies on acid leaching of metals from nickel laterites, manganese nodules and spent catalysts/batteries in the absence or presence of reducing agents show that the rate controlling step involves the diffusion of protons through a thickening product layer on the particle being leached. It is shown that the leaching of nickel and cobalt from manganese nodules and zinc-carbon batteries in ammoniacal sulphur dioxide solutions also obey shrinking core kinetics.

Jan 1, 2014

By Doug Barnstable

"Quinsam Coal Ltd. is assessing the potential of developing a thermal coal deposit near Middle Quinsam Lake on Vancouver Island. The coal reserve outlined is classified as a high-volatile, bituminous ""A” steam coal and is composed off our separate seams of varying quality within the Late Cretaceous Comox Formation.Open-pit mining methods will utilize a walking dragline and a truck / shovel module as the primary stripping tools. Following washing and mechanical drying in a Baum jig preparation plant, the coal will be transported to the proposed dock at Campbell River for shipment via 55, OOO-DWT vessels to world markets. The paper will outline the development and status of the project to date. IntroductionQuinsam Coal Ltd. is a joint venture of Weld wood of Canada Ltd. and Luscar Ltd . The participants propose to develop a thermal coal mine in the Middle Quinsam Lake area, 17 miles inland from Campbell River on Vancouver Island (Fig. I). By acquiring all the assets of Canadian Collieries in 1962, Weldwood also came to own the coal rights of the area proposed for development. Luscar Ltd . ha s been designated as project manager until completion of construction and thereafter will act as operator of the mine.Surface mining methods will be used to produce approximately 1.0 million short tons of coal annually from the Quinsam property. Seven separate mining pit s will be developed along with the supporting minesite facilities, including a proper paration plant. Transportation routing to Campbell River and the establishment of docking facilities will be required. The initial economic life of the mine is 12 years, with the provision to extend this in the future by developing higher-ratio, auger or underground reserves."

Jan 1, 1980

By Edward Martinez

Due to its unique properties, chrysotile asbestos is used in many diversified applications. In recent years, a better understanding of the structure and properties of chrysotile has evolved due to the research efforts of many investigators. A summary of the results of some of these investigations is given. An attempt is made to show the relationships between the properties of chrysotile and its crystal structure. Examples taken from the literature are cited in which methods have been developed for modifying the properties to improve the performance of asbestos in some applications. These include the effect of pH on the positive zeta potential and the addition of sodium silicate to improve filtration characteristics. The dehydroxylation and formation of forsterite when chrysotile is heated are also discussed.

Jan 1, 1966