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By Lawson F

The leaching behaviour of BHAS copper matte in oxygenated acidic sulphate chloride solutions at 85¦C has been studied using samples containing 34% copper, 41% lead and 12% sulphur. Copper sulphide in the matte, essentially Cu2S was found to leach in two distinct stages. Similar to the behaviour of pure chalcocite, copper dissolution in the first stage was affected by the availability of oxygen in solution. The presence of chloride ions in the leachant was essential if there was to be any leaching in the second stage (which usually commenced after about 40% of the copper had been taken into solution). Lead sulphide in the matte was oxidised to lead sulphate and formed a shell around the partially leached matte particles. Electrochemical studies showed that this lead sulphate and/or sulphur produced during leaching can form a passivating layer around the copper sulphide. However, this layer was disrupted when chloride ions were present. A Plackett-Burman analysis was used to determine the species in the recycled leach solution that affect the leaching of copper. Under the experimental conditions used, in the first stage the rate of copper dissolution was influenced by the concentrations of sulphuric acid, Zn(II), Cu(II), Fe(III) and Cd(II). In the second stage, the rate was futher modified by the concentrations of Cl(I) and As(V) ions. In solutions of low acidity and high As(V) concentration, insoluble copper arsenate formed which coated the partially leached matte particles and acted as a barrier to futher reaction.

Jan 1, 1989

Copper entering a lead ,smelter in concentrate or from other sources is recoVered as matte and speiss which contain appreciable quantities of lead. The matte and speiss are usually sold to copper smelters to recover the copper content and also any gold and silver in these products, but the value of the lead is largely lost. Some copper plants pay for portion of the lead content, but regarded as a means of recovering lead it is more costly and less efficient than if the lead were recovered at the lead smelter.Because of the value of this lead loss, the metallurgy of copper recovery has assumed greater importance in recent years owing to the rise on the price of lead.Two processes are in use today to produce matte and speiss, namely the iron matte process and the soda matte process developed by the American Smelting and Refining Co. 1 in D.S.A. The latter process is characterised by a higher copper to lead ratio than the older iron matting process.The following analyses are typical of matte and speiss produced at Broken Hill Associated Smelters, by both processes, although the soda matte process is still in a developmental stage and experience indicates that matte and speiss of lower lead tenor can be produced under favourable conditions.

Jan 1, 1951

By S Furman, M Caccetta, A Hacket, B McDonald, M A. Wells, D Lau

In 2004, the Western Australian Department of Industry and ResourcesÆ Burrup Rock Art Management Committee commissioned a number of independent scientific studies to evaluate the condition of rock art in the Burrup Peninsula near Karratha (Western Australia). These studies are evaluating the physico-chemical aspects of the effect of environmental modification on the visible appearance of the rock art. Because of the cultural significance of the sites, the research approach has been to employ non-destructive testing strategies and work in the field has progressed with respect for the importance of the area. This paper only reports the spectral mineralogy monitoring at each of the sites to evaluate whether changes in mineralogy are observed on rock surfaces. Reflectance spectroscopy is a non-destructive, in situ materials characterisation technique that provides information about the mineralogy. The minerals detected include haematite, kaolinite, chlorite, goethite, gibbsite and manganese oxides. Current results indicate that the surface mineralogy of the rock art has not changed in the last four years.

Jan 1, 2008

By D Lau

Traditionally X-ray diffraction (XRD) has not been significantly used by the cultural heritage sector, as the most commonly used technique, X-ray powder diffraction (XRPD), requires sample removal from the artwork or artefact, followed by grinding of the sample to a fine powder. With the development of micro-X-ray diffraction (micro-XRD) and other associated advances, non-destructive, in situ analysis of crystalline pigments on micro-areas of paintings and artefacts has become possible. This is illustrated with the application of this technique to the in situ analysis of propriety paints, paint cross-sections and small paintings. However, workers have noted that XRD can be insufficiently sensitive with pigment mixtures, due to matrix effects. This study obtained X-ray diffractograms of 17 single pigment preparations and determined relative amounts of crystalline content. The purity of single pigments was compared with Joint Committee on Powder Diffraction Standards (JCPDS) database diffractograms. The impact of pigments with high X-ray absorption coefficients on the detection limits of pigments with low X-ray absorption coefficients was further investigated by building on work done with the chromium oxide-zinc oxide series with the preparation of a second series of binary mixtures of zinc oxide (which has a high absorption coefficient and is almost fully crystalline) and ultramarine blue, which has a lower absorption coefficient but which is more crystalline. Semi-quantitative analysis, where baseline and absorption factor corrections are made, confirm detection limits as low as five per cent for chromium oxide and ultramarine blue when in a binary matrix with zinc oxide. However, this type of analysis is very time consuming. So in order to theoretically simulate issues that will be encountered with binary pigment mixtures, the single phase diffractograms were used to theoretically investigate the matrix effects of the three white pigments with the various coloured pigments. This illustrated that detection limits can be as low as five per cent or in non-ideal conditions, such as with partial peak clashes or where there are large differences in relative peak intensity, as high as 50 per cent. These results have significant implications for the analysis of painted surfaces on artworks or artefacts. It has been demonstrated that ideally this method is more suited to the investigation of surfaces where there is minimal mixing of pigments or where there is not a significant difference between the absorption coefficients of the mixed pigments.

Jan 1, 2008

By Tran T

The kinetics of cementation of silver chloro-complexes from sodium chloride solutions onto copper and zinc was studied using rotating disc electrode system. The activation energies were found to be 10.8 and 30.5 k7/mole, in a 3M NaCl solution on copper and zinc discs, respectively. Higher dissolution factors were obtained on zinc disc, due to hydrogen evolution, whereas, copper dissolved close to the predicted values. Scanning electron microscope studies were conducted both on copper and zinc- cdiscs-to evaluate the deposit morphology and its effect on reaction kinetics. Two stage deposit growth was observed both on copper and zinc discs. Smooth, coherent initial deposit followed by tree-like secondary dendrites formed on copper, whereas, scattered bulbous initial deposit followed by porous dendrites was typical on zinc disc.

Jan 1, 1992

By Kuster D

Under humid conditions geochemical exploration for rare-metals is, at the reconnaissance level,usually carried out by stream sediment and soil sampling. As the secondary dispersion patterns are distinctly different in arid environ- ments, other exploration methods have to be applied (MATHEIS & KOSTER, 1985).

Jan 1, 1988

The on-going technical developments to enhance the productivity and cost effectiveness of large blasthole drills incorporate many of the blasthole drilling operating experiences garnered over the past half century.Those experiences have shown in part that on a drill unit with good quality structural elements the higher the percentage of the electrical and electronic components designed into the product, the higher its productivity and the lower its operating cost.

Jan 1, 1992

By Lovett EP, Johnson CR, Dunlop GA

Seven streams of a low tonnage pilot plant operation on Cu/Pb/Zn ore from the Golden Grove Project were continuously assayed using an AMDEL In-Stream Analysis (ISA) system. The ISA instrumentation is briefly described as is the calibration procedure employed. The successful application of this instrumentation in the dynamic environment of a pilot plant operation is discussed. The operational sequence of the Golden Grove pilot plant is outlined along with the original project objectives and how they were achieved by the implementation of ISA. Results for the different complex flowsheets used are discussed, followed by the perceived benefits of installing such equipment in this operation.

Jan 1, 1986

By Tomlinson R. C

The paper will briefly describe planning in the National Coal Board (NCB) and the contribution that operational research makes to it. It will then give details of some of the models in use and will finally consider critically the problems of looking ahead to the next century.

Jan 1, 1977

By Woodlands W. K

A 3D graphics modelling system has been applied to longhole stope ring design at Z.C. Mines, Broken Hill, NSW. This has been in operation for a four month period (January, 1988). The purpose of this application was to provide computer assistance to mine planning engineers and blasthole design draftsmen for the longhole design process, particularly by: 1. reducing the- volume of tracing, drafting and geometric manipulation which is a significant feature of the manual design process, 2. providing additional design drawings to enhance the conception and implementation of stoping design.

Jan 1, 1988

Dealing with Aboriginals and various others purporting to represent them has become part and parcel of exploration and mining in Australia, whereas 20 years ago it was not. The author has been involved in dealings with Aboriginal groups over this period. The following paper is a summary of the social background to such dealings and a compendium of rules for the newcomer to this aspect of the resource industry.

Jan 1, 1990

Spiral separators have been used to treat heavy mineralsands in Australia for some 35 years. During the last five years the logical extension of this technology has been torecover cassiterite from alluvial deposits. Plants incorporating spirals are already operating in Indonesian andAustralian tin mines. A more fundamental understanding of the design of spiral separators has recently led to their use in other mineral treatment plants.In particular, the treatment of alluvial gold and fine coal has been most successful. The new generation of spirals that has been developed to treat these minerals is more easily operated than other competing processes and is therefore ideal for new mine situations.

Jan 1, 1986

As the mining sector increasingly embraces the sustainability agenda, and implements thorough environmental reporting in support of its case for a continued æsocial licence to operateÆ, there is a need for ever-clearer metrics for key areas of impact. It is clear that natural waters are both the predominant pathway and main recipient of the environmental impacts of mining. A new approach to summarising the impacts of mining operations on water quantity and quality is proposed, adapted from an existing generic framework, which is increasingly used to quantify the æwater footprintsÆ of cities and nations. This includes both direct water use and ævirtual waterÆ use, implicit in goods and services used by the mine. In contrast to the existing formulation of æwater footprintÆ, it is here argued that it makes hydrological sense to express the water footprints of mines in areal terms, as equivalent catchment areas. It is also important in the mining sector to capture systematic changes in the scale of impact, which can be anticipated and predictively quantified over the full life cycle. This includes the essentially infinite post-closure phase, during which æremanent water consumptionÆ occurs, either through physical water loss (eg by evaporation from pit lakes) or by ongoing contamination of sizeable flows of natural waters. Methods for assessing the water footprints of mines are now available, and the time is increasingly ripe for them to be applied in earnest in environmental reporting. An example application to a mine in a humid subtropical area of South America is presented. In that case, the mine site itself extended over 106 ha, whereas the maximum water footprint exceeded this by a factor of 27. Although the water footprint can be expected to decline by a factor of ten immediately after closure, sustained evaporation from pit lakes and tailings dams with water covers will gradually increase the remanent water consumption rate, such that the final post-closure water footprint remains about 25 per cent of that encountered during the peak of mining.

Jan 1, 2006

By J H. Baker, P G. Beadle, J P. O&apos, Brien

In 1974 a preliminary study of the refractories industry in theRepublic of Indonesia was completed by Crown Lynn Consultants, a subsidiary of Cerarnco Ltd., on behalf of the Indonesian and New Zealand Governments. As a result of recommendations arising from that study the two Governments commissioned, in 1976, as a Bilateral Assistance project, an investigation into the potential of the refractories industry in Indonesia. Ceramco Ltd., was retained to carry out the study on behalf of the New Zealand Government. The Directorate-General of Chemical Industries, Directorate of Silicate Industries administered the project on behalf of the Indonesian Government. Indonesian counterparts to the New Zealand study team were provided by the Directorate of Silicate Industries.

Jan 1, 1978

By Smith P

The past 20 years have seen the replacement of hydraulic control of longwall mining systems by the neater. smaller and better controlled electronic units.Early problems of moisture and other effects on reliability were overcome to see electronically controlled supports chosen for Corrimal Colliery ten years ago. Lessons from Corrimal and elsewhere, with following improvements and sophistication led to wider use as exemplified by Meco and other electronically controlled supports used in more recent installations in New South Wales, Queensland, USA and Czechoslovakia of the total of over 80 electronically controlled support installations worldwide in the past decade. Present work is toward a fully "integrated face" of British Coal by 1993, incorporating the Meco automatic face straightening system already due for practical use in the UK later this year. However the manless face still appears to be some way off although the present minimum crews and close monitoring, including early warning, are promising stages.

Jan 1, 1991

A large scale distributed process con-trol system has been successfully applied to the automatic control of aluminium reduction cells at Boyne Smelters. A three stage hierarchy of minicomputers and microcomputers is used to continuously monitor and control conditions in each cell and to manage the data generated during the process.The automation hardware was purchased on the basis of low cost, high reliability, prior use in the aluminium industry and a high level of backup under failure conditions. The hardware has met performance criteria to date.The process control strategies have continually been updated to minimise the energy and raw material consumptions in each cell. A major change to systems software has recently been made to decrease the development time for-future changes. Various low energy potline retrofit alterations are currently being investigated requiring significant changes to the process control strategies.

Jan 1, 1985

By K-S Kim, C-Y Kim, D-G Kim

In tunnel construction or other underground construction, a detailed knowledge of the rock mass ahead of the face is essential for both safety and efficiency of work. Many tunnel collapses have been reported to occur because of lack of appropriate information, such as the geological conditions ahead of the tunnel face. One of the methods which can identify rock mass conditions is the application of drill monitoring data obtained from blasting drill holes, which can detect abrupt and unexpected changes in ground conditions, geological structure and the mechanical and physical properties of rock mass. This paper presents a new approach to how drill performance parameters can be used for prediction of geological conditions ahead of tunnel face. The predictions are based on monitoring the drill parameters of instantaneous advance speed, torque and tool pressure. In order to assess conditions ahead of tunnel face, tunnel seismic profiling (TSP) and a horizontal boring investigation were undertaken and the obtained data compared to the drilling data. The predicted results using drilling performance parameters correlated well with geological conditions ahead of tunnel face.

Jan 1, 2008

The patented "Epytensic" pump of Minnovation Ltd, a multiple piston pump, is used widely on shearer loaders and by partial high pressure watcr jet cutting strategically in relation to cutter picks not only improves cutting rates, but saves power and increases the life of gearboxes and picks, as well as improving dust suppression. The "Face Side Pump", also a piston pump, located on the ranging arm gearhead has advantages over gateroad pumps and shearer body pumps. The "Extraction Drum", hydraulic air mover system, linked with the above innovations and high pressure water, have further advantages in methane and dust removal. Some modifications providing these systems need workshop applications but most are possible underground with minimal changes to shearer profiles and advantages of minimising hosing, along with the other advantages stated.

Jan 1, 1991

By Chilman G. F, Lean P. J

The New Broken Hill Oonsolidated LImited (NBHC) concentrator was commissioned in 1952 and underwent a number of expansions over the next 25 years. In 1978, the decision was taken to expand further from 1.20 million tonne/yr to 1.43 million tonne/yr. This increase necessitated a substantial modification to an already over-taxed grinding circuit. The circuit consisted of rod mills, ball mills and rake classifiers. Plant data of grinding mill performance was obtained to develop mathematical models of individual units that could be combined to simulate total circuit performance in a number of configurations. The data provided further illustration of the validity of the perfect mixing model for relatively small increments of ball mill scale-up.

Jan 1, 1983

One of the most frequently asked questions at the feasibility study stage of a project is, æhow big can one go?Æ This important question effects costing and efficiency of metallurgical equipment, the real estate required and the operating plant strategy.The presentation covers both engineering and process considerations and explains the limits that exist today and explores future trends.The paper is specific about large slurry application usually found in gold applications; however, it could apply to silver and uranium or other dense media leach duties.Agitator drive sizes are examined as well as process risks associated with large tank agitation. New technology has increased the maximum tank size and designers are now experienced in tank volumes in excess of 5000 m3. Tanks of 6000 m3 have been agitated and 10 000 m3 tanks are within present engineering know-how and scale-up.Fabrication techniques for shaft and impeller designs exceed the existing standards and new specifications will be needed to cover large mixer design. The paper covers certain aspects of mechanical design and proposes alternative standards that are more appropriate. Process considerations such as fluid natural frequency as well as typical superficial velocities for efficient operations are examined. Scale-up techniques based on existing and new technology are also examined to ensure a successful installation.The presentation therefore covers the majority of large mixer design questions that are frequently asked.

Jan 1, 2006