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The Effect of Bulk Iron Concentration on the Copper Activation of Sphalerite at pH 9

Sep 13, 2010

By Junji Shibata

Keywords: Synergistic effect, Solvent extraction, Nickel ion, extractant mixture Waste solution from the Ni non-electric plating process contains 4.0 kg/m3 Ni (II), 0.1 kg/m3 Fe (III), 0.01 kg/m3 Zn (II), 48 kg/m3 SO42-, 98 kg/m3 HPO32- and 31 kg/m3 lactic acid as a typical composition. Solvent extraction, cementation, ion exchange resin and precipitation methods may be used for the treatment of this kind of solution. In this study, solvent extraction of Ni (II) is investigated by using two kinds of extractants in order to clarify the relationship between extraction equilibrium (static synergistic effect) and extraction rate (dynamic synergistic effect) for several extractant mixtures. The static synergistic effect does not take place significantly for the extractant mixtures of acidic extractants and neutral organphosphorous compounds, while a large static synergistic effect is confirmed when the extractant mixtures of acidic extractants and nitrogen-containing compounds are used. Nickel ions can be extracted in the wide pH range of 3.0-8.0 without any pH adjustment by using the several extractant mixtures. At the same time, the extraction rate remarkably increases by using the extractant mixtures of acidic extractants and nitrogen-containing compounds.

Jan 1, 2005

By O. Lashkari

Manipulation of pouring temperature is an efficient way to produce different microstructural features. In order to characterize the microstructure of rheocast billets due to different superheats of 615-695 °C, the parallel plate compression method was employed. Foundry 356 Al-Si alloy with different morphologies of primary a-Al particles were tested at different initial pressures of 4,8, 11,2 KPa, The resulted strain-time graphs were further treated mathematically to calculate viscosity of SSM billets. The interrelationships of viscosity, the microstructure and primary phase flow during compression are discussed, It is shown that the dendritic primary a-Al structure has the highest viscosity number which is almost three orders of magnitude greater than those for globular morphology, The current research have, for the first time, shown the validity and reliability of "parallel plate compression viscometry" method in characterizing microstructural evolution of Rheocast SSM billets.

Jan 1, 2005

By Allan J. Clark

This paper, describing the milling practice of the Homestake Mining Co., is one of a series being prepared by the Bureau of Mines. The author acknowledges the assistance of T. G. Chapman, one of the consulting engineers of the Bureau of Mines, in arranging this paper for publication.

Jan 1, 1931

By J Hall, A Gallardo, M Strizek

Mineralogy and coproponents Sino Iron, International Minerals and Austeel are in the process of developing four world class magnetite iron ore mines with multiple open pits along a 25 km strike length of Brockman Iron Formation to the south of Cape Preston on the West Pilbara coast. The close proximity of the proposed pits raises some challenging project approvals and environmental management issues relating to the impacts of dewatering at individual projects and the cumulative impacts of progressive development on local and regional groundwater resources, which includes a large fresh water aquifer system in the Fortescue River alluvium.This paper presents an outline of the hydro-environmental impact assessment process adopted and the key result that the cumulative impacts of dewatering at all four projects on the local brackish groundwater system in the basement rocks is only marginally more than the impact of any one project on its own, and that the impact on the Fortescue River alluvium aquifer is negligible. The paper also presents an outline of the proposed integrated water management approach that will involve coordinated monitoring, ongoing impact assessment and management, and reporting programs for all projects.

Jan 1, 2009

By G. S. Victorovich

Technical progress in primary smelting has changed the face of the copper industry in the years since the Second World War. Much of this change has resulted from a wide acceptance of flash smelting technology. In addition, research has been directed toward devising converting processes to replace conventional Peirce-Smith converting technology. One major thrust has involved a revival of the old " ", idea of oxygen flash converting of comminuted mattes. This paper reviews the 60-year history of flash converting. Particular attention is paid to Inco's investigations into the processing of white metal containing significant amounts of nickel and, in some cases, iron. Thermodynamic analysis and laboratory experimental results are presented which throw light on the behaviour of nickel and other salient features of flash converting. The possible role of oxygen flash converting in the copper pyrometallurgy of the future is briefly discussed vis-a-vis direct production of copper.

Jan 1, 1993

By L. Lacerda

Spray-on ground support membranes (GSM) or thin support liners hold today perhaps as much potential to impact underground (u/g) ground support operations as dry and later wet-mix shotcrete when introduced to mining in the latter part of the 20th century. This emerging technology has come a long way from the time the first single component experimental coatings were tested in the mid-1980s. Due to a number of factors, including occupational health risk and mine safety regulations, it has taken quite some time for the development of non-hazardous membrane products. However, at this junction most existing u/g mines that employ more conventional forms of ground support could benefit from evaluating GSM technology as a means of improving safety and the bottom line. The same is especially true for future mine developments. This paper describes Master Builders Inc.’s CS1251 GSM product and its implementation. It discusses the situations in which GSM may replace other forms of ground support. Furthermore, it evaluates GSM costs & safety issues and looks at present applications and the potentially bright future of this technology.

Jan 1, 2002

In this paper a numerical formulation is presented for determination of the axial load along a cable bolt for a prescribed distribution of rock mass displacement. Results using the program CABLE indicate that during excavation, the load distribution that develops along an untensioned fully grouted cable bolt depends on three main factors: (i) the properties of the cable itself, (ii) the shear force that develops due to bond at the cable-grout interface (i.e. bond stiffness), and (iii) the distribution of rock mass displacement along the cable bolt length. In general, the effect of low modulus rock and mining induced stress decreases in reducing bond strength as determined from short embedment length tests, is reflected in the development of axial loads significantly less than the ultimate tensile capacity even for long cable bolts. However, the load distribution is also dependent on the deformation distribution in the reinforced rock mass. Higher cable bolt loads will be developed for a rock mass that behaves as a discontinuum with deformation concentrated on a few fractures, than for one which behaves as a continuum, either due to a total lack of fractures or a very high fracture density. This result suggests that the stiffness of a fully grouted cable bolt is not simply a characteristic of the bolt and grout used, but also of the deformation behavior of the ground. In other words, the same combination of bolt and grout will be stiffer if the rock behaves as a discontinuum than if it behaves as a continuum. This paper also explains the laboratory test programme used to determine the constitutive behavior of the Garford bulb and Nutcase cables bolts. Details of the test setup as well as the obtained results are summarized and discussed.

Jan 1, 1996

By Markus Schönit

Double rotary drilling combines continuous flight auger drilling with a casing for producing a cast-in-place pile. When producing a pile an outer casing and an auger (hollow auger) rotating inside the casing are driven into the ground in counter-rotation. The outer casing serves to support the surrounding soil and the inner auger excavates the drilling cuttings to the surface inside the casing. After reaching the projected drilling depth concrete is pumped through the hollow stem of the auger and outer casing and auger are extracted. After their complete extraction a reinforcement cage can be inserted in the fresh concrete. Compared to Kelly drilling the double rotary drilling method offers numerous advantages, including, for comparable diameter and length, shorter production times and higher accuracy (pile inclination and excess concrete) combined with increased occupational safety and lower noise emissions. Moreover, pile tests have proved that piles produced by double rotary drilling feature higher axial load-bearing capacities than comparable piles produced by Kelly drilling. This article offers an overview of the basic theoretical principles of double rotary drilling lists the required and currently available machinery and, finally, discusses the results and conclusions of a current jobsite.

Jan 1, 2011

By Holly J

The period following World War II has seen many changes in stoping techniques at The Great Boulder Gold Mine. The new methods resulted in improved unit production figures, and have given some relief from the rising worldwide cost spiral in the post war years.Significant production figures are shown graphically in...

Jan 1, 1956

By James J. Dowd

The investigation to evaluate the reserves of coking coal in the United States suitable for the manufacture of metallurgical coke is being made by the Bureau of Mines in three parts: (1) To estimate known (measured plus indicated) recoverable reserves of all coking coal; (2) to upgrade marginal coals through effective preparation; and (3) to study the carbonizing properties of coals and coal blends not now widely used for metallurgical coke making. This is the sixth of a series of reports giving the results of studies by counties under part (1) of the investigation. (See appendix.) This report covers Fayette County, Pa., which comprises the Uniontown and parts of the Brownsville, Connellsville, Donegal, Waynesburg, Masontown, and Confluence, Pa., Morgantown and Bruceton, W. Va., and Accident, Md., quadrangles. (See fig. 1.) A short resume of the chemical and carbonizing properties of the coals ar.9 included. Data on the coal beds in this county were obtained from mining companies, land companies, individual landowners, and other sources of authentic information.

Jan 1, 1951

By Giorgio De Tomi, Ricardo Tichauer

Mineral exploration is a critical step for success in mining. However, small-scale mining often ignores exploration best practices. This paper introduces the Tichauer-DeTomi Matrix, a tool for assessment of geological uncertainty in small-scale mining. This matrix, which measures the level of compliance of exploration programs in small deposits with industry best practices, has been applied to three small mining projects in Brazil: an artisanal gold mine in the Amazon, a small-scale manganese mining venture in the Northeast, and a small manganese deposit in the Southeast. The application of the matrix resulted in indexes that reflect the actual level of maturity of the mineral exploration program in each project. Therefore, the matrix has shown potential to be an effective tool for assessment of the geological uncertainty remaining in small-scale mineral projects, as well as to identify priority exploration activities for reduction of risks associated with the geological uncertainty. As a risk assessment tool, the TichauerDeTomi Matrix may be helpful in promoting investment and sustained development in and around small mines.

By M. Olalde, I. Watson

"The consequences of ineffective mine closure in South Africa are evident from the number of abandoned mines and operations on extended care-and-maintenance, the on-selling of mines to less well-resourced companies to close, and increasing illegal mining activities. However, the data to substantiate these observations and provide insight into the underlying issues has not been available. Through the Promotion of Access to Information Act, a list of mine closure certificates applied for between 2011 and 2016 and a list of certificates granted over the same period for all nine regions of South Africa was obtained. From the analysis of this data, we show that the mine closure system as implemented in South Africa is largely ineffective. Although closure certificates are being granted, these are for prospecting sites and small-scale mines, which have a relatively small environmental impact. No large mines of any environmental significance were relinquished over the period under review, with very few applying for closure certificates. Furthermore, the issuing of closure certificates varies significantly between regional offices, with the success rate for applications being generally low and issuing of certificates taking an extended period. IntroductionThere are a number of concerns with the mine closure process as practiced in South Africa, and these have largely been laid at the door of government. Alberts et al. (2017) stress that the legislation generally conforms to international best practice. However, the system is ‘complex and unwieldy’, involving various pieces of legislation and different government departments with overlapping requirements and different interpretations of the law. A further area of concern is the capacity and competence of government to implement legislation. The ‘shortage of relevant mine closure skills and knowledge within the regulator’ was identified by van Druten and Bekker (2017) as a key contributor to unsuccessful closure. Lack of capacity and resources within the regulator has also been highlighted by Botham, Kelso, and Annegarn (2011) and Milaras, McKay, and Ahmed (2014). A recent study of the mineral application process by Corruption Watch (2017) indicates that positions in the regulator have been frozen for many years, leading to a shortage of staff, and that unqualified individuals have been appointed. There is also the perceived reluctance of government to grant closure in order to limit transfer of the liability to the state and delay the inevitable job losses."

Jul 1, 2019

By C. E. Wood

A special appropriation made by Congress in July 1940 provided funds for the investigation of methods for recovering manganese from low-grade [ ] domestic deposits. These funds were assigned to the United States Department of the Interior, Bureau of Mines. A committee, identified as the Technologic Committee on manganese of the National Research Council, National Academy of Sciences, was appointed to recommend the allocation of the funds for investigation of the more promising projects.

Jan 1, 1942

By C. E. Wood

A special appropriation made by Congress in July 1940 provided funds for the investigation of methods for recovering manganese from low-grade [ ] domestic deposits. These funds were assigned to the United States Department of the Interior, Bureau of Mines. A committee, identified as the Technologic Committee on Manganese of the National Research Council, National Academy of Sciences, was appointed to recommend the allocation of the funds for investigation of the more promising projects.

Jan 1, 1942

By Wils L. Cooley

This report analyzes electrical accident data in the metal/non-metal mining industry. Accidents are categorized to determine their root causes. Special attention is given to accidents associated with inadequate or defective grounding of mine power systems. Recommendations are made concerning proper grounding practice, especially for dredges and for quarries in hard rock or sand. The costs of instituting the recommended practices are estimated for model mine power systems which are based on field data obtained from 37 mines and several electrical contractors. The expected benefits of various suggested safety practices are also estimated.

Jan 1, 1981

By Joseph A. Vanous

The inductive communication system was developed under this contract for use in the hoist of deep mines. This program was a four phase program with experimental dual frequency equipment resulting from Phase I, emergency single frequency equipment developed under Phase II, and equipment documentation required under Phase III. An additional emergency system was provided under Phase IV.

Jan 1, 1976

By A. C. T. Bigg

"The mineral potential of the Nanisivik area was discovered as far back as 1910 when a prospector of the Geological Survey of Canada, on an expedition under Captain J. G.Bernier, recorded a deposit of pyrite with minor sphalerite and galena. An outcrop of the present orebody was discovered by Texas Gulf Company in 1957. Subsequent drilling outlined the orebody consisting of 6,000,000 tonnes of ore containing 13 % Zinc and 1.5 % Lead. The orebody appears to have been formed by the filling of a limestone cavern with sulphides. The sulphide minerals consist of pyrite, sphalerite and galena. The limestone bedrock is mostly dolomite with some calcite and magnesite. A cutoff grade of about 6% Zinc has been calculated.In 1972 Mineral Resources International Limited took an option on the property. Upon completion of the feasibility study by Watts, Griffiths and McOuat, the then new independent project management group of Strathcona Mineral Services Ltd. were engaged to develop the project through the financing, construction and operating phases. Strathcona Mineral Services still manage the project from their head office in Toronto and through the Mine Manager and Department Superintendents at the Mine site. The interest for the project is presently split five ways: Mineral Resources International Ltd. 53.5 %, Government of Canada 18 %, Metallgesellschaft A.G. of Germany 11.25 %, Billiton B. V. of Holland 11.25 % and Texas Gulf Co. 6 %."

Jan 1, 1980

This paper reviews the development and operation of a small underground tin mine in NE Tasmania. Tin mineralisation was discovered in the Lottah area in the 1880s with early alluvial and eluvial workings leading to the development of large low grade open pit operations. Apart from short lived activities operations ceased in 1915. Intensive exploration in 1978 - 1981 outlined substantial tonnages of low grade tin mineralisation (0.2% Sn) of open pit material. An underground ore body was also located (800 000 tonnes 0.6 per cent Sn). Spectrum Resources Australia Pty Limited acquired a 98 per cent interest in the property in 1988. Mine and mill development began in early 1989 based on an underground mine utilising trackless mining using room and pillar with fill stoping. The milling circuit involves primary jaw crushing, Barmac secondary crushing to 1 mm, Mogensen and DSM screens with jigs and tables to make a wet concentrate. Final tin concentrates are produced by high tension and magnetic separation. Planned production rates are 500 t/day with a mine life of six to seven years.

Jan 1, 1990

By Jerry J. Ran

In open stope mining borehole deviation is one of the main factors affecting the blasting results. Though previous research has identified some actual deviation patterns, these studies are unable to relate the hole deviation pattern with the blasting results and therefore it is not possible to modify the design or take remedial measures based on the prediction of the blasting results. An alternative to the conventional method for borehole surveying is the in-hole probing techniques. With their inherent errors, it is important to evaluate these surveying systems under conditions of different mine sites. The lack of available assessment methods has limited the application of these techniques. In this paper some of the characteristics of the actual hole deviation pattern are discussed based on data from surveying production holes in six stopes. A method of predicting the blasting results is proposed by considering the borehole deviation pattern. Based on the prediction stope design can be modified or further surveying is carried out to improve the blasting results. The tolerable error is introduced to relate the surveying error with the drilling pattern and therefore it is possible to assess various in-hole-surveying techniques.

May 1, 2002