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By B. D. Nash

The Bureau of Mines continued its research into the recovery of fluorine by the phosphoric acid acidulation defluorination of phosphate rock concentrates. A small process development unit with a capacity of about 10 kilo-grams of charge per hour was operated, and concentrates from both Idaho and Florida were processed. Over 80 percent of the fluorine was evolved and recovered as a dilute fluosilicic acid solution. Phosphate extraction from the concentrates always exceeded 98 percent. The fluorine was converted to a synthetic fluorspar product (3CaFa?SiOa) suitable for use as a slag conditioner in electric furnace steelmaking operations.

Jan 1, 1977

By Norman A. Pace

This paper is one of a series being published by the Federal Bureau of Mines on methods and practices used in mining and preparing crushed stone for market. Performance, in terms of units of work or tons produced per machine and per operator man-hour, is given whenever that information can be obtained. Direct operating costs are useful for comparing different methods and are included, if available. In addition to describing equipment and methods used} the Bureau considered it desirable to discuss the engineering reasons for the choices that have been made. This paper is particularly concerned with operation of the Camak quarry and plant of the Weston-Brooker Co. The quarry and plant are near Cedar Rock, north of State Highway No. 80 and east of Middle Creek in Warren County, Ga., and about 40 miles west of Augusta. Rail access is by a spur line of the Georgia Railroad from Camak, 5 miles southwest. The main office of the company is at Cayce, S. C.

Jan 1, 1959

By Leo A. Schrider

A prediction for oil recovery from a pilot waterflood in the Kane oil- field, located in Elk, Forest, and McKean Counties, Pa., was made and compared to actual field performance. Water-injection and production histories, well logs, other field data, and results from laboratory tests of core material were used in this analysis. Performance of the pilot waterflood, initiated in January 1963, was predicted using a modified Craig, Geffen, and Morse calculation technique. Maximum recovery from this low permeable, preferentially oil-wet formation was predicted to be about 22,500 barrels of oil after 300,000 barrels of water had been injected into the pilot waterflood area. After additional field data were collected it became necessary to reevaluate the pilot waterflood area. The gas saturation prior to the waterflood was estimated to have been 20 percent, based on an assumption regarding the required volume of water injected to initiate oil production. In view of the actual field performance, a gas saturation of 13 percent is indicated. When this gas saturation and the method originally proposed by Craig and others are used) the predicted results are more representative. In December 1965, field performance was further analyzed using a hyperbolic-decline curve as presented by Arps. Based upon this evaluation method, the pilot water flood in the Kane sand should produce 37,000 to 42,000 barrels of oil with the injection of 300,000 barrels of water into the pattern. By continuing this secondary-recovery project to a reasonable economic limit, ultimate oil recovery may be as much as 50,000 to 55,000 barrels, or 129 to 142 barrels per acre-foot from 36.5 acres.

Jan 1, 1967

By D. S. Kingery

Investigations over several years have disclosed that the principal manners of occurrence of shuttle-car injuries are in order: 1. Victims in contact with roof or crossbars. 2. Victims in contact with ribs or timber legs. 3. Victims falling from, or jerked from, shuttle cars. 4. Victims in contact with overhanging brows or protruding pine for pin timbers, or water lines. 5. Contact with persons or collisions with parked equipment. 6. Victims injured by roof falls or falling timbers caused by knocking out roof supports with shuttle cars. 7. Victims injured by runaway shuttle cars. 8. Victims injured while loading or unloading timbers or other materials from shuttle cars. These recurring types of shuttle-car accidents reflect the physical conditions of the working sections, certain safety deficiencies in shuttle-car maintenance and design, and unsafe practices by operators.

Jan 1, 1952

By K. K. Kelley

Synthetic fluorphlogopite mica (KMg3AlSi3010F2) is a relatively new product developed at the Norris (Tenn.) Station of the Bureau of Mines, Thermodynamic data have applications both in the production and use of this product, and the work described in this paper was undertaken to fill the need for such data. Measurements were made of the heat of formation at 298° K., the heat capacity between 50° and 298° K., the entropy at 298° K., and the heat-content and entropy increments between 298° K. and a maximum of 1,804° K. These basic data are combined to obtain heats and free energies of formation of the mica from the elements and from molecular constituents at temperatures ranging from 298° to 1,800° K. Minimum heat requirements to form melted mica from commonly used ingredients were calculated.

Jan 1, 1959

By Nunna Malakondaiah

Plant samples collected from the mined sites of Beulah, Center and Zap and the test sites of North Beulah 1, North Beulah If, South Beulahh and Center were analyzed for their nutrient concentrations. The vegetation from the mined areas generally showed lower concentrations of Na, P and Cu and failed to meet the nutritional requirements for beef cattle as defined by National Research Council (minimum requirements are: Na, 600; Cu, 4; P, 1800 µg/g dry weight). Plants from Beulah showed generally higher concentrations than from Center or Tap. Tissue concentrations of K varied significantly between sites for 5 species due to the low tissue concentrations at Center. Deficiencies are difficult to isolate as the sampling was done in mid-summer and generally during that season the tissue concentrations tend to decrease in several species. All of the plant species at the unmined sites, with the exception of western wheatgrass at Zap, had lower concentrations of P than the minimum nutritional requirements for beef cattle. Sodium concentration was low but Cu was marginal to adequate in plant species at the unmined sites. Concentrations of K, Mn and Cu in western wheatgrass were greater at Center than at Zap while the opposite was true of the concentrations of Zn, Cu and P in blue grama and Cu in green needlegrass. Amending the spoil with slack at North Beulah I decreased the concentrations of Zn, Cu and P in wheatgrasses grown on spoil from 0-2, 5-10, and 20-25 foot depths, respectively. In general, the mean tissue K+/Na+ ratios were greater in plants on slack amended spoils, primarily due to the reduced Na concentrations in the tissue. At North Beulah II test site, only wheatgrasses grown on spoil amended with slack showed significant increase in K and decrease in Na and Mn concentrations. At South Beulah test site which received 12" topsoil over graded spoil, leonardite amendment decreased P concentrations in all of the grasses as compared to control, whereas fertilizer treatment increased the same. Nutrient concentrations were lower in both fescue and needlegrass with leonardite treatment and higher with fertilizer treatment although not significantly different from control. The concentrations of Ca, Mg, Na, Fe, Cu and N in grasses grown on topsoil at Center test site were significantly higher than on slack amended spoil. Legumes grown on topsoil at Center site contained higher concentrations of P than those grown on spoil; there were no significant effects due to slack on spoil or topsoil. The data presented in this report act only as an indication of between-treatment and between-species differences in tissue composition of plants harvested in mid-summer season. With respect to the nutrients analyzed, since none were found to be toxic, the cattle can safely feed on the vegetation of these mined areas.

Jan 1, 1982

By A. W. Ambrose

"Introduction.Oil-field operations have often been carried on under great stress and haste, in which the prime purpose has been to put the wells down rapidly as possible, without regard to a few of the various factors affecting cost. In such fields as Burkurnett, Texas, where the well locations are town lots and other small tracts, the operator was concerned primarily with in drilling. In such cases a few thousand dollars more or less in the cost of a well not considered. We are reaching a time, however, when our reserves a,more definitely outlined and properties are being along more economic lines. Operators are becoming more concerned with the actual cost of this work, and are gradually learning that fuel consumption can be reduced in drilling and producing without delaying the speed of drilling, and in the case of production, it will greatly reduce the unit cost per barrel of production.Types of Field Boilers.In the oil fields there are in general two types of boilers; those which are used for drilling wells and are of a more or less portable character, and those established later in a more permanent form and serve for the purpose,of generating steam for producing the oil. As a rule, the latter type of boilers are larger than those of the drilling type. Usually, little care is given to the installation of drilling boilers; particularly in attempting to set them up in such a way as to avoid waste in of fuel. Because of the temporary nature of these installations there may be some justification for not giving them more,attention in this resend, but it is believed that a few precautions could be taken that would amply repay the cost and trouble taken. In connection with the boiler plants that are afterwards established, when a few producing wells have been,brought in with a life of two to ten years and probably longer, much care to the boiler-plant construction and to the installation of recording instruments which will assist in operating the plant at minimum cost."

Nov 1, 1920

By J. Tomlinson

Shuttle car trailing cable splices were tested for resistance to failure upon being subjected to repeated bending, abrasion, and tensile shocks using a new testing method that closely simulates shuttle car induced stress. The results show that under normal stresses, splices can be made to withstand the equivalent of three months of operational use. Restoring the tensile strength to the conductors is found to be as critical as restoring flexibility. Splices in which the conductors are of slightly unequal length did not present as serious a workmanship problem as previously thought since test results show that the conductors tend to equalize when longer cables, in contrast to short cables employed in previous testing methods, were used. Dynamic recordings of cable tensile stresses are presented for a shuttle car and the new simulated testing method. Two simple but effective methods for removing insulation using a knife and a pair of pliers are described. None of the designs tested for a sacrificial splice covering were satisfactory.

Jan 1, 1979

By Beatrice Lukens, David Schlain, John D. Prater

"The electrolytic manganese process4/ developed by the Bureau of Mines involves the electrolysis of a solution of manganese sulfate and ammonium sulfate in a diaphragm-type cell. Metallic manganese is deposited on the cathodes, and sulfuric acid is produced at the anodes. The spent electrolyte contains, in addition to the sulfuric acid, approximately 40 percent of the manganese sulfate and most of the ammonium sulfate originally present in the feed solution. This spent solution is used to leach fresh ore that has previously been subjected to a reducing roast. The resulting leach liquor is purified and returned to the cell.Manganese of very high purity is produced by the electrolytic process. The properties of this metal are so different from those of the best grade of manganese that can be made by any other commercially feasible process that it is virtually a new material. Electrolytic manganese has been used in the preparation of new high-manganese alloys with valuable properties.3/ and further developments are to be expected. The electrolytic manganese process not only results in a product of superior qualities, but is applicable to large tonnages of domestic ores that are unsuitable for direct use in producing ferromanganese.The future industrial use of electrolytic manganese is of course, related to its cost. Decreases in the cost of production will lead to wider use of the metal; conversely, increases in the volume of production made possible by greater demand will bring further .decreases in cost."

May 1, 1946

By Manuel Gomez

The heat contents of thermally dried lignite, subbituminous B coal, and their corresponding low-temperature chars were determined at various temperatures below the highest temperature to which these materials had been exposed before testing. Similar studies were made on high-temperature char and coke, spent shale, and ash prepared from both coal and spent shale. Heat content of the carbonaceous materials tested correlated well with temperature. Heat con-tent results for spent shale compared well with the published results. Statistical analysis of experimental data together with published information showed moisture, volatile matter, carbon content, and temperature to be the principal variables influencing the specific heat of coal. The specific heat of devolatilized carbonaceous substances, char and coke, approached that of graphite as the carbonization temperature was increased. The elemental specific heats of coal constituents, estimated from the ultimate analysis and the specific heat of coal, compared favorably with published elemental specific heats.

Jan 1, 1965

By J. J. deBarbadillo

This Bureau of Mines report describes a process for recovering chromium and other metals from superalloy scrap. Laboratory-scale experiments were conducted to test a complex flowsheet utilizing a wide range of extractive metallurgical operations. The novel basis for the process is the fonnation of a sulfide matte in which chromium is concentrated in a discrete chromium sulfide phase. Mineral processing and hydrometallurgical procedures are used to separate chromium sulfide from the other matte constituents. The products of the process are a chromium-nickel alloy suitable for reuse in the superalloy industry, electrolytic nickel, electrolytic cobalt, and iron-molybdenum residue. Recovery of the principal elements contained in the scrap is chromium--93 percent, nickel--99 percent, cobalt--96 percent, and molybdenum--92 percent.

Jan 1, 1981

By Donald F. Reed

The bauxite deposits of Tippah and Benton Counties in northeastern Mississippi were developed by drilling as a part of the investigation by the Bureau of Mines of the domestic sources of supply of aluminum. The primary purpose of investigations of this nature was to provide essential information to the war agencies of the United States Government and to assist owners and operators of mining properties in the production of minerals vital to the prosecution of the war. These reports are based upon the field work of the Bureau of Mines and upon data made available to the Department from other

Jan 1, 1948

By Corwin L. Cooper

This paper, describing; the milling and cyanidation methods and costs at the Yellow Aster gold mine, is one of a series of papers being prepared by the Bureau of Mines on bold milling practices in the United States. Acknowledgments Acknowledgment is made to the executives of the Anglo American Mining Corporation, Ltd., for permission to publish this article, and to A. W. Frolli, manager, and other members of the company staff, for assistance` in preparing the, paper.

Jan 1, 1936

By H. F. MILLE, Charles A. Kumke

This paper describes mining operations at the Iron King mine of the Shattuck -Denn Mining Corp. in Yavapai County , Ariz . It is one of a series being prepared by the Mining Division of the Bureau of Mines on mining practices and methods in various mining districts of the United States . The mine and surface plant of the Iron King mine are situated in secs . 15 and 21 , T. 13 N. , R. 1 E. , about 20 miles by State highway 69 east by southeast from the city of Prescott and 1 mile southwest of the mining town of Humboldt on the Prescott -Mayer branch of the Atchison , Topeka & Santa Fe Railroad (fig . 1 ) . A l-mile truck haul brings the mill concentrates (lead and zinc ) to bins on a siding of this line at Humboldt ; the silver -gold bullion is handled separately . Some of the oldest residents in the vicinity of Prescott claim that the original location for the Iron King mine was made in 1880. The earliest recorded production was in 1906-1907 . During the first World War the mine produced fluxing ore for the Humboldt smelter . In 1936 the property was purchased under tax sale , and a mill (140-ton capacity ) was erected in 1938. The capacity of this mill was increased to 225 tons the following year , and a cyanide plant was added in 1940 to treat mill tailings . In 1942 the Shattuck -Denn Mining Corp. purchased the property . A new working shaft was sunk , mine development was speeded , and mill capacity was again increased . The predominating locally formation of this district is a pre -Cambrian schist known as Yavapai schist . The Iron King deposit , which carries gold, silver , lead , zinc , and copper , occurs as a series of lenses in a sheared zone of the pre -Cambrian schist . Down to the 600 -foot level the ore was mined and drawn by the shrinkage method . The cut -and -fill method was adopted for the lower levels . Waste rock for stope fill was provided by block-caving an area on the 600 level . Main haulage drifts were driven in the firm footwall , and crosscuts were driven across the mineralized zone at 100 -foot intervals . Grab samples taken from each car of every working place and channel samples cut every 5 feet in development work are considered sufficient for estimating ore reserves .

Jan 1, 1950

By D. C. Dahlin

To identify and characterize potential domestic chromium resources, the Bureau of Mines investigated podifom chromite deposits along the Border Ranges Fault in southern Alaska. Part 1 of this two-part report describes an extensive field investigation and preliminary resource evaluation studies by the Bureau's Alaska Field Operations Center. This paper, part 2, describes the mineralogy of 38 samples that were collected from low-grade deposits in the Chugach Mountains, on the Kenai Peninsula, and on Kodiak Island, and presents the results of laboratory batch beneficiation tests designed to concentrate the chromite. The samples are peridotites and chromites that consist primarily of variable amounts of chromite, olivine, and serpentine. They were beneficiated by a sequence of grinding, sizing, and gravity concentration operations. Twenty-four high-chromium or marginal high-chromium chromite concentrates, six high-iron or marginal high-iron chromite concentrates, and five submarginal concentrates were produced with chromium recoveries that ranged from 37 to 95 pct. Three very low-grade samples were not beneficiated. These results indicate that several of the de- posits may be significant chromium resources, Potential precious metals association with the chromite was also investigated. Analysis of these samples indicates that the chromite deposits are not good platinum sources.

Jan 1, 1985

By Robert M. Strong

The following report is a summary of the commercial results which 'Were obtained from 2,000 tests conducted by the technologic branch of the United States Geological Survey at St. Louis, Mo., and Norfolk, Va., in 1907 and 1908, under the technical supervision of R. H. Fernald, engineer in charge of the producer-gas section. The tests dealt primarily with gasoline, forming part of the investigation of mineral fuels provided for by acts of Congress. To determine the relative economy and efficiency of gasoline it was compared with denatured alcohol. The tests, many of which were undertaken in connection with work for the Navy Department, supplemented, to a certain extent, the work of previous investigations, but only so far as was necessary to emphasize some of the more important points and to lead up to the defining of conditions required for the economical use of gasoline and alcohol. In order to determine and eliminate the affecting engine conditions as far as possible, the investigation was commenced by making comparative gasoline and alcohol tests on the same engines. These tests were repeated on other engines of approxiElately the same size and speed, having different degrees of comFression, different methods of governing, and different carburetors. The final report will include much material that may be of use in engine design, but that side of the investigation was not pursued any further than was necessary to obtain the best possible results, for alcohol and for gasoline with the engines at hand, and to prove that the minimum fu·el-consumption rate for each could be obtained in approximately the same manner. The effects of engine and of operating conditions both have a bearing on the commercial deductions but will be discussed only in a general way at this time.

Jan 1, 1911

By J. B. Gayle

Numerous investigators have studied the addition of inert4 substances to coking blends. Generally, the results have yielded trends applicable only to the particular coals and inerts studied. Recently, somewhat more general results were obtained for cokes produced from blends containing added inerts, using the sole-heated oven. The present investigation represents an extension of this work to include a wider range of inerts and to determine the applicability of the various conclusions to cokes produced with the Tuscaloosa oven. The results indicated that an increase in dry-coal charge density of 1 pound per cubic foot (p.c.f.) caused a corresponding change in the hardness (1/4-inch tumbler index) of Tuscaloosa oven cokes of 0.9 percentage points. This value compares favorably with the value of 0.7 determined previously for the sole-heated oven and Bureau of Mines-American Gas Association (BM-AGA) retort.

Jan 1, 1961

By Paul M. Tyler

Graphite is chemically identical with diamond, both being crystallized allotropic forms of carbon. Graphite obviously differs greatly from diamond in physical properties and is easily recognized by its blackness, its softness (1 to 2 on Mohs' scale), and its slick feel when rubbed between the fingers. Strictly speaking, all graphite is crystalline, but grades in which the individual grains cannot be distinguished with the naked eye are commercially classed as amorphous. Natural mixtures of the two varieties occur in all proportions, and the classification of a given sample as "amorphous" or "crystalline" graphite is based largely upon trade practice. Until recently different varieties of vegetable or animal charcoal, lamp black, soot, gas carbon, and coal ware considered strictly amorphous, but modern examination by X-ray methods indicates that even these materials possess the same internal crystalline structure as graphite, differences in physical properties being perhaps explained by porosity or presence of combined hydrogen or other impurities.

Jan 1, 1941

By David C. Grant

A laboratory technique for simulating in-situ uranium mining was developed and used to determine the effects of leaching variables on permeability, uranium recovery, leach solution interaction with the ore-aquifer environment, and post-leach chemical leakage. In particular, ammonium bicarbonate, the commonly-used leach solution, was examined in great detail. Agitation leach tests were conducted to examine the effect on ammonium sorption and desorption of clay content, solution and clay ammonium levels, pH, and the type and concentration of other anions and cations in solution. Initial column tests were performed to determine the degree of ore-aquifer interaction that could be expected for various leach solutions; sulfuric acid, and ammonium, sodium, and potassium bi-carbonates. Subsequent tests examined various methods to restore the ores by lowering the post-leach chemical leakage. The restoration tests examined the use of reducing agents (e.g., ammonium bisulfite, sodium bisulfite; and sodium sulfite), ore blocking and stabilizing agents (e.g., sodium silicate, aluminum chloride, and magnesium-calcium salt).and ammonium displacement agents (e.g., aluminum chloride and lanthanum chloride-sulfate)

Jan 1, 1980

By R. H. Church

As part of the research effort of investigating the effects of microwave energy upon the chemical and physical properties of different minerals and ores, the Bureau of Mines has conducted basic research into identifying those properties of minerals that are affected by microwave energy, namely, the dielectric constant and loss tangent. These properties were determined utilizing the theory of microwave propagation in a coaxial waveguide filled with a dielectric material and measuring the input impedance with an RF impedance analyzer that operates from 1 MHz to 1 GHz. By knowing the microwave frequency and filling the waveguide with a powdered mineral, the dielectric properties of the mineral sample were determined. From these dielectric properties, theoretical microwave heating characteristics of each mineral could be calculated. These same mineral samples were then irradiated by a 915 MHz 30 kW variable power microwave oven and dielectric heating studies were performed. A comparison of the theoretical heating characteristics and the results from actual dielectric heating studies was conducted to evaluate the dielectric property measurements on each mineral. This report presents the results of the Bureau's research in identifying the dielectric properties of low-loss minerals according to the mineralogical classification scheme along with their irradiation studies. Though far from complete, this study represents some of the more frequently encountered low-loss minerals.

Jan 1, 1988