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By B. Hosseini

Considering the subtractive trend of the sulfide and high-grade zinc ores in worldwide and also in Iran, Nowadays special attentions have been drawn to the extraction of zinc from its other resources such as low-grade oxide ores and secondary resources. Oxide ore of the eastern part of Mehdi-abad lead and zinc mine is silicate and has an average grade of 7% (with cut off grade of 4%). Main mineral of the Mehdi-abad ore is Hemimorphite and this mineral is associated with Goethite, Hematite, Ferrous Dolomite, and Manganese oxide mineral so that oxides of Iron, manganese and silica include almost 50% of the total ore. In this paper, the results obtained from the leaching kinetic study of the low-grade zinc oxide ore using Sulfuric acid are presented. The effects of particle size, reaction temperature, acid concentration, and solid percent on the dissolution rate have been investigated. The results obtained from the Taghochi approach showed that the zinc recovery is about 78% under the following optimized conditions: particle size: 106µm, leaching time: one hour, temperature: 45°C, acid concentration: 15% and solid percent: 15%. Kinetics study was revealed that zinc minerals leaching controlled by diffusion rate through the product layer during leaching time with the activation energy of 5 KJ/mol and compliance with the 1- (2/3. x) ? (1- x) 2/3 = k. t model. Keywords: leaching kinetics, kinetics models, sulfuric acid leaching, taguchi methods, low grade zinc ore, mehdi-abad mine

Sep 1, 2012

By Brabcova Z.

This contribution deals with bubble adhesion on particle surface which consists of three steps ? the liquid film thinning, the film rupture and expansion of the three phase contact (TPC). Our attention is devoted to the third step ? to the description of the TPC expansion. Three-phase contact line expansion can be theoretically described using hydrodynamic and molecular-kinetic models. Both of these models were originally developed for the interaction of the bubble with horizontal plane in pure water. Our experiments deal mainly with the interaction of the bubble with the inclined plane in the solution of surface active agents. It was proved experimentally that molecular-kinetic model corresponds also to these conditions and this model was used for the description of the TPC expansion. The model is based on the theoretical description of the bubble contact angle on the three-phase interface. These contact angles change dramatically from 180o to equilibium (Young) contact angle close to 90o. Modificated ADSA method is used for the calculation of the contact angle. This method utilizes the Laplace equation of the capillarity; the bubble profile and the contact angle are evaluated using the set of experimental points around the edge of the bubble. The comparison of the experimental and calculated bubble profile shows a good agreement. The aim of the project is to describe the process of the TPC expansion during the adhesion of the bubble with the diameter up to 1 mm. Inclined planes were used instead of an experimental solid particle. Our experiments were provided in the solution of surface active compounds. The process of the adhesion was recorded using high-speed digital camera and images were evaluated using the image analysis software NIS-Elements. Calculations were performed using the MATLAB software. Keywords: bubble-particle interaction, adhesion, three-phase contact, contact angle

Sep 1, 2012

By W. Fander, Zhonghan Zhang, T. Choo, J. Enraght-Moony

"This paper describes the mineralogical and metallurgical procedures used to determine the recovery and concentrate grade of heavy oxide minerals occurring in lode deposits. The data produced also provide vital information to the processing engineers, which allows them to develop the most suitable flow sheet for that particular heavy mineral, here called an Economic Oxide Mineral (EOM). It demonstrates how results are interpreted to ensure that the proper process is used at each treatment stage to optimise recovery and to produce the most suitable concentrate at that point. Reference is made to some of the current equipment and techniques that can be used to process EOMs. The paper shows that when assessing the economic potential of a new ore body, or existing ore treatment plant, ore characterisation (OC) is necessary. This is especially true for EOMs such as cassiterite (SnO2), wolframite ((Fe, Mn, WO4,) pyrochlore ((Na,Ca)2Nb2O6(OH,F)), and tantalite (MnTa2O6) where often what seem to be small changes in ore types can have major effects on recovery and concentrate grade. Due to advances in flotation technology scheelite (CaWO4) in some deposits can be less vulnerable to OC variability than other EOM’s. Thorough mineralogical examination is shown to be the fundamental basis of correctly undertaking OC. This is because mineralogical analysis identifies each of the steps required to ensure that all ore types and zones are recognised, and differences explained, and shows the benefit in using reference samples to compare differences in the ores. The OC methods used for EOMs containing metals such as tantalum, tin, tungsten and niobium are similar; if two or more of these EOMs occur in one deposit as separate minerals, then OC will show when and how these minerals should be separated. The OC techniques described for EOMs can also be tailored for other heavy minerals, precious metals and graphite."

Jan 1, 2014

By A. N. Lazaridi, S. I. Afanasenko, S. A. Safonov

"This scientific work presents the results of comparative tests of centrifugal concentrators with a vertical and horizontal axis of rotor spinning. The article also describes a qualitative analysis of the behavior of mineral particles in a centrifugal field with fluidization for concentrators with a horizontal axis. The analysis was aimed at studying the effect of the quantity of fluidization holes in the basket on the degree of magnetite recovery and the effect of the basket rotation speed. The experiment demonstrated that concentrators with a horizontal axis are not inferior in terms of the qualitative recovery indicators to concentrators with a vertical axis. The researches also provided facts about the wide practical application of concentrators with a horizontal rotor arrangement. INTRODUCTION Methods of gravity concentration, attractive for their ecological purity, see their revival. First of all, this is due to the invention of centrifugal concentrators with the fluidization of the layer of mineral particles. The creation of a new generation of gravitational centrifugal concentrators made it possible to achieve a tangible breakthrough toward the direction of reducing the grain size of mineral particles effectively divided by density, up to 10 µm at a high production capacity of the vessels reaching 500-600 tons per hour. Such separators enable dressing a crushed ore of flotation grade and in some cases replace the flotation process, especially in primary operations, in joint cycles. In the long term, this method of concentration should significantly expand the scope of application, replace partial flotation processing, ensure the introduction of environmentally friendly energy-saving technologies at ore-processing plants. Summarizing the international experience for the last 30 years, it can be confidently asserted that centrifugal methods of concentration have become widely used in processing schemes for the separation of finely dispersed products in the mining industry. An interest in the creation of installations using centrifugal acceleration for the separation of mineral particles by density has particularly grown. Dozens of centrifugal concentrator designs have been created and continue to be improved. Centrifugal concentrators have a number of obvious advantages, which are especially relevant today. Losses of fine gold during the process of mining are well known. Gold washers screw, spiral separators, jigging machines and sluices traditionally used in the production processes do not solve the problem of fine gold recovery. Table 1 shows the results of comparative tests of a centrifugal concentrator (ITOMAK) and other concentration equipment. According to the research conducted by the company GMRS, Krugersdorp, South Africa (2000), the initial material was gold ore crushed to 150 micrometers (90%)."

Jan 1, 2018

By H. R. Manouchehri

The importance of the grinding environment and its effect on sulphide minerals flotation behavior has been known for many years. The grinding environment may play a role in controlling fine and coarse particle flotation along with dissociation of different chemical species in grinding environment. Dissociation of different chemical species and ions within the process water may result from changing the grinding environment. The mining and mineral processing industry undertakes activities that may impact on water resources. These include use and storage of chemical storm-water management, process water management, mine dewatering and management of tailings. In mineral flotation understanding and controlling water quality is paramount important not only because of its effect on flotation but also with respect to control the quality of the water which is released to the environment. Releasing of different anionic and/or cationic chemical species in the process water results from the interactions among different mineral within the ore, process water, and the milling environment. In fact grinding mill acts as an electrochemical reactor which affects the flotation performances of different value minerals as well as the quality of the tailing products. An increasing in antimony content in process/discharge water at Boliden?s Tara processing plant in Ireland to above limitation level was reported in April 2010 which needed to be controlled. An increase up to 6 times of the permitted level was reported which needed an immediate action to control due to environmental considerations. Therefore attempts were made to detect why this higher amount of Sb is released and how to control and minimize its release to the process/reclaim water. This paper discusses how/why Sb content in process/reclaim water was increased by changing the mill electrochemistry and the strategies were taken into considerations to control it. Different strategies, including electrochemical controlling of the milling section, Fenton process, using Bauxsol in treating the process water, etc., have been considered and tested which are described herein. All strategies taken into consideration for solving the problem were successful which indicated good understanding of the issue and good decision making. Furthermore, for each solution the capital and operational costs were roughly estimated. Accordingly, the Sb content in process/discharge water was controlled to a value lower than allowed limitation, i.e., 1 ppm. Keywords: antimony, water contamination, mill electrochemistry, ag milling, grinding media, eh-ph, sulfide minerals, fenton process, bauxsol, lime addition

Sep 1, 2012

By D. Moradkhani

The objective of this research was, to evaluate the hazard of heavy metals in the soil around the National Iranian Lead & Zinc (NILZ) Company. In this study, 38 samples of soil around the NILZ factory were collected using standard sampling method, so that, the heavy metals Pb, Zn, Cd and Cr have been evaluated. The concentration of heavy metals were measured and compared with standard limits. The results show that the hazard of heavy metals in soil is not so serious and the content of Pb in just 5 percent of samples, and the content of Zn in just 3 percent of samples were above standard limits and the concentration of Cd and Cr were under the standard limits. Average, variance and standard deviation of the elements are calculated and with due attention to the standard deviation, Pb and Zn are seen to be more distributed than Cd and Cr. Also the isograde curve of heavy metals was drawn using software called Surfer. These curves showed that the heavy metals are concentrated at particular distances from the factory. Keywords: heavy metals, remote sensing, sampling method, isograde curve, Surfer software

Sep 1, 2012

By Indrajit Paul, Atanu Pal, Kapil Modi, Sanjay Chandra, Chandra Sekhar, Srinivas Dwarapudi

"High alumina content in the Indian iron ore fines (2.5% Al2O3) resulted in poor quality pellets at the recently commissioned 6 MTPA pelletizing plant and a study was under taken to establish suitable pellet chemistry through proper fluxing agents. Limestone fluxed pellets were prepared at varying basicity (0 to 0.8) and pyroxenite fluxed pellets at varying MgO contents (0 to 3%) to study their effect on the metallurgical properties. Fired pellets were tested for their strength, RDI, reducibility and swelling. Microstructural studies, optical and SEM-EDS, were carried out to quantify different phases and their chemistry. Acid pellets exhibited poor quality whereas limestone pellets at 0.8 basicity and pyroxenite pellets at 1.5% MgO exhibited optimum metallurgical quality. Formation of widely distributed silicate melt in limestone pellets and high melting point slag & magnesioferrite in pyroxenite pellets found to improve their quality. However during commercial production of MgO bearing pyroxenite pellets, their room temperature and low temperature properties found to be inferior, but exhibited better high temperature properties, viz. softening-melting behavior. Contrary to this, commercially produced limestone pellets, comprising CaO, exhibited better strength and RDI but showed poor high temperature properties. To yield the benefits of both CaO (for good strength and RDI) and MgO (for low swelling and high softening), a dual flux combination was established by using both limestone and pyroxenite/olivine together that resulted in optimum metallurgical properties. Coke rate at the blast furnaces found to be reduced by 1kg for every1% increase of dual flux pellets in the burden.INTRODUCTION Iron ore agglomerate quality plays a vital role in decreasing the reducing agent consumption and increasing the productivity of blast furnace. In most of the integrated steel works, the burden mix for blast furnace is decided as per the availability of the iron ore agglomerates like sinter and pellets. More attention has been given in recent years to the use of fluxed pellets in blast furnace due to their good strength and improved reducibility, swelling and softening melting characteristics. Generally, quality of pellets is influenced by the nature of ore or concentrate, associated gangue, type and amount of fluxes added and their subsequent treatment to produce pellets. These factors in turn result in the variation of physicochemical properties of the coexisting phases and their distribution during pellet induration. Hence properties of the pellets are largely governed by the form and degree of bonding achieved between ore particles and the stability of these bonding phases during reduction of iron oxides (Panigraphy et al., 1990). It is important to note that conditions and parameters of pelletizing are specific to given ore or concentrate; the present study is undertaken for typical Indian hematite ore fines high in alumina. Except authors earlier work on quality of pellets from Indian iron ore (Dwarapudi et al., 2008, 2010), there is no considerable literature reported on the effect of pellet basicity and MgO content in the basicity range of 0 to 0.8 for Indian hematite ore."

Jan 1, 2018

By Jing Zhou

In view of the state of the long time use of sodium cyanide in lead-zinc-sulfur-silver multimetallic ore production, we propose alternative reagents system through experimental research. The experiment first used TJ, sodium sulfide to adjust the flotation pulp, after that, zinc sulfate, sodium sulfite was added to low alkaline pulp to inhibiting zinc sulfur mineral and adapted MB, 25# aerofloat and diethyl dithiocarbamate combination collectors to float lead minerals. The obtained test index is as follows: lead concentrate recovery rate of small scale test was increased by 5 to 10%, the recovery rates of gold and silver in lead concentrate were increased by 7% and 11% respectively; the industrial test is conducted under the condition that the total grade of lead and zinc content in raw ore decreased by 4.81%, the total recovery rate of lead and zinc increased by 7%, recovery rates of gold and silver in lead concentrate were increased by 7.62% and 9.65% respectively. So it successfully realizes the target to replace the sodium cyanide, using low-alkaline non-toxic reagents system in mineral processing practice of three kinds of complex lead-zinc-sulfur ore of this mine. Keywords: refractory lead-zinc-sulfur ore, depressant, non-cyanide flotation

Sep 1, 2012

By K. C. Corin, M. S. Manono, J. G. Wiese

"It has been suggested that hydroxo species, particularly those of calcium, selectively adsorb onto gangue minerals. Such species enhance the depressive action of carboxymethyl cellulose (CMC) onto gangue via an acid-base interaction between the positively charged mineral surface and the negatively charged CMC molecule. Thus, the hydrophilicity of gangue minerals is enhanced, preventing the dilution of the concentrate. However, as there is little evidence to support these claims it is important to investigate. Adsorption data and mineral surface charge analyses will allow a fundamental understanding into how electrolytes and their ionic strengths affect gangue-depressant adsorption. It is strongly anticipated that decoupling these effects will allow process operators to tailor their process water quality needs towards best flotation operating regimes and in the long run effect closed water circuits. Thus, using talc and pyrrhotite as proxies, this work investigates the influence of the ionic strength of process water on the adsorption of CMC onto minerals in sulphide flotation.INTRODUCTIONThe phenomenon of gangue depression in mineral flotation is of critical importance as regards the attainment of a required concentrate grade. This thus suggests that the depressant of choice has to have a highly selective affinity for the targeted gangue minerals. This would ensure the necessary prevention of gangue from reporting to the concentrate without inadvertently depressing the value bearing mineral. The chemistry of the environment regulates the manner in which gangue depression occurs. In sulphide flotation, polysaccharides are used as depressants of choice to depress naturally floatable gangue which may in the case of Merensky ores exist as talc. The two widely used polysaccharides in the South African context are carboxymethyl cellulose (CMC) and modified guar gum. It is suggested that polysaccharides depress gangue by rendering the surface of gangue hydrophilic or by preventing the formation of hydrophobic layers on gangue mineral surface, forming large gangue aggregates and thereby increasing their heterocoagulative nature (Shortridge et al., 1999)."

Jan 1, 2018

By O. Kökkilic

This study covers the tests to develop separation process for production of clay and colemanite rich concentrates, and aims to serve the clay and colemanite concentrates extracted from the tailing dams to the industrial applications. For this purpose, samples from the tailing dams in Kestelek Boron Plant (Turkey) with an average B2O3 content of 8%~11 % were subjected to the investigations. The separation process of hydrocyclone--to make clear the way to obtain either clean clay or cole-manite--was initially discussed. Therefore, following the gentle scrubbing (to keep the bimodal size distribution between clay and colemanite) of the tailings to disperse the slurry, two alternative multistage hydrocyclone processes; allowing to recycling the overflows or underflows to concentrate clay and colemanite were respectively tested. As a result of the preliminary tests, the multistage hydrocyclone separation in direction to the clean colemanite concentrates (recycling the underflows) gave the better separation efficiencies. So, all the parameters such as apex and vortex finder diameters and feeding pressures were examined with the multistage hydrocyclone process allowing the recycling the underflows. The detailed multistage hydrocyclone separation process of the tailing dam wastes yielded with colemanite concentrates (approx. 12 % of the feed, w/w) with B2O3 content of 35.0 % and the clay concentrates (approx. 42 % of the feed, w/w) with B2O3 content of 2.1 %. Colemanite concentrates were found good enough either to re-feed in to the separation process or to keep upgrading for final product ready to use in Industry whereas the attempts on production of light bricks from clay concentrates has failed. But it is worth to point out that these clay concentrates can be used for agricultural purposes just in the form as it is.

Jan 1, 2014

By M. Ito

Cobalt-rich ferromanganese crust and nodule ores from seamount areas contain volcanic and sedimentary rocks as substrate or nuclei and these ores require mineral processing to remove the substrate/nuclei rock before smelting. This paper reviews the results of jig separation and air table treatment for the coarse fraction and flotation and hybrid jigging for the fine fraction. Using these techniques substrate/nuclei rock was removed from the cobalt-rich ferromanganese oxide components. The mineralogical properties and metallurgical treatment methods including hydrometallurgical treatment of low grade ore is also reviewed.

Sep 1, 2012

By Rogerio de Oliveira Baldoino

The sedimentary phosphate deposit of Bayovar is located in a very dry area of Peru (desert of Sechura) which is close to the Pacific coast. It consists of seven superposed layers (beds) which call for different strategy of concentration. The ore is composed predominantly by apatite (84% in weight basis) plus silicates (16%). In order to treat the ore from beds 1-5, a suitable standard mineral processing circuit (composed of scrubbing, screening, attrition and desliming) started its operation in 2010, yielding 3.9 Mt/y of concentrate assaying 30% of P2O5. To concentrate phosphate from beds 6-7, however, it is necessary to carry out further cationic reverse flotation of silicates, at neutral pH, to yield a concentrate, which meets market specification. The new process was developed in laboratory scale by a collaborative program conducted between Vale S.A. and the University of Sao Paulo-Brazil. A pilot plant has currently been running in order to confirm the very good results yielded in laboratory scale. The successful accomplishment of flotation in the current beneficiation flow sheet will enable a capacity expansion of 1.9 Mt/y of concentrate assaying 30% of P2O5. As water resources are very limited at Bayovar region, all the steps of concentration, including flotation, must be performed with seawater, which must be continuously recycled. This work addresses some relevant topics related to the use of seawater in the reverse cationic flotation of silicates: influence of temperature, water quality (ageing and chemical composition) and collector type (ether amine versus condensate). The results indicate that condensate amine works better than ether amine. If flotation is conducted with the former collector, the separation process is able to tolerate changes in temperature (25-40oC) and water quality caused by either evaporation or ageing. Keywords: phosphate, flotation, seawater, temperature, ageing, concentration, salt

Sep 1, 2012

By P. Ying

An auxiliary system connected with SEM-EDX for rapid identification of mineral and rock sample has been developed. With the aid of a synthetic spectrum library created, using the compare and match techniques provided by INCA software in EDX the mineral or rock sample names for refer-ence can be given at the same time analyzed.

Jan 1, 2014

By Sravya Kosaraju, Christian Ekberg, Stefan Allard

Li-ion batteries are now used in electric vehicles (EVs), plug-in hybrid vehicles (PHEVs) and, hybrid electric vehicles (HEVs). Nanostructured Li(NiyMnzCo1-y-z)O2 is one of the more popular cathode chemistries for automotive Li-ion battery, due to its enhanced properties such as large surface area, short diffusion length, enhanced ionic and electronic conductivity, improved mechanical strength and structural integrity [Pan et al, 2013]. Recycling of Li-ion batteries helps to mitigate environmental effects of virgin metal extractions along with improper disposal of end of life batteries. To fulfill these objectives of the recycling, recovery of pure streams of the involved metals should be considered. In this study, the batteries were first discharged and dismantled in an inert atmosphere (Ar). The electrodes were then heat treated in a box furnace. This was done in order to break the chains of the adhesive (PVDF) and consequently separate the metallic substrates Cu and Al from the electrochemically active compound. This heat-treatment also helped to simplify the dissolution of the metal constituents in the electrochemically active compound from the cathode in the acid leaching process. Solvent extraction was chosen to achieve separation and recovery of metals with higher purity from these leachates. In the scope of the present work, a complete process from the point of dismantling to separation of constituent metals using solvent extraction was studied.

Jan 1, 2014

Dielectrophoresis is a separation technique that uses a non-uniform electrical field to separate particles on the basis of their permittivity. There are many areas of mineral processing that might benefit from the application of dielectrophoresis. These include: coarse removal of gangue, recovery of ultrafine particles, upgrading of flotation concentrates or simply as a laboratory analysis technique. In order to determine the potential value of dielectrophoresis to the mineral processing industry, the response of composite particles was investigated. The electrical properties of composites involve complex relationships between the shape, distribution and permittivity of the individual grains within the rock. The relationship between mineral composition and dielectrophoretic force was measured on single particles from two ore types. The results were used to populate a model that could predict the separation characteristics of the ore. The insights gained from this model separator allowed potential applications of the technology to be examined and their performance evaluated.

Sep 1, 2012

By Y. C. Liu

Arsenic bearing copper-gold ores deposit have been found in most areas of China, especially in southwest. Due to the very closed association between arsenic, copper and gold, conventional flotation and cyanide leaching process may not give positive results. An arsenic bearing copper-gold ore in Sichuan province ,with gold grade of 10.12 g/t, 0.6% Cu and 0.14% As, is characterized by superfine grains with -40 microns fraction accounting for 70.9% and the gold enwrapped mainly by pyrite and tennanite accounts for 34.31%. Arsenic in this ore occurs in isomorphism, deposited in tetrahedrite. The ore was processed primarily in two stage flotation to get copper bearing gold concentrate and pyrite bearing gold concentrate respectively, and sequentially processed by leaching. Under the pressure of 300 KPa and 110~115 ?, the copper-gold concentrate was leached by an oxidizing and catalyzing leach agent then copper and gold were separated from each other in leach solution. The pyrite bearing gold concentrate was processed by cyanide leaching with the leach residue as sulfur product. The test results showed that copper recovery was up to 88.89%, gold recovery up to 89.18% and sulfur recovery up to 92.64%.

Jan 1, 2014

The Sydvaranger magnetite mine was shut down in 1996 due to low iron ore prices. It was reopened in 2009. The flowsheet has remained more or less as in the old plant, based upon two grinding steps followed by magnetic separation. The Sydvaranger magnetite is free of harmful elements and should therefore be sold on the high quality market. This requires a concentrate containing less than 2 % SiO2. In the old plant, this grade was achieved by amine flotation. Amine was preferred as collector because it could be used in process water from the sea. The use of amine has been restricted by the Norwegian pollution authorities during the time the mine was shut down. Test work to replace cationic with anionic flotation is therefore done. Research on activation of quartz with Ca or Mg ions prior to anionic flotation was shown by basic research in the period from 1960 to 1980 to be effective under simplified laboratory conditions. This old research has now been followed up from a practical/empirical point of view. The basic work was mainly done on quartz and iron minerals only. In this case, an actual feed containing a number of minerals common in iron ores is used, in order to demonstrate that a commercial process is possible. Calcium activation is shown to work excellently but requires too high pH to be environmentally and economically attractive. Magnesium activation is a more difficult process, because the maximum concentration of MgOH+, which was shown to be the activator, is about 100 times lower than the alternative CaOH+. Flotation success depends partly upon the ore, some amphibole minerals are more difficult to float than pure quartz. Ordinary batch flotation test work is time consuming. A South African microflotation test cell has shown promise, because work can be focused upon flotation of the more critical coarser fractions of the Sydvaranger ore. Keywords: iron ore concentration, anionic flotation, mineral activation, microflotation, Sydvaranger

Sep 1, 2012

By L. Tong

Stirred milling of laterites offers possibilities for improving liberation and selective size reduction of soft nickel-bearing minerals in laterites. Batch grinding tests were performed in a Netzsch LME4 stirred mill on a siliceous goethitic (SG) nickel laterite sample (-2000 µm particle size) to evaluate the effect of operating conditions such as stirrer speed, grinding time, pH, solid content, water salinity and charge volume. The target was to produce a -38 µm fraction in the milling product with high nickel recovery and grade. Addition of dispersant (sodium hexametaphosphate) was also optimized with respect to the rheology of the slurry. In terms of stress intensity, the optimum grinding conditions for selective size reduction were: 1000 rpm, 50 per cent charge volume. At higher stress intensity (2000 rpm), Ni recovery in the -38 µm product was higher, but Ni grade was low, due to the breakage of the harder siliceous particles. Decreasing the yield stress by modifying slurry pH or adding dispersant improved the rheological properties of the pulp, but had no great influence on Ni upgrade in the fine product. Modifying water salinity by adding 2 M NaCl had also little effect. The breakage of the +38 µm particles in the feed determined Ni upgrade greatly. Ni grade in the -38 µm product decreased with grinding time, suggesting that the Ni-bearing minerals break first, while the harder siliceous minerals have a lower breakage rate. The breakage rates with respect to sample mass for Ni, Mg and Si indicate that: Mg > Ni > Mass > Si. The optimum grinding time for the highest Ni upgrade was 0.25 min. The Ni grade increased from 0.88 per cent to 1.35 per cent (upgrade 54 per cent), with 24 per cent Ni recovery. Keywords: fine grinding, stirred media mill, nickel laterite, slurry rheology

Sep 1, 2012

By Sirish L. Shah

It is now common to have archival history of thousands of sensors sampled every second over long time. Yet we frequently have process engineers complain:??.We are drowning in data but starving for information??. How can these rich data sets be put to use? This paper addresses the issue of information and knowledge extraction from data with emphasis on process and performance monitoring including fault detection and isolation. Most of the major plant, factory, process, equipment and tool disruptions are avoidable, and yet preventable fault detection and diagnosis strategies are not the norm in most industries. It is not uncommon to see simple and preventable faults disrupt the operation of an entire integrated manufacturing facility. For example, faults such as malfunctioning sensors or actuators, inoperative alarm systems, poor controller tuning or configuration can render the most sophisticated control systems useless. Such disruptions can cost in the excess of $1 million per day and on the average they rob the plant of 7% of its annual capacity. Over the last decade the fields of multivariate statistics and data visualization and analysis methods have merged to develop powerful sensing and condition-based monitoring systems for predictive fault detection and diagnosis.These methods rely on the notion of sensor fusion whereby data from many sensors or units are combined with process information, such as physical connectivity of process units, to give a holistic picture of health of an integrated plant. Such methods are at a stage where these strategies are being implemented for off-line and on-line deployment. This article attempts to outline the field of sensor fusion - the application of signal processing methods, in the temporal as well as spectral domains, on a multitude and NOT singular sensor signals to detect incipient process abnormality before a catastrophic breakdown is likely to occur Keywords: Process analytics, process and performance monitoring, multivariate statistical analysis, sensor-fusion

Sep 1, 2012

By Jingzhong Kuang, Zheyu Huang, Chuanzhou Guo, Pengfei Liu

"In this paper, scheelite and scheelite coated with Pb2+ (SC) were synthesized by chemical precipitation with the help of ultrasonic. The role of the Pb2+ on scheelite was evaluated. Additionally, the dissolution behavior of minerals and the adsorption mechanism of collectors were investigated systematically via SEM, XRD, EDS. The results indicate that the ultrasonic cavitation can promote the formation of scheelite with large particle size and high crystallinity. Due to the exchange of WO4 2- and OH-, the dissolution of scheelite are not in a 1:1 equivalent amount by chemical formula and the concentration of WO4 2- is higher than that of Ca2+ in the solution because Pb2+ promotes the transfer of WO4 2- from scheelite surface into the solution. The dissolution of scheelite is an endothermic reaction and its enthalpy reaches the maximum value of 692.59J·mol-1 at pH=8~10. But the coating of Pb2+ changes the thermal effect of scheelite in the solution and the dissolution of SC is an exothermic reaction with the dissolution enthalpy of -262.30 J·mol-1. At pH=8~10, the adsorption capacity of sodium oleate and salicylhydroxamic acid on the surface of SC is higher than that of scheelite which delivers that Pb2+ contributes to the scheelite surface dissolution and enhances the adsorption of collectors on the mineral surface, thus achieving activation.INTRODUCTIONIn modern society, tungsten is a type of quite important rare metal and also a strategic resource. Because of its low vapor pressure, high melting point, good electrical and thermal conductivity properties, it is widely applied in high-temperature technology, lighting, machine and engine construction (Zhao,Z.W, 2013; Yan, W, 2017; Ilhan, S, 2013). Both scheelite and wolframite are the major tungsten deposits. With the depletion of easily-processed wolframite, scheelite has drawn a great deal of scientific and industrial attention. Scheelite can be recovered by flotation due to the metathesis of polarity and chargeability on minerals surface via adding regulators and collectors."

Jan 1, 2018