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By Avishan Atrafi, Marek Pawlik

"Gas dispersion properties of sodium salts of 6, 12 and 18-carbon fatty acids (hexanoic, lauric and oleic acid) were investigated as a function of pH. A strong effect of pH was observed on gas dispersion properties of fatty acids. At high pH for 12 and 18 carbon fatty acids, at which these surfactants formed a true solution, the gas dispersion properties were similar to those of MIBC. In the case of sodium hexanoate, which has a much higher solubility than the longer chain fatty acids and therefore does not form precipitates, the gas dispersion properties of this surfactant were strongly enhanced in the acidic pH range, where hexanoic acid was fully associated. This result is an indication that undissociated hexanoic acid is much more surface-active than anionic hexanoate. Only a small effect of the surfactant chain length on gas dispersion properties of the tested reagents was observed. The measured critical coalescence concentration (CCC95) values increase slightly by decreasing chain length and range from 5.8 x 10-5 mol/L (17.7 mg/L) for sodium oleate to 7.2 x 10-5 mol/L (16 mg/L) for sodium laurate at pH 10 and 1.9 x 10-4 mol/L (26 mg/L) for sodium hexanoate at pH 3.7. These are compared to CCC95 of MIBC, which is measured to be 8 x 10-5 mol/L (8 mg/L). The soluble molecular species were recognized as the most effective species in preventing bubble coalescence."

Jan 1, 2014

By M. Bhartia

India is the 5th largest producer of steel in the world and is slated to produce more than 180 Mt by 2020. Expectedly about 50 % of this would be through the Blast furnace route and the rest through Sponge iron / DRI route. Considering that there will not be any major change in iron making technology by that time, the Blast operation would require lump ore (10-40mm) with around 64% Fe grade and sinter fines (<10mm) with 60% Fe (min) as its feed. DRI process would need calibrated ore of size 5-18 mm as the most suitable size of feed. It is also expected that of the total requirement of ore for the DRI route a significant part would be DRI pellets. In India, there is considerable debate going on regarding the technology to be adopted for the processing of iron ore and there is a lack of clear consensus. The above scenario indicates that the processing requirement of iron ore in the country would involve both washing technology as well as beneficiation technology. CDE Asia Ltd is in the forefront of iron ore processing in the country and the experience gained by the company over the last few years of functioning has led the company to believe that route to be adopted depends on the end product requirement and the starting grade of the feed. Keeping in mind the nature of the feed required for the Blast furnace & DRI operation; it is obvious that good washing technology would be highly beneficial to the iron ore industry. Depending on the grade of ore available the limits of washing will be decided and equipment for lump ore beneficiation such as jigs could be incorporated into the washing circuit. Scrubbing of ore either before washing or selectively scrubbing the lumps could be necessary. Very low grade ore and jig rejects would be required to be totally ground and beneficiated for the production of pellet feed in order to utilize the iron ore resources entirely. Another source of ore for pelletisation would be slimes generated from the washing process as well as the huge quantities already available in the tailings dams in the operating mines. Deslimimg and magnetic route of beneficiation could release at 30-40% of the Fe locked up in these tailings ponds/dams. The paper describes the concept with examples from operating plants and proposes how the adoption could be engineered through test work and proper plan of integration. Keywords: washing, beneficiation, iron ore, lumps, sinter fines, pellets, jigs, screens, evowash, nanowash, thickeners, log washers, drum scrubbers

Sep 1, 2012

By Brian Loveday, Sandile Nkwanyana, Indresan Govender

"Recent batch experiments by the authors in a pilot scale ball mill (Ø = 0.6m) have demonstrated that a partial replacement of the ball charge by pebbles (25 % pebbles; 75 % steel balls) optimally reduces the ball and power consumption without altering the rate of production of fine material (passing 75 microns). At higher pebble volumes, the production rate of fines was reduced progressively. With the 25/75 composite charge a saving of 13 % in power consumption was achieved, and a saving of 25 % in steel ball consumption is implied. A partial replacement of steel balls by pebbles reduces the overall density of the grinding media in the charge. Taking into consideration that the production rate of fines is usually proportional to the bulk density of the charge in the mill, it would be expected that a composite charge (e.g. 25/75) would coarsen the grind and consequently reduce the rate of production of fines. Pebble wear contributes a small proportion of fines and it doesn’t provide a full explanation of why the 25/75 composite charge has no (or minimal) adverse effects on the rate of production of fines. Clearly, the production of fines across the mill is directly related to the shear and compressive power dissipation density. Accordingly, we hypothesise that the spatial power dissipation distribution meeting the minimum requirements for fines production— at the so-called active regions—are equivalent, or minimally comparable, for both the 25/75 composite and 100 % ball charge operating conditions. To test the hypothesis, we performed DEM simulations to analyse power dissipation in the active regions. 1. INTRODUCTION Comminution remains to be the most expensive process in mining operations, particularly because the energy consumed in this process accounts for 30-70 % of the total cost of a mining operation (Nadolski et al, 2014). Optimization of comminution circuits has been focussed on reducing capital and operating costs and maximising throughput capacity. For existing operations, it is often a challenge if the optimization process recommends retrofitting new ‘major’ equipment. The challenge arises from new capital cost and the difficulty of retrofitting in an existing circuit, while maintaining production (Major et al, 2001). Thus, for existing mining operations, optimization of comminution (cost and throughput) is often limited to operating conditions and/or addition of auxiliary equipment (such as pebble crushers, additional screens and high pressure grinding rolls (HPGR)) (McIvor and Greenwood, 1996; Hart et al, 2001; Powell et al, 2015b)."

Jan 1, 2018

By Anand Anupam

Conventionally, beneficiation in Indian coal washeries is done using dense medium cyclones upto the size of 0.5 mm. Coal fines below 0.5 mm size are extensively cleaned by froth flotation. There are many problems associated with flotation of Indian coals, e.g. poor response of coal particles to flotation, misplacement of fine high-ash material to froth, loss of good quality coarser coals (within ?0.5 mm size range) to tailing streams, high cost of reagents, water contamination, etc. In addition, sophisticated control systems for efficient management of the fines washing circuits are needed. Thus, there is an escalation in the capital and processing costs. In view of these facts, studies were carried out to establish the cleaning potential of dense medium cyclones for beneficiation of fine coal down to a size of 0.1 mm, essentially aimed at reducing the load on fine coal circuits mainly comprising of flotation. ROM Coal (in the size range of -2 + 0.1 mm) obtained from JogtaOCM,Jharia coalfield possessing relatively low ash (about 21%) was used in this study. Purpose for using low ash coal was to further lower, its ash content down to 8% which is comparable, to the ash content of imported coal. After characterization studies, nine tests were carried out on the prepared feed sample for its beneficiation using a dense medium cyclone of non-conventional design (very low cone angle and longer barrel), by varying its apex and vortex finder diameters. The efficiency of separation has been evaluated using Tromp curves. It could be established that it is possible to produce a clean coal of 8% ash, with Ep value of 0.044, using Jogta OCM coal by treating it in a modified dense medium cyclone. These results are summarized and discussed in detail in the present paper. Keywords: dense medium, cyclone, fine coal, beneficiation, Jharia coal

Sep 1, 2012

By Tom Liu

This paper is a fundamental study of bubble-particle collision efficiency in turbulent flows. A CFD-based microscale scheme for the prediction of turbulent bubble-particle collision efficiency in a 3D isotropic turbulent flow is developed, and in this way, turbulence effects on particle-bubble collision efficiency are taken into account for the first time. By comparing the computed results with experimental data from the literature, the CFD simulation is shown to correctly predict the bubble-particle collision efficiency in a quiescent environment. The CFD method was then applied to the investigation of bubble-particle collision efficiency in a turbulent flow, and the simulation results are shown to be qualitatively consistent with the real observations. The predicted collision efficiency can be used in a multiscale modelling scheme, which would account for all control variables in a flotation cell, such as impeller structure and tip speed, air nozzle structure and air flow rate This study indicates how microscale simulations of bubble and particle behaviours, coupled to macroscale CFD simulations of flotation cells, can provide a powerful tool predicting the flotation rate in a real flotation cell.

Jan 1, 2014

By Duong Huu Hoang, Nathalie Kupka, Urs A. Peuker, Martin Rudolph

"The froth ability, froth stability and the froth structure are strong influences in flotation process i.e. on water recovery, bubble size, entrainment of gangue particle, flotation rate constants, grade and recovery. The labscale flotation of rich apatite ore with a high mass pull leads to significant changes in pulp and froth properties over time. The froth stability decreases with increasing the flotation time. These changes can be related to different solid contents, reagent concentration, froth heights and bubble size distributions. This study presents the results from froth studies and discussions on the particle size of fully liberated silicates and degree of entrainment based on automated mineralogy size-by-size analysis. The change of entrainment in a rich apatite ore batch flotation with time will describe more precisely by measuring froth properties using a Dynamic Foam Analyzer. It is concluded that the degree of entrainment is not only dependent on particle size but also the pulp density due to its effect on particle settling and also froth properties in varying resistance to particle drainage. Furthermore, entrainment models are applied to predict the effect of size, flotation time on entrainmentINTRODUCTIONFroth flotation belongs to the group of heterocoagulation separation techniques. Froth flotation is classically divided into two active zones, the pulp zone (where particle collection occurs) and the froth zone. A schematics drawing of the interaction between both zones is plotted in Figure 18 (Yianatos and Contreras, 2010). In froth flotation, the collision probability in the collection zone is governed by the physics of the process or hydrodynamics (Wills and Finch, 2016). The true flotation event in the pulp occurs when the hydrophobic valuable mineral particles collide with bubbles and formation of a stable particle-bubble aggregates moving upwards against gravity to the froth phase (Yianatos et al., 2009)."

Jan 1, 2018

By M. Saghaeian, R. Hejazi, M. Mohammadinejad, M. Zare

"Water quality and quantity at the Tailing Thickening Section of processing plants is considered to be a crucial factor and impacts the performance of several sections. Therefore, gaining stable and effective performance at the Tailing Thickener Section is one of the principal goals of minerals processing plants. Different factors such as: qualitative and quantitative sustainability of plant feed, the balance between the mass of input and output water flow, the dissolving method and distribution of flocculant and the amount of dirt, solid percent of thickener inlet pulp, affect the performance of Tailing Thickener. The present study investigates the successful improvement of Tailing Thickener performance at Jalal Abad Hematite Iron Ore Concentrate plant through optimizing the above operational parameters. For this purpose, the following optimizations have been done: homogeneity and sustainability of plant input feed rates, fine pulp removal collected by the bag filters at the input of the thickener, adding an quietness box before moving the tail pulp into the thickener to reduce the pulp turbulence, replacing flocculant pump and injection pipes, improving water mass balance which leads to optimizing and stabilizing the concentration of input tail pulp into the thickener, adding a mixer to increase the flocculant preparation time, increasing the locations for adding flocculant to thickener from 1 point to 6 points. Applying the above modifications and monitoring the Tailing Thickener performance over the course of months, has led to the improvement of recovered water quality from 500 ppm to 200 ppm, increasing the solid underflow of the thickener from 40% to 48.5%, and similarly, reducing water loss by 60%. Of other important effects, due to improvement of water quality, grade of final concentrate 0.5% increased and because of 73% increase in monthly working hour, concentrate tonnage 55% increased. Finally, sludge thickener optimization has had a significant effect in selecting and designing the dewatering system from the underflow of the sludge thickener."

Jan 1, 2018

By Yuhua Wang, Huilan Yang, Yanqing Jiang, Dongfang Lu

"Generally, the concentration of bauxite flotation tailings is around 10%, a large amount of water in tailings needed to be recycled in the flotation process. Sedimentation and dewatering properties of tailings were investigated under different conditions. Surface high negative charges on mineral particles are the key factor to destroy the settlement of tailings when the pulp pH is around 8.9. Hence, the modification of pulp pH around 7 is necessary to the diminution of the repulsive force between mineral particles and then the acceleration of sedimentation of tailings. Anionic polyacrylamine with molecular weight of 14 million is the best flocculant for the settlement of tailings in all tested polyacrylamines. P-toluene sulfonic acid shows better properties than hydrochloric acid for pulp pH adjustment when anionic polyacrylamine with molecular weight of 14 million is used as flocculant. Although the flotation of diaspore is depressed in the presence of polyacrylamine using sodium oleate as collector, but the recycling water traded by the combination of ployacrylamine and p-touenesulfonic acid does not show the depression effects on the flotation of bauxite ore. The lower residual content of polyacrylamine in recycling water treated by the combination of ployacrylamine and p-touene sulfonic acid plays an important role. INTRODUCTION Generally, the waste water generated from mineral processing plant is usually treated by sedimentation, oxidization, electrodialysis, ions exchange, active carbon adsorption and flotation technology, and the treated water is also used again in the industrial process. Flotation was adopted widely to improve the quality of bauxite from low grade diasporic bauxite in China. For flotation, the grinding fineness of bauxite is over 90% -0.074 mm, sodium carbonate and sodium hexametaphosphate were used as regulators, so the tailings pulp is very difficult to settle and be dewatered (Y. Wang et al., 2004; Y. H. Wang et al., 2007; Wang Yu-hua et al., 2008; Wang Yuhua et al., 2011). The water recycling of bauxite tailings are becoming the highlight for the industrial application of the flotation process for bauxite ore. Researchers in China shift their attentions onto this topic."

Jan 1, 2018

By W. Kobal

The extraction of nickel (Ni) and cobalt (Co) from the laterite deposit of Ramu nickel-cobalt Project in Papua New Guinea was performed in this study. Chemical analysis by Inductively Coupled Plasma (ICP-AES) atomic emission spectrometer, SPS-3000 (Seiko Instruments (Inc.), shows the ore contains 48% Fe, 1% Ni, 0.1% Co, 1.8% Al, 0.14% Mg, and 0.8% Mn. Characterization by X-ray diffraction (XRD) analysis of the laterite ore obtained from the mine site shows the ore contains 70 to 80% goethite (FeOOH), assuming Fe content of 48% is mainly from geothite. The main leaching parameters investigated include; slurry temperature, leaching time and sulphuric acid (H2SO4) concentration to evaluate nickel and cobalt extraction. For all experiments, 10g batch samples are put into 300 ml beaker containing 100 ml of sulphuric acid of varying concentrations (1M, 2M, 4M). During the leaching period, 5 ml slurry samples are withdrawn at different times and filtered to obtain filtrate for ICP analysis to monitor nickel and cobalt extraction. Solid samples at the end of all tests are also obtained by filtration and after drying, XRD and ICP tests are performed to monitor nickel and cobalt contents. According to the test results performed at normal atmospheric pressure, over 99% of nickel and over 50% cobalt were extracted into solution within 120 min at 95ºC in 2M H2SO4 solution. Similar results were obtained when only temperature was reduced to 90ºC, but cobalt extraction increased to over 70% when leaching time was increased to 240 min. Further reduction in temperature to 80 and 60ºC resulted in reduction of nickel and cobalt extraction. At the end of each leaching test, magnetite was seen to attach to magnetic stirrer. The study showed nickel can be completely leached into solution but cobalt only up to 70%. Keywords: atmospheric pressure, sulphuric acid leaching, nickel laterite

Sep 1, 2012

By Chenyang Zhang, Zhigang Yin, Jianyong He, Yuehua Hu

"A lot of floatation reagents (collectors, inhibitors and regulators) for the beneficiation of copper ores have been well developed in the past century. However, it is still unclear about the micro interaction mechanism of these flotation reagents with copper ores. In this paper, the interaction mechanism of these flotation reagents with the copper atom on chalcopyrite has been systematically investigated by first principle DFT (density functional theory) calculations. Thirty-four specific common functional groups linked with the same hydrocarbon chain (ethyl) are optimized at a B3LYP/def2-TZVP level, the solvation effect was included with the SMD solvation model. The analysis of the highest occupied molecular orbital (HOMO), the lowest unoccupied molecular orbital (LUMO) and nature bond orbital (NBO) charge of these reagents reveals their potential applications to other types of copper-bearing mineral. Further investigation of the thermodynamics calculations gives more reliable data to screen collectors or inhibitors for copper-bearing mineral. The flotation results from carefully reviewed literatures are in good agreement with the calculation results. This work might also shed new light on the development and discovery of highly efficient and selective flotation reagents with low cost based on the computational methods.INTRODUCTION Froth flotation,(Shean & Cilliers, 2011) a mineral processing approach, is applied to efficiently enrich valuable minerals from the mixture, which is achieved according to the dictinctive surface properties of minerals. In the past century, researchers have develped an aboundant of flotation reagents by extraction or synthetize, and many carefully selected reagents might die in the bench tests or the pilot tests before the pratice.(Bulatovic & SrdjanM, 2007) Generally, it involves a lot of cost and tedious works by conducting flotation tests to screen flotation reagents. Flotation reagents have been boomed robustly with the developing of the organic synthesis.(Liu, Yang, & Zhong, 2017) Reseachers found the specific properties of a reagent are determined by its functional groups and the length of the hydrocarbon, where the functional group is assigned as the adsorption site to adsorb onto mineral surfaces and the hydrocarbon chain is called as a hydrophobic group."

Jan 1, 2018

By J. Jirestig

Poor grade iron ore, suffering from interlocked particles, is challenging for any process technology. Extensive grinding is required to attain liberation and to yield concentrates of desired grade. Fine particles are commonly very difficult to retrieve, resulting in value losses to tailings. In this paper, results from HGMS tests on fine to ultra fine hematite are reported. Special emphasis is put on slurry flow velocity. If hydrodynamic drag force, i.e. flow velocity is not controlled and kept constant during the feed and/or rinse phase, fine particles will not be captured and retained. Flow velocity control and constant flow during separation are achieved by discharge valves/slots and parallel magnetic flux and pulp flow configuration. In tests, increased slurry velocity from 178 to 268mm/s caused Fe-recovery to drop from 78 to 48%. Proving that flow velocity control is essential to optimise grade and recovery. HGMS tests at the Metso mineral laboratory on natural (weathered) hematite fines clearly show a large potential to recover valuables, currently lost to tailings. Even at particle size distributions as low as D80=35µm concentrate grades and recovery are very satisfying. Two samples, in-plant desliming rejects (D80=35µm and 50µm) where significantly upgraded and recovered, from 45,3% to 63,6% and 53,0% to 63,4% Fe, at 73,8% and 81,1% Fe-recovery respectively. Other types of in plant rejects, such as gravity separation or WHIMS tailings, also benefits from HGMS separation. Gravity separation reject, 55,8% Fe, at D80=500µm was tested, yielding a magnetic concentrate of 60,8% Fe at 50,7% Fe-recovery. The results indicated that the hematite was poorly liberated. HGMS separation was repeated after a regrind to D80 150µm, resulting in a magnetic concentrate of 62,8% Fe at 75,9% Fe-recovery. The tests prove that hematite, presently lost to tailings streams, can be recovered by HGMS and thereby significantly contribute to improved overall economy. Keywords: HGMS, magnetic separation, recovery of ultra-fine hematite, Indian hematite ores, hematite recovery from tailings

Sep 1, 2012

By D. Z. Wang

A red copper plate, discovered in the ruins of Dachengshan in Hebei province, was recognized as a forged one rather than a cast one, which means it was probably made from natural copper during the Longshan Culture period (2200~2208 BC) in the Chinese history. The copperware, found in the Niangniang Tai relics in Wuwei city, Gansu province, contains 99.6% copper and 0.4% Sn, Pb, Sb and Ni, which was guessed to be made during the Qijia Culture about 2000~ 1900 BC in the Chinese history in the late Neolithic before Shang dynasty. This shows that Chinese ancestors were able to distinguish, sort and use some native metals and minerals more than 4000 years ago.

Jan 1, 2014

By N. Dhawan

In the last decades, High Pressure Grinding Roll (HPGR) has gained significant importance in hard rock processing due to numerous metallurgical benefits such as energy savings, particle weakening, preferential damage of coarse particles, and preferential comminution-liberation. There are a limited numbers of lab-scale HPGR units throughout the world. The laboratory-scale HPGR machine at the University of Utah is first-ever lab-scale machine designed by late Dr Klaus Schönert, the inventor of HPGR. This HPGR is constructed with two counter-rotating hardened tool steel rolls, each 200 mm in diameter and 100 mm in width. The HPGR unit is equipped with eight sensors and a robust control system, which serves as an ideal system for fundamental studies and lab-scale testing. In HPGR operation, throughput, energy and product size distribution are intricately linked to specific grinding pressure, roll gap and rolls speed. The nip angle existing during the operation determines the volume of feed material above the rolls that is pulled into rolls without slip. In this paper, scale-up factors and some of the existing models have been reviewed. A number of experiments have been carried out with limestone and a slag material. The influence of operating variables and their complex relationship has been studied.

Sep 1, 2012

By T. Moloane, C. Bergman, Heloise Thiele

"A pilot test campaign was undertaken to evaluate dense medium cyclone separation efficiencies on samples of iron ore fines (-1mm +300µm). Evaluations were done using both gas and water atomised FeSi types across a range of operating conditions in the presence of slimes build-up. A Mineral Liberation Analyser (MLA) was used to measure size, density, shape and liberation data of DMS feed and products. The results of the test work were used to obtain parameters for modelling of the partition size/density response. The findings indicated that accurate density characterisation of the feed ore is essential in understanding product quality and recovery, particularly due to the effect of porosity and micro-inclusions. A significant off-set between cyclone underflow density and separation cut-point (D50) was found indicating that relatively low feed media densities (about 3.4g/cm3) are required to achieve high density cutpoints of over 4.0g/cm3. In agreement with CFD modelling, the separation quality is dominated by viscous effects, hence FeSi type and slimes content will need to be carefully controlled to ensure efficient separation.INTRODUCTION In the South African context, future resources of hematite are expected to be both of lower head grade and will contain a higher content of banded iron formation (BIF) (1). These ores may require finer crushing in order to liberate the high-grade fractions and will thus increase the amount of -1mm material to be processed. In order to efficiently upgrade these materials, it becomes necessary to re-examine both traditional and novel processes to treat material finer than 1mm in size. These include spiral and up-current classifiers, wet high intensity magnetic separation processes, Reflux classification and potentially includes dense medium separation (DMS). This study presents a technical evaluation of fines DMS using a mineralogically-based particle tracking analysis method (PTA) to calculate efficiencies of separation."

Jan 1, 2018

By Elves Matiolo

This paper describes, in detail, results obtained from a research study of a complex iron ore aiming to produce a pellet feed concentrate with at least 65% of Fe and less than 3.5% of SiO2 in the final concentrate. The work includes an ore desliming followed by column flotation at laboratory scale. The ore sample was from Carajás province - Brazil and represents a complex low grade compact itabirite ore, analyzing 35.9% Fe, 45.1% SiO2 and 0.57% of Al2O3. Yet, the feed was treated previously by magnetic separation and grounded to 97% < 20 µm; this sample was named MAG 2. The chemical and mineralogical characterization of the MAG 2 sample showed that Fe and SiO2 grades were 50.7% and 24.3% respectively and was composed mainly by hematite, goethite and quartz. The particle size distribution, using a laser diffraction technique, showed that 90% of the particles were < 18 µm; 50% less than 8 µm and 10% minor than 1 µm. When the cationic reverse flotation without desliming was tested the selectivity of the process was very low and did not meet the concentrate metallurgical goals of the pellet feed product. However, when desliming was applied prior to flotation, a concentrate product with chemical characteristics of the pellet feed was obtained. The best results after desliming and column flotation achieved global iron metallurgical recovery of 72% with Fe grade in the concentrate of 66.5% and 2.1% SiO2 using starch as depressant for the iron oxides minerals at 1200 g/t ? 1500 g/t and an amine as the quartz collector at 100 g/t concentration (pH constant, at 10.5). It is believed that the desliming stage was key in the separation of the iron bearing particles and has a high potential for the flotation process of this type of ores.

Sep 1, 2012

By Y. M. Fu

In order to evaluate the flotation process, the process flow sheet was investigated. The process mineralogy of main products was studied. Through chemical mineralogical and screening analysis as well as surveying using a microscope and scanning electro-microscope, the oxidation degree and mineral composition of main-products the liberation of main minerals, the occurrence of elements such as Pb, Zn were revealed. It is pointed that to determine the flotation process, the type of prod-ucts optimum grind of original ore and middling was provided on the basis of liberation of main minerals is reliable. As correct finer ground original ore, first high-grade lead-concentrates and zinc-concentrates fast was floated from a great part of free of the galena and sphalerite of liberated. Then for finely re-ground middling of locked mineral grains of difficult liberation, mixing lead-zinc-concentrates second was floated. The four products was best in contact with characteristic of ore of Fan Kou. Therefore be obtained certain to successful economic effect.

Jan 1, 2014

By Haragobinda Srichandan

The present study aimed to investigate the bioleaching efficiency of moderate thermophilic microorganism in a growth medium without Fe supplement on three different size fractions of spent catalyst obtained from petroleum refinery. All the experiments were conducted on shake flasks at a temperature of 65 °C and a pulp density of 10% (w/v) on three size fractions viz. 45-106 µm, 106-212 µm and >212 µm and a working volume of 100 ml comprising of 10 ml of microbial inoculums and 90 ml of Modified Kelly medium. The parameters like pH, redox potential, viable planktonic cell count and the amount of acid addition was measured and quantified on regular basis to follow the progress of the bioleaching. The pH varied much in the lag and logarithmic phase of the experiments but stabilized toward the stationary phase. The total acid additions in each batch experiment were determined the amount of Conc. H2SO4 requirement, which ranged between 683-757 kg/ton of spent catalyst. The redox potential values ranged between 625-650 mV, Ag/AgCl, but were very low ranging between 350-450 mV during initial period. The planktonic viable cell count ranged between 108-109 cells/ml active in the bioleaching system, without any toxic influence of the spent catalyst, but initially due to fall in redox potential and new environment for the microbes, their population was low. The leaching yield of Ni was found to be promising with very high leaching yield of 92-96% followed by Al as 61-62%, which means both Ni and Al leaching were favored by the moderate thermophilic bioleaching compared to the mesophilic bioleaching. There was very little difference in the leaching yield, when compared with different size fractions and hence grinding can be avoided prior to leaching. This process seems to be economical as no Fe source is supplemented together with no requirement of grinding and over all a biological process resulting for an eco-friendly process for future optimization of the metal recovery from petroleum refinery spent catalysts. Keywords: bioleaching, spent catalyst, thermophile, 9K medium

Sep 1, 2012

By A. A. Rogozhin, E. G. Likhnikevich, S. I. Anufrieva, A. V. Kurkov

"Russia is among the nations holding the world's largest lithium ore reserves. Lithium is of key importance for the global economy. Therefore, it is important to review the current state of technology research aimed at finding the most effective solutions for the recovery of lithium from promising reserves in Russia. In Russia, a number of process solutions for the flotation of spodumene into salable concentrate (5% Li2O) have been implemented at the earlier existing complex low-grade ore concentration project. By applying these solutions, a sample of high-grade spodumene ore (4.7% Li2O) of the Greenbushes deposit was processed into a spodumene concentrate (7.5% Li2O) at a high recovery (~93%) of lithium. In Australia and Canada, new processes have been developed for the recovery of high-grade spodumene concentrates from high-grade ores using dense medium separation and flotation. For the recovery of mica lithium concentrates from low-grade ore, a flotation process was developed in Russia using the cationic collector ANP-2 and Oxifos-B as an additional collector. Low-grade ore containing 0.14% of lithium oxide was processed into a 2.7% Li2O concentrate. New hydrometallurgical lithium concentrate and ore processes are developed to avoid high-temperature (>1000 °C) roasting. The Sileach process (Australia) includes leaching of lithium ore with sulfuric acid in the presence of a halogen-containing component at a temperature of 95-115 °C. In the Russian process, lithium is recovered into an alkaline solution from low-grade spodumene ore in a pressure alkaline leaching environment (250 °C, NaOH concentration > 300 g/l). The developed concentration and hydrometallurgical methods will allow to design on their basis efficient processes for recovering salable products for hi-tech industries from lithium ores.INTRODUCTION Lithium has many unique and important properties. It is the least dense hard metal. Its alloys have some of the highest strength-to-weight ratios. Lithium has the lowest melting point of all known solid elements and is used as a highly-effective heat transfer medium. The high demand for lithium is due primarily to its unique electrochemical potential and low thermal expansion coefficient. It is used in the production of glass and ceramics, in petrochemicals, metals, medical and other industries. Since the late 20th century, the electronics industry has been the largest consumer of lithium. In recent years, lithium has attracted much attention also as an important component of ultra-lightweight electronic devices. It is also the preferred metal for electric batteries used in mobile electronic devices, vehicles, household power generators, making it an important resource for the development of environmentally friendly technology. Leading automotive brands have ambitious plans for the production of electric cars — Tesla Motors, VW, Toyota, GM, BYD Auto. It is expected that the production of electric vehicles alone will triple the demand for lithium by 2025. A sharp increase in the production of lithium is expected. Lithium has all the prerequisites to become a strategic resource of the 21st century. (Deutsche Bank, 2016; Bradley et al, 2017)"

Jan 1, 2018

By I Brum

Brazil and Colombia have large reserves of coal, those reserves in Brazil are located predominantly in the south and Colombia the main reserves are located in the north. Despite the relative ease of exploitation, these resources have been underestimated as a source of energy. Currently, these countries are developing projects and partnerships aiming to qualify this mineral resource, adding quality to the final product of the processing plants. In this scenario the processing of Brazilian and Colombian coal in flotation columns appears as a promising alternative, having been successful in mineral systems containing fine particles This paper aims to study the overall process of column flotation for a specific Brazilian coal and a specific Colombian coal. The material used in this study consists of fine coal from Brazil (Copelmi) and Colombia (Cerrejon). The objective is to recover carbonaceous matter and reduce the ash and contaminants grade. The two coals were floated using a negative bias in a 5 cm diameter conventional flotation column of 5 m high. Flotation parameter investigated included air velocity in the range 0.6 to 1.5 cm/s. For all runs, a constant negative bias of -0.25 cm/s and a pulp concentration of 8% w/w were used. For Cerrejón coal, 300 g/ton of frother and 907 g/ton of collector was used, whereas for Copelmi coal, 600 g/ton of frother and 1815 g/ton of collector was employed. The frother was a commercial Aerofroth 65 (AF65), whereas the collector was Kerosene. For the Colombian coal, in general, yield, organic recovery, ash recovery and water recovery decreased with the increasing air rate. However, for Brazilian coal the air rate had no significant effect. For Colombian coal, the highest yield (60% w/w) and organic recovery (69% w/w) were obtained at the lowest air rate (0,6 cm/s). Keywords: negative bias, column flotation, coal

Sep 1, 2012

By Sergio Castro, Janusz Laskowski

In the flotation in highly concentrated electrolyte solutions not only ionic strength but also chemical composition, flotation pH and mineral properties play an important role. As a result an improvement or depression may be observed. A strong improvement in the floatability of hydrophobic bituminous coals and other inherently hydrophobic minerals is characteristic for the "salt flotation process", which is carried out in concentrated electrolyte solutions at natural pH and without addition of any flotation reagents. However, pH is a key factor when saline and hipersaline waters with hydrolyzing metallic ions are used as process water. In the case of flotation of Cu-Mo sulfide ores in seawater, molybdenite is strongly depressed by the Mg2+ hydrolysis products when pH is raised to depress pyrite. Process water with a high content of Mg2+ and Ca2+ ions, and this also includes seawater, have deleterious effect on the anionic flotation of industrial minerals with fatty acids. The flotation of potash ores is carried out in NaCl-KCl saturated brine (6-7 mole/L of NaCl and KCl) with the use of long-chain amines. Such a high electrolyte concentration changes dramatically the amine Krafft point making the collector insoluble in brine; its mode of action entirely differs from that in conventional flotation processes.

Jan 1, 2014