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By Sergei Decterov, Peter Hayes, Evgueni Jak, Taufiq Hidayat, Denis Shishin

Copper smelter operations around the world are under sustained pressure to reduce costs and increase output. Through the provision of reliable data on fundamental properties of the chemical systems the opportunities for improvements of industrial copper production can be identified. Experimental and modelling studies on phase equilibria, thermodynamics of copper slag/matte/metal/gas systems have been combined into an integrated research program undertaken at PYROSEARCH. Experimental phase equilibria studies involve high temperature equilibration in controlled gas atmospheres, rapid quenching and direct measurement of compositions of equilibrium phases with electron probe X-ray microanalysis (EPMA). Thermodynamic databases development and modelling is undertaken using the computer package FactSage in conjunction with advanced models used for complex solution phases. Progressive development of these research methodologies has brought significant advances in characterisation of these complex systems, including a new optimised thermodynamic database for the copper-containing slag system Cu2O-Al2O3-CaO-FeO-Fe2O3-MgO-S-SiO2.The new data and models can now be applied to assist in improvements of the processes. The effects of changes to chemistry and process conditions within the smelting reactor can be examined. Several examples of new descriptions of the phase chemistry of the Cu2O-CaO-SiO2 and Cu2O-FeO-Fe2O3-SiO2 systems in equilibrium with metallic copper showing calculated and experimental data are presented.

Jan 1, 2014

By Jessica Egan, Daniel Hodouin, Mohammed Reza Khalezi, Steve Bellec, Claude Bazin, Carl Duchesne

"A model for gold leaching was developed and implemented into a simulator. The simulator uses a description of the ore that is based on the mineral composition and precious metal content. The model accounts for the distribution of minerals and precious metals through the size intervals. An ore texture model based on precious metals and minerals grain sizes within the ore is used to predict the exposed surface of the species in the various size intervals. A model is proposed to predict the rate of dissolution of any species dissolution using the exposed surface, particle size, cyanide and oxygen concentrations, temperature, pH and agitation. The flow of slurry through a leaching tank is modelled using a parallel arrangement of perfect mixers to simulate a bypass and a Cholette-Cloutier mixer model. The simulator can be used for circuit optimization but was developed to provide an environment for learning the basic concepts of process analysis methods. Examples are given to illustrate the application of the simulator for planning tracer tests and sampling campaigns.INTRODUCTIONThe constant pressure to improve the operation of processes that are already close to optimum imposes to plant engineers to be aware of the available process analysis tools and to be able to use them to assess process operation and make a diagnosis to possible problems. Some of these tools are:•,Sampling the streams of a process;•,Data reconciliation;•,Analysis of mixing in reactors;•,Estimation of rate parameters;•,Optimal tuning and flow sheet modification;•,Automatic control and real time optimization.Although some of these tools are part of the curriculum of many university engineering programs, the students are not exposed to actual process analysis problems. In addition the complexity of the ore dressing processes compounded with unavoidable measurement errors and plant disturbances can discourage many motivated engineers. These factors often lead to an incomplete valorization of the collected data and a poor return on the investment associated with the sampling, testing and analysis of the samples.Simulators are readily available for process optimization (Yalcin and Shang, 2006) by allowing:•,The simulation of various flow sheet configurations;•,The simulation of a change of operating conditions;•,The simulation of various control strategies;•,The training of plant operators.However few simulators have been developed with the objective of providing an environment for training plant engineers and technicians to the use of tools for process analysis and optimisation."

Jan 1, 2008

By W. J. Young, K. B. Macneill, C. N. Smith

"A BRIEF HISTORY OF THE MURRAY BROOK MINERAL DEPOSITDuring the mid-1950's intensive exploration activity in northern New Brunswick followed the discovery of the world class Brunswick base metal deposit. Using the prototypes of modern airborne geophysical and geochemical exploration techniques many mineralized areas in the Bathurst-Newcastle area were quickly identified. This base metal - silver camp is situated within the metavolcanic - metasidementary rocks of the Tetagouche Group which forms a roughly circular caldera-chaped voloanio complex of Ordivician age.One of the early results in the exploration history in the camp was the discovery of the Murray Brook Deposit by Kennco Explorations, (Canada) Limited. During routine ground checking of geophysical anomalies, most of which turned out to be graphitic schist, the discovery of some copper bearing float was made by the exploration team. This encouraged the company sufficiently to carry out a regional stream sampling program which lead to a large anomaly associated with a hematitic gossan. Diamond drilling of a weak Slingram anomaly over the gossan zone resulted in the discovery of massive sulphide lenses. This was followed in 1956-7 with an intensive drilling program. The result was the delineation of a potential ore body containing an estimated 23 million tons with an overall grade of 0.44% copper, 0.86% lead, 1.95% zinc, 25.73 g/tonne (0.91 oz/ton) silver, 0.28 g/tonne (0.01 oz/ton) gold. Within this package were higher grade zones of copper and lead-zinc mineralization approaching ore grades.A thick blanket of gossan was present and is reported to have caused the drillers considerable trouble as they attempted to penetrate it to get to the underlying sulphides. The gossan, consisting of iron oxides and silica fragments sits on top of the massive sulphides and attains a remarkable thickness of 45.5 meters (150'). Early work had suggested that the gossan was enriched in gold and silver. If this were the case and if the precious metal could be leached out with cyanide, then mining and recovering those values might be economic.With this in mind Northumberland Mines Limited optioned the property from Kennco in 1985. Preliminary leach tests indicated that indeed the gold in particular leached readily. Subsequent drilling of the gossan (using triple core barrel technology for better recovery of the easily ground core) indicated 1,536,363 tonnes (1,690,000 tons) with an average grade of 1.05 g/tonne (0.037 oz/ton) gold and 42.13 g/tonne"

Jan 1, 1993

By James W. Cassie

The Snap Lake Diamond Project is located approximately 220 km northeast of Yellowknife, NT, Canada at an approximate latitude of 63?35?. The project location is within the zone of continuous permafrost; measured ground temperatures are about ?2?C at 10 to 20 m depth below surface. The site is located on a peninsula jutting into Snap Lake. The site is generally barren of vegetation, except for some isolated areas with low trees located in topographic lows and near the shoreline of Snap Lake. As part of phased evaluation process with regards to the mining project, an Advanced Exploration Program was undertaken in 2000 and 2001. This program included the underground extraction of a bulk sample of kimberlite, which was processed on site. A Processed Kimberlite Containment (PKC) area was required as part of this program. The area chosen as the PKC facility was a small inland lake, called Inland Lake #1, on the peninsula. Construction of the PKC area required the construction of two dams, one on either end of the lake. At the south end of the lake, Dam 1 was constructed partially on a talik and partially on continuous permafrost. Dam 2 was constructed entirely on permafrost. The effects of the remote location, selection of suitable construction materials and permafrost conditions on the designs of the dams are discussed. A description of the design elements and construction schedule are provided. A review of the performance of these two dams, in terms of settlement, deformations, pore pressures and thermal regime, over the last several years is provided.

May 1, 2003

By Hidenori Hatta, Takero Watanabe, Hideo Yoshida

"The effect of the quenching rate on age hardening in an Al-6.0mass%Zn-0.75mass%Mg alloy sheet was investigated. The quenching rates and aging conditions were as follows: water quenching (WQ) or furnace cooling (FC) followed by pre-aging at 20°C,then artificial aging at 120, 160 or 200°Cwere performed. The peak strength of the FC and the WQ are very similarat120°C aging. It is important high strength was obtained even at the extremely slow quenching rate. On the other hand, the strength of the WQ significantly decreased compared to the FCat200°C aging. GP(I) zones were formed during the pre-aging at 20°C even if the cooling rate was very slow like the FC, and were transformed into the GP(II) ones at 70°C or higher and then into the ?’ phase. However, these zones were dissolved by reversion during heating to 200°C. Thus the strength of the WQ decreased. On the other hand, it is considered that an unknown cluster or GP zone with a thermal stability formed during the FC was not dissolved up to 200°C and was transformed into the ?’ phase. Therefore, a higher strength was obtained in the FC for the200°Caging.INTRODUCTIONAl-Zn-Mg alloys are widely available in commercial production because these alloy have lower quench sensitivity and can be produced by air cooling (AC). Heat treatable aluminum alloys are usually produced by water quenching (WQ) to increase their strength because a high cooling rate inhibits the precipitation of the stable phase during cooling and increases supersaturated solute atoms. However, Baba(1967)reported the strength of an Al-6%Zn-1.8%Mg(mass%) alloy without additional elements quenched by very slow cooling (15°C/min) was 96% of that quenched by WQ. Furthermore,the age hardening at room temperature (RT) occurs after annealing at 410°C followed by furnace cooling (FC, 0.5ºC/min or less)in these alloys. Therefore, the process of annealing at 410 to 430°C for 120 min followed by AC, and reheating at 230°C for 240 min, then cooling is recommended in the specifications (Japan Aluminum Association, 2011). Matsuda and Yoshida(1996)also recommended annealing at 300°C for Al-Zn-Mg alloy extruded products to inhibit age hardening at RT by precipitating the solute atoms and decreasing them in the matrix. It has been considered that the higher the content of excess quenched-in vacancy becomes by WQ, the higher aging rate at RT is obtained. Therefore,it is theoretically and commercially important to clarify the reason why the age hardening occurs relatively quickly in almost no excess quenched-in vacancies such as the FC, and why the same strength as the WQ can be obtained in the FC"

Jan 1, 2018

By A. Griffiths, G. Vickell

"INTRODUCTIONA successful cyanide destruction process has to ensure environmental compliance at reasonable cost. That this is possible with hydrogen peroxide is shown by the fact that over twenty gold mines either already use H2O2 or intend to start using it within the next few months. About half of these mines are in Canada.This growth is remarkable, considering that the first treatment plant to use H2O2 for detoxifying cyanide was commissioned less than five years ago at Ok Tedi, in Papua New Guinea.Hydrogen peroxide is being applied to a wide range of situations, including:Treatment of CIP pulps; examples: Ok Tedi, PNG; Hope Brook, Nfld.Treatment of barren bleeds and filtrates; examples: Nickel Plate, B.C.; Puffy Lake, Man.Treatment of tailings pond discharge; examples: Detour Lake, Ont., Page Williams, Ont.Treatment of excess heap leach solution; examples: Hope Brook, Nfld; Gordex, NS.Treatment of barren heaps after heap leaching; examples: Alhambra, NV; Wharf Resources, S.D.Treatment of pond reclaim water to prevent either ""preg-robbing"" or depression of gold-bearing pyrite in a flotation step; example: Getchell, NV.Treatment of backfill to prevent possible groundwater contamination; example Hope Brook, Nfld.Treatment of tailings ponds to prevent bird kills; example: Paradise Peak, NV.""Emergency"" units to deal with unusual events such as freak storms or dam failures."

Jan 1, 1989

By Tad Crowie, Victor Delgado, Nick Katsikaros, Tim Hughes

"A number of silver producers have identified a need for a system to recover silver and gold from base metal flotation concentrates on site rather than sending the concentrate to third party smelters to improve mine economics. Historically intensive cyanidation has only been used for coarse gold gravity concentrates in batch machines but Gekko have applied the InLine Leach Reactor (ILR) to these difficult to leach concentrates.The ILR’s unique ability to operate at various solid to solution ratios, high mass capacity, the ability to handle fines, the use of peroxide to aid silver leach kinetics and simple operation has resulted in significant economic benefits to Hochschild PLC’s Selene and Arcata operations. This paper describes the commissioning phase of the ILR5000BA intensive cyanidation reactors on concentrates from the Selene mine at the Ares Concentrator.INTRODUCTIONIntensive leaching of high grade concentrates in gold ore treatment is now commonplace and is considered an essential feature of most gold circuits (Lane, Fountain and LeBrooy, 2008). The devices commonly used for intensive leaching (InLine Leach Reactor, Acacia Reactor, etc) are specifically designed for the typical coarse nature of the concentrate.In some of these intensive leach applications, significant amounts of silver are co-recovered with the gold. In fact, the intensive leaching conditions of 1 to 2% NaCN in solution and high dissolved oxygen levels, overcome the issue with silver’s slow dissolution rate in traditional CIL/CIP circuits and avoids the formation of insoluble silver sulphide minerals on the surface of the gold (Marsden, 2006).There are a significant number of mine operators producing silver in the form of mixed base metal sulphides flotation concentrates. Typically the mine operators are paid for the silver after processing of the concentrate by the base metal smelter whom recovers the silver during the refining process."

Jan 1, 2010

By A. Yaghini, Y. Pourrahimian

"Human factors (HFs) play an important role in the mining and mineral industry, affecting operational and maintenance efficiency and safety. Despite the introduction of new technologies and automation in this sector, it is well known that a significantly large proportion of total human errors occur during the operation and maintenance phase. A comprehensive literature review of HFs across several industries is provided. From this review, the impact of HFs on operation and maintenance is summarized, with a focus on what the mining industry is currently doing and what opportunities exist for additional improvements. Future research directions and themes are also identified.RÉSUMÉ Les facteurs humains (FH) jouent un rôle important dans l’industrie des mines et des minéraux, en ce qu’ils affectent l’efficacité et la sécurité de l’exploitation et de l’entretien. Malgré l’apparition de nouvelles technologies et de l’automatisation dans ce secteur, il est bien connu qu’une grande partie des erreurs humaines (EH) se produisent durant une phase d’exploitation et d’entretien. Cet article propose une analyse documentaire approfondie des FH dans plusieurs secteurs. L’impact des FH sur l’exploitation et l’entretien est résumé à partir de cette analyse, une attention particulière étant accordée à l’évolution de l’industrie minière et aux possibilités d’améliorer davantage ses activités. Sont également identifiés les futurs thèmes et voies de recherche.INTRODUCTIONDuring the past several decades, the mining industry has focused on improving equipment, machinery, and methods that have led to more advanced hardware and software, equipment with higher reliability and productivity, and other technological advancements. These actions have improved safety and productivity and have reduced casualties and maintenance workload. Although today’s mining equipment and machinery are technologically advanced and highly reliable, the risk of accidents is still relatively high and key performance indicators have not improved significantly compared to other industries (Sorensen, 2012). A prominent reason could be due to insignificant integration of human factors (HFs) as part of planning, operation, and maintenance activities. The current mining system is a people system, and inevitably HFs and human error (HE) figure prominently in all aspects of this industry. Even the most advanced technologies and innovations require operators and maintainers with significant knowledge and skill, which could increase the potential for HE."

Jan 1, 2018

By Paul E. Lamoureux

Introduction The Author As the pail of smoke and wartime destruction gradually rises from the surface of the earth, from all countries, statesmen assemble to discuss and prepare pacts and treaties which are designed to, once more, bring people of all nations to understand each other and live in harmony. Scientists and engineers throughout the world are also undergoing a drastic reconversion in their ideas and objectives. No longer do they think only in terms of destruction and twist their brains to develop more devastating weapons or to surpass production records of war machinery. They have turned their eyes and ambitions to more pleasant tasks and are taking stock of wartime developments in materials, fabricating procedures, and equipment, many of which had been carefully shrouded with a veil of secrecy, and are applying their new knowledge to the fabrication or improvement of the tools of peace. The next few years will see the gradual elimination of scores of substitutes and makeshifts, expedients which the constantly changing law of supply and demand' under wartime stress necessitated. The universal search for satisfactory substitutes, however, has resulted in a general awakening of plant engineers to the possibilities of materials with which they were relatively inexperienced, with the result that, in many instances, what was considered a substitution at the outset turned out to be more satisfactory than the original material, and, in reality, can be considered a worthwhile development. Not only have materials been explored, but existing fabricating processes have been reviewed, and others, built around the properties and characteristics of new materials, created.

Jan 1, 1947

By J. Patterson

"Acid Mine Drainage (A.M.D.) formed from oxidation of disposed pyritic wastes presents a potential pollution hazard for Equity Silver Mines Limited and the mining industry in general. Failure to collect and treat these acidic effluents can eventually affect the quality of receiving streams and endanger aquatic life forms. Treatment and discharge of A.M.D. to the receiving environment must comply with stringent anti-pollution laws.Wastes mined at Equity Silver Mines Ltd. are predominantly acid generating and must be handled according to a materials management plan to minimize impact on the environment. Effluent collection and treatment facilities have been constructed to address the short term environmental concerns with reclamation and research programs being developed to address and monitor abatement measures for control over the long term.The purpose of this paper will be to offer a brief overview of these measures. Key topics for discussion will be: kinetics of Acid Mine Drainage, acid generating potential, water treatment and sludge handling, special wastes, waste dump construction, waste rock amendments, bacteriocide research, simulations, and reclamation measures. Programs designed to evaluate impact on the receiving environment, although they form an extensive part of the program, will not be discussed in this paper.INTRODUCTIONEquity Silver Mines Limited is located in the Central Interior of British Columbia, within the Omineca Division, 35 kilometers southeast of Houston Mining and approximately 575 kilometers by air north-northeast ofVancouver (Figure 1).The deposit consists of three economic mineralized zones: The Southern Tail, Main and Waterline Zones. Mining of the Southern Tail commenced in April, 1980 and was completed in the first quarter of 1984. Main Zone production was initiated during the last quarter of 1983 and the Waterline Zone remains undeveloped to-date. Remaining reserves are in the order of four years contingent on favourable metal prices. The three deposits (Figure 2) occur within a window of interbedded volcanic and minor sedimentary rocks. The older volcanic sequence is bounded on the west by a small granite-like stock and on the east by a gabbro-monzonite complex. All are overlain by a series of younger lava flows."

Jan 1, 1988

By R. G. Hamm

A brief outline covering the shovels and draglines in use in the open-pit mines of Western Canada, including British Columbia, Alberta and the Yukon, is given, followed by the procedure for the selection of the correct wire rope for each application. Such fa ctors as wire rope constructions, lay directions and types of cores are mentioned. Once the correct wire rope has been selected, there are variousfactors that can affect the service fife ofthe rope and the reduction ofdown-time during rope change-overs. Factors such as hairpin winding, types of Becket loops, and shovel drum and bail adaptors are described.

Jan 1, 1979

By Horst Konig

This paper illustrates that, with the application of new processes, smaller steel plants using local raw materials can be economical and advisable. It also introduces the problems connected with the direct reduction processes, which use non-coking coal or gas as reducing agents, and which are employed in connection with conventional reduction to produce excellent results. Electric smelting is also discussed, and some practical examples of operating plants are given.

Jan 1, 1970

By I. S. Thompson

"Exploration properties form a continuum from grass roots to those with favourable geology, geochemical and/or geophysical anomalies, mineralization, showings (prospects), and finally to those with defined mineral deposits. Often, properties exhibit a composite of these categories.The most problematic to value are properties or deposits that are not economically exploitable at the time of the valuation due to a lack of exploration, insufficient grade or tonnage, poor mining conditions, or the imposition of socio-economic, environmental, or legal constraints.Various acceptable methods of valuing the range of all such mineral properties or deposits are reviewed. Some less appropriate methods are also discussed."

Jan 1, 2002

By A. B. Cron, R. MacPhail, L. Melis, K. Armstong

"Mt. Milligan is a porphyry gold/copper deposit in north-central British Columbia. Diluted and mineable drill-indicated reserves total 449 million tons at an average grade of 0.013 oz gold/ton and 0.19% copper. Large-scale commercial development of the deposit will make Mt. Milligan Canada's third largest gold mine.Metallurgical investigations for the Mt. Milligan project were done in three phases: scoping tests in the first half of 1989; bench-scale work from October 1989 to April 1990; and a pilot plant program in May and June 1990. Various process alternatives for the recovery of gold and copper are described and results are presented. Net smelter return evaluations led to the selection of optimum process conditions for maximizing revenue from gold/copper flotation concentrates.The selected flotation circuit and basic design criteria are described. Forecast average recoveries over the presently-defined 20-year project life are 75.2% for gold and 90.5% for copper in a copper concentrate averaging 17.6% copper and 1.0 oz gold/ton. 1.0 PROJECT LOCATIONThe Mt. Milligan porphyry gold/copper deposit is located in northcentral British Columbia, 150 km north of Prince George, British Columbia. The site is at an elevation of 1,100 m in an area of logged, gently-rolling topography. Nearby communities include MacKenzie and Fort St. James. Climate in the area is moderate and there is direct road access to the property. A location map is presented in Figure 1-1."

Jan 1, 1991

By B. Karnath, K. Guha, S. Tandon

At Jhagadia Copper Ltd (India), Copper is produced through secondary route using Top Blown Rotary Converter (Kaldo Furnace). The basic raw material being treated includes Matte-slag Reverts, Copper Cakes, dross & Cement, Oxide Ore, Low S bearing Concentrates & various metallics along with high grade copper scraps. The plant has capability to refine & produce Blister grade copper from Kaldo furnace as well as PS Converter . Blister is fire refined in Anode furnace & electro refined in Refinery to produce cathode copper. Our product , Copper Cathode , has already been established in the market as its quality is better than 'LME Gr'. The paper deals with the experiences encountered during commissioning & stabilization of the plant.

Jan 1, 2007

By S. Dessureault, J. Porter, M. Woodhall

Information and communication technology (ICT) is seen as a key source of future productivity improvements in mines. The information technology infrastructure (ITI) necessary to achieve these productivity improvements will come in the form of data integrated from multiple source systems throughout the mining value chain. Two pure approaches are available: supplier-controlled or operations controlled data structures; each strategy has its own advantages and disadvantages. Case studies involving the South African mining industry are used to demonstrate the advantages of using hybrid-controlled data structures. Depending on the level of operational control, new skills are also necessary to be learnt by mining professionals including: information engineering; creating consistent and quality data; and process improvement techniques that use the integrated data for improving the operation.

Jan 1, 2004

By H. Reimer

The rates of return on investment are examined for several major Canadian mining companies. Because we are dealing with a highly cyclical industry, subjected to widely fluctuating metal prices, rates of return are examined over a 20-year period. Conveniently, the first decade examined reflects the period when the industry enjoyed incentives to develop deposits; during the second decade, incentives were reduced and the industry became the most heavily taxed industry in Canada. The high rates of inflation since 1973 have distorted the real rates of return on investment if one considers replacement cost.

Jan 1, 1977

By H. D. Stolovitch, M. L. Lavallée

"An engineering system used to analyze and improve the performance of industrial grinding circuits has been adapted into a training program. The systematic approach to the design of training was applied in order to:Determine if training was an appropriate and effective tool for the transfer of this new technology;Define the technical content of the program;Establish program specifications based on learner and context characteristics;Design and test prototypes of the instructional modules; and,Establish a strategy for plant implementation and maintenance of the training program.This paper thus describes how a engineering system is transferred to the workplace through the use of designed instruction.INTRODUCTIONTraining can change human performance in a permanent way. It can improve productivity for the overall benefit of an operation. Organizations can therefore use training as a mean to achieve their specific goals. Training is not the solution to every performance problem. However, in many cases, it can be a very effective way to attain desired performance.The benefits of training are often difficult to assess. However, to remain competitive, organizations must introduce new products and innovative technologies. Often, they can do both most effectively through suitable training interventions.In order for the effort and investment of training to provide optimal results, two points of view should be adopted.• An overall view of the system in which training is to be applied.• A systematic approach to the design of training (Stolovitch and Keeps, 1989)."

Jan 1, 1992

By W. A. Ahrens, J. H. McNamara, J. G. Franek

"An economical, pollution-free process has been developed for the hydrometallurgical extraction of copper from sulphide ores. The extracted copper, in the form of cuprous chloride (CuC/), is converted by reduction to copper metal. The metal is melted and fire -refined into wire bars which meet the standards of electrolytic tough pitch (ETP) copper wirebars. IntroductionThe successful development of the Cyprus Copper Process has been an evolutionary series of events covering a time span of some nine years. The original process, based on an electrolytic membrane cell principle , was abandoned in 1975 because of technical, economic and pollution problems. During the past four years, the pilot plant has been reconstructed based on a new flowsheet and operated successfully in several campaigns, some for as long as four months. The pilot-plant hydro section operates at a 225-lblhr copper rate. In October 1977, a feasibility study was completed by Jacobs Engineering, Pasadena, California. The study showed favourable economic and technical feasibility. Jacob's studies in 1978-79 revealed favourable comparative economics with other known pyrohydro processes and favourable economies of scale.The Cyprus Copper Process converts copper concentrates of varying composition into copper metal, which has been proven to be equivalent in every way to electrolytic tough pitch copper, suitable for electrical applications. This is accomplished at capital and operating costs which are estimated to be lower than those associated with any other known currently applicable technology. Also, the total energy requirement is equal to or less than any other known process and the process is essentially pollution free."

Jan 1, 1980

By Gaby Steinbach

A novel synthesis is described for the preparation of supported gold catalysts for low-temperature CO oxidation. The novel route is a variation of the inverse co-precipitation method and requires amphoteric metal hydroxides, with zinc and aluminium hydroxides chosen. Catalysts were prepared by inverse co-precipitation (ICPa) and by the novel route (ICPb) and tested for CO oxidation at 60ºC. Preliminary results showed the novel route to be superior to ICPa; the catalysts prepared by ICPb showed higher catalytic activities. The effect on catalytic activity of parameters such as pH, calcination temperature, washing of precursor and calcined catalysts and ageing was investigated. A preparation pH of 9 and a Zn to Al mass ratio of 3 proved to be optimal. It was possible to remove residual chloride by washing thereby enhancing catalyst performance. Ageing and Mg citrate addition were also shown to improve catalyst performance. Characterization of the catalysts revealed that better activities were obtained when the support was more crystalline and had a higher surface area. The presence of carbonate-containing species in the support decreased catalytic activity. 197Au Mössbauer Spectroscopy revealed the presence of Au3+ when catalysts were heat-treated at temperatures of 200ºC and below. Catalysts calcined at 400º had 75% of the gold present as Au0, with the remaining gold present as Au3+.

Oct 1, 2003