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By M. Mohammadi Zahrani

The morphological modification of primary and eutectic Mg2Si phases by bismuth (Bi) addition in Mg-5wt.% Si in-situ composite was investigated. It was found that with addition of 0.5wt.% Bi, the morphology of primary Mg2Si precipitates was altered from coarse dendritic to polygonal shape, and their mean size was significantly decreased from more than 20 µm to about 8 µm. Moreover, the rod-like eutectic Mg2Si in Bi modified Mg-Si alloy solidified much finer than that of the base alloy. Such improved microstructure of the modified alloy resulted in 10% tensile strength and 20% elongation improvement. The isotropic growth manner of primary Mg2Si particles in modified alloy was attributed to the poisoning of growth in preferred directions by dissolving Bi atoms in Mg2Si lattice. The reduction in size of eutectic Mg2Si was found to be the result of Mg3Bi2 compound formation around eutectic Mg2Si rods.

Oct 1, 2011

By H. J. Hartjens

"With the trend towards bringing into production ore bodies of lower and lower copper content every possible avenue of approach to achieve maximum copper metal recovery and keep milling costs to a minimum are of increasing importance.Equipment manufacturers have contributed a great deal by designing larger mills, flotation machines, pumps, etc. in lowering capital and operating costs; instrumentation and automation usually as a joint effort of operating staffs and equipment manufacturers have resulted in lower operating costs and improved metallurgy. Likewise manufacturers of chemicals used in mineral beneficiation have directed their research and development at new flotation reagents and treatment schemes to complement the needs for more efficient products, permitting coarser grinds without detriment to recovery, higher flotation rates, higher degrees of selectivity, as well as chemicals to improve settling, clarification and filtration. The various treatment schemes in use and suggested for consideration are:1) The choice of the flotation treatment scheme is largely dictated by the desire to operate a simple circuit, originally consisting of rougher and scavenger flotation, with scavenger concentrate either returning to the head of the rougher circuit or joining the rougher concentrate for cleaning by reflotation, with and without prior regrinding. The cleaner tailing was also recycled to the head of the rougher circuit. In the case of porphyry copper ores, this was originally the standard circuit. Lime is the preferred alkalinity regulator to adjust pH, usually in the range 10-12.To avoid the undesirable effects of circulating loads and gain the advantage of simplified control of the rougher circuit, open circuit cleaning is practiced more and more. In this scheme, cleaner tailing is scavenged to produce a discardable tailing and the scavenger concentrate returned either to the cleaner or the regrind circuit."

Jan 1, 1970

By X. J. Guo, Q. K. Wang, S. P. Zhong

With depletion of traditional clean copper reserves and fast expansion of the global copper demand and smelting capacity in the past decade, more and more copper smelters have to treat copper concentrate with increasing content of complex arsenic-bearing minerals. Developing economically viable and environmentally reliable methods and approaches for arsenic control in copper smelting has become more critical for sustainable growth of the copper industry. This paper will report the recent effort of Zijin Mining Group Ltd. in developing processes for improving arsenic control and management in the Zijin Copper Smelter. The arsenic distribution and balance data for matte smelting, converting and refining operations in Zijin Copper Smelter is reviewed for understanding of the current challenges in arsenic control. The processes developed for treating the arsenic bearing waste acid bleed stream from the smelting-converting off-gases wet cleaning circuit and the arsenic sludge produced in the refining electrolyte purification circuit for arsenic disposal are discussed. INTRODUCTION With fast expansion of the global copper smelting capacity to meet the world copper demand and depletion of traditional clean copper reserves, more and more copper smelters have to treat copper concentrate with an increasing content of complex arsenic-bearing minerals. China is the world largest copper consumer and also has the largest copper smelting and refining capacity, but majority of its smelting capacity relies on supply of imported copper concentrate. In order to meet the increasing copper demand and ease the tight supply of clean copper concentrate, the Chinese copper industry has to look at the domestic opportunity of developing non-traditional copper resources, specifically those of lower grades, more complex mineralogy, and increasing level of deleterious elements especially arsenic and also process imported copper concentrate with increased arsenic content. Due to a significant and growing environmental issue associated with arsenic contamination, developing economically viable and environmentally reliable methods and approaches for arsenic management and control in unlocking the maximum value of such arsenic bearing copper resources has become more critical for sustainable growth of the industry.

Jan 1, 2019

By T. Gonzales, S. Thakurdin

The conducting of risk reviews is an essential activity in ensuring safe operating conditions, both during project design phases and for existing facilities. The following paper presents a structured approach to the conducting of risk reviews for existing operations, including descriptions of supporting documentation and guidelines for on-site review activities. The conducting of regular site risk reviews and safety audits is crucial in ensuring the continued safe operation of existing facilities, particularly in the copper industry where numerous processes and unit operations can present catastrophic risks, both in terms of loss of life and financial liability. The structured approach presented aims to provide a logical and comprehensive analysis of risks to align safety-related facilities and procedures with current industry best practice and ensure consistency across multiple client operations. INTRODUCTION The production of copper, whether by pyrometallurgical or hydrometallurgical process routes, carries significant inherent safety risks. Production volumes are relatively large, often requiring complex processing routes, multiple production trains and a variety of supporting ancillary facilities. Furthermore, considering the relatively large size of ore reserves, copper production plants can have operational lives well beyond the typical design duration of 20 years. In this context, the conducting of regular risk reviews is essential in ensuring safe operating conditions and aligning facilities with current industry best practices. Risk reviews and safety audits can take various forms and have various areas of focus. The methodologies and approaches described below relate specifically to catastrophic risks, defined broadly as risks that carry the potential for multiple fatalities and significant financial losses. Focus is given to existing facilities and does not consider the risk-related activities such as hazard and operability (HAZOP) studies conducted during plant design. The structured approach presented aims to provide a guide for effective site- based audits and a logical analysis of risks identified. RISK CLASSIFICATION Table 1 provides a typical summary of the classification of risk types and the associated consequence categories and descriptions. It illustrates the descriptions of a catastrophic risk in terms of the broad categories of Health & Safety, Environment, Financial, Image & Reputation and Legal & Compliance. In terms of the Financial category, numeric costs ranges are often prescribed depending on the financial characteristics of the specific operation and the associated parent company.

Jan 1, 2019

By J. F. Nie

Mechanical properties of precipitation hardenable magnesium alloys depend critically on the chemistry, structure, morphology, orientation and distribution of strengthening precipitates. It is therefore important to gain an improved understanding of these information and their correlations with mechanical properties. Our recent studies indicate that additions of 1-2 wt% of Zn to a Mg-6wt%Gd alloy result in a substantial enhancement in precipitation hardening and in creep resistance. If the strength and creep resistance of the resulting ternary alloy are to be further enhanced for commercial applications, then a detailed characterisation of the strengthening precipitates in these alloys is required. In the present study, the precipitates formed in a Mg-6Gd-1Zn-0.6Zr (wt%) alloy, peaked aged at 250°C, have been characterised in detail using transmission electron microscopy and 3-dimensional atom probe field-ion microscopy. It is found the peak-aged microstructure contains a dense and uniform distribution of precipitate plates that form on the basal plane of the matrix phase and are typically less than 1 nm in thickness. Detailed analyses of the structure and composition of these basal precipitate plates will be presented and discussed in the context of previous work on other Mg-RE¬Zn alloys of similar compositions.

Jan 1, 2006

By Damian Connelly

The option to leach iron from low grade copper concentrates could reduce transport costs and significantly improve the saleability of the concentrate. In addition, it reduces smelting costs and can remove undesirable impurities. The trend to produce cleaner and higher grade copper concentrates is very appealing to the smelters. A recent copper project came on line and there were three serious deficiencies which were not identified in the feasibility study. This came as a surprise and resulted in a number of projects to investigate ways of rectifying the problems in the shortest timeframe possible and using minimal new capital. The first serious issued not identified when commissioning was the lower than expected copper recovery, which was 70% compared to a predicted recovery of 80% to 87% in the feasibility study. This required investigating new flotation reagents and incorporating controlled potential sulphidisation. The second serious issue overlooked is the presence of significant amounts of talc minerals (insol) in the ore which are naturally floatable. This leads to lower concentrate grade and attempts to remove the talc resulted in lower copper recovery. Smelters have limits on the amount of talc in concentrate because it produces viscous slags and difficulties for the smelter. It also incurs higher transport costs. The third serious issue not identified in the feasibility study was the high arsenic reporting to the concentrate. Arsenic is a penalty element for smelters and at levels exceeding 0.3% the smelters may reject the concentrate. Arsenic is a problem environmentally for copper smelters and penalties apply when it is high. This paper describes the options for penalty element removal and suitability to incorporate into the modified flowsheet. It also highlights where the geometallurgy was not properly addressed and how these surprises could have been avoided. INTRODUCTION From 1970 to 1985, a copper company undertook metallurgical testwork on the Peruvian project copper ore. The ores were mined underground and treated over many years previously. Various other groups undertook studies and work until Aker Kvaerner undertook a feasibility study in 2006. Three ore composites were tested and grind-recovery relationships were developed. The feasibility study testwork identified that talc was a possible concern and will have an impact on copper concentrate grade. This was to be managed by blending. The current operating reality is that there is so much talc in the ore body it is not possible to blend it out. There was far more emphasis on molybdenum recovery. No mention was made of arsenic issues other than blending. There was a Concentrate Leach Study and a Molybdenum Hydrometallurgical Plant Study but these options did not proceed to a final flowsheet. A Scoping Study in 2006 looked at a Heap Leach project. The heap leaching gave very poor copper recovery on the sulphide ore. Heap Leaching was evaluated and tested for the high talc and high arsenic ore but recoveries were poor. The Aker Kvaerner feasibility study opted for a simple primary crush SAG/ball grind followed by flotation and sale of a concentrate. This is the current flowsheet utilised and the scale of the project is very large based on processing 117,200 tonnes of ore per day. A feasibility study does not guarantee success and the deviations from the feasibility study suggest there is a lot of technical work required to improve the current metallurgical performance.

Jan 1, 2019

By Wataru Inagaki, Kozo Kawano, Tetsuya Ando

Cu–Ni–P alloys are the typical precipitation-hardening material. Thus, Cu–Ni–P alloys is expected to apply alternative materials for heat-exchanger tubes. Therefore, it was investigated that the effect of the heat-treatment simulated brazing on mechanical properties of Cu–Ni–P alloy in this study. The hardness of specimen as heat-treatment simulated brazing after solution heat treated (sht) was shown approximately 105 HV. The peak hardness and tensile strength of the specimen as performed aged at 498 K for 43.2 ks following the heat-treatment simulated brazing achieved at approximately 140 HV and 260 MPa, respectively. From these results, it is expected the application to higher-strength tube for heat-exchanger after brazing in a furnace. INTRODUCTION Copper prices have increased dramatically with high in recent years. At the same time, manufacturing industries are required to reduce the environment load by reducing the wall thickness of the copper tubes used in heat exchangers. High-strength copper alloys are developed for reducing the wall thickness, while achieving high strength, of the copper tubes. Moreover, excellent workability and corrosive durability are also required by these copper tubes. Furthermore, the brazing, which are carried out at about 1050 K during the assembly process of heat exchangers, leads to grain growth and re-solving of additive elements. Nomura et al. achieved a tensile strength and Vickers hardness of approximately 260 MPa and 110 HV, respectively, after aging at 723 K for approximately 36 ks. Tamagawa et al. studied that the strength of Cu–Ni–P alloy rapidly increased at about 125 HV during the cooling process after the heat brazing due to the Ni2P precipitates sized 5–10 nm. Furthermore, Inagaki et al. achieved a Vickers hardness of approximately 130 HV by aging at 498 K for 10.8 ks. In the present study, we focused on the lowest aging temperature of 498 K in the previous study, and investigating the effect of heat-treatment simulated brazing on the mechanical properties of the Cu–0.93 mass%Ni–0.24 mass%P alloy.

Jan 1, 2019

INTINERARY ?What is SRI? ? How do we define good corporate social and environmental performance in the mining and petroleum industries? ? Why should you care? MJRA Inc. ? Established in 1992 ? Canadian Social Investment Database (CSID) launched in 1993 ? Jantzi Social Index launched in January 2000 ? created in 2000 SRI is ?the incorporation of social and environmental parameters into the investment decision making process.

May 1, 2002

By Bian Xue, Wu Wenyuan

High quality, mono-dispersed, hollow CeO2 microspheres with high surface area were produced by a spray pyrolysis method at 700oC. CeCl3 was used as the raw material of the process rather than Ce(NO3)3 because the latter is relatively difficult to obtain in industrial quantities. X-ray diffraction and electron microscopy results confirm the high quality synthesis of hollow CeO2 microspheres with narrow size distribution, good mono-disperse, and good reproducibility. The process of the formation of mono-dispersive CeO2 microspheres was investigated by chemical dynamics and a possible mechanism is proposed. This simple method for synthesis of CeO2 microspheres is easily scaled up to fabricate other metal oxide nanostructured materials at industrial scale.

Jan 1, 2014

By S. Komar Kawatra, Youlian Zhou, Joseph A. Halt

"Bentonite clay has been the most common binder for iron ore pellets. Although bentonite increases pellet strength and durability, it has several disadvantages. For example, its use increases the cost of pellets and decreases pellet purity due to its composition and the higher levels of flux required to meet basicity limits. Several new types of binders have been proposed to replace clay. The binders include starch, modified humic acid (MHA), and dispersants. These binders were used to pelletize a magnetite concentrate from the United States. Typical doses of each binder type were 0.05-0.1 % starch, 0.5-0.75 % MHA, and 0.05 % dispersant. At these doses, the pellets exceeded the minimum recommended values for wet drop, dry compression strength, and fired compression strength. Pellets made with the MHA and dispersants had the lowest abrasion rates of the new binders, and were comparable to pellets made with bentonite clay. In this paper, we compare the new binders, considering pellet quality and the advantages and disadvantages of each binder type.INTRODUCTIONIron ore pelletizers need binders in order to make good quality iron ore pellets. The typical binder is bentonite clay, an alumino-silicate material. Bentonite increases the ballability and strength of iron ore concentrates, but reduces pellet iron grade and reducibility. As high quality bentonites can be expensive to ship, low quality bentonites are often used at significantly higher doses – this reduces iron grade and reducibility even further. Thus, several new types of binders have been proposed to replace bentonite clay.In this paper, we present several new binders for iron ore pellets: starch and modified humic acid (MHA). These have been tested alone and in mixtures with dispersants, or else with bentonite clay. Starch, MHA and their mixtures are briefly described below."

Jan 1, 2016

By T. Fliß

The protection of natural resources is of essential importance in times of rapidly increasing populations and resulting shortage of agricultural land. Soil and groundwater resources play a central role for the production of food or feed of any kind. The intensive agricultural and environmentally friendly use of these resources must ensure sufficient income and sustainability of life for future generations. Mining projects often represent a particularly deep intervention into ecosystems due to their size as well as the most expensive treatment processes. Conventional mines comprising of shafts and developed mining fields require the stockpiling of waste rock and in particular to potash mining, the discharge of brines from raw salt processing. In contrast, mining operations based on the solution mining method can be operated without major environmental impacts and lower security risks. While the solution mining for the production of rock salt finds application since more than 500 years, exist a procedure to produce potash using solution mining only since the 1980's. For solution mining drill holes are used to exploit the potash, launched from the surface into the deposit. The exploitation of the raw material occurs by the dissolution of the potash injecting solvents and creating so-called brine caverns. Currently, a number of mining projects in Carnallite deposits by the solution mining method are in progress around the world. Often these projects are located in sensitive ecosystems. K-UTEC project and support actual a solution mining operation of a Carnallite deposit for a Chinese customer in South-East Asia. This work comprises a comprehensive geological and geomechanical modeling as well as stability analyses. Furthermore the cavern design and brine field layout as well as the planning of the brine processing and the plant design. The present paper introduces this project as a case study. The application of a special solution mining procedure and processing design ensures an emission-free mining operation (Zero Disposal Plant). The emission-free operation is achieved by utilizing the full extent of the caverns to dispose the liquid solutions from processing. The presentation of principal salt processing and technical equipment will be rounded by information about the geology of the deposit. Since the deposit includes a number of sensitive minerals, such as Tachyhydrite and Bischofite the presentation comprise a lot of interesting items with special view at the brine field operation. K-UTEC designed and delivered a special blanket measuring system and a well cement according the request of the customer. K-UTEC, a research and engineering company with more than 60 years of experience in the sector of potash and rock salt mining, developed the world's first solution mining operation for Carnallite in Germany more than 30 years ago. In recent times K-UTEC served in different solution mining projects worldwide, with special view at the environmental impact, as well as the optimal utilization of the deposits.

Aug 1, 2013

By D. Lascelles, J. A. Finch, E. El-Ammouri

Flotation separation is expected to be related to the degree of dispersion of the pulp. For instance, highly aggregated systems may show reduced selectivity, reduced entrainment and increased flotation rate. In an attempt to test the impact of aggregation on flotation, we have taken advantage of the effect of Mg ions. Using combinations of Mg2+ and pH gave a wide variation in aggregation of several Cu-Zn ores (measured by settling rate) and corresponding flotation response was determined by batch tests. The trials were conducted on-site at Louvicourt and Agnico-Eagle. In a majority of cases a similar trend in aggregation and flotation selectivity (grade at given recovery) was observed. At Louvicourt, improved selectivity with increasing aggregation at pH 10.5 was found. At Agnico-Eagle, an analogous association between aggregation and selectivity was observed at pH 11.5. It is suggested that aggregation influences particle entrainment, the increased effective particle size reducing gangue recovery and hence improving selectivity.

Jan 1, 2004

By Patrick Laflamme, Jean-François Boulanger

Les minerais de cuivre sulfurés, qui représentent 80% de la production mondiale de cuivre, imposent une étape de concentration des minéraux, premièrement pour atteindre une teneur en cuivre minimale qui permette le traitement pyrométallurgique, mais aussi pour limiter la présence d’élément pénalisants (délétères). Cette introduction offre un survol des principes, limites et pistes d’améliorations touchant la concentration des minéraux de cuivre.

May 2, 2024

By John Crusius

? 3-year research program overview ? initial results- MainZone pit Waterline pit ? questions raised ? increasingly common in western N. America ? frequently low-pH waters with elevated concentrations of many metals ? water quality controls poorly understood ? some in U.S. are Superfund sites

May 1, 2002

By V. Chatain

The environmental assessment of historical mining sites contaminated with various inorganic species, as also the determination of remediation targets require a better knowledge of pollutant-bearing phases. The objective of this paper was to investigate the operational fractionation of arsenic (As) in an As contaminated (ca. 3 wt%) soil collected from a gold mining site in France, where mining activities and smelting processes of gold ores took place until 2004. Single and sequential chemical extraction procedures were performed to evaluate the potential mobility of As according to the fractions to which it was associated in the contaminated soil, and also the part of As sorbed onto soil particles. These procedures used provided information on the nature of As fixation processes in the mining soil studied. Results showed that As appeared mainly sorbed (ca. 72%) with iron on the soil particles, in particular amorphous iron oxyhydroxides. These results confirmed a potential risk of arsenic mobilization under acidic and/or reducing conditions, which frequently occur in mining environment. This research evidenced the importance of the knowledge of As-bearing phases to better predict the mobility of this pollutant and in turn improve the management of As contaminated sites.

Aug 1, 2013

By J. Smit, F. Parada, R. Parra, E. Balladares, M. P. Merino

"In this study, a two-step process was developed for recovering copper, molybdenum, zinc and iron (hematite). In the first step, grinded slags (-65 mesh) were sulphated with SO3 at 350-500ºC to form iron, copper and zinc sulphates. In the next step, the formed sulphates were decomposed to hematite, copper and zinc sulphates and oxysulphates at 700-750ºC. The generated SO3 was recirculated back to the sulphation step. The generated calcine in the decomposition step is leached with 25 gpl acid at 50ºC to dissolve the copper, zinc and molybdenum for further conventional separation and recovery. The hematite residue, of intense red color, can be used as pigment, in the ceramic industry or as pellet feed. The fine crystalline silica remains in the hematite residue."

Jan 1, 2014

By N. Katsikaros, R. Agius, B. Adaszynski

"With stricter limits globally being imposed on cyanide discharge levels in plant tailings, having a reliable and well designed cyanide detoxification circuit is critical for any operation. The INCO SO2/Air method is most commonly used for cyanide detoxification where sulfur dioxide and oxygen combine to oxidize cyanide to the much less toxic cyanate. This paper discusses the steps involved with the development, from laboratory through to design, of a robust cyanide detoxification circuit. The goal is to produce a cyanide detox circuit that reliably meets discharge target with the lowest operating and capital cost.Design begins in the laboratory where continuous tests simulate full scale operation of a detoxification circuit. Detailed design relies on several design parameters, based on theory and experience, to ensure the reactor can satisfy requirements of the cyanide destruction reaction. Selection of the correct reagents and their supply to the reactor is important to an operable process with minimal operator workload. The operability of the system relies on correct process control strategies to maintain optimal reagent addition and chemical conditions in the reactor. These design factors are critical to providing a robust plant that will consistently meet cyanide discharge levels, ensuring uninterrupted production and plant profitability."

Jan 1, 2014

"In conjunction with Banick Mercur , Wright Engineers Limited designed the first multi-stage aqueous pressure oxidation system in an alkaline environment in North America. A three-stage slurry heating and slurry pressure let-down with heat recovery was an innovative approach to the problem of high energy cost with the low sulphur content of the ore. The design of this system required solving a number of problems associated with heating and pumping of slurries at pressures up to 3230 kPa and temperatures in excess of 220°C. Wright received an Award of Merit in October 1989, from the Canadian Consulting Engineering Awards Committee in the Process Category for its design of the Mercur pressure oxidation system.The Mercur Mine is located at the south end of the Oquirrh Mountains in Tooele County about 65 miles by road from Salt Lake City, Utah, U.S.A. The original mill was designed to process 5000 tpd of oxidized gold ore in a carbon-in-leach (CIL) circuit. A new ore treatment system was required to treat the substantial quantities of refractory ore reserves which could not be treated economically in the existing mill. The new pressure oxidation circuit makes the refractory ore amenable to gold recovery by oxidation of the sulphides contained in the ore .Wright Engineers Limited was commissioned by Barrick Mercur Gold Mine Ltd ., a wholly-owned subsidiary of American Barrick Resources, to design the pressure oxidation facility. This followed completion of a feasibility study by Wright which showed that the project was technically and economically viable.Work on the feasibility study began in 1986, detail design commenced in February 1987, and was completed in December 1987. Mechanical installation was completed in January 1988, and slurry feed began in February 1988. The plant has operated since June 1988 without major interruption . Wright was responsible for engineering, procurement and construction management for the addition of the 750 tpd pressure oxidation circuit to the existing mill and also had commissioning responsibility.Major unit processes involved in the pressure oxidation facility are ore thickening, three-stage slurry preheating, pressure oxidation and three-stage slurry cooling with heat recovery, stearn generation, propane and oxygen storage and a video graphic display process control system were included in the scope as process anciliaries.The pressure oxidation increases gold recovery from the refractory ore by conventional CIL from as low as 35% to more than 86070. A patent has been granted for the process."

Jan 1, 1989

By M. A. Nadar

Harsh and dynamic construction sites are generally equipped with cranes in order to rapidly and conveniently move heavy loads from one location to the other. If not properly inspected and managed, this operation can be very hazardous and lead to accidents. As such, a reliable and self-contained monitoring system that can update construction and safety personnel about the status of the crane, the weight of the load lifted, the location of the boom with respect to nearby buildings and other tower cranes, and the weather conditions under which the crane is operating, is deemed necessary. This can lead to significant time and cost savings as well as safety and productivity improvement due to the accuracy and immediacy of relevant on-site crane information delivery. This paper takes the initial steps and presents research targeted at evaluating the capability of wireless sensor networks (WSN) for monitoring tower crane operations in construction environments. A reliable long range WSN system is implemented and information is obtained from various special-purpose sensors (temperature, wind, proximity, etc.) mounted on special motes that relay data to and from each other and a central hub. The latter continuously monitors and manages network performance and relays incoming data to the host application. This application, in turn, displays the received data, and maps it onto a user-friendly visualization scheme, triggering alarms when a set of pre-programmed rules and safety conditions are crossed. The components of the proposed system have been tested through proof of concept experiments and preliminary results highlighted the potential of WSN systems for improving monitoring of tower cranes and reducing related accidents on construction sites, especially in Lebanon and the Middle East region where safety precautions are usually not properly implemented.

Aug 1, 2013

By R. Hagiwara, S. Kobayashi, K. Yasuda, T. Nohira, K. Kondo

To establish a process for the electrochemical recovery of rare earth elements from used magnet scraps, the electrochemical formation of RE-Ni alloys in molten NaCl-KCl-RECl3 salt at 973 K was investigated. Cyclic voltammetry and open-circuit potentiometry indicated the formation of several phases of RE-Ni alloys. The formation potential for each RE-Ni alloy phase was determined from the results of scanning electron microscopy and X-ray diffraction of alloy samples prepared by potentiostatic electrolysis of a Ni plate electrode at various potentials. The optimum electrolysis conditions for the separation of Nd, Dy, and Pr are discussed.

Jan 1, 2014