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By Theophile Yameogo

The rock mechanics literature has documented the challenges, failures and successes of tunneling through weak rocks. Cases usually deal with low RMR rock masses or high stresses in a fractured zone. With the combination of 5MPa water pressure, 14 RMR ground with clay infillings and ground freeze walls, the case of the 510-8225N development drift at McArthur River is certainly much more challenging, especially when high grade uranium production is at stake. The article explains the excavation and the ground control techniques that were used to overcome the challenges of development at the Unconformity in the Athabasca Basin.

Aug 1, 2010

By M. Fafard, D. Picard, J. -F. Bilodeau, G. Soucy

To simulate adequately the behaviour of a Hall-Heroult electrolysis cell, a finite element model must take into account the properties of each material. However, it has some lacking knowledge on the mechanical behaviour of materials, like the long-term visco-elastic (creep/relaxation) behaviour of cathode. A three-dimensional model is then proposed in this paper and will be ready to be implemented in the finite element code FESh++. The model was developed using the three-dimensional model based on thermodynamic of irreversible processes where the choice of the internal variables is based on a phenomenological approach. All parameters of the model are represented by constant constitutive tensors and the temperature and chemical dependencies are taking into account through scalar functions multiplying the constant constitutive tensor. The goal of the first part of this project was to determine the parameters of the threedimensional visco-elastic model at the reference state (virgin material at ambient temperature) of three different cathode materials. This paper presents the theoretical model and the results of creep tests at ambient temperature for the semi-graphitic carbon cathode.

Jan 1, 2006

By C. Sist, J. Shannon, J. Fossenier, J. F. Adams

With the cleanest and easiest to treat copper concentrates dwindling and becoming harder to find, electrorefineries must deal with the reality of higher impurity anodes. There are well-known strategies for managing nickel, bismuth, antimony, etc. using bleeds (Ni, Bi, Sb, As) or arsenic control (Bi, Sb) or hydrometallurgical add-on circuits (IX, MRT, SX for As, Bi, Sb). However, for integrated copper producers and those producing other base metals it is often worth considering a more holistic, global approach. This paper will discuss both the well-known strategies as well as some global strategies and the role that hydrometallurgy can play in them. Examples will include atmospheric and pressure leaching, selective precipitation and impurity recycling or fixation. INTRODUCTION In the electrorefining of copper, impure copper anodes are electrically corroded, and pure copper is deposited on cathodes by passing DC current through an acidic copper sulphate solution. The anode copper impurities either settle to the cell bottom as insoluble components (anode slimes) or remain in solution with minimal deposition at the cathodes when correct operating parameters are maintained. Consideration of impurities is important in all copper electrorefineries. A typical impure anode contains 98.5–99.5% copper (Schlesinger et al., 2011). Table 1 shows the range of impurities reported for all copper anodes in the 2007 survey of operating refineries (Moats et al., 2007). Also shown is an approximate “limit” of anode compositions within which the majority of refineries operate without additional impurity removal capacity (beyond conventional liberator/bleed circuits). The column is somewhat subjective and meant to be an approximation only since there are many factors that influence impurity deportments and refinery impurity tolerances. More recent world survey data from 2013 show the averages for all impurities trending upward from 2003 to 2013 (Moats et al., 2013). With a competitive market for good concentrate and more copper recycling from electronics (which contain high levels of impurities such as nickel, lead and antimony), this trend is expected to continue through the coming years. The traditional primary method of impurity control is refinery bleed through liberator cells which are employed in the vast majority of refineries (Moats et al., 2013). These are used to control copper (primary liberators), nickel, arsenic, antimony and bismuth (secondary and tertiary liberators). Other methods of impurity control include arsenic addition (upstream in the smelter deporting to anode or directly to electrolyte) to control antimony and bismuth (Kamath et al., 2003), ion exchange or molecular recognition technology (Hur et al., 2005; Navarro et al., 2012) for antimony and bismuth. Many refineries also operate nickel evaporators to remove nickel sulphate before recycling back acid. Some use, or are contemplating using, acid purification units to recycle acid and arsenic without nickel and making nickel carbonate (Kamath et al., 2003; Sheedy et al., 2006).

Jan 1, 2019

By F. Weinberg

"The recent development of the continuous casting process for steel has required basic understanding in a number of areas in the metallurgcal sciences. In some areas, information is still lacking. The success of the application of basic knowledge and research to the process is evidenced by the fact that a large percentage of the steel now produced in the world is produced by continuous casting.A number of areas in which metallurgical science has contributed and is currently contributing to better design and control of the continuous casting process and leading to a better quality product will be considered. These include:(a) heat transfer studies of the entire casting process;(b) fluid flow in the tundish, strand and liquid metal stream;(c) solidification structure and segregation;(d) strength and ductility of steel at high temperatures related to bulging and cracking; and(e) problems related to horizontal casting developments.IntroductionThe continuous casting of steel is a relatively new technology in steelmaking. It is now used extensively throughout the industry. In Japan, for example, continuous casting accounts for approximately 40010 of steel production, and this value is expected to increase to over 50% in the near future . New steel plants are now designed to use continuous casting exclusively. This means the process must work well and be completely reliable, because all the steel produced must go through the caster.The development of the continuous casting process in a short period of time has required concerted research and development in many areas . I shall cite a number of examples of these developments and refer to work done in Canada when applicable. No attempt will be made to review all of the research in continuous casting, nor refer to all of the workers in the field.The developments in continuous casting are based in many cases on metallurgical science, as described below. The use of metallurgical science in these developments is qualitative, in that concepts and idea s are used, as opposed to quantitative values calculated from fundamental equations. In general, most metallurgical problems are too complicated to enable fundamental equations to be used without the introduction of uncertain approximations and boundary conditions in the calculations.Starting at the beginning of the steelmaking process, very extensive research and development has been carried out to produce liquid steel of the required composition and temperature. The replacement of open hearth furnaces with BOF furnaces reduced refining time from many hours to roughly 30 minutes for 250 tons of steel. Two BOF furnaces effectively enable a continuous flow of steel to be available in a plant, essential for the introduction of the continuous casting process. This area of research will not be considered here."

Jan 1, 1981

By John Battista

Uranium mining in Australia has a chequered history. This paper reviews the development of the Australian uranium mining industry from the 1930?s to the present day. It outlines the geology of the various deposits and the mining and metallurgical techniques used to extract the uranium. The industry is profoundly affected by government policies and the paper considers the roles of the Federal, State and local governments. The influence of public opinion on nuclear issues and the effects current and historical policies of various governments have had on uranium mining are outlined. Despite heavy restrictions placed on it, Australia?s uranium mining industry has maintained its place as one of the world?s largest producers. This paper also provides an outline of where the industry in Australia may be headed in future.

Aug 1, 2010

By C. L. Belyk

There are fifteen accepted types of uranium ore deposits and at least forty subtypes readily identified around the world. Each deposit type has a unique geological model which may also have unique processing implications. Primary uranium production in the past decade has come from a handful of these deposit types: unconformity, sandstone, calcrete, intrusive, breccia complex and volcanic. Processing implications for each of the fifteen deposit types can vary widely between and within different geological models. Some key characteristics of uranium deposits that may have processing implications include: ore grade, uranium and gangue mineralogy ? including clay and carbonate species and content, hardness, porosity, uranium mineral morphology, and carbon content. Processing roadblocks may occur as a result of one or more of these characteristics for any of the fifteen deposit types. Future technological advances and innovative thinking around uranium ore processing could provide avenues for roadblock removal setting the stage for additional and economically-viable uranium production from traditional and non-traditional uranium ore deposits.

Aug 1, 2010

By Kimberly Morrison

Strategically located within the Uravan Mineral Belt District of western Colorado, the Piñon Ridge Project is the first new uranium mill being proposed for construction in the United States in over 25 years. In 1992, dramatic changes to the US regulatory environment for uranium ore processing occurred making regulatory compliance an increased challenge for a new facility. Proposed as a 6.3 million tonne uranium milling operation, the mill will receive ore from a number of mines in the region. The project includes design and permitting of a uranium/vanadium processing facility, tailings cells, evaporation ponds, and ore stockpile pads. The focus of this paper is to provide an overview of the US regulations and how these regulations were applied to design of the mill facilities, as well as provide a status update on the project as the mill license application was submitted to the Colorado Department of Public Health and Environment (CDPHE) in November 2009.

Aug 1, 2010

By K. Waters, A. Navarra, T. Grammatikopoulos

Strategic decisions to develop a mineral deposit are subject to geological uncertainty, due to the sparsity of drill core samples. The selection of metallurgical equipment is especially critical, since it restricts the processing options that are available to different ore blocks, even as the nature of the deposit is still highly uncertain. Current approaches for long-term mine planning are successful at addressing geological uncertainty, but do not adequately represent alternate modes of operation for the mineral processing plant, nor do they provide sufficient guidance for developing processing options. Nonetheless, recent developments in stochastic optimization and computer data structures have resulted in a framework that can integrate operational modes into strategic mine planning algorithms. A logical next step is to incorporate geometallurgical models that relate mineralogical features to plant performance, as described in this paper.

Jan 1, 2017

By K. Poorhaydari, B. M. Patchett, D. G. Ivey

In this paper, some applications of carbon extraction replicas, as samples for transmission electron microscopy (TEM), are discussed. Modern high strength microalloyed (HSMA) steels, used as structural or pipeline materials, have very small grains with substructures. Replicas used in TEM can resolve the grain boundaries and can be used for grain size measurements in cases where the small size of the grains pushes the resolution of conventional optical microscopes. The grain size variations obtained from replicas correlated very well with mechanical property variations, indicated by hardness, in the fine-grained heat-affected zone and base metal of some welded HSMA steels. Replicas are also very suitable samples for precipitate examination with analytical TEM. Advantages and limitations of the application of replicas, as well as some corrections for the estimation of the volume fraction of fine precipitates, are discussed.

Jan 1, 2005

By Schoeman L., K. C. Sole

Evaluation and measurement of the influence of changes in conditions and electrolyte composition during early stages of a growing metal electrodeposit are crucial to predict changes in developing morphology. A galvanodynamic polarization technique was developed to reliably measure overpotentials for nickel electrodeposition from sulfate electrolyte. The validity of these polarization parameters as indicators of the relationships between changes in the electrolyte and resulting deposit morphology was evaluated for electrolytes of varying composition. Findings indicate that nucleation and plating overpotentials measured by the described technique can be used as indicative tools for monitoring, evaluating and ultimately improving control of the electrodeposition of nickel from sulfate electrolytes. The results predict that nickel deposits of desirable quality and morphology are obtained when plating overpotentials are higher than 700 mV vs. Ag/AgCl and nucleation overpotential is less negative than plating overpotential.

Jan 1, 2017

By L. Haavanlammi

The Outokumpu HydroCopper® process is a chloride based atmospheric leaching process alternative that can treat a variety of different concentrates. Chalcopyrite and other copper sulfides can effectively be leached under atmospheric pressure in strong, aggressive chloride solution using copper (II) ions as oxidant. Impurities are removed from the solution as carbonates and ion exchange. Copper is precipitated from the purified pregnant leach solution as copper (I) oxide, which is filtered and reduced by hydrogen gas to metallic copper powder, which is melted and cast into copper product. Sodium chloride solution from copper (I) oxide precipitation is decomposed in a chloralkali electrolyser, to products of which are circulated back to the process. The process has been designed for copper concentrates and is a fast and economical way to produce copper wire rod directly from concentrate. The process can efficiently handle impurities like arsenic and mercury, which can be harmful in the pyrometallurgical processes. The process has been tested in the laboratory and 1 ton/day demonstration plant scale and it has been proven to be commercially viable. The process has been designed to meet the strictest directives for emissions. Other environmental factors are carefully considered to obtain the highest possible eco-efficiency.

Jan 1, 2007

By Joey R. Kish, Shooka Mahboubi, Hatem S. Zurob, Gianluigi A. Botton

The kinetics of the Cr2O3-based scale oxidation and volatilization were studied in the presence of water vapour (H2O). A commercial Cr2O3-based scale forming Type 310S stainless steel was examined at the ambient pressure (0.1 MPa) and 550ºC in relatively low and high H2O containing environments of air- 10% H2O and air- 70% H2O, respectively. The increase in the partial pressure of H2O (pH2O) from 10% to 70% resulted in transition of the oxidation and volatilization kinetics from the parabolic rate law for air-10% H2O to the paralinear rate law for air-70% H2O. The kinetics transition was attributed to the increase in the Cr loss rate from the base scale after coupons exposure in air- 70% H2O. The significant role of the Mn alloying element in the base scale protectiveness was also discussed in the context of the Cr2O3-based scale stability.

Jan 1, 2017

By S. Castro

Hydrolysis of metallic ions depends on pH and the products of hydrolysis either activate flotation or can lead to inadvertent activation of gangue particles, but can also depress flotation of valuable components. One of the most recently studied topics is the use of seawater in flotation. Seawater is a concentrated NaCl solution (about 0.6 mol/L) that also contains considerable amount of Mg2+ and Ca2+ ions. The hydrolysis products of Mg2+ strongly depress flotation of molybdenite over the pH ranges over which they form in the process water. This effect can be eliminated by removal of hydrolysing ions from the process water or by carrying out the flotation at the pH over which such a hydrolysis can be avoided. The former can be exemplified by prior precipitation of the harmful hydrolysing ions as, for example, in the University of Concepcion Patent. The latter can be exemplified by the use of metabisulfite to depress pyrite in the flotation of Cu-Mo sulfide ores in seawater, the process that is carried out at much lower pH, which avoids formation of Mg2+ hydrolysis products.

Jan 1, 2017

By J. Donnelly, A. V. Deev

Substitution of coal and coke by renewable carbon (charcoal) is a low-risk and low-capital path to 50% or more reduction in net CO2 emissions by the steel industry. However, the high cost of charcoal and its low availability in most countries are barriers for the implementation of this approach. Development of an efficient wood carbonisation technology (slow pyrolysis) capable of producing large-volumes of charcoal from low-cost wood feed (e.g. wood wastes or forest residues) is an essential step towards the use of renewable carbon by the iron and steel industry. This paper provides a summary of the progress made over several years of R&D covering: (1) development and piloting of a new energy efficient slow pyrolysis process for production of charcoal from woody biomass at a competitive cost to the PCI coal, (2) techno-economic evaluation of the process. The main feature of the process is that the material undergoing pyrolysis is heated spontaneously without the supply of heat or air to the reactor. This makes it possible to carbonize large volumes of small-sized wood (e.g. wastes and residues) in a single reactor unit and capture high calorific value pyrolysis by-products

Jan 1, 2015

By P. Homola, M. Karlík, M. Slámová

"Aluminum sheets (AA1199, AA8006, and AA5754) were processed by accumulative roll-bonding (ARB) in the temperature range from 20 to 350°C. The microstructure of the sheets was characterized by means of scanning and transmission electron microscopy and electron backscattered diffraction. Mechanical properties were monitored by hardness measurements and tensile tests. Increasing strain (number of ARB cycles) led to incremental development of lamellar microstructure with a decrease of the spacing between high-angle grain boundaries in the normal direction of sheets. ARB process produced an important increase of strength while maintaining thickness and relatively high ductility, without accenting of the anisotropy of mechanical properties of sheets. The level of hardening decreased with the processing temperature and at 300 and 350°C ARB caused even the softening of the material due to the recovery of the deformed microstructure or partial recrystallization during heating to ARB processing temperature.INTRODUCTION Accumulative Roll Bonding (ARB) is a technique of grain refinement by severe plastic deformation (SPD) proposed by Saito et al. (1999). One ARB cycle consists in sheet cutting, surface treatment, stacking of two pieces, heating (optional), and rolling with 50% reduction in thickness. Since the sheet thickness remains unchanged by this cycle, ARB processing can be repeated as many times as desired. The goal of ARB is to impose an extremely high plastic strain on the material, resulting in structural refinement and strength increase without changing specimen dimensions. After several cycles, ultra-fine grained (UFG) materials with high strength and relatively high ductility are produced. An advantage of this method is that it does not require any special equipment as other SPD methods such as equal channel angular pressing (ECAP) (Valiev & Langdon, 2006), high pressure torsion (HPT) (Valiev et al., 2000), or cyclic extrusion and compression (CEC) (Richert et al., 1999), but only a conventional rolling mill and so it is seen as an economically viable and industrially scalable processing route. ARB processing has been successfully applied to various kinds of metallic materials at room or elevated temperatures (Tsuji, 2005). Besides processing single metals and alloys, ARB has also been used for creating ultra-fine grained and nanograined metallic composites (Wu et al., 2010; Qu et al., 2014)."

Jan 1, 2018

By N. Djilali

Many of the transport phenomena encountered in proton exchange membrane fuel cells occur intrinsically at the microscale level. Physically representative models that fully account for the salient physico-chemical and transport processes in PEM fuel cells are necessary to achieve truly predictive models that can be used with confidence to: (i) gain a better understanding of in-situ processes and couplings, (ii) explore new concepts, and (iii) support design and optimization. The development of more general, rationally based macroscale models requires use of knowledge on the microscale level to provide guidance, and to determine the required parameters and coefficients (model "constants"). In this paper we present a new membrane transport model, the binary friction membrane model (BFM2), recently developed to account for coupled protonic and water transport in polymer membranes. This general model is based on rational and physical consideration, removes several of the limitations of the empirical models used to date, and is formulated for all purfluoro-sulfonic acid membranes. The use of the BFM2 in a fuel cell model is illustrated highlighting significant performance predictions compared to existing empirical model. The second part of the paper addresses the fundamentals of two-phase transport in hydrophobic gad diffusion media. Computational and experimental visualizations resolving the microscale dynamics of water transport between the fibres of a GDL are presented, revealing transport mechanisms that are, contrary to assumptions used to date, dominated by fingering and channeling.

Jan 1, 2005

By Elizabeth Edwards, Radhakrishnan Mahadevan, Vladimiros G. Papangelakis, Srinath Garg, Kurtis Judd

Mineralogical characterization of the tailings showed the deportment of Ni to be similar in the Vale and Glencore tailings, with 60% of the total Ni locked in pyrrhotite, and the balance 40% associated with pentlandite. The overall Ni dissolution was correlated with the individual dissolution extents of pyrrhotite and pentlandite as functions of four leaching regimes: ‘anoxic acid’ (with and without pH control), ‘oxic acid’ (oxygen sparging), ‘oxic acid’ (air sparging), and ‘oxic ferric’ (air sparging). The results showed that the maximum Ni dissolution was obtained during the pH controlled oxic acid leach with oxygen sparging at pH 1.5, while the anoxic acid leach at pH 1.5 resulted in minimum Ni dissolution (10–15%) from pyrrhotite. An overall Ni mass balance showed that pyrrhotite and pentlandite dissolve simultaneously in the presence of Fe(III) and oxygen, in contrast to the preferential dissolution of pyrrhotite in the absence of Fe(III). Sulphur mass balances revealed that the yield of elemental sulphur is maximized (65%) during the oxic Fe(III) leach at pH 0.6. Furthermore, the kinetics of Ni leaching and elemental sulphur formation from pyrrhotite tailings leached with ferric sulphate between 55–80°C was investigated at constant oxidation-reduction potential. Elemental sulphur yield increased with increasing temperature, but no observable trend could be linked to ferric or ferrous ion concentration.

Jan 1, 2017

By N. Schreithofer, M. Aspiala, R. Serna

The novel attachment timer apparatus presented in this paper serves as a diagnostic tool that allows the detection of changes in bubble-particle attachment probability and therefore floatability caused by alterations in the chemical environment and particle properties. The apparatus consists of six identical capillaries where bubbles with defined size are produced simultaneously in a measurement chamber. The bubbles at the capillary tips are placed in contact with the submerged particle bed for specific time periods, controlled with the help of automatic actuators. The advantage of the instrument is that hundreds of bubble-particle contacts can be measured automatically within a short time period. Microscopic pictures of each measured bubble are taken while recording the movement of the bubble before, during and after contact with the solid particles. The recorded pictures can be used to determine the actual bubble size and its corresponding deviation, and to detect the attachment of particles. The attached particles are collected in a detachable chamber for subsequent characterization. Furthermore, the device is portable and can be taken to the mineral processing plants for quick evaluation of particle-bubble attachment efficiency with particles and process water sampled directly from real processes.

Jan 1, 2017

By Nawshad Haque, Leanne Smith, Hal Aral, Joseph Cho, Warren Bruckard

"Water availability is one of the principal parameters in determining the feasibility of mining projects in arid and semi-arid regions. The volumetric water footprint (VWF) of a conceptual model of a copper flotation plant was found to be 2.45 kL/t Cu ore, compared with an actual measurement reported in the literature of 2.72 kL/t Cu ore. The flowsheet considered included mineral processing stages such as crushing, screening, grinding, classification, separation, flotation, thickening and filtration. The effect of a number of variables on the VWF was evaluated, including solid/liquid ratio, feed mass flowrate, ore loss, water loss, moisture content of ore, ore grade and water recycling. The use of seawater with recycling provided the most environmental and economic advantage among several scenarios evaluated. The study assumed a price of $1/kL freshwater, $4/kL for transport over a 200 km distance at 2,000 m altitude and $4/kL for water treatment. The water related cost of the desalinated seawater use scenario was A$493/t Cu concentrate, while the water related costs of fresh water and blended water scenarios were A$308/t and A$268/t Cu concentrate, respectively. The water related cost (fresh water scenario) accounted for 44% to 49% of the entire mining and processing costs that included drilling, blasting, loading, hauling, crushing, grinding and concentrating. The total overall cost was A$435/t Cu concentrate for the seawater with recycling, compared to A$451/t Cu concentrate for the fresh water with recycling case.INTRODUCTIONReducing the water footprint (WFP) by utilising alternative water sources has been a focus of mining projects due to increasing concerns about water scarcity and growing energy costs. The global mining industry can expect to experience fresh water shortages in the future, and saline or hyper-saline water may be the only available water source to process minerals in arid regions. Extensive studies on alternative water sources (e.g. seawater, desalinated seawater, blended water) and the reuse of process water have recently been conducted (Moreno, Aral, Cuevas, Monardes, Adaro, Norgate & Bruckard, 2011; Aral, Mead, Cuevas, Davey & Bruckard, 2010). Such studies provide sustainable and economic strategies for mines and concentrators in the arid or semi-arid regions of the world such as in Chile, Peru, Indonesia, and Portugal. More work, however, is needed to confirm water consumption data for different base metal flowsheets and use this data to develop water models that can lead to reduced WFPs and more sustainable water usage in the mining industry."

Jan 1, 2016

By L. Voisin, E. Díaz, V. Montenegro, W. Kracht

Grinding media is of great concern in the mining industry mainly because its consumption represents an important part of the costs during mineral processing and consequently, of the total mining business OPEX. In addition, grinding media consumption impacts directly on flotation performance through negative contamination by corrosion, affecting the pulp chemical potential, complicating the understanding and control of the process, as galvanic interactions between mineral species also occur. In addition, during the process there is also a physical consumption of the grinding media through erosion and impact. In both cases, mineralogy has an important role because pulp abrasion power, chemical reactivity, rheology, hardness and other variables depend on the minerals contained in the pulp and their interactions. In the present study, a geometallurgical and phenomenological model, which describes the grinding media consumption and its relationship with mineral hardness expressed by Bond Work Index, was obtained based on advanced mineral characterization techniques such as Hylogger3TM, X-ray diffraction, X-ray fluorescence and experimental grinding tests using a laboratory mill applied on Chilean copper pulps. The results obtained show that pH has an important effect on grinding media consumption, because corrosion varies with hydrogen ions availability. Also, mineral hardness depends on mineralogical composition, but textural analysis must be performed to have a better description of this property. Finally, minerals present in a sample define the grinding media consumption mechanism, because a sample with harder minerals and a greater value of Bond Work index is capable of protecting grinding media from impact wear, while a sample with lower hardness but with a big sulfide minerals content would be more aggressive with grinding media because corrosion is more important in this case. The geometallurgical model obtained is capable to relate the grinding time, mineral hardness, content of sulfide minerals and grinding pH to estimate the grinding media consumption.

Jan 1, 2017