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By L. Nutter, J. Clancy

"Barite is used extensively by the oil and gas well-drilling industry as a weighting agent. It is particularly well suited for drilling mud because of its qualities; it is non-abrasive, heavy, virtually inert chemically, easy to handle and inexpensive compared to other available heavy materials. Increased deep well drilling in Western Canada, and especially in the Arctic regions, could dramatically affect the demand for barite through this decade. Known deposits in northeast British Columbia are possible sources of incremental barite supplies, should the situation develop.IntroductionThe purpose of this report is to examine the opportunities for expanding barite production in British Columbia. Of primary interest will be the relationship between the projected future levels of production and consumption of barite in Western Canada and the extent to which increased domestic production could replace the need for imports in filling any expected supply shortages.After a brief overview of the nature and uses of barite and some of the relevant features of the barite supply industry, the discussion will turn to the supply gap in the Canadian market and the possibilities for import substitution.OverviewBarite is an industrial mineral which is used in large quantities by the oil and gas well-drilling industry. It is often an important component of drilling mud, a fluid circulated continuously in the well during the drilling process to lubricate and cool the drilling apparatus and to contain the high oil and gas pressures found at depth. Barite (BaSO4) is particularly well suited as a weighting agent for drilling mud because it is a heavy (specific gravity to 4.5) inert mineral which is inexpensive in relation to other materials having a high specific gravity. In the on-site use of drilling mud, ground barite is combined with numerous other solid ingredients and chemicals in the form of a slurry. Other advantages of barite include cleanliness, ease in handling and its non-abrasive character (hardness of 3-3.5)."

Jan 1, 1982

By Kazuteru Tozawa, Robert G. Robins

"The stability of calcium arsenate is discussed in relation to the possible misuse of lime in the treatment of gold processing waste waters. Stability diagrams have been derived and experimental results cited to show that calcium arsenate has a higher solubility in neutral to alkaline solution than has previously been recognized and this solubility is further enhanced by the presence of carbon dioxide, bicarbonate or carbonate.IntroductionThe removal of arsenic from gold mine waste waters has been of interest for more than thirty years, but with the recent emphasis on clean water standards there has been renewed activity in relation to that problem. The processing of gold-bearing sulphides which contain arsenopyrite and other complex arsenic sulphides is well established. Initial roasting to oxidize the sulphides leaves the arsenic in the form of both arsenic and arsenic, in which forms it is soluble in the subsequent leaching stage. Further oxidation of the leach liquors is required before the well-established procedure of precipitating calcium arsenate with lime, which is carried out despite an immense lack of knowledge of the calcium-arsenic-water system.The solubility product and free energy of formation for Ca3(AsO4)2, which are to be found in recent and reliable sources of data, originate from the work of Chukhlansev, whose experimental determination of the concentration of calcium from the solubility of calcium arsenate in solutions of various pH yields the results plotted in Figure 1. This is the work which has resulted in a wide acceptance of the ""insolubility"" of calcium arsenate and the use of lime to stabilize arsenic in that form.Laguitton attempted to further elucidate the chemistry of the lime addition method for treating arsenical waste waters from gold processing operations. The low solubility product for Ca3(AsO4)2 was the basis for his examination of likely chemical equilibria in the system. Laguitton and other workers have not considered atmospheric carbon dioxide as an important component in this system."

Jan 1, 1982

By V. Vekris

A diverse patent portfolio and an effective intellectual property strategy are vital in today’s small business world. Not only does a diverse patent portfolio enable a company to secure a monopoly within the market, it greatly increases the value of a company’s intangible assets and keeps competitors at bay. An overview of the patenting process as it pertains specifically to the materials science-related start-ups will be given, together with a summary of some general patenting strategies and a review of some patenting errors to be avoided, such as premature disclosure of the invention to the public. Additionally, a review of new “green technology” initiatives recently adopted by Patent Offices around the world is also provided. These initiatives are expected to greatly benefit patent applicants in the fields of metallurgy and mining, where research efforts are often directed to environmentally-friendly products and processes. INTRODUCTION Patents are playing an increasingly significant role in the business world. A diverse patent portfolio can enable a company to secure a monopoly within the market, which can provide a competitive advantage over competitors. At the same time, patent portfolio of any size can greatly contribute to the total value of a company’s intangible assets. As an example, Nortel entertained bids in 2011 for its portfolio of about 4000 patents, a large portion of which were directed to 3G- and 4G-mobile communication technologies. The portfolio was eventually sold for $4.5 billion to a consortium including Apple, EMC, Ericsson, Microsoft, Research in Motion, and Sony. Copper mining, and indeed the global mining industry as a whole, is facing challenges. Ore deposits are increasingly low grade, complex, and deeper in the ground, rendering copper mining operations more difficult and costly. Production costs are increasing. According to one study, the cost of producing copper has increased by an average of 10% per year since 2005 (Cantallopts, 2017). To illustrate, the cost of producing a pound of copper in 2005 was 90 cents, but had increased to 217 cents by 2014.

Jan 1, 2019

By V. ?. Chanturiya, G. P. Dvoychenkova, ?. Ye. Kovalchuk

"Several mineralogical investigations have revealed the composition of modified kimberlites and the mud generated during treatment of diamonds, which contains up to 50% clay minerals (e.g., talc, talcsaponite, chlorite-saponite, Na-saponite) and X-ray amorphous phase. We investigated the composition of the natural diamond surface in relation to the diagnosed minerals and established the sequence and conditions for mineral formation on the crystal surface under kimberlite processing conditions. This article suggests a method to destroy and further dissolve minerals on the crystal surfaces using water system electrolysis products, which makes it possible to restore the diamond hydrophobic properties. The application of chemically treated water in the foam separation cycle under the conditions of high recovery of diamonds made it possible to increase the content of the factory concentrate by 8.0%.INTRODUCTIONThe high content of the modified minerals in the kimberlite ore results in the formation of hydrophilic slicks on the surface of the crystals which decreases the diamond’s hydrophobic properties and increases the losses thereof in the process of grease and foam separation to 20-30% (Kurenkov, 1957; Chanturiya et al., 1998, 1999, 2005; Duikarev et al., 2000).The previous researches have revealed the fact that the prospective way of solving the problem of intensity of mineral impurities formation on the surface of the crystals and the increase of concentration parameters is reached due to application of physical and chemical stimulation techniques on the solid and liquid pulp (Stricland-Constable, 1971; “Improvement of the technology…”, 2006; Makarskii, Adodin & Tarasova, 2011; Chanturiya, Dvoychenkova & Trofimova, 2012). However, the main task of investigations to stipulate the objective achievement is the studying and justification of the reasons of the diamond surfaces covering by the mineral slicks"

Jan 1, 2016

By E. Mataradze

Statistics shows that the majority of accidents with fatal outcome are caused by methane and/or coal dust explosion. This leads to assume that contemporary counter-explosion systems of various designs cannot be considered effective. Considering the growing threat of methane explosion in the coming years along with the development of deeper levels, the improvement of a system for protecting people in underground opening appears urgent. This paper presents the results of the testing of the Automatic System from Methane Explosion in Coal Mines. The protective system consists of: i) a wireless device for the detection of explosions and activation of a protective system, and ii) an absorber with a pyrotechnic device ensuring the discharge of dispersed water. The protective system, at the command of the initiation signal, produces tailored dispersing water mist with droplet sizes in the range of 25?400 ?m along selected tunnel sections.

Aug 1, 2013

By J. Jara

Oxygen, ozone and air were evaluated in the oxidation of ferrous iron in the presence of hydrochloric acid ranging from 0.1 to 4 M HC1. Stoichiometric coefficients were determined through mass balances of gases and ferrous titration. The molar ratio ferrous to ozone increases from two at 0.1 M HC1 concentration to six at 4 M HC1. For oxygen the same ratio is constant and equal to 2 and it is in agreement with other works. The stoichiometric coefficient of hydrogen ion was not defined due to the effect of hydrolysis of ferrous and in particular ferric ion on measuring acid concentration by titration with sodium hydroxide. Agitation, gas flow and pressure contribute in the utilization of gas. A technique to compare the gas efficiency at several conditions is discussed and it is based on the relationship between oxygen and ferric during time. There is a strong compromise between gas efficiency and ferrous conversion. Oxygen efficiency decreased with time due to ferrous depletion. The gas efficiency ranged from 3 % (low level of agitation) producing 25 g Fe(III)/h to 12 % at 1000 rpm with 60 g Fe(III)/h converted. At 405 kPa absolute the oxygen efficiency was in the range of 80 % producing 300 g Fe(III)/h. The replacement of chlorine with oxygen to enrich molybdenite concentrates by reducing copper to less than 0.2 % was evaluated. Oxygen can be employed in batch or continuous operation and it can treat molybdenite concentrates with high variation of copper content. The dissolution rate is mainly controlled by oxygen addition in which utilization of oxygen plays an important role. Improvement on safety and environmental conditions is feasible by using oxygen instead of chlorine gas. The economics indicate good opportunities to implement oxygen without significant modifications to the actual circuit and enough benefit when oxygen is well used.

Jan 1, 2007

By Philippe V. Scheers

Polycrystalline gold, glassy carbon and gold-activated glassy carbon electrodes were compared for the production of hydrogen peroxide by the cathodic reduction of dissolved oxygen. Gold was deposited on glassy carbon by sputtering with a sputter coater and by electrodeposition from a diluted KAuCl4 solution using short potential steps. The sputtered gold particles were not adherent enough, but there were no adhesion problems with the electrodeposited gold particles. The gold coverage of the glassy carbon surface could be varied by applying a different number of potential steps. The overpotential for the electroreduction of oxygen to hydrogen peroxide decreases with increasing gold coverage of the glassy carbon surface, and for gold coverages exceeding about 16 %, the overpotential is close to that observed on polycrystalline gold.

Oct 1, 2003

By R. D. Brown

"Concerns over possible additional involvement of governments in Canada's mining industry and its adverse effects on the industry 's growth were a frequent topic of conversation at the recent Annual General Meeting of the CIM.Still painfully fresh in the minds of industry leaders are the disastrous results of the federal/provincial scramble over resource revenues which followed the relatively high metal prices witnessed in 1973/1974. At current metal prices, it is not surprising, then, that a nagging fear persists that these governments may once again restructure tax and other rules to the detriment of the industry and the country.This month, Tax Notes recalls some of the progress which the industry and governments have made in 1979 in the taxation of the resource sector, and urges that higher metal prices be viewed in light of the costly exploration, development and production efforts which will be required for the industry to continue to play its important role in our economy.IntroductionAt the Annual General Meeting of The Canadian Institute of Mining and Metallurgy, held in April, 1980, it was abundantly clear that there is widespread concern in Canada's mining industry that this country's tax regime may once again be blasted by ill winds of change.A stable and more favourable tax climate, as well as higher metal prices and profits, made 1979 almost a golden year for Canadian mining. However, from the tax viewpoint at least, there are some spots on the silver lining as apprehensions grow that the well-heralded battle between federal and provincial governments over oil and gas may spread to the mining sector, with serious damage to the industry and its newfound federal-provincial cooperation."

Jan 1, 1980

By K. N. Karparov

?Two highwall failures in a South African coal mine defied analysis by widely accepted limit equilibrium methods. ?The geological conditions were complex, with undulating coal-bearing strata overlying a karstic topography formed in underlying dolomite belonging to the Transvaal Supergroup. ?It was clear that the simplifying assumptions made by all limit equilibrium methods were inappropriate in the conditions.

May 1, 2007

By W. J. Przybylowicz, V. M. Prozesky, D. de Bruin

"The common style of gold mineralization in the Basal Reef and other auriferous conglomerates of the Witwatersrand Supergroup comprises clusters of gold grains occurring interstitially to quartz and pyrite pebbles as well as gold accumulations attached to the surface of and infilling hairline cracks and fractures in round, compact, detrital pyrite. The latter textural association is generally interpreted as a result of remobilization of originally detrital gold during regional metamorphism and related hydrothermal fluid circulation. There is general agreement that, although gold solubility was low, ore modification occurred during the metahydrothermal event, but uncertainty exists about the magnitude and scale of gold remobilization.Micro-textural and chemical investigation of compact round pyrite and associated gold accumulation has established that gold is preferentially deposited on chemically heterogeneous pyrite surfaces. Combinations of alternating high- and low-As zones in pyrite result in mixed np-type conductivity accompanied by electron exchange and the reduction-driven deposition of gold at the cathode. This model does not explain gold accumulations which are not immediately linked to chemical heterogeneities and it is inferred that an additional control on the deposition of gold was exerted by physical defects which lead to zones of increased charge density and/or areas of focussed conductivity. The inferred precipitation mechanisms suggest that submicrocopic physical and chemical controls are the important factors that determined the sites of gold nucleation and that precipitation mechanisms based on physicochemical changes of the hydrothermal system were not involved. The Basal Reef contains on average close to 5OJo of round, detrital, chemically zoned pyrite which provides a large number of electrochemically active pyrite surfaces. The extremely effective electrochemical precipi- . tation mechanism together with the low solubility of gold in Witwatersrand fluids is the main reason for the spatially restricted remobilization of gold in the conglomerate reefs."

Jan 1, 1994

By Lawrence Devon Smith

The Business Case for Sustainable Development ?What are SD & TBL? ?Investment Funds & Fund Managers ?Banks and Risk Aversion ?The Dilemma of Juniors ?Meet Your New Partners ?The Cost of Problems ?The Cost of Delays Sustainable Development ?Humanity has the ability to make development sustainable -to ensure that it meets the needs of the present without compromising the ability of future generations to meet their own needs.? Our Common Future BrundtlandCommission, 1987

May 1, 2003

By Ernest Becker

Golder Associates provided overall radiological direction and assistance to the client in their interactions with the Canadian Nuclear Safety Commission and operational radiation protection services for the remediation of a calciner that had been used to process uranium. The project was somewhat unusual in that the radioactivity from within the calciner room was removed from the site and the cleaned steel recycled. The presence of yellowcake within the process equipment required stringent radiation protection measures. This project was completed successfully with minimal radiation exposures to the workers and the effective protection of the environment.

Aug 1, 2010

By M. Oliazadeh

The bioleaching of fine low grade copper sulfide ore is described. A sample of ground (> 1 mm) copper ore from Sarcheshmeh, Iran, was subjected to a series of agglomeration procedures and subsequently leached. The best agglomerate was obtained by using lime and sulfuric acid as binders. A column bioleaching test of agglomerated ore was then run for 105 days along with a non-inoculated control column having thymol as bactericide. The results show that about 77.5% of copper was extracted in the bioleaching, whereas the control column achieved only 57% copper leaching.

Jan 1, 2007

By D. Fredlund

The decommissioning of uranium tailings facilities often requires the design of a suitable cover system. In northern climatic environments there is a portion each year that can be considered to be ?inactive? while the remainder of the year can be considered to be ?active?. There are numerous engineering design assumptions required when analyzing both the ?active? and the ?inactive? portions of the year. Cover systems are subjected to complex boundary conditions and nonlinear unsaturated soil properties. The proposed paper describes the steps necessary for the preparation and the analysis of a multi-year climatic database for the design of a cover system in northern environments. The paper also explains how climate can be classified and how observed variations from one year to the next can be taken into consideration in cover design. The results of climatic records at two different sites are used to illustrate conditions that need to be taken into consideration when designing soil cover systems.

Aug 1, 2010

By Maria D. Mastalerz, Wei Wang, Maria E. Holuszko, Amit Kumar

In this study, the micro-FTIR analysis was used to investigate in-situ surface properties of coal and its components (macerals) and these were directly correlated to the coal hydrophobicity as measured by the contact angle before and after reagent addition to understand the suitability of the reagent for flotation. The micro-FTIR technique can provide a semi-quantitative analysis of the chemical functional groups on coal surface, exactly where the contact angle is being measured. Selected functional groups and their ratios that provide information about aromaticity, the contribution of oxygenated groups, and aliphaticity are used to evaluate the reactivity between reagents and various coal components. The observations made in relation to the susceptibility of some reagents towards certain coal components should lead the way to a smarter way of using process design in terms of reagents selection for coal flotation.

Jan 1, 2017

By D. B. Dreisinger, A. A. Gunaratnam

A pressure oxidation (POX)-hot cure (HC)-lime boil (LB) process is used in industry to recover silver from refractory gold sulfide ores containing minerals such as pyrite and arsenopyrite. Pressure oxidation is used to oxidize minerals and liberate occluded gold particles. As such, iron goes into solution and under acidic and high temperature conditions often precipitates as basic iron sulfate (BFS). BFS consumes excess lime during neutralization prior to cyanidation. Therefore, a hot cure stage is required to re-dissolve BFS back into solution. BFS re-dissolution consumes acid and produces ferric sulfate. In the presence of silver, these conditions favor the slow formation of silver jarosite. Silver jarosite is refractory to cyanidation, and must be broken down prior to cyanidation. This is done in the lime boil to produce a cyanide-soluble silver hydroxide. A study was conducted to investigate parameters that affect the precipitates that form in each stage of the POX-HC-LB process.

Jan 1, 2017

By I. Raheb, M. Y. Debili

"A set of Al-Co binary alloys (with respectively in weight percent 10%, 20%, 30%, 40%, 50% and 60% Co) have been studied by X-ray diffraction at the as compacted state. The structural evolution according to cobalt addition shows special features as the apparition of fcc cobalt and hcp cobalt beside aluminium in some cobalt compositions of the Al-Co mixtures using only cold compaction without sintering at high temperature. Figure 1 Cobalt is not a common alloying element in aluminium because its solubility is very low [1]. According to the pressure-temperature phase diagram, Co is known to exist in two allotropic forms: a low-temperature hcp phase and a high-temperature fcc phase [2-3]. At room temperature, Co is stable in the hcp form but it transforms to the fcc form when it is heated to above the transition temperature 695K. Powder aluminium and cobalt (99.999 %) were used in the proportions defined according to the required compositions. The total mass of the samples to be elaborated was between 8 g and 10 g. Cold compaction of mixed powder (Al-Co) under an uniaxial load of 10 MPa has been achieved to obtain a dense product (60%)."

Jan 1, 2015

By V. G. Papangelakis, I. Guzman, S. J. Thorpe

Pressure oxidation (POX) leaching has been commercially applied to refractory gold ores since the 1980s. In the process, sulphide material is oxidized and dissolved in order to release the gold encapsulated in the sulphide matrix, making the gold available for further recovery. Redox potential is a significant parameter during POX, however it is only measured ex-situ at atmospheric conditions. In-situ redox potential measurement would provide instant information that allowing adjusting the process parameters accordingly. In the present study, redox potential measurements were performed during POX of sulphide material at high temperatures and high pressures. The working electrode was an Ir electrode combined with a flow-through reference electrode in a novel and robust configuration. Experiments were performed in a 2 L titanium autoclave, at 200–220°C, 50–110 psi oxygen overpressure, and 10–30% solids mass fraction. Temperature and oxygen pressure conditions were selected in order to reflect POX of refractory gold ores. Results show that the Ir electrode is consistent with theory and is able to perform well under these conditions, showing promise as a new in-situ sensor.

Jan 1, 2017

By Baseer Abdul, Edouard Asselin

Hydrometallurgical leaching of sulfide concentrates of copper and nickel at medium temperature (150°C) produces residues that contain sulfur and iron bearing minerals and phases. During leaching, and depending on various process parameters, iron may be precipitated as hematite, goethite, jarosite or other oxyhydroxides, which may be more or less crystalline. Hematite is the favored precipitate because it is the most environmentally stable and does not ad/absorb as much copper, nickel or other solution constituents during precipitation. However, the low solubility of iron during the medium temperature processing of sulfide ores can favour the formation of poorly crystalline, nano-scale iron oxide/oxyhydroxide phases. In some cases these phases have been positively identified as the metastable ferrihydrite, which transforms into iron oxides such as goethite, hematite and magnetite over time. A better understanding of what may help drive this transformation during leaching would ultimately result in lower valuable metal losses and more stable leach residues. Higher acid concentrations result in increased copper extractions and favor the formation of hematite during concentrate leaching, rather than other metastable phases. Furthermore, commercially available water displacement formula “WD40®” and other novel reagent(s) affect Fe precipitation and sulfur chemistry, leading to very different process outcomes such as improved extractions and larger, more easily separated, sulfur particles.

Jan 1, 2017

By S. Banisi, M. Pourkani, A. R. Laplante, A. Partoazar

"Canadian experience in industrial modeling of grinding, classification, and flotation kinetics was applied at the Sarcheshmeh copper mine, which processes 40,000 t/d of ore at 0.9 % Cu, in an effort to improve capacity and metallurgical performance. Mcivor's functional performance analysis was applied to ball mill cyclone circuits to maximize circuit capacity. Plitt's cyclone model was applied to predict how apex wear would affect classification performance, as part of a predictive maintenance program whereby the optimum wear period is determined for cast iron apexes. The flotation flowsheet was improved using Agar's optimization criteria. The impact of these technologies has been nothing short of spectacular, with an improved capacity of 1 S to 20""/o, and increased recoveries.1-IntroductionThe Sarcheshmeh copper ore body, which may rank as third or fourth largest in the world, contains 1 billion tonnes averaging 0.90 % copper and 0.03 % molybdenum. It is located southeast of Iran and has been processing 40,000 t/d of ore since 1982. The mine produces 100,000 tonnes of copper and 2,200 tonnes of molybdenum concentrate per year. After three stages of crushing, the ore with a Fso of 12. 7 mm is fed to 8 parallel ball mills in closed circuit with cyclones to produce a product 70""/o finer than 7 S microns. The concentrate of the first stage of flotation is reground and the tailings constitute the main component of the plant final tailings. A concentrate with an average grade of 31 % Cu is obtained after cleaning and re-cleaning stages. Total recovery of the plant varies between 83 and 87 % depending on the operating conditions and ore type.To improve the overall performance of the plant, it was first decided to evaluate the performance of grinding, classification and flotation. Measures were then taken to improve performance using the following criteria: (i) The improvements should be of the types that have resulted in significant improvements in other plants (e.g. Shannon et al, 1993); and (ii) The proposed improvements must be achievable with the manual operation presently used at Sarcheshmeh. The outcome of this study could also help in making decisions on the implementation of automatic control systems in the Sarcheshmeh copper mine."

Jan 1, 1998