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By W M. Cameron

Geophysical studies have extended seaward in recent years, and the important discoveries which have been made have led to a better understanding of geological processes. A present source of certain minerals, the sea will eventually serve as an important source of desalinated water. The continental helves, in particular, represent a potential mineral resource. The expansion of Canadian oceanographic effort that is now underway will eventually lead to the exploitation of the wealth beneath the sea. THE subject of this symposium, which emphasizes the word "geophysics," the specialties of the speakers who are contributing and the nature of the audience at first made me believe that I, a a physical oceanographer, would be out of place. However, I shall undertake to classify myself as a geophysicist, and shall arrange my remarks on my specialty o that they might be of interest to those of you who are predominantly geologists, metallurgists or mining engineers.

Jan 1, 1963

By A. Staley, W. J. Cashwell, M. S. Moats

In the 1990’s, Técnicas Reunidas developed the Modified ZINCEX® Process to recover zinc from ores and secondary materials. The heart of this process was the use of solvent extraction to produce purified zinc electrolyte instead of traditional zinc dust cementation. This development was commercialized by Reunion Mining and Anglo American for primary ore at the Skorpion mine in Namibia with the first SHG zinc produced in May 2003. Horsehead Corporation through Horsehead Metal Products, Inc., its wholly owned subsidiary, is presently commercializing the MZP for the treatment of Waelz oxide. This paper will review open source information about the lessons learned and process modifications that have occurred at Skorpion over the past decade. It will also provide an update on Horsehead’s facility being constructed in Rutherford County, North Carolina.

Jan 1, 2014

By T. Sakai

Present authors have succeeded in single pass large draught rolling of AZ31 and ZK60A magnesium alloy sheets below 200 °C without heating rolls by raising rolling speed above 1000 m/min. Heavy reduction larger than 60% can be applied by single pass high speed rolling even at room temperature. The rolled sheets showed fine recrystallized microstructure by dynamic recrystallization. The improvement of workability at lower rolling temperature is due to temperature rise by plastic working. In high speed rolling, almost all of the work done by plastic deformation is converted into the heat that raises the temperature of the sheet during rolling because the heat did not flow out of the sheet by conduction and radiation within very short time.

Jan 1, 2006

By Hans D. Gougar

To meet an increasing demand for minerals, mining operations are moving to ever more remote regions. The lack of a local energy supply and infrastructure, coupled with social and regulatory demands for lowered environmental impact of mining operations, presents an opportunity for a seemingly unlikely competitor ? a nuclear power plant. The Modular Pebble Bed Reactor concept, currently in various stages of research and development around the world, offers a high degree of reliability and safety with minimal consequences for the local or global environment. The passive safety features of this design eliminate the need for the extensive active safety systems that add significantly to the cost of current water-cooled reactors. With the MPBR, as with all nuclear plants, there are no appreciable quantities of waste products released to the environment during normal operations. In contrast with conventional reactor designs, the MPBR would also remain radiologically safe even under the most severe abnormal circumstances. The key to the design is the fuel element. Enriched uranium microspheres are coated with various layers of pyrolytic carbons and silicon carbide to form a highly-temperature resistant particle that effectively retains all fission products. These particles are mixed with graphite and formed into 6 cm pebbles. A randomly packed vessel of such pebbles forms the reactor core through which helium is circulated as a coolant. Computer models and tests performed on actual pebble bed reactors confirm that fuel failure temperatures are not reached even during the most severe conceivable loss of coolant accident. The reactor drives a gas turbine cycle with resulting efficiencies as high as 48%, comparable to natural gas-fired units. The low price of uranium fuel and low maintenance requirements translates into competitive operating costs. However, high capital costs prevent the MPBR from competing with natural gas in most markets. In remote applications where no fossil supplies are readily available, the playing field is more level. This paper summarizes the features of two of the more promising candidates for remote applications and discusses the strengths of the MPBR from the perspectives of fuel supply and environmental impact.

May 1, 2002

By R. Clarkson

"Free gold particles occur in many base metal and precious metal mines throughout the world. Due to the high density and malleability of gold, large circulating loads of free gold particles can build up over time in grinding circuits. This gold is often deposited in unintended traps throughout the mineral processing system.These unidentified free gold deposits represent a serious security risk as well as an inaccessible inventory of gold. Deposits of free gold particles often remain undetected by mine management until they are accidentally discovered while repairing mill equipment.Nuclear tracers have been used to determine the free gold recovery efficiency of gravity recovery equipment, drills, and sampling equipment (Clarkson, 1994, 1995; Walsh and Rao, 1986; Walsh and Kelly, 1992). In November, 1993, the author inspected the grinding circuit at La Mine Doyon in Rouyn-Noranda, Quebec and made recommendations to recover coarse gold and to eliminate gold traps from the circuit. In 1995, the author salted mineral processing circuits with radioactive gold particles. The gamma and X-ray radiation from gold’s nuclear isotope (Au198) were detected through steel, in pipes, and in moving equipment using scintillometers. The radiotracers proved to be a safe, rapid and accurate method of identifying gold traps and improving security.Nuclear TracersWhen particles of gold are placed in a nuclear reactor, some of the gold atoms (Au197) absorb another neutron in their nucleus to form gold’s radioactive isotope (Au198). In the process of radioactive decay, this isotope emits high energy gamma rays and X-rays which are easily detected (even through steel) with scintillometers.Radioactive gold (Au198) has a very short halflife of 2.7 days. At the relatively low activity levels used for tracing, the particles remain detectable with a small hand-held scintillometer for about 10 to 14 days. After 14 days the irradiated gold is close to background levels and within two months it is essentially non-radioactive. The radiation has no effect on the recovery characteristics of the gold particles. The gold radiotracers are very safe due to their very low level of radiation, short half-life, and their inherent physical and chemical stability. However, the use and possession of even mildly irradiated gold is strictly licensed and regulated."

Jan 1, 1997

By Tai Sik Lee

Why ISRU into Space Exploration are important NASA and International Mission statements calls for the sustainable human exploration of the Moon, Near-Earth asteroids, and Mars Common Exploration Goals and Objectives are Strongly influenced by ISRU Extend Human Presence: Continually increase the duration and level of self sufficiency at all destinations Develop Exploration Technologies and Capabilities: Develop and validate tools, technologies, and systems that extract, process, and utilize resource to enable exploration missions Perform Science to Support Human Exploration: Characterize available resources at destinations Stimulate Economic Expansion: Encourage commercial services and create new markets, including markets for discovered resources Enhance Earth Safety: Test techniques to mitigate the risk of asteroid collisions with Earth

May 1, 2013

By M. Olper

Commercial copper plants utilising current best technology are tending towards ever increasing scale, the concentrate requirements of which cannot be serviced by a single mine. In such cases, raw materials are often sourced from different mines, which are often far away from the production plant and usually with very different ore compositions. These plants tend to use the traditional thermal processing steps of smelting, converting to blister, anode refining and casting to produce copper anodes that are then refined in a sulphate electrorefining operation. These thermal steps are in some cases troublesome and require the recycling of considerable quantities of material. A new process was developed taking advantage of the latest developments of the first thermal step of the classic loop, the smelting of copper concentrate to high grade matte or white metal using the well known AUSMELT Top Submerged Lancing Technology. The white metal and/or high grade matte product is converted directly to copper cathode and elemental sulphur using the ECUPREX technology. This approach provides an alternative to the traditional thermal steps of conversion to blister, thermal refining and anode casting, which, especially at small scale, can be expensive and problematic in terms of technical and environmental concerns. At first evaluation, this new process can be operated at low capacities, thereby, changing the traditional approach to copper production. Instead of taking the concentrate to the copper production plant, the copper production plant is taken close to the mine with some significant economic and technical advantages.

Jan 1, 2007

By Hervé Toubon, Matthieu Davrinche, Jim Corman, Mamane Bello Boubacar Kinassa, Pierre Amadieu

Orano Mining maintains a significant level of Innovation and Development Research for its sites in Canada, Niger, Kazakhstan, Mongolia, and France. This effort is formalized within the six major thematic programs below, which include more than one hundred affiliated R&D projects:  Geological understanding, tools and methods for exploration  ISR technology (geology, modeling, mining development tools)  Mining technology (SABRE)  Ore treatment and processing (in particular via our Centre for Innovation for extractive metallurgy, CIME)  Environment (radiochemistry, modeling, tools and methods for remediation)  Digital Mine (sensors, transmission, database, and data modeling) This paper describes the main actions of these six programs, their stakes, and their progress. There is no single path leading to innovation but fostering an innovative context and a structured project approach are essential ingredients to successful development and industrial deployment. As a result, Orano Mining has, over the years, developed a disciplined methodology for R&D portfolio and project management. This methodology, presented here, targets a reduction in time to implementation while valuing both the expertise and the work in project mode.

Jan 1, 2020

By P. M. Huck, R. John

"The National Uranium Tailings Program was established in 1982 to develop, in part, a mathematical predictive model which would allow the assessment of the impact of uranium mill tailings on the environment and particularly on humans. . To achieve this , various studies were undertaken to establish the role played by key constituents of the tailings. This paper summarizes the findings of a study carried out under that program, to examine the leachability of barium-radium sulphate sludges produced in the treatment of uranium mill tailings decants. The investigators performed detailed chemical an alysis of the sludge, applied geochemical computer models to investigate sludge leaching behaviour, and conducted experiments to assess the impact of bacteria on leaching. The modelling showed that the redox state o f the sludge-leachant system was the most important factor. Substantial bacterially-mediated dissolutio n of the sludge and release of radium was demonstrated experimentally under suitable reducing conditions . INTRODUCTIONIn September 1981, Phillip A. Lapp presented the final report of the National Technical Planning Group on uranium tailings research to the federal government (Lapp, 1981). Lapp' s group had performed an in-depth survey of the status of uranium tailings research in Canada and, as a result, recommended that a national program be funded in the amount of $18 .6 million. Half of this fund ing was to come from the federal government, with the two producing provinces , Ontario and Saskatchewan, providing the balance. However , the provinces declined to support the program and the federal government decided to inaugurate a reduced program with $8.5 million o f funds .In late 1982, the formation of the National Uranium Tailings Program (NUTP) was announced by the minister of state for mines. A primary objective of this program was to develop a mathematical predictive model that would permit the assessment of the impact of uranium mill tailings on the environment, a nd particularly on humans. The program was to use existing information to the greatest possible extent, and then fund research to fill in gaps or substantiate data where necessary .The NUTP was established to administer this program of contract research over a five-year sunset life. By the end of the 1986-87 fiscal year the NUTP had completed about 100 contracts. One of those projects was to study the effect of placing barium-radium sludge ba ck within the tailings matrix. Th is paper gives the results of that study."

Jan 1, 1989

By Erik Richer La Fleche

LEGAL RISKS LEGAL RISKS ARE COUNTRY RATHER THAN PROJECT RISKS OTHER COUNTRY RISKS ARE POLITICAL AND MACRO-ECONOMIC RISKS COUNTRY RISKS ARE EXAMINED AFTER PROJECT RISKS COUNTRY RISKS COUNTRY RISKS INCLUDE: WAR AND ARMED CONFLICT TERRORISM AND SABOTAGE CURRENCY INCONVERTIBILTY AND TRANSFER NATIONALIZATION AND CREEPING EXPROPRIATION GOVERNMENTAL BREACH AND REPUDIATION OF CONTRACT CHANGE OF GOVERNMENT CORRUPTION COUNTRY RISKS FIRST NATIONS AND LANDOWNER CLAIMS LABOUR UNREST SINGLE CAUSE ACTIVISTS REGULATORY AND BUREAUCRATIC DELAYS CONFLICT BETWEEN GOVERNMENT LEVELS ETHIC AND RELIGIOUS TENSIONS INTERNATIONAL SANCTIONS TAXATION CHANGES CHANGES IN LAW

May 1, 2013

By A. Mukherjee, C. Kelly, B. Markovich, G. E. Agar, G. E. Robertson, F. Khan, B. Shea

"Laboratory batch flotation tests were performed on a sample of bulk slow cooled converter matte (Cu:Ni = I) to optimize the time in each of the separation stages. Numerical simulations were carried out to estimate a continuous circuit material balance for the conditions selected. An experimental simulation of a continuous circuit (locked cycle test) readily came to steady state and there was reasonable agreement between the numerical and experimental results. The use of nitrogen as the flotation gas and the addition of collector to the grinding mill minimized the oxidation of chalcocite, which has previously resulted in increasing circulating loads, and led to a stable circuit with very low weights in the recycle streams.IntroductionINCO Limited developed a flotation process for separating the components of copper-nickel matte [Sproule, Harcourt and Rose 1945; Sproule, Harcourt and Renzoni 1960] in 1945 to replace the Orford process and continues to use the flotation process in almost the original mode to this day. Initially the matte processed was the result of smelting a nickel concentrate that analyzed about 12% nickel and 2% copper and all of the recycle material that was generated in the smelting process. The matte generated analyzed about 25% copper and 53% nickel, roughly 2: 1 nickel to copper. This matte was blown in Pierce-Smith converters to be sulfur deficient in order to produce a metallic phase that collected the precious metals contained in the smelter feed [Wilson and Stratton-Crawley 1991]. This process continued with little change until 1994 when the separation of chalcopyrite from pentlandite in the Copper Cliff mill was discontinued after 63 years of operation. As a consequence of the elimination of the primary separation of chalcopyrite from pentlandite in the milling process a bulk concentrate was produced for smelting. Bulk concentrate smelting came into practice in 1994 as part of the initiative to meet government legislation that restricted the emission of sulfur dioxide to the atmosphere. Previously, the copper concentrate was smelted in an INCO oxygen flash furnace which resulted in the capture of a high strength sulfur dioxide stream from which liquid sulfur dioxide was produced. Nickel concentrate was smelted in reverberatory furnaces that produced low strength sulfur dioxide gases which were difficult to treat. The action taken by INCO to meet the environmental constraints was to smelt a bulk concentrate in oxygen flash furnaces which would produce gases suitable for the production of liquid sulfur dioxide and another stream that was high enough in sulfur dioxide to be readily converted to sulfuric acid [Bell et al 1990]. The end result of this decision was that all the copper-nickel separation would be done in the matte separation plant."

Jan 1, 1996

By T H. Clark, R P. Doig, V. A. Saull, R B. Butler

Terrestrial heat flow has been determined for four boreholes in the Montreal area. The mean value of the results (uncorrected for glacial effects) is 0.790 ± 0.053 x 10-6 cal/ cm2/sec (95 per cent confidence limits). Thermal gradients were determined using a thermistor probe and d-c bridge, and also by a new method using a probe-contained phase-shift oscillator, the output frequency of the oscillator being a function of probe temperature. Thermal conductivity determinations were made on core from the boreholes, using a divided bar apparatus. INTRODUCTION T HIS paper concerns the terrestrial heat flow in the St. Lawrence lowland of Quebec, as determined from measurements on four of the numerous boreholes drilled in this region for gas and oil. The work has been supported by Geological Survey of Canada Re-search Grant 3-58, awarded to T. H. Clark and V. A. Saull. This sup-port is hereby gratefully acknowledged.

Jan 1, 1962

By Paul G. Dunn

The planning of underground mines is a complicated process involving geological, engineering and operational constraints. MIRARCO is in the process of developing a 5D Mining Exploratorium where 3D mining models are combined with time (4th dimension) and costs (5th dimension). The mining exploratorium is a collection of external and inhouse software packages specifically geared to help underground mining companies arrive at better mine plans. This paper discusses the progress made in the development of the 5D Mining Exploratorium and a change in mine planning philosophy by conducting frequent audits in a Virtual Reality Laboratory. The development of genetic algorithms for optimising stope sequences is also presented.

May 1, 2003

By W. L. Single

"LET ME FIRST OF ALL thank you for sending this invitation to me to participate in this Annual Meeting of The Mining Society of Nova Scotia. As an engineer, although I don't get an opportunity to practice very much engineering these days, I am, of course, always pleased to be able to meet with my fellow engineers to exchange views, but I must admit that today I feel a little bit out of place in the midst of all the experts that are here today. Let me make one thing clear - I'm a generalist! Your program states that I am to make a keynote address. I have always thought that a keynote speech is one that says something that has not been said before - announces some new program or policy, or says something startling. I am sure you will understand when I tell you that keynote addresses are made by politicians and that civil servants speaking publicly are usually expected to give an account of what is, or what is likely, to happen as a result of policies that have been announced in keynote speeches by politicians. I am reminded of a statement by a distinguished parliamentarian who said, ""However exalted a civil servant may be, he is not above the elected officials."" So today I will confine myself to giving you an overview with particular emphasis on the development side of oil and gas. The theme of ""Oil and Gas"" is a topical one these days. I suppose it's because of all the copy that is being generated by the media on the U.S. energy crisis, the Mid-East situation, the fact that most of the world's proven oil reserves are in Arab hands and, of course, the accelerated exploration activity that is taking place in the North Sea, in the Arctic, and off the coast of Newfoundland and Nova Scotia."

Jan 1, 1973

By The Staff

This is in direct contradiction to the generally accepted philosophy of tube-mill grinding, which is based upon an enormous amount of experiment carried on in different parts of the world. Personally, I have no faith in the reliability of these conclusions of the authors. (Incidentally, the two circuits compared consist of six mills each of which the change in the hook-up is only in the last three mills-in one case, these three mills are in closed circuit and in the other, open or series circuit. Hence the last three mills are alone responsible for the alleged improvement, which means that the improvement in these three mills amounts to at least 18.8 per cent). The value of these figures depends upon the reliability of the work, of the measurements and the calculations of the authors. As very little information is contained in this Addendum concerning the methods of the work and the details of the measurements, it is necessary, in order to form an estimate of this reliability, to study carefully the previous paper published in the July, 1940, BULLETIN(3). Referring to the original paper, the present paper has this to say (bottom of page 379): "Here it may be remarked that we have made more money for Lake Shore digging into and forming the report than in obtaining the figures and data, and so far have never gone back to work on it without a resulting Lake Shore profit". Let me state that I, so far, have never gone back to work on it without finding more discrepancies and inconsistencies and illogical reasoning. In my first contribution to the discussion of the first paper, which discussion was published on page 355 and following, in the July, 1941, BULLETIN, I pointed out discrepancies and inconsistencies and illogical reasoning.

Jan 1, 1942

By I. G. L. Sinclair

"ABSTRACTTill geochemistry was the principal exploration tool employed by Selco in the investigation of a zinc prospect in Lanark Township, Ontario. The geochemical studies were undertaken after the discovery at surface of marble boulders containing bands of sphalerite and lesser amounts of galena.The source of these mineralized boulders was sought by means of B-horizon soil geochemistry, followed, where appropriate, by back-hoe trenching and till sampling. The thickness of the tiff in this part of Ontario seldom exceeds 3 m or 4 m and it was generally possible to sample complete profiles of the till and thus to obtain detailed information concerning the dispersion of zinc. Drilling and trenching at the up-ice extremity of the zinc dispersion trains showed the source of the float to be sub-economic bands of sphalerite in the Grenville marble. IntroductionTill geochemistry was used extensively by Selco during the period 1975 through 1980. It was the principal exploration technique employed in a program seeking carbonate-hosted lead-zinc deposits of the Balmat-Edwards type in the Grenville rocks of southeastern Ontario. This paper describes the use of the method to locate the bedrock source of a group of sphalerite boulders found at the surface near the village of Hopetown in Lanark Township (Fig. I) . Geochemical investigations at this locality were the subject of a previous publication by the author (Sinclair, 1979).All of the analytical work related to this project was done by Bondar-Clegg & Co. Ltd. in their Ottawa laboratory. In all cases the -80 mesh fraction of the till was analyzed. The total zinc content was determined by atomic ab sorption spectrometry after hot aqua regia digestion; readily extractable zinc was determined by atomic absorption after samples had been cold-leached for 18 hours in an ammonium citrate hydroxylamine hydrochloride solution, the pH of which was adjusted to 8.5"

Jan 1, 1986

By W. J. D. Stone

Discussions with people knowledgeable in the insulating material field revealed that materials on the market would be considerably improved if there was a greater meeting of certain very desirable criteria. Such criteria include: (1) the material should not burn, even at higher temperatures; (2) at an elevated temperature, the material should not give off toxic gases or produce smoke; (3) the material should have a low energy input; and (4) vermin would find the material unattractive. Theoretical discussions led to the conclusion that an insulating material made by foaming a mineral, preferably of a platy nature, with an inorganic binding system that could be converted to a rigid structure at low temperature would likely meet all the above requirements. It was also theorized that the use of microwaves in the converting stage would be beneficial in the creation of a cellular structure by aiding the foamer through creating vacules of steam. Talc was selected as readily meeting the theoretical mineral requirement and the material of Baker Talc Limited was used as the basic filler. The early results obtained led to an agreement between Americ Mines Limited and Baker Talc Limited pertaining to commercial production in a specific geographic area. It was recognized that due to the economics of shipping, the availability of the basic filler material should be geographically widely spread. Samples of materials were requested and many received from all over North America and one from Britain. Enough work has been done to show that they respond to the basic process in a similar manner as the Baker Talc material. From the data acquired, it is considered that the process is applicable for the production of loose fill insulation, moulded insulation for pipes and structural steel, ceiling tile, batts, sheet and for incorporation into other products such as various roofing board materials. Sufficient development has been done to enable a budget to be prepared for the construction and operation of a loose fill insulation plant.

Jan 1, 1979

By R. V. Kumar, C. Schwandt, S. Subramanian, S. Sampath, S. Vimalnath

Waste waters and industrial effluents containing toxic heavy metals such as Pb, Hg, As and Cr, beyond permissible limits (0.1 ppm, 0.01 ppm, 0.02 ppm and 0.05 ppm, respectively) (WHO, 2011), pose serious threats to the ecosystem, when discharged into the environment. It thus becomes imperative to monitor the concentration of the toxic heavy metals and treat them before discharging. In this study with the above objective in mind, a microbial sensor has been developed using P. aeruginosa cells drop coated onto a carbon paste electrode (CPE) for the detection of Pb(II) ions in aqueous solutions. Detailed biosorption experiments confirmed that complete bioremoval of lead could be achieved using P. aeruginosa cells under optimum conditions of pH and biomass loading. For the electro-analytical determination, the Pb(II) ions were initially preconcentrated on the P. aeruginosa modified CPE, reduced and then anodically detected with oxidation of Pb0 using differential pulse anodic stripping voltammetry (DPASV) technique. All the experiments were carried out in the presence of 0.1 M sodium acetate buffer and KNO3 as background electrolyte. The parameters namely pH, scan rate, biomass loading, deposition potential, deposition time and concentration of Pb(II) ions were optimized for the biomass modified CPE, to obtain maximum voltammetric response. Under the optimized conditions of pH 5.6, scan rate of 0.008 V/s, biomass content of 1.7–1.8×109 cells/mL, deposition potential of –1.2 V, and deposition time of 500 s, the developed microbial sensor showed a linear response for the peak current between 0.5×10-5 M and 1×10-8 M of Pb(II) ions with the R2 value of 0.9979. The lowest limit of detection (LLOD) was determined as 2.4×10-7M of Pb(II) ions (0.05 ppm). The redox mechanisms of Pb(II) ions on the P. aeruginosa modified CPE surface are discussed.

Jan 1, 2016

By M. Wittke

"In the course of the extension of the railway network in Israel, currently the two 4.6 km long tubes of the Gilon Tunnels on the line from Akko to Carmiel are being constructed. The tunnels run through the limestones of the Bina- and Yirka-formations, which locally are karstified. The maximum overburden amounts to 160 m.The limestones are mostly horizontally bedded and vertically jointed. Occasionally also inclined joints exist. The tunnels cross various fault zones, which mostly strike at an acute angle to the tunnel axis and are steeply inclined. The karstic cavities which were encountered during tunneling have partially been filled by clay. In the vicinity of the fault zones, the rock has often been strongly jointed and weathered respectively. The two single-track tubes have a cross section with vertical walls and an open invert. The tubes are connected by cross cuts with a spacing of approx. 250 m.During the tender phase, WBI has elaborated the tender design for a joint venture of a Chinese and an Israeli construction company. After the joint venture had been awarded the contract, the preliminary and the detailed design have been elaborated by WBI and the construction works have been guided. On the basis of the geological description, rock mechanical models have been elaborated, followed by stability analyses on the basis of the Finite Element method. The tunnels have been excavated according to the shotcrete method. The support in most areas only consisted of a very thin shotcrete lining and radial bolts in the area of the roof. Depending on the degree of jointing and weathering, locally advancing support by means of spiles has been applied.The internal lining of reinforced concrete has been constructed in parallel to the heading of the tubes. Mucking and delivery of materials was carried out through the cross cuts.The breakthrough was achieved in April 2014 and thus within schedule. The predicted distribution of the excavation and support classes along the tunnel has been in good agreement with reality."

Jan 1, 2015

By S. M. C. Santos

Preliminary bench-scale studies were carried out on the leaching of a zinc sulphide concentrate from Somincor, Portugal, and the purification of the resulting pregnant solution using solvent extraction techniques. The sulphide concentrate contained 36% Zn, 36% S, 2% Fe and 4% Cu. The leaching was carried out with sulphuric acid in the presence of ferric sulphate as the oxidant. Important leaching parameters, such as the effect of reaction time, the solid-liquid ratio, temperature and concentrations of acid and oxidant, were investigated. After leaching, the recovered solution was contacted with an organic phase containing Acorga 5640 to remove the copper. Subsequently, the removal of iron from the leaching solution was achieved with a mixture of Cyanex 272 and TBP. This solvent mixture was relatively selective for iron over zinc. The stripping of the loaded solvent was performed with 200 g/L H2SO4. Six countercurrent extraction stages achieved a separation of about 99% of the iron from the leaching solution. The iron-free leachate can be further treated to recover minor metals by cementation, and finally, zinc by liquid-liquid extraction. The advantages of the suggested process relative to the traditional jarosite process are discussed.

Jan 1, 2006