Search Documents

By N. E. Nelson

"The Hidden Creek mine is about l~ miles north of the north end of Granby bay; a nearly landlocked body of water on the west side of Observatory inlet; 90 miles north of Prince Rupert; British Columbia.The main haulage way of the mine at 385 feet above sea-level has been driven north into the somewhat precipitous end of a north-south ridge that rises from the tide flats between the east and west forks of Hidden creek. The outcrops of the principal orebodies, two prominent bluffs of stained rocks and sulphides, were higher on the face of the ridge and extended from about 530 to 850 feet elevation. North from the bluff tops, the ridge comb rose gradually to about 1,200 feet elevation. The name of the discoverer and the date of discovery of the Hidden Creek orebodies are probably unknown, but the discoverer is believed to have been an Indian from one of the reservations along Observatory inlet. The deposit was brought to the attention of John Flewin, Government Agent at Post Simpson, near the beginning of the present century. Mr. M. K. Rodgers, developer of the Nickel Plate mine at Hedley, did the first organized work on the deposits. Next the Hidden Creek Copper Company prospected the property. Rodgers acquired the prospect a second time, did more work, and finally in 1910 optioned the property to the Granby Consolidated Mining, Smelting and Power Company, Limited, at that time operating at Phoenix and Grand Forks in the Boundary district of British Columbia. The optionees stepped up the development work and brought the property to production in 1914. The ores were direct smelted until 1924. In that year a mill was built. From 1930 until the end of the productive life of the properties in 1935, all of the ore was milled and the concentrate smelted. From March 17, 1914, until July 31, 1935, the production from the Hidden Creek mine was, in round numbers, 18,000,000 tons of 1.70 per cent copper ore and 6,000,000 tons of low grade dilution rock. The Hidden Creek mine ""died with its boots on"". During 1934 the average monthly production was 146,377 tons of 1.06 per cent copper ore. For 7 months of 1935 the average was 161,750 tons of 1.03 per cent ore, and for the final month, July 1935, the production was 156,950 tons."

Jan 1, 1954

By D. R. Pyke, R. S. Middleton

"Three main types of base metal sulphide mineralization are present in the Timmins area:(1) -Massive and stringer-type copper-zinc deposits occurring mainly in pyroclastic rocks, as typified by the mines of Kam-Kotia, Jameland and Canadian Jamieson, or within or close to possible breccia pipes as shown by the Genex and Kidd Creek mines. With the exception of the Kidd Creek mine, all of these orebodies occur northwest of Timmins (Kamiskotia area) and appear to lie within or close to a major center of volcanic activity characterized by a thick accumulation of felsic pyroclastic rocks and subordinate epizonal intrusions. The margins of the rhyolitic pile are interfingered with mafic volcanics; overlying sedi-ments mark the termination of a vol-canic cycle. The copper-zinc deposits in the Kamiskotia area are confined to a particular stratigraphic unit. Ore-bearing solutions were probably derived from the intrusive complex of the volcanic pile.(2) -Porphyry copper deposit of the Mcintyre mine. The deposit occurs in a quarz porphyry intrusion related to the volcanism in the area (Hurst, 1936). Mineralization was probably introduced at the time of intrusion, and subsequently redistributed within the porphyry during deformation. (3) -Massive and disseminated nickel mineralization, associated with serpentinized alpine-type ultramafic intrusions, as shown by the Alexo, McWatters, Hart, Inco and Texmont deposits. The nickel mineralization occurs at or near contacts of the serpentinites with felsic or mafic volcanics, or sulphide-bearing iron formations. The nickel deposits south of Timmins are confined to a particular stratigraphic unit along the margins of domical-shaped structures which appear to outline former volcanic centers. Sulphurization as pro-posed by Naldrett (1966) appears to be a workable hypothesis for the formation of some of the deposits."

Jan 1, 1971

By H. W. Kasaini, E. Bourricaudy, T. Larochelle

Rare Element Resources Inc., a U.S. based company, has developed a three-stage process for producing a +98% mixed REO powder from hard rock feedstock (-48 mesh, 2.9-4.8% REO) consisting of bastnaesite and ancylite minerals. Firstly, the whole ore is digested in chloride media at low temperature in counter-current flow mode. Secondly, the rare earths (REEs) are selectively precipitated as oxalates directly from an impure pregnant leach solution (PLS). Finally, significant amounts of free acid and water are recovered from the REE-depleted filtrate and subsequently recycled within the process. Excess heat from the oxalate calcination process is captured and reused in the plant. Due to the low leach temperature (45 ºC) and moderate acid dosage (240-297 kg/t, HCl), rare earth oxides (REOs) are preferentially leached out of fine solids leaving most of the base metals (Ba, Fe, and Al ) in the residue. Selective recovery of REEs from the PLS is achieved by mixing dilute oxalic acid (33% H2C2O4) and PLS at elevated temperature (85-95 ºC). The REEs plus thorium are precipitated as oxalates (REE2 (C2O4).xH2O) while the base metals are left behind in the barren filtrate. Multiple batch and pilot test results have confirmed that 50-80% of the oxalic acid can be recovered from the REE-depleted PLS through low-temperature crystallization (10-15 ºC). Typical leach efficiencies of critical rare earths at 45 ºC range from 85-99% (average 93%) while oxalate precipitation at high temperature increases the crystal size of RE oxalates (>450 microns, d80) thereby improving filtration. The economic benefits of this process include elimination of flotation and magnetic separation Capex and driving hydrometallurgical Opex down to $6- 7/kg, REO produced. As part of a comprehensive risk mitigation strategy, Rare Element Resources Inc has operated multiple pilot plants at SGS in Lakefield, Ontario, Canada to optimize counter-current leaching (CCL), REE oxalate precipitation (OXP), and thorium removal circuits. This paper presents pilot testing data from CCL and REE OXP circuits.

Jan 1, 2016

By M. F. Goudge

This paper is intended to call attention to the manifold uses of limestone in industry; to indicate the types of limestone desired by some of the large consuming industries; and to give some information on the resources of limestone in Canada, so that an idea may be obtained of the present and future possibilities for limestone production. The word limestone is used in the usual broad sense to include both high-calcium limestone and the highly magnesian variety known as dolomite, as well as all intermediate types. Lime is simply calcined limestone, and in this general paper its uses have been included with those of raw limestone. It is of interest, in dealing with this subject, to glance back over the early history of the utilization of limestone, for by so doing we see that limestone has been of importance to mankind since the beginning of civilization and has contributed in no small measure to the development of a number of the arts and sciences. One of the first uses, if not the first use, of limestone was in connection with the making of lime for plastering purposes. This use antedates civilization. In the day of the ancient Greeks and Romans, the art of plastering had been brought to a state of perfection that is not nearly approached by the modern artisan.

Jan 1, 1930

"The Cooperative Research Centre for Mining Technology and Equipment (CMTE) is funded by the Commonwealth Government, by its mining research members — the Universities of Queensland and Sydney and the CSIRO1, and by its industry members — BHP Coal, RioTinto R&TD, Hamersley Iron, Mining Technologies Australia, Pasminco, Shell Coal, WMC Resources, Advanced Mining Technologies, and Aberfoyle. The Centre conducts work aimed at improving the competitiveness of the Australian mining industry. The current work is focused in four areas: new mining and drilling systems, geological sensing, automation, and equipment maintenance and reliability. This paper describes much of the work in these program areas that relates to metalliferous mining. Mechanized Rock ExcavationThe disadvantages of the drill-and-blast excavation method are widely recognized and the last half of the 20th century has seen mining companies and mining research organizations aggressively pursue technology to excavate rock by other means. As discussed below, despite considerable effort and large amounts of funding, the quest for mining’s “Holy Grail” has been unsuccessful in all but the weakest rock types.COMRO (the Chamber of Mines Research Organisation) supported by the South African gold mining industry, spent three decades and (probably) tens of millions of dollars developing prototype drag bits and, later, impact breaking machines aimed at the mechanized stoping of narrow, tabular reefs. This work has not yet produced a commercially-attractive mining system. Work continues in South Africa to mechanize these stoping operations although now the emphasis is on the use of diamond-wire sawing techniques. This work remains in the experimental phase.Both British Coal and Germany’s Bergbau- Forschung spent many years developing techniques trying to extend the range of rock types which roadheaders could cut economically. Again, although new knowledge was produced, it is difficult to claim that any new commercial mining systems emerged from this work."

Jan 1, 2001

By Alfred E. Pugsley

PAYMASTER CONSOLIDATED MINES, LIMITED, began an investigation into the economy and use of detachable bit drill-steel in June, 1937. This investigation has continued to the present time, and was made necessary by transportation and distribution difficulties that had arisen through the use of standard steel in three widely separated mine areas serviced by a central steel-sharpening shop. Detachable bit drill-steel performance was first studied in the workings of No. 2 mine, where the rock being drilled was composed mainly of porphyry or tourmaline, and where standard drill-steel transportation costs had been excessive. The results obtained in this early work definitely established the economy of detachable bit drill-steel at No. 2 mine. This conclusion was reached when the 're-grind' system of re-sharpening dulled detachable bits was 1n use. Preliminary observations on the performance of detachable bit drill-steel in the quartz-carbonate veins of No. S and No. 6 mines gave encouraging results, and warranted a large-scale investigation under practical mining conditions. All drilling operations were gradually changed over to use of detachable bit drill-steel. This change was completed by February, 1938.

Jan 1, 1939

By Richard A. McIvor

"All mine shaft conveyances in Canada and most of the United States that are supported by a single hoist rope or attachment point and used for transporting persons are required by regulation to be equipped with safety catches and mechanisms. These safety mechanisms, commonly called safety dogs, are designed to stop and hold a free falling conveyance, with a full personnel load, in the event of a hoist rope or attachment component failure. The conveyance’s safety mechanism must be tested under dynamic conditions before it is used to transport personnel. This paper will discuss free-fall testing and it’s results on conveyance free-fall tests performed in the test tower at INCO Limited, Sudbury, Ontario.Topics covered will be free-fall tests on various wood types such as B.C. fir, Karri wood and Trusjoist MacMillan Limited Parallamwood (PSL), comparison of deceleration rates versus free-fall velocity and the influence of safety dog tooth design on deceleration rates."

Jan 1, 1996

By Forrest A. Kerr

Northern British Columbia is a term which probably conveys to various individuals quite different meanings. To the average person it signifies an area of indefinite size and indefinite position which may start at Prince Rupert, Stewart, or somewhere else, and end at Alaska or .the Yukon. Many people, in their conception, fail to encompass in their mind's eye that vast tract of land lying ~o the east of the panhandle of Alaska. Few realize that the area north of an east-west line through Stewart represents more than one-third of the Province and is, of course, the part most appropriately designated as northern British Columbia. This section, more especially the northernmost 100,000 square miles, from political, geographic, and economic viewpoints stands isolated perhaps more than any other part of British Columbia. Unlike the rest of the Province, it has no coast line, being cut off from the Pacific ocean by a narrow strip of Alaska. It is bounded on the north by the Yukon, and on the east by Alberta. In the south this northernmost 100,000 square miles is limited by a divide of rugged mountainous country separating the drainage basins of the Stikine and Liard rivers from those to the south.

Jan 1, 1929

By V. Aprahamian, G. B. Harris, C. W. White, M. Tangen

"In 2005, the Royal Canadian Mint (RCM) commissioned a new silver electrorefining circuit. This circuit was intended to operate with a minimal electrolyte bleed for the control of copper. However, by the time of start-up, the levels of copper-rich silver doré to electrorefining had increased, and despite partial pyro-conversion in a small Top Blown Rotary Converter (TBRC), copper concentration in the silver anode still averaged 7.5%. This necessitated frequent replenishment of the electrolyte with fresh silver nitrate since copper displaced dissolved silver during electrolysis, and therefore requiring a robust copper bleed treatment step in order to maintain cathode silver flake purity at 99.99%. The originally-installed bleed treatment system could not meet the RCM’s needs. A thorough review of known technologies, however, did not indicate one capable of handling the copper load, and resulted, therefore, in the development of a novel copper hydrolysis approach for removal of copper as an insoluble basic nitrate salt, and recovery of the associated nitric acid for re-use in the circuit. Laboratory-scale trials showed reproducible results, and existing equipment was subsequently modified.INTRODUCTIONIn 2005, the introduction of a new silver electrorefining circuit at the Royal Canadian Mint (RCM) initiated changes in the way customer silver, collected from the gold doré circuit, was processed. These circuit changes were discussed in a recent paper (Aprahamian, 2015). A wastewater treatment plant had not been budgeted at the time, and this represented a significant constraint when considering the introduction of a wet processing circuit. After a review of various options, a turnkey silver electrorefining circuit was purchased from a European firm. Initially, enough cells were ordered to produce 2 million oz of fine silver (999), with the option to increase to 5 million oz. The selected equipment was based on a Moebius cell design combined with a silver grain pressure dissolver to produce make-up silver nitrate solution. Additionally, an evaporator/hydrolysis unit included in the package appealed to the Mint Refinery, on the basis that it offered a simple way to bleed dissolved copper in electrolyte without generating effluent."

Jan 1, 2016

By C. Edwards

"The processes for rare earth (RE) extraction include the decomposition of RE ore concentrate minerals, and the concurrent or subsequent leaching of the rare earth elements (REEs) from the decomposed minerals. Ore beneficiation concentrate can be decomposed by, for example, acid roasting, caustic cracking, and chlorination. The REEs can be selectively extracted. The nature of the REE extraction process depends on the concentrate mineralogy and the targeted products. Based on the experience of the Saskatchewan Research Council (SRC) in RE processing, this paper reviews REE extraction from the major RE minerals, including bastnaesite, monazite, xenotime, ion-adsorption clay, allanite, cerite, and eudialyte. An update on the development of RE extraction processes is also provided.INTRODUCTIONRE processing usually involves two operation stages, physical processing and chemical processing. Physical processing, also known as ore beneficiation, separates the RE minerals from gangue minerals to produce an RE mineral concentrate. Chemical processing, which includes extraction and separation processes, converts the RE mineral concentrate to an RE compound which is either an end product or an intermediate product for the subsequent production of individual REEs or other compounds. The RE extraction process uses one or more reagents to decompose the RE minerals and to leach the REEs into solution. The RE separation process uses solvent extraction, ion-exchange, or chemical precipitation to produce either rare earth oxides (REOs) or individual REEs. The authors have previously reviewed RE ore beneficiation processes (Zhang & Edwards, 2012). This paper focuses on extraction processes for a variety of RE minerals. Table 1 gives the chemical compositions of the RE minerals mentioned in this paper. The varieties of RE extraction methods use many different reagents. These reagents are mainly inorganic acids, alkalis, salts, and chlorine gas. The commonly used acids include sulfuric acid (H2SO4), hydrochloric acid (HCl), and nitric acid (HNO3). Sodium hydroxide (NaOH) and sodium carbonate (Na2CO3) are the most common alkalis. Salts include ammonium sulphate ((NH4)2SO4), ammonium chloride (NH4Cl), and sodium chloride (NaCl). HCl is normally used to extract RE from silicate ore minerals such as allanite and gadolinite. The alkalis and H2SO4 are mainly used to leach REs from phosphate ores minerals like monazite and xenotime. The carbonate ore RE minerals such as bastnaesite can be treated using either acids or alkalis. HNO3 is mainly used to leach eudialyte and apatite. The extraction of REs from ionadsorption clay deposits uses salt solutions. Chlorine gas (Cl2) is exclusively used in the RE chlorination process which can be used to treat any RE minerals."

Jan 1, 2012

By X. Cao, J. J. Jonas, Wanjara. P., J. Gholipour, E. Dalgaard

The linear friction welding (LFW) behaviour of near-ß titanium alloy Ti-5Al-5V-5Mo-3Cr (Ti- 5553) was investigated. Microhardness measurements were performed in order to evaluate the mechanical properties of the welded material. The linear friction welded (LFWed) Ti-5553 was examined with optical microscopy and scanning electron microscopy (SEM) to evaluate the microstructure’s response to the thermomechanical conditions. Characterization of the welds included analysis of the microstructural features of the weld region and thermomechanically affected zone (TMAZ) in relation to the parent material.

Jan 1, 2010

By Maurice Lauzon

"Aerial surveys of the open pits have been conducted regularly at Lake Asbestos of Quebec, Ltd. -a subsidiary of American Smelting and Re-fining Company -since 1958. Ground controls are supplied by Lake Asbestos, and a topographic map of the pits at a scale of 1 in. to 50 ft., with 2-foot contour intervals, is obtained by aerial photography. The information from the topographic map is then transferred by the Lake Asbestos engineering staff to sections from which the volumes removed are calculated. Considering the size and complexity of the operation, this system has proved to be the cheapest, fastest and most accurate way of determining the quantities of rock and overburden removed. More than 11,000,000 tons of ore and waste are mined each year in three different pits. Further-more, the nature, shape and extent of the orebodies make it necessary to mine on many (up to eight) benches of a pit during a single year. In addition, there are sections of the pits where it is impossible or un-safe to survey the crest of some benches by standard ground methods. For these reasons, the tonnages obtained by truck count are checked and adjusted by aerial survey. These surveys are now taking place every six months. With this system, it is possible for a two-man surveying crew to look after all field work in the mine area."

Jan 1, 1967

By A. Becker, C. Gauvreau, L. S. Collett

"A scale model was designed to simulate the airborne Barringer INPUT time domain electromagnetic system. The amplitude of the response to a vertical conductive dyke varies considerably with the conductor's thickness conductivity product (TCP). The response increases from a minimum detectable level at a TCP of about 2 mhos, rises to its maximum value at a dyke TCP of 15 mhos and then falls again so that conductors with a TCP exceeding 500 mhos would probably remain undetected. Measurements made with both standard receiver coil configurations (maximum or minimum coupled) indicate comparable effectiveness for both systems, either from the viewpoint of vertical conductor detection or from the viewpoint of discrimination against overburden anomalies."

Jan 1, 1972

By R. Viljoen, K. Manns

"The mining industry instinctively follows rule-of-thumb design velocities often based on very simplistic theoretical “economic velocity” optimization calculations to determine airway sizes. Although these are important building blocks in ventilation planning it should be recognized that mines are far more complex and various, often opposing factors, are at play. Therefore, it is important that each ventilation situation be analyzed on a case-by-case basis to determine the best-fit solution for an operation. The ventilation design process should not necessarily be constrained by theoretical optimal economic velocities that become rules-of-thumb. In some cases, this could lead to unrealistic infrastructure requirements and exorbitant capital expenditure. This type of design often lacks corporate support leading to a scenario where no ventilation upgrades are implemented. Economic velocities typically consider the cost of power, development costs and operational risk. These typical rules-of-thumb work reasonably well as a starting off point when considering feasibility of greenfield projects. For established mines that are looking at expansion these rules may not be appropriate due to capital expenditure constraints or geotechnical ground conditions. The theoretical optimum should be reviewed in the case of an established mine where existing infrastructure could perhaps be maximized. For example, the geotechnical risk of large diameter raises at depth may require multiple small diameter raise to maintain the theoretical economic velocity. If a mine has a life of less than 5 years, then the cost of power is an insignificant proportion of the total owning cost. For these mines, operating the ventilation raises at an increased velocity to avoid a complicated and expensive capital upgrade might be the more appropriate option, even though it opposes the traditional rules-of-thumb. Mines which are capital constrained may be better off accepting a higher operating cost for the interim or settle for minor infrastructure upgrades rather than run the risk of the entire ventilation upgrade not being approved at all. This paper explores a number of examples derived from case studies undertaken by the authors for several deep mechanized mining projects in Australasia. The examples explore conditions under which higher than the economic norm would be applicable."

Jan 1, 2019

By W. G. Miller, J. D. Scott, D. C. Sego

ABSTRACT The influence of using different extraction processes (caustic versus non-caustic) on thethixotropic strength of oil sands fine tailings is examined, as is the influence of adding a coagulant tocaustic fine tailings. The thixotropic strength of fine tailings at large void ratios manifests itself as a bonding or gel strength that has been widely noted both in the laboratory and in the field. This gel strength has a significant influence on preventing the initial consolidation or settlement of fine tailings. Differences between the fine tailings’ thixotropic strength development are explained based on their physical and chemical characteristics.

Jan 1, 2010

By L. Haavanlammi

Iron is a significant component of all copper concentrates leached in the HydroCopperTM process. The metals in the concentrate are leached in a chloride solution by oxidation with cupric ions. Copper enters into the solution as a cuprous chloro¬complex. Iron dissolves at the same time in the ferrous form, but it is immediately oxidized to the ferric state. Oxidation is effected by sparging air or oxygen into the leaching reactors. Because the pH is 1 - 2.5, ferric ion precipitates as akaganeite (T<90°C) or hematite (T> 90°C). Arsenic, antimony and the main part of the bismuth co-precipitate with iron and report to the leach residue. Cupric leaching is faster than iron oxidation; thus, leaching of low-iron concentrates (secondary copper minerals) is quicker than leaching high iron concentrates (chalcopyrite). Pyrite does not dissolve during copper leaching, but is oxidized slowly at higher redox-potentials after the copper has been leached.

Jan 1, 2006

The Mineral Industry of Canada in 1951 Continuance of the remarkable, successive increases in the value -of Canada&apos;s mineral production, chief basis of the nation&apos;s post-war expansion, was one of the highlights of Canadian development in 1951, when, according to the preliminary estimate is-sued by the Dominion Bureau of Statistics and reported in the BULLETIN for February, 1952, mineral output for the year reached a new high of $1,228 millions. This marked an increase of 17.5 percent over the previous year, which was the first in which the billion dollar mark had been reached, and an increase of 143.7 per cent over 1946, when production was valued at approximately $503 millions. While higher prices for the principal base metals accounted for a large part of the 1951 increase, quantity gains were made by copper, nickel, zinc, asbestos. lead, cement, and strikingly important. by petroleum, the value of which exceeded for the first time that of coal production. Gold was an exception to the general trend, being lower in both quantity and value than in 1950. For the first time nickel .came within $9 millions of surpassing-gold as the leading mineral product. Metals and Fuels The value of all metals, estimated at $733 millions, was 18.7 per cent more than in the previous year. Nickel advanced 11 per cent in volume and 34 per cent in value. Copper was up 2.4 per cent in quantity and 21 per cent in value, zinc rose 6.6 per cent in quantity and 35 per cent in value, and although the volume of lead produced was lower by 8 per cent, its value increased by 17 per cent. The tonnage of iron ore was 31 per cent higher than in 1950.

Jan 1, 1952

By A. E. M. Warner, I. E. Hills, C. L. Harris

Since the late Dr. Keith Brimacombe, et al, performed tests at the now-closed Asarco Tacoma smelter and the Inco Copper Cliff Smelter on Peirce-Smith copper converters almost thirty years ago, many Pyro-metallurgists have investigated using the technology. To the best of the authors knowledge, except for shrouded tuyere technologies using substantial oxygen enrichments, the core idea of using high pressure air injection has not been implemented anywhere in the world. This paper reviews the fundamentals of this technology and summarizes the basic economic considerations. It also presents the circumstances of where and when high-pressure injection might be justified.

Jan 1, 2007

By Lachezar Tsotsorkov

Being a mining company, Assarel-Medet has a significant impact upon the environmental components. In order to meet the legal requirements and the requirements stipulated by the effective permits as well as to reduce the environmental imprint throughout the years, the policy of the company to implement a number of projects to improve the environmental components quality and the environmental state in the company?s region. The projects associated with atmospheric air quality management and reduction of the impact exercised by Assarel-Medet JSC by implementing various measures to eliminate the potential sources of the impact, preventive and rehabilitation initiatives as well as organizational and administrative activities are among the most important ones. A stable improvement of atmospheric air quality in the region and minimization of the company impact upon the ground air state in the region was observed in the period from 2005 to 2012 due to the applied measures. This project is a contribution to the environmental protection, in particular to atmospheric air protection, by applying integral monitoring and modeling methods to identify the negative impact by the mining companies and plan measures to reduce and restrict it as well as to improve the quality of the environment and living area of people working and living in the impact range as an element of sustainable development.

Aug 1, 2013

By M. Melashvili

"The SART Process was introduced to the gold mining industry in the late 1990s and several commercial plants were built over the following 10 to 15 years. Most of these plants have operated well and enjoyed plant performance in line with expectations based on the underlying chemistry of the process. However, two of the plants have consistently suffered from high reagent consumption and poor product quality, which has motivated a re-examination of the process fundamentals.The primary product in the SART Process is synthetic chalcocite, Cu2S, and the stoichiometric requirement for sulphide addition is therefore 0.5 moles per mole of copper in solution. It is shown here that when sulphide is added in excess of this amount (generally with the express purpose of lowering residual copper in solution) it not only fails in its intended purpose, but can have a negative impact on the settling and filtration characteristics of the copper sulphide product, as well as the final product quality. Moreover, these problems are exacerbated the higher the selected operating pH in the pH 3 to 5 range, and the longer the residence time of slurry in this pH range.Freshly precipitated copper sulphide compounds are known to be very fine and slimy, with poor settling and filtration characteristics. It is therefore important to engineer the SART Process in such a way as to encourage growth in the average particle size of the precipitate crystals. This was the rationale for recycling a portion of the thickener underflow to the primary reactor when the SART Process was developed. However, the theory of crystallization predicts that compounds of extremely low solubility, such as chalcocite (Cu2S: KSP = 10-48), are unlikely to experience growth in crystal particle size through heterogeneous nucleation and are more likely to grow through aggregation. On this basis, the SART practice of recycling a portion of thickener underflow to the primary reactor in the commercial plants is unlikely to lead to crystal growth via nucleation, and could in fact promote breakage of the aggregates that formed in the thickener. Recycling thickener underflow could therefore have the opposite of the desired outcome. The result of testwork that is reported here lends credence to this theory and questions the wisdom of recycling in the SART process."

Jan 1, 2016