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By Karl J. C. Harries

"6.1. INTRODUCTIONThis chapter comments on some of the more common types of agreements related to property examination and acquisition, other than the farm-in/joint venture agreement or common undertaking, which is dealt with in the next two chapters. Many of the comments made in Part IV of Chapter 4 apply equally to any such agreement. In addition, many of the comments in Chapter 8 and the examples in Volume II are most certainly relevant to many other types of agreement.6.2. RIGHTS OF FIRST REFUSAL1A right of first refusal is a right that obligates an owner to offer his property, or an interest therein, to the holder of the first right if the owner intends to sell or otherwise dispose of it. It may be triggered either by the owner wishing to offer his property for sale or by receipt of a bona fide offer to purchase his interest from an “outside” third party. The mechanics and procedures to implement a first right should be set out clearly in the agreement, and their basics are the same, whether the first right is a stand-alone document or is part of an acquisition agreement.2Rights of first refusal are common in agreements to permit some control over the disposition of an interest and there they can be a valuable provision. However, some explorationists feel that they are also a good stand-alone agreement to have while a property is being evaluated to decide whether or not it is worth optioning. The reasoning is that such an arrangement will tie up the property to allow a quick look and, if the property looks interesting, the balance of the term of the first right will give an ample exclusive period of time to negotiate with the owner and settle an acquisition agreement. In addition, the explorationist is protected by the first right if the owner decides to negotiate a deal with another party."

Jan 1, 2003

By Mauro Torres, Gabriel Zarate

"AngloAmerican used the extractant M5640 at Mantos Blancos and Mantoverde and uses PT5050MD at Los Bronces Division, which are aldoxime and modifier blends. In the first case, the modifier is the esther TXIB, while in the second case is the tridecanol TDA. It is a well-known fact that the extractant degrades while the modifier does not and with time the oxime/modifier ratio can change significantly, depending on the operating conditions of each plant.In order to evaluate the effect of this varying modifier content in the plant organic, especially in the organic losses, a complete metallurgical test work program was conducted at laboratory and pilot plant scale by Flomin SNF, a new extractant supplier. Results showed that the addition of an aldoxime without the modifier did not affect the chemical performance of the extractant, but there was a significant decrease in the viscosity and density of the organic.Based on the results obtained in the metallurgical program, it was decided to run plant scale tests at the SX plants of Mantos Blancos and Mantoverde. In these tests, instead of adding extractant to maintain the organic inventory, CuPROMEX 3406 which is an unmodified aldoxime was added until the original oxime/modifier ratio was reached. This was obtained after 6 months of operation and since then both plants are running with the extractant CuPROMEX 3302 both supplied by Flomin SNF.In the case of Los Bronces, the pilot plant work was completed and it is programmed to run similar plant scale tests. In this case, the oxime/modifier ratio increased and TDA will be added until reaching the original ratio.The plant results obtained at Mantoverde and Mantos Blancos, together with the pilot plant test results obtained at Los Bronces, are discussed in this paper."

Jan 1, 2016

By John C. Robbins

A new technique for the determination of trace levels of uranium in solution has been developed. A compact laser emits short, but intense, ultraviolet pulses to excite the green fluorescence of a uranyl-complex formed by the addition of a proprietary reagent to the sample. Organic species present in most natural waters also fluoresce quite intensely, but their emission does not last appreciably longer than the excitation pulse, in contrast to the relatively long persistence of the uranyl fluorescence . Electronic 'gating' is employed to separate the long-lived contribution, rejecting substantially the organic emission. Results using the laser fluorescence method on many sets of natural waters of various origins have been compared against corresponding values generated by independent laboratories. Correlation has been generally good over a range from less than 0.1 to more than 100 ppb U. Solid samples have also been analyzed after extraction of the uranium into solution. Accuracies adequate for most exploration purposes have been achieved, but further work is required to determine effects of interferences in samples with complex matrices. The transport and deposition of uranium in natural waters is controlled by the organic and inorganic chemistry of the waters involved. It is suggested that interpretation of very low uranium levels will be aided by additional measurements of conductivity and organic content, with subsequent statistical treatment.

Jan 1, 1978

By L. Kilburn

A survey of 281 mineral exploration agreements examines the ratios among three ways that may be used to purchase an interest in a mineral property, viz: pay cash, pay shams and make future expenditures on the property. The dollar value of the future expenditures exceeds that of cash or shams by about nine times in most of the 110 agreements that contain cash-expenditure or share-expenditure components. Results suggest that cash and shams are treated about the same in terms of value. Buyers and sellers haw opposing priorities for the way that they prefer to purchase a mineral property. These opposing priorities should give rise to a perceived 50:50 balance between cash/share payment and future expenditures to satisfy the idealized situation described by most definitions of fair market value (FMV). This balance between cash/share payments and future expenditures appears to be rationalized in negotiations to a FMV when expenditures are nine times greater than cash and/or payments. On this basis, it is proposed that the FMV of a property may be determined by aggregating the dollar amount of the cash/share payments plus one-ninth the dollar value of future expenditures, as set forth in the respective purchase agreement, and proportionately applying such aggregate to full property value.

Nov 1, 2005

By D. McConchie

BauxsolTM, prepared by treating bauxite refinery residues with Mg2+ and Ca2+, has an excellent ability to remove arsenic from acidic waters. The addition of BauxsolTM to sulphidic waste rock at the Gilt Edge Mine, South Dakota, reduced As concentrations in leachate water from 35 mg/L to < 0.005 mg/L; the concentrations have remained below 0.005 mg/L for the five years since the treatment was initiated. However, ordinary BauxsolTM does not effectively remove As from near-neutral water and it needs to be acid-treated or blended with small amounts of reagents, such as jarosite or ferrous sulphate, to increase the proportion of positively charged binding sites on the particles. The use of a jarosite/BauxsolTM blend can effectively treat ponded water, and As(V) concentrations can easily be reduced from over 1 mg/L to < 0.001 mg/L; As(III) has to be oxidised to As(V) for effective removal. Metal contaminants in the jarosite are trapped by the BauxsolTM and only very small amounts of the As, or other elements bound during treatment, are liberated using a TCLP leaching test. The exhausted treatment reagents meet the criteria for classification as an inert solid and do not need to be disposed of in a secure repository.

Jan 1, 2006

By E. J. Marcotte

"INTRODUCTIONThe Upper Canada Mine is located at Dobie, approximately ten miles east of Kirkland Lake, Ontario.The mill contains Upper Canada's cyanide circuit and Upper Beaver's flotation circuit. The combined capacity is 590 tons per day consisting of 415 t.p.d. of Upper Canada gold ore and 175 t.p.d. of Upper Beaver copper-gold ore.The Upper Beaver ore is trucked five miles to the Upper Canada mine site.Crushing:The crushing circuit consists of primary, secondary and tertiary crushing employing one C .A. C. 15 in. x 24 in. Superior jaw crusher, one 4 ft. x 8 ft. Tyler-Niagara double deck screen, one 3 ft. Symons standard cone crusher and one 3 ft. Symons shorthead cone crusher.The -2 in. product from the jaw crusher is fed to the double deck screen. The+ 5/ 8 in. passes over the top deck to the 3 ft. standard cone crusher; the+ 3/ 16 in. material passes over the lower deck to the shorthead cone crusher. The - 3 / 16 in. material pas sing through the lower deck of screens is the product to the mill.The screens used prior to the installation of rubber screen cloths were: one 4 ft. x 4 ft. section with 3/ 4 in. square openings and one 4 ft. x 4 ft. section with 5/ 8 in. square openings on the top deck; two 4 ft. x 4 ft. sections with openings of 3/16 in. x 4 1/2 in. slot on the lower deck. The fine screens were positioned so that the 4 1/ 2 in. slots were parallel to the flow of feed.The crushing circuit is operated on a three shift per day basis by one operator per shift."

Jan 1, 1968

By X. G. Zhao, M. Cai, L. K. Ma, P. F. Li

"Crack initiation stress is one of the characteristic stress thresholds in the rock deformation process under compression. By analyzing AE responses of brittle rocks in uniaxial compression, a new method which is called cumulative AE hit (CAEH) method is proposed for determining the crack initiation stress. An advantage of the CAEH method is that the method removes the user's subjective judgment. To verify the CAEH method, uniaxial compression tests with AE measurement using 77 crystalline rock specimens were conducted. The test specimens cover eight rock classes with different mineral grain distributions. Crack initiation stresses of these specimens were determined by the proposed CAEH method and the LSR method, and the resulting mean crack initiation stresses determined using the two methods were comparable. In addition, taking one rock class with 20 specimens for example, the mean crack initiation stresses determined using the CAEH method and those from several established strain-based and AE-based methods were similar. Hence, the CAEH method can be used as an alternative method for crack initiation stress determination.INTRODUCTIONExperimental observations indicate that the failure process of brittle rocks is associated with crack initiation, crack propagation, crack damage and final strain localization (Brace et al., 1966; Bieniawski, 1967; Lockner, 1993; Wawersik & Fairhurst, 1970). Compression tests on cylindrical specimen are often used to characterize the crack development process. The crack initiation stress (sci), crack damage stress (scd), and peak stress (sc) represent important stress thresholds during the failure process of brittle rocks. Among the three characteristic stress magnitudes, sci is difficult to be determined objectively, directly from examining the stress–strain curves. Some researchers argued that sci obtained from laboratory compression tests is an important parameter for estimating the spalling failure observed in brittle rocks around underground excavations (Andersson et al., 2009; Diederichs, 2007; Martin, 1997). sci can also be used to estimate rock tensile strength and Hoek-Brown failure criterion parameter mi (Cai, 2010). Over the last 40 years, various strain-based methods have been proposed to determine the crack initiation stress in compression tests (Brace et al., 1966; Diederichs, 2007; Eberhardt et al., 1998; Lajtai, 1974; Martin & Chandler, 1994; Stacey, 1981). Nicksiar and Martin (2012) proposed a Lateral Strain Response (LSR) method for establishing sci for low-porosity rocks. Meanwhile, they also used different strain-based methods to evaluate sci of Äspö diorite, and the results showed that all strain-based methods gave acceptable crack initiation stress values. Subsequently, they utilized the LSR method to further investigate the crack initiation stresses in igneous, metamorphic, and sedimentary rocks in compression tests (Nicksiar & Martin, 2013). Compared with previously proposed strain-based methods, an advantage of the LSR method is that it removes the user judgment when interpreting sci. However, the use of the LSR method relies on accurate determination of scd and on having a polynomial fitting equation to find the maximum LSR value."

Jan 1, 2015

By D. Haraguchi, S. Izawa, C. Tokoro, S. Owada

"Arsenic is widely known as a toxic element for humans, animals and plants. Because of more stringent wastewater standards not only in Japan but also around the world, research for appropriate and efficient treatment method for arsenic is becoming increasingly important. Coprecipitation or adsorption process using ferrihydrite is widely implemented for dilute As(V) removal from wastewater. In this study, the sorption mechanism of dilute As(V) with ferrihydrite in coprecipitation or adsorption process was investigated. To accomplish this, we conducted batch experiments of coprecipitation or adsorption and compared these results for sorption isotherm and zeta potential. These experimental results showed that sorption mechanism in coprecipitation process depends on the initial As/Fe molar ratio; simple twodimensional adsorption onto the surface of ferrihydrite when the initial As/Fe molar ratio was < 0.4, and some three-dimensional uptake with ferrihydrite when it was = 0.4. We also evaluated the sorption mechanim by analysis of X-ray diffraction (XRD) and X-ray Absorption Fine Structure (XAFS). XRD or XAFS spectra showed that surface precipitation of amorphous ferric arsenate was formed when the initial as/Fe molar ratio was = 0.4, beyond the thermodynamic bulk precipitation range for ferric arsenate.INTRODUCTIONArsenic is toxic to animals, including humans, and long-term exposure to arsenic via drinkingwater causes cancer of the skin, lungs, urinary bladder, and kidneys, as well as other effects on the skin such as changes in pigmentation and thickening (Ghosha et al., 2008). Elevated levels of arsenic are often present in the environment as a result of the weathering and dissolution of minerals as well as in response to numerous anthropogenic sources including the discharge of mine wastes, coal fly ash and the use of pesticides that contain arsenic (Nriagu, 1994; Singh et al., 2007). Indeed, the potential for arsenic exposure affects many people, as evidenced by several million people in Bangladesh and India being at risk of exposure via drinking water obtained from contaminated groundwater sources (Ahmed, 2001).Acid mine drainage (AMD) containing arsenic is a global environmental problem (Dold, 2008; Liang and Thomson, 2008) that also affects Japan, which has many abandoned or closed mines that have been generating AMD for the last few decades (Masuda et al., 2008). Several such facilities in Japan produce AMD containing dilute concentrations of arsenic that exceed Japanese effluent standards (0.1 mg/dm3) (METI, 2006). For example, AMD from the abandoned Horobetsu sulfur mine, the largest AMD source in Japan, contains approximately 10 mg/dm3 arsenic."

Jan 1, 2012

By Y. N. Zhang

Friction Stir Welding (F SW) is a novel "green" manufacturing technique due to its energy efficiency and environmental friendliness. This solid-state joining process involves a rotating tool consisting of a shoulder and/or a probe. The shoulder applies a downward pressure to the work-piece surface, constrains the plasticized material around the probe, generates heat through the friction and causes plastic deformation in a relatively thin layer under the bottom surface of the shoulder. The rotating probe mainly drags along, plasticizes, and mixes the adjacent material in the stir zone, creating a joint without fusion. Friction Stir Processing (FSP), a variant of FSW, has been developed to manufacture composites, locally eliminate casting defects, refine microstructure and/or improve the associated mechanical and physical properties including strength, ductility, fatigue, creep, formability and corrosion resistance. However, major challenges such as tool design and wear currently limit the use of F SW/P for manufacturing applications, particularly for high melting temperature or high strength alloys. In this review, the FSW/P tools are briefly summarized in terms of the tool types, shapes, dimensions, materials and wear behaviors.

Jan 1, 2011

By O. Mejia

"As study was undertaken to investigate the relationship between mill liner wear and grinding energy efficiency and to assess the opportunity to control mill speed to improve energy performance as mill liner wears. The study involved analysis of plant operating data and liner wear profiles over time. The operating work index was found to be an effective tool to identify the decrease of grinding efficiency along the liner service. The plant data show that the mill grinding efficiency as determined by monitoring the operating work index, and throughput decreases as liner wears. However, efficiency and throughput can be maintained by either changing the liner more frequently or by increasing the mill speed. Two scenarios for increasing mill throughput were analyzed. The first one involves changing the liner before the efficiency drops and the second one requires increasing the mill speed from 75% to 79%. Both scenarios show financial benefits that can be used in mill operations.INTRODUCTION The analysis of the mill power draw is used in this study as a key parameter for comparing mill liner profile and its effect on mill performance. Current technology and simulation software used in the mining industry do not factor in the impact of liner wear profiles in grinding efficiency and mill throughput (Toor, 2013). To address this gap, this study provides an analysis of key factors affecting mill throughput and grinding efficiency: mill speed, ball loading, and liner profiles. Several years of plant mill operating data, published research papers, and MillTraj® simulation results are used to demonstrate that face angles impact grinding efficiency and throughput and that mill speed can be used to overcome this problem. Moreover, the liner profile wear analyses clarify a mismatch between actual and estimated power draw calculations."

Jan 1, 2019

By Qin-yong Ma, Jing-shuang Zhang, Bo Han, Pu Yuan

In order to improve the utilization rate of blasthole and blasting effect in vertical shafts, 5 kinds of millisecond blasting model tests with three circle vertical blastholes have been conducted in various delay times with concrete as model material. The blasting effects of millisecond blasting model tests are investigated from cutting volume, cutting depth, and blasting fragmentation, then a reasonable delay time is obtained. In the middle of concrete model, there are 4 blastholes uniformly distributed in the first circle, 6 blastholes uniformly distributed in the second circle, and 10 blastholes uniformly distributed in the third circle. Each blasthole is charged with one millisecond delay electric detonator, and the rest is blocked with stemming. The depth of blastholes in the first and second circle is 180mm, which is 20mm deeper than those in the third circle. After initiation, the blasting cavity is cleaned up, then the cutting volume and cutting depth are measured. Meanwhile, the blasting fragments are gathered and have analysed by function Rosin-Rammler. The test results show that when the inner two circle blastholes initiated simultaneously and the third circle blastholes initiated with millisecond delay, the reasonable delay time is 50 ms. At this time, the cutting volume and cutting depth of blasting model are 3920 cm3 and 68 mm respectively. The fragmentation indexes of blasting fragments, X50 and X80, are 53.2 mm and 74.6 mm respectively. While when all three circle blastholes initiated with millisecond delay, the reasonable delay time is also 50 ms. At this time, the cutting volume and cutting depth of blasting model are 10705 cm3 and 118 mm respectively. The fragmentation indexes of blasting fragments, X50 and X80, are 51.0 mm and 81.7 mm respectively. The researches indicate that for millisecond blasting with multiturn blastholes, the reasonable blasting scheme is multiturn blastholes initiated in millisecond delay and the reasonable delay time is 50 ms.

Jan 1, 2015

By E. J. Sides

In this paper, the argument is put forth that the codes used for public reporting of mineral resources and mineral reserves have some significant limitations with regard to the information provided to investors on the short- to medium-term value of mining properties. Such limitations include a) failure to explicitly incorporate a time element and b) failure to state explicitly the quantity and quality of mineral product that will be produced for sale. A time-value framework for reporting mineral assets is proposed in order to overcome these limitations. The proposed system is based on two classification axes: a) an X-axis representing time in years during which the value of the asset is likely to be realized and b) a Y-axis representing the value identified by a mining or exploration company\u2019s activities. The potential benefits of this system are discussed, including the ability to incorporate factors, such as permitting and construction times, directly into the magnitude of the reported mineral assets. The proposed framework would assist in the standardization of mineral assets reporting in such a manner that they could eventually be more readily included in financial statements. Year of Publication: Not explicitly mentioned in the document.

Jan 1, 2010

By S. Khoshkhooei

In this research, the effects of rare earth elements addition on thermal fatigue behaviors of AZ91 alloy were studied. Repeated heating and cooling cycles were applied on the samples at 170°C and 210 °C to develop thermal fatigue cracks, Crack growth mechanisms and microstructural influences were investigated by optical and scanning electron microscopy (SEM) as well as energy dispersive X-ray spectroscopy (EDS), Thermal fatigue behaviors were improved successively by addition of up to 2-wt% RE, This improvement is attributed to consummation of the aluminum of the melt by precipitation of the needle shape Al 11 RE3 phases, This process reduces the volume of Mg17Al12 phases and consequently decreases the brittle Mg/Mg17Al12 interfaces which are the main reason of weak thermal properties of the alloy at rather high temperatures, Further additions of RE, however, reduced the thermal shock resistance of samples by increasing in the mean length of the brittle needle shape phases.

Jan 1, 2005

By Tong Guan, Guangqin Fu, Lihong Deng, Yuanlin Chen, Xiaotong Zhou

"In natural world, some kinds of scheelite minerals are rich in molybdenum. Molybdenum exists in the crystal lattice of scheelite in the form of isomorphism, and the content of MoO3 varies from 2% to 10%. As a result, the flotability of seyrigite (scheelite with molybdenum) turns to be weaker. One seyrigite mine, which has been built for 3 years,still could not produce qualified seyrigite concentrate due to the weak flotability of seyrigite (Mo-bearing scheelite) in raw ore. In our experimental research, through adopting new seyrigite collector TA-3 and advanced mineral processing technology, the seyrigite concentrate with a grade of 65.62% WO3 at a recovery of 87.47% was obtained for the raw ore containing 0.19% WO3 and 0.074% Mo. By applying the new technical achievement, for the raw ore containing 0.272% WO3, the seyrigite concentrate assaying 68.03% WO3 with a recovery of 77.56% was obtained in industrial production.INTRODUCTIONIn natural world, some kinds of scheelite minerals are rich in molybdenum. Molybdenum exists in the crystal lattice of scheelite in the form of isomorphism, and the scheelite is changed to be seyrigite (Ca[(W,Mo)O4]) (Ma, Bian, & Wang, 2013). The content of MoO3 in seyrigite varies from 2% to 10% usually, the content of MoO3 in some of the seyrigite even reaches 34%. The flotability of seyrigite is weak (Zhang, 2007), and the seyrigite is difficult to be recovered by flotation with common collectors and regulators. One scheelite mine in Anhui China, which is a skarn type seyrigite mine, has not produced qualified concentrate yet since 3 years it has been built due to the limit of beneficiation technology. Therefore, it is necessary to conduct research on the collectors with high efficiency and developing advanced processing flow for this kind of ore."

Jan 1, 2016

By W. A. Gow, J. A. Vezina

"A new process for treating scheelite for the production of tungstic tri-oxide is described. The novelty of the process resides in that an ion-ex-changer is used to convert sodium tungstate to either ammonium tung-state or tungstic acid.The process consists of a conventional hydrochloric acid leach of the scheelite concentrate, and the dissolution of the impure tungstic acid thus produced with sodium hydroxide at pH 8. The sodium tungstate solution is clarified and passed through a column of Dowex 50Wx8 ion-ex-change resin to exchange the sodium ions for either hydrogen or ammonium ions, both being suitable. The tungsten-bearing column effluent is evaporated to crystallize the tungsten as ammonium tungstate; the crystals are washed with nitric acid and water and decomposed by heat to pro-duce tungstic trioxide of high purity.Ninety-six per cent of the tungsten in the concentrate may be re-covered as tungs tic trioxide (W03), and the reagents consumed are 0.7 g HCl, 0.41 g NaOH and either 1.73 g NH.Cl or 225 g HCl per gram of tungsten."

Jan 1, 1966

By P. W. A Severin

"The Sturgeon Lake deposit, a partly eroded lens of massive sulphides with an underlying sulphide stringer zone, is one of five orebodies that occur in the Sturgeon Lake area of northwestern Ontario within volcaniclastic rocks of the Archean Wabigoon Subprovince in the Superior Province of the Canadian Shield.The Sturgeon Lake Cu-Zn-Pb-A g-Au deposit was discovered in October 1970 as a result of an I.P. survey. Production from this open-pit mine began in March 1974 and continued until the ore was exhausted in March 1980.The Sturgeon Lake property is underlain by basaltic volcanics, minor amounts of mafic lapilli tuff and rhyolite volcaniclastics. A quartz crystal-bearing rhyolite occurs at the top of the felsic volcaniclastics and is ""capped"" by the Sturgeon Lake massive sulphide deposit. The felsic volcanics have been intruded by a crudely layered sill-like, carbonatized mafic intrusion. Recent work suggests that the felsic rocks that underlie the Sturgeon Lake deposit are lateral equivalents of those in the vicinity of the Mattabi Mine and are not correlative with the dacitic volcaniclastics that underlie the Lyon Lake and Creek Zone deposits. Hydrothermal processes that resulted in the formation of the Sturgeon Lake orebody have resulted in a depletion of Na2O, CaO and FeO and an increase in MgO, K2O, copper and zinc. In the vicinity of the sulphide stringer zone, the rhyolites are ""bleached"" due to silicification and sericitization. The rocks lying immediately below the massive sulphides are locally strongly chloritic.The Sturgeon Lake deposit may have formed on a top ographic high which prevented mafic flows and dacitic volcaniclastics that underlie the Lyon Lake and Creek Zone deposits from inundating the Sturgeon Lake fumarolic vent from the west. Continued or resurgent activity from the Sturgeon Lake fumarole may have resulted in the formation of the Lyon Lake and Creek Zones as more ""distal "" deposits in topographic lows. The Sturgeon Lake, Lyon Lake and Creek Zone deposits were subsequently overlain by mafic tuffs and flows."

Jan 1, 1982

By K. Hawboldt, J. E. Halfyard, C. Bottaro, I. A. Harrison

"The removal of elemental sulfur from leach residues derived from massive sulfide concentrates via hydrometallurgical routes has been demonstrated in a laboratory setting by converting water-insoluble sulfur to water-soluble polysulfides. The approach was applied to leach residue from Vale's nickel hydromet demonstration plant in Argentia, Newfoundland, which contained significant amounts of elemental sulfur. This technique offers an alternative treatment protocol for residues with a sulfur component not amenable to standard flotation/hot filtration processes. The practical considerations of a proposed flow sheet will be discussed including the impact of other sulfur species (e.g. thiosulfate and sulfides) and key process variables. INTRODUCTIONPresently, large scale elemental sulfur extraction from hydrometallurgical leach residue is performed by Teck Resources using a process of sulfur flotation followed by hot filtration (Chalkley et al., 1993). As mentioned, the technique proves viable for residues derived from specific concentrations - in this case zinc - whose residues constituency is primarily elemental sulfur itself. However, problems arise when this constituency is altered as happens when, for example, a mine containing one particular concentrate is mixed or replaced with a differing concentrate from a second mine. Such cases can often strain the effectiveness of current sulfur removal processes (D'Odorico, 2004). If hydrometallurgical residue containing elemental sulfur cannot be effectively treatment by flotation, the residue is stored subaqueously as is the case in some 'grass roots' hydrometallurgical plants (those not coupled with smelting operations). Hydrometallurgical processing of concentrates involving pressure leaching is becoming increasingly common throughout the mining world, the genesis of which can be found in research performed by Sherritt in Fort Saskatchewan since the 1950’s (Ozberk et al., 1995).The investigation of elemental sulfur removal by means other than flotation includes the uses of sulfide salts (NH3S or Na2S) effecting the conversion of hydrophobic elemental sulfur to hydrophilic polysulfides. The work of Kunda et al. (1974) and Olper et al. (2007) shows that elemental sulfur can be quantitatively removed from hydrometallurgical leach residue via the formation of a mixture of polysulfides."

Jan 1, 2012

By F. Tanaka

Copper losses to discard slag have long impacted on the profitability of copper smelters. Businesses based on the treatment of secondary materials have also revealed that copper losses are indices of precious-metals losses. Many custom smelters are thus required to obtain more reliable controls for reducing copper losses than ever before. Mitsubishi Materials Corp. has cooperated with academic research institutes in conducting research projects on the pyrometallurgical fundamentals of copper smelting systems, including mutual evaluation of magnetite behavior between synthetic and industrial slags. The state-of-the-art pyrometallurgy has subsequently been introduced to Naoshima smelter for controlling the Mitsubishi process. The revised controls function successfully and the operational results demonstrate that avoiding the discharge of solid magnetite from the S-furnace is quite effective to reduce copper losses. Magnetite behavior has been controlled over the Mitsubishi process so as to reduce copper losses while satisfying the needs of recycling businesses growing in Japan. In-situ estimation of magnetite behavior using the absorbed heat from the melts to cooling water will also be discussed.

Jan 1, 2007

By J. Font

The RAF or copper fire refining process at the Caletones smelter of CodelcoChile consists of several pyrorefining stages that successively lowers the levels of S, Fe, Pb, As, Sb, Te, Se and to some extent 0 in the copper melt, allowing the production of high quality fire-refined copper of 99.93 % purity (RAF copper). This chemical feature of the RAF copper is only achieved by quite long processing times, and a considerable consumption of fluxes and fuels in the RAF vessels. The main goal of this study was to improve the RAF process performance by thermodynamic considerations and industrial scale tests, i.e., an in situ approach for the process as featured by intensive sampling, characterization and subsequent modifications. Thus, both theoretical and industrial data were derived, and based on kinetic and thermodynamic evaluations, a higher operational standard was achieved for the RAF process. These new operational practices allowed enhancing the overall economic of the RAF process, by reducing the time and operational costs, and consequently increasing the availability of the vessels.

Jan 1, 2007

By Douglas R. Schmitt

In general, knowledge of the state of stress within the Antarctic lithosphere remains largely unconstrained due in part to Antarctica?s inaccessibility and because of the paucity of seismic focal mechanism solutions. As such, an important component of the ANDRILL project was to acquire new information on the stress directions and magnitudes within the upper crust. Extensive fracture mapping of the core and oriented ultrasonic televiewer logging were carried out to provide strong constraints on both stress orientations and the faulting regime. The first hydraulic fracturing stress determinations in Antarctica were also carried out to provide complimentary stress magnitudes. These measurements were accomplished using a wire-line transported hydraulic fracturing system consisting, essentially, of two synthetic polymer packers that were inflated to isolate the 1-m long pressurization interval. The tests were conducted at the end of the drilling and logging in a ~130-m section specially drilled below 1000 mbsf (nearly 1500 m from the rig floor) for hydraulic fractures. This zone was drilled primarily through competent, dense, and low permeability diamicts. The core fracture and televiewer logging information was used to site twenty separate measurements. Classic hydraulic fracturing pressurization records with unambiguous breakdown and fracture closure pressures were obtained in about half of the measurements. The remaining tests provided fracture propagation and closure pressures that are consistent with the classic breakdown curves, but they did not include a clear breakdown pressure and are indicative of the reopening of either natural or drilling induced fractures in the wellbore wall. The preliminary analysis of the results are in generally good agreement with the stress directions indicated by the core fracture logging and the stress regime suggested by the character of the drilling induced core fractures.

Jun 1, 2012