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By P. W. Bennett, E. M. Elkin

A new technique for the recovery of palladium and platinum and sludge from go12 electrolyte eliminates many of the drawbacks of the zinc-dust cementation process. In the electrolytic refining of gold by the Wohwill method, the electrolyte contains about 100 gpl gold as AuCl, and 100 gpl free hydrochloric acid. Any palladium and platinum contained in impure gold dissolve and accumulate in the electrolyte. When their concentration approaches that of gold, it becomes desirable to discard the electrolyte and to recover the gold and the palladium and platinum. As practiced at Canadian Copper Refiners until recently, discarded electrolyte was treated with sulfur dioxide to precipitate the gold. 2AuCl3 + 6H2O + 3SO2 —2Au + 6HC1 + 3H2SO4 The gold precipitate was filtered off, washed with water, and melted with scrap anodes. The wash water was added to the gold-free filtrate and treated with zinc dust to cement the palladium and platinum. PdCl2 + Zn — Pd + ZnCl2 PtCl4 + 2Zn—Pt + 2ZnCl2 The precipitate was separated and sold as Pd-Pt concentrate, and the barren filtrate and wash water were discarded. The receipts of palladium and platinum at this company were too small to warrant their refining. The process suffered from a number of disadvantages. Handling the gold-free solution was disagreeable, as it was laden with sulfur dioxide even after blowing with air overnight. Subsequent treatment with zinc dust was also troublesome. A large excess of zinc dust was required. Spray, acid mist, and vigorous evolution of hydrogen accompanied the reaction. The Pd-Pt precipitate was grossly contaminated with occluded unreacted zinc and with yellow granules of sulfur, thought to be formed by the reduction of sulfur dioxide and its derivatives. Repeated boiling of the precipitate with hydrochloric acid and washing with water decreased somewhat, but did not eliminate, the zinc. After drying overnight, the precipitate hardened to a clinkerlike mass that was difficult to grind. Grinding, handling, and packing created heavy dusting. Even weighing in an analytical balance generated dust, indicating that the powder was easily charged with static electricity. The total palladium and platinum content of the powder varied from 56 to 72 pct, with an average of 65 pct. The powder dissolved in aqua regia with difficulty, leaving a small amount of insoluble residue. However, the main drawback of the process was the strongly hygroscopic Pd-Pt product. The powder showed a marked though erratic increase in weight and a corresponding decrease in assay on exposure to air, even during the course of laboratory analysis. Such changes were the source of disagreement between Canadian Copper Refiners and the buyers of concentrate. The cause of the change in weight is believed to be hydrogen, liberated by the action of zinc dust on hydrochloric acid. Some of this hydrogen was adsorbed so strongly by the precipitate that it could not be driven off during the drying. On exposure to air it oxidized catalytically, forming water. Experiments soon showed that the entire process of treatment of discarded electrolyte then in use would have to be changed. A small quantity of apparatus was moved into the gold room, and experimentation was held to a minimum compatible with the development of a new process. PALLADIUM AND PLATINUM PRECIPITATION It was thought that zinc could be replaced with a reagent other than a hydrogen-evolving metal. Semiquantitative experiments showed that platinum and palladium could be precipitated completely from the gold-free solutions with such well-known reagents as sodium formate, formic acid, formaldehyde, and paraformaldehyde. Sodium formate was the preferred reagent, since the other three are volatile and somewhat toxic. The gold-free solutions used were those saturated with sulfur dioxide, partly freed of sulfur dioxide by aerating overnight, completely freed by boiling, as well as strongly and weakly acidic, neutral, and alkaline solutions. The reactions are complex and can be represented by these over-all equations: PdC1, + HCOONa — Pd + NaCl + HC1 + Co2 PtCl4 + 2HCOONa — Pt + 2NaCl + 2HC1 + 2CCX, Strongly acidic solutions required as much as five times the theoretical amount of sodium formate as did solutions neutralized to pH 4.5. Increasing the pH decreased the consumption of

Jan 1, 1965

By Don M. Jackson, Robert W. Howard

Techniques for the epilaxial growth of single -crystal silicon carbide films on silicon were developed. The vapor-phase decomposition and bydrogen reduction of silicon tetrachloride (SiC14) and Propane (C3H8) resulted in clear films of silicon carbide, lip to seveval microns in thickness. The growth took place in a horizontal . silicon epilaxial reactor at 1100°C (pyrometer) at a rate of- 3000Å per minute. Electron diffraction and X-ray diffraction studies demonstrated that the films were single-cyrstal, ß -phase, or cubic silicon carbide. SiO2 film were used to mask areas of the silicon sur-lace in order that the silicon carbide might be grown in controlled geometries. Both n- and p-type films were grown on p-type silicon waters.. Heavily doped silicon films of the same conductivity type as the silicon carbide films were deposited over the silicon carbide in order to affect better probe contact to the structures. when n-type silicon carbide mesas were grown on p-type silicon substrates the de vollage-current relationships between films and substrates were that of junction diodes. These diodes showed a sensitivity to while light ill that the incident light increased forward- and reverse-satro,ation currents, P-type silicon carbide mesas grown on p-type silicon were ohmic rather than rectifying in their voltage -current relationship. No conclusions could he reached concerning heterojunc-tiou rectification in the structure. SILICON carbide is a semiconductor with many interesting properties. It decomposes at temperatures above 2200°C.1 It occurs in two general crys-tallographic forms—hexagonal (a Sic) and cubic (ß Sic)—with the cubic form having a forbidden-gap energy of 2.32 ev and the hexagonal form (specifically the 6H polytype) a gap energy of 2.86 ev.3 It behaves as an extrinsic semiconductor at temperatures approaching 5003C. It has been shown to have a high resistance to radiation damage4 and p-n junctions formed in Sic have been shown to radiate visible light under forward- or reverse-bias conditions. Epitaxial silicon carbide on silicon carbide has been successfully grown through the use of a variety of techniques, such as gaseous cracking of SiCL4 and CC4, nearly all of which require a deposition temperature above 1500°C.6 This paper will cover very recent work on the gas-phase deposition of highly ordered films of silicon carbide on high-quality silicon single-crystal substrates. The films have been shown to ex- hibit junction-rectification properties when geometrically isolated regions are electrically biased with reference to the silicon substrate. There will be no discussion of the mechanism of heterojunction rectification, but the methods of film fabrication, geometry control, and structural evaluations will be covered in detail. Electron diffraction, X-ray diffraction, and diode electrical properties were used to characterize the films and the junctions. GAS-PHASE DEPOSITION OF Sic The techniques for the deposition of silicon carbide films were a logical outgrowth of the standard silicon epitaxial process. The major premise followed was that, for any film to nucleate in an ordered fashion where there is considerable mismatch in lattice parameters (in this case 22 pct), an extremely clean, damage-free substrate surface must be presented to the gas stream. Thus a standard gas-phase HCl etching step was used to prepare the substrates for growth. A minimum of 5 µ of substrate-surface material was removed prior to the deposition of Sic overgrowth films. The techniques used for growing silicon carbide films were those of growing silicon alone, with the added injection of a hydrocarbon gas into the hydrogen and silicon tetrachloride gas stream. The hydrocarbon gases used thus far have been research-grade (99.99 pct) methane (CH4) and propane (C3H8). Propane ultimately gave the best results. The gas flows were controlled through a panel shown schematically in Fig. 1. A hydrogen main stream of 30 liters per min passed through the horizontal quartz-tube epitaxial reactor, while SiC14, C3H8, HC1, and doping gases were injected as side streams. The

Jan 1, 1965

By H. W. Schreiber, H. R. Babitzke, R. E. Rodriquez, Patterson J. A., C. D. Masters, J. J. Schanz, R. B. McCammon, E. A. Noble, P. M. Krishna

A five-year effort by the ASTM subcommittee E10.14 on uranium resource evaluation has culminated in the approval of E901-82, Classification System for Uranium Resources (ASTM Standard E901-82, April 1983). The standard classification was prepared with participation of representatives from the US Department of Energy, the US Department of Interior's Geological Survey and Bureau Mines, utilities, and consultants. The classification a resource is based on level of knowledge and the economic producibility of the resource at a given time. Alphanumeric identifiers are used rather than words to avoid confusion with existing terms, definitions, and classifications. An example demonstrates the dynamic nature of the process of classification and attests to the necessity of addressing both the aggregate needs of broad-scale resource planning and the specific needs of individual property evaluation. Problems that remain infixing the classification a given uranium resource include uncertainty in estimating the quantity of undiscovered resources and resolving differences that may exist in deciding when the drill-hole spacing is adequate to determine the tonnage and grade of discovered resources.

Jan 1, 1985

By N. L. Muench, J. S. Osba

Research conducted previously has demonstrated that spectral analysis of gamma radiation from the naturally radioactive elements present in earth materials permits detervination of the relative concentrations of these elements. This research suggested that spectral analysis of gamma radiation resulting from neutron bombardment of elements not nor-mally radioactive might serve to identify these non-radioactive elements, and might permit their quantitative determination. To investigate this possibility, laboratory experiments were conducted in which various earth materials were subjected to bombardment by neutrons from a polonium-beryllium source, and in which the spectra of the resultant gamma radiation were analyzed. The geometry of the lab-ortory system was designed to simulate wellbore conditions. The laboratory work demonstrated that some elements not only can be identified with relative ease, but also can be determined quantitatively. This finding indicates that the use of an intense source of more energetic neutrons may lead to the identification and measurement of additional elements of interest by means of induced nuclear reactions. INTRODUCTION In recent years the applications of nuclear physics to the producing branch of the petroleum industry have become increasingly numerous. One significant development, an outgrowth of nuclear science which is of potential importance in well logging, has been the analysis of gamma-ray spectra of naturally radioactive elements in earth strata. The work of Brannon and Osoba1 has demonstrated that presently available equipment and techniques may be used to determine the relative concentration of thorium, potassium, and uranium in underground strata by means of gamma-ray spectral analysis. Success of the research on spectral analysis of naturally radioactive elements suggested that spectral analysis of induced radioactivity might serve to identify, and perhaps measure quantitatively, those elements which normally are not radioactive, but which become radioactive on neutron bombardment. It was to investigate this possibility that the research described in the following sections was undertaken. THEORY OF INDUCED NUCLEAR REACTIONS Of fundamental importance is the fact that an element, when bom- barded with neutrons, emits gamma rays of energies characteristic of that element. Therefore, in theory, an element may be identified by analysis of the energy spectrum of the neutron-induced gamma radiation. If a neutron impinges upon the nucleus of an atom, any one of several reactions may occur. For identification of elements in earth formations the more important are listed below: 1. The neutron may be elastically scattered, as in a collision between two billiard balls. In this case the total kinetic energy is conserved, and no nuclear radiation is emitted. 2. The neutron may be inelast-ically scattered, as in a collision between two automobiles in which case the total kinetic energy is not conserved. The lost kinetic energy reappears in the form of gamma radiation. 3. The neutron may be captured, in which case the neutron becomes a part of the target nucleus, and a gamma ray is emitted. For example, if the target nucleus is H1, the pro-duced nucleus will be H3, and gamma radiation of a particular energy will be emitted. 4. The neutron may produce nuclear fission, or may enter into miscellaneous reactions which result in the emission of

Jan 1, 1958

By B. G. Bunting, D. L. Abata, J. Robb, J. H. Johnson

Toxic gases produced by the detonation of six explosives were measured in an underground hardrock metal mine during mining operations. The explosives included two semi-gelatin dynamites, three slurry explosives, and an ammonium nitrate, fuel-oil/ammonia dynamite combination. Explosives were detonated at the face of a drift and toxic gases produced by the detonation were trapped at the end of the drift by a bulkhead located a short distance away from the face. Toxic gas concentrations were then measured with direct readout instruments and together with the containment volume, the toxic gas volumes per mass of explosive were calculated. Toxic gas measurements were found in the following ranges (ft3/1bm): NO, 0.0100-0.035; N02, 0.003-0.019; CO, 0.08-0.30; SO2, 0.00-0.05; and CO2, 0.7-1.8. Results showed that toxic gas production (ft3/lbm) correlated with the densities (kg/m3) and energy densities (kJ/kg) of the explosives tested.

Jan 1, 1983

By S. R. Goodman, Hsun Hu

PREVIOUS investigations on the temperature dependence of rolling texture transition in high-purity silver1'2 and in electrolytic copperS have shown that a brass-type texture is favored at low rolling tem- peratures, whereas a copper-type texture is favored at high rolling temperatures. The transition takes place gradually as a function of the temperature of deformation, and a general correlation between texture transition and stacking-fault frequency or probability exists—a copper-type texture is associated with low stacking-fault frequencies, and a brass-type texture is associated with high stacking-fault frequencies. If the stacking-fault energy is calculated from the stacking-fault frequency and the dislocation density of the specimen, one finds that with low stacking-fault energies a brass-type texture will be developed, and that with high stacking-fault energies the texture will be of the copper-type. These findings are consistent with the idea that the formation of rolling textures in fcc metals may depend on their stacking-fault energy, although results of such nature always involve the ambiguity that a change in the density (or width) of stacking faults produced by deformation at different temperatures may be actually due to a variation in the stress, rather than due to a change in the specific stacking-fault energy per se. It has also been shown that the type of annealing texture depends entirely on the deformation texture. From a copper-type rolling texture, a strong cube texture will be formed upon recrystallization, whereas from a brass-type rolling texture, the annealing texture will be quite different from the cube orientation. Based on these results on texture transition in pure fcc metals, it appeared possible to effect a

Jan 1, 1963

By J. H. Wiggins

This paper first pictures the economic phase of evaporation losses and the actual evaporative conditions in handling and storing crude and gasoline in the United States; then follows a discussion of some of the theories of physics involved in evaporation loss and lastly an application of these theories to handling oil and gas on producing properties. GRANTING that about 600,000,000 bbl. of light oil will be produced in the United States this year and taking the Bureau of Mines' statement that 7 1/2 per cent. of the total crude production will be lost before the finished gasoline is shipped from the refinery, the volumetric evaporation will be 45,000,000 bbl. of the cream of the gasoline. This is a conservative figure and is equivalent to 1,890,000,000 gal. The real value of this liquid is at least 150 per cent. of the value of an equal volume of motor fuel. At only 10 c. per gal., the value lost is $189,000,000; at 15 c. per gal. the loss is $283,000,000. If 750,000,000 bbl. of light and heavy oil are produced here this year and the average price per barrel is $1.333, the gross return to producers will be $1,000,000,000 and the net returns about $200,000,000, if the cost of production is only $1 per barrel. Thus, the evaporation bill is about 20 per cent. of the gross income and is equal to the net income of the crude-oil producers. Two other comparisons with popular phases of the petroleum industry will help give an adequate conception of the evaporation problem. These are: cost of preventing evaporation compared to cost of cracked gasoline and volume of gasoline evaporated compared to volume of gasoline manufactured from natural gas.

Jan 7, 1924

By H. W. Seamon

THE data here given were obtained by 1500 tests made, by the United Verde Copper Co. to determine the most economical air pressure for the operation of hammer drills under the varying conditions of use, and to investigate the variation in drilling speed at different air pressures Twelve models of drills were used at gage pressures ranging from 40 to 130 lb. No effort was made to harmonize theory and practice; but rather to formulate empiric rules that would cover the. average variation of the results obtained. These rules on the performance of hammer drills, based on the air pressure as the main variable, however, are not necessarily of universal application, but they apparently satisfy the results obtained in this series of tests. The drilling conditions at this property vary widely; an average of twenty-one machine shifts to a 3-ft. (0.9-m.) round has been found necessary in some of the development work, while an, advance of 56. ft. has been made in seven shifts in the "oxide" ground. This range pre-eludes the adoption of one type of drill as a standard; consequently almost every kind of hammer drill sold in this country has been tested. At present, sixteen models are in use, of which two types of the heavy (150 to 160 lb.) mounted drills, one of the light mounted drill, one stoper, and two hand plugging drills are considered as standard.

Jan 1, 1921

By C. S. Duncan, S. Scuro, D. R. Muss

Work is vepurted which was aimed at accentuating the pec14liar attributes of the GaAs laser diode, namely its sutzull size and its high efficiency. This has been done by reducing- transport losses in the bulk p and n regions of the diode and combining many of. these diodes into series stacks with common optical cazlities. The result of this effort is a nearly monochromati source at about 8450A With a luminous areu 0.05 by The GaAs laser diode is an attractive pulsed light source in the near ir because of its ability to emit very large pulse powers and its small size. In addition to this, the device is efficient; and the higher the 0.05 cm emitting peak pulse po we rs at greater than 300 LC at repetition rates below 200 pps into a cone about 0.01 steradians when operated at 77°K. The results of nzeasuvetnents of peak optical power and spectra frorr~ these stacks are reported and some conclusions are drawn about the vole the individual diodes play in the stacked operation. peak output power, the more efficient it is. The limit for the amount of power that these diodes can emit is the transient and average dissipation associated with the pumping pulse. This power dissipation arises primarily from transport across the bulk regions of the diode; this fact, along with the relatively low thermal conductivity of the GaAs, led us to the conclusion that higher power

Jan 1, 1968

By J. L. Rodda

A large amount of time has been devoted to the microscopical study of the copper-zinc alloys, emphasis naturally being placed upon the commercially important alloys of the system. Suitable methods are available for microscopically recognizing the two phases richest in copper, but none appear to have been developed for the positive identification of the other phases. This is, however, accomplished, for the phases normally encountered, by an electrolytic method described in the following pages. Five phases of the copper-zinc diagram (Fig. I) are considered for the purpose of this paper: the solid solution of zinc in copper, alpha (a); the intermediate phases, beta (ß), gamma (?), and epsilon (e); and the solid solution of copper in zinc, eta (11). Beta prime is not considered a separate

Jan 1, 1937

By M. P. Nackowski

Geological engineering expanded its role and significance during 1966 in the areas of construction, raw materials exploration and inventory, water supply and pollution, mechanical properties of earth material and regional environmental planning. Efforts varied immensely in scope and magnitude, in simplicity, difficulty and importance. Observations, measurements, and analysis encompassed both simple and sophisticated procedures. CONSTRUCTION Activities in construction ranged from preliminary to detailed evaluations of sites, development of preventative measures and designing corrective measures following construction failures. Most investigations concerned dam sites, highway locations and slope stability, building sites, tunnels and underground storage facilities.

Jan 2, 1967

By T. E. Godson

AS this is the age of reform, a uniform mining law for North America is a moot subject for discussion at this meeting of the Institute. The question is one of peculiarly technical and, in many respects, local character. We all appreciate the value of the metal-producing industries and recognize the necessity and importance of a well-considered and evenly balanced mining law as a branch of our jurisprudence either for the Provinces or the Dominion as a whole. Mining has taken its place as a forempst industry and legislation that seeks to control and govern it is the concern of not only the active miner but the citizens of the state. A law that, through its charitable measures brings into being the prospector, the pathfinder and superstructure of all mining activity and industry! protects his interests, safeguards invested capital, and encourages and enforces development, possesses at least the salient requirements of a businesslike Act. The manner of doing so is, I think, one of local and internal concern. May I be permitted to say without presumption that of the five mining codes, or Acts, that we have in the Dominion of Canada born and bred within the Provinces of British Columbia, Ontario, Quebec, New Brunswick, and Nova Scotia, some of them could be materially improved. In many respects they do not measure up to the times; they were no -doubt creations of merit at the date of their .birth but they have not been clothed in seasonable raiment as the years passed by. It is a stern fundamental principle that all natural resources are the inalienable property of the crown. If it is mineral land, then it follows for the protection of the state and the direct advancement of the occupant that the land should be developed as such. The method or machincry by which this must be accomplished is a matter of detail, not of principle. If the right to possession as a licensee depends on discovery, it is not inconsistent with the duty the crown owes to the state that a grant in fee should pass to the discoverer if there is imposed, after patent issues, a requirement of continuous work or the alternative of an acreage tax sufficiently burdensome to make it unprofitable that the land should be held in an undeveloped state. If this requirement is recognized, the mental distinction between a grant and lease ceases to exist. A

Jan 1, 1920

By Y. C. Liu, G. A. Alers, S. S. Choi

In searching for an explanation for the obvious difference between the copper and the brass type of rolling texture, it is common practice to look for correlations with other properties. For example, there are obvious differences between copper and brass in the critical resolved shear stress, the extent of easy glide or stage I, and the amount of "overshooting)) during single-crystal deformation.' Also, the slip lines in copper are fine and wavy while those in brass are more coarse and better described as slip bands.' Since neutron irradiation is known to make these properties in copper change in such a way as to resemble brass,2'3 an excellent test for these possible correlations is to see whether neutron irradiation produces a corresponding change in the texture, i.e., whether irradiated copper develops a brass-type rolling texture. The experiment would also answer the more important question of whether or not lattice defects like those introduced by neutron irradiation have any effect on the development of rolling textures in fcc metals. Experimental studies using conventional X-ray pole figure techniques are inconvenient because the X-ray detection system must be modified to discriminate against the radioactivity which is induced in the specimen by the necessarily long exposure to neutrons. Nevertheless, some texture determinations have been

Jan 1, 1968

(Members are urged to send in for, this column any notes of interest concerning themselves or their fellow-members.) Members and guests who registered at Institute headquarters during the period Aug. 10 to Sept. 10, 1915: Everett L. Booth, New York, N. Y. Raymond B. Ladoo, Cambridge, Mass. T. E. Sturtevant, Dover, N. J. Henry A. Tobelman, Ajo, Ariz. C. A: Filteau, New York, N. Y. R. B.Tinsley, B. Tinsley; Venezuela. Guy C. Riddell, Helena; Mont. ; E. H. Hamilton, Norfolk, Va. Joseph Leiner, New. York; N. Y. M. Yoshimura, Tokyo, Japan. Alfred W. G. Wilson, Ottawa, Canada. Van H. Manning has been appointed Director of the U.. S., Bureau of Mines, to succeed the, late, Dr. Joseph A. Holmes. Mr. Manning was Assistant Director of the Bureau. 0. M. Lewyn, formerly Mine. Superintendent for the Braden Copper Co., has accepted the position of Assistant Mine Manager with the Union Minière de Haut Katanga of South Africa.

Jan 10, 1915

By O. P. Arora, M. Metzger, G. R. Ramagopal

Single-phase aluminum containing 0.0001 to 0.06 pct Cu was studied in strong acid, mainly through observations of hydrogen evolution. The strong influence of copper was exerted almost entirely through the imposition after a certain delay time of an auto-catalytic localized-corrosiott reaction. Additions of cupric ion to the acid produced lower accelerations. The significance of the quantity and distribution of copper was discussed, and the implications for intergranular corrosion and neutral chloride pitting were indicated. AN investigation of intergranular corrosion in single-phase high purity aluminum exposed to hydrochloric acid indicated the copper content of the metal to have an influence on corrosion at lower levels than previously suspected.&apos; The work reported here was a closer examination of the action of copper but dealt with general corrosion to gain the advantage of having a continuous measure of corrosion through the volume of hydrogen evolved, the reduction of hydrogen ion to hydrogen gas being the principal or only cathode reaction in strong hydrochloric acid. Previous work on the hydrochloric acid corrosion of aluminum was sometimes insufficiently structure-conscious and the need for care in evaluating it arises from the low solubility of the iron impurity,&apos; and of some alloying elements, and the known or possible presence in many of the compositions studied of second phases leading to greatly increased corrosion rates.3 These increases are attributed to the presence of low hydrogen-overvoltage cathodes provided by the second phase.3&apos;4 For the present single-phase work, a few studies which used high-purity base material and small copper additions5-&apos; provide the essential information most unambiguously. The corrosion rate was shown to be increased markedly by the introduction into the acid of small quantities of the ions of copper (and of certain other metals) which cement on the aluminum and provide cathodes of low overvoltage.5 When there was sufficient copper in the aluminum, the same result was produced during the course of corrosion leading to a rate which increased with time as the reaction was stimulated by one of its products (autocatalytic reaction). In 2N (7pct) HC1, an accelerating rate was observed at 0.1 pct Cu but not at 0.01 pct.5,7 The present work dealt with corrosion rate and morphology and their correlation with the quantity and distribution of copper catalyst for copper contents from 0.0001 to 0.06 pct. PROCEDURE A lot of high-purity aluminum containing 0.0021 pct Cu, 0.001 pct Fe and 0.003 pct Si (Alloy A) was alloyed with copper to yield aluminum containing 0.014 pct Cu (B) and 0.06 pct Cu (C). Later it was found necessary to include the lower copper Alloy K which contained 0.0001 pct Cu, 0.0004 pct Fe and 0.0004 pct Si. The upper limit for any other element can be confidently estimated as 0.0005 pct. No element other than copper appears to be present in quantities sufficient to have an effect on general corrosion as great as the observed effect of the copper in A, B, and C. The only other heavy metal detected by spectrographic examination was silver (< 0.0001 pct). The acid was made up from a selected lot of 37 1/2 pct CP hydrochloric acid containing 0.1 ppm heavy metals (mainly Pb), 0.05 ppm Fe, and < 0.008 ppm As and from water distilled from 1 megohm-cm demineralized water and believed to have contained negligible quantities of heavy metals influencing corrosion. Acid strength was adjusted to within 0.05 pct HCl of the stated value by using precision specific gravity measurements. Test blanks 10 by 41 mm were sheared from 1.65-mm cold-rolled sheet. Edges were finished by filing. The blanks were annealed in air at 645°C for 24 hr in alundum boats and rapidly water quenched. The anneal is thought to have produced a substantially homogeneous solid solution—for iron, copper, or silicon, for example, the annealing temperature was 200°C or more above the solvus-and the quench is considered to have preserved the high-temperature structure except for the condensation of lattice vacancies into dislocation loops.&apos; The 0.06 pct Cu alloy did not appear unstable in respect to slow precipitation reactions at room temperature since two pairs of tests failed to show significant differences between specimens heat treated 3 1/2 years earlier and specimens heat treated 1 or 2 days before.

Jan 1, 1962

By G. W. Bain

The Canadian magnesite deposits are situated in Grenville township, about 8 miles from Calumet station, on the Canadian Pacific Railway, but the poor transportation facilities have hindered their development. Magnesite was discovered in the boulders near White Rock Lake by Rev. W. P. Boshart in 1900. Observing that the material of these boulders was more glistening and whiter in color than Grenville limestone, he sent a specimen to the Department of Mines, Ottawa. An analysis showed this to be almost pure carbonate of magnesia and of commercial value if present in sufficient quantities. That summer, Boshart and McAllister found numerous outcrops, both of boulders and of bed rock, that gave promise of being magnesite of a commercial grade, and decided that this mineral deposit, if developed, would rival that at Veitsch, Austria. So they procured options on most of the land on which they knew the magnesite occurred. But the transportation difficulties were too great for the deposits to be mined at the prices offered for the product. In 1907, T. J. Waters organized the Canadian Magnesite Co. and opened a quarry on the north half of lot 18, range IX, and later on lot 15, range IX, of the same township. A lirnestone kiln was erected and the calcined rock was hauled to Calumet. In 1914, the North American Magensite Co, took over the quarries and shipped both crude and calcined magnesite until January, 1923. During 1915, S. Melkman organized the Scottish Canadian Magnesite Co. and opened a quarry on lot 15, ranges X and XI, Grenville township. A light, narrow-gage railway connects this quarry with the C. P. R. at Magnesite station. but shipments are made only during the summer months. Numerous other quarries have contributed to the output of the district but the greater part has come from the open pits of the

Jan 1, 1923

By G. W. Bain

The Canadian magnesite deposits are situated in Grenville township, about 8 miles from Calumet station, on the Canadian Pacific Railway, but the poor transportation facilities have hindered their development. Magnesite was discovered in the boulders near White Rock Lake by Rev. W. P. Boshart in 1900. Observing that the material of these boulders was more glistening and whiter in color than Grenville limestone, he sent a specimen to the Department of Mines, Ottawa. An analysis showed this to be almost pure carbonate of magnesia and of commercial value if present in sufficient quantities. That summer, Boshart and McAllister found numerous outcrops, both of boulders and of bed rock, that gave promise of being magnesite of a commercial grade, and decided that this mineral deposit, if developed, would rival that at Veitsch, Austria. So they procured options on most of the land on which they knew the magnesite occurred. But the transportation difficulties were too great for the deposits to be mined at the prices offered for the product. In 1907, T. J. Waters organized the Canadian Magnesite Co. and opened a quarry on the north half of lot 18, range IX, and later on lot 15, range IX, of the same township. A lirnestone kiln was erected and the calcined rock was hauled to Calumet. In 1914, the North American Magensite Co, took over the quarries and shipped both crude and calcined magnesite until January, 1923. During 1915, S. Melkman organized the Scottish Canadian Magnesite Co. and opened a quarry on lot 15, ranges X and XI, Grenville township. A light, narrow-gage railway connects this quarry with the C. P. R. at Magnesite station. but shipments are made only during the summer months. Numerous other quarries have contributed to the output of the district but the greater part has come from the open pits of the

Jan 1, 1923

By E. L. Estabrook

THE production of crude oil in Wyoming rose to 44,290,010 bbl. in 1923 and declined, during 1924, to 39,295,030 bbl., a decrease of about 11 per cent. The Salt Creek field supplies 75 to 80 per cent. of the production. Pipeline runs from the Salt Creek field reached a maximum in November, 1923, at a daily average for the month of 116,437 barrels. During 1924, the gas pressure in Salt Creek has declined rapidly and the production dropped to about 60,000 bbl. per day. Part of &apos;the decline during the last few months was due to lack of power to pump the wells. The electric-power plant of the Midwest Refining Co. did not begin to deliver current until the middle of December, by which time several hundred wells were off production. The cold snap in December, which brought, the temperature down to 30° below zero on the 17th, tied up operations almost completely and the average production for the month was only 49,545 barrels. As more wells are being pumped and the number of dead wells reduced, the production is rising and was up to 61,000 bbl. during the last week of January. A further increase is expected as the weather becomes warmer. The production of Salt Creek, by months, during 1924 is given in Table 1. TABLE 1.-Total Monthly Production, Average Daily Production and Number of Producing Wells in Salt Creek during 1924 TOTAL PRODUCTION, DAILY AVERAGE, NUMBER OF MONTH BARRELS BARRELS WELLS January 3,523,647.40 113,666.05 919 February 3,074,916.67 106,031.61 929 March 2,977,095.14 96,035.32 950 April 2,811,110.22 93,703.67 987 May 2,858,842.04 92,220.71 1,024 June 2,649,752.57 88,325,09 1,092 July : 2,697,829.36 87,026.75 1,153 August 2,624,371.84 84,657.15 1,213 September 2,281,219.04 76,040.64 1,274 October 2,073,961.42 67,000.84 1,313 November 1,722,050.09 57,401.67 ~ 1,335 December 1,535,903.78 49,545.28 1,352 Total 30,831,699.57 84,239.61 1,352

Jan 3, 1925

By Sidney Powers

INTRODUCTION THIS paper aims to present the results of an investigation concerning gravitative differentiation in lava flows, based on a quantitative microscopic and chemical study of a Triassic basalt from Nova Scotia, and confirmed by data secured from a study of certain Keweenawan ophites. At Cape d&apos;Or, Nova Scotia, near the head of the Bay of Fundy, marine erosion has exposed a series of Triassic basalt flows in which copper has been sought for a number of years. Studies of the thickest flow of the series with regard to volumetric composition, specific gravity, and grain have been made by the junior author, and measurements by students at Tufts College, together with confirmatory observations of the same nature on this and other flows by the senior writer, and chemical analyses made by the Division of Mines, Mines Branch, Ottawa,1 all show differentiation in lava flows comparable to that in intrusive bodies. The work was made possible by the availability of the drill-cores, the property of Tufts College, and emphasizes the desirability of the study of drill-cores from other localities. Measurements of the specific gravities of certain Keweenawan lava flows of -Michigan by the senior author, from material collected in 1915, will be given as a comparison to those of the Cape d&apos;Or flow. It has been found that the specific gravity of drill-cores, or volume per cubic foot, can be readily obtained by measuring their dimensions. This can be done to an accuracy of within 1 per cent. in pieces of core over 100 min. in length by using a micrometer gage for the diameter, and taking the average of six measurements of the diameter; and the average of four measurements of the length made with a finely graduated ruler. Then, after weighing them, the weight in grains per cubic centimeter, or what is practically the same thing, ounces per cubic foot, is obtained. System-

Jan 2, 1916

By A. W. Hahn

ALTHOUGH enormous tonnages of sulfide lead and lead-silver ores are treated by flotation, the products of flotation mills treating oxidized ores of lead and silver are almost negligible. However, each year there is a slight tonnage increase, and it is possible, should a sizeable oxidized lead ore tonnage be developed, the field will become an important one. In 1918, the Shattuck-Arizona Copper Co. erected a plant at Warren, Ariz., for the treatment of oxidized gold-silver-lead ores. Glenn L. Allen worked out the metallurgy for this plant, employing tabling, followed by flotation concentration. The Shattuck-Denn Mining Co., successors to the Shattuck-Arizona Co., now employs straight flotation in the same mill, treating about 200 tons daily. In 1922, the San Diego mill of the American Smelting & Refining Co., in the Parral district, Chihuahua, Mexico, started operating a 600-ton mill on a mixed sulfide-oxide gold-silver-lead ore. Tables and flotation are used here, and about 200 tons of oxidized slime treated by flotation. In 1923, the Eureka Holly Mining Co. started operating a 90-ton mill at Eureka, Nev., using tables and flotation, on an oxidized lead-silver ore. In 1924, the American Smelting & Refining Co. started a 250-ton mill in northern Peru, to treat a high grade oxidized gold-silver ore with very low lead values. In 1924, the Grand Central Mining Co. started a 200-ton flotation mill on old oxidized gold-silver-lead tailings at Fairbank, Ariz. In 1926, the Compania International Minera, a subsidiary of the Union Corporation of London, started a 250-ton flotation mill on oxidized lead-silver ores, and during April of this year, the Phelps-Dodge Corp. will probably start a 250-ton mill at Warren, Ariz., on oxidized lead-silver ores, similar to those being treated in the Shattuck-Denn mill.

Jan 1, 1927