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By Matthew D. Viergutz

MECS? HRS technology has reliably recovered intermediate pressure steam from sulphuric acid plants for more than 20 years. This steam can either generate electricity or replace steam produced by an existing fuel-fired boiler. As worldwide greenhouse gas emissions continue to rise, industries are looking for novel and cost effective solutions to reduce pollution, particularly carbon dioxide, from their plants. Waste heat recovery technologies such as HRS offer new and existing plants the opportunity to maximize energy efficiency while reducing their reliance on energy supply from external sources. This paper offers a unique look at energy recovery in sulphuric acid plants and how recent innovations in MECS? Heat Recovery System technology make HRS more financially viable ? and more green - than ever.

Jan 1, 2009

By V. Sheikhzadeh, M. Saghaeian, N. Esmaeili, R. Hejazi, A. D. Ahmadabadi

The main challenges in most low grade iron ore deposits are finding the optimum flowsheet for beneficiation to achieve a final concentrate from both technical and economic viewpoints. Dry preconcentration techniques are being used to assist in reducing the amount of ROM feed to the plant. In this paper the benefits of utilising a dry cobbing magnetic separation technique for upgrading the product of HPGR in a closed circuit with dry screen 4 and 1.4 mm by performing a pilot scale test work was investigated. The experimental test work was done on two sample types of Yogi BIF magnetite iron ore located in Western Australia. Prior to magnetic separation studies, detailed characterisation of the feed materials including physical, chemical, mineralogical and magnetic properties were carried out. Furthermore, the effects of process parameters: drum rotation speed (1.5, 2.5 and 3.5 m/s), magnetic field intensity (1100 and 3800 gauss) and feed size (minus 4 and 1.4 mm) were investigated. The results revealed that sample type1 with 33.90% Fe could be upgraded to 41.51% Fe by using a stage of 1100 gauss dry magnetic separator with 69.12% weight recovery and 84.36% Fe recovery at a size of 4 mm. Also for sample type2, it is possible to increase Fe grade from 29.84% to above 36.68% with 75.58% weight recovery and 90.32% Fe recovery by applying one stage of 1100 gauss dry magnetic separator to a 4 mm size sample. Keywords: Banded iron formation (BIF), pre-concentration, dry cobbing technique, magnetic separator

Jan 1, 2020

By G. Akdogan, J. H. Zietsman, C. Dorfling, D. Attah-Kyei

The development of newer and improved electrical products has led to an increase in the rate at which older products are discarded as waste. The main focus of electronic waste is the printed circuit board (PCB) because of the inherently high value of contained metals such as gold and copper. Several options for treatment of the non-metallic fraction including material recycling, where the residue may be used as inclusions in concrete or asphalt materials with minimal processing or chemical recycling, where chemicals and fuels are produced from the residue using pyrolysis exist. In this paper, the utilisation of the non-metallic leached PCB waste fraction as reductant in secondary copper smelting was investigated. Analysis of the leached residue revealed that PCB is highly amorphous and has a carbon content of 28.5%, an oxygen content of 23.1%, with the ash and volatile matter contents 40.1% and 44.8% respectively. Thermodynamic simulations of secondary smelting of copper were conducted in terms of metal recovery, and the energy required when PCB was used as a reductant. The results were also compared with that of coal and PCB-coal blends. The simulations revealed that as PCB in the blend used as reductants increases, the amount of energy required for the smelting operation decreases. Metal recovery slightly decreased as the mass percent of PCB in the blend increased due to lower carbon content present in PCB relative to coal. The results also highlighted the energy saving with PCB-coal blends which was around 160 kWh per ton of feed relative to coal. The decrease in the amount of energy required for the operation is attributed to the higher volatile content of the PCB, which is also a part of the reduction process. Keywords: PCB leach residue, alternative reducing agent, secondary copper smelting

Jan 1, 2020

By Z. Tshentu, M. Ngayek, P. Moleko-Boyce

This paper is focused on the development of iridium(IV)-specific quaternary diammonium cations containing electron-donating substituents in the benzyl group of methyl and electron-withdrawing substituents such as triflouromethyl and nitro groups. Quaternary diammonium cations used were tetra- 4-methylbenzyl-1,10-diammonium decane chloride (QuatDMDAMeBnz), tetrabenzyl-1,10- diammoniumdecane chloride (QuatDMDABnz), tetra-3-trifluoromethylbenzyl-1,10- diammoniumdecane chloride (QuatDMDACF3Bnz) and tetra-4-nitrobenzyl-1,10-diammoniumdecane chloride (QuatDMDANO2Bnz). Polyvinylbenzylchloride (PVBC) nanofibres were used as support material, and the functionalised nanofibres were used for separation of Ir(IV) from Rh(III). The sorbent materials were characterised by FTIR and elemental analysis. The efficiency of the quaternary diammonium cations was investigated in a column study under dynamic flow adsorption conditions. Column sorption of [IrCl6]2- and [RhCl5(H2O)]2- on nanofibres functionalised with diammonium cations showed [RhCl5(H2O)]2- was not adsorbed by the sorbent materials while [IrCl6]2- was loaded onto the column. The loading capacities of [IrCl6]2- on the quaternary diammonium sorbent materials increased in the order of F-QuatDMDAMeBnz (3.08 mg/g) < F-QuatDMDABnz (3.39 mg/g) < FQuatDMDACF3Bnz (5.46 mg/g) < F-QuatDMDANO2Bnz (7.10 mg/g). The loading capacity for Ir(IV) with quaternary diammonium cationic nanofibres increased with an increase in the electron-withdrawing nature of the substituent on the quaternising group. The charge delocalising ability of the 4-nitrobenzyl group resulted in the best interaction of the decamethylene diammonium cation with [IrCl6]2-. Keywords: Iridium(IV), rhodium(III), quaternary diammonium, polymer nanofibres, separation

Jan 1, 2020

By B. Besa, S. Nalukui

Globally, the demand for mineral products is ever increasing. Extraction of these mineral resources results in the continuous production of a huge volume of waste material, including tailing dumps. The mass of tailings usually exceeds the actual resource and often contains hazardous contaminants. This study investigated the effects of tailings disposal on soil, water, and air quality in the Nampundwe area. Water, soil, and dust samples were collected from different locations in the surrounding communities. The constituents analysed in the samples included copper, cobalt, iron, sulfate, and silica. According to the results obtained, some seepages occurred from the tailings impoundment to the shallow aquifer in the area. However, the general water quality meets the Zambia Environmental Management Agency (ZEMA) statutory limits. Recorded concentrations of sulfate (1500 mg/l), copper (1.5 mg/l), cobalt (1.0 mg/l), iron (2.0 mg/l), and silica were between 0.003 mg/l and 705 mg/l, which is far below ZEMA’s statutory limit. Silica concentration was also evident in the air. The highest concentration recorded was 260 ppcc (particle per cubic centimeter) recorded in July 2019 from the northern direction of the tailings dam. The concentration was below the statutory limit of 350 ppcc. The topsoil from the northern part of the tailings recorded a silica dust concentration of 39.9 ppcc. Iron was evident in the underground soil with a concentration of 8.01 ppcc, cobalt 0.005 ppcc, copper 0.051 ppcc, while sulfate was recorded as 0.41 ppcc.

Oct 9, 2024

By J. Bullón, A. Pérez

Some years ago, Ferroatlantica developed a new type of electrode known as the ELSA electrode. In this electrode there is a central graphite core that provides support, surrounded by an annulus of Søderberg paste that gets baked during operation. This technology has been implemented on several silicon furnaces around the world, and was reported on during the previous Infacon conference. In all electrodes, but particularly in the ELSA electrode, the quality and consistency of the paste are important for correct operation. As the type of paste varies between customers and between countries, Ferroatlantica has developed a quality control procedure for their customers of this technology. This procedure is geared to the point of view of the customer rather than the paste producer. The analysis is based on the desired flow pattern of the raw paste and on the desired mechanical and electrical properties of the baked paste, as experience has shown that these are the most important parameters to monitor in order to avoid having problems with the resulting electrodes. This paper discusses these methods of paste analysis in the light of complementary studies that have been done when there has been an electrode breakage in the different plants.

Jan 1, 2007

By T. Mahlangu Mahlangu, T. Fungene, K. C. Sole

"Although oxygen is widely employed as the oxidant of choice in gold leaching by cyanide, its low aqueous solubility presents some drawbacks in practical application; hydrogen peroxide has therefore been considered as a possible alternative. The aim of this investigation was to study the catalytic decomposition of hydrogen peroxide, which generates an oxidizing intermediate species, and to understand its effect on cyanide destruction. Operating conditions that facilitated the effective decomposition of hydrogen peroxide were established by varying the pH and catalyst type and concentration. The oxidizing intermediate, detected using an indirect technique, was found to be the hydroxyl radical (OH?). OH? is commonly generated in acidic solutions, but this work demonstrated that it is also produced at the alkaline pH values necessary for cyanide gold leaching. The effects of free and complexed iron and copper catalysts on the oxidation and consumption of hydrogen peroxide and cyanide were also investigated. It was shown that the cyano complexes of Fe(II) and Cu(I) are also effective as decomposition catalysts. Hydrogen peroxide concentrations above 0.01 M decreased the free cyanide concentration, which was attributed to the probable formation of the cyanate anion (CNO-). Although cyanide consumption increased due to its oxidation in the presence of OH?, excessive cyanide consumption in the presence of copper was attributed primarily to its complexation by the unstable copper(I) cyanide species. Rate constants for the decompositions of H2O2 and cyanide by ferrocyanide and copper cyanide were calculated; the latter was identified as being a better catalyst. IntroductionLeaching of gold from its ores using cyanide has been employed for well over a century (Habashi, 2016). Addition of cyanide converts the gold into a cyanide complex (Au(CN)2 -) that is soluble in water (Wang and Forssberg, 1990). The leaching reaction can be represented as Equation [1]:"

Dec 1, 2018

By N. Snyders, I. Mwandawande, S. M. Bradshaw, M. Karimi

"Flotation columns are normally operated at optimal superficial gas velocities to maintain bubbly flow conditions. However, with increasing superficial gas velocity, loss of bubbly flow may occur with adverse effects on column performance. It is therefore important to identify the maximum superficial gas velocity above which loss of bubbly flow occurs. The maximum superficial gas velocity is usually obtained from a gas holdup versus superficial gas velocity plot in which the linear portion of the graph represents bubbly flow while deviation from the linear relationship indicates a change from the bubbly flow to the churn-turbulent regime. However, this method is difficult to use when the transition from bubbly flow to churn-turbulent flow is gradual, as happens in the presence of frothers. We present two alternative methods in which the flow regime in the column is distinguished by means of radial gas holdup profiles and gas holdup versus time graphs obtained from CFD simulations. Bubbly flow was characterized by saddle-shaped profiles with three distinct peaks, or saddle-shaped profiles with two near-wall peaks and a central minimum, or flat profiles with intermediate features between saddle and parabolic gas holdup profiles. The transition regime was gradual and characterized by flat to parabolic gas holdup profiles that become steeper with increasing superficial gas velocity. The churn-turbulent flow was distinguished by steep parabolic radial gas holdup profiles. Gas holdup versus time graphs were also used to define flow regimes with a constant gas holdup indicating bubbly flow, while wide gas holdup variations indicate churn-turbulent flow. IntroductionTwo types of flow can be distinguished in gasliquid flows in bubble columns: bubbly flow and churn-turbulent flow. The bubbly flow regime is characterized by uniform flow of bubbles of uniform size. Churn-turbulent flow, on the other hand, is characterized by a wide variation in bubble sizes with large bubbles rising rapidly and causing liquid circulation.Flotation columns are normally operated in the bubbly flow regime, which is the optimal condition for column flotation (Finch and Dobby, 1990; Yianatos and Finch, 1990; Ityokumbul, 1992). However, it has been generally observed that flotation column performance deteriorates when the superficial gas velocity is increased beyond a certain limit where the flow regime changes from bubbly flow to churn-turbulent flow (Xu, Finch, and Uribe-Salas, 1991). The identification of this critical or maximum superficial gas velocity is therefore important for optimal operation of flotation columns."

Feb 1, 2019

Dr Hanekom I would like to thank Dr Hanekom for a very valuable -contribution; it summarizes careful statistical test work which was an omission from the original paper. Minor manipulative details, the application of a finer measuring graticule and the reproducibility of the procedure are described and the author accepts with gratitude this ready-made answer to the first and second points of Dr Finkelstein&apos;s comments. Mr Williamson The author is indebted to Mr Williamson for historical background to early experiments with captive bubbles and it is conceded that the original paper described another avenue to an old flotation goal. The field of application is restricted and we would not work with all the material illustrated by Klassen and Mokrousov.1 The particles in Figure 74(a) are far too large and irregular; material in Figures (b) through (d) could be employed for semi-quantitative work in spite of obvious disadvantages; Figure 74(f) represents ideal conditions. We have studied this mineral-collector association in the size range given and results were satisfactory. For larger pick-up values than that illustrated an induction period of more than 0.01 second was required (actually 90 seconds for a maximum bubble load at pH 7.2 with 25 g/t oleic acid!). REFERENCE 1. KLASSEN,V. I. ANDMOKROUSOV,V. A., &apos;An Introduction to the Theory of Flotation,&apos; Butterworths, London, 128, Figure 74, (1963). Mr Slander and Mr Kooij Researchworkers in a practical mineral development laboratory may well ask what contribution yet another micro-technique can make to the problems of large scale ore flotation. The obvious answer is that there can be little or no direct translation of results obtained with a static system comprising air bubble and pure mineral concentrate to a dynamic multicomponent operation. However, for the rapid study of one mineral or variable some small scale apparatus must be employed. In the Anglo American Research Laboratory, the described semi-quantitative pick-up technique has filled a niche and requirement. For ourselves, the system represents a definite advance over the contact angle approach in that samples of minerals conventionally prepared in laboratory or plant may be used, which is a desired step nearer flotation. We bracket this pick-up apparatus with the Hallimond tube1,2 and evidence is now to hand that pick-up curves may often be related to flotation recoveries obtained from this tube with pure mineral samples and from the Fuerstenau glass cell3 with the total ore at low pulp densities. We would not wish to push the comparison of pick-up results past this stage for there is much published development work relating the Hallimond and Fuerstenau equipment to flotation on a larger scale. At the Anglo American Research Laboratory for example, a test in a Fuerstenau cell is often the final integrated step in laboratory investigations into the TORCO process. As these contributors rightly point out, pick-up tests can offer nothing towards the determination of optimum reagent dosage for large scale flotation. This is the function of bench-type flotation cells with up to 2 kg batches of ore. At this level, collector performance and consumption and physical properties of the froth are more comparable with large scale operation. The pick-up cell, Hallimond tube and Fuerstenau cell are essentially equipment from which the effect of control parameters can be derived. For the assessment of collector behaviour, the pick-up approach is rapid and economic and we offer here a pick-up contribution towards the flotation of Witwatersrand uraninite with anionic sulphonate collectors (Fig. 1). A large crystal of the local mineral was not available for contact angle measurements and owing to its low concentration in Witwatersrand gold-bearing reef, a small sample was laboriously obtained by tabling, superpanning and heavy medium separation. The pick-up values of a sized portion were determined by the described procedure in the presence of nine petroleum sulphonate collectors. Responses fell into two categories; "normal" curves (dotted lines) and a group of collectors which were very active at low concentration but showed depression of pick-up at the higher levels. The similarity in form of curves for collectors 1 and 3 was apparent and reagent 3 was found to be simply a diluent of 1. Otherwise, collector performance could not be related to either sulphonate content or molecular weight of the active constituent. However, reagent 2 gave the best performance in a bench flotation cell with regard to overall uranium distribution but, as predicted, reagent 1 yielded the best grades. Later pick-up tests with a similar class of collector have suggested that depression at high reagent concentrations may be due to "bubble armouring" whereby an hydrophilic air-liquid interface is produced which rejects mineral attachment. Prolonged investigations with the same mineral sample have not been required except for the study of uraninite which lasted for more than a year. Variation in pick-up response could not be detected over this period during which the mineral was stored under distilled water. The only visible change was a small efflorescence of lead sulphate, readily removed and decanted off after stirring with a glass rod in the sample tube. In its main role as a "trouble-shooter", the pick-up method is applied to fresh mineral samples taken from a flotation plant and soon discarded or from a current run in the ore-dressing laboratory. After production of a concentrate, a solvent cycle, as described in the original paper, may be required to remove heavy organics or other contaminants as when a sample has been taken from circuits containing detergents, grease or return flotation solutions. This solvent cycle will not remove chemisorbed collectors and we prefer not to work with minerals from flotation tailings or with pick-up cell discards. It has been thought preferable to answer the contributors&apos; other apprehensions with regard to sample preparation, activators, depressants and the physical properties of reagents in another paper on offer to this Journal. It covers pick-up investigations relating to the flotation of nickeliferous pyrrhotite at two Anglo American Corporation Mines, which approach seemed the correct orientation for a reply to another contributor to this paper.

By J. E. Gebhardt, B. Temel Mckenna, W. Lee, C. S. Macomber

X-ray diffraction (XRD) data was extracted from various sources to develop qualitative ternary and tetrahedral plots differentiating mineralogy, bond work index (BWi) and hardness of ore bodies at different mine sites. A large number of historic reports and compiled characterization laboratory data were used to create a searchable "data lake." The data lake provides a means to locate, consolidate, and visually represent XRD from disparate sources. Visualizations with large amounts of mineral ore XRD characterization data provide a qualitative assessment of ore properties, including comminution qualities such as material hardness. The visual map can be employed to quickly estimate expected ore character and behavior, given XRD analysis of samples from newly characterized and unfamiliar ore. Keywords: Mineralogy, Characterization, Comminution, Database, Ternary, Tetrahedral

Jan 1, 2020

By D. F. Malan, R. P. Els

The limit equilibrium model, used in displacement discontinuity codes, is a popular method to simulate pillar failure. This paper investigates the use of physical modelling to calibrate this model. For the experiments, an artificial pillar material was prepared and cubes were poured using the standard 100 mm × 100 mm civil engineering concrete moulds. The friction angle between the cubes and the platens of the testing machine was varied by using soap and sandpaper. Different modes of failure were observed depending on the friction angle. Of interest is that significant loadshedding was recorded for some specimens which visually remained mostly intact. This highlights the difficulty of classifying pillars as failed or intact in underground stopes where spalling is observed. The laboratory models enabled a more precise calibration of the limit equilibrium model compared to previous attempts. Guidelines to assist with calibration of the model are given in the paper. The limit equilibrium model appears to be a useful approximation of the pillar failure as it could simulate the stress-strain behaviour of the laboratory models.

May 3, 2023

By B. A. Obadele, R. Machaka, M. L. Raganya, M. E. Makhatha, N. A. Moshokoa

The influence of solution treatment on the phase evolution and tensile properties of Ti-Mo alloys was investigated to assess their potential use in biomedical applications. Phase formation and microstructural evolution were studied using X-ray diffraction (XRD), optical microscopy (OM), scanning electron microscopy (SEM), and electron backscatter diffraction (EBSD). The mechanical properties were characterized by means of tensile tests and bending strength. XRD analysis showed that solution treatment increased the volume fraction of β phase and supressed the α" phase. The microstructures of the as-cast alloys consisted of β equiaxed grains with sub-grain structures of different sizes, while the solution treated alloys comprised β equiaxed grains only except for Ti- 10.02Mo, which comprised needle-like α" structures. EBSD showed an increase in the volume fraction of the ω and α" phases in all the alloys after solution treatment. The elastic modulus and UTS of all the alloy significantly decreased after solution treatment, except for Ti-15.05Mo,whereas the elongation significantly increased. The fracture surfaces of all the alloys after solution treatment indicated more ductile behaviour than brittle

Jun 10, 2024

By T. Mützea, L. Schützenmeister, G. Kacheb

High-Pressure Grinding Rolls (HPGR) are employed in cement plants worldwide. Although the technology has been mastered in the majority of applications, design-, scale-up- and operationalchallenges still exist today. In addition to modelling throughput, energy requirement and comminution success, the prediction and avoidance of malfunctions is of great importance in current research. The performance of the mill is highly influenced by the roll speed and the fineness of the feed material. Another parameter influencing the composition of mill feed is the circulating load, which is determined by the grinding circuit configuration, the target fineness and the separation efficiency of the classifier. In order to meet this circumstance and simultaneously maintain a reasonable level of material input and testing effort, a complete grinding circuit on a small technical scale was set up in the research centre of Thyssenkrupp Industrial Solutions AG. The present study varied the roll speed (0.5-2 m/s) and the proportion of fines in the feed (0-75 %) in order to investigate the influence of both parameters on the finish grinding of a Portland cement with a target fineness of 4000 cm²/g according to Blain. The experimental results are compared with model concepts and critically examined with regard to their transferability to industrial plants. Keywords: Cement grinding, grinding circuit, HPGR

Jan 1, 2020

By I. Mitov, A. Stoilova, D. Krastev, B. Yordanov

We present three technological scenarios for the recovery of valuable components from gangue, stored in the tailings dam at Kremikovtzi metallurgical plant in Bulgaria, into marketable iron-containing pellets. In the first approach the iron concentrate was recovered through a two-stage flotation process, desliming, and magnetic separation. In the second proposed process, the iron concentrate was subjected to four sequential stages of magnetic separation coupled with selective magnetic flocculation. The third route entails the not very common practice of magnetizing roasting, followed by selective magnetic flocculation, desliming, and magnetic separation. The iron concentrate was pelletized in a laboratoryscale pelletizer. Each technology has been assessed with regard to the mass yield of iron concentrate, the iron recovery. and the iron, lead, and zinc content in order to identify the most effective route.

May 1, 2021

By J. Hadjigeorgiou, T. R. Stacey

This paper introduces the Quantified Value-created Process (QVP), a decision-making process for use in mine design and operation. The implementation of the QVP is founded on a ten-step rock engineering design process and a ten-step strategic planning process. The potential of this approach is demonstrated by examples of value created as a result of good research, design, and planning. The QVP is divided into two parts, namely, a ‘planning the process’ section and an ‘implementing the process’ section, and can be considered to be an extension of the risk approach. All costs, direct and indirect, associated with a significant mining decision (design, operational, investment) must be quantified in advance of committing to that decision, to determine the value that will be created in the short, medium, and long terms. Ethical values, associated with health, safety, the environment, public perception, and social aspects, may be difficult to quantify in economic terms, but must nevertheless also be considered. In contrast with a traditional risk approach, the QVP will identify the upside, and allow executives to make more informed strategic decisions. In this context it is essential to actively engage upper management in the decision process.

Feb 2, 2022

By R. D. Alorro, B. Tadesse, E. Aghaei

Cinnabar (HgS) and native mercury (Hg) are the most common naturally occurring forms of mercury found in most gold ores subsequently released into the environment during processing. Mercury and its compounds are extremely toxic and recognised as serious health and environmental hazards. This research investigates the possibility of mercury (Hg) removal from waste solutions from gold processing using iron-aluminium (Fe-Al) bimetallic particles. The synthesis of Fe-Al bimetallic particles using zero-valent aluminium and ferric chloride as precursors were performed following the optimisation of influencing factors. The presence of both metals in the prepared bimetals was confirmed by XRD analysis. The experiments for mercury removal by bimetals were designed using the central composite design and Minitab software based on two variables including contact time and adsorbent dosage. The best result of Hg(II) removal (>90%) was achieved using 4 g/L bimetals and contact time of 75 min. However, the statistical analysis of results indicated that these parameters have only a minor contribution to the removal of Hg(II) by Fe-Al bimetals. Higher bimetal dosage and contact time resulted in a higher Fe dissolution from the Al surface which can be attributed to the presence of nitrate (# $) ions in the solution. However, adding 0.1 M NaCl to the Hg solution had a positive impact on Hg removal by improving the conductivity and electron transfer within the solution. The Fe-Al bimetallic particles are promising substances for further testing of Hg removal from gold processing waste solutions with different conditions and constituents. Keywords: Mercury removal, gold processing, Fe-Al bimetals, optimisation

Jan 1, 2020

By R. T. Rudd

DISCUSSION R. T. RUDD I have the following comments on Mr Bosman&apos;s paper. Before giving the company permission to discharge neutralized mine drainage containing 1800 mg/l of dissolved solids into a public stream, my Department had to consider the matter from both the legal and the practical viewpoint.

Jan 4, 1974

By T. Bhambhani, E. Arinaitwe

Solvay has developed several novel reagent innovations to improve separations in sulfide ore flotation and address major industry challenges. These innovations include: a) carbon management strategies to reduce the deleterious impact of organic carbon on flotation circuits; b) new collectors for heavily tarnished or oxidized Cu-Au ores; and c) a functionalized depressant for minimizing penalty elements in metal concentrates. Owing to their unique chemistries, these innovations exhibit a wide spectrum of rather unique properties that are quite in contrast to the traditionally used reagents. The chemistry, attributes, application, and advantages of these innovations are discussed in this paper based on laboratory, pilot, and plant results and observations for various ores

Jan 1, 2023

By A. Santana, J. Jankolovits, G. S. Reyes

The flotation of sulfide ores that contain carbonaceous gangue requires significant operational and chemical intervention to achieve suitable metallurgical outcomes. Carbonaceous gangue dilutes concentrate grades, alters the froth behaviour, reduces operational stability, adsorbs reagents, and reduces value recovery. Carbon management processing strategies like preflotation and depression are often presented as point solutions. Moreover, oversimplified mechanisms of carbon depressants belie their complex and nuanced impact on flotation behaviour. Optimising the flotation of carbonaceous sulfide ores requires a holistic consideration of interactions between the carbon management reagents and the processing strategy, ore mineralogy, flotation behaviour, flowsheet, and all other aspects of the flotation system. Examples are shown where conventional, simplistic mechanisms of carbon depressants fail to explain the observed flotation behaviour. The multifaceted impacts of carbon depressants on froth behaviour, collector performance, and value recovery highlight the need for a holistic approach to carbon management. Keywords: Carbon management, carbonaceous ores, sulfide flotation, carbon depressant

Jan 1, 2020

By H. Manurung, I. M. Bendiayasa, W. Astuti, and H. T. B. M. Petrus, F Anggara, K. C. Wanta

The leaching kinetics of cerium (Ce) and yttrium (Y) in sodium-hydroxide-digested non-magnetic coal fly ash using acetic acid were investigated. The variables analysed were pH, solid-to-liquid ratio (S/L), and temperature. The results show that cerium and yttrium's maximum recovery was 57.33% and 58.36%, respectively, under leaching temperature of 90°C for Ce and 60°C for Y at pH of 1,74 and 10 g/mL solid-liquid ratio in 240 minutes. Increasing the leaching time to more than 120 minutes did not significantly improve the results. After the magnetic separation process, the ICP-OES analysis shows a slight increase in the concentration of cerium and yttrium on nonmagnetic components. The XRD and ICP-OES analysis for the sample before and after silicate digestion shows that 40% silicate was dissolved. The calculation of apparent activation energies of leaching using the Arrhenius law for the leaching of cerium and yttrium gives 22.72 kJ/mol and 35.84 kJ/mol, respectively. The kinetic leaching model of cerium and yttrium all fit Dickinson's new shrinking core model. The calculation results show that the leaching reaction is controlled by combining interface transfer and diffusion across the product layer.

Nov 6, 2024