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By Ray J. Holmquist

"INTRODUCTION The Elk Mountain mica deposit was examined in June 1943 by the Bureau of Mines. An exploratory project and an access road for the property were recommended, provided the zinc was put in operation under competent management. K. Garard obtained a lease on the properly and started operations in June 1944; this was followed immediately by the Bureau's exploratory work. Road construction was begun by the Forest Service in July the same year.The lessee mined mica from the richest exposure with a crew of three men for 2-1/2 months. His operation terminated late in September, but the Bureau of Mines project and the Forest Service road construction continued until snow forced suspension of activity during the first week of November.The Bureau of Mines work consisted of trenching with a bulldozer, hand excavating on undeveloped outcrops, extending an existing adit, and starting a new adit below the older workings."

Jul 1, 1946

By Irving Kabik

Chlorates and perchlorates, when mixed with certain reducing materials, may give a detonating explosive of considerable power. Concerning explosive chlorate mixtures, Guttman3/ states that they "have at all times fascinated inventors on account of the large amount of oxygen stored up in potassium chlorate, which can be given off so readily. When Lavoiser and Berthollet tried to make a chlorate powder in a stamp mill in 1788, they made a great show of it, and even two ladies were present. Unfortunately, after a certain amount of pounding the powder exploded and killed an official and the daughter of the Government commissary, who assisted at the experiments.***. It is interesting to observe how the same old mixtures are proposed over and over again with slight alterations only, in order to qualify for a patent. Potassium chlorate with some carbonaceous matter like charcoal, sugar, starch, glycerin, flour, or sometimes a vegetable or mineral oil and the like occurs again and again." Sprengel explosives, in which some of the undesirable sensitivity of the chlorate was minimized by coating the crystals with a liquid reducing agent, received some attention after a patent was issued to Dr. Herman Sprengel in England in 1871.4/ A somewhat similar explosive, known as Rack-a-

Jan 1, 1945

By J. A. Organiscak

The U.S. Bureau of Mines investigated the relationship of bituminous coal seam parameters and the amount of airborne respirable dust generated at longwalls. Dust and coal samples were obtained from 20 longwalls operating in geographically representative coalfields throughout the United States. Statistical analyses of coal seam parameters and airborne respirable dust measurements indicate a likely causal relationship between seam type and respirable dust. Low-ash, high-volatile coal seams were associated with higher airborne respirable dust levels. A negative linear correlation (significant at the 95-pct confidence level) was observed between the seam's ash content and airborne respirable dust, explaining up to 18 pct (R2 = 0.18) of headgate dust level variation and up to 15 pct of tailgate dust level variation. Volatile matter was found to have a positive linear correlation with tailgate dust level, explaining 16 pct of the variation. Further data examination indicates that these relationships with dust are most likely nonlinear, because of improved R2 values over the linear correlations. However, a notable portion of longwall dust production is influenced by other operational parameters, so additional research under more controlled conditions is needed to determine the seam's causative functions.

Jan 1, 2010

By R. Barany

Thermodynamic calculations pertaining to the minerals gibbsite, kaolinite, halloysite, and dickite have been hampered by the lack of adequate heat and free energy of formation data. Previous data for gibbsite were highly uncertain, and there were no data for the other three substances. By use of hydrofluoric acid solution calorimetry, the Bureau of Mines derived heat of formation values from the elements and from the oxides for the four substances, and the data were combined with known entropy values to obtain the corresponding free energies of formation. The results show that gibbsite and halloysite are thermodynamically unstable with respect to the oxides (a- alumina, a- quartz, and liquid water) at 298.15° K,, while kaolinite and dickite are only moderately stable (to about the same degree), The instability of halloysite, in comparison with kaolinite and dickite, results in a 60°-lower equilibrium decomposition temperature.

Jan 1, 1961

By David C. Scott

Between 1990 and 1991, the Bureau of Mines studied the mineral resources of the Kaibab National Forest to appraise the resources present and to determine the types of deposits, and their location. The study included a comprehensive literature search and a limited amount of field investigation of minerals and mining activity in and near the Forest. Small amounts of copper with lesser amounts of gold and silver have been produced from limestone-hosted, strata-bound deposits in the North Kaibab and Tusayan Ranger Districts. In addition to these small metallic deposits, volcanic cinders, pumice, flagstone, and sand and gravel have been quarried in the Chalendar and Williams Ranger Districts. At least ten uranium-mineralized breccia pipes have been identified in the Tusayan Ranger District, One of these, the Canyon pipe, contains a high-grade uranium ore body with associated silver, copper, lead, vanadium, and zinc. The mine permit for the Canyon pipe has been approved and the mine shaft head frame erected.

Jan 1, 1992

By Peter H. Toepfer

This report presents the factual data obtained by the Bureau of Mines during diamond-drilling investigation of the Sunset copper deposit in the Index mining district, Snohomish County, Wash. The Sunset mine, first produced copper ore in 1902, but its main period of activity was from 1923 through 1930, The mine has produced 263,500 tons of ore, from which 1,500 ounces of gold, 156,000 ounces of silver, and 12,912,000 bounds of copper-were recovered. The mine has, been idle since 1946

Jan 1, 1953

By Thomas A. Phillips

An economic evaluation of the Bureau of Mines process for the separation of raw urban refuse into its metal, mineral, and energy components is presented. The process recovers ferrous metal, mixed nonferrous metals, aluminum, mixed-color glass cullet, and refuse-derived fuel products from raw refuse. Data for this evaluation were obtained from selected runs at the Bureau's pilot plant in Edmonston, Md. A cost estimate was prepared for a plant capable of processing 1,000 tons per day of raw urban refuse operating two shifts, 6 days per week. The fixed capital cost, based on second quarter 1976 equipment costs, is approximately $14.5 million excluding land and shipping containers. The estimated operating cost is approximately $8 per ton of refuse processed. This does not include credit for the products, transportation of the products, a tipping fee, or a dumping fee for wastes produced. No finance charges or taxes are included in the operating costs.

Jan 1, 1977

By J. B. Gayle

Although heated circuits frequently have been employed in the conditioning stases of certain flotation processes, particularly the flotation of fluorite, the control of temperature is not generally considered economically feasible for the flotation of coal. This viewpoint, although widely held, can neither be substantiated nor refuted by reference to published data. Some evidence is available, however, that temperature is an important variable in the floatability of coal as well as other minerals. For example, Gayle and Swelley4 found that contact angles for coal and related substances were definitely dependent on temperature. Bailey and Whalan5 showed that changes in pulp temperature may exert a pronounced influence on recoveries of coal in batch flotation tests. The present laboratory-scale investigation was undertaken to obtain information about the effects of changes in pulp temperature on coal flotation recovery and also on the selectivity of separation possible using different reagents. The results indicated that flotation recoveries were markedly affected by temperature variations when certain reagents, particularly simple aliphatic alcohols, were used. For other reagents, particularly kerosine, flotation recoveries were substantially independent of variations in pulp temperature. Release-analysis results indicated that temperature variations did not greatly affect the selectivity of separation possible with the reagents tested.

Jan 1, 1961

By G. A. Smyres

A GaC12--B2 l-eachtng procedure and meEal-recovery method for treating an arsenical Cu-Co sulfide concentrate was developed by the Bureau of Mines as an alternative to smelting, which is no longer considered an environmentally acceptable method for treating arsenic-containing ores. The procedure involved leaching in a CaC12 solution with CaC03 for 96 h at 26 pct solids (concentrate and CaC03), 1150 C, and a pressure of 50 psig (345 kPa) with oxygen. More than 98 pct of the cobalt and 97 pct of the copper were extracted, and 99.98 pct of the arsenic and 99.9 pct of the iron remained in the leached residue. A filtration rate of 2.9 gal/(ft2.h) [118 L/(m2.h)] and a cake formation rate of 36 Ib/(ft2.h) [172 kg/(m2.h)] were obtained by filtering reacted pulp at 1000 C. More than 99 pct of the copper in the pregnant solution was extracted as CuCl2 by golvent extraction with a new copper extractant. Copper was stripped from the loaded organic with a sulfate-chloride solution, which was used as the anolyte for electrowinning of copper in a membrane cell. Copper plate produced was more than 99.99 pct pure and requi.red 0.81 (kW'h)/lb Cu [1.78 (kW·h)/kg Cu]. Cobalt sulfide was precipitated at pH 3 with Ca(HS)2.

Jan 1, 1986

By John E. Shelton

The growing interest in beryllium as a structural material, and its in-creased use in recent years for atomic energy application, have led both government and industry to express concern over the inadequacy of the beryllium resources in the United States and the free world. Contemplated and proposed uses for this unique material will surpass the capacity of the domestic beryllium mining industry to supply raw material, which is presently extracted from relatively small deposits by hand sorting. The need for a simple beneficiation process for beryl ores has long been recognized by the Bureau of Mines, but to date no single process has proved satisfactory for treating deposits containing a sufficient tonnage of beryl ore to warrant commercial exploitation. As a part of the Bureau's continuing effort to develop an economical recovery process, this report describes flotation research on samples of beryl-bearing pegmatites from the George Roebling mine in Connecticut, and the Colony mine in New Hampshire. The study resulted in two methods of treatment to which the ores responded reasonably well.

Jan 1, 1961

By Kathleen M. PH. D. Kowalski

This paper discusses human judgment and decision-making under stress. The authors review selected recent literature across various disciplines and suggest a definition of stress within the context of decision-making during the management of emergencies. They also discuss fieldwork by the Pittsburgh Research Laboratory, NIOSH, which explores traumatic incident stress, the relationship between previous training and performance under stressful conditions, and human behavior in underground mine fires. The authors assert that stress is one of the factors that decision-makers must contend with in most life-or-death situations. They suggest that a better understanding of individual's judgment and decision-making activities while under stress would yield a better understanding of how people reach the choices they make in emergencies. This enhanced understanding would be of enormous value to emergency managers, researchers, and policymakers.

Jan 1, 2008

By D. Harrington

The prevention of accidents to children from blasting cans is of vital importance not only to everyone using commercial explosives but to the country at large. The manufacturers of explosives have realized this danger for years and have attempted to publicize the hazards of allowing blasting caps to fall into the hands of children. Unfortunately, many of tie users of explosives have failed to realize the danger or have ignored their responsibilities in the matter. Investigations of accidents to children from blasting caps (and scores of them occur annually) reveal that most of them are caused by blasting caps picked up or made easily accessible to the victims. The children who are blinded, maimed for life, or killed are in large part the innocent victims of the carelessness, thoughtlessness, or negligence of their elders, by whom blasting caps are left lying about, carried in the pockets, dropped or lost around blasting operations, stored away and forgotten, or left in places where trey can be found or are accessible to children. Many such accidents occur to children under 12 years of age, when they are still curious or inquisitive. One of the first reactions of a child upon finding a blasting cap is to investigate and "see" how it is made or how it "works." A blasting cap in itself, with one end open, invites a child to poke it with a nail, piece of wire, or some other object to see what is inside; or he may attempt to break it open with a rock or hammer. A lighted match could be thrust into the open end, and there are numerous other approaches, may of which can result in serious accidents.

Jan 1, 1944

By D. Harrington

"In at least three out of every four working faces in metal mines there is no attempt made to cause air circulation other than by use of compressed air, and in at least nine cases out of ten the compressed air is released merely by opening, or partly opening, the valve and allowing the compressed air to escape through open air hose used to convey the compressed air to the drilling machines. Usually no blowers are in use during periods of drilling, as the exhaust from the drill provides cool, comparatively fresh air for the driller; however, in some instances, the compressed-air line is provided with a tea connection, which permits taking air for the drill from one side of the tee, and air for ventilation through a separate hose used as a blower, simultaneously with drilling.Table 1 contains temperature and humidity data as to compressed-air blowers from open end of air hose at 36 working places in eleven metal mines of four States, embracing the mining of gold, silver, copper, lead and zinc ores, and at horizons ranging from 500 feet below the surface to as low as 4900 feet.It is noticed that the ordinary air surrounding the worker at the face gives an average wet bulb temperature of 81.7° F. for the 36 working faces, with 84.7° F. dry bulb and 87.2 per cent relative humidity. The average wet bulb tem¬perature of 36 readings at these working faces of compressed air at the end of the,hose as the air issues from the hose was 67.4° F., or 14.3 degrees lower than the average wet bulb readings of the air of the working places; however, the average dry bulb temperature of the 36 readings of compressed air as it issued from the end of the hose was 79.7° F., or only 5 degrees less than that of the general air (84.7°); the relative humidity was 51.1 per cent as against 87.2 per cent for the surrounding air. Readings were taken in five raises, seven crosscuts, ten drifts and 14 stopes.It will be noted that the velocity or movement of the general atmosphere at each of the entire 36 working faces, was found to be practically imperceptible; this might readily be inferred since compressed air is rarely used on blowers if there is adequate circulation of the general air of the place. Where rook temperatures could be obtained readily, they are shown; it is noticeable that the dry bulb temperature of the air of the working place varies little from the rock temperature, and that the dry bulb temperature of the compressed air as it issues from end of air hose varies only a few degrees from the temperature of the surrounding rock; in some instances the dry bulb temperature of the compressed air as it issued from the end of the air hose was higher than the rock temperature or the dry bulb temperature of the surrounding air."

May 1, 1921

By John P. McDonnell

Coal mine bounces and bursts are major problems facing U.S. mine operators. Bounces and bursts have the potential to inflict severe injury on mining personnel, damage equipment, and cause mine closures. High- stress conditions, at or near the working face, are the common denominator in the burst problem, If mine operators can locate high-stress and potentially burst-prone zones, they can then use stress-relief methods to control the burst condition. One method of locating the high-stress zone is the probe-hole-drilling or drilling-yield method. Probe-hole drilling is used frequently in Europe, the U.S.S.R., and Japan as a means for locating potential burst zones. Consequently, the Bureau of Nines performed tests in the laboratory and in a deep, burst-prone western mine to analyze probe-hole drilling. The in-mine method, very simply, involves drilling a hole into the coal seam and measuring the volume of cuttings obtained. A certain volume of cuttings can be expected from a certain diameter and length drill hole. A significant increase in the volume of cuttings means the zone around that particular hole is highly stressed. In-mine use of the drilling yield method has shown it to be a useful tool for locating highly stressed and potential burst zones. Results from laboratory testing confirm that high stress applied tri-axially to a cube specimen will cause a significant increase in the volume of cuttings from a small-diameter drill hole in the specimen.

Jan 1, 1988

By N. S. Dalal, X. Shi

"Electron spin resonance measurements provide evidence for the formation of long-lived Cr(V) intermediates in the reduction of Cr(Vl) by glutathione redtuctase in the presence of NADPH and for the hydroxyl radical formation during the glutathione reductase catalyzed reduction of Cr(Vl). Hydrogen peroxide suppresses Cr(V) and enhances the formation of hydroxyl radicals. Thus Cr(V) intermediates catalyze generation of hydroxyl radicals from hydrogen peroxide through a Fenton-like reaction. Thus the mechanism of Cr(VI) toxicity might involve the interaction between macromolecules and the hydroxyl radicals.C(Vl) compounds have been found to exert serious toxic and carcinogenic effects on humans and animals (1-3). In contrast, most Cr(III) compounds are relatively nontoxic, noncarcinogenic, and nonmutagenic (1,4). Cr(VI) and Cr(III) oxidation states are different in their metabolic pathways: Cr(VI) , ions are rapidly transported across cellular membrane (1,4,5), while Cr[III) moieties do not easily penetrate cells and are not oxidized by cellular constituents (!). Since it is known that the reduction of Cr(VI) ion is required for its reaction with DNA (1), the molecular mechanisms for the intracellular Cr(Vl) reduction has been the focus of current studies but the details are still not understood.Earlier studies on the mechanism of Cr(Vl) reduction include those on the reduction of Cr(VIJ by glutathione (GSH) .0,6-8), ascorbic acid (9), glucose (10), lactose (IO), galacturonic acid (11), microsome (12), and mitochondrial electron transport chain complexes (13). These studies have shown that the Cr(VI) reduction involves the formation of Cr(V)-containing species which are often considered to be the toxic form of chromium. Thus far, however, no information is· available on the subsequent fate of those biologically formed Cr(V) species, in particular employing well defined biochemical systems. In this context, we report here our investigations of the reduction of Cr(VI) by glutathione reductase (GSSG-R). This enzyme was selected because it is ubiquitously present in cellular systems and it has been postulated to be involved in the Cr(VI) reduction (14-17) but the underlying mechanism has not been clarified. We find that the reduction proces·s involves not only Cr(V) but also ·OH radicals. We further investigate the reactivity of Cr(V) and find that it catalyzes generation of OH radical from H2O 2 through a Fenton-like reaction. The role of ·OH in Cr(VI) carcinogenicity is suggested from this study."

Jan 1, 1989

By E. A. Pelczarski

Initially, the objective of this contract was to develop a PWSCSR that could meet proposed criteria (that were different from 30 CFR 11(Title 30 of the Code of Federal Regulation part II) and that would be less than twice the size and weight of a filter self rescuer. This objective was met. Consequently, the original contract was extended to develop a PWSCSR that would meet existing CFR-30 criteria within the same size and weight constraints. This resulted in the development of a PWSCSR (the SR-100) that received NIOSH/MSHA approval (TC-239). This report presents a historical discussion of the design and development of the SR-100 as developed by CSE Corporation under Bureau of Mines contract number H0368013. The technical parameters and the test results of NIOSH/MSHA 30 CFR 11 certification are also presented.

Jan 1, 1990

By Oliver Bowles

The wire saw, introduced by the Bureau of Mines about two years ago, has revolutionized slate quarrying in Pennsylvania. The success of the saw since its early accomplishments has become greater and greater as the equipment has been perfected and skill acquired .in its use. In the first test made, a cutting rate of 9.7 square feet per hour was attained; in the next four cuts, made early in 1927, the average rate of cutting was increased to 12.8 square feet per hour; in 1928 a maximum of 34 square feet per hour had been attained, with a general average of about 20 to 25 square feet, The wire saw is now regarded as essential equipment in practically all of the quarries in the Bangor, Pen Argyl, and Windgap districts. The wire saw consists of a three-strand steel cable of 3/16 or 1/4 inch diameter running as an endless belt. The driving pulley is a 40-inch double-groove cast-iron sheave. A tension pulley supported by a frame mounted on wheels may travel back and forth on a short track. A weight of 800 to 2,000 pounds gives the desired tension on the wire. The driving units consist of electric motors with direct-drive compactly enclosed gear reduction, or double-belt speed-reduction units; the former is preferred. Silent chain and. pinion gear reductions are used to a limited extent. The travelling speed of the wire is about 15 feet per second. The driving and tension equipment are shown in Figure 1, A.

Jan 1, 1929

By Louis C. Brichta

The Kline tract ?3.nd the Frey tract are two separate properties situated in the Wentworth district on the easterly edge of the Tri-State zinc-lead region (fig. 1). The Kline tract is in the southwestern corner of Lawrence County, Mo., and the Frey tract, 1 1/2 miles west of the Kline, is in the northeastern part of Newton County, Mo. A bureau Of Mines drilling project embraced work on both properties, but the amount of work done on the Frey tract was comparatively small. At the time of the project the Kline tract was under lease to the Wentworth Mining & Milling Co. The Surprise Mining Co. held the lease on the Frey tract. Underground workings on the generally flat-bedded are deposits of the Kline property-covered an area of-about 15 acres. No total metal-production records are available. In 1942-1943 the mine, operated by the Wentworth Mining & Milling Co., produced at an average monthly rate of 83 tons of 60-percent zinc concentrate derived from mining and milling 1,700 to 2,100 tons of ore. At the end of that period no significant amount of reserve ore was in sight. The gravity-flotation mill on the property was operating at about one-sixth capacity.

Jan 1, 1949

By C. Thomas Hillman

This Bureau of Mines report describes an investigation of factors influencing economic viability of a proposed system to mine and process manganese nodules. The system consists of hydraulic dredging and ammonia leach processing designed to recover three metals: nickel, copper, and cobalt. A ferromanganese recovery plant is a considered option. Annual capacity is 3 million dry metric tons (t) nodules. Aftertax rates of return (ROR's) of only 7.38 and 6.63 pct are predicted for three-and four-metal base scenarios, respectively. Sensitivity analyses indicate that variations in commodity prices, metal recoveries, and deposit grades produce similar incremental changes in ROR. Estimated cumulative effects of price variations are greatest. While three-metal operations generally yield higher predicted returns, potential increases in manganese price and process recovery could make four-metal operations most profitable. Maximum variations in both capital costs and three-metal operating costs result in ROR changes of about 25 pct. In contrast, four-metal ROR's exhibit variations to 70 pct. Even so only a best case analysis, utilizing favorable variations in all categories tested, generated ROR's approaching a level thought necessary to trigger company interest. Consequently, it is concluded that nodule mining will not take place in the foreseeable future without significant financial incentives.

Jan 1, 1985

By D. A. Larson

This is the second in a series of Bureau of Mines reports which de-scribe experiments designed to devise an efficient, economic mechanical fragmentation technique for hard rock. The previous study described the development of the ripper cutting technique to successfully cut hard rock with 3-to 6-in-wide drag cutters. This study was conducted to test the ripper cutting technique at full scale using 9-in-wide drag cutters. The experiments were conducted with a special test device that cut shallow, 6-by 6-ft openings in 9,200-lbf/in2 compressive-strength concrete blocks. The tests showed that ripper cutting can excavate large-scale openings of the type required by the mining industry at a production rate that outperforms the conventional drill-blast technique. Moreover, the system can produce openings of various sizes and shapes, is simple to oper-ate and maintain, and produces very little dust or noise during operation. The system appears to meet all of the criteria for a successful hard-rock mining machine.

Jan 1, 1987