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By X. J. Lu

Purified Na-montmorillonite samples were used as the starting materials to prepare organically modified montmorillonites (OM), and a series of OM samples were prepared by intercalation of al-kyl quaternary ammoniums with different alkyl chain length. The interlayer spacing (d001) of the OM was determined by small angle X-ray diffraction and its gelating performance was characterized by measuring the viscosity of OM/dimethylbenzene mixture. The effects of alkyl chain length, dosage of alkyl ammonium, intercalation duration and layer charge of the starting material on the OM structure and gelating properties were investigated. According to the results, the adsorption quantity of the alkyl ammonium is dependent on the hydrocarbon chain length, the dosage of the alkyl ammonium and the retention time. The adsorption quantity of the alkyl ammonium increases with the chain length and the dosage, and extra adsorption more than the CEC of the montmorillonite sample was observed under the dosages of more than 1.3 CEC. The interlayer spacing (d001) of the OM shows a dynamic variation with the dosage and the retention time, and super interlayer spacings greater than the length of the alkyl ammonium were observed under larger dosages and shorter retention times. However, the gelating performance of OM does not follow the variations of the adsorption quantity of alkyl ammonium, an optimum viscosity value of OM/ dimethylbenzene gel was observed with the moderate adsorption of the alkyl ammoniums. Furthermore, the layer charge plays an important role on the gelating performance of OM. The OM synthesized by the starting material with lower layer charge shows better gelating performance in the dimethylbenzene solution.

Jan 1, 2014

By S. Castro, L. Uribe

Seawater can be considered as a particular process water with a high concentration of NaCl (about 0.5- 0.6 mole/L) and high concentration of hydrolyzing metal cations (mainly, Mg2+ and Ca2+ ions). Micro-flotation tests, induction time measurements, and zeta potential measurements have been used to investigate the effect of these ions on the natural floatability of molybdenite. The results demonstrate that molybdenite is strongly depressed in the alkaline pH range over which hydrolysis products of Mg2+ and Ca2+ ions are formed. At pH 10, colloidal magnesium hydroxide seems to be responsible for molybdenite depression in seawater and in Mg2+ solutions. This is also supported by the measurements of the effect of Mg2+ ions on the zeta potential of molybdenite. The mechanism of depression of molybdenite with Ca2+ ions is different, and depression takes place in the pH range were Ca(OH)+ complexes are formed, below the pH of precipitation of calcium hydroxide. Adsorption of the cationic hydroxy species and/or hetero-coagulation of the positive charged colloidal hydroxide on the negative charged molybdenite particles seem to be the main mechanisms involved.

Jan 1, 2014

By M. A. C. Goes

Over the last twenty years CETEM has been involved in the preparation and certification of reference material from ores, concentrates and related materials for use in analytical laboratories associated with mining, metallurgy and earth sciences. CETEM provides reference materials from mineral samples, not available from the existing sources, to meet the needs of the mining and mineral industry. CBPA-1 and CBPA-2 respectively are samples of copper sulphide ore and flotation concentrate, both originated from Sossego Mine, located in Pará State, Brazil. The batch characterization was carried out by a collaborative measurement program with participation of 20 industrial, commercial and government laboratories from South America, North America, Europe, Asia and Africa. The certificates and report were issued in December 2007 (http://www.cetem.gov.br/ mrc/ing). The objective of this paper was to describe the procedures for material preparation and the collaborative approach involving a collaborative interlaboratory measurement program to certify CBPA-1 and CBPA-2.

Jan 1, 2014

By Kazutoshi Haga, Atsushi Shibayama, Altansukh Batnasan

"The aim of this study was to develop a hydromellurgical processing for removal of arsenic from high-arsenic copper sulfide ores and concentrates, providing increase in copper recovery. In this study, three different enargite ore samples containing 28.2–46.7% copper, 1.9–15.0% arsenic and 10.6–27.5% iron were used to determine optimum conditions for the extraction of copper and removal of arsenic. High pressure oxidative leaching process was preformed using various leaching reagents such as sulfuric acid (H2SO4), ferric sulfate (Fe2(SO4)3), hydrochloric acid (HCl), ferric chloride (FeCl3), sodium sulfate (Na2SO4), sodium chloride (NaCl) solutions and distilled water (DW), respectively, under the fixed conditions which were selected to be as follows: NaCl concentration, 0.34 M; concentrations of other leaching reagents, 0.1 M; particle size, -45 ?m; pulp density, 100 g/L; agitation speed, 750 rpm; leaching temperature, 160 ?C; leaching time, 60 min and total pressure (oxygen gas and vapor pressure) into an autoclave, 1 MPa. Results show that under the leaching conditions, more than 90% of copper leaching was achieved with lower than 2% arsenic content as a consequence of the formation of arsenic precipitates in a solution of Fe2(SO4)3–NaCl. It was determined that copper, arsenic and iron concentrations in the pregnant leach solution were 42 g/L, 0.3 g/L and 0.3 g/L, respectively. As a result, it can be concluded that the Fe2(SO4)3 solution in the presence of NaCl or FeCl3 are more efficient leaching media compared to other leaching agents under the high pressure oxidation conditions, because of their high copper recovery and lower arsenic level in the pregnant leach solution.INTRODUCTION Generally, copper is usually produced from copper sulfide ores by a combination of several processes which are flotation and smelting followed by refining [1-3]. Arsenic content in copper sulfide ores tends to increase due to the depletion of high grade copper deposits, hence conventional mineral processing and metallurgical processes cannot effectively treat these ores containing high levels of arsenic to obtain consistently high purity copper concentrates. Because high levels of arsenic in copper ores/flotation concentrates reduces the value of concentrates due to the restriction of smelting process and causes it to be a source of environmental pollution [4-6]. From this point of view, the known way of prevention against high-arsenic copper sulfide concentrates in further metallurgical treatments is to develop economically and environmentally competitive technologies for removal of arsenic impurity from copper sulfide ores before treating the ores/flotation concentrates by the pyrometallurgical routes."

Jan 1, 2018

By Sergey Romanenko, Tatyana Aleksandrova, Karen Arustamian

"Current status of question about grinding stage effect to electrochemistry parameters of operation preparation slurry before intermediate selective flotation was assessed in the present scientific work. Needs of more detail study chemical reactions in the slurry preparation and flotation processes were shown. The ores are polymetallic sulphide type and the one are most difficult for mineral processing. The methodology allows increase information base during floatation tests. Ionometric methods and elements of neural network have been used in the study of mineral processing questions.We have also identified the relationship between the received values of the electrochemical parameters and the technological results in selective flotation. The optimal values of the electrochemistry parameters in operation of the preparation slurry before selective flotation has been found. The main effect of using the proposed methodology is to obtain scientifically based solutions to improve the technology parameters of flotation polymetallic sulfide ores. Challenging issue of selectivity of sulphide-polymetallic ores will be considered using case study of sulphidepolymetallic ores. It was shown that several factors are formed in ore grinding: formation of hydroxyl oxides of iron compounds, copper cation leaching, metal-sulphide and metal-sulphite complexes formation. The chemistry was revealed for current processes in slurry preparation operation before selective flotation. Quantitative assessment of interrelations between electrochemical parameters of slurry and process performance was given with using electrochemical control methods. Neuron network-based model was estimated based on data array and was allowed to establish optimum electrochemical conditions of metal-sulphite complex formation to provide maximum efficiency of selective flotation.INTRODUCTIONPhysical and chemical processes that take place in ore grinding have a significant impact on flotation selectivity and can cause low selectivity of the flotation process. Today this issue is given much attention. In the paper [1] it is pointed out that sulphide oxidation products and slurry components, such as sulphide ions, metallic iron and its oxidation products, have effect on flotation performance. So, metallic iron has impact on metal-sulphite complex formation as a result of oxidation-reduction reactions as follows:"

Jan 1, 2018

By L. A. Vaisberg

"Mining processing plants are the most high-performing industrial enterprises in the world economy system. Even at an average-scale mining enterprise, the grain-size separation equipment continuously processes 105 to 106 dissimilar mineral particles per hour. In separation by physical properties, their number increases by at least 10 to 50 times. Mathematical modeling of such a high flow of discrete particles is carried out using two different approaches: the discrete-particle and the phenomenological methods. The calculations demonstrate the possibility of handling big data when describing the processes of separation of granular material. INTRODUCTION The interest to the screening process and the process of formation of new screen designs in Mekhanobr is traditional since the moment of its foundation. It is symbolical that the first publication of the Mekhanobr proceedings in 1924 was the monograph dedicated to screens and screening products as such, which was the first one in the world at that moment. It was a book of Prof. L. B. Levenson, one of the founders of Mekhanobr, who headed the Technical Bureau of the Institute. Vibratory screening is the most mass process in the technologies of solid minerals processing, which determines significantly the energy demands of crushing and grinding cycles, and at some enterprises determines the quality of the final product, for example in case of crushed stone, coal or abrasive materials production. The general understanding and simulation of the process of poly-dispersed granular materials vibratory screening was developed at several conceptual levels taking into account the features of classification of materials with different size and density.Considering the real industrial processes of vibration screening, it shall be noted that at the sieve surface of the screen in the initial part of the deck the classification in a thick material layer (in natural conditions) occurs, which further transfers to a thin layer (free movement). In the process of screening of light minerals, for example coal or metallurgic feedstock, screening is mainly performed in the thick layer."

Jan 1, 2018

By V. Panayotov

Slag and by-products of metallurgy bear valuable components and their processing raises an in-creasing interest. Coke and iron have to be separated and other components have to be depressed, in order to obtain sellable high quality copper concentrates. Use of classical mineral processing technologies, such as magnetic separation, sulphidization, hydrometallurgy, etc. yields copper concentrates with grade of 4%~6% Cu. Copper is lost in tailings and the whole technological cycle is low profitable. Technology proposed applies an electrochemical treatment of the industrial water entering the flotation cycle. Iron and iron compounds that do not bear Cu, coke and gangue materials are depressed during the copper flotation. Copper concentrate of grade of 9.8%~10% Cu is obtained at simultaneous increase of Ag recovery by 8%~10%. As a result company profitableness is increased. Technology proposed is easy to implement, it does not require changes in the existing technology flow-sheet, and additional investment is low. The flotation process can be aided by a specially developed system for real-time analysis of the obtained copper concentrate which allows in-time corrections in the flotation parameters and entire process control. Applied flotation schemes, technological parameters and results obtained are described.

Jan 1, 2014

By M. Kadiyski, V. Stoyanova, E. Visariev, V. Stoilov

"The present study deals with copper losses in slag from copper smelting. Copper slag cooling at Aurubis Bulgaria is traditionally done in pits. A new type of slag-cooling is introduced in the site, involving cooling ladles. In a previous study, the ladle cooling process was studied in detail, showing an improvement in the recovery of copper in the slag after flotation. The main reason for better recovery of copper is the increased cooling time, which allows for the accumulation and aggregation of copper droplets. The effects of the newly introduced slag cooling process are studied using optical microscopy and scanning electron microscopy. Cooling in pits and in ladles is compared, based on copper droplet size, distribution and content. Specialized image processing software is employed on images taken with an optical microscope. The results are then compared with a similar technique, available in SEM software. The availability of phase-analysing image software in combination with electron dispersive X-ray spectroscopy makes it possible to study the morphological properties, distribution and chemical composition of the copper droplets. The obtained results confirm the initial conclusions about size, distribution and composition of the copper-bearing particles. A large amount of copper particles is examined showing an obvious increase in their size from pit- to ladle cooling. The results show an increase in the average size of the droplets, which doubles from pit-cooling to ladle-cooling. There is a well-pronounced tendency of decrease of the percentage of droplets in the smallest fraction (<5 µm) in the ladle-cooled slag. In addition, the number of droplets in the larger fractions increases, compared to the ones in the pit-cooled slags. It is believed, that the developed methodology for analysis provides a relatively quick and reliable solution for comparison of the cooling rates in the slag. INTRODUCTION In the process of copper smelting and converting, iron-silicate slags are produced that contain various amounts of dissolved and entrained copper. Different physical and chemical techniques are employed for the valorisation of the remaining metals in the slag – magnetic separation, leaching, roasting, flotation, etc. According to Gorai et al (2003), about 2.2 tons of slag is produced per ton of metal. In 2016, about 20 million tons of copper have been produced globally (www.icsg.org). At an average of 0.5 percent copper content after treatment, these slags contain more than two hundred thousand tons of copper which is lost due to inefficient processing."

Jan 1, 2018

By E. Gock

Based on the scientific investigations on mechanochemical synthesis of metal sulphides from metals or metal compounds and sulphur or sulphur compounds, the article describes the industrial production of nanoscale metal sulphides. Special operational conditions such as inert atmosphere, size and type of the grinding balls, grinding time and specific energy input are taken into consideration. A system configuration for the manufacturing of sulphides at a capacity of 100 kg/h is presented.

Jan 1, 2014

By A. Lane

Africa is ripe with opportunity for the mining industry. The continent has large, and relatively unexplored mineral deposits, and recent high economic growth rates have meaningfully improved the political, economic, and infrastructural environments. However, these opportunities are accompanied by significant risks, including resource nationalism, uncertain regulation, corruption, and continuing political instability (up to and including war). Forward-looking companies actively manage these risks by creating a sense of shared purpose with the countries and communities that own the resources, using tools such as stakeholder analysis, local narratives, scenario planning, and constituency engagement. They also measure socio-economic impact to insure the creation and demonstration of shared value.

Sep 1, 2012

By Susanna A. C. Stadler, Chris Aldrich, Jacques J. Eksteen

Slag foaming occurs in several pyrometallurgical processes. These processes include steelmaking in basic oxygen steelmaking furnaces and electric arc furnaces as well as various non-ferrous operations like sulphide smelting/converting and base metal slag cleaning. Although slag foaming in steelmaking processes has been extensively researched, little attention has been given to slag foaming in non-ferrous operations. Slag foaming phenomena are complex because often the system consists of three or more phases. With this in mind, factors previously identified as influencing slag foaming were investigated. These include the slag basicity, physical properties of the slag, namely viscosity, surface tension and density, the formation of particles due to undercooling of the slag and the FexO concentration in the slag. The effect of increasing FexO concentration was found to decrease the foam index due to lower viscosities, but higher surface tension depression appears to have led to increased foam index values at high FexO concentrations. The foaming index decreases with increasing basicity, until precipitation of solids occurs. After this point, the foaming index was found to increase with increasing basicity due to increased solids precipitation. In general, increasing amounts of slag-wettable solids led to higher foam indices, but the precise nature of the effect on slag foaming was dependant on the nature of the solid precipitate.

Jan 1, 2003

By Kym Runge, Wei Huang, Fengnian Shi, Christian Antonio

"This paper presents an emerging High Voltage Pulse (HVP) technology for ore pre-treatment. Unlike previous studies where HVP was utilized as a crusher to pulverize ore particles to micron size ranges for downstream processing, the researchers at the Julius Kruttschnitt Mineral Research Centre (JKMRC) use HVP to enhance ore processability. Application of relatively low levels of HVP energy to selectively break mineralized particles from barren rocks, followed by size-based screening separation enables the feed ore to be split into high grade and low grade products. During HVP treatment, cracks/micro-cracks are generated which results in pre-weakening of the treated ore particles, which ultimately results in energy savings in the downstream comminution processes. HVP treatment followed by conventional grinding also results in improved liberation of the valuable minerals in comparison to that achieved with traditional conventional comminution, subsequently improving downstream separation efficiencies. The three major improvements in ore processability through HVP pre-treatment have the potential to facilitate rejection of low grade ore prior to processing, increase production rates, reduce the energy required for comminution and improve flotation separation recoveries. This paper summarizes the major research outcomes of HVP pre-treatment demonstrated using ores from various mining operations conducted by the JKMRC. It also discusses the barriers that must be overcome before it can be adopted by industry with confidence in a continuous high tonnage rate application.INTRODUCTIONThe challenges of declining ore grades and increased plant throughput rates, resulting in higher energy consumption and operational costs, require the mining industry to adopt new technologies to make future ore treatment economically viable. Over the past 50 years, many researchers have engaged in investigating novel comminution techniques. Since Yutkin (1955) first demonstrated the potential to generate shock waves with pressures exceeding 103 MPa via electrical breakdown of water, several applications of electrohydraulic crushing by shock waves have been reported (Curley-Macauly, 1968). Interest in this technique was bolstered when Andres (1977) demonstrated that electrodynamic fragmentation results in superior liberation of mineral grains as compared with conventional grinding techniques. Despite mounting laboratory-scale evidence of the efficacy of electrodynamic fragmentation for mineral liberation, development of the technology for full-scale operation has stalled, primarily because the energy required to achieve desirable mineral liberation is approximately two to three times that of mechanical comminution, amounting to approximately 100 kWh/t for typical mineral ores (Andres et al., 2002)."

Jan 1, 2018

By P. Somasundaran

Treatment of mineral surfaces with appropriate surfactants plays an important role in mineral processing operations such as flotation, flocculation and dewatering. Recently biosurfactants, in particular, have received a considerable amount of attention because of their unique surface active properties and biodegradability. In this work we examined the performance of biosurfactants, sugar based alkyl glycosides and sophorolipid esters as reagents to control the hydrophobicity of minerals with selectivity of adsorption on mineral surfaces for flotation applications. It was discovered that n-dodecyl-ß-D-maltoside adsorbs on alumina, titania and hematite but, interestingly, not on silica. The hydrophobicity obtained is governed both by the surface coverage as well as the nanostructure of the adsorbed layer in terms of orientation of the adsorbed species. Surprisingly, even though the above surfactants are non-ionic, their adsorption was pH-dependent. We have correlated this pH dependence to the type of species on the mineral surface. Also it is shown that mixing of these surfactants with traditional ones can help reduce the carbon footprint due to synergy between the reagents and help selectivity due to antagonism. The experimental results were analyzed to get information on optimal pH and dosage conditions, for mineral surface modification. The study provides guidance for mineral treatments using biosurfactants and the potential use of these next generation reagents in mineral processing.

Jan 1, 2014

By Jacqueline Satur, Yoshiaki Kon, Buenaventurada Calabia, Xiao Sheng Yang, Arvo Naumanen, Kenzo Sanematsu, Sayaka Morita, Tetsuichi Takagi

Granite ores are composed of silicate minerals and a variety of valuable REE (rare earth elements)-bearing minerals, however the processing technique to recover these valuable minerals is not yet developed. In this study, the recovery of REE-bearing minerals by dry magnetic separation and wet high intensity magnetic separation (WHIMS)-settling from surface sample and from drill core sample, respectively, of a granitic REE-Zr-Nb ore deposit was investigated. The two samples have different mineralogy however in both samples, light REE are commonly contained in REE carbonate minerals while Y and heavy REE are commonly contained in zirconium silicate minerals and pyrochlore. The liberation size of the REE-bearing minerals in the two samples ranges from 10-250 ?m. Previous flotation testwork conducted on the drill core sample reported high recoveries of La2O3 (88%) and Ce2O3 (88%) but low recoveries of Y2O3 (42%), ZrO2 (17%), and Nb2O5 (29%). The objective of this study was to obtain higher recoveries of Y2O3, ZrO2, and Nb2O5 by dry magnetic separation and WHIMS-settling. Both processes implemented the application of a low magnetic intensity to initially separate the ferromagnetic minerals then a high magnetic intensity to recover the REE-bearing minerals. The results showed higher recoveries of Y2O3, ZrO2, and Nb2O5 by dry magnetic separation and WHIMS-settling indicating the potential of magnetic separation and gravity separation in recovering the heavy REE-bearing minerals. WHIMS-settling is more recommendable than dry magnetic separation because of its applicability in treating a wider range of particle size. In the WHIMS-settling, the light REE, Y, and Zr minerals were recovered mainly by applying four stages at high magnetic intensity of 21,500 gauss while the weakly magnetic pyrochlore was recovered mainly by decantation of the nonmagnetic slurry after a short settling time of 0.25 to 0.50 h. (MAX.300 words)

Jan 1, 2014

By Pejman Oghazi

During the last decade the output of mining companies has increased rapidly. The key driver is the increase in demand for raw materials in the developing world, and thus this demand has driven up ore prices. From the time when the Raw material group (year 2000) started to introduced their index, it was set to 100 points. Today, year 2011, the index is over 400, which means that ore prices have quadrupled since then. Mine companies have to go deeper in the mines to access the ore bodies to increase the mine capacity and to be able to respond to the market. By going deeper in the mine, there will be new challenges that have to be considered. One of these challenges is how to handle the mine water that is produced in the mine. The water has to be moved to the surface in order to keep the mine from flooding, and this causes more challenges. One solution is to pump the mine water up to the surface without treatment; however, this causes considerable pump wear and the water will still require treatment on the mine?s surface. Another solution is to treat this water in the mine before pumping it to the surface. Metso Minerals has a system solution to treat the mine water, by separating the solids from the mine water. This system reduces the erosion in the pumps and will save many maintenance hours in the long term. One other option is to use the treated water in a closed circuit and reuse it in the process. This system can be divided into three steps: Firstly, a spiral dewaterer to remove the coarse solid particles. For the next step, lamella thickener is used to remove most of the solids, and lastly tube press to handle the sludge from the underflow lamella thickeners. Keywords: mine water, mineral processing, dewatering, separating

Sep 1, 2012

By M. P. Krasteva

The froth flotation process for separation of mineral ores depends on the establishment of care-fully controlled froth. The formation of very stable froth in the flotation circuit is a problem that may occur in many plants, resulting in down-time, low quality and grade of final product and considerable expenses. Froths build up on the top surfaces of thickeners, tanks and flotation cells until they overflow, or until the efficiency of the circuit is impaired. A similar problem exists in Assarel concentrator, Assarel-Medet PLC, Bulgaria. Copper and copper-pyrite ores are dressed in Assarel concentrator. They are characterized with variable and complex mineral and physical composition. During the flotation cycle, resilient and difficult to break-down froth is formed, which subsequently impedes the process of thickening and clear overflow obtaining. Due to this problem continuous sampling in the cycle of thickening was conducted. The mineralogical, chemical composition, particle size distribution and solid phase content of the products were determined. It was established that the solid phase of the froth build up on the top surface of the thickener differs considerably from this one of the thickener underflow. The data clearly indicates that a separation process takes place on the top surface of the thickener ? fine particles of chalcopyrite are concentrated in the froth. The role of chemical reagent addition in the break-down of the flotation froth is investigated in terms of surface chemical phenomena involved in the stabilized froths. Measurements of the coper minerals wettability and surface tension at the air/liquid interface were performed. The surface active agent AERODRI® dewatering aids were laboratory tested. Bench-scale froth collapse tests were conducted. Reagent addition into pulp-froth system promotes and leads to a bubble coalescence, an improvement of the wetting of the mineral particles and a decrease of the surface tension at the air/liquid interface. The results of the laboratory experiments showed that the presence of the surface active agent leads to considerably decrease of the froth stability and the destruction of the deleterious froths build up on the top surface of the thickeners in Assarel concentrator.

Jan 1, 2014

By A. S. Choudhary

India is endowed with a reasonably large reserve of chrome ore, amounting to about 100 million tons in different grades and is one of the leading producers of ore/concentrate along with South Africa, Kazakhstan and others. Chromite production in India has registered a 10 times increase during the last 30 years. Till late 1940s, the practice was to mine the high-grade ore for making ferrochrome and charge chrome and export the same leaving the low and medium grade ores stacked around the mine as waste material. This practice was continued for quite some time till the increase in world wide de-mand of chromite initiated an increase in production of chromite ore in India and the aspects of ?economy of operation? and ?conservation of mineral? dawned on the producers and associated authorities. Recovery of chrome values from low and medium grade ore was initiated to produce high-grade saleable concentrate. Suitable legislation was made by Government of India to induce and provide incentives to the operators to do so. First large scale chromite beneficiation plant in India was commissioned about three decades back at Byrapore in the Southern state of Karnataka. The ore, rather simple in nature and relatively free from clay, was obtained from underground. The processing consequently was simple washing and wet tabling. Further more, some test work, on the samples from eastern coast particularly from Orissa, was carried out at an internationally reputed laboratory by a large private operator and the plant was set up. This consisted of a combination of crushing-grinding-de-sliming-classification followed by concentration in multi stage spiral concentrators and shaking table. The plant was commissioned and operated successfully. Soon a state owned company followed suit on the basis of test work carried out in a well equipped Indian laboratory. The plant worked satisfactorily after some initial teething trouble and the company plans to double the existing plant capacity by installing balancing facilities. This development prompted a number of operators, including industry leaders to join the fray and the chrome ore processing industry flourished in India. More and more operators are now in the process of adding capacities to their existing plants. This paper attempts to chart the evolution of chrome ore beneficiation industry in India through a case study with reference to an existing plant. The process technology adopted and modified to suit the altered requirements as well as the future trends are outlined.

Jan 1, 2014

By C. Y. Wang

Based on Slurry Electrolysis, and combined with the problems of extraction antimony, lead and their separation from complicated antimony-lead concentrate, a series of tests have been done in this paper. Using Slurry Electrolysis to treat complicated antimony-lead concentrate, antimony and lead can be separated in one step. And 2# metal antimony can be achieved in cathode directly at the same time. Lead in concentrate is restrained still in the residue at the form of PbCl2. After converting the residue with ammonium carbonate and removing sulfur with kerosene, the high quality of lead concentrate (Pb is above 45%, S is below 15%) and pure sulfur can be achieved, respectively. The recovery of all in Slurry Electrolysis process is as: Sb 95%, Pb 95%, Ag 80%, S 60%.

Jan 1, 2014

By Tilak Raj Mankhand, Mudila Dhanunjaya Rao, Kamalesh K. Singh

"Zinc dust is used for the removal of primary impurities by cementation from the zinc sulphate electrolyte before electrowinning of zinc. However, the industrial zinc electrowinning plants has been reported that the zinc dust consumption is in large excess than the stoichiometric requirement. In the present investigation, morphology of the zinc dust has been altered by ball milling and utilized for the cementation of cadmium, which is one of the major impurity and compared the change in the rate of cementation with original zinc dust. Initially, 325 mesh size zinc dust was used for the optimization of the excess quantity of zinc dust to be used at a temperature of 50 °C. The chemical analysis of zinc dust before and after ball milling and morphology were studied by scanning electron microscopy (SEM), and the solution was characterized by Atomic Absorption Spectrophotometer. The rate of cementation increased with increase in ball milling time. The residual precipitate obtained after filtration was also characterized by X-ray diffraction analysis. Finally experiments were conducted to study the effect of temperature and kinetics of cadmium cementation using first order reaction kinetics. Based on the integral method, the calculated activation energy for the cadmium cementation with 4-hours ball milled zinc dust was found to be 3.39 KJ/mole. INTRODUCTION Primary production of zinc in the world is carried out by hydrometallurgical route. The primary impurities in the neutralized zinc sulphate solution that cause negative effect on electrowinning are copper, cadmium, cobalt, and nickel. Copper diminishes the current efficiency and cadmium contaminates the cathode zinc (Morgan, 1977) while electro winning. Nickel and cobalt lead to perforation in the zinc deposit and prevents the electro winning process (Abrasheva et al, 1984). Due to higher electro positivity of these metal impurities than zinc, they can co-deposit with cathode zinc at the time of electrolysis. In addition to that, some possible impurities (including cobalt) in the electrolysis may lower the hydrogen overvoltage, allowing deposition of hydrogen at cathode resulting in fall of current efficiency. The deposition of zinc on the cathode is possible only at higher hydrogen overvoltage which is practicable in the absence of such impurities (Raghavan et al., 1999). Cementation is one of the prominent purification technique, and in that less reactive metal can be replaced by highly reactive metal by allowing them into precipitation. Cementation of cadmium from zinc sulphate electrolyte is being done by the addition of zinc dust."

Jan 1, 2018

By S. S. Lu

In sodium oleate and salicylhydroxamic acid systems, sequence of floatability of three sulfate minerals is: barite>celestite>gypsum, in lauryl amine system is: gypsum>celestite>barite. XPS and infrared spectrum analysis are used to find that it is chemical reaction between sodium oleate and three minerals, physical adsorption on the surface of minerals for lauryl amine, and it is chelating reaction between salicylhydroxamic acid and three minerals possibly. Theoretical calculation on chemical bonds in crystal structures of three minerals is carried out, finding that breaking degree of Mn+?O2- in crystal structures of three sulfate minerals is closed related with floatability.

Jan 1, 2014