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By A. L. Mackie

Mine water from base metal mines is generally characterized as having high concentrations of heavy metals and low pH, resulting in the need for treatment prior to discharge to receiving waters. In this study, two high-rate clarification processes were evaluated at bench-scale: the high density sludge (HDS) process and sand-ballasted flocculation. High-rate clarification processes generate larger, denser flocs which settle more quickly than those formed in conventional flocculation processes. The HDS process uses recirculated sludge in order to seed floc formation, whereas ballasted flocculation uses microsand. Both of these high-rate processes require the addition of quicklime or hydrated lime to increase pH and allow for the formation of insoluble metal hydroxides, which can then be removed in the clarification stage. Previous research has shown that cement kiln dust (CKD) can effectively replace quicklime in conventional sedimentation processes for metals and acidity reduction to meet discharge guidelines (Mackie & Walsh 2012). CKD is an alkaline by-product of cement manufacture that has fine particle sizes and varying free lime concentrations depending on the manufacturing process. The lower solubility (i.e., free lime content) of CKD requires larger doses of material to be added to reach treatment pH targets for metals precipitation. The purpose of this study was to evaluate the treatment efficacy of high-rate clarification processes for mine water treatment, compared with conventional sedimentation, at bench-scale with conventional (i.e., lime) and novel (i.e., CKD) pH adjustment additives. Results of the study showed that all treatment processes (i.e., HDS, ballasted flocculation, and conventional sedimentation) were able to reduce target metal concentrations to well below Canadian guidelines (i.e., total zinc and total nickel < 0.5 mg/L, total copper < 0.3 mg/L) using either CKD or lime. Additionally, mine water samples treated with CKD generated lower sludge volumes than those treated with lime (i.e., 50 versus 100 mL for conventional sedimentation and 100 versus 200 mL for HDS) even with increased concentrations of solids introduced during treatment. This is most likely due to slower neutralization rates when using CKD, due to its lower solubility, as well as finer particle size. The sand-ballasted flocculation process was able to reduce final turbidity in CKD-treated samples while the HDS process did not when compared to conventional sedimentation, making the ballasted flocculation process preferable for reducing final solids concentrations in CKD-treated mine water.

Aug 1, 2013

By R. Aubertin, G. Panneton, P. Donovan

The Detour Lake gold project is located in northeastern Ontario, approximately 300 km northeast of Timmins, within the Abitibi greenstone belt in the northwestern portion of the Archean Superior Province. Historically this greenstone belt has produced approximately 180 million ounces of gold, largely from narrow vein underground mining. The Detour Lake project is a site of extensive past exploration since 1974, as well as underground and limited open pit mining activity from 1983 to 1999. During this period, it produced 1.8 million ounces of gold. Underground mining focused on narrow vein conventional shrinkage and mechanized longhole stoping. After acquiring the property in January 2007, Detour Gold Corporation initiated a comprehensive drill campaign to define the potential for a large, open pitable, low-grade gold deposit. From 2007 to present, Detour Gold has completed over 500,000 metres of diamond drilling. A technical report completed in March 2011 defined an open pit mineral reserve of 14.9 million ounces of gold, which is Canada&apos;s largest undeveloped gold reserve. The Detour Lake project is currently in development and infrastructure construction of the mine facilities started at year-end 2010, after all the necessary Provincial regulatory permits were received. Gold production is expected to commence in early 2013. Gold mineralization at Detour Lake is associated with a large scale deformation zone (Sunday Lake Deformation Zone; "SLDZ") that occurs at the contact between the 2.72 Ga Deloro Group mafic metavolcanics and the 2.69 Ga Porcupine Assemblage metasedimentary and metavolcanic rocks. The bulk of the gold mineralization is found in the hanging wall of the SLDZ, which is associated with a stockwork of auriferous quartz veins that splay from a flexure along the deformation corridor. The mineralization forms a 200-350 metres wide auriferous corridor defined over 3 kilometres along the strike of the mafic metavolcanic assemblage, from surface to at least 1,000 metres depth. The richest gold mineralized zones are commonly associated with quartz veins with a strong biotite alteration and local zones of pyrrhotite-chalcopyrite-pyrite-gold enrichment formed during the deformation of the quartz vein system.

Jan 1, 2011

By Ian Orford, Ken L. Boyd

"Can the ever-increasing tonnages of ore and waste being mined today be accommodated simply by using bigger and better crushers? This paper updates the principal author’s earlier publication, “Crushing Plant Design and Layout Considerations” (SME Mineral Processing Plant Design, Practise, and Control, 2002). It reviews the latest primary crushing and large cone crusher designs. Its goal is to help consultants and operators select the optimal equipment and custom-designed items in the material handling flowsheet from the mine to the mill, maximizing operating hours per year.INTRODUCTIONAre larger crushers the answer to meeting the demands of existing or new mining projects for increased tonnage? The principal author’s previous paper in the year 2002 on ""Crushing Plant Design and Layout Considerations"" provided a detailed design and layout review for the design of primary and fine crushing (Secondary, Tertiary, Quaternary) mineral processing facilities. Some of the conclusions in this previous paper had predicted that larger crushers for primary and fine crushing would be beneficial and contribute to the further development of mineral processing. Larger crushers for primary and fine crushing applications are now available.The rock size reduction process, from the mine to the selected milling process facility has not changed since man first broke a rock to get at the interesting mineralization within. The rock size reduction process circuit from the mine to the mill can be summarized into four (4) stages:• Stage 1: Mining ( Rock Breakage and Fragmentation)• Stage 2: Pre-Screening (Scalping)• Stage 3: Primary Crushing• Stage 4: Fine Crushing (Secondary, Tertiary and Quaternary; the crushers used in this stage are identified by the titles which usage has conferred on them)Plant throughput and ore delivery schedule will form the basis for flowsheet design and equipment selection. Once a project's design criteria and the mine plan has been established, the actual circuit's utilization percentage (percentage of hours when the circuit is being utilized) can be optimized for each of the four stages. The mining and process departments are the key stake holders in the selection of the final comminution circuit and both departments should be familiar with and contribute to the design of the circuit."

Jan 1, 2016

By Georges Houlachi, Akram Alfantazi, Maysam Mohammadi

Manganese ions in zinc electrowinning electrolytes form a protective MnO2 layer that ultimately decreases Pb contamination in the zinc product. In this study, the effect of dissolved Mn2+ on the electrochemical performance of Pb, Pb-Ca and composite Pb-MnO2 anodes was investigated. The properties of the MnO2 layer formed on these anodes were studied and compared. Potentiodynamic polarization and cyclic voltammetry experiments were performed in 180 g L-1 sulphuric acid to study the electrochemical reactions occurring on the anodes. The anodes were subjected to galvanostatic polarization at 50 mA cm-2. The morphology and uniformity of the MnO2 layer on the anodes were examined using scanning electron microscopy (SEM). Experimental results revealed that the MnO2 layer formed on the composite anode was more compact and uniform compared to that formed on the Pb and Pb-Ca anode. It was also observed that the cell mud formation rate, and consequently manganese ions consumption, depended on the anode type. Although initial formation of the MnO2 layer decreased the oxygen evolution overpotential, its growth might negatively affect electrocatalytic activity of the anodes.

Jan 1, 2014

By S. Fabich

Since the very beginning of Polish copper mining, special consideration of sink shaft techniques through highly saturated Cenozoic rocks was required. Shaft freezing has been chosen as a method to consolidate these rocks. Due to the rock mass structure and water inflow potential, shaft sinking without freezing was considered dangerous. In the course of time, rock mass freezing technology and experience were evolved and this technology became safer and more reliable. New techniques appeared not only in the technical method of freezing, but also in the matter of designing. Computer aided techniques allow engineers to make a detailed analysis and view of freeze wall development. Nevertheless it is important to determine basic thermal rock properties. In this paper, the evolution of knowledge and engineering experience taken in Polish copper mines and current knowledge level in that matter were shown.

Aug 1, 2013

By M. Yao, D. Thibodeau

"Selective mining, such as post pillar cut and fill, is used in large, flat, irregularly shaped ore bodies where ground stability is to be maintained. This selective mining is used to open the stope to the full lateral extent of the ore body in order to minimize the dilution and maximise the recovery. For increased mining depth, design of the post pillar becomes more challenging since those pillars will eventually fail as mining progresses upwards. The post pillar should be designed such that failure does not occur at the early mining stage, such as at the first cut. After mining progresses upwards, the post pillars are expected to fail but be confined by backfill. In order to maximise ore recovery, both drift width and post pillar size must be designed adequately with a consideration of all geomechanic parameters. This paper will describe the process used to design post-pillar cut and fill for one of the ore bodies in Vale’s Copper Cliff Mine using a combination of both empirical deterministic and numerical modelling techniques. By utilizing both empirical deterministic and numerical modelling techniques drift width and post pillar size can be effectively designed. Current post pillar cut and fill design in the existing Vale operations are used to validate the design for Copper Cliff Mine. INTRODUCTIONCopper Cliff Mine is located within the Copper Cliff Offset in the limits of City of Greater Sudbury, Ontario, Canada, as shown in Figure 1. The Copper Cliff Offset extends about eight kilometres south from the Sudbury Igneous Complex into the footwall rocks. Until 2008, the current Copper Cliff Mine was operated as two separate mines i.e. North Mine and South Mine. However, as part of restructuring of Vale Ontario Operations, the North and South Mines were merged in 2009 to form the “Copper Cliff Mine”."

Jan 1, 2015

By A. B. Luz, A. Middea

Kaolin clay is heavily used in the paper industry as a coating and a filler, however to attend the specifications required by the industry it has to be processed. Kaolin is also used as a filler and pigment in various materials, such as paint, plastic, rubber etc. Some crude kaolins as mined in Northern Brazil, contain colored impurities such as iron oxide and rutile/anatase. These minerals normally are stained by iron and as a result vary from yellow to dark brown in color. The kaolin beneficiation process used in that region consists mainly of degritting, fractionation by centrifuge, high gradient magnetic separation, bleaching with sodium dithionite, filtering and drying. In some kaolin clays from that region, titanium oxide mineral occurs in fine fraction, lower than 2 µm, and so making the industrial process more difficult. The conventional method of classification and bleaching with sodium dithionite, markedly improves kaolin brightness, but has little effect on anatase removal. In fact, the fine fractions resulting from centrifugation, in many cases contain more TiO2 minerals than the original whole clay or the coarse fraction. The present work is related to purification of Brasilian kaolin clay using selective flocculation for removing its colored impurities such as rutile and anatase. This study was conducted in bench scale and it consisted of: blunging, screening, conditioning and decantation. Overflow and underflow resulting from settling of the flocculated material were then dried and submitted to TiO2 and brightness analyses. Sodium polyacrylate and sodium silicate were added to kaolin clay suspension as dispersant and ammonium hydroxide was also added to adjust pH. After degritting, the minus 44 µm fraction was conditioned with hydroxamate surfactant and then polymers of different anionic charge were added. The influence of pH and type of polymer on efficiency of TiO2 removal, as well as kaolin mass recovery were studied. The results obtained in the present study are quite promising. It was possible to diminish TiO2 content and increase kaolin brightness (ISO) from 82 to 88%.

Jan 1, 2004

By W. R. Gunter

"INTRODUCTIONThis article documents the current non-metallic mineral s resources of Manitoba (Fig. I), and makes comparisons with currently producing deposits in North America and elsewhere in the world. Industrial minerals may lack the glamour of gold, silver or the base metals, but they contributed approximately 20070 to the value of Manitoba&apos;s raw materials, and even out-performed our petroleum industry, except during the oil boom of the early eighties (Fig. 2). Values per tonne of industrial commodities can be as high or higher than for base metal ores. Commodity prices (Canadian), listed in the February 1988 issue of Industrial Minerals magazine, are: talc $202.00 - $306.00, sillimanite $427.00; kaolin $69.00 - $270.00; garnet $175.00 - $250.00; and mica $405.00 - $540.00. The prices are converted to Canadian dollars using the prevailing exchange rates of February I, 1988. Some commodities are not sold by weight. Building stone, for example, is sold by the cubic foot. An average rough granite block, 4 ft by 4 ft by 8 ft, is worth approximately $2000 sitting on the quarry 1100r in southeastern Manitoba (Fig. 3).Thus, not all rocks that do not contain sulphides are worthless. Some may be extracted more profitably than either the base or precious-metal bearing varieties.Industrial Mineral CommoditiesThe commodities available in Manitoba are described in two categories: (1) those already in production that have additional development or expansion potential, and (2) those not in production logical information available at this time.Current Industrial Mineral ProductionThe commodities described herein are currently in commercial production in Manitoba (Fig. 4). These mineral products also have good market expansion potential provided additional geological and market research is conducted. The use of company names in reference to sundry products and locations should not be interpreted as specific endorsement by the Government of Manitoba. The numbers following the commodity name refer to Figure 1. that have good development potential on the basis of geo-"

Jan 1, 1989

By M. S. Ünal

Creation of 3D model of coal seams is a tedious and time consuming operation. Computer aided 3D solid modelling of coal seams can be performed in a fast and detailed manner. However, in case of having tectonically disturbed coal seams where faults may be observed, expert opinion is necessary to decide the geometry of the coal seam. The aim of this study is detection of fault zones with computers by using drill hole data. Firstly, a digital database is generated by using the drill hole data. Surface models of the layers are produced by applying triangulation method on coal seam roof elevations. The generated surface is divided into small squares and consequently dip and dip direction values are calculated for each square. Variograms for dip and dip direction are determined and maps showing the variation of dip and dip direction are generated by using geostatistical methods such as kriging and co-kriging. Examination of disconformities observed on estimation maps created by kriging and co-kriging clearly reveals the extension of faults. The method used in this study is applied to detect fault lines of a known mine field. 3D solid modelling of the coal seam has also been performed by using conventional cross-section method. The results of both methods were in good agreement. Identification of major faults by using the method introduced in this study could certainly simplify 3D solid modelling of coal seams.

Aug 1, 2013

By Walter K. (Cory) Conrad

Two pumping tests in the Chilson Member of the lower Lakota Formation were completed at nearly the same location in 1979 and 2008. The 1979 test consisted of a pumping well and several surrounding observation wells penetrating the full 55-m thickness of the aquifer. The 2008 test consisted of a pumping well and three surrounding observation wells screened over 10 m in one of the known uranium ore horizons in the lower portion of the Lakota penetrated only about 3 meters of the more than 55-m thick lower Lakota aquifer. The average transmissivity and storativity values determined from the 1979 tests were 17.6 m2/day and 1.8 x 10-4, respectively. Comparing median transmissivity of 13.9 m2/day and storativity of 1.2 x 10-4 determined in the 2008 test to the 1979 test, the new aquifer parameters for the lower Lakota are respectively about 80 and 70 percent of the 1979 results. Because transmissivity and storativity depend on aquifer thickness, comparing the results suggests that there may be some scaling effect between the tests due to the differing lengths of screened intervals. However, the effect cannot be predicted by calculations such as relative screen lengths or open intervals to the formation, or sandstone versus shale thicknesses on geophysical logs. The scaling effect is attributed to partial disconnection between the lower and upper portions of the Lakota Formation aquifer by locally continuous shale interbeds. Suggestions to resolve this scaling issue are presented.

Aug 1, 2010

By O. P. Garg

Based on improved methods of collection and analysis of geotechnical data, slope angles have been steepened in some mines of the Iron Ore Company of Canada at Schefferville, Quebec. This paper describes the slope design case history for Fleming NO.3 mine and illustrates the application of modern techniques. The new design has resulted in significant financial savings due to a reduction in required waste stripping.

Jan 1, 1978

By E. P. Evoy, A. W. Jolliffe

"The Uranium deposit of Gunnar Mines, Limited, is on the south shore of Crackingstone peninsula in the Beaverlodge area of northern Saskatchewan.The ore consists of disseminated pitchblende and uranophane in brecciated syenite, and forms a tubular or pipelike body, outcropping at the surface and plunging southward at about 45 degrees for a known length of1,400 feet (see Figure I). The upper portion is being removed by open-pit mining to a depth of 300 feet below adjacent Lake Athabasca. The remainder will require underground mining methods (see Figure 2).The property was staked in July, I 952, and the orebody was subsequently defined by about 70,000 feet of diamond drilling. A 1,250-ton mill was completed in 1955, and production commenced in September of that year with ore from the open-pit operation. The mill is presently being increased to 1,650 tons capacity, and a three-compartment vertical shaft is being sunk to 1,250 feet in preparation for underground mining.GeologyThe mine property is underlain by an assemblage of Precambrian metasediments known locally as paragneiss, granite-gneiss, and syenite. These lie on the southeast limb of a southwest-plunging anticline, strike about north 75 degrees east, and dip southward at about 45 degrees. Para- gneiss outcrops in the northwestern half of the claim group, and again on the islands south of St. Mary's Channel. The granite-gneiss lies conform-ably within the paragneiss and makes up the southeastern part of the property. The syenite forms an irregular, triangular-shaped mass within, and near the footwall of, the granite-gneiss band. Small lenticular bodies of mafic rocks are also present, the former being most prevalent in the paragneiss.The granite-gneiss is coarse to medium-grained, pink to grey, well foliated, and composed of feldspar (65 per cent), quartz (20 per cent), chlorite, and minor mica. The general concordance of its contacts with paragneiss and the absence of intrusive relationships along these, the presence of uniformly oriented inclusions of obviously sedimentary origin within the granite-gneiss, and the variation in colour and texture across the strike all strongly suggest that this member represents a granitized sedimentary rock."

Jan 1, 1949

By G. M. Humphrey

It is a great honour and privilege to be here in this distinguished company of the outstanding men in the mining industry and the political life of Canada. I fully recognize that I am so honoured as a symbol of the combination of American and Canadian leaders in industry who are partners in the sponsor-ship of the Quebec-Labrador iron-ore mining development which we are undertaking, and as such I want to express our great appreciation of the co-operation and assistance we have met on every hand in Canada, and the genuine friendliness and never-failing courtesy which we are always accorded. We are quite aware that it springs primarily from the very high regard in which our partner and sponsor, Jules Timmins, and our other Canadian associates are held. Their high standing among you is well known and we quite naturally fall heir to the benefits of the great esteem in which you hold them. Jules Timmins and his long-time associate, John Knox, were the original inspiration for our participation in this venture. It was their enthusiasm and vision which caught our interest and led to our joining with them in the years of exploration and search which have brought us to the threshold of this great development where we stand today. So much has been written of the details of our exploration and plans for future development that it would bore you for me to review them further here, but there is a phase of this development, and an extremely important phase of it, which I think has passed almost unnoticed and which it may be well worth while for me to bring to your attention this evening.

Jan 1, 1951

By M. Hekmati1

SAG/AG mills have been most common choice in grinding circuits last decades. In the most cases, at the discharge of SAG/AG mills, a trommel screen is used that is equipped with baffles to provide appropriate residence time and improve separation efficiency. Using baffles, with the resultant maintenance requirements could lead to decrease in mill availability. In this research, an innovation in the structure of baffles of a trommel is presented. The results show that using new baffles led to 67% decrease in SAG mill downtime due to problems of baffles and 80% decrease in fine particles on recycle conveyor.

Jan 1, 2012

By A. Sutherland Brown

"The Red Rose Mine is in the Rocher Deboule Range, 8 miles south of Hazelton. The mill camp (elevation 4,000 feet) is on Red Rose Creek, 11 miles by road from Skeena Crossing. The mine camp is one mile northeast and 1,600 feet above the mill camp on a spur of Red Rose Peak.The Red Rose mine was described in the Jubilee Volume, Structural Geology of Canadian Ore Deposits (Davis, pp. 129-131), but regional geology and mine development have progressed to a stage at which a more complete description is possible.The property was first located in 1912, and for the next 7 years was prospected actively for gold and copper on the southern extension of the Red Rose shear. Scheelite was first discovered in the vein in the northern part of the shear in 1923. The Consolidated Mining and Smelting Company of Canada, Limited optioned the property in 1939, and after a drilling program in 1940 the present mine development was initiated in the vein in the northern part of the shear. A 75-ton-per-day mill started operating early in 1942 and continued until 1943. The property was inactive until 195 l, when Western Tungsten Copper Mines Limited leased the property from The Consolidated Mining and Smelting Company of Canada, Limited. A mill, which later was enlarged to 140 tons per day, started operations at the end of 1951. The mine and mill were closed in December, 1954.The mine has twelve levels and sub1evels, and most of the workings are in the plane of the vein (see Figure 2a). The level interval is not constant, but between the lower four levels is 87 feet (100 feet in the plane of the vein). Access is provided by four adits; the 800 (elevation 5,659 feet), 600 (5,920 feet), 300 (6, 133 feet) and 200 levels (6,237 feet). The 600 level is the main haulage, and from it the ore is transported to the mill by aerial tram. From this level an inclined shaft extends in the vein to the lowest level (I, 100)."

Jan 1, 1949

By M. Maccagni, J. Nielsen

"The recovery of lead from battery paste has been investigated for a long time and with the use of many different electrolytes. A number of processes have been presented, but none of them reached even the demonstration step. Engitec has developed a new concept for the battery paste electrowinning using a chloride electrolyte fed through a very innovative flow cell. The process has passed the lab and the demo scale and it is ready to be introduced on the market. In this paper, a description of the process will be provided.INTRODUCTIONThe need for improved energy storage systems as well as the introduction of commercially viable electric vehicles is providing a strong compulsion toward the research of new batteries. The lead battery is playing an important role because it is inexpensive, reliable and it is the most recycled material. This last aspect marks the lead acid battery as quite peculiar making it both the primary lead based product and the main raw material for lead production.In the last years the legislative pressure has become very strong and has forced the lead production to react through the introduction of important process innovations and market changes. The dispersive products, such as additives for paints and for fuel as well as bullets, have been practically banned all over the world while the battery market continues to grow. The lead acid battery remains the cheapest and most integrated energy storage system available and is improving to meet the new technical challenges. This is testified by the news coming from the development of new and more efficient lead acid batteries which are confirming their leading position.Unfortunately, the image of lead is very negative in the public opinion and some important actions are required to try changing this sentiment. Among them, better information to the market and users and the introduction of new and cleaner technologies in the production of lead can help."

Jan 1, 2016

By M. Maeda, H. Sasaki

"Precious metals such as platinum, palladium, and rhodium are commonly used for automotive catalyst converters. To recover these metals with lower environmental load and cost, exposure to zinc vapor was proposed as a pretreatment prior to acid leaching. Alloying with zinc is expected to enhance dissolution of precious metals and reduce the amount of toxic chemical agents required for the leaching. This study examined the effect of the alloying pretreatment using model catalysts. Catalysts were immersed in leaching solutions for a predefined time with or without zinc vapor pretreatment, and the amount of dissolved metals was then evaluated. INTRODUCTIONAutomotive catalysts account for large portions of the world consumption of platinum (Pt), palladium (Pd), and rhodium (Rh) (Butler, J., 2011). Because of their limited production and high prices, recovery of the precious metals from spent catalysts is obviously an important issue. A representative structure of an automotive catalytic converter can be described as a monolithic ceramic support with a honeycomb structure which is coated with porous oxides such as those of aluminum (Al2O3), cerium (CeO2), and zirconium (ZrO2) (Heck & Farrauto, 2001; Matsumoto & Shinjoh, 2007). Small particles of precious metals, originally several nanometers or less, adhere to the oxides.Typical recovery processes for precious metals from scraps are shown in Figure 1 (a)-(c) (Habashi, 1997; Yoo, 1998; Shibata & Okuda, 2002). Precious metals can be recovered by using non-ferrous smelters as Figure 1 (a) shows. Smelted along with metals such as copper (Cu), precious metals and ceramics in the scraps are absorbed into the metal phase and slag phase, respectively. Because the metals separate from Cu as anode slime in successive electro-refining, such a process can recover precious metals as co-products of Cu. However, in order to prevent negative effects on the principal process, a specialized procedure is needed. Figure 1 (b) is a specialized approach in which scraps are melted at elevated temperature with Cu called the Rose process. Here Cu works as a collector metal, and the absorbed precious metals are then concentrated by oxidation of Cu. Such a process can separate precious metals from ceramics constituting catalyst converters. Smelting at high temperature, however, requires extensive equipment as well as a high amount of energy. On the other hand, hydrometallurgical processes may be effective to separate precious metals from ceramics into an aqueous solution, because chemical agents can act on these metals selectively (Figure 1 (c)). Leaching of precious metals, however, requires strong acid and oxidizing agents because of their corrosion resistance; this makes liquid waste disposal and the large environmental load controversial. To solve the problem, a metal vapor pretreatment was proposed (Okabe, Yamamoto, Kayanuma, & Maeda, 2003a, 2003b; Kayanuma, Okabe, Mitsuda, & Maeda., 2004; Kayanuma, Okabe, & Maeda, 2004; Itoh, Kayanuma, Miyake, Kimura, & Maeda, 2005). A flow diagram of the process using zinc (Zn) vapor is shown by Fig. 1(d). Exposed to Zn vapor, precious metals are expected to form alloys which dissolve more easily than pure precious metals, thus reducing the use of chemical agents and environmental load involved with successive leaching. In previous research (Sasaki, Miyaki, & Maeda, 2010; Sasaki & Maeda, 2010, 2012), dissolutions of precious metal alloys formed by Zn vapor treatment were examined in hydrochloric acid (HCl) using an electrochemical method, and it was confirmed that these metals dissolved at higher rates from the alloys than from their pure states (Figure 2). In this study, the availability of the alloying pretreatment was demonstrated by testing on model catalysts in leaching solutions."

Jan 1, 2012

By S. Kelebek

Efficient separation of minerals is the essence of mineral processing. Separation of hexagonal pyrrhotite in processing of Ni-Cu sulphide ores was investigated together with particle size effects with respect to selective flotation recovery of pentlandite and nickel. The recovery by size response was compared for sodium metabisulphite (SMBS), triethylenetetramine (TETA) and their combinations with amyl xanthate as a collector. The pyrrhotite recovery for all sizes was lower than that of pentlandite for the blank case as well as individual cases with SMBS and TETA. For pyrrhotite, the recovery by size relations in the case of individual uses of reagents were mainly determined by recovery losses at coarser size range (>74 um), which occurs at a coarser size for pentlandite (>212 um). The combined use of SMBS and TETA, and the associated synergistic effect very significantly knocked down the pyrrhotite recovery to less than 7% that was a maximum for the –10 um (attributable to hydraulic entrainment). High recovery of pentlandite in a wide range of intermediate sizes and drastically low recovery of pyrrhotite resulted in a very efficient separation of pentlandite from pyrrhotite in all sizes. Separation of this mineral is discussed in relation to fundamental functionality of the reagents used.

Jan 1, 2017

By D. Mu

A method is presented for evaluating the effective gas diffusion coefficient of porous media. A series of random-distributed porous solids with different porosity are generated, a solution of the gas diffusion equations inside the porous media is obtained using the finite element method (FEM), and then the effective gas diffusivities are computed. The results show that there is a percolation threshold sp, and this percolation threshold decreases with an increase in the connectivity of the pore network; the relationship between the effective diffusivity and the porosity is strongly nonlinear when the porosity £ is less than about 0.2; and is quasi linear for higher porosities. The threshold decreases with increasing the connectivity of the pore network. A formula relating the effective diffusion coefficient with porosity is proposed.

Jan 1, 2005

By Gautier Njiekak

The current study provides an experimental approach that aims at documenting the effects of different phases of CO2 (gas, liquid, supercritical fluid) on rock seismic responses. This has implications on obtaining quantitative estimates of fluid saturations for geological storage. The ultrasonic pulse transmission technique is the underlying methodology used in this work. Unlike previous rock physics studies involving CO2 as pore fluid, care is taken to fully saturate the studied samples and also to separate pore fluid effects from pore pressure build-up effects during the experiments. This allows to record seismic effects that are solely reflective of changes in the pore fluid properties. Measurements were done on a CO2 saturated Berea sandstone. Laboratory results show P- and S- waveform variations (velocity, amplitude) in response to CO2&apos;s varying phase state. Overall, CO2 phase changes (gas to liquid and gas to supercritical fluid) are marked by a drop in velocities, with the drop being smaller and less immediate over the gas-supercritical fluid transition than over the gas-liquid transition.

Jun 1, 2012