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By Patrick R. Taylor, T. A. R. Putra

A review of various methods to treat high arsenic copper concentrates through pyrometallurgical processing is presented. Examples are drawn from various past and current operations and research. Various aspects of the engineering alternatives for treatment methods are discussed. Some of the methods discussed include: controlled oxidation roasting, adaptation of some smelter technology to accept higher amounts of arsenic, complete oxidation with arsenic fixation; sulfation roasting; acid baking, soda ash roasting, and others methods. Other topics include: a short discussion of other problematic impurities; the effects of arsenic on copper electro-refining and product purity; and methods for the ultimate disposal, or marketing, of the arsenic. The latest work being done at the Colorado School of Mines on soda ash roasting is also presented.

Jan 1, 2014

By J. W. Hendry

"This paper will discuss the application of tools and the evolution of computer-assisted procedures in the production planning process at Quintett e Coal Limited (QCL). In 1986, QCL produced 5.3 Mt of clean coal from their surface mining operation located in north eastern British Columbia. The structural complexity of the sedimentary deposit and high rate of mining necessitate the consideration of large amounts of geological information which continually updates the interpretation. There are multiple unit operations required during the process of mining through a given multi-seam sequence, which results in many interdependent faces, and multiple iterations of scheduling sequences in order to satisfy a given set of objectives. In order to facilitate these activities in a timely fashion, it was recognized that a computer systems' capability needed to be developed which could increase the efficiency of information input, manipulation and output. IntroductionQuintette Coal Limited (QCL) has been operating a large metallurgical open pit coal mine in northeastern British Columbia, since 1982. The mine produced 5.3 Mt of clean coal in 1986 for export to Japan. Throughout the start-up period and the subsequent build -up of production levels, it became evident that the primary producing area was comprised of extremely complex faulted structures. This has resulted in development and modification of specialized mining methods employed to effectively recover the resource. Similarly, the planning and engineering techniques employed have been evolved over the same period of time. The implementation of computerized methods has been one of the major developments in this process, including geology interpretation, modelling, reserve definition, quantification, production planning and scheduling, and graphical plan presentation. These capabilities have been employed, in various forms, for project scale feasibility work and long range planning for some time, however, the use of computer tools for short-term, detailed production planning of a complex mining environment presents a different set of problems. It is hoped that a presentation of the current state of evolution and future plan s for development will be of interest to organizations considering implementation of a similar system."

Jan 1, 1988

By N. E. Chaouai, M. Lavigne

"Indicator kriging is one of the non-parametric geostatistical techniques, ideal for estimating the reserves of irregular mineralizations (e.g. gold, uranium, platinum, diamonds, etc.). Such mineralizations are characterized by variograms which are very sensitive to extreme values (outliers) and very difficult to model.The classical approach to this problem in the industry is to trim off these high grades using arbitrary empirical upper limits established either from practice or subjectively. Contrary to this simplistic approach, indicator kriging discretizes the histogram of the grades (usually log normal) in several classes and carries out interpolation separately for each class. This paper gives an overview of the differences between ordinary and indicator kriging along with the steps required to carry out indicator kriging. The paper concludes with a case study involving a gold deposit estimation.IntroductionParametric geostatistics (ordinary kriging) has given us satisfactory results over the years in estimating the reserves of well behaved deposits with coefficients of variation close to 1 (e.g. sedimentary and porphyry type deposits). However, numerous problems have been encountered in estimating irregular mineralizations (e.g. small vein deposits of precious metals) with high coefficients of variation in the range of 2 to 5. Such deposits are characterized by a very small proportion of extreme values (outliers) which create distortions on the variograms (pure nugget effect) and render them useless(1,2).The solution often followed by the mining industry today is to trim off these values based on empirical limits. These limits are derived either by comparison with production results (or bulk samples) or by geological interpretations. Needless to say that such manipulations can lead to serious errors in estimating ore reserves (usually underestimation of total metal quantity), especially when production results or bulk samples are absent.On the other hand, the solution followed by the geostatisticians in the past was to smooth out the data using transforms (e.g. normal-score or natural logarithms). Such transforms are nonlinear and they required non-linear estimation techniques such as disjunctive kriging (DK) or multivariate gaussian kriging (MG) which require normal related hypotheses, not necessarily true in geology.Nonparametric geostatistics (indicator and probability kriging) have been -developed in order to handle these problems related to highly skewed distributions."

Jan 1, 1990

By R. S. Nichols

"During 1973 to 1978, Canadaka Mines Limited, a subsidiary of St. Joseph Explorations Ltd., undertook an extensive exploration and development program in the Cobalt area. This program resulted in the delineation of previously unknown stratigraphic units in the Archean volcanic sequence. During this time period, significant are controls related to area silver deposits were also identified.The Archean geology is comprised of a volcanic pile conformably overlain by sediments. The volcanics contain at least two felsic volcanic centres near the stratigraphic top of the pile. The bulk of the pile consists of mafic flows and interflow sediments. lnterflow sediments around silver are shoots contain mineralized halos of base metal sulphides. The halos exhibit lateral and vertical metal zoning with Cu, Pb and Zn mineralization decreasing away from an are shoot.Silver mineralization controls determined during the Canadaka program agree with the historically well established importance of Coleman sediments as well as Archean contacts for hosting silver deposits. The vertical extent of are shoots is typically 150to 250ft. A strong correlation was found to exist in the Cobalt area between Archean strike and the strike of are veins. Finally, al/ Cobalt area are deposits appear to be associated with a distinct volcanic pile at the top of a sequence of Archean flows."

Jan 1, 1988

By K. MacMaster

"This paper deals with the history, development, present and future of the Employee Assistance Programs in place at the Inco Ltd. operations in Thompson, Manitoba. It should be noted that, although many similar programs exist in various industries and jurisdictions, these programs had to be fine-tuned to meet the needs of Inco employees, having in mind the helping professional resources available in Thompson and its geographic location. IntroductionIn the late 70s, many Canadian industries and the Canadian Labour Congress and their affiliates commenced discussions on the value of the Employee Assistance Program (E .A.P.) philosophy to both management and labour.In the contract signed between Inco Ltd., Manitoba Division and Local 6166, U.S.W .A. in 1981, a commitment was made to establish a joint E.A.P. for the hourly workforce in Thompson, Manitoba. With this background and sequence of events in mind, it is appropriate to explain the methodology and the steps that were taken for the implementation of the hourly program. Development of Hourly ProgramIt was agreed by the company and the union that the committee to develop the program should consist of equal numbers from both sides: three active union members plus an advisor representing the Union and three supervisory personnel plus an advisor representing the Company; in addition, a person familiar with E.A.P.s from the Alcoholism Foundation of Manitoba was to act as a facilitator. The Union appointed a social worker who was working as a counsellor for union members as their advisor , and the company appointed a staff employee who had worked voluntarily in the field of alcohol and drug abuse for many years. The makeup of the committee was extremely important in order to give credibility to the entire process. The makeup of the committee is shown in Table 1.The facilitator selected from the Alcoholism Foundation of Manitoba was well known in the community and highly respected in his profession."

Jan 1, 1989

By T. Alan O'Hara

"The decision to invest capital in developing a mine and constructing a mineral processing plant and services is usually made after a feasibility study shows 'that the estimated future cash flow from mine operations will yield an adequate return on the estimated capital expenditures.The actual return on investment may differ substantially from that estimated in the feasibility study, because of the probabilities of errors in estimating capital costs, ore reserves, operating costs, mineral revenue and operating productivity. This paper outlines the R.S.S. (root sum of squares) risk analysis procedure of computing the overall probability of the actual project D.C.F. (rate of discounted cash flow), differing from that estimated in the feasibility study.Variation in Project D.C.F.It is assumed that a feasibility study of the project has been completed which has defined the estimated values for all the project parameters, such as ore reserve tons and grade, capital cost, concentrate recovery, metal revenue, daily milling capacity and operating costs.The financial analysis of the mining project will have determined that the cumulative cash flow will yield an expected D.C.F. on the capital cost if all project parameters attain the estimated values. If, however, the actual value of any parameter varies from that estimated, the actual project D.C.F. will vary from the estimated D.C.F. Risk analysis methods attempt to determine the overall effect of probable variations in the estimated values of all project parameters on the D.C.F. of the mining project. This overall effect is expressed as a probability profile, which shows the likelihood of actual D.C.F. values greater or less than that estimated.Thus, a completed risk analysis of a mine project, with an expected D.C.F. of 15.51%, would display the characteristics shown in the preceding diagram."

Jan 1, 1982

By B. J. Morash

"The six mineable coal seams at Quintette Coal Limited (QCL) vary in thickness from 0.75 m to 9.5 m and include waste partings varying from 0.2 m to 4 m thick. They are highly faulted and folded in some areas and dip angles range from horizontal to 90 degrees. Due to this variation in thickness and orientation of the seams, several different mining methods are used to economically recover the coal. The key to QCL's success depends on the timely collection of detailed geology data and on mine planning which allows selection of the best method of mining to achieve maximum coal recovery with minimum dilution and cost. This paper will describe the various methods of mining employed and the criteria used to select them. IntroductionThe unique challenge in mining at Quintette Coal Limited (QCL) is to extract large quantities of coal and waste, from a complex orebody, with constricted areas for mining and waste disposal. This challenge dictates the mining of as many as four 10 m benches per year, through complicated coal structures, from three separate open pits with a total of 19coal seams. This total is made up of 5 seams at Mesa, 8 seams at Wolverine and 6 seams at Shikano (Fig. 1).Computer-aided mine planning and scheduling is carried out on a routine basis to ensure the prudent selection of methods of mining, to produce plans which ensure delivery of appropriately blended raw coals to the plant, and to coordinate disposal of large quantities of waste.Several methods of mining are applied simultaneously, and as a result coal and waste are released at different rates from twelve to fifteen mining faces. In order to ensure uninterrupted flow of material from excavators and to utilize the truck fleet effectively, a computerized dispatch system is employed.GeologyGenerally, geological conditions can be related to structural (faults and dip angle) and/or stratigraphic (coal seam and interseam waste thickness) sources"

Jan 1, 1988

By Jorgen Elbrond, Yve Lizotte

"A mine evaluation method based on the use of a computer program that models mining with an open-ended dynamic program is presented in this paper. It is demonstrated with an example how the method is applied, how some of the decision variables are related in the particular industrial environment and how these decision variables affect the economic benefits of mining.IntroductionTwo distinguishing characteristics make mining a particular industrial environment: exhaustible resources of a given ore deposit and heterogeneousness of the ore grade spatial distribution in the ore deposit. These characteristics, inflation, uncertainty and cyclical price variations which greatly affect estimated cash flows also contribute in rendering difficult the evaluation of the economic outcome of mining at the preliminary planning stage.Decision variables and their ranges are associated with the mine plan; basically, they include choices of the mine's nominal capacity (mining and milling), the sequencing of mining through the deposit, the ranges of possible production rates and cutoff grades, and the stockpiling policies. The mine's nominal capacity must be decided at the planning stage, but this capacity choice must take into account flexibility to modify other decision variables as mining commences and uncertainty resolves.Although it is generally accepted in discounted cash flow analysis that the sequence of mining must proceed from the richest to the lowest-grade stopes (with correspondingly ajusted cutoff grades), this may not produce optimum benefits when cyclical price variations are considered.Mining rates and cutoff grades can also be adjusted to changing economic conditions, taking into account the limited resources of the ore deposit. Thus, when prices are thought to be in the trough of a cycle, production can decrease to preserve ore for expected greater future profits. When prices rise, mining rates can increase possibly even over the mine's nominal capacity. In both cases, the machinery's effectiveness shall not be-optimally utilized; this will be reflected particularly by the variations in the concentrator's metal recovery and the concentrate grade output."

Jan 1, 1982

By Rashid Bashir

The presence of groundwater in the form of large aquifers can have an important influence on investment decisions for underground mines. The design for such mines requires development of special mining methods, and mine dewatering infrastructure to avoid hazards during shaft sinking and underground development. The costs associated with mine drainage control and Mine Dewatering Systems (MDS) are relatively small compared to the huge consequential losses that can occur in case of an uncontrolled inflow and subsequent flooding of the mine. The design of MDS needs consideration of accurate prediction of the maximum uncontrolled inflow rate, availability of the system during an uncontrolled inflow while the inflow is mitigated, and decision on pumping system technology to have capability to operate under water. The research presented in this paper provides a theoretical framework for a reliability based design procedure which takes into account the uncertainty in the estimate of the maximum uncontrolled inflow, performance of the system during the period of an uncontrolled inflow and a methodology to decide on appropriate pumping technology considering the reliability of the system and available underground storage. The reliability based mine design procedure integrates the ideas of Effective Reserve and Hydraulic Reliability Index to come up with a unified methodology for design of Mine Dewatering Systems.

Aug 1, 2010

By W. F. Moore

"In January 1981, Quintette Coal Limited (QCL) signed a 2a-year coking coal sales agreement with the Japanese Steel Industry which was followed by the commencement of mining operations in October 1982 and preparation plant operation in November 1983. During the mine 's startup, the town of Tumbler Ridge, the Anzac rail spur line, coal port facilities at Ridley Island plus numerous related elements of infrastructure were completed to support QCL and the neighbouring Bullmose operation in northeastern British Columbia. QCL's annual product coking coal levels have accelerated from 2.9 to 5.2 Mt between 1984 and 1986 with related increases in total mined volume from 14.8 to 41.0 M BCM between 1983 and 1986. This paper presents an overview of QCL 's current operation and related infrastructure. Development BackgroundDuring the 1970s, the Japanese Steel Industry (JSI) was forecasting a steady and significant growth in its steel production. By 1980 they were expecting crude steel production to increase from about 105 Mt in 1980 to 125 Mt by 1985 and almost 140 Mt by 1990.Discussions between Quintette Coal Limited (QCL) and the JSI for the development of the QCL project began in the 1970s and continued over a period of several years. During that time detailed and regular meetings took place, at which technical and commercial presentations were made to the JSI. The geology of the project area and the alternative mining methods and sequences were studied in detail. The new rail line which would connect the mine to tidewater was a critical factor and received particular attention. Alternate routes for the rail line from Tumbler Ridge to Prince George were the subject of much detailed study and discussions. The Anzac route was chosen in the best long-term interest of the northeast area development, after careful consideration and advice from the Japanese side.The new bulk coal terminal on Ridley Island at Prince Rupert was also a key factor and completed the development of an independent and new major coal field to supply the JSI. The QCL project and the development of the northeast area of British Columbia was a major strategical initiative of the JSI. It provided Japan with an important new coal field which was both self-sufficient and distinct from the traditional Japanese coal field resources in southern Canada, Australia, and the United States."

Jan 1, 1988

By G. S. Dobby, J. A. Finch

"A significant development in froth flotation technology has been the emerging industrial acceptance of column flotation during the past few years. Flotation columns are being employed now in several Canadian base metal concentrators and they are being considered f or a wide range of flotation applications throughout North and South America. Since the operating principles of a column differ markedly from those of conventional flotation machines, and have been poorly understood, scale-up of columns has been difficult. This paper describes a methodology f or translating laboratory column data to industrial operation.The scale-up model utilizes kin etic data that is obtained from a series of laboratory column experiments; the laboratory column can be as short as 2 m. For modelling purposes the column is considered to consist of two zones: the collection zone, where particle recovery occurs, and the cleaning zone, a packed bubble bed generated by downward flowing wash water. Mixing conditions in the collection zone have been characterized using the results of tracer experiments on plant columns at Mines Gaspe. The same experiments demonstrated the nearly complete suppression of entrained gangue minerals that is attained in the cleaning zone. The model explicitly accounts for both the collection zone and cleaning zone recoveries and allows for the effects of bubble overloading. Results of column scale-up experiments at Gibraltar Mines are presented."

Jan 1, 1986

By D. Madsen, B. Salamondra, A. Moss, D. Etienne

"Raise mining at the Namew Lake Nickel Mine in Manitoba uses 3 m diameter bored raises driven at 45 to 50 degrees dip for stope access and drilling. These raises are developed within the orebody on 20 m centres to accommodate electric-hydraulic longhole jumbos and charging wagons. Critical elements of stope development include delineation of are contacts, control of deviation during raise development, optimal stope sequencing to permit a high extraction rate, drill anchorage installation, production drilling and blasting, and ground control. Procedures to deal with these elements are described, with emphasis on the geotechnical investigation for design of open stopes and pillars.Although mining with drilled raises does not have the flexibility to follow large variations in orebody dip, results to date indicate that it can be used successfully in the thicker ore zones. Thinner zones are currently mined using a modified Avoca method. Some flexibility to accommodate variations in orebody dip in thin are zones may be obtained by using alimack raise climbers to drive access raises, and carry longhole drills and charging equipment. Rock quality has been sufficiently good to maintain stable stope walls for full-height mining of primary stapes at 20 m strike length.IntroductionThe Namew nickel deposit is located 60 km south of Flin Flon, Manitoba. It is a moderately dipping (45 to 50 degrees) pipe-like ultramafic intrusion with a sulphide halo enrichment. The diluted recoverable ore reserves at January I, 1990 are 2.2 million tonnes grading 2.05% Ni and 0.7% Cu. The operation is a joint venture between Hudson Bay Mining and Smelting (60%) and Outokornpu Mines Ltd. of Toronto (40%). The mine is budgeted to produce 530 000 tonnes in 1990. The deposit was discovered in 1984 and mine development commenced in 1987.In the raise mining area, primary stopes will be filled with a high quality backfill consisting of cement and quarried limestone. Secondary stopes will be mined out between the primaries in the second pass of mining. The design extraction rate is 94% over all.The orebody above 120 level has an average mining width of 2.4 m, so is too narrow for raise mining. A modified form of Avoca stoping is used."

Jan 1, 1991

By E. Ozberk, N. Gibson, W. G. Davenport

"In the 1950s, Canada produced more than ninety-five percent of the non-communist world's nickel and achieved dominance in terms of production, technology and pricing policies.Over the past thirty years there have been dramatic changes in the nickel industry to the extent that Canadian production is now less than thirty per cent of the total.In this document we have presented statistics relevant to this transformation and reviewed the technology, particularly with regards to energy and environmental considerations.Under the new market conditions nickel producers are likely to face more difficult competition than they have encountered in the past.The economic scene and measured nickel reserves dictate that for the purpose of increasing production, new nickel smelters will not be built in Canada in the foreseeable future. However, in order to reduce sulphur dioxide emissions, Canadian nickel smelters will possibly go through some modifications or rebuilding.IntroductionThis paper presents a review of the Canadian nickel industry in relation to the world nickel industry. Major changes are described which have occurred in the characteristics of the nickel market over the last thirty years. The pre sent status of the nickel market with respect to Forecasting future trends is reviewed and attempts are made to predict what further changes will take place in the next two decades. Comparisons are made of the economics of producing nickel from sulphide ores and oxide ores and the advantages and disadvantages the Canadian nickel producers face.A brief critique of the existing and emerging nickel production technologies in Canada and the world is carried out and attempts are mad e to predict the changes which may take place in the foreseeable future."

Jan 1, 1983

By John De La Vergne, Morri Medd

"This paper describes the sinking of a circular concrete ventilation shaft through 110feet of water-bearing overburden. The brine circulation freezing method was used to stabilize the walls during excavation. In order to take advantage of the cold winter weather, a custom-built heat exchanger (natural radiator) was installed in place of the standard mechanical refrigeration plant.IntroductionIn the late fall of 1979, Les Mines Selbaie awarded a contract to the firm of 1.S. Redpath Limited to sink a ventilation shaft on its property in northwestern Quebec. The shaft was to be sunk through 110 feet of water-bearing overburden and approximately 90 feet of rock to a final depth of 200 feet below surface. The water table was measured at 16 feet below the surface elevation.After examining the soils report and diamond drill core from the shaft area, Redpath came to the conclusion that freezing was the best way to stabilize the overburden for sinking. LocationThe mine site is 420 statute miles due north of Toronto, just east of the Ontario/Quebec border (Fig. 1). Access to the site is provided by a development road built by the Quebec government from the Matagami/lames Bay Highway. History of Ground Freezing In the Mining IndustryIn 1862, shortly after the development of mechanical refrigeration, a mine shaft was sunk through an artificially frozen water-bearing formation in the United Kingdom. The first application of ground freezing in North America was for a Michigan iron ore shaft in 1888. Since that time, the freezing method has been used to sink hundreds of shafts throughout the world. Its best known application was to sink sixteen shafts through the Blairmore Formation in Saskatchewan.The same method has been used in every case. It involves chilling a calcium chloride brine solution and circulating the brine in concentric pipes, spaced between 3 and 6 feet around the shaft perimeter and usually 4 to 5 feet from the limits of the proposed shaft excavation."

Jan 1, 1982

By C. -M. Katsari, G. N. Anastassakis

"Copper is considered one of the most important industrial metals because of its properties (conductivity, malleability) and variety of uses. Approximately 70% of the global copper is used for various electrical applications, with a significant part of copper originating from recycling, since copper can be recycled and re-used countless times, without any loss of performance and difference in the quality of recycled copper in comparison to that from ore. Copper recycling significantly contributes to natural resources conservation, waste minimization, energy saving, and overall cost reduction. Approximately, 35% of the globally produced copper originates from recycled copper.The objective of the current work is to investigate the recovery of copper from electric wire scraps using wet shaking table as an alternative to air separation methods that prevail over the wet ones in recycling processes. The tests were carried out using feed of correspondingly high- and low-grade in copper. In the first case, the wire scraps had been subjected to shredding only, prior to tabling separation; in the later, the low-content tailing of prior air separation was used as feed ?n table separation.In regard to testing, the following factors were examined: table tilt, water flow-rate, and reciprocating speed. The results of the tests clearly denote that copper wire separation from plastic polymer is feasible, as in most cases, table separation resulted in heavy products of high purity in copper and high recovery, and tailings of very low copper grade. The results of the current work clearly denote that wet tabling can be applied efficiently for the separation of recycled copper wire from plastic, as an alternative to air separation methods, as well as for the recovery of copper from the low-grade tailings derived from air separation methods."

Jan 1, 2016

By M. Bourassa, R. del Villar, S. St. Arnaud, J. Valenzuela

"Autogenous grinding is used quite frequently for mineral comminution as a result of its lower capital and operating costs. However, it is more difficult to control than conventional grinding, particularly when the autogenous or semiautogenous mill is the only comminution stage (i.e. no secondary grinding is available). Analysis of the control strategy used then becomes extremely important, a task that is greatly simplified by the use of an empirical dynamic simulator:This paper presents the methodology used in the development and the calibration of such a simulator for the autogenous grinding circuit of an iron are concentrator: The various steps are described: industrial data acquisition, preliminary treatment of the gathered information. and empirical modelling of the process. Finally, both the actual and the proposed control strategies are compared using simulation results.This exercise has shown that the variability of some of the controlled variables could be reduced through a better handling of the water addition and the use of filters on some of the signals used for control purposes. The reduction in variability of critical variables, such as power draw, would allow their average value to be increased without the risk of exceeding their safety values. Some advanced control techniques were also tested, with interesting results."

Jan 1, 1995

By P. A. Verhey

"This paper describes a series of wear-resistant ceramic materials which have been successfully used in the mineral processing industry in Canada. Applications include use with metallic ores, coal, potash and asbestos, and in other processes where wear degradation is of major concern. The paper will also deal with considerations involving the selection of the different ceramic materials available. It will cover the installation of ceramic materials on support structures under varying process ' conditions, as well as the other physical and chemical factors which have to be taken into account.IntroductionIn the mineral processing industry, large volumes of ores tailings and other materials are handled. The abrasive nature of most of these materials results in extensive wear to both handling and processing equipment.Wear ratios versus cost, production losses due to down time and wear-resistant material suitability for a given application all demand particular attention when viewed against the need for increased efficiencies in existing processes. As a consequence, a very active continuous search for materials with improved wear resistance has been carried out for many years.In this search, starting about 20 years ago, dense ceramic materials were tested and evaluated in certain applications, notably in the iron ore and asbestos operations in Eastern Canada. As a result of substantially better performance both in continuous extended life and ultimate economics realized , wear-resistant ceramic applications developed progressively in many other processing applications, replacing traditionally used materials.In the vast majority of wear-resistant ceramic applications, considerable extended life over previously used materials was established. This invariably was not just a fractional increase but, in most cases , in factors of double, triple and often all the way up to 18 and 20 times the life of alternative materials used previously. In certain applications, extended life could not be measured and appears to be indefinite.Obviously, as a result of such experiences, the progressively wider use of wear-resistant ceramic materials is now an established trend."

Jan 1, 1981

By I. G. L. Sinclair

"ABSTRACTTill geochemistry was the principal exploration tool employed by Selco in the investigation of a zinc prospect in Lanark Township, Ontario. The geochemical studies were undertaken after the discovery at surface of marble boulders containing bands of sphalerite and lesser amounts of galena.The source of these mineralized boulders was sought by means of B-horizon soil geochemistry, followed, where appropriate, by back-hoe trenching and till sampling. The thickness of the tiff in this part of Ontario seldom exceeds 3 m or 4 m and it was generally possible to sample complete profiles of the till and thus to obtain detailed information concerning the dispersion of zinc. Drilling and trenching at the up-ice extremity of the zinc dispersion trains showed the source of the float to be sub-economic bands of sphalerite in the Grenville marble. IntroductionTill geochemistry was used extensively by Selco during the period 1975 through 1980. It was the principal exploration technique employed in a program seeking carbonate-hosted lead-zinc deposits of the Balmat-Edwards type in the Grenville rocks of southeastern Ontario. This paper describes the use of the method to locate the bedrock source of a group of sphalerite boulders found at the surface near the village of Hopetown in Lanark Township (Fig. I) . Geochemical investigations at this locality were the subject of a previous publication by the author (Sinclair, 1979).All of the analytical work related to this project was done by Bondar-Clegg & Co. Ltd. in their Ottawa laboratory. In all cases the -80 mesh fraction of the till was analyzed. The total zinc content was determined by atomic ab sorption spectrometry after hot aqua regia digestion; readily extractable zinc was determined by atomic absorption after samples had been cold-leached for 18 hours in an ammonium citrate hydroxylamine hydrochloride solution, the pH of which was adjusted to 8.5"

Jan 1, 1986

By Douglas W. Reeve, Hoc Nghia Tran, David Barham

"In kraft pulp mills, the spent pulping liquor is concentrated and used as fuel in the recovery boiler. Extensive deposits are formed in the upper section of the boiler due to the very high ash content of the fuel and the volatite nature of the ash. Deposits are composed of Na2S04, Na2C03 NaCI, some potassium salts and reduced sulphur compounds. Chloride and potassium salts are enriched in the deposits compared to the smelt due to their greater volatility.Severe corrosion of the superheater tubes in a recovery boiler has been traced to three factors: a non-uniform temperature profile in the flue gas, relatively high operating steam temperatures and high chIoride and potassium concentrations in the fireside deposits.The role of chIoride and potassium in superheater corrosion has been explained by increased Iiquid phase in deposits. Together with corrosion studies, this information has shown that kraft recovery boiler superheater corrosion due to the chloride and potassium enriched deposits can be avoided by proper boiler operation and by judicious superheater and furnace design.IntroductionThis investigation of recovery boiler superheater corrosion was initiated by the discovery of severe corrosion of the final stage superheater in a Canadian closed cycle kraft pulp mill(1,2). Metal wastage leading to tube failure was believed to be due to three major causes : the relatively high operating steam temperatures, the uneven distribution of flue gas temperature across the boiler which created a "" hot spot"" and the high chloride and potassium concentrations in the superheater fire side deposit. The mill responded to the problem by i) lowering the superheater steam temperature from 475°C to 380°C, ii) minimizing the chloride content in the spent pulping liquor, by controlling the NaCI input with recovered bleach plant effluent, and iii) changing metallurgy of a portion of the bottom section of the final stage superheater platens from ferritic steel T-22 (2.25% Cr, 1% Mo) to austenitic steel Incoloy 800H (21% Cr, 32% Ni, 46% Fe, 1.5% Mn, 1% Si, 0.6% Al) (Fig. 1). Details of the superheater corrosion experienced in the closed cycle mil! have been reported in previous papers(l ·2,) ."

Jan 1, 1984

By Roger J. Goodman

"Major industrial restructuring, which started to manifest itself in the mature economies of the Western World and Japan in the 1970s, will accelerate in the 1980s and 1990s. Conventional heavy manufacturing industries will continue to lose ground to lighter processing/assembly operations and the new wave of high technology, information and service sectors. The decline in heavy manufacturing has severely impacted on the steel industries of Western Europe, the U.S.A . and Japan.World trade in metallurgical coal has shifted correspondingly, with declining demand in the mature developed countries being only partially offset by large increases in the steel intensity of the newly-industrialized countries (NICs) of the Far East, Latin America and, to a more limited extent, the Middle East and Africa. These trends will be accentuated in future years with direct implications for the distribution of metallurgical coal trade. This paper discusses, in quantitative terms, such changes in the 1980s and 1990s, and examines the implications for, and impacts on, Canadian metallurgical coal exporters.IntroductionThe twenty-year period from the early 1950 s to the early 1970s was characterized by inexorable growth in consumer demand and industrial expansion in most of the advanced countries of the western world. Long- term forecasting during this period typically used linear extrapolation techniques which , despite their simplicity, invariably ended up predicting future demand and production level s with uncanny accuracy. Times have changed!The last decade has been characterized by a n abysmal failure of our economies to respond to simple long-term, linear growth patterns. We appear to have entered a new world in transition, where we can observe a wave of dying or sunset industries reluctantly being submerged by a wave of emerging or sunrise industries.This paper is aimed a t examining the evidence for long-term industrial restructuring trend s. For want of a better word, these so -called, megatrends are then used to predict future demand level s and spatial distribution of steel development and , hence, metallurgical coal trade. It is tempting to correlate the decline in economic activity in the western world with the first Organization of Petroleum Exporting Countries' (OPEC) crisis of 1973. This crisis was probably no more than the straw that broke the camel's back, as the megatrends and embryo s of major industrial restructuring were already evident. Today these megatrends are merely more apparent and transparent than they were ten years ago.While the concept of industrial restructuring is the new economic buzz word, the process was at work, to a lesser degree even throughout the period of strong economic growth of the post-Second World War boom. Many people still remain convinced that our present-day sluggish economy is just part o f the typical , though rather more prolonged, recessionary cycle. Yet, we have always been part of a dynamic economic system and industry throughout history has been the subject of a continuous process of evolution, restructuring and reconstitution . Now the time is ripe to examine the evidence for such restructuring in order to develop coherent policies of adjustment in this transition from one industrial regime to another."

Jan 1, 1985