Search Documents

By M. Holmes, R. Molnar, E. Norton, K. Baxter, J. Riordan

The Boleo Copper-Cobalt-Zinc-Manganese Project of Baja Mining Corp. is situated adjacent to Santa Rosalia on the Baja Peninsula of Mexico. The El Boleo ore is a mixed oxide-sulfide deposit with major values in copper, cobalt, zinc and manganese. The metallurgical process designed to treat the El Boleo orebody involves a sulfuric acid leach in seawater using oxidative and then reductive leaching to maximize metal extraction. The leach solution is separated from the barren solids via counter current washing through a series of high rate thickeners. Copper is recovered using conventional SX-EW processing as cathode. Zinc and cobalt are extracted from the copper SX raffinate after iron and aluminum precipitation. The CSIRO DSX solvent system (Versatic® 10 and LIX® 63 mixture) are used in this extraction. Manganese remains in the DSX raffinate and is recovered by soda ash addition as a high quality manganese carbonate precipitate. Zinc and cobalt are acid stripped from the loaded DSX solvent. Zinc is then re-extracted away from cobalt using Cyanex® 272 extractant and stripped into a highly concentrated strip liquor (+100 g/L Zn) and directed to either a spray dryer or a granulator for production of zinc sulfate monohydrate. The zinc solvent extraction raffinate, containing cobalt, advances to another SX circuit using Cyanex® 272, for the recovery of cobalt as cobalt cathode. In this paper, the detailed results from bench and integrated pilot plant testing for zinc recovery from the El Boleo ore will be described. The results of this testing are currently being used to engineer the commercial plant at El Boleo.

Jan 1, 2008

By Leslie S. Weldon

THE Lake Shore mine has been developed by two vertical shafts, with level intervals at 200 feet to the 2200 level and at 125 feet below this horizon. A main cross-cut joins the two shafts on all levels to the bottom of No. 3 shaft, and opening into these cross-cuts are the ore passes and sand passes, which are completed from surface To the 4450 level. In the west part of the mine, additional connections have been made between No. 1 and No. 2 veins, through which the major part of the ore from No. 2 vein west is routed to drifts in No. 1 vein. With the lesser amount of stoping on No. 1 vein, this arrangement permits better haulage to be maintained. The ore passes are driven at 50 degrees from the ends of short cross-cuts off the main ones and are broken through to the levels above at the mouths of the short cross-cuts, to allow for dumping on each level. The passes are controlled at each level by ball-and-chain gates and deliver to crushers and thence to loading pockets, shown in Figure 1. That system is quite flexible in that it is possible to by-pass the crushers at any station and load from either shaft at a number of different pockets. The sand passes are driven from the main cross-cuts at the same inclination as, and parallel to, the ore passes. Each is equipped with a chute and dump hole, so that waste or sand fill may be loaded or dumped at each level. A transfer door, hinged on the bottom, is installed opposite the chute for by-passing fill from one level to the next, and in the closed position protects the opening at the top of the pass. The dump hole situated beside the transfer door is protected by a grizzly with 10-inch spaces. Waste rock may be withdrawn from the system through No. 3 shaft loading pocket at the 2950 level to a waste bin on surface. Levels are developed by drifts in No. 1 and No. 2 veins for their entire lengths. Subsidiary breaks are followed at a later date, when full information has been obtained by exploration, and a considerable amount of development by sub-drifts is carried out in the upper part of the mine, particularly in more or less erratic sections of No. 1 vein.

Jan 1, 1936

By William E. Roscoe

"Mineral exploration properties are those on which an economically viable mineral deposit has not yet been discovered. Such properties are bought, sold, optioned and joint ventured on the basis of their perceived potential for the existence and discovery of a viable mineral deposit. The intrinsic value of an exploration property is therefore based on the exploration potential. One measure of the exploration potential is the amount that can be justified to spend on exploration for a viable deposit.The appraised value method uses a cost approach to value exploration properties. It is based on the premise that an exploration property is worth the meaningful past exploration expenditures plus warranted future costs to test remaining exploration potential. Results of past exploration work are analyzed in order to retain only those past expenditures that are productive in terms of identifying remaining potential. Warranted future costs comprise a reasonable exploration budget to test that potential.INTRODUCTIONThe purpose of this paper is to describe a cost approach to the valuation of mineral exploration properties and to provide some valuation examples. The particular cost approach described is the Appraised Value Method, which is best applied to mineral properties at the exploration stage.At present there are no comprehensive regulations or guidelines in Canada which specify what approaches and methods to use for the valuation of mineral properties. In this paper, the Appraised Value Method described is one method that the writer considers to be accepted industry practice for mineral properties at the exploration stage.Mineral properties are valued for a number of reasons, including mergers and acquisitions, non arm's length transactions, pricing of initial public offering of stock, support for property agreements, litigation, expropriation, and insurance claims."

Jan 1, 2003

By N. T. Avard

THE profitable disposal and utilization of much of our slack coal, lignite, and other low-grade fuels is one of the major problems facing the coal mining industry of Canada today. It is my belief that the pulverization process applied to these fuels opens the door to greater efficiency and greater prosperity, and I wish to discuss briefly with you some features of its development and advantages to date. Indeed, the art of burning pulverized coal under stationary boilers is one of the romances of modern engineering. As a Nova Scotian, I feel some pride in the fact that at Chignecto Mines, N.S., was built in 1906 the first pit-mouth power plant on the North American continent. This was built to make effective for the first time Edison's dream of carrying coal for power by wire rather than by rail. This plant, built by the Maritime Coal, Railway and Power Company, Limited, success-fully utilized underfeed stokers for twenty years but in 1927 was replaced by a more modern plant equipped with machinery for burning pulverized coal, which is now operating very successfully. A further source of pride is the fact that the first boilers on this continent to be operated by pulverized coal were installed by the Dominion Coal Company at New Waterford, N.S., in 1912 and were satisfactorily operated during the lifetime of the plant. It is an acknowledged fact that average living conditions on a large part of the North American continent are far superior to those of any other people on earth. The reason is that we use so much more machinery per capita, and cheap power supply has been a large factor in bringing that about. Statistics show that where one horse-power was used one hundred years ago to assist man in his work, five hundred horse-power is used today. Truly a remarkable development and the key to our present high standard of living. Lack of coal in the chief industrial centres of Canada has forced the extra-ordinary development of the water powers which Providence has placed in those centres. How many of us realize that Canada stands second in the world in the per capita development of hydro power, Switzerland being first and the United States sixth? From this condition, we are reminded of the fact that the per capita foreign trade of Canada far exceeds that of our great neighbour to the South-but another illustration of the benefits accruing from our great power development.

Jan 1, 1937

By Marvin E. Lane

Viburnum, located in the foothills of the Ozarks in south-east Missouri, is the site of a modern lead mining and milling operation. Two mines are currently producing a total of 5,000 tons per day and a third mine is in the final development stage, with full production scheduled for late this year (1964). These mines will supply the tonnage required to keep the Viburnum mill operating at a full capacity of 7,000 tons per day for many years. The efficient underground mining operation is completely trackless. Drill jumbos are used to break the ore in a room and pillar method of mining. Transloaders, or St. Joe shovels, and trucks do the loading and hauling. The Viburnum mill has a world-wide reputation as a most efficient operation. This is due to the extensive use of automatic process controls, and labour saving materials handling facilities. Introduction THE St. Joseph Lead Co., has operated lead mines in southeast Missouri for 100 years. These operations have been confined largely to the area called the

Jan 1, 1964

By J. L. Jobe

In planning the operation of a new mine or new sections of an operating mine, due provision must be made for the ultimate recovery of as much of the seam as is consistent with safety and economic principles. Each mining district and, indeed, each seam, especially in mining under submarine conditions, has individual problems which render hard and fast rules under all conditions of mining impossible. However, certain basic principles can be applied to all seams under specific conditions. In all mines, the two basic methods of mining, 'longwall' and ?room-and-pillar? or their variations, can be adopted, but certain fundamental factors must be analyzed before either method is finally applied to the extraction of the seam. The factors which enter into the successful, safe, and economic extraction of all seams are, briefly stated, as follows: (1) Character and thickness of the seam. (2) Character of the floor and immediate roof of the seam. (3) Composition, strength, and thickness of the overlying beds to the surface. (4) The depth of cover to the surface or sea bottom. (5) Conditions under which the seam is mined (land or submarine area). (6) Pitch of the seam. (7) Economic value of the seam. (8) Mining laws.

Jan 1, 1947

By Xuanxue Mo, Kaihui Yang

"Abstract- The Laochang mine, located in the Sanjiang area of southwestern Yunnan Province of China, is a volcanogenic massive Pb-Zn-Cu sulfide deposit. It is hosted by a pyroclastic sequence of Barly Carboniferous age, namely the lower member of the Yiliu Group, which was intruded by syenite and rhyolite porphyry . The volcanic suite is basaltic or basaltic-andesitic in composition, has alkaline affinities, and is associated with the initial rifting along the margin of the Baoshan-Shanstate continental rnicroplate (Yang, 1989). The ores are typically Pb>Zn>Cu in composition, averaging 3.820Jo Pb, 3.51% Zn, from 0.01% to 1.85% Cu (0.107% av.), a high average content of Ag (113 g/t) and recoverable amounts of Au, Tl, Gd, Ga, Ge, In. A massive sulflde zone, in which lenticular and stratiform orebodies are localized in a sulflde-carbonate-silica shale unit or sulfldic tufflte horizon that usually overlies coarse-grained pyroclastic rocks, is underlain by a stringer sulflde zone developed in a subvolcanic intrusion or volcanic sequence. The sulfide mineral assemblages, from the top to the bottom of the deposit, are: realgar + orpiment - galena + sphalerite + pyrite- chalcopyrite + pyrite + pyrrhotite + arsenopyrite. Oxide and sulfate minerais occur rarely in the massive ores. The massive ores are generally fine-grained and banded, but coarse-grained ore, colloform and framboidal texture, and growth-zoned pyrite and sphalerite are common. Sedimentary features such as graded bedding, brecciated and deformed ore clasts, and chaotically emplaced blocks, are well preserved, indicating that the massive orebodies have undergone slumping and dis­ placement. Alteration is weak in the hanging-wall rocks, but strong in the stringer zone. Two dis­ tinctive alteration zones have been identified: the upper zone, characterized by an assemblage of quartz, carbonates, chlorite, albite, zeolite and sericite, and the lower zone containing diopside, trema­ lite, actinolite, gamet, clinozoisite, and epidote.The general features of the Laochang deposit are in accord with the descriptive mode! of VMS deposits (Lydon, 1984). However, it falls into neither the Zn-Cu group nor the Zn-Pb-Cu group chemically (Franklin et al., 1981). The depositional setting of the Laochang deposit is quite different from Cyprus or Besshi-type massive sulfide deposits. Laochang is hosted by alkaline lavas that were erupted in a submarine continental rift. Although some features of the Laochang deposit are similar to those of Kuroko-type deposits, there are remarkable differences in the alteration mineral assemblage, the proportion of ore-forming elements (lead enriched) and the amounts of oxides and sulfates. These suggest corresponding differences in ore fluid composition and the associated ore-forming environment. Thus, the authors suggest that the Laochang deposit may be a distinct type of VMS deposit."

Jan 1, 1993

By Penny C. Stewart

Narrow vein underground stope design engineers in Australia have expressed significant interest in the requirements and methodology for developing site-specific stability charts. This is largely due to a concern that existing stope stability charts inadequately take into account factors influencing narrow vein stope stability, such as the effect of backfill abutments and the effect of in stope pillars. This paper presents conclusions from a comprehensive statistical examination of case history requirements for a site specific stability chart and critiques literature arguments for site-specific charts. A new statistical analysis technique and a large comprehensive stability database enabled the authors to quantify case history requirements and any site-specific effects the model exhibits. The analyses indicated that a reliable stable-failure boundary requires at least 150 case histories, of which a minimum of 10 percent should be unstable stope surfaces. Marginal site-specific effects were observed for the operating conditions captured within the database. The authors conclude that the apparent site-specific effects noted in previous literature are attributable to operating conditions inadequately represented in the database. Such operating conditions could induce erroneous stability predictions at any site, and are therefore not truly site-specific. Following from these conclusions, a strategy for taking into account operating conditions particularly relevant to narrow vein mining has been proposed. In particular, the development of a chart that accounts for the effect of backfill abutments on stope stability. Backfill abutment effects are particularly relevant to mechanised narrow vein mining methods such as modified Avoca. Collaboration from at least five sites is required to obtain access to relevant data and underground drives for geotechnical mapping. Preliminary estimations indicate that approximately three months fieldwork is required to meet case history requirements. CMS data in conjunction with 3-dimensional design software will be used to calculate equivalent linear overbreak/slough (ELOS). In contrast to stable, failure, major failure and caving categorical variables, ELOS is an objective and continuous stability variable and is therefore, more conducive to mathematical modelling.

Oct 1, 2001

By R. D. Brown

"""A matter of serious concern to the mining industry in British Columbia""; this comment reflects the attitude of the Mining Association of British Columbia toward the proposed new B.C. Mineral Royalties Act. The proposed legislation, introduced by the provincial government in February and now being debated by the legislature, combines a basic 5% royalty on the selling price, less approved p1ocessing and transpo1•tation costs, of minerals produced in B.C. with an ""excess"" royalty of 50% of any price increases over a predetetmined base. Government estimates project annual revenues of $20 million from the new royalty structure. The accuracy of these figures has been contested by the mining industry. Based on current world prices for copper the industry estimates that the provincial revenues from this mineral alone may run as high as $140 million in 1974 and $150 million in 1975. The Mining Association has warned that the new royalties “threaten to become confiscatory""."

Jan 1, 1974

By C. O. Stee

IN the October, 1936, issue of the Canadian Mining Journal there was published a series of very comprehensive and exccellently illustrated papers by Mr. C. O. Stee and members of his staff dealing with Siscoe operations and ore-bodies. These were, in the order in which they appeared: Geology of Siscoe Gold Mine, by O. L. BACKMAN Diesel Power at Siscoe Gold Mines, Ltd., by C. O. STEE andE. A. BLOMQUIST Mining at Siscoe, by L. T. POSTLE and W. F. Engineering and Surveying, Siscoe Milling Practice, Research and Testing Laboratory, Assaying of Mill Tails and Solutions, BROWN(6) by P. A. TEEPLE (7) by L. E. DJINGHEUZTAN by L. RIVETT (8) by G. IRWIN (9) The Editor of the Canadian Mining Journal cordially assented to our suggestion that these papers be reviewed at the 1937 Annual General Meeting of the Institute, and the authors very kindly accepted our invitation to present such reviews . Of these courtesies, full acknowledgment is here accorded. To our readers, we commend the original papers in the Canadian Mining Journal. The summaries presented at the meeting follow. EDITOR. THE GEOGLY OF THE SISCOE MINE The Siscoe gold deposits lie in and near a stock of granodiorite, related to the Bourlamaque batholith, which has intruded highly folded Keewatin volcanic rocks .. The volcanic rocks lie to the north of a belt of Timiskaming sediments.

Jan 1, 1937

By S. Steinlechner, G. Schneeberger, J. Antrekowitsch

The recycling of steel mill dusts is getting more and more important. The costs and requirements of land filling are rising and companies are interested in new recycling strategies. The rising of sustaina¬bility hand in hand with the high rate of valuable metals in these residues supports new research activities on the recycling sector. Especially zinc but also iron and lead are economical factors due to the treatment of steel mill dusts. This paper gives a small overview of fundamental studies concerning the chemical and physical composition of these dusts. Furthermore aggregates for the reduction of these dusts in the liquid phase are introduced and compared. The Flash-Reactor, the TBRC-Technology (Top Blown Rotary Converter) and submerged arc furnaces and there use for melting and treatment of these dusts are in the center of interest of this paper. The final conclusion gives an overview of possibilities for reduction of filter dusts in the liquid phase.

Jan 1, 2011

By John S. Stevenson

ZEBALLOS is a relatively new mining camp. It is on the west coast of Vancouver island, approximately 195 nautical miles northwestward from Victoria. Previous to 1934, a small amount of placer gold had been recovered from the Zeballos river and tributary creeks. However, it was not until the winter of 1934-35, when shipments of high-grade gold ore were made from the property of the White Star Gold Mines, Limited, that lode gold mining really began. Since then, several new mines and many promising prospects have been found. Milling in standard sized mills only commenced late in 1938, when the 75-ton mill of Privateer Mines, Limited, and the 50-ton mill of Spud Valley Gold Mines, limited, were first turned over. The most striking feature of the camp is the high-grade quality of the ore as usually mined. At one property, the ore along a drift 650 feet long has ranged from 5.8 ounces per ton to 17.5 ounces, over average vein-widths ranging from 8.3 inches to 14.5 inches in selected blocks along the drift. One . high-grade shipment of 196.6 pounds of ore from the same property contained 142.877 ounces of gold. The present paper deals only with that part of the area in which mining operations are most active, namely the main Zeballos River valley and its tributaries, Spud and Goldvalley creeks. During the summer of 1938, prospecting was carried on beyond this circumscribed area. The geology and early developments in the area have been described in the following reports: (1) CLOTHIER, G. A., Annual Report of the British Columbia Minister of Mines, 1929, p. 376; 1930, p. 441; 1932, p. 205; and 1933, pp. 252-254. (2) GuNNING, H. C., Geological Survey of Canada, Summary Report, 1932, Part A-II, pp. 29-50, Zebaltos River Area, Vancouver Island, B.C. (3) STEVENSON, John S., Annual Report of the British Columbia Min-ister of Mines, 1935, pp. F-38-40. ? ( 4) BANCROFT, M. F., Geological Survey of Canada, Memoir 204, 1937, Gold-Bearing Deposits on the West Coast of Vancouver Island Between Esperanza Inlet and Alberni Canal. (5) STEVENSON, John S., British Columbia Department of Mines, 1938, Lode-Gold Deposits of the Zeballos Area. (6) MAcDoNNELL, G. F., The Privateer Mine, Zeballos; The Miner, Van-couver, B.C., December, 1938.

Jan 1, 1939

By A. V. Corlett

MR. C. S. Gibson: Mr. Chairman, I listened with much interest to Mr. Corlett's paper. Those of us who are directly engaged in mine ventilation and dust control are impressed by the improved atmospheric conditions to be derived from the use of methods of mining such as those in operation at Aldermac, which Mr. Corlett has just described, and those employed at Noranda. It is a well known fact that drilling-dust is one of the most potent factors in the production of silicosis in mines handling ores containing quartz, so that from that angle the use of diamond drills, instead of percussion drills, to drill ore for blasts in stopes is an important development. A second point which I think merits mention is blasting. Blasting, we all know, creates the most dust in a mine and the fact that you can drill ore for a large blast with diamond drills and fire it, say, on Saturday night, and then have all the next day to ventilate the workings, is a great advance in dust control. 1 have wondered if Mr. Corlett, or possibly those at Noranda, can en-vision the use of the diamond drill as a means of advancing cross-cuts and drifts, preparing stopes, etc. I believe it is a matter which is receiving considerable attention at the moment in some parts of the world and J thought it would be interesting to have Mr. Corlett's reaction on that point. MR. A. V. CORLETT: I am not quite so hopeful of using diamond drills as a means of drilling holes in the ordinary drift. Maybe some of the diamond drill men can give us some further information on that point. MR. R. D. LoNGYEAR: The diamond drill manufacturers are working on that problem, but until further work is done we have nothing definite to offer. Drilling holes with a diamond drill to compete with rock drills for advancing drifts and cross-cuts is a desirable objective, because of the elimination of drilling dust and the ability to cut a smooth bore of uniform diameter. To reach this objective, higher rates of penetration are required, which can only be achieved by discovering the optimum bit rotating speed, by reducing vibration, and by further improving the bits and machines. We are optimistic, but the problem is still largely in the research stage.

Jan 1, 1940

By William J. Davis, R. Blair Hrabi, Sally Pehrsson, Amelia V. Logan, Ross Sherlock

"Abstract - The Meadowbank gold deposits are hosted by a series of polydeformed and metamorphosed auriferous iron formations located in the Neoarchean Woodburn Lake group, western Churchill province, Nunavut. The supracrustal rocks in the Meadowbank area consist of a thick sequence of intermediate-composition volcanic rocks with intercalated iron formation, ultramafic volcanic rocks, and quartzite to quartz arenite. U-Pb geochronology gives an interpreted age of 2711 ± 3 Ma for the host strata at Meadowbank.The intermediate volcanic rocks are predominately volcaniclastic and have a geochemical composition that is consistent with an active continental margin setting. Iron formation deposition was coeval with the intermediate volcanism, as indicated by incorporation of volcanic detritus in the chemical precipitate. The geochemistry of the iron formation indicates that it precipitated from a fluid that at one time was at high temperature (>250°C), reducing, and likely acidic. Intercalated ultramafic rocks rarely show spinifex textures and have trace element ratios that are consistent with mantle plume-related undepleted mantle asthenosphere, likely recording episodic mantle upwelling associated with rifting in an active continental margin. The contact between the ultramafic volcanic rocks and the overlying quartz arenite is a disconformity marked by a quartz pebble conglomerate. However, similar geology on the structural hanging wall and footwall of the contact suggests that the conglomerate does not represent a significant hiatus in deposition, and is more likely a prograding terriginous siliciclastic unit.Three metamorphic events are recognized. The first, M1, is a cryptic greenschist facies event that is pre-D2. The second event, M2, is a mid-greenschist to amphibolite facies, syn-D2 event. M3 is the last event recognized, and is a post-tectonic greenschist facies event that is regional but inhomogeneous in extent, possibly reflecting thermal aureoles around post-tectonic 1.7 to 1.8 Ga Nueltin granites. The structural geology of the area is complex with four phases of deformation recognized, two of which had a significant effect on the geometry of the deposit. All of these regional events are interpreted as Paleoproterozoic in age. Relationships between deformation fabrics and mineralization, as well as the overall geometry of the mineralized envelopes, suggest that the deposit formed during syn- to late-D2. Superimposed on the mineralization are D4 structural elements that postdate gold mineralization.The main control on gold mineralization is replacement of magnetite by pyrrhotite and pyrite in high-strain corridors. The composition of amphiboles and chlorites associated with gold mineralization is remarkably consistent and shows no spatial or temporal variation, suggesting that it was buffered by the iron-rich nature of the host rocks. The bulk metasomatic effect on the intermediate volcanic rocks is characterized by the addition of K2O and the loss of CaO, Na2O, and MgO, with little variation in the total iron content. The elemental losses are likely the result of destruction of feldspars, stilpnomelane, and ferroactinolite, which are relatively common in the unmineralized rocks, and the formation of sericite, chlorite, and grunerite."

Jan 1, 2004

By D. Duffy, V. Papangelakis

"MgCl2 brines present a number of potential advantages for the processing of saprolite ores for nickel production. With a chloride system it is economically requisite to recover hydrochloric acid, which can be performed in a more energy efficient manner by precipitation and subsequent decomposition, as compared with conventional pyrohydrolysis. In addition, concentrated MgCl2 solutions enhance the activity of acid used, allow atmospheric leaching at elevated temperature and inhibit magnesium dissolution, which reduces acid consumption and increases metal selectivity. Leaching and iron control experiments have been conducted in concentrated MgCl2 brines, up to 4.5 m, to determine the most amenable process conditions. INTRODUCTIONChloride metallurgy has received an increasing amount of attention in recent years, especially with respect to the treatment of nickel laterites. Although the limonitic fraction can sometimes be economically treated by High Pressure Acid Leaching (HPAL), acid-consumption problems are encountered with the higher magnesium content of the saprolite fraction. As magnesium does not hydrolyze under HPAL conditions, as iron and aluminum do, any sulphuric acid used to leach magnesium is subsequently neutralized and wasted. In addition, this magnesium must later be disposed of in some fashion, further complicating the process. The most common method used to process saprolite is the Rotary Kiln-Electric Furnace (RKEF). This uses a kiln to dry and preferentially reduce nickel, before sending the calcine to an electric furnace. Although nickel recoveries are high, and the problems of acid consumption are avoided, the capital and energy costs associated with this process are high (de Bakker, 2011).The problems outlined above have led to the investigation of an atmospheric chloride process for the treatment of saprolite ores. The use of a chloride system presents a number of advantages, but also a few limitations. Metal chlorides tend to be very soluble, with a few notable exceptions (silver, mercury and lead), allowing for smaller processing equipment through more concentrated solutions. This solubility also serves to reduce the potential for scale formation. In addition, a hydrochloric acid leach is more aggressive than a comparable sulphuric acid system, and the activity of the hydrogen ion can be augmented by further chloride addition (Peek, 2011). This activity augmentation in concentrated chloride systems, first reported by Jansz, has repeatedly been referenced as a motivating factor behind chloride hydrometallurgy (Jansz, 1983; Harris and Magee, 2003; Harris et al., 2004; Demopoulos et al., 2008; McDonald and Whittington, 2008; Demopoulos, 2011; Peek, 2011; Verhulst and Lakshmanan, 2011). This activity increase allows a similar amount of acid to perform more in a concentrated solution than in a dilute solution, decreasing overall acid requirements. As such, much focus has been placed on leaching in concentrated chloride systems, or brines, using calcium, magnesium or sodium as the cation (McDonald and Whittington, 2008)."

Jan 1, 2012

By E. L. Bruce

Introduction The Outokumpu copper mine is situated in eastern Finland, 50 kilometers west of the city of Joensuu or 225 kilometers directly north of the city of Viborg (Viipuri), which is situated at the eastern end of the gulf of Finland (Figure 1). The ore-body was discovered in 1910 by Dr. Otto Trüstedt after two years of careful, scientifically-directed, search. During the early period of development of the mine, the ore was treated locally and the copper re-covered by an electrolytic process. Now the ore is concentrated by tables and by flotation. The concentrates are shipped to Germany for refining. In 1929 the mine produced 150,000 tons of ore from which between 20,000 and 25,000 tons of flotation concentrates containing 20 per cent copper were produced. Profits in 1929 were approximately half a million dollars, but the present price of copper will affect very seriously the profits for 1930. The ore reserves are given as between 7 and 8 million tons (1). The grade of ore is stated to be 4 percent to 6 percent copper, with a little zinc.

Jan 1, 1931

By Thom Mambe, Angelo Fernando

The objective of this work was to identify key parameters related to the reduction of the sulphur content in ammonium diuranate (ADU), and the identification of solid products being formed under various operating conditions. A laboratory-scale, continuous ADU precipitation circuit was assembled using a glass reactor vessel immersed in a temperature-controlled water bath. A pre-prepared uranium feed solution was fed continuously using a peristaltic pump. Anhydrous ammonia mixed with compressed air was metered and pumped using a double-headed peristaltic pump. An over-head mixer was used to keep the solids in suspension. The precipitated ADU slurry was removed from the reactor at the same flow rate as the feed solution. The slurry was sampled to generate ADU solids for chemical and physical analysis after four hours of continuous operation to ensure steady-state conditions. The following variables were studied to determine their influence on the sulphur content in the resulting ADU. (a) sulphate:uranium molar ratio in the reactor (1:1, 1:5, 1:10 and 1:20) (b) precipitation pH ( pH 6, 6.5, 6.9, 7.5 and 9) and (c) precipitation temperature (40C and 60C) A total of 18 tests covering the above parameters were conducted, and the results indicated that the sulphur content in the resulting solids was highly dependent on the reaction pH. Out of the pH levels tested, tests completed at pH 6.9 and 7.5 generated solids containing the lowest sulphur contents, between 0.5 to 1.5% S uranium basis (UB). The sulphur content in solids was found to vary linearly with the sulphate:uranium ratio in the feed solution, showing a statistically valid correlation. The impact of temperature was minor between 40°C and 60°C, with a slight advantage at higher temperatures. Tests at a sulphate:uranium ratio of 1:1 produced solids with the lowest sulphur contents. The influence of pH or temperature on sulphur content in solids was almost non-existent at this sulphate:uranium ratio. Precipitation pH is the major factor influencing ADU sulphur content, followed by the uranium to sulphate ratio.

Jan 1, 2020

By C. Edwards

"The processes for rare earth (RE) extraction include the decomposition of RE ore concentrate minerals, and the concurrent or subsequent leaching of the rare earth elements (REEs) from the decomposed minerals. Ore beneficiation concentrate can be decomposed by, for example, acid roasting, caustic cracking, and chlorination. The REEs can be selectively extracted. The nature of the REE extraction process depends on the concentrate mineralogy and the targeted products. Based on the experience of the Saskatchewan Research Council (SRC) in RE processing, this paper reviews REE extraction from the major RE minerals, including bastnaesite, monazite, xenotime, ion-adsorption clay, allanite, cerite, and eudialyte. An update on the development of RE extraction processes is also provided.INTRODUCTIONRE processing usually involves two operation stages, physical processing and chemical processing. Physical processing, also known as ore beneficiation, separates the RE minerals from gangue minerals to produce an RE mineral concentrate. Chemical processing, which includes extraction and separation processes, converts the RE mineral concentrate to an RE compound which is either an end product or an intermediate product for the subsequent production of individual REEs or other compounds. The RE extraction process uses one or more reagents to decompose the RE minerals and to leach the REEs into solution. The RE separation process uses solvent extraction, ion-exchange, or chemical precipitation to produce either rare earth oxides (REOs) or individual REEs. The authors have previously reviewed RE ore beneficiation processes (Zhang & Edwards, 2012). This paper focuses on extraction processes for a variety of RE minerals. Table 1 gives the chemical compositions of the RE minerals mentioned in this paper. The varieties of RE extraction methods use many different reagents. These reagents are mainly inorganic acids, alkalis, salts, and chlorine gas. The commonly used acids include sulfuric acid (H2SO4), hydrochloric acid (HCl), and nitric acid (HNO3). Sodium hydroxide (NaOH) and sodium carbonate (Na2CO3) are the most common alkalis. Salts include ammonium sulphate ((NH4)2SO4), ammonium chloride (NH4Cl), and sodium chloride (NaCl). HCl is normally used to extract RE from silicate ore minerals such as allanite and gadolinite. The alkalis and H2SO4 are mainly used to leach REs from phosphate ores minerals like monazite and xenotime. The carbonate ore RE minerals such as bastnaesite can be treated using either acids or alkalis. HNO3 is mainly used to leach eudialyte and apatite. The extraction of REs from ionadsorption clay deposits uses salt solutions. Chlorine gas (Cl2) is exclusively used in the RE chlorination process which can be used to treat any RE minerals."

Jan 1, 2012

By G. Van Weert, O. Wang

ABSTRACT: When exposed to microwaves, rocks containing sulphides adsorb energy preferentially over barren gangue and quickly become warmer with minimal energy consumption. This effect makes subsequent machine sorting of ore from waste rocks or overburden possible using infrared sensing. This paper reports on the 2450 MHz microwave response of a variety of sulphide minerals by mesh size and spatial distribution, as they might occur in ore rocks. The implications for infrared ore sorting are discussed.

Jan 1, 2011

By G. Van Weert

ABSTRACT When exposed to microwaves, rocks containing sulphides adsorb energy preferentially over barren gangue and quickly become warmer with minimal energy consumption. This effect makes subsequent machine sorting of ore from waste rocks or overburden possible using infrared sensing. This paper reports on the 2450 MHz microwave response of a variety of sulphide minerals by mesh size and spatial distribution, as they might occur in ore rocks. The implications for infrared ore sorting are discussed.

Aug 1, 2011