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By K. C. Marsden, B. Pesic

"Interest in the efficient production and recycling of rare earth elements has increased in recent years along with the prices of these elements. The molten LiCl-KCl eutectic is one ionic solvent which can be utilized for these purposes. The LiCl-KCl eutectic has also been selected as the electrolyte for focused research for advanced pyrochemical recycling processes for used nuclear fuel in several nations. Rare earth elements are fission products with notable neutron absorption characteristics, and thorough understanding of the properties and behavior of these elements is critical to their successful partition from the electrochemically-similar actinide elements. The number of research papers investigating individual rare earth elements has greatly expanded in the approximately 35 years since the last review. These research papers are presented in a variety of languages and technical formats, making data difficult to compare, and are sometimes contradictory. A review and summary of diffusion properties of rare earths in LiCl-KCl eutectic was performed, and the data translated to a common format for evaluation. INTRODUCTIONThe rare earth elements have experienced growing importance in recent decades due to their application in high technology, including optical lenses, lasers, high-temperature superconductors, improved alloys, high energy-density batteries, and powerful magnets for compact electronic devices. Their historic production methods and uses are detailed in several texts (Hampel 1971; Bautista &Jackson 1992; Gupta & Krishnamurthy 2005). A s the p rice o f these e lements has r isen in r ecent years, so has interest in their efficient production and possible recycling options. Rare earth oxides are concentrated through hydrometallurgical techniques, but the high thermochemical stability of their oxides precludes production of rare earth metals in aqueous systems. However, the wide electrochemical window and better control of pO2- in fused salt systems allows the production of these reactive metals from their halides or oxides. The high ionic conductivity and diffusivity of the molten ionic electrolyte allow high currents with limited resistive losses (Fray 1980). Electrolytic methods in fused salts are commonly adopted for the production of bulk rare earths in a variety of molten salt systems. Fluorides are sometimes proposed for oxide electrowinning processes due to ability to dissolve the rare earth oxide, reduced hygroscopic behavior, and the wider electrochemical separation between O2 and halide gas evolution (Mohan Das, Damodaran et al. 1988; Gibilaro, Pivato et al. 2011). However, in most electrolytic production processes, such as that for mischmetal, the rare earth oxides are converted to chloride prior to electrolysis in a chloride bath (Gschneidner Jr. & Eyring 1978; Sharma 1987). Of the chlorides, the LiCl-KCl eutectic is one specific medium in which metal production and production-related investigations have been conducted (Gschneidner J r. & Eyring 1978; Driscoll & Fray 1993). L iCl-KCl eutectic has the advantages o f h igh conductivity, but relatively low viscosity and operating temperature. The low operating temperature allows simpler design, with reduced energy consumption, salt volatility and cell corrosion."

Jan 1, 2012

By A. Brown

IN INTRODUCING the subject of rock pressures, it may safely be assumed that mining men are only too familiar with the physical effects of strata stresses that accompany the extraction of minerals. It may be further assumed that they have, as individuals, arrived at certain conclusions regarding their nature, based upon years spent in observing such phenomena and in learning how to continue mining in spite of them. Such hardly won experience forms the core of what is often referred to as 'pit sense'. This essential type of knowledge is not ?based on theoretical considerations, nor can it be found in text books. It is highly individualistic in nature and almost impossible to pass on from one generation to another in terms of precise rules for guidance. It is this aspect of individual judgment based on practical experience that has led to the significant phrase The Art of Mining.

Jan 1, 1956

By J. R. Kish, J. Dabrowski

"The susceptibility to intergranular corrosion modes is a major technical issue preventing widespread utilization of higher strength welded AA7xxx extruded beam profiles, in the peak-aged T6 condition, in automotive bumper assemblies. A study was undertaken to evaluate the relative exfoliation corrosion resistance (ASTM G85-A2) as a function of joint design parameters, namely the base alloy composition, heat-treated condition and beam orientation after exposure to a cyclic acidified salt spray test. This paper documents the major findings extracted from this study.INTRODUCTIONBumper systems play a predominant role in the passive safety of an automobile, since they are one of the main structures for absorbing the collision energy in the event of an automobile crash. Heattreatable AA6xxx-series (Al-Mg-Si) and AA7xxx-series (Al-Zn-Mg) Al alloys, with relatively high strength, toughness, energy absorption, weldability and formability, make it possible to design costcompetitive bumper systems to crush in a controlled fashion. In this context, Cu-lean AA7xxx extrusions, such as AA7003 and AA7108, which exhibit higher strength than AA6xxx extrusion, such as AA6082, represent an attractive light weight material from which to fabricate bumper assemblies (Clausen et al., 2000; Pedersen et al., 2008; Chen et al., 2009).Arc welding is a key joining process for AA7xxx alloys within the transportation industry. A major technological issue preventing widespread utilization of arc-welded AA7xxx joints is the susceptibility to severe localized corrosion (Kent, 1970, Reboul et al., 1985; Holroyd et al., 1987). It generally occurs as exfoliation corrosion within a heat affected zone (HAZ) a few millimeters from the weld bead, or a type of stress corrosion cracking (weld-toe cracking), which initiates at the weld toe and propagates into the interfacial region between the weld bead and the HAZ (so called “white zone”). In addition to the micro-galvanic cell activity induced by the intermetallic compound constituent and strengthening particles present, there is strong evidence that macro-galvanic cell activity between the weld bead and base AA7xxx alloy may be playing a controlling role. Electrochemical profiles taken across fusion welded joints, in cross-section, during exposure to saline solutions suggest that a significant potential difference exists across the AA7xxx arc-welded joint (Shumaker et al., 1967; Grauer and Wiedmer, 1980; Tuck, 1985, Onoro and Ranninger, 1993). These studies consistently show that the HAZ and base alloy are more electronegative with respect to the weld bead (arc-welded with AA5xxx filler wire). Despite this initial important work, the majority of the recent corrosion research effort on welded AA7xxx alloys has focused on the performance of friction stir welds (Lumsden et al., 1999; Wadeson et al., 2006; Hatamleh et al., 2009)."

Jan 1, 2012

By F. Awotwe-Appiah, P. Koshy, J. Dankwah, J. R. Dankwah

This research investigates the generation of an effective carbonaceous material from waste ‘pure water sachets’ and their subsequent utilisation as reductants for the reduction of the Opon Mansi iron ore. Composite pellets of Opon Mansi iron ore and pulverised carbonaceous material generated from waste pure water sachets were heated from room temperature to 1200 °C in a gas fired furnace for seventy minutes. The reduced pellet was analysed chemically for its oxygen and carbon content using a LECO Oxygen/Nitrogen and LECO Carbon/Sulphur analysers, respectively. It was observed that nuggets of metallic iron were readily produced with the carbonaceous materials acting as an effective reductant and source of chemical energy. XRD analysis of waste ‘pure water sachets’ revealed that the polymer was semi-crystalline with peaks that were identical to those of high density polyethylene (HDPE). Gas emission behaviour of the iron ore-PWS pellet was studied in a horizontal tube furnace at 1200 °C using an infrared gas analyser; the results revealed an exhaust gas rich in the reducing gases CO and CH4 along with CO2.

Jan 1, 2015

By E. R. Weltevreden, C. Klauber, C. Vernon

"In this paper a review of the current status in recycling technologies for cathode ray tubes is given for both the glass and phosphors. Particular emphasis is placed on the opportunities for the recovery of the rare earth elements (REE) from the phosphor coatings. This is placed in the market context of alternative virgin sources and some of the advantages and disadvantages for REE waste recovery. Future opportunities are explored and also some experimental detail on a low cost leach system is presented. INTRODUCTIONThe disposal of cathode ray tube (CRT) based colour televisions has accelerated world-wide with the development of high definition flat screen panels. The total number of colour CRT televisions that have been sold in the United States in the mid-20th century is estimated to have been over 2 billion (U.S. Environmental Protection Agency, 2007), with high current rates of disposal. It is estimated that of the 20 million televisions annually discarded, 78% are send to landfill (Nnorom, Osibanjo & Ogwuegbu, 2011). However, this easily accessible item of electronics cannot only be turned into a valuable resource using the right recovery procedures, it can also prevent the substantial environmental contamination arising from improper disposal. In this review we focus on previous and current work performed on the recycling of CRT based televisions. Due to the increasing demand for rare earth metals, the main focus will be on the possibilities and challenges of recycling the fluorescent phosphor powders on the CRT’s panel glass.CATHODE RAY TUBE’S GLASS RECYCLINGConventional cathode ray tubes consist of three main parts, the panel, the funnel and the neck (Figure 1). To produce the different colours on the screen, the inside of the panel is coated with a matrix of hundreds of thousands of small phosphor dots. Each dot is one of three types of coloured phosphors, emitting either red, green or blue light. These emit light when excited by a beam of electrons generated by electron guns located in the neck of the CRT. These beams pass through holes in the shadow mask and excite the phosphor coating on the inside of the panel, to give light of variable RGB composition, see Figure 1."

Jan 1, 2012

By James K. B. Booth

The natural crustal abundances of the principle metals of commerce are examined in relation to production and prices for each metal. Two factors, the abundance x price ratio (BP factor) and abundance/production (B/T factor) are listed for each metal. Ideally, for these desirable commercial metals, each factor should be a constant and the same for all metals; comparing the divergences for the full list of metals allows conclusions to be drawn on the relative degree of natural availability of each metal and the ease or difficulty of winning the metal from the earth's crust. Plotting the two factors for each metal over the past decade of steady industrial usage illustrates the anomalous position of copper and, to a lesser degree, molybdenum and it is concluded that over the long term the price of copper will continue to rise steeply. Possible future prices for copper are examined and a suggested preferred order of ranking of the metals as exploration targets would be copper, nickel, tin, zinc, silver, molybdenum and lead, for the near term, with molybdenum possibly increasing its ranking in the list within the next decade.

Jan 1, 1971

By T. A. Utigard, S. Pedler

Ilmenite from the Everett deposit in Quebec was characterized both chemically and mineralogically. The sample investigated contained the following main components: 40% Fe2O3, 21% TiO2 and 21% SiO2. The ilmenite grains contained about 20 to 25% hematite intergrown blades, with widths ranging from 2 to 30 \u03bcm. Crushing the sample to less than 0.85 mm led to significant liberation of the ilmenite from the gangue minerals. Gravity separation followed by magnetic separation of this size fraction led to a TiO2 concentrate grading of about 30% TiO2, with a recovery of 94%.

Jan 1, 2010

By Robin E. Goad

?Located 160 Km northwest of Yellowknife, NWT, Canada Current winter road access ?New all-weather road planned ?Power within 22 km ?Hwy to Edmonton 80 km south Close to existing infrastructure

May 1, 2006

By C. Hu

A MOS capacitor hydrogen sensor array is reported for hydrogen gas distribution mapping. Si(100) was used as substrate for film deposition. After silicon oxide growing on the silicon surface with dry thermal oxidation, palladium film was sputtered on silicon oxide as hydrogen-sensitive gate material in MOS structure. The 3x3 sensor array was patterned on silicon substrate and packaged in one chip. Sensors' response was test with impedance analyzer. The sensors in array were calibrated in the hydrogen concentration range from 10ppm to 10000ppm. The 2D hydrogen concentration distribution was obtained with the calibrated sensor array.

Jan 1, 2005

By M. Gauthier, A. C. Brown

"Monometallic zinc mineralization associated with marbles of the Grenville Supergroup in the Mont-Laurier Basin of Quebec is found to be stratiform and to occur (1) within limited zones of dolomitic marble and (2) more precisely along contacts between these marbles and adjacent metaclastic units. Massive sphalerite with accompanying pyrrhotite and pyrite is the prime exploration target, and commonly gives rise to good geochemical anomalies, but generally weak and ambiguous geophysical responses. Disseminated sphalerite in dolomitic marbles may signal proximity to interesting massive mineralization, although, due to weathering, this broadly disseminated mineralization may not be detected easily on outcrops. It is concluded that the western and possibly the eastern margin of the Mont-Laurier Basin constitute favourable areas for continued exploration.IntroductionThe Grenville Supergroup marbles of Ontario, Quebec and New York State host numerous occurrences of zinc mineralization (Fig. I) , several of which have been periodically mined since the beginning of this century (Fig. 2). The Balmat Edwards district of New York is the giant of this depo sit-type, with the production since 1915 of some 20 million tons of ore grading 10% zinc, and acknowledged current reserves of approximately equal tonnage and grade. At present, there is renewed interest in the potential for similar mineralization throughout the Grenville Supergroup, and this paper outlines some of the geological, geochemical and geophysical guidelines that may be employed in the search for new ore. The geologic guidelines are derived especially from lithologic and stratigraphic features which survived intense, multiphase deformation and metamorphism.Although major portions of the extensive Grenville Supergroup hold potential for zinc mineralization, the present study is confined to a known zone of mineralization in the Mont-Laurier Basin of Quebec. Concurrently, we are compiling information on the regional metallogeny of the basin so that our conclusions can be applied to areas of similar Grenville Supergroup host-rocks elsewhere."

Jan 1, 1980

By A. J. Monhemius

This paper reviews the history of modern iron-control processes in hydrometallurgy. Attention is paid to processes developed in the electrolytic zinc industry for removal of iron from zinc sulfate leach liquors and the problems faced by the industry in the safe disposal of the iron residues produced by these processes. Past lessons learned are projected onto current efforts to develop hydrometallurgical processes for treatment of copper sulfide concentrates. It is argued that any attempt to create a \u201chydrometallurgical copper smelter\u201d will fail, unless methods are developed that can recover iron in a form that can be directly used by the steel or pigment industries.

Jan 1, 2017

By R. A. Price

The base of the biozone of Olenellus is accepted as the most universally applicable criterion for defining the base of the Cambrian System. The use of this definitive criterion is restricted by important practical considerations. In the southeastern Canadian Cordillera this zone appears to truncate the basal ortho-quartzite of a west to east marine -transgression. This transgression began in Interior British Columbia in the Late Proterozoic and terminated in the region of the present Rockies in the Late Waucobian. Most of the material deposited by the transgressing sea originated in the eastern positive element 'Laurentia' and was transported over the intervening low Proterozoic-Windermere erosion surface. The configuration of the advancing shoreline and the distribution of the sediments were controlled by the tectonic activity of positive elements in northwestern Montana (Montania) and in the Fairmont Hot Springs-Radium area of British Columbia.

Jan 1, 1956

By E. Howard Lambert

"Operating costs of mining plants are increasing due to the increased cost of labour, materials and fuels. Labour and materials costs are factors not readily controlled. However, the use of energy from fuels may be controlled by plant operations. This paper describes the fossil fuels, their expected rate of depletion and their costs. The paper considers methods which may be used to provide an efficient use of energy from fuels. It includes an outline of obtaining energy, as heat, from mine milling operations (air compression) and obtaining the maximum use of energy from fuels used to generate electricity."

Jan 1, 1973

By Mauro Torres, Gabriel Zarate

"AngloAmerican used the extractant M5640 at Mantos Blancos and Mantoverde and uses PT5050MD at Los Bronces Division, which are aldoxime and modifier blends. In the first case, the modifier is the esther TXIB, while in the second case is the tridecanol TDA. It is a well-known fact that the extractant degrades while the modifier does not and with time the oxime/modifier ratio can change significantly, depending on the operating conditions of each plant.In order to evaluate the effect of this varying modifier content in the plant organic, especially in the organic losses, a complete metallurgical test work program was conducted at laboratory and pilot plant scale by Flomin SNF, a new extractant supplier. Results showed that the addition of an aldoxime without the modifier did not affect the chemical performance of the extractant, but there was a significant decrease in the viscosity and density of the organic.Based on the results obtained in the metallurgical program, it was decided to run plant scale tests at the SX plants of Mantos Blancos and Mantoverde. In these tests, instead of adding extractant to maintain the organic inventory, CuPROMEX 3406 which is an unmodified aldoxime was added until the original oxime/modifier ratio was reached. This was obtained after 6 months of operation and since then both plants are running with the extractant CuPROMEX 3302 both supplied by Flomin SNF.In the case of Los Bronces, the pilot plant work was completed and it is programmed to run similar plant scale tests. In this case, the oxime/modifier ratio increased and TDA will be added until reaching the original ratio.The plant results obtained at Mantoverde and Mantos Blancos, together with the pilot plant test results obtained at Los Bronces, are discussed in this paper."

Jan 1, 2016

By X. G. Zhao, M. Cai, L. K. Ma, P. F. Li

"Crack initiation stress is one of the characteristic stress thresholds in the rock deformation process under compression. By analyzing AE responses of brittle rocks in uniaxial compression, a new method which is called cumulative AE hit (CAEH) method is proposed for determining the crack initiation stress. An advantage of the CAEH method is that the method removes the user's subjective judgment. To verify the CAEH method, uniaxial compression tests with AE measurement using 77 crystalline rock specimens were conducted. The test specimens cover eight rock classes with different mineral grain distributions. Crack initiation stresses of these specimens were determined by the proposed CAEH method and the LSR method, and the resulting mean crack initiation stresses determined using the two methods were comparable. In addition, taking one rock class with 20 specimens for example, the mean crack initiation stresses determined using the CAEH method and those from several established strain-based and AE-based methods were similar. Hence, the CAEH method can be used as an alternative method for crack initiation stress determination.INTRODUCTIONExperimental observations indicate that the failure process of brittle rocks is associated with crack initiation, crack propagation, crack damage and final strain localization (Brace et al., 1966; Bieniawski, 1967; Lockner, 1993; Wawersik & Fairhurst, 1970). Compression tests on cylindrical specimen are often used to characterize the crack development process. The crack initiation stress (sci), crack damage stress (scd), and peak stress (sc) represent important stress thresholds during the failure process of brittle rocks. Among the three characteristic stress magnitudes, sci is difficult to be determined objectively, directly from examining the stress–strain curves. Some researchers argued that sci obtained from laboratory compression tests is an important parameter for estimating the spalling failure observed in brittle rocks around underground excavations (Andersson et al., 2009; Diederichs, 2007; Martin, 1997). sci can also be used to estimate rock tensile strength and Hoek-Brown failure criterion parameter mi (Cai, 2010). Over the last 40 years, various strain-based methods have been proposed to determine the crack initiation stress in compression tests (Brace et al., 1966; Diederichs, 2007; Eberhardt et al., 1998; Lajtai, 1974; Martin & Chandler, 1994; Stacey, 1981). Nicksiar and Martin (2012) proposed a Lateral Strain Response (LSR) method for establishing sci for low-porosity rocks. Meanwhile, they also used different strain-based methods to evaluate sci of Äspö diorite, and the results showed that all strain-based methods gave acceptable crack initiation stress values. Subsequently, they utilized the LSR method to further investigate the crack initiation stresses in igneous, metamorphic, and sedimentary rocks in compression tests (Nicksiar & Martin, 2013). Compared with previously proposed strain-based methods, an advantage of the LSR method is that it removes the user judgment when interpreting sci. However, the use of the LSR method relies on accurate determination of scd and on having a polynomial fitting equation to find the maximum LSR value."

Jan 1, 2015

By G. R. Heffernan

"IntroductionTHE PURPOSE of this paper is to give a •brief history of iron and steel in British Columbia, a quick look at the present operations of Western Canada Steel, Limited, a review of iron ore resources and iron and steel markets, and a projection of what the future might hold for the industry in British Columbia.From the Past to the PresentWhile the paper is entitled Past, Present, and Future, in covering the past, which we shall call the time prior to 1947, there is very little to be said. Small shipments of iron ore were made from the Texada deposits by the Puget Sound Iron Company from 1886 to 1907. Total ore shipped did not exceed 70,000 tons. Part of this is believed to have been used in building a United States battleship in 1907 in the Bremerton Naval Yards in Seattle, Washington.In 1914 a small steel mill was started on Lulu island, rolling bars from •box piles and used shafting. This mill operated spasmodically for a few years but finally burned down in 1921. The rolling mill stands were sold to China and are no doubt in operation in China today.In 1916 the City of Port Moody assisted in the financing of a mill which operated on re-roll rails, box piles, and steel ingots made in an experimental electric furnace in Port Moody. This furnace also produced small quantities of pig iron scrap. The backers of the Port Moody mill showed a great deal of enterprise and must have been a very forward looking group, since this was one of the first recorded applications of the electric furnace to small ingot production. Despite their enterprise, the operation was unsuccessful and terminated in 1921."

Jan 1, 1953

By G. G. Richards, Y. Oyediran, V. Chow

The oxygen softening process for partial removal of arsenic and antimony from lead bullion has been in use at Teck Cominco's Trail smelter since 1986. In this process, industrial oxygen is injected into bullion to remove As and Sb with the formation of an oxide slag. In Trail, the levels of these elements are reduced to concentrations suitable for processing in the Betts electrorefining plant. Recent moves toward the treatment of higher arsenic-bearing feeds have necessitated an increase in the process capacity to meet the specifications for drossing plant bullion. Process intensification trials were conducted in-plant to develop an operating strategy for higher bullion processing rates. This was preceded by a study conducted with McGill University to develop a fundamental understanding of the therm ochemistry and kinetics of the process. The results have yielded more effective control of the operation, and identified opportunities for further improvements.

Jan 1, 2008

By D. McConchie

BauxsolTM, prepared by treating bauxite refinery residues with Mg2+ and Ca2+, has an excellent ability to remove arsenic from acidic waters. The addition of BauxsolTM to sulphidic waste rock at the Gilt Edge Mine, South Dakota, reduced As concentrations in leachate water from 35 mg/L to < 0.005 mg/L; the concentrations have remained below 0.005 mg/L for the five years since the treatment was initiated. However, ordinary BauxsolTM does not effectively remove As from near-neutral water and it needs to be acid-treated or blended with small amounts of reagents, such as jarosite or ferrous sulphate, to increase the proportion of positively charged binding sites on the particles. The use of a jarosite/BauxsolTM blend can effectively treat ponded water, and As(V) concentrations can easily be reduced from over 1 mg/L to < 0.001 mg/L; As(III) has to be oxidised to As(V) for effective removal. Metal contaminants in the jarosite are trapped by the BauxsolTM and only very small amounts of the As, or other elements bound during treatment, are liberated using a TCLP leaching test. The exhausted treatment reagents meet the criteria for classification as an inert solid and do not need to be disposed of in a secure repository.

Jan 1, 2006

By Roland B. Hoag, Roger G. Webber

Sulphate concentration in groundwater is a good measure of the extent of oxidation of sulphides, provided that sulphide minerals are the primary source of the sulphate. A study was conducted near the Eustis Mine in Quebec to determine where and how the sulphate in groundwaters originated. Atmospheric precipitation is the only source of sulphate other than oxidation of sulphides, and in this study area it is equal to 0.01,. millimole per litre. The oxidation of sulphides can be divided into subsurface oxidation (mainly inorganic processes) and surface oxidation (including both organic and inorganic processes) . The maximum sulphate concentration due to subsurface oxidation of sulphides depends on the solubility of 0 2 in water and is 0.25 millimole per litre. Surface oxidation is, therefore, responsible for any amount greater than atmospheric plus subsurface contributions (0.29 millimole per litre). Surface inorganic oxidation occurs in waters with a pH greater than 15 and is controlled by the kinetics of the oxidation processes. Organic (bacterial) surface oxidation is dominant only in acid (pH< 1.5) waters. The bacterial action accelerates the oxidation of sulphides, and large quanttties of sulphate may be introduced into solution.

Jan 1, 1976

By Gordon L. Kidd

The object of this paper is to show the relations of the East Coulee coal area to the near-by Willow Creek, Wayne, Rosedale, and Drumheller areas, all being parts of the Drumheller field. The word ?area? is here used in a more local sense than that employed by Dr. J. A. Allan, whose. &apos;area&apos; is rather comparable with the &apos;mining division&apos; in British Columbia. I have drawn freely from the published information, particularly from Dr. Allan&apos;s report on the "Geology of Drumheller Coat Field, Alberta", and from Dr. E. Stansfield&apos;s paper on " A Chemical Survey of Alberta Coals", to whom thanks are due. The Drumheller field is served by branch lines of the two principal Canadian railways. The C.N.R. traverses the district by its Goose Lake line from Calgary to Saskatoon; and the C.P.R. by a line from Calgary to Acme and then southeasterly to Drumheller, where it effects a junction with the C.N.R., over which the C.P.R. has running rights as far as Rosedale. From Rosedale, a joint line built during the summer of 1928 extends about forty miles down the Red Deer river to the mouth of Bull Pond creek. From that point the C.P .R. turns more southerly to connect with the Bassano-Empress line. The C.N.R., it is expected, will eventually proceed eastward to connect with a transcontinental line. The joint line from Rosedale down the Red Deer river opened up the Willow Creek and East Coulee areas.

Jan 1, 1929