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By C Philander

The West Coast of South Africa is well known for its placer gem quality diamond deposits and also associated with these hosts of Cenozoic unconsolidated marine and aeolian sand and gravel are significant concentrations of heavy minerals. Exploration for economic concentrations of zircon, ilmenite and rutile along the coast started in the mid-1980s. This resulted in the discovery of an inferred 1.6 billion tonne resource with a grade of ten per cent total heavy minerals (THM), which developed into the Namakwa Sands Mine, a world-class producer of heavy minerals. Several other resources, including satellite deposits proximal and distal to the mine area, extensive diamond mine dumps and present day beach placers, demonstrate the vast heavy mineral potential along the West Coast. The favourable gangue to economic mineral ratio, a higher zircon content compared to other similar deposits, relatively lower U+TH content of zircon, low slimes content and effectively pristine low chromium-manganese ilmenite of these deposits, render them attractive exploration targets. Negative factors that will affect conventional mineral beneficiation and liberation include secondary mineral coatings and the regional coastal development of several layers of superimposed duricrust. The economically attractive heavy mineral assemblage along the West Coast is the result of erosion of the proximal, gneissic Namaqualand Metamorphic Province and mature Table Mountain Group sandstone, concentration by marine and aeolian processes and preservation under arid climatological conditions over a period of more than 100 Ma.

Jan 1, 2008

Western Mining Corporation (W.M.C.) operates a nickel refinery at Kwinana, 30 km south of Perth. The refinery commenced pro- duction in May 1970, with a rated capacity of 15 000 tpa of nickel metal. A hydrometallurgical route was chosen as the most expedient way to produce nickel metal at a time when world demand for nickel was outstripping the supply. Later events dictated that an increase in production from the refinery be achieved. To this end, matte produced from Kalgoorlie Nickel Smelter, which was commissioned in 1972, was used in varying proportions as a complement to the concentrate initially utilised as input to the refinery. The effect of matte addition was to increase the capacity to 30 000 tonnes of nickel per annum. This was accompanied by other benefits which were 1. reduction in energy consumption per unit of nickel produced, 2. improved metal extraction, 3. improved precious metal recovery, 4. reduced production of ammonium sulphate by-product. Refinery operating results for the years 1970 to 1983 show how matte feed has improved refinery performance in these areas.

Jan 1, 1984

By J M. Palin

Hydrothermal scheelite precipitated in fault-veins at Paradise, Bonnie Jean, Davidson's and Glenorchy mines display chemical variability involving REE patterns that are transitional between two end-member types. Type I is a MREE-enriched pattern with no or a small positive Eu anomaly. Type II is a flat to MREE-depleted pattern with a strong positive Eu anomaly. The chemical inhomogeneity of these scheelites can be explained by a model of fractional precipitation of REE, with preferential removal of MREE from the fluid during precipitation of scheelite. Irrespective of the mechanism responsible for scheelite precipitation, the source of dissolved constituents is different for scheelites from the Paradise Mine. Bonnie Jean, Davidson's and Glenorchy scheelites formed from LREE-enriched fluids whereas Paradise scheelites precipitated from fluids that were lower in LREE. These inferred fluid characteristics cannot be linked unambiguously to specific source rocks in the region, but could suggest that scheelite deposited in the Paradise fault-vein reflects a more mafic source of REE possibly greenschists, whereas the REE in scheelite from the other mines suggest a more felsic source.

Jan 1, 2003

The far reaching consequences of designing pillars for coal mines, while retaining concern for safety and economics, are cause for the search for refinement of the existing engineering methods to continue. Coal pillars, while having various functions within the overall mine plan, are the basic structural elements that assure the stability of a mine. Reliable coal pillar design methods take into account criteria which the pillars should meet in specific applications. These applications include typical mining situations such as the partial extraction room and pillar method with and without subsidence considerations, high extraction rate room and pillar, longwall mining chain pillars, and barrier pillars. However coal pillars are onlyu one element of a three element roof-pillar-floor system, weakest element of which system usually determines the stability of the excavations; however, the mining engineer can ony change dimensions of a pillar, properties of the surrounding strata remain beyond his control. The state of the art approach in pillar design places emphasis on recent developments in research. A widely encountered problem in certain coal fields is where pillars are underlain by weak floor strata. The resultant pillar design constantly maintains the perspective of the reliability of the design.

Jan 1, 1991

By Woodcock JT

This paper reviews the chemistry of flotation pulps with the aim of gaining a better understanding of the effect of chemical environment in flotation and ap- plying the knowledge to improving the con- trol of reagent additions. Theories of flotation are considered briefly, but they are only of limited help in specifying an appropriate chemical environment and in establishing control techniques. The chemical nature of flotation pulps is reviewed. Four distinct phases are present - solids, an aqueous liquor con- taining many dissolved reactive sub- stances, organic liquids, and gases. All of these vary in many ways and interact with each other. It has now been estab- lished that there are many previously- unsuspected materials present in plant pulps that can or might affect flotation. Concentration profiles of selected para- meters in operating plants are given to show some typical changes that occur. Recent advances in collector chemistry, especially that of xanthate and related species, are reviewed. Modes of decompo- sition and/or formation in pulps of xan- thate, dixanthogen, perxanthate, xanthyl thiosulphate, and monothiocarbonate are reviewed, and their W absorption spectra are compared. Some relevant information on dithiophosphates, mercaptobenzothia- zole, and thionocarbamate is summarized, and some speculative comments are made about reactions of these collectors.

Jan 1, 1984

By Grinenko VA

Mineralogical, chemical, and isotopic data have been obtained for samples from 11 volcanoes and 4 kortlandite intrusives on Kamchatka.Similarities and differences in ore-bearing and barren intrusives are discussed. Differences in sulphide mineralization and sulphur isotope compositions of intrusives are explained in terms of the "auto-sulphurization" hypothesis which involves the redox conditions of the host rocks. possible role for carbon in nickle sulphide ore formation is also considered.

Jan 1, 1990

Recent operating experience from West Australian open pit gold mines has shown that geotechnical input into initial design is rare. As a result, ground stability is poor - almost half the pits designed in this way suffer major failure.West Australian experience shows that geotechnical studies for individual mines are site specific, and therefore empirical experience cannot be transported from site to site. Geotechnical studies performed prior to design have resulted in significantly improved pit stability.

Jan 1, 1990

Solid EnergyÆs project evaluation process utilises a standard staged gate approach, with five levels leading ultimately to project execution (level 6). For a project to progress through each level, specific financial criteria need to be satisfied. Solid Energy primarily use value based (discounted cash flow) metrics to support investment decisions. Within this approach Solid Energy utilise a number risk-based techniques to quantify project uncertainty. This includes the use of risk-based probabilistic analysis using Monte Carlo simulation and probability-based scenario analysis. Figure 1 shows the net present value (NPV) cumulative probability. Project risks are identified through comprehensive risk workshops. The output of these workshops (list of key risks, ranges of uncertainty and probability of occurrence), is quantified within the financial models. Incorporating this risk information on a probabilistic basis allows an investment decision to be made with a robust knowledge of the range of possible project outcomes along with the likelihood (probability) of those outcomes occurring, for example 80 per cent confidence that the project value will be greater than NZ$10 M, 50 per cent confident it will be greater than NZ$50 M and ten per cent confident it will be greater than NZ$70 M. Incorporating risk implicitly into the financial analysis allows the business to easily evaluate/measure projects with different risk profiles. The detailed risk analysis does away with the complexity of arbitrary risk-based hurdle (discount) rates, as projects can be evaluated based on their specific risk characteristics. Whether a project will progress to the next level of investment and ultimately into implementation depends firstly on the value assessment in comparison with the associated risk/uncertainty, and secondly matching this with the businesses appetite for risk. At Solid Energy standard criteria are used for specific project evaluations, but in addition projects are considered on a portfolio or strategic basis also. Solid Energy attempts to maintain a mix of low risk (low value) projects with some high risk (high value) opportunities. The mix of projects must remain in line with the shareholdersÆ risk appetite. One of the keys to a successful investment decision is ensuring that the appropriate information is available to decision-makers so that they may proceed with a comprehensive understanding of the risks and impacts associated with the decision.

Jan 1, 2007

The Hartley layered mafic igneous complex within the Great Dyke of Zimbabwe contains economically-recoverable quantities of platinum group metals and gold, nickel, copper and cobalt. The recoverable metals are concentrated in a thin gently-dipping stratigraphic unit - the Main Sulphide Zone. The Hartley Platinum mine, jointly owned by BHP and Delta Gold NL, is scheduled to come on stream at the end of 1996 at an initial mining rate of 2.16 million tonnes per annum and will produce approximately 150 000 oz of platinum and 3300 tonnes per annum of nickel, as well as saleable amounts of palladium (110 000 oz), rhodium (11 500 oz) and copper (2232 tonnes).

Jan 1, 1996

By D La Rosa, W Valery, A Jankovic, S Ese

Metso Minerals Process Technology Asia-Pacific (MMPT-AP) has been working with many mining companies worldwide performing æMine to MillÆ or Process Integration and Optimisation (PIO) studies. MMPT-AP has developed a proven methodology to improve the efficiency of the mine-mill interface and gain maximum benefit. The PIO methodology involves rock characterisation, mathematical modelling and simulation to generate a list of operational and control changes for both the mine and concentrator. Following the methodology, the list of recommendations is developed relatively easily; the more challenging part depends on the company. Success of a PIO project relies on the ability of an organisation to implement change û both operationally and culturally: the human element. When a PIO project is started, there is initial interest and commitment from the company. But how can this be maintained? How does an operation know if the benefit continues? MMPT-AP is now developing long-term relationships with clients to ensure that the increased production and improved efficiency continues. Direct and indirect measurements are used to determine the key factors involved and to understand the cause/effect relationships. Simulation tools also can be used to compare current with recommended practices û so when material properties vary over time, the benefits can still be quantified. PIO is about empowerment: by measuring and understanding what parameters affect concentrator performance, the site personnel now have the knowledge to make a difference. Rather than simply reporting variable or poor concentrator performance, operations can predict when production will be affected and put controls in place to prevent it from happening. This requires support and commitment from the company or æbuy inÆ. Ensuring this buy in continues is the challenge facing every company involved in PIO work û but the benefits are well worth it. This paper will review MMPT-APÆs experiences in implementing PIO projects in the long term: from both the consulting and operational viewpoints. MMPT-APÆs involvement with a number of companies will be discussed as examples of what works and what does not.

Jan 1, 2007

By King D

Recent field experiments in the United Kingdom (Buchanan, 1979) have shown that the in-seam technique is capable of detecting a 1m fault in a 3m seam, at a range of 280m and with a resolution of ¦40m. Comparable tests in Australian collieries are proceeding. Although the practicality of an implementation of the technique on a routine basis remains to be demonstrated, the potential of the technique for the prediction of outbursts clearly warrants detailed examination. This potential will,depend, inter alia, on the level and scale of variations in elastic (and anelastic) properties of bodies of coal undergoing stresses associated with mining. Available data, mainly from studies of the seismic properties of gas saturated reservoir rocks, confirm the intuitive view that stress increases give rise to increases in seismic wave velocity and decreases in wave attenuation, markedly at low stresses (as pore spaces close with little resistance) but less so as stress increases. Such increases are of the same order as aniso- tropic effects, but should provide impedance contrast sufficient for detection by in-seam seismic methods. At higher stresses, cracks form within the rock mass. Results from research on earthquake prediction provide some clues to the behaviour of sedimentary rocks sub- jected to large stresses. In particular, the

Jan 1, 1980

To gain further understanding of the operating efficiency of the BHP Slab and Plate Products Division (SPPD) RH vacuum degasser, physical and mathematical model studies of the process have been undertaken. The purpose was to investigate how the various process parameters affect the liquid circulation rate, to visualise the flow patterns, and to identify and eliminate the cause of localised wear in the downleg. In the physical model mixing times were measured using an acid tracer technique. The results were applied to predicting trends in times required to obtain homogenous melt composition under varying conditions. A 2-dimensional mathematical model describing the liquid metal flow has been developed using the PHOENICS fluid-flow package. The physical model results were simulated and incorporated into the mathematical treatment and an improved design for vessel geometry is proposed. The effect of rounding the downleg entrance or installing a baffle between the legs is discussed.

Jan 1, 1987

By Hemingway J, Read T. A, Anderson V. G

IN the determination of very small amounts of lead, the usual analytical methods are far from being satisfactory. Small amounts of lead may be present in the reagents empioyed, and it is customary to run a blank experiment to correct the error arising in this way. When the correction is of small magnitude compared with the amount of lead in the sample, this procedure may be adopted; but when very small amounts of lead are being determined it may happen that the lead found in the blank is as much, or even more, than the lead actually present in the sample, and the analysis has to be rejected. Moreover, the blank experiment cannot check errors which are not common to the blank and the analysis itself eg, the apparatus used in the parallel experiments, etc. It seemed to be desirable, tl;l.erefore, to make an investigation of the problem to ascertain, as far as possible, the nature of the errors arising from the introduction or loss of lead during the analysis, and how far these could be eliminated or corrected for; also, to determine the limits of accuracy of the improved method and the minimum amount of lead that could be reliably estimated.In the investigation, reliability and sensitiveness were regarded as essential features. Speed of operation, on the other hand, was considered of less importance. The amounts of lead dealt with being usually less than 1 mg, there is no alternative to the use of a colorimetric method. The latter, depending as it does upon the development of a brown coloration when ammonium sulphide is added to a very dilute -solution of a lead salt, is far from being a characteristic test for lead. Indeed, it is well known that the salts of most of the commonly occurring metals interfere with this test. Hence it is of vital importance that the lead should be isolated in the form of a pure compound possessing quite definite and characteristic properties before the colorimetric estimation is proceeded with...

Jan 1, 1921

By P F. Knights

Mining companies are striving to achieve new levels of operational maturity and drive process improvement across the organisation in the face of unprecedented demand and limited supply of experienced human resources. Advanced analytics techniques can help overcome these fundamental challenges by applying data techniques not previously applied in mining. Today, decisions are usually locally optimised but do not achieve optimum capability for the value chain. Although more information is collected then ever before, it is difficult to link many sources of data together in the same place in real-time, for example plant history, maintenance, mine planning, logistics and engineering data. Consequently complex analysis of data is time consuming and requires specialist skills and knowledge, and is often neglected in the decision-making process. In the future, analytics will close the loop between analysing data and taking action. Analytics will become embedded in the business and routinely applied to improve decision making across the organisation, from senior management to operations and maintenance workers, but will not require specialist skills or be time consuming to analyse data. As analytics becomes embedded in the business process, decisions are supported by data (not on gut feel), and critically, data from many sources are integrated in real-time to improve the quality of decisions. Ultimately, predictive tools will help suggest, or even in some cases automate, courses of action. The main opportunities for analytics exist where the enterprise requires supporting technology to enable it to continue to evolve to higher level of maturity. This will be in the areas of asset management, rapid reconciliation and adaptive planning, and the inbound and outbound supply chains. Advanced analytics are also a key enabler for increasing the effectiveness and realising the true value of Remote Operations Centres to safely and efficiently support operations in remote locations with smaller workforces.

Jan 1, 2008

By M Roper, M Lovitt

WMC Resources Olympic Dam Operation located in South Australia, is a poly metallic underground sublevel open stoping (SLOS) mining operation with a current annual production rate in excess of 9.0 Mt. Stope size, geometries, geotechnical considerations, drilling and blasting are critical components in stope performance. These factors are further influenced by stringent ventilation requirements due to the presence of airborne radioactive contaminants from uranium mineralisation. Stope planning is complex and mass blasting methodologies have been trialled at Olympic Dam with the view to reducing the frequency of stope blasts, improving stope stability, productivity and ultimately improving overall stope performance. A key aspect in the ability to undertake underground mass blasts of this scale is the application of i-konTM electronic initiation technology by Orica. In the past two years in excess of three million tonnes has been initiated utilising this electronic technology, with an average blast of 250 000 t ranging to the largest to date being 580 000 t. By providing flexibility in blast designs, the use of electronic detonators has allowed mass firings over multiple sublevels. This has resulted in a significant reduction in stope extraction steps compared to conventional pyrotechnic firings. The benefits of this reduction in the number of stope blasts are wide ranging from improved stability of interim stope voids between blasts, reduced blasthole damage, improved blast vibration management and reduction of complex changes to ventilation systems for blasting.

Jan 1, 2004

By Heyes GW, Orrock GI

The fine grained complex orebody at Elura contains galena, silver and sphalerite in a matrix which is mostly pyrite; sulphides account for about 90% of the orebody. A differential flotation circuit is operated to con- centrate lead and silver in the first section and zinc in the second. The metallurgical performance to date indicates the need for improvement. The lead section has been sampled in detail to comprehensively assess its overall performance and to define problems associated with lead and silver flotation. The substantial amount of pyrite in the feed dominated the perfor- mance of each stage of the separation. It was responsible for extensive dilution of all concentrates and, as a consequence, for very large circulating loads. The rougher concentrate contained 68% pyrite some of which was rejected through the three stages of cleaning to 39% in the final concen- trate. However, this was still sufficient to hold the assay of this product below 45% Pb. Size by size behaviour shows that flotation rates of the valuable minerals, as characterised by their rate coefficients, were low through- out the circuit. There was a significant deterioration in these rates between rougher and cleaner I stages which resulted in large circulating loads between these stages. There was practically no recovery of coarse valu- able minerals to the final concentrate. The dilution of the final concen- trate by non-sulphide gangue was not a major problem. If the recovery of the galena and silver in the +38¦m size range could be raised to that of the - 381Lm size range, galena recovery would rise from 78% to 86% and silver recovery would improve from 46% to 59%. The Pb grade of the final concentrate would remain the same.

Jan 1, 1988

By T Mizuta, T Nakano, D Ishiyama

The Tamagawa Hot Spring, from which Ra-Pb-Sr-bearing barite precipitates, is a representative hot spring in a volcanic gas-bearing hydrothermal system associated with Quaternary andesitic to dacitic magmatic activity beneath the Yakeyama Volcano. Thermal water in the Tamagawa Hot Spring is divided into three types: Cl-SO4-type (Ohbuki hot spring: pH 1.2); SO4-type (pH 1.8 to 2.9); and neutral-type (pH 6.1). The concentrations of dissolved components in the Ohbuki Cl-SO4-type thermal water are about ten times higher than in the SO4-type thermal water. The 87Sr/86Sr isotopic signatures of the Ohbuki Cl-SO4-type thermal waters (0.703992 ¦ 0.000004 to 0.704032 ¦ 0.000006) are different from those of SO4-type thermal waters (0.704245 ¦ 0.000003) formed by the interaction of andesitic volcanic rocks (0.704065 ¦ 0.000007 to 0.704093 ¦ 0.000009) and groundwater derived from river water (0.704314 ¦ 0.000012 to 0.704519 ¦ 0.000013) in a shallower part of the hot spring area. The possible origins of Sr in the Ohbuki Cl-SO4-type thermal water and in the SO4-type thermal water are different. The Sr isotopic ratios (0.704130 ¦ 0.000012 to 0.707556 ¦ 0.000014) of Aniai Formation andPreYakeyama Lake deposits occurring below the hot spring area are distinctly higher than those of the Cl-SO4-type thermal water. However, it is expected that a solidifying andesitic or dacitic magma which has similar Sr isotopic ratios of the Ohbuki Cl-SO4-type thermal water, occur in the deep portion of the Tamagawa Hot Spring. The Cl-SO4-type thermal waters having low Sr isotopic ratios do not acquire their Sr isotopic signatures by interaction with strata below the hot spring area, but they are likely to reflect water interaction with a solidifying magma with low Sr isotopic ratios. Components including rare metals in Cl-SO4 type thermal water could be transported from a deeper part. An EXTENDED ABSTRACT is available for download. A full-length paper was not prepared for this presentation.

Jan 1, 2008

By D Craw

Interactions between structure and lithology in the Hyde-Macraes Shear Zone controlled the style of gold mineralisation at the Macraes mine. Large volumes of rock in some mine pits have most gold disseminated in hydrothermally altered schist, rather than in quartz veins. Mineralisation was initiated in the latter stages of metamorphism. Pods of massive schist rich in quartz and feldspar are surrounded by more fissile schist consisting of interlayered micaceous and quartzofeldspathic schist. Later shears have been partly controlled by the micaceous schist, and anastomose around pods of more massive schist. Micaceous schist was replaced by pyrite and arsenopyrite, accompanied by recrystallisation of phengitic muscovite under lower greenschist facies conditions. Gold occurs in sulfides and with microcrystalline quartz formed during minor silicification. Massive schist is locally mineralised along sulfidic microshears which have phengitic muscovite largely illitised under sub-greenschist facies conditions. Mineralised massive and micaceous schists were overprinted by cataclastic shears, with addition of graphite and more sulfides. Mineralisation occurred during a transition from ductile to brittle deformation regimes as the schist was uplifted in the late Jurassic.

Jan 1, 2004

By Rajan S, Mainwaring P, Gould WD, Beaulne M

Polished discs of a complex sulphide ore were leached with three lixiviants; a mixed culture of Thiobacillus ferrooxidans and Thiobacillus thiooxidans, Thiobacillus ferrooxidanalone, and ferric sulphate. At either one or two week intervals the discs were examined by scanning electron microscopy, and the amount of soluble metals released from the discs were determined. The mixed culture solubilized more Cu, Zn and Pb than did either ferric sulphate or T. ferrooxidans alone. However, no differ-ences were observed between the three treat-ments by scanning electron microscopy during the first 44 weeks. The minerals were attacked in the following order: pyrrhotite, cubanite, sphalerite, pyrite and chalcopyrite.

Jan 1, 1990

By Sandenbergh RF

The debate on the mechanism of adsorption of gold and silver di-cyanide onto activated carbon could be divided into two schools of thought. On the one hand, it has been proposed that the combined effects of electrostatic and chemical interaction between the activated carbon surface and adsorbing gold di-cyanide anion results in the adsorption of the latter. On the other hand the `ion-pair' adsorption reaction mechanism has been vigorously advocated as the dominant mechanism responsible for the adsorption of gold di-cyanide onto activated carbon. It is maintained that gold is adsorbed onto the carbon surface as the neutral ion-pair [M"+][Au(CN)z ]". Adsorption is viewed as the result of mainly the chemical interaction while electrostatic interactions are neglected. The validity of the `ion-pair' adsorption mechanism may be challenged on a number of counts. However, the alternative mechanism (based on aqueous surface chemistry principles) has not gained general acceptance yet, because it has not been applied widely enough to explain the different adsorption phenomena associated with gold di-cyanide on activated carbon. In the present study the case in favour of an adsorption mechanism based on general aqueous surface chemistry principles is presented. A model framework is developed for the adsorption reaction mechanism of gold di-cyanide onto activated carbon which incorporates the effects of chemical and electrostatic interactions between the dissolved species, the aqueous solution and the carbon surface. This model is then employed to explain a wide variety of reported adsorption phenomena for gold di-cyanide on activated carbon, such as the effects of pH, the adsorption of different metal cyano complexes, ionic strength, and type and concentration of cations in solution. In addition the effects of cyanide and dissolved oxygen concentration were investigated. No ready explanation, in terms of aqueous surface chemistry principles, is yet available for the switch in adsorption behaviour that agrees with ion exchange to ion-pair adsorption with increasing ionic strength.

Jan 1, 1997