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By S. M. Spottiswoode

The aim of the hybrid location method is to improve seismic event locations by reducing the effects of errors in the wave velocity of ray paths between each event and each recording site. We report on further enhancements made to the hybrid location algorithm, which is based on the double-difference method developed by Spottiswoode and Milev1and Waldhauser and Ellsworth2. The term ?double-difference? refers to the residuals between the observed and theoretical travel-time differences and are obtained using either picked arrival times or various measures of time differences obtained from waveform pairs. These residuals are minimized for pairs of earthquakes at each station while linking together all observed event-station pairs. An important enhancement is that the double-difference term uses the median arrival time residuals to reduce the effect of outliers on the system of equations. In addition, the hybrid locations are further constrained by considering events of known locations, in this case along lines of development blasts. We relocated some 20 000 previously located seismic events in the Driefontein 5E area; 5 800 of these events were considered to have been development blasts and we constrained their locations to lie on the straight lines joining about 2 150 survey pegs from the mine?s database. Relocated events were shown to distribute more closely around advancing faces than had been the case before relocation. Wave velocities from the development blasts show evidence of anisotropy.

Jan 1, 2005

By K. M. Godiwalla, S. Ranganathan

The thermal state in submerged-arc furnaces (S.A.F.) producing ferro alloys is important for the conditions of both the grade of alloy produced as well as specific energy consumption. The temperature profile in the S.A.F. is affected by the endothermic chemical reactions and the rate of gas evolution. The gas evolution commences at about 900 C due to the reduction of iron in the ore. A first-principle-based 2-D model has been developed to predict the temperature profile in the furnace. In this study, four ores of different grades have been considered in order to simulate the thermal profile in the S.A.F. The influence of the composition of the ore on the thermal profile and its significance in rationalisation of charge distribution to optimise the process are discussed.

Jan 1, 2007

The estimation of the spatial variation of the b-value of the Gutenberg- Richter relationship is important for both the general interpretation of the mechanism of rock mass response and seismic hazard assessment. The interpretation of b-value as a parameter of rock mass response is discussed in this paper. The methods applied to evaluate the spatial variation of b-value and the algorithm for obtaining the magnitude of completeness and b-value for subsets of data are presented with some verification analyses. The algorithms presented enable the automation of a spatial evaluation of b-value.

Jan 1, 2014

By V. A. Leach, J. R. Johnson

The calculation of the dose to the bronchial epithelium, lungs and other body tissues from exposures to airborne radon and thoron daughters requires a knowledge of the pattern of deposition in the respiratory system and clearance from it. Exposure to radon or thoron daughters is measured in units of Working Level Months (WLM), which is independent of the aerosol particle size, the fraction of daughters that are attached to the aerosol and the degree of disequilibria between the daughters, and age and breathing rate of the subject. These factors will influence the deposition and clearance, and hence dose. It is therefore of interest to find the relationship between WLM and calculated dose as a function of aerosol size, unattached fraction, and disequilibria, and of age and breathing rate, and to define ranges for these parameters for which WLM is an acceptable measure of the risk. This presentation briefly reviews the two dosimetry models being considered by a current Nuclear Energy Agency (OECD) Working Group, and using these models, defines limits on parameters for which the WLM is applicable.

Jan 1, 1981

By Dennis McLaughin

This report contains a description of the contract activities performed by ENSCO, Inc. under contract No. H0178069. The purpose of this project was to enhance the Bureau of Mine?s Cableless Electronic Survey System use to aid in the drilling of long (approx. 2000 feet) boreholes in coal. This drilling is performed as part of the methane drainage program. The system that was ultimately developed was field tested 2nd demonstrated in actual in-mine drilling activities. The significance of this system as compared to previous drill survey systems is the fact that it surveys without having to be inserted and removed for each survey point. It is so designed that it can withstand the shock and vibration experience by the drill string during drilling. This means an increased productivity is now possible in that drill operators can determine drill bit positioning in a near real-time environment.

Jan 1, 1981

By L. R. Plitt, A. J. Neale, B. C. Flintoff

"INTRODUCTIONThis is not a technical paper in the normal sense. It is an informal document which is intended to share the results of some recent cyclone research with our colleagues both in operations and in research.PILOT PLANT FACILITIESFigure 1 is a schematic of the closed circuit hydrocyclone pilot plant testing facility at the University of Alberta. In this figure the system is configured for some experimental work on wide angle cyclones which was recently completed. The rig is designed to study cyclones in the approximate range of 10 cm to 20 cm diameter. Notable features include the variable speed feed pump, the magnetic flowmeter and pressure sensors on the cyclone feed line and the travelling launder which permits simultaneous sampling of both product streams.ORGANIZATIONFor organizational convenience the subject matter has been divided into three parts:(1) Peculiar Partition Curves(2) Wide Angle Cyclones(3) Rope DischargePECULIAR PARTITION CURVESMuch of the initial empirical mathematical modelling work on cyclone classifiers dealt with homogeneous ores. A homogeneous ore is one in which all particles have substantially the same apparent density, or where one phase is very clearly predominant. In contrast, a heterogeneous ore is one in which there are at least two different density classes, each making a significant contribution to the ore composition. (Particle shape similarity is always assumed.)One of the problems which can arise when analysing the overall solids partition (selectivity, Tromp, etc ... ) curve for a heterogeneous ore is the peculiar shape which may be observed, when compared to partition curves for homogeneous ores. This is not an unusual occurrence and it has been documented by Lynch and Rao, Finch and Laplante and Larsen and Spring. The purpose of this section is to identify those operating conditions which may give rise to peculiar partition curves."

Jan 1, 1986

By J Graaf, R A. Murrell

Gold Fields Australia is constructing two major ventilation shafts at the Wallaby gold mine in Western Australia. The new ventilation shafts are required to facilitate the long term ventilation strategy for the mine, thereby allowing continued extraction of ore beyond 1000 m below the surface. The construction work has involved all of the challenges that shaft construction can throw up, including challenging geotechnical conditions, unexpected high water inflows and major circulation loss during pilot hole drilling for raise boring. An extensive geotechnical and hydrological investigation program was undertaken prior to awarding the shaft construction contracts. While most of the risks were identified, several proved to be much more challenging than expected. The shaft construction methods included conventional sinking into the fresh rock profile in each shaft, followed by raise bore pilot hole drilling and reaming. A headframe was constructed for the first shaft, which was sunk to 92 m with a stage suspended in the shaft to facilitate the concrete lining and provide rope guides for the kibble winding. Drawing from experience when sinking the first shaft, additional ground pre-conditioning was implemented for the second shaft, which was pre-supported with continuous piles to 28 m followed by sinking to 50 m using a crane instead of winders and a headframe. Following the conventional sinking through the weathered zone in each shaft, the shafts were completed using a raise bore. The first shaft utilised a riser pipe and rotary vertical drilling system (RVDS) with the second shaft having utilised a dual rotary rig for pilot hole drilling. This paper reviews the site investigations undertaken, construction methodologies applied, the results achieved and the lessons learnt.CITATION:Murrell, R A and Graaf, J, 2017. Shaft construction at the Gold Fields Wallaby mine, in Proceedings 13th AusIMM Underground Operators’ Conference 2017, pp 321–334 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Oct 16, 2017

By Gregory M. Molinda

Extremely difficult ground conditions were encountered in the main belt entry in a room and pillar mine in West Virginia. Several generations of supplemental support, including cable bolts, cribbing, and Heintzmann jacks and beams failed to halt roof falls that threatened workers safety and the life of the mine. Polyurethane (PUR) was injected into 27 intersections in the roof and the results were monitored by borehole video camera. The mine had averaged 2-3 falls in the beltway per year and, since the roof injection, no roof falls have occurred. Pre- and post injection monitoring of test holes showed that stability can be achieved without filling all of the existing void spaces. Video logging showed that the project goal of building a beam from 2-6 ft into the roof was successful. Pre-injection monitoring of roof fractures uphole can delineate the zones to target for reinforcement, and avoid pumping PUR into large voids to little effect. Multiple-injection zones can be identified, and the entire intersection drill hole array can be optimized based on knowledge of the fractured zones. In addition, pre-monitoring can prevent excessive hydrofracturing in solid zones. Polyurethane injection is a proven method of rock stabilization in even the weakest, most broken ground. Optimization of the injection design by pre-injection video diagnostics can greatly contribute to the successful and efficient roof stabilization.

By N. Fardin, O. Stephansson, L. Jing

A pair of silicon rubber replicas of size 250 mm by 250 mm, from a natural rock joint, was used to produce several high strength concrete fracture replicas of different sizes, from 50 mm by 50 mm to 200 mm by 200 mm. The morphology of the concrete fracture replicas were digitized at the laboratory using a 3D-laser-scanning machine with high accuracy and resolution. The scale dependency of the geometrical properties, including surface roughness and aperture, of the samples were investigated using fractal method. The investigation was extended to study the scale effect on the mechanical properties of the concrete fracture replicas. Four concrete replicas having same geometry from each sampling size were sheared under four different normal loads. The results show that normal and shear stiffness and peak shear strength decrease with increasing sample size and decreasing normal stress. It is concluded that for accurate determination of geometrical and mechanical properties of rock joints in the laboratory and field scales, samples with size equal to or larger than stationarity limit are required. Silikongummiabdrücke der Größe 250 mm x 250 mm einer natürlichen Kluft dienten als Vorlage für mehrere Hochfestbeton Rissreplikas verschiedener Größe. Die Morphologie der Beton Rissreplikas wurde mittels eines 3D-Laserscanners hoher Genauigkeit und Auflösung im Labor digitalisiert. Die Skalenabhängigkeit der geometrischen Eigenschaften, dies inklusive Oberflächenrauhigkeit und Öffnungsweite, wurden mittels Fraktalen bestimmt. Die Studie wurde durch die Untersuchung der mechanischen Eigenschaften der Betonrepliken erweitert. Hierbei wurden vier Betonrepliken der selben Geometrie jeder Probengrösse unter vier verschiedenen normalen Belastungen abgeschert. Die Ergebnisse zeigen das sowohl Normal- und Schersteifigkeit als auch die Spitzenscherfestigkeit mit zunehmender Probengrösse und abnehmender Normalspannung abnehmen. Es hat sich gezeigt, daß für eine genaue Bestimmung der geometrischen und mechanischen Eigenschaften von Felsklüften im Labor und im Feld Proben einer Größe gleich oder größer des stationären Limits verlangt werden. Deux répliques en gomme de silicone d’une fracture naturelle, de dimension 250 mm par 250 mm, ont été utilisées pour produire des répliques en béton de haute résistance de dimensions allant de 50 mm par 50 mm à 200 mm par 200 mm. La morphologie de ces répliques a été digitalisée au laboratoire à l’aide d’un laser-scanner 3D haute résolution et haute précision. L’influence de l’échelle des propriétés géométriques, incluant rugosité et ouverture, a été étudiée en utilisant la méthode des fractales. Des essais complémentaires ont été réalisés afin d’étudier l’effet d’échelle sur les propriétés mécaniques des répliques de fracture en béton. Quatre répliques béton de même géométrie pour les différentes tailles d’échantillons ont été cisaillées sous quatre valeurs de contrainte normale. Les résultats montrent que la rigidité normale et tangentielle ainsi que la résistance de pic diminuent en proportion de l’augmentation de la taille de l’échantillon et de la diminution des contraintes normales. On peut en conclure que, pour une détermination précise des propriétés géométriques et mécaniques des fractures au laboratoire et sur le terrain, des échantillons de taille égale ou supérieure à la limite stationnaire sont nécessaires.

Jan 1, 2003

By D. J. Young

Alloys used at high temperature must resist both creep and corrosion. Design for corrosion resistance is based on the formation of a slow-growing, protective oxide scale by selective oxidation of an appropriate alloy component, usually chromium or aluminium. A successful scale will exclude other corrodents, notably carbon, which can otherwise cause extremely rapid corrosion at high temperatures. Selective oxidation of an alloy component necessarily lowers the concentration of that metal in the alloy subsurface region. Under thermal cycling conditions, mechanical damage to the scale leads to renewed oxide growth and accelerated alloy depletion. Eventually, a point is reached where diffusion of a corrodent into the alloy becomes competitive with the outward diffusion of alloy metal to repair the protective scale. Two examples of alloy failure by carbon attack are considered. In the steam cracking (pyrolysis) process, centrifugally cast tubes of heat-resisting alloy are exposed to a gas stream of hydrocarbon and steam, at a carbon activity of unity. Formation and repair of the surface chromia scale causes alloy depletion, Kirkendall void formation, and subsequent internal precipitation of chromium-rich carbides. Their formation makes chromia scale formation much more difficult, and generates internal stress. Eventually, the tubes fail by creep rupture. In other processes (e.g. steam reforming, heat treatment), synthesis gases are supersaturated with carbon at intermediate temperatures. Once the alloy's protective scale is breached, carbon attacks the depleted substrate. In the case of ferritic alloys, it forms a surface scale of Fe3C. As this scale thickens, the supersaturated carbon precipitates as graphite within its outer regions. The resulting volume expansion causes disintegration of the cementite in a process known as metal dusting. In the case of austenitic alloys, no metal carbide is formed. Instead, carbon dissolves in the depleted metal to diffuse inward and precipitate as graphite within the metal matrix. Again, volume expansion causes disintegration of the alloy, and metal dusting results. Dusting occurs at an extraordinarily rapid rate, and leads to failure by section loss or even penetration.

Jan 1, 2013

By E. Swartzman

This paper presents a general re-view of the various methods of briquetting coals, with and without the aid of a binder, with special reference to the production of a suitable briquette from Nova Scotia 'fines' for re-blending with industrial coal. From the economic and technical viewpoints, either small stoker-sized briquettes made with about 4 per cent asphalt in standard low-pressure double-roll presses, or briquettes made without binder in high-pressure double-roll presses, appear to be the most reasonable solution at present.

Jan 1, 1959

By D. Christofferson

This final report documents the cooperative efforts of the Engineered Systems Division and the Mining Equipment Division of FMC Corporation during performance of Bureau of Mines Contract H0252091. Improved operator compartments incorporating overhead canopies, logical arrangements of controls, and design features offering greater operator comfort were developed and retrofitted to the FMC 320A roof bolter and 6L shuttle care The vehicles were evaluated in underground operations at separate mine sites. The successful evaluation has resulted in incorporation of the designs as standard features of the 320A roof bolter, and the 5L, 6L, and 10L shuttle cars.

Jan 1, 1978

By D. Laguitton, D. Hodouin, V. K. Gupta, R. Spring

"The CANMET SPOC project aims at inducing progress in process evaluation and optimization by developing user oriented software based on state-of-the-art theory. The present work is the result of a joint effort by CANMET, Noranda Mines and Université Laval to develop two computer packages: one (RTD) to calculate the residence time distribution that best describes the material transport through the mill, the other (FINDBS) to estimate the rate of breakage and distribution function of the population balance model in a ball mill. The RTD package can handle data from various experimental methods (impulse or complex tracer feed, with or without recycling, etc...). The FINDBS package provides options for the functional description oj both model parameters Band S. The full detail of the methods and programs appears in a users guide. The program capabilities and several sample runs are presented.IntroductionSimulation of mineral dressing operations by computer has been largely contained within academic and research circles and has not yet gained a status of routine practice in the ore and coal industries. It is however a matter of time before process simulators are available on every process engineer's desk to assist process optimization tasks, flowsheet design and professional training. The CANMET SPOC project (Simulated Processing of Ore and Coal) was initiated in 1980 to assist the Canadian industry in integrating computer-based methodology for process evaluation and optimization(1). Software development, documentation and transfer is one of the main priorities of the project which will mature in 1985 by releasing a complete package of manuals and programs covering sampling, material balance computation, unit modelling, flowsheet simulation and optimization . This paper is a condensed description of a typical project element in its 1982-1983 state of development. The required methodology for ball-mill modelling and simulation was consolidated an d merged to other project elements during a joint study under contract financed by CANMET and Noranda Mines Ltd . The first part of the study dealt with documenting experimental methods and software for ball-mill computer simulation. Université Laval GRAAIM (Goupe de Recherche en Automatistion Appliquée à l'Industrie Minérale) acted as sub-contractor for this part of the study(16,17). A second part dealt with applying the model calibration techniques to a large industrial data base and is reported elsewhere(2,18,19)."

Jan 1, 1984

Plan de l?exposé ?? Présentation du site de la mine Restigouche et du mandat confié à Genivar ??Dénoyage de la mine ??Processus d?enlèvement des boues au fond de la fosse ??Utilisation de Géotubes dans le procédé à l?usine de traitement des eaux.

Feb 1, 2008

By Jeffiey B. Austin, Maurice Tagami

"The ores of the Iberian Pynte Belt are typically massive sulphide ores with very fine grained mineral textures. EuroZinc Mining Corporation is currently evaluating one of the massive sulphide deposits located near the town of Aljustrel, in South Central Portugal. The deposit contains significant grades of lead, zinc and silver. The ores are comprised solely of sulphide mineralization consisting of pyrite, sphalerite, galena and some secondary copper minerals. Liberation requirements for these ores are typically 22 to 25 microns. A selective flotation process has been utilized to produce separate lead and zinc concentrates for sale to off-site contract smelters.This paper outlines the process test results and describes the process parameters required to optimize the process parameters. Ths test program has been conducted in support of the re-opening of the facilities in Aljustrel. The 3500 tpd mining and milling facility was commissioned in 1990 and operated for 18 months before closing. The previous facility was designed to produce three products using a selective copper-lead-zinc flotation process. EuroZinc Mining Corporation is proposing to re-open the operation, selectively mining from a lead-zinc phase of the massive sulphide deposit and produce only lead and zinc concentrates.Results are presented and discussed.PROJECT HISTORY AND CURRENT PROJECT OBJECTIVESThe EuroZinc Aljustrel Project is a potential major producer of lead, zinc and silver located in the Iberian Pyrite belt of south-central Portugal. The town of Aljustrel is historically associated with mining dating to the time of the Romans. The area is rich in pyrite deposits, and sections of the pyrite deposits contain significant zones of copper, lead, zinc and silver. Mining in Aljustrel during the last century (1900’s) included a major pyrite mining operation, which produced feed for sulphuric acid production. Pynte mining operated from the 1930’s to the early 1970’s and a short-lived base metal operation from 1989 to 199 1."

Jan 1, 2000

By Peter Kowalczyk

Magnetic surveying and map production is well established in land based mineral exploration. Magnetic data are routinely used to map geology in covered terrains, to estimate the depth to basement in overburden covered areas, and to identify altered zones, mineralization, bedding attitudes, and fault networks both regionally in map view, and through interpretation to depth in 3D. Best practices for magnetic survey methods and magnetic interpretation exist in all areas of land based geophysical survey methodology - mineral exploration, hydrocarbon exploration, geological mapping, archeological mapping, and in military applications. At sea, and particularly under the sea, sophisticated magnetic surveys are being done, but it can be argued that these are primarily in niche applications, for example in naval mine-hunting and UXO applications. Magnetic data is not normally collected on AUVs and ROVs conducting mapping and hydrographic survey operations. OFG has developed physical and mathematical calibration routines so that magnetometers can be mounted directly onto AUV and ROV bodies where significant heading errors and magnetic gradients exist. This simplifies the routine deployment of magnetometers on AUVs and ROVs for mineral exploration and other magnetic survey applications without the need for towed bodies, ungainly mounting frames, or degaussing of the survey equipment. Our experience shows that magnetometers can be operated routinely on AUVs and ROVs and that with careful processing useful maps can be produced routinely at low cost.

Sep 1, 2014

Due to the reduction in frictional resistance, the characteristics of joint infill have a major role to play on rock mass instability. This paper elucidates the laboratory behaviour of graphite infilled joints based on a large-scale shear apparatus under constant normal stiffness (CNS). Discontinuities in a graphite mine have been simulated using high strength gypsum plaster, with the joints infilled with compressed graphite layers. The Fourier series was employed to characterize the joint surface, and the method of using the Fourier coefficients for the prediction of dilation and normal stress with displacement is explained. Die Charateristik von Verbindungsfüllungen hat einen wichtigen Einfluss auf Felsmassenstabilität aufgrund der Verringerung des Reibwiderstandes. Diese Veröffentlichung untersucht das Verhalten von Graphit gefüllten Verbindungen im Labormaßstab mit einer Methode die auf einem gross-umfang Apparateprinzip unter konstanter Normal-Steifheit beruht. Unregelmässigkeiten in einer Graphit Mine wurden mit Gypsum Gips von hoher Festigkeit simuliert, die Verbindungen wurden mit kompressierten Graphitschichten gefüllt. Fourier Reihen wurden angewandt um die Verbindungs Fläche zu Characterisieren. Die Methode die verwendet wurde um die Ausdehnung und Normalkraft mit der Verschiebung mit Hilfe von Fourierkoeffizienten zu bestimmen wird beschrieben. Due à diminution des résistances par frottements, les caractéristiques des joints de remplissage joue un rôle majeur sur les instabilités de la roche. Cet article étudie le comportement en laboratoire des joints de remplissage en graphite à partir d’un dispositif de friction à grande échelle sous rigidité normale constante. Les discontinuités dans une mine de graphite ont été simulées grâce à un plâtre à haute teneur en gypse, dont les joints ont été remplis de couches de graphite compressées. La caractérisation de la surface des joints a été réalisée avec les séries de Fourier. La méthode utilisant le coefficient de Fourrier pour la prédiction de la dilatation et de la compression en fonction du déplacement est également expliquée.

Jan 1, 2003

By Tim Hughes, A. H. (Sandy) Gray, Jennifer Abols

"The selective recovery of gold and silver from solutions containing other metals such as copper is possible using AuRIX®100 resin in conjunction with the Gekko Resin Column. Selectivity is driven by controlling the solution pH, which enables activities such as loading copper, gold and silver and then selectively stripping copper before gold and silver. Alternatively gold and silver can be loaded and the copper left in solution. The selective loading of gold while reducing the silver loading has also been demonstrated opening the possibility of producing high grade gold doré from high grade silver pregnant leach solutions. This paper reviews the AuRIX®100 resin and Gekko Resin Column Technologies, discusses the uses of AuRIX®100 in the recovery of gold and silver and the chemistry relating to several projects for which AuRIX®100 is being tested.INTRODUCTIONGekko SystemsGekko Systems specializes in the design, development and distribution of innovative mineral processing equipment and systems with a particular focus on gravity separation for the gold and diamond industries. The company, which has been around since 1996, has five main products: the InLine Pressure Jig, the InLine Spinner, the InLine Leach Reactor (ILR), Gekko Resin Column and Modular Systems.The InLine Leach Reactor is an intensive cyanidation reactor that uses high cyanide (0.5 – 2 % NaCN) and high oxidant (20 ppm dissolved oxygen as O2 or hydrogen peroxide) to dissolve gold from medium and high-grade gravity or flotation concentrates. The ILR, which typically replaces a shaking table in the gold room, is available in both batch and continuous models. There are 42 installations worldwide. Further details on this technology can be found in papers written by Gray et al (2003) and Longley, McCallum and Katsikaros (2003). By replacing a shaking table with an ILR, the overall gravity and plant recoveries can be increased significantly. Other advantages include reduced security risks, lower operating costs, reduced operator involvement due to the automatic process and increased safety for gold room operators."

Jan 1, 2006

By E. P. Youngman

Tantalum is a rare element ; estimates indicate that there is less tantalum than gold in the earth's crust . After remaining a laboratory curiosity for many years , it was used to a limited extent and for relatively few years (1903- 1911) for incandescent electric-light -bulb filaments . Another wave of interest in tantalum appeared when its electrolytic-valve action was taken advantage of in charging storage batteries , especially for radio work . Tantalum chargers were eventually displaced by other types of chargers , but for a time they were manufac tured in sufficiently large numbers to create a demand for the metal and to bring about its production on a commercial scale in the United States . As tantalum became available in larger quantities and at substantially lower prices , and as high prices for platinum encouraged the employment of tantalum as a substitute , the metal was put to many new uses . Ferrotantalum was made and sold before the World War , and patents have been taken out for a number of special alloys for industrial purposes , but probably the largest use for the metal to-day is in vacuum tubes .

Aug 1, 1930

By Filip Rochette, Yvan De Busscher

Extraction of minerals can be achieved by a variety of technologies; one of them is ion exchange. There are several ion exchange configurations and mechanical set-ups available, but only one technology will provide more process performance and flexibility compared to the other. The multiple column Continuous Countercurrent Ion Exchange (CCIX) technology provides the highest form of process flexibility with also the highest mineral recovery feasible through ion exchange. In comparison with a fixed bed system, the PuriTech CCIX system offers the benefits of continuous counter-current contact mode. This way the resin capacity is fully exploited leading to reduction in resin inventory and, at the same time, in chemicals and water consumption, and product dilution. For any set of operating conditions the mass transfer zone has a characteristic length (MTZL). The MTZL can be expressed in duration, column length, or volume, but is the measure of the quantity of resin in the system that is doing "work" at any given moment in the process. The objective of continuous ion exchange processing is to eliminate all resin volume from the process equipment that is not within a mass transfer zone. In most commercial ion exchange processes for the recovery of metals, CCIX engineering can eliminate as much as 20 - 80 % of the ion exchange resin inventory. Consumptions of water and chemicals are typically brought down around 40% or more. For each type of resin the selectivity/affinity towards a particular metal depends on the basic process conditions such as pH, concentrations of other competing metals in solution. By changing the pH in the ion exchange process phase, the selectivity of the resin can be changed. By doing this, a split elution, or extraction of metals separately can be achieved and the effect of other competing metals (cross-contamination) can be reduced. For example the DOW resin XUS43578 is commonly used for the recovery of copper or nickel/cobalt separation.

Jan 1, 2016