Search Documents

By Olexandr Gydin

The evolution of grain and dislocation structures during cold deformation of the new steel LH800 of Salzgitter AG is investigated in the frame of this work. The main feature of this material is its ability to air-harden by carbon content of about 0.1%. The initial ferrite structure of the metal provides high plasticity at cold deformation and subsequent heat treatment increases tensile strength approximately two times. Described are results of in-situ tensile tests in the SEM. SEM and TEM analysis of grain and dislocation structures evolution in samples, which have been uniaxially deformed to certain strains, are carried out. After statistical evaluation of results the grain elongation against strain is determined. A microstructure of a deep drawn cup is analyzed by means of SEM. A quantitative evaluation of grain elongation on the different cup zones and comparison of these data with prediction results based on tensile tests are carried out.

Jan 1, 2009

By Ikuhiro Sumi

A new steelmaking process, in which manganese ore was intentionally reduced, was developed to achieve a higher manganese Yield using a combined blowing converter. In this study, manganese behavior was discussed through the introduction of a model. Apparent reduction rates of manganese were calculated by the two terms that were determined experimentally, with SOkg and 2S0ton combined blowing converters. The model calculated manganese changes during the operation. We applied the model to the actual operation and found that manganese behavior was predicted fairly well by this model.

Jan 1, 1996

By A. González

Arsenic is one of the main contaminants present in Chilean copper concentrates and its abatement represents a challenge for the process metallurgy, particularly under the strong environmental requirements in the global community. The possibility to form ferric arsenate directly from a gas phase by means of a heterogeneous reaction between an arsenic gas bearing and iron oxide was studied at laboratory scale. A thermodynamical analysis for the system Fe-As-O-S has been initially made, in order to obtain the stability conditions for the ferric arsenate or other FeAsyO2 type compounds. Experiments were made using an hematite sample suspended in a thermogravimetric device. AS4O6 gas generated from solid AS2O3 that was passed through the iron oxide sample and its instantaneous weight change was recorded directly. A kinetic study for the AS4O6 volatilization was made to control the gas composition. A chemical control between 300 and 600°C with an apparent activation energy of around 14 Kcal/mol As2O3 was determined. The samples after the reactions were chemically and XRD analysed. Arsenates detected corresponds to complex compounds. Results shows a dependence on temperature and oxygen content in the gas phase. The kinetics for iron arsenates formation is slow, reaching an arsenic capture of 6% after 80 minutes of reaction when an oxygen content of 50% is fed continuously at 800°C and 3,56% As in the gas. Experiences made at the same temperature but under higher oxygen content in a closed reactor, allowed arsenic capture close to 60%. For higher temperatures the capture is considerably lower.

Jan 1, 2003

By Andrew L. Puwis

Methodologies were presented for computing the thermal gradient associated with single crystal solidification in macroscopic computer modeling. The. heat transfer, and solidification of a shaped investment casting model were simulated using properties from three different alloys. Following the simulation of solidification, the resultant thermal gradients (G) and rates of solidification (R) from representative points were extracted in various ways and compared: It was discovered that alloy properties have a strong influence on the computed thermal gradient and rate of solidification for the three methods investigated. Data also showed that the computed gradient for each model was very different depending on the temperature range used to compute these values.

Jan 1, 1994

By J. P. Bellot

During the non-ferrous metal processing, the melting step under vacuum or under rarefied gas leads to volatile metal losses. It is the case of the metallurgical processing of the nickel-based, titanium-based or zirconium-based alloys where the evaporation losses don't allow a sufficient control of the alloy chemical composition. A theoretical approach has been carried out involving both a continuum description in the liquid phase and a molecular approach in the rarefied gas phase. The finite volume method is used in order to solve the coupled transport equationsin the liquid, whereas the Boltzmann equation is modelled by using a Monte Carlo method. At the liquid metal and metallic vapor interface, the volatilization and recondensation fluxes link up the two calculations. Simulation results are given for the melting and refining of reactive metals such as titanium alloys where the control of the chemical composition remains a major difficulty. The validity of the kinetic Langmuir's law is discussed for different operating conditions.

Jan 1, 1996

By Wen Liangying, Zou Chong, Tan Xiuqin, Bai Chenguang, Zhang Shengfu

"Eight typical metallurgical byproducts containing iron were selected based on the effect of the chemical composition, particle size, additives on the burnout degree of pulverized coal. Effect of three typical byproducts including fine iron ore, BOF dust and BOF sludge on combustion reactivity and combustion efficiency were investigated using TG-DSC method. The results indicated that the three additives have obvious catalytic effects on pulverized coal. By comparison, the relative active sequence of byproducts to the catalytic combustion can be described as follows: BOF dust>BOF sludge>fine iron ore. Moreover, adding BOF dust as component of additives also shows significant catalytic effects on combustion efficiency during rapid heating process.IntroductionChina is the largest producer in the world with an annual output reaching over 6 billion tons. Solid wastes arising from iron and steel making increases the environment pressure in recently years. For instance, annual output of dust during the production of iron and steel making in China reach up to 5 million tons, which is close to 8%~15% of the amount of steel [1]. Another characteristic of these byproducts is they are finer particle which are just harder to deal with. Since some of solid wastes, including dusts, scales, and sludge, usually contain high iron content, sintering plants have traditionally been used to recycle byproducts in integrated steel plants in China. However these byproducts also have noticeable effects on sinter quality, sinter strength and productivity and, therefore, waste recycling is limited depending on the analysis of the waste materials [2]. Another method which is pre-treatment of byproducts in pelletizing process, increases of energy consumption and production cost. In addition, metallurgical byproducts often contain heavy metals and alkalis. For these reasons, recycling rate of the byproducts in China is very low. Therefore, how to recycle the byproducts in iron and steel making process is an important subject."

Jan 1, 2012

By J. E. Dutrizac

The mineral forms of silver, lead and cadmium in the zinc concentrates and the various roaster products made by the Kidd Creek Division of Falconbridge Inc. have been elucidated. In the concentrates, all three elements occur mainly in sulphide form, either in solid solution in the principal ore minerals or as discrete mineral grains. During roasting, Ag, Pb and Cd are preferentially concentrated in the hot cyclone and ESP dusts of the roaster train. Silver is converted to <0.5 µm grains of silver metal and to Ag2S04 which dissolves in or impregnates silicates. Lead is converted to Pb-bearing silicates or to PbS04 and PbO which are present either as tiny free grains in ZnO or as an intergrowth with lead silicate. Lead is also a minor constituent of the ferrite phase. Cadmium occurs mostly as cadmium-bearing zno and ZnFe2o4 , but a significant amount also reports as Cd-bearing silicates or zinc sulphate.

Jan 1, 1990

By Shengli Wu, Laixin Wang, Minyin Kou, Xinliang Liu, Weidong Zhuang, Yujue Wang

COREX process has obvious advantages in environment protection but still has some disadvantages, for example, it has a higher sulfur content of hot metal than blast furnace. In this paper, the thermodynamics and dynamics of desulfurization have been investigated to obtain the main operation parameters related to the mass fraction of sulfur in the hot metal. In addition, statistical analyses have been carried out to study the relationship between operating parameters and sulfur content of COREX hot metal based on actual plant data. It has been found that the mass fraction of sulfur in hot metal is significantly influenced by the C content in hot metal, MgO/Al2O3 in slag, the concentration of MgO in slag, the temperature of hot metal and binary basicity (R2).A linear model has been developed and subsequently used for reducing the mass fraction of sulfur in hot metal, improve the quality of hot metal and contribute to low carbon ironmaking.

Jan 1, 2016

By Nathalie Neveux

For the first time, dehydrated ferrous sulfate was successfully used for the dry synthesis of potassium ferrate. In addition, ferrate ion is stabilized as a solid solution where hexavalent iron is partially substituted by S(V1) leading to a sulfato-ferrate having the following formula K2(Fe,S)04. This substance has an efficient life time of about six months. Ferrate ion is a powerful oxidant ( EO = 2.2V ), a bactericidal agent and possesses coagulant, flocculant properties. Its reduction generates nascent oxygen, hydroxyl groups and Fe(OH)3. Alkali metal ferrate is probably the future global agent for water treatment. Applications of this material in the field of urban and industrial effluents treatment have been investigated. Heavy metals cations such as Cu, Cd, Mn, Ni, Pb, Zn, ... were successfully removed. The results of sulfato-ferrate use for cyanide destruction, decrease in COD, soil, discoloration of pulp and paper effluents will be summarized.

Jan 1, 1999

By D. Morin

A general study of gold refractory arsenopyrite-pyrite concentrate bioleaching has been carried out including two continuous bioleach testworks at different sizes, namely one at a laboratory scale with a 100 I unit at a 2 kg/d dry solid flowrate and the other at a pilot scale at a 100 kg/d dry solid flowrate. Both tests show a 80% bioleaching of arsenopyrite in about four days of treatment and with the same kinetic. Pyrrhotite is attacked at the earlier stage of the bioleaching but pyrite remains unaffected. The weak potential of oxidation associated with the decomposition of arsenopyrite and the abundance of arsenite leads to a high grade of elemental sulfur in the bioresidue which consumes the major part of the cyanide during the gold recovery. Furthermore. the arsenite and ferrous produced in solution have to be oxidized to obtain a stable precipitate in the waste products and as outlined in previous works of other authors on this subject the addition of iron to obtain a Fe/As molar ratio at least above 3 is necessary. The agitation equipment used in the pilot unit allowed an optimization study calculation for scaling-up the design and power requirements of an industrial installation. For the pretreatment of a gold refractory As high-graded concentrate the reagent cost has the greatest part in the operating cost of the biooxidation step due to the necessary retreatment of the biosolution. In that conditions the power cost is quite marginal. actually it is significant for the treatment of pure pyrite.

Jan 1, 1991

By Dandan Jian, Christian Karcher

Information of liquid steel flow patterns inside the mold may be obtained from the velocity at the free surface (meniscus). This meniscus flow may be measured using the contactless electromagnetic technique termed Lorentz force velocimetry (LFV). It is based on the measurement of Lorentz forces acting on a magnet system when an electrically conducting metal melt interacts with the field lines stretched by the magnet system. Force sensor and the magnet system form a so-called Lorentz force flowmeter. In this paper we present a series of model experiments that demonstrate the feasibility of using two identical flowmeters that are arranged in a certain distance one behind the other. In this case, surface velocity may be determined by just cross-correlating the two force signals recorded by the two sensors. This technique is called time-of-flight LFV. A special prototype of a respective measuring device, called meniscus velocity sensor (MVS), has been developed to measure local free-surface velocity. In the present paper we describe experimental results of respective measurements in the model test stand LiMeSCo (liquid metal surface velocity correlation). To check the potential of the time-of-flight technique, in a first step we measure surface velocities during solid-body rotation of metallic substances. We observe that small modulations in the signals that are due to the natural unevenness of the solid body can be used to determine surface velocities. In a second step we apply the time-of-flight technique to liquid metal free-surface flow. Here we use the low-melting eutectic alloy GaInSn as a test melt. In this case we observe that the cross-correlations between the signals are much rarer and much weaker than in the solid-body experiments. We conclude that the presence of the localized magnetic fields, produced by the permanent magnets of the flowmeter, give rise to intense deformation of the free surface and the creation of surface waves. The field acts as a magnetic obstacle. We observe that the flow velocity is decreased right underneath the magnetic field and is accelerated in the side regions. This magnetic obstacle effect may restrict the determination of the local surface velocity in application.

Jan 1, 2012

By Debbie Marshall

Nickel and cobalt in lateritic ores can be extracted by either a hydrometallurgical or a pyrometallurgical route. The high-iron limonitic fraction of a deposit is best processed&apos; hydrometallurgically while the magnesium-rich transitional and saprolitic fractions are more suited for pyrometallurgical processing. During hydrometallurgical processing, it may be attractive, for economic reasons, to blend the limonitic component with transitional and saprolitic ores, which contain higher nickel levels. However, blending increases the concentration of magnesium in the feed, leading to increased acid demands. The decision on how much ore to process then becomes an economic one. Ore samples with different magnesium contents were prepared for the leach test program by blending limonitic and transitional ores. The ore samples were slurried in seawater and tested in the Falconbridge Hydrometallurgical Pilot Plant. As expected, acid consumption increased with increasing magnesium content of the ore. For target extractions of 95% nickel and 92% cobalt, the required residual free acid concentration increased from 30 g/L at 1.7% magnesium to 50 g/L at 2.7% magnesium. When the magnesium content was raised to 3.8% and 4.6% in subsequent pilot plant testing, the final free acid requirements did not increase beyond what was observed at 2.7% magnesium. Thus, the cut-off ore composition to maximize nickel units and minimize acid requirements is between 1.7- 2.7% magnesium. Keywords: high pressure acid leaching, laterites, magnesium

Jan 1, 2004

By G. Fazel Jahromi

Enargite, known as one of the major arsenic containing copper minerals, with approximately 19% arsenic, introduces challenges to typical processing options. In most hydrometallurgical processing methods, arsenic remediation occurs after the copper recovery in an autoclave or in a stepwise neutralization process. In this study, the in situ precipitation of scorodite was investigated during an atmospheric leaching process in the presence of carbon-based catalysts and chloride media. The effective parameters of initial ferric addition, temperature, catalyst addition, and oxygen sparging rate were studied and the ferric behaviour was monitored during the scorodite precipitation. The most influential parameters on efficient scorodite precipitation are found to be: initial ferric addition, catalyst to concentrate ratio, and temperature. A 99% scorodite precipitation yield was achieved in this process.

By Edward Rosenberg

The synthesis and characterization of silica polyamine composites modified with a variety of sulfur containing ligands is described. The two most successful ligands in terms of sulfur in-corporation and mercury capture are ethylene sulfide and carbon disulfide. The ethylene sulfide forms either an amino mercaptane or a polysulfide upon reaction with amino groups on the composite. The carbon disulfide undoubtedly forms a dithiocarbamate functional group upon reaction of the amino group under basic conditions. Both materials posses excellent capture kinetics and capacities for mercury, Once captured, the mercury is extremely difficult to remove from the composite materials, even with concentrated acids, and they easily pass the TCLP test. The materials are compared with related thioether modified silica polyamine composites and appropriate potential applications are discussed.

Jan 1, 2003

By Sun Ying, Zhang Jing, Li Qiuju

A new process of enrichment Cu in molten copper slag under electric field is presented in this article. The experiments were carried out in the laboratory on a kilogram scale. The mobility of copper slag was improved by the technique of carbon reduction. The effects of temperature, electric field strength and intermittent feeding speed were investigated on Cu migration. The results showed that the best experimental conditions were the temperature at 1523K, electric field strength was 1.5V•cm-1 and feeding rates was 15 g•(10min)-1. The copper content of the slag decreased below 0.6wt%. The process was compared to the traditional electric furnace process of slag cleaning, there was reduced the energy consumption and heat loss, and also harmful gas emissions such as SO2 and CO2, accompanied by improved the efficiency of slag cleaning.

Jan 1, 2016

By Bradford H. Miller

Separation and Recovery Systems, Inc. (SRS) provides on-site waste minimization and resource recovery using its state-of-the-art MX-1500 centrifuge and MX-2000 thermal desorber. The MX-1500 can process over 450 feed tons of material per day, resulting in centrifuged cake containing 20% to 60% by weight. The MX-2000 is a hollow-flite thermal processor indirectly heated by either steam or hot oil. SRS has dewatered and/or deoiled over 1,000,000 feed tons of material in the refining, chemical, and energy industries using the MX-1500. SRS estimates that over 300,000 barrels of reusable oil have been recovered from that material. Additionally, SRS has dried and/or detoxified over 150,000 wet tons of solids or soil to regulatory or customer-specified limits using the MX-2000.

Jan 1, 1994

By Donna Guillen, Matthew Lehar, Sebastian Freund, Jennifer Jackson, Helge Klockow

"Research and development is currently underway to design an Organic Rankine Cycle (ORC) system with the evaporator placed directly in the hot exhaust stream produced by a gas turbine (GT). ORCs can be used to generate electricity from heat that would otherwise be wasted, thus producing carbon-free energy. In conventional ORC configurations, an intermediate oil loop is used to separate the hot gas from the flammable working fluid. The goal of this research effort is to improve cycle efficiency and cost by eliminating the pumps, heat exchangers and all other added cost and complexity of the additional heat transfer loop by developing an evaporator that resides in the waste heat stream. Direct evaporation – although simpler and less expensive to implement than indirect evaporation of the working fluid – has historically been avoided due to a number of technical challenges imposed by the limitations of the working fluid. The high temperature of the hot exhaust gas may cause decomposition of the organic working fluid and safety is a major concern due to the high flammability of some of these working fluids. The research team has addressed these challenges and developed a new direct evaporator design that can reduce the ORC system cost by up to 15%, enabling the rapid adoption of ORCs for waste heat recovery. The ORC system is intended to integrate with the GT either as a retrofit or to be marketed as a single package, thus maintaining the manufacturer’s warranty.IntroductionWaste heat from turbines and engines used in industrial applications along with waste heat from industrial processes are exceptionally abundant sources of energy. If even a fraction of this waste heat could be economically converted to useful electricity, it would have a tangible and very positive impact on the economic health, energy consumption, and carbon emissions in the U.S. manufacturing sector. Land-based gas turbines are used in a broad range of applications to produce both shaft and electrical power. Most commonly known for generating electricity either as peaking units or as base load units, they are also used to directly drive pumps, compressors or other machinery requiring shaft power. Simple cycle gas turbines have the advantage of a short startup time relative to coal-fired and nuclear units, however, they incur a significant penalty on their efficiency. Large frame gas turbines usually are combined with bottoming steam-based Rankine cycles to increase the overall efficiency of the system and thereby improve their cost performance. Small-frame gas turbines with exhaust temperatures around 500°C could in principle benefit from steam bottoming cycles, but rarely use them in practice because of the high capital cost of the steam system. Particularly for base load small frame gas turbines, akin to those used in pipeline applications, an increase in efficiency is highly desirable."

Jan 1, 2011

By Kazuyoshi Shimakage, Shinji Hirai, Kenji Wada

"An amorphous zirconium oxide coating was prepared by the sol-gel process using zirconium tetra-n-butoxide on the surface of aluminum to improve the corrosion resistance to salt, acid and alkaline attacks. The coating films formed on the smooth aluminum substrates under UV-irradiation indicated an excellent corrosion resistance for salt, acid and alkaline attack tests. For example, the corroded area of coating film in salt attack test for 3600ks in the order of sol-gel coating· film< chromate film <boehmite film, and the sol-gel coating film had the best corrosion resistance. The coating film prepared on the coarse aluminum substrate by a boiling treatment after heat treatment at 573K also had greater corrosion resistance, and a water-avid surface appeared a contact angle of approximately 3°.IntroductionAs given in a previous paper1; a composite film consisting of a porous layer of anodically grown aluminum oxide filled with amorphous zirconium oxide and an amorphous zirconium oxide coating layer deposited thereon via the sol-gel process utilizing the dip-coating technique, was prepared to improve the alkaline corrosion resistance of aluminum. The alkaline corrosion resistance of these composite films was increased in the range of 24 to 50 times those of conventional anodic oxide films anodized in sulfuric acid. As a result, it was proved that heat treatment at 573K after dip-coating was an important process to .remove organic component from gel film and to accelerate the densification of coating layer. Furthermore, the effect of ultraviolet (UV) irradiation at ambient temperature on the densification of coating layer was also examined to lower the heat-treatment temperature2.Then, a sol-gel film prepared by UV irradiation at ambient temperature indicated that alkaline corrosion resistance of aluminum was superior in the range of 2.4 times to 2. 6 times that of the conventional composite film heated at 573K."

Jan 1, 2000

By A. J. van der Zeeuw

The use of SME 529 in the extraction of copper from acidic liquors and of copper and nickel from ammoniacal solutions, is illustrated with results of laboratory and bench scale mixer/settler experiments. Special features of SME 529 are its high loading capacity and the ability to keep the complexes dissolved in the organic phase up to quite high concentrations.

Jan 1, 1976

By R. Padilla

A thermogravimetric study has been conducted to follow the decomposition and volatilization of arsenic from enargite concentrate in nitrogen and slightly oxidizing atmospheres. Temperature has a large effect on the rate of volatilization of arsenic. Fractional volatilization of arsenic as high as 98% were obtained in less than 60 min at 650°C in nitrogen atmosphere, while in slightly oxidizing atmosphere the same volatilization could be achieved in 30 min. It was found that arsenic volatilizes as sulfide in nitrogen atmosphere and as 4xture of sulfide and oxide in atmospheres containing 1% oxygen. By using the pore blocking and the first order kinetic models, apparent activation energies of 213 and 200 kJ/mol for the temperature range of 780 - 900 K and 205 and 184 kJ/mol for the temperature range of 900 - 985 K were determined for enargite and copper concentrate, respectively.

Jan 1, 1997