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By W. D. Keller

Scan electron micrographs, SEM's, will be shown of representative refractory clays from Missouri deposits, with counterparts from other localities. The story is in the pictures, ("1000 words in each picture"), but clay types include the following. Plastic, semi-plastic, and semi-flint "fire clays" of Missouri have textures which appear to retain certain relic texture of ball clay. Flint clay is composed of tightly interlocking packets, sheaves, and books of kaolinite. Diaspore and boehmite mineral textures characterize those "clays". Surface-boulder diaspore shows very pronounced recrystallization and crystal enlargement from original, unexposed first-grade diaspore.

Jan 1, 1977

By M. H. Rauschkolb, J. A. Cremeens

Geotechnical solutions were developed for closure of two historic, remote underground mines in the deserts of southern California. Closure criteria included access closure, minimal site impact, and optimum use of native materials. The closure designs and construction activities incorporated techniques for protecting sensitive biota, particularly bats and desert tortoise. The types of mine openings that were closed include adits, declines, shafts, daylighted stopes, and dugout dwellings. The desert locations permitted implementation of cost-effective closure techniques that relied upon the use of native materials. The strategies and techniques developed for these desert closures are adaptable to other climates.

Jan 1, 2002

By T. C. Vogt

Earlier we described the uranium mineralogy of an areally broad sampling of Crownpoint ore, including the characterization of organic carbonaceous material associated with the uranium mineral. (1) We also reported on the leaching behavior of Crownpoint ores with a mild alkaline leaching system, oxygen (02)-sodium bicarbonate (NaHC03). (2) There was a wide range of leaching responses, with samples from some areas leaching at a slow rate with low uranium recovery. Evidence indicates that in these samples the organic material is intimately associated with the uranium mineral and shields it to some extent from contact by the leachate. (1,2) One method to obtain faster leach rates and higher recoveries is to use a chemically severe leaching system such as sodium hypochlorite (NaOCI) as an oxidant. (3) The use of sulfuric acid (H2SO4) and an oxidant for leaching ore in surface milling operations is widely practiced to effect high recovery of uranium (U308) from the ore. (4,5,6) The U308 is mobilized as the disulfate complex, U02(S04)224-, or possibly, the trisulfate complex, U02(S04)34-, is the soluble species. (7) Sulfuric acid leachate formulations were used in the first in-situ leaching operation in the Shirley Basin in Wyoming. (8) More recently H2S04 formulations have been used in the Rocky Mountain Energy field tests in the Powder River Basin (Bear Creek) and in the Teapot forma¬tion at Nine Mile Lake site near Casper. (9,10) Laboratory studies related to the use of H2SO4 for in-situ leaching have been reported (11-17) and Yan has .reported packed column leach studies on Crownpoint ore using H2504 and oxidant. (18)

Jan 1, 1981

By Panagiotis Chryssanthakis

"The aim of this study is to give a better understanding for the performance of the composite material RRS and the synergy effect of its components under different stress regimes and while an excavation face advances during tunneling. The lower part of the Q-system scale (i.e. Q-values of 0.4 or less for a tunnel span of 10m) is commonly used for tunnel applications in softer rock formations. This is implied in the updated Q-chart, where the dimensioning of rock support by using Reinforced Ribs of Shotcrete (RRS) comprises the use of fiber reinforced shotcrete, S(fr), rock bolts and shotcreted beams reinforced with steel rebars. In this study, an effort has been made to simulate RRS in a numerical code and to study its behaviour in a real case study. A double tube, triple lane tunnel in weathered tuff has been chosen as reference material for testing RRS under changing load. A rather extensive parametric study has been run by using the same key input rock mass parameters and three different in situ stress regimes (sH/sv =2, sH/sv =1 and sH/sv =0.5). Changes have only been made to the RRS key input parameters in order to simulate the changing loads during the face excavation process in tunneling. The critical part of this numerical modelling work that is under investigation in this study under each stress regime, is the period just after the excavation: i.e 4 hours; 16 hours after excavation; and finally after the complete curing (28 days) of the cement based components. The RRS are installed in three consecutive numerical steps as follows: a) the application of S(fr) on the rock surface in order to even it up for the RRS application; b) radial bolting; and c) installation of the reinforcing steel rebars, that form the reinforced beam. The results are varying and are strongly dependent on the imposed stress regime and they show in general the following tendencies: The axial forces on S(fr) show that S(fr) is almost overloaded during the first 4 hours in all 3 stages. More particularly: For the case with sH/sv =2 a) the axial forces on S(fr) and on the steel rebars are reduced after 16 hours and 28 days; b) the same is observed on the shear stresses in S(fr) and on steel rebars, they are decreasing after 16 hours and 28 days; and c) the bolts loads are almost unchanged. For the case with sH/sv =1 a) the axial forces on the S(fr) are reduced after 16 hours and 28 days; b) the same is observed for the axial and shear stresses, as well as moments on the steel rebars, they are decreasing after 16 hours and 28 days; and c) the bolts loads are almost unchanged."

Jan 1, 2016

By E. F. Draskovich

In 1984 a high temperature heat recuperation system was installed in the pellet plant of the National Steel Pellet Company located in Keewatin, Minnesota. The system is similar to those of Cleveland Cliffs Empire and U.S. Steel's Minntac operations. It recovers hot process air from the cooler by induced flow, and directs it to an intermediate zone between the drying and preheat zones on the grate machine. This system recently underwent further modifications in April 1985, following initial operation in 1984. The M. A. Hanna Company, which manages the property, developed the design criteria and made the subsequent recommendations for modification through its research facility in Nashwauk, Minnesota.

Jan 1, 1986

By A. Bhagwat, S. Tadolini

"Steel members of the ground support systems in underground mines are routinely exposed to corrosive environment that may range from acidic to alkaline. Corrosion of steel bolts leads to metal loss and thereby, reduction in strength and useful life. Protective coatings are commonly applied to the steel bolts to combat corrosion. However, coatings are expensive and often cumbersome in practical applications. Instead, Minova has developed an innovative technology based on sacrificial anodes. The anodes were designed from non-ferritic alloys that are inferior to steel on the Galvanic Series. This paper will present data from field testing to show significant benefit of the technology. Potential applications in current products will be discussed. INTRODUCTION Corrosion is a physical alteration of a steel material from electrochemical reaction with its environment that often results in reduction of the mechanical and physical properties of that material. Mine roof bolts, the subject of this investigation, are particularly susceptible to corrosion as they can be exposed in their working environment to ground water and air with high humidity. As other researchers have determined, corrosion increases markedly in sulfide ore bodies due to acid runoff. There are several types of corrosion that a rock bolt is likely to undergo when used for ground reinforcement in underground mines (Aziz et al., 2013). Of all the types of corrosion, pitting is particularly dangerous as it can remove capacity for the bolt to deform with subsequent strata movements. Sudden failure of a bolt is likely to occur when severe pitting corrosion is experienced. The type and nature of corrosion depend on the nature of the ground condition and bolt encapsulation. Generally, the type of corrosion and severity of the corrosion varies along the axis of bolt. Almost all of the mine roof bolts used in mines, with the exception of fiber reinforced polymers, are made from steel. The corrosion of iron is an electrochemical phenomenon with the overall equation:"

Jan 1, 2018

By Robert R. French

Commercial grade gypsum beds up to 16 feet thick is present in southwestern Indiana. The major deposits are found at a depth of 350 feet to more than 500 feet below the surface. The ore body averages about 75 to 95 percent gypsum. Two companies are currently exploiting a deposit which underlies an area of several square miles near Shoals, in Martin County. Another deposit has been located in southwestern Owen County but has not been developed. The Indiana Geological Survey is currently drilling in Greene County and is considering further exploratory work in Perry end Dubois Counties.

Jan 1, 1965

By Tedd B. Bodimer

Why complicate an already complex machine such as a continuous miner by adding roof drills? Immediate permanent roof support is an immediate thought of the mining engineer just as elimination of frequent time-consuming places changes is a thought of the methods engineer. The realization of those two objectives has the potential for improved safety with increased production is the thought of the general manager. Miner-Bolters Used a Generation Ago These are not new thoughts as the 1CM continous miner equipped with two integral roof drills was introduced twenty-five years ago. Approximately two hundred of these machines were sold in the next five years for use in medium and high seam operations. The 1CM miner chassis that remained stationary in the center of an entry or room while the ripper bar was swung and sumped hydraulically provided an ideal platform for mounting two roof drills that could be operated during the continuous miner's production cycle. Two roof bolts could normally be installed in less time than required for the mining cycle. A typical roof drill unit is shown in Figure I.

Jan 1, 1981

By S. K. Mohanty, T. M. Dittrich, M. J. Allen, M. Dardona, A. C. Strzelecki, J. Hovey, Boukhalfa. H.

Rare earth elements (REEs) have many critical uses in advanced technology and the lack of a reliable domestic supply has been identified by the US DOE as a vulnerability to US economic security. Our research focuses on developing an economical process for extracting REEs from coal fly ash and power plant wastewater sludge by coupling a hydrothermal extraction process with the engineering of a ligand-associated media for concentrating REEs from the extraction liquid. Ash samples have been collected from two Detroit-area Power plants that burn 100% low sulfur coal (Trenton Channel) or fuel blends of 75% low sulfur coal and 25% high sulfur coal or 70% low sulfur coal, 15% high sulfur coal, and 15% petcoek (Monroe Power Plant). Ash samples are then subjected to hydrothermal conditions from 100-350 °C for 1-24 h at Los Alamos National Laboratory and leachate concentrations are measured by inductively coupled plasma-mass spectroscopy (ICP-MS) and compared to hydrofluoric acid digestion results. Experiments designed to aid in ligand selection and loading optimization show that di-(2-ethylhexyl)methanediphosphonic acid (H2DEH or DIPEX™) can be successfully loaded to a commercially available swellable organically modified silica (SOMS) media. Preliminary results show that DIPEX-associated SOMS surface loading can exceed 4x on a mass/mass basis and in simplified sorption experiments with Nd solutions (~pH 2), the DIPEX-SOMS media can sorb >90 mg Nd per g of media. Recovery of the sorbed Nd with low pH solutions has had low efficiency with the high (4 g DIPEX/ g dry media); however, near complete recovery was achieved with lower surface loadings (0.05 g DIPEX/ g dry media). Column experiments are being conducted to evaluate the optimal ligand/media ratio for repeated use. Completive sorption with Fe and other major cations are also being evaluated.

Jan 1, 2019

By H. EI-shall

The conventional beneficiation scheme for Florida phosphates involves reverse flotation with an intermediatory acid scrubbing step. A single reagent flotation process, using fatty acids or amine as the collector, would eliminate the scrubbing step along with the other flotation step. This can not only simplify the process flowsheet, but also result in reduced reagent costs. The potential of single reagent flotation of Florida phosphates using fatty acids as the collector was examined in this study.

Jan 1, 1993

By G. C. Allen

Selective flocculation is used for the purification of clay minerals. Here we present data from a surface spectroscopic investigation into the polyacrylamides mediated selective flocculation of kaolin from an impure matrix. Use of X-ray photoelectron spectroscopy (XPS) was shown to offer a useful approach for investigating the observed selective separations. In particular, a new small area XPS technique was used to characterize, in situ, the differential competitive, f1occulant adsorption onto mixed kaolin/gangue systems.

Jan 1, 1998

By M. A. D. Azevedo

The effect of pulping reagents on the flotation de-inking of laser printed wastepaper was investigated with regard to the removal efficiency of toner and mineral filler particles for different pH values. These results show that caustic pulping causes the toner to be released from the fibers at larger particles sizes. On the other hand, acid pulping not only causes the toner to be released at smaller particles sizes but also increases the concurrent flotation removal of mineral filler particles. It was experimentally observed that the froth generation and stability during flotation were improved for acidic pH values.

Jan 1, 1997

By V. M. Torres

Arapiraca ore deposit has a mixed chalcopyritelbornite mineralogy, with a copper head grade of 0.7%. The reserve size does no allow profitable exploration by grinding/flotation. The technical feasibility of exploring the reserve by heap leaching was studied. Preliminary agitation tests indicated 85% copper recovery. To simulate heap leaching, column tests were performed. The tests included different ore types and acid addition levels. Operating at pH range 1.6-1.8, 67% copper extraction was achieved. Also, it was found an empirical correlation between the operation pH range, copper extraction and acid consumption.

Jan 1, 1996

By N. N. Manu

In the Central African Copper Belt, sulfidization flotation is the standard practice for dolomitic copper oxide ores. It is a delicate process, and its plant application requires close control of the reagent addition. This paper presents the results of a thorough laboratory investigation. It features the monitoring, during sulfidization, of the pulp pH, the residual sulfide ion concentration and redox potential. Variables examined during the process were: retention times, sulfidizer additions, pH, collector type, dispersant dosage and reducing agent addition. Implications of the findings for plant application and process control are also briefly examined.

Jan 1, 1994

By Kenneth N. Han, Peter Mam-soo Kim

The extraction behavior of gold in ammoniacal solutions in the presence of bromine as an oxidant has been studied. The effect of concentration of ammonia, bromine, and pH of the solution on the rate of dissolution of gold was investigated. The dissolution behavior has been analyzed using electrochemical method, and its results were compared with direct leaching tests using gold powder. The overall dissolution of gold in ammoniacal solution containing bromine was found be affected significantly by pH of the solution and the concentration of bromine. The rate expression found in this study has the following form.

Jan 1, 2005

By I. González, G. Lapidus, M. Teutli

The cementation kinetics of silver with aluminum particles were studied with model solutions under nitrogen atmosphere, varying the temperature, aluminum/silver ratio, pH and concentrations of thiourea and surface activator Recoveries were evaluated both by solution concentrations and by REDOX measurements. Tafel curves were determined for this system. The results showed the cementation process to be essentially independent of the pH and thiourea concentration. However, a strong influence was observed with respect to temperature, aluminum/silver ratio and the quantity of activator. There is evidence that the controlling step is the dissolution of aluminum oxide from the particle surface.

Jan 1, 1990

By David R. Baughman, Ray V. Huff, Paul D. Chamberlin

ISL Ventures, Inc. (ISLV) is developing a process for recovering gold and silver from ores using a chloride-hypochlorite lixiviant. The leach solution, composed of water, NaCl and NaOCl, is maintained at a pH of about 7. At this pH most base metals are not leached. This is important for deposits that contain cyanide-soluble copper. An inhibitor can be incorporated to slow the decomposition of the oxidant. This paper reviews the history of development, presents details of the chemistry and indicates the nature of deposits, which we believe to be amenable to production using the process.

Jan 1, 1999

By J. H. Rowland, R. A. Thomas, III, C. D. Litton

Atmospheric monitoring systems (AMS) are required when using air from conveyor belt entries to ventilate working sections in U.S. underground coal mines. AMS technology has the potential to increase fire safety mine-wide, but research is needed to determine the detection and response times for fires of a variety of combustible materials. To evaluate the potential of an AMS for fire detection in other areas of a coal mine, a series of full-scale fire experiments were conducted to determine detection and response times from fires of different combustible materials that are found in U.S. underground coal mines, including high- and low-volatility coals, conveyor belts, brattice materials, different types of wood, diesel fuel, and a foam sealant. These experiments were conducted in the Safety Research Coal Mine (SRCM) of the U.S. National Institute for Occupational Safety and Health (NIOSH) located in Pittsburgh, PA, using a commercially available AMS that is typical of current technology. The results showed that through proper selection of sensors and their locations, a mine-wide AMS can provide sufficient early fire warning times and improve the health and safety of miners.

Jan 1, 2016

By David M. Mchaina, Allan E. Hall, Siegfried Rohr, J. D. Botsford

Incidents associated with secondary dust ignitions in the mining of massive sulphide ore deposits are of major concern in Canadian underground metal mines. During stope or development blasting, a highly concentrated cloud of sulfide dust is created and may be ignited, resulting a secondary explosion which releases a considerable volume of sulphur dioxide and possibly other sulphur gases. The consequent pressure, heat and toxic gases can result in loss of life, significant damage to equipment and loss of production. These losses are expensive and should be prevented. Explosions of this type have occurred at the H-W mine of Westmin Resources mainly in the development headings and cut and fill stapes. This paper presents the results of a study conducted at the H-W mine to compare dust sampling methods for explosivity tests. The associated benefits and pitfalls of each sampling technique are examined. The investigative work conducted to develop and test preventive and control methods against sulphide dust ignitions is also discussed. The techniques which will minimize the risk of sulphide dust ignition in metalliferous mines are outlined. A review of current preventive and control measures practised at the H-W mine is also presented.

Jan 1, 1989

By Marie-Antoinette Dziurla, Barrie Johnson, Åsa Kolmert

Acidophilic bacteria are well known for their role in accelerating the oxidative dissolution of sulfide minds, such as pyrite. Other acidophiles, however, are able to catalyze dissimilatory reductive reactions. Bacteria that reduce ferric iron to ferrous, and sulfate to sulfide, were isolated from ARD-impacted environments and immobilised onto porous beads made of recycled glass. Column bioreactors containing colonized beads were constructed and peacolated with synthetic and actual ARD, and evaluated for their capacities to promote iron or sulfate reduction, and pH amelioration. Iron reduction did not require strictly anoxic conditions in bioreactors, and rates of up to 800 mg Fe3+ reduced/(l*day) were achieved, with a conversion efficiency of up to 98%. Using mixed populations of acidophilic fungi and iron-reducing bacteria, the bioreactors were capable of promoting iron reduction using paper pulp as sole carbon and energy source. Reduction of sulfate in pack bed bioreactors was observed with acidic wastewaters of pH 3 and above, though average rates of 300 mg sulfate reduced/(l*/day) were less than those recorded for circum-neutral pH systems. Bioremediation of ferric iron-rich ARD was assessed using coupled iron-reducing and sulfate reducing bioreactors.

Jan 1, 2000