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Datun Concentrator currently processes complex sulfide ores in Gejiu Municipality, Yunnan Province, China. The ore contains much higher arsenic than other ores. The run of mine ore is fed to the concentrator to recover copper and tin by bulk flotation and gravity concentration, and then the other sulphides, such as pyrite, arsenopyrite, etc. didn?t get utilized and are discarded as tailings due to the high arsenic content. In order to utilize the pyrites in the tailings, a series of tests have been conducted for finding the solution of arsenic removal from high arsenic-bearing pyrite concentrates through simple flotation process. By means of orthogonal experimental design, the optimized levels and main factors have been found out for the roughing stage. Through selection of the effective in-organic depressants for the arsenic-bearing minerals, the arsenic in the pyrite concentrate can be removed to meet the requirement of sulfuric acid plant (As%=0.5%) by the open flotation process, i.e., one-time roughing and two-time cleaning.

Jan 1, 2014

By T. Bhambhani

Research at Cytec over the past two decades has shown that the traditional approach for ore metallurgical characterization (typically conducted via laboratory-scale batch flotation tests), which involves changing reagents and conditions one-factor-at-a-time, leads to several pitfalls. The chemical solution thus selected has a narrow un-optimized window of performance and will likely fail in the plant. A holistic approach, called the Flotation Matrix 100? process for ore metallurgical characterization, was developed at Cytec about a decade ago and has been successfully used to develop robust reagent solutions for several operations around the world. The premise for the approach is that flotation outcome from ores is variable and is determined by complex interactions between various physical, chemical and operational factors. A key component of the process is the use of efficient multivariate designs focused on the chemistry aspects (reagents and pulp chemistry), which helps identify the best processing conditions for each ore type, as well as the conditions resulting in poor performance. It also includes advanced statistical methods for dealing with the complexity and variability of experimental data. The holistic approach is illustrated in this paper with a case study on Pb/Zn ores. Using just 18 carefully designed batch tests, it is possible to partially simulate the behavior of each ore type in the plant. The best conditions for each ore type, along with the conditions to avoid, are identified. Along with this, insights are obtained into the reasons for high reagent dosages for certain ore types, and interactions between variables. Keywords: flotation, holistic approach, metallurgical characterization, multivariate experimental designs, base and precious metals recovery, sulfide collectors and modifiers, Pb/Zn sequential flotation

Sep 1, 2012

By E. Lee

With the growing environmental concern, as well as the increasing concern for sustainability of natural resources, the need of improving the performance and efficiency of today?s crushers is be-coming increasingly important. However, the development of existing crushers requires an extended basic knowledge about the crushing process itself. The aim of the present study is therefore to find the theoretically optimal way of crushing compressively under given circumstances. In the present paper, optimizations have been performed with the purposes of maximizing product yield and minimizing energy consumption. Performed on an ideal crushing stage free from physical limitations, the optimization results have been obtained in terms of number of compressions and their corresponding compression ratios. Complementing earlier results on interparticle breakage (Hulthén et al., 2006), presented here are thus the results from corresponding optimizations with single particle breakage and interparticle breakage. It is concluded that modern crushers are not working optimally in any of the studied aspects for gneiss. In fact, optimizations indicate that a lowering of the compression ratio, as well as a shortening of the crushing sequence, are theoretically favourable. The outcome of this study is therefore highly promising as to giving new ideas and suggestions of improvements in existing crushers, and can even result in redesign of compression crushers.

Jan 1, 2014

By B. Peszko

There are many measuring methods of grain sizes. Taking into consideration the fine grained materials, one of the existing techniques is measurement of grain size by the Coulter Counter method. This method is based on the measuring the changes of electrolyte resistance during grains flow through the calibrated diaphragm. This method is relatively simple to apply, significantly precise and the results are given quickly. However, the problem is that the measurements are limited by the size of diaphragm. Because of this situation, measurement of grain sizes by this instrument is possible in range from 10% to 60% of diaphragm diameter. This limitation causes the necessity of re-placing diaphragm in case when the measured grain size distribution concerns the material of large size range. In purpose of determining the total grain size distribution, the synthesis of some partial distributions, given for individual grain fractions (with different diaphragm applied), is required. This is possible to do by calculating the mixture of distribution functions, created from the partial distribution functions. Two materials were selected to research: quartzite and glass, which were comminuted in cylindrical crusher, additionally grinded, screened and then analyzed by Coulter Counter for five grain fractions: 0~125 µm, 0~80 µm, 0~56 µm, 0~40 µm and 0~25 µm. For each fraction, five different partial distributions were given (in case of glass ? four), which are the basis for the creating the joined grain composition. To assure the adequacy of the given distribution function, it is necessary to obtain the possibly best approximation of partial distributions. In the work, both the parametric and non-parametric methods of density approximations of investigated random variable. For each grain fraction the approximations were done by three traditional distribution functions: RRB, GSA and log-norm distribution functions and three methods of non-parametric approximation: Gauss kernel, Epanechnikov kernel and orthogonal Fourier series method. As the criterion of the certain distribution function acceptance, the value of the residual deviation was assumed, given by the formulae:

Jan 1, 2014

By Sanchita Chakravarty, Sumantra Bhattacharya, Divya Jyoti, A. K. Mukherjee, Soni Jaiswal

"Release analysis is independent of collector and frother dosage and type, but it is primarily influenced by the degree of liberation or “state of release of the sample”. The shape of release curve is an indication of the degree of liberation. This paper briefs about the effect of reagent combination, particle size and surface characteristics on the release analysis of difficult-to-clean LVC coal.Release analysis of three LVC coal fines obtained from two different coalfields of India was carried out at three different size levels such as -0.5mm, (-0.5+0.1) mm, and -0.1mm. The collectors used were n-dodecane and commercial diesel oil. Incomplete liberation of coal fines even at a size of -100µm, corroborated by photomicrographs of ROM and clean coal macerals, in a great measure reduced the flotation-based cleaning potential of the fines. FESEM images of fines reveals that the adherence of ultrafine onto the surface of relatively coarser particles reduced the clean coal recovery. The results obtained also appear to be coal, reagent combination and, particle size and particle surface specific. Only one coal indicated the liberation as is usually expected for -0.1mm particles with a reasonable yield of 65% at 18% ash. INTRODUCTION Froth flotation has a long history of being used to treat coal fines. Coal flotation is considered to be difficult, if the percentage of Near Gravity Material (NGM), i.e. essentially locked particles, in flotation feed is >10% [Aplan, 1993], which is usually the case with all the coking coal fines in India. The fines are rich in vitrinite, so valuable for coking coal. Unfortunately, there appears to be no standard procedures to determine the separation efficiency of froth floatation. Release analysis proposed by C.C. Dell in 1953 [Dell, 1953], aimed to determine the ultimate floatability of coal. Several other techniques had been proposed but release analysis technique has been considered to be a vast improvement over the batch flotation process [Forrest et al. 1994]."

Jan 1, 2018

By Haragobinda Srichandan

The present study aimed to investigate the bioleaching efficiency of moderate thermophilic microorganism in a growth medium without Fe supplement on three different size fractions of spent catalyst obtained from petroleum refinery. All the experiments were conducted on shake flasks at a temperature of 65 °C and a pulp density of 10% (w/v) on three size fractions viz. 45-106 µm, 106-212 µm and >212 µm and a working volume of 100 ml comprising of 10 ml of microbial inoculums and 90 ml of Modified Kelly medium. The parameters like pH, redox potential, viable planktonic cell count and the amount of acid addition was measured and quantified on regular basis to follow the progress of the bioleaching. The pH varied much in the lag and logarithmic phase of the experiments but stabilized toward the stationary phase. The total acid additions in each batch experiment were determined the amount of Conc. H2SO4 requirement, which ranged between 683-757 kg/ton of spent catalyst. The redox potential values ranged between 625-650 mV, Ag/AgCl, but were very low ranging between 350-450 mV during initial period. The planktonic viable cell count ranged between 108-109 cells/ml active in the bioleaching system, without any toxic influence of the spent catalyst, but initially due to fall in redox potential and new environment for the microbes, their population was low. The leaching yield of Ni was found to be promising with very high leaching yield of 92-96% followed by Al as 61-62%, which means both Ni and Al leaching were favored by the moderate thermophilic bioleaching compared to the mesophilic bioleaching. There was very little difference in the leaching yield, when compared with different size fractions and hence grinding can be avoided prior to leaching. This process seems to be economical as no Fe source is supplemented together with no requirement of grinding and over all a biological process resulting for an eco-friendly process for future optimization of the metal recovery from petroleum refinery spent catalysts. Keywords: bioleaching, spent catalyst, thermophile, 9K medium

Sep 1, 2012

By Ali Dehghani Ahmad Abady

In Sarcheshmeh Copper Complex, a molybdenite floatation concentrate was produced by selective removal of copper impurities with 7 stages of cleaner floatation banks, that contains around 1% copper and 54.5% molybdenum. Mineralogical studies, physical and chemical characterizations showed that the sample contained 91% molybdenite (MoS2), 2.6% chalcopyrite (CuFeS2), 0.2%Covellite (CuS), 1.6% pyrite (FeS2) and 4.6% other nonmetallic impurities. In the present study, the removal of the copper sulfide was investigated by ferric chloride leaching for achieving a molybdenite concentrate with copper content less than 0.3%. Therefore, the application of response surface methodology (RSM) for modeling and optimization of the influence of three control parameters including ferric chloride (FeCl3) dosage, reaction temperature and reaction time, each varying in five levels, were considered, and the mathematical model for prediction of %Cu removal from molybdenite concentrate was derived. This study showed that RSM could effectively be applied for the modeling of ferric chloride leaching, and finding an economical optimum condition to achieve maximum de-coppering efficiency while consuming minimum leaching reagents. The optimum dissolution conditions to maximize Cu extraction were 200 kg/t for ferric chloride dosage, 120 min for reaction time and 80 °C for reaction temperature with a prediction of 83.20% Cu dissolution. Keywords: molybdenite concentrate, ferric chloride, leaching, response surface methodology (RSM)

Sep 1, 2012

By V. V. Lvov, L. S. Chitalov

"The purpose of the research is intensification of physico-mechanical ore properties determination for ball grinding processes in comminution circuits. The research presents comparative studies aimed at intensification of Bond Ball Mill Work Index (BWi) determination, such as testing technique of Ahmadi and Shahsavari, Berry and Bruse, Gharehgheshlagh, Horst and Bassarear, Kapur, Magdalinovich. The subject of the research is a test procedure of apatite-nepheline, copper-nickel, gold-sulfide and iron ores for the Bond ball mill index. The Bond Ball Mill Work Index for the material firstly was determined by standard Bond test methodology. Two the most promising testing techniques - Ahmadi and Kapur testing techniques - were modified. For the Ahmadi technique it was proposed to pay attention to the circulating load, which should be stabilized on the value of 250% as fast as possible. Two methods were put forward to quicker stabilize the circulating load. For the Kapur technique it was proposed to use empirical coefficients, which is determined especially for the apatite-nepheline, copper-nickel, gold-sulfide and ores. The modified Ahmadi and Kapur techniques require no more than two cycles of ball grinding to determine BWi (while normally 6-8 cycles are required) and less than 5 kg of initial feed. The suggested modified Ahmadi and Kapur techniques allow to intensify the physico-mechanical ore properties determination for ball grinding processes and BWi test costs considerably, which makes them useful for mass sampling and monitoring strength properties of ores entering a concentrating mill. INTRODUCTION When designing concentrating mills, the choice of the technological scheme for ore pretreatment, particularly the type, quantity and size of the main process environment, the determination of optimal grinding conditions and the calculation of equipment load are carried out by preliminary studies of grinding in semi-industrial or laboratory-scale plants. Semi-industrial tests on full-scale plants provide the most reliable information for calculating specific loads for equipment. However, this requires a significant amount of ore samples, a high labor costs and the pilot plants. Thence the most researchers performed grinding tests with small laboratory equipment using small ore samples."

Jan 1, 2018

"The most common comminution testing methods and the associated analytical procedures provide average values and do not capture the variability in breakage behaviour of ore particles. Therefore, plant designs and process performance predictions use only average values; hence, the inherent variability that exists within an ore domain translates into variation in process performance. This paper discusses the drawbacks of using the average approach to impact comminution testing and plant design. It considers breakage intensity from a single-particle testing perspective. To clearly delineate breakage behaviour of each broken particle, an experimental technique using the JK Drop Weight Tester (JKDWT) has been developed by which actual comminution energy per particle and breakage intensities were measured directly. Four different ore types in ranges of -45+37.5mm and -22.4+19mm were tested at three energy levels of 0.1, 0.25, 0.5 kWh/t and six energy levels of 0.5, 1.0, 2.0, 2.5, 3.0 and 4.0 kWh/t, respectively. Sieved results of individual particles, notionally, t5, t10 and t50 showed the presence of large variability in their breakage behaviour, which was not captured by the standard JK impact breakage testing approach. In addition, the original JKMRC model is modified by introducing a third parameter, ‘Emint10’ which describes the minimum energy required to produce the minimum percent t10 for a given ore type and its significance is tested statistically. These results suggest that the analysis of breakage variability may lead to more robust plant designs. Perhaps, the most useful insight from this work is to extend single particle breakage model developed by JKMRC to a comminution percentile envelope which may provide a more detailed picture of ore breakage variability. INTRODUCTION Rock consists of mineral grains, pores, voids and cracks that may differ markedly in size/density which make rock a heterogeneous material by nature. The degree of heterogeneity in rock affects its breakage characteristics where these variations increase local differential strain and stress within a stressed rock (Scholz, 1968) and it depends on many factors such as rock genesis, alterations, etc. One important aspect of this heterogeneous feature is presence of a large amount of experimental scatter in rock breakage results when considered from a quantitative perspective (Bieniawski, 1967; Liu, Roquete, Kou, & Lindqvist, 2004)."

Jan 1, 2018

By J. Z. Yuan

The purity of rectorite is only about 70% after preliminary mineral processing, which has limited its application. In this research, different pulp densities, different dispersants, different dispersing methods and purification flow sheets were used to purify rectorite. The results show that it is possible to obtain high pure rectorite clay with the purity above 90% and concentrate yield between 24.9% and 29.4% by the purification process with composite dispersants, stirred mill grinding dispersion and so on. The obtained high pure rectorite can be further used in rectorite nanocomposites.

Jan 1, 2014

By J. Botula

In the region of the North-Bohemian Coal Basin and its environment, there, in a row of places, are found the accumulations of rocks of the sedimentary and pyro clastic origin, the preliminary composition of those shows the possibility of their being utilized for the production of ecologically sparing natural Fe- and Ti- pigments and filling substances. In many places of the regions of Chomutov and Podborany and near Bilina and also in other places, there are found raw stocks perspective for the preparation of yellow up to ochre-brown, red, brown-red and green dyes. The target of project is the verification of dispensable reserves, their mineralogical composition and chemical and physical attributes, verification of treatment ways of Fe-and Ti-pigments separation (hydrocyclones, magnetic and electrostatic separation) and their stabilization and technological painting attributes for applications in colors, coating and plastic masses, mortar mixtures etc.

Jan 1, 2014

By S. Narra, M. Nelles, I. Eickhoff, S. Teitge

"The aim of the research is to develop a holistic process flow for the recycling of glass fibres from glass reinforced plastics (GRP) and carbon fibres from carbon fibre reinforced plastics (CFRP), wherein the dissolution of the fibre epoxy resin matrix, separation of fibre fractions and their renewed material use is intended. In clear distinction to the previous research and development projects, the aim here is to recycle complex composite structures such as dismantled/disused wind turbine rotor blades and end-of-life composite wastes. In the course of the study, mechanical, hydrothermal and thermal processes and their combined procedures will be developed. As the fibre length is a decisive quality criterion in the recycling of composite materials, the further focus of the study will be the development of upstream and downstream material processing, in which the fibres are retained in their original form. The evaluation of the recycled fibres obtained is based on the elemental composition, measurement and morphological evaluation of individual filaments by scanning electron microscope (SEM), micro tensile tests on single fibres and their comparison to virgin fibres. The resulting process water is analysed by gas chromatography and mass spectroscopy (GC-MS) and a potential recirculation is determined. In cooperation with companies from the composite processing industry as well as recycling companies, a return of the recycled fibres to the known manufacturing process will be examined and an energetic and economic evaluation of the overall process will be carried out. Ambitious aim of the study is to achieve an actual recycling instead of the present downcycling or the energetic utilization. INTRODUCTION As global warming increases, so does the awareness of consumption and production of energy. To counteract the effects of global warming, renewable energy has been increasingly used during the last two decades, not only in Germany, but worldwide. Both, hydropower and wind energy, hereby play a fundamental role. After the end of their useful life of 20 to 30 years, the wind turbines (WTs) are being dismantled. Due to their foundations and tower segments, their recycling rate hereby exceeds 90% by mass. So far, the resulting rotor blade waste played a minor role accounting for only 2 - 3 weight-% of the total plant. Rotor blades of modern wind turbines are made of glass and carbon fibers, which are embedded in an epoxy or polyester resin matrix, balsa wood, PU or PET foams as fillers as well as various paints and coatings. These wastes currently end up in waste incineration or are sold to non-European countries."

Jan 1, 2018

By S. Castro

The aim of the present paper is to review the current technologies for arsenic removal in the copper metallurgical industry, and to show the progress made with some promising emerging strategies, involving the pre-treatment of copper-arsenic concentrates by selective flotation or by alkaline leaching with Na2S-NaOH solutions. The advantages of alkaline leaching are the selective dissolution of arsenic and antimony, the high extraction yield, and the practically nil loss of copper, which remains in the clean copper concentrate as a CuS residue. Alkaline ?cured? ? a procedure similar to ?acid-cured? in conventional leaching ? improves arsenic extraction and reagent consumption, making this an interesting technology for the treatment of high As-Sb concentrates. In light of recent advances on the selective flotation of enargite and tennantite, the importance of redox conditions to control the flotation/depression of enargite-tennantite from copper sulfides has been well established. However, problems of selectivity must still be solved. Additionally, the limitation imposed in some cases by the need to recover the molybdenum by-product must be considered. The application of selective flotation to obtain a high-arsenic or ?dirty? concentrate and its sub-sequent treatment by the alkaline leaching process is suggested.

Jan 1, 2014

By Z. Naziemiec

Since several years in Poland a huge demands on mineral aggregates occur, for the reason of intensive development of housing and road industry, as well as industrial building. Limitations in re-sources of broken aggregates in Central and Northern parts of Poland cause, that both the non-waste production of aggregates with high quality and the production of alternative aggregates from recycling gain greater importance, nowadays. It entails increase in demands for crushing devices, which are easy and reliable in operating as well as inexpensive and enabling to obtain a good quality products. Jaw crusher, regarded as the most spread in Polish industry, meet these requirements, however, their crucial disadvantage is a large content of irregular grains in crushing products. Numerous investigations show, that the shape of grains is a significant feature of aggregates, which influences on durability and quality of produced concretes. The advantage of jaw crushers is their easy operation, low price as well as low amount of dusts (wastes) generated in comminution products in comparison to other types of crushers (i.e. hammer crushers).

Jan 1, 2014

By Sravya Kosaraju, Christian Ekberg, Stefan Allard

Li-ion batteries are now used in electric vehicles (EVs), plug-in hybrid vehicles (PHEVs) and, hybrid electric vehicles (HEVs). Nanostructured Li(NiyMnzCo1-y-z)O2 is one of the more popular cathode chemistries for automotive Li-ion battery, due to its enhanced properties such as large surface area, short diffusion length, enhanced ionic and electronic conductivity, improved mechanical strength and structural integrity [Pan et al, 2013]. Recycling of Li-ion batteries helps to mitigate environmental effects of virgin metal extractions along with improper disposal of end of life batteries. To fulfill these objectives of the recycling, recovery of pure streams of the involved metals should be considered. In this study, the batteries were first discharged and dismantled in an inert atmosphere (Ar). The electrodes were then heat treated in a box furnace. This was done in order to break the chains of the adhesive (PVDF) and consequently separate the metallic substrates Cu and Al from the electrochemically active compound. This heat-treatment also helped to simplify the dissolution of the metal constituents in the electrochemically active compound from the cathode in the acid leaching process. Solvent extraction was chosen to achieve separation and recovery of metals with higher purity from these leachates. In the scope of the present work, a complete process from the point of dismantling to separation of constituent metals using solvent extraction was studied.

Jan 1, 2014

By Ying Gu

Automated mineralogy methods and tools, such as the Mineral Liberation Analyzer (MLA) and the QEMSCAN, are now widely used for ore characterization, process design and optimization. Several case studies published recently demonstrate that large gains can be obtained through grinding and flotation optimization guided by automated mineralogy data. However, since automated mineralogy can only provide the information pointing to where the process gains can be made, it does not directly impact the production gain. Thus, a question is often asked: how to value the contribution of automated mineralogy to process improvement of a particular plant. This appears to be a difficult question. On close examination however, it is found that this is essentially a question of the value of information and it is reasonably well documented in various other industries. Hubbard (2010), in chapter 7 ?Measuring the Value of Information?, dealt with exactly this type of problem. The value of information is the reduced risk of an investment and opportunity loss. The methods Hubbard developed can be applied to estimate the value of automated mineralogy, as well as metallurgical test work, which also produces information that reduces the risk of investment. This paper first introduces Hubbard?s theory on the value of information and how to measure it. It then applies his methods to estimate the value of automated mineralogy, using Anglo Platinum?s fine grinding project as an example. In this case, the value of automated mineralogy includes the reduction in investment risk worth US$ 62.5million, in project rejection worth US$197 million and in opportunity loss worth US$320 million. In the end, a general model is developed to allow the simulation of the value of automated mineralogy in different mining operations constrained by different parameters.

Sep 1, 2012

By K. B. Venkatesh

In view of the importance of size reduction operations from the energy consumption point of view, during the past one hundred and fifty years a number of attempts have been made to develop a general energy-size relationship. However, to date it has not been possible to clearly define the scope of application of various laws proposed, though Bond law has been widely used with a moderate degree of success. It was, therefore, decided to carry out a thorough analysis of the batch ball mill grinding data available in the literature on several minerals that were ground under normal range of operating conditions. In particular, relationships proposed by Bond, Kapur, Voller and Morrell were examined in detail. It was found that the relationship proposed by Kapur in terms of the mean particle size provided a more accurate basis for estimation of energy. The value of the exponent of mean particle size in this relationship, a, is same as the exponent of the particle size in the expression for the grinding rate parameter: ki = Axia, provided the particle size distribution range corresponds to the self-similar or self-preserving regime. In this regime, mean particle size is proportional to the 80 percent passing size and size modulus. From the practical application point of view, it was possible to describe the variation of µ1 over limited, but significantly broad size range, using a constant value of a. Thus, by carrying out a few batches, grinding experiments over the size distribution range corresponding to the contents of the production mill, the applicable value of a can be determined. Keywords: energy-size relationship, ball mill, mean particle size, self-similar size distribution regime

Sep 1, 2012

In flotation, particulate materials are separated by controlling the hydrophobicity of the particles using appropriate collectors. In this regard, contact angle (?) is the most important process variable. However, the flotation models used in industry today do not include ? as a parameter. As result, flotation circuits are designed based on the first-order flotation rate constants (k) determined from laboratory experiments. A problem with this approach is that laboratory experiments usually give substantially higher k values than achievable in full-scale operations, which makes it difficult to use the model for plant design. In the present work, we have developed a model from first principles using both surface chemistry and hydrodynamic parameters, such as ?, ?-potentials, surface tension (?), particle size, energy dissipation rate, etc. The basic approach is similar to the one developed previously for bubble-particle interactions under laminar flow conditions (Yoon and Mao, J. Colloid and Interface Science, 181, 61, 1996) except that the model parameters have been modified by considering the turbulence in a flotation cell. In addition, the model describes the recovery processes in froth phase, including bubble-coarsening due to coalescence. Based on this model, we have developed a computer simulator (FlotSim) that can be used to design flotation circuits from the mineralogical (or liberation) data on the feed and the hydrodynamic characteristics of a flotation machine. Since the model is dynamic, it can also be used for process control. Further, the simulator has predictive capacity as it is based on a first-principles model. The model-based simulator has been validated in a carefully controlled bench-scale flotation experiments. Keywords: flotation kinetics, flotation model, contact angle,?-potential, size-by-size recovery, liberation, DLVO theory

Sep 1, 2012

By G. Bonifazi

Mining activities belong to human history, they are lost in the mists of time. They usually impact on large portions of the territory, both directly (exploitation areas and logistic activities directly related to exploitation) and indirectly (exploited material handling, processing and storage areas). As a result, at the end of mine life cycle, dismissed areas usually cannot be directly re-utilized without efficient and well addressed rehabilitation actions. Main goal of the proposed approach was to analyze the results obtained when a set of procedures, based on the collection and the analysis of remote sensed data, is developed to evaluate the effect of rehabilitation of land contaminated by extractive industry activities and to perform a monitoring and registration of the environmental impact of such operations by the application and the integration of modern information technologies, as Earth Observation (EO) and Geographic Information Systems (GIS). The study was developed in the framework of the EU-Asia program of the European union (EXTRACT-IT Project-Contract No: CN/ASIA IT&C/006 (89870): Application of Information Technologies for the sustainable management of Extractive industry activities) and it was addressed to three different dismissed mine areas in India, Thailand and China, respectively. The results, in terms of methodologies selected, strategies applied and results obtained, are described with particular reference to Fuxin coal mine area in China.

Jan 1, 2014

By Ingvar Ymén, Alexandra Lundmark

"The depressive effect of dichromate on galena was evaluated with chemical experiments and small-scale depression experiments at a pH of around 12. The depressive effect was measured with Dynamic Vapor Sorption (DVS), which measures the water uptake of a sample as a function of the % relative humidity. The depression is due to PbCrO4PbO, which in the presence of Ca2+ and SO4 2- forms a more or less amorphous solid solution (Pb,Ca)(CrO4,SO4)PbO, which clogs to the surfaces of the ore. Free Pb2+- ions are needed for depression to occur and at high pH Pb2+ - hydroxide complexes, supply enough Pb2+ - ions to precipitate (Pb,Ca)(CrO4,SO4)PbO. In air CO2, precipitates CaCO3 which slowly lowers pH, precipitating more (Pb,Ca)(CrO4,SO4)PbO and CaCO3 on galena. Similar experiments where performed with five alternative depressors whereof phosphate, which forms an amorphous precipitate of approximate composition Pb3Ca13(PO4)10SO4, gave the best results. Phosphate was tested in laboratory scale flotation experiments giving encouraging results.INTRODUCTIONWithin Boliden Mines, concentrating of copper and lead from complex sulfide ores is performed by bulk flotation, meaning that copper and lead are concentrated in the same product. Downstream, copper and lead are separated by flotation of chalcopyrite, and depression of galena. Boliden has for many decades used sodium dichromate to depress galena (reference 1). Dichromate is both toxic and carcinogenic and Boliden has for many years investigated several alternatives. So far, however, the best results have been obtained with dichromate. Since Boliden has tried to substitute dichromate for a long time without finding a process as effective, Boliden decided to clarify the function of dichromate in the depression of galena and on the basis of the outcome find alternative depressors with similar function. This study was given to RISE Bioscience and Materials / Surface, Process and Formulation as a consultancy assignment. This paper presents the outcome of the combined efforts of Boliden and RISE."

Jan 1, 2018