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By A. Ceylan

Pyrite is present as a gangue mineral in most of complex sulphide ores and most of time it is removed as a tailing. However, beneficiation of pyrite from tailings could be important because of its economical value and for the environmental concern. This paper presents a research for the enrichment of pyrite from copper plant tailings, Siirt-Madenköy/Turkey, by flotation. Siirt-Madenköy copper mine is operated by Park Electric Production Mining and Industry since 2005. In order to obtain the pyrite from Siirt-Madenköy copper plant tailings, laboratory test work has to be done to determine the type of reagents, the flowsheet, and the size of plant. The objective of the company is to develop a pyrite flotation circuit for concentration of pyrite from tailing dam to obtain 500.000 tons/year pyrite concentrate. There are about 3 million tons tailings that containing pyrite in the tailings dam. Experiments were carried out with three different types of tailings from the plant and the pyrite concentrate with 46% Fe and 90% recovery has been obtained. Therefore, this study shows that high grade pyrite with high recovery can be recovered from the tailings.

Sep 1, 2012

By Juan Estrada, Mirtha Frómeta, Rubén Alcalá, Emilio Montejo, José Castellanos, Juan Berto, María Rivas

"The oxidized nickel ores from San Felipe deposit are composed mainly Smectites which gives to the pulps very unfavorable rheological .properties (cinematic viscosity and high shearing strength) for transportation processes (pumping), very low settling velocities and very low thickened pulps. These properties do not allow the preparation of high % solids, which affects the economic efficiency if a high pressure acid leach (HPAL) process is used. Pulps of close to 30% solids have very high BYS making pumping impossible. CIPIMM developed three technologies to solve these problems and to substantially increase the % solids in the pulps to be leached without a thickening step. These technologies are: • CIPIMM 2. At Preparation of pulps using additives. This method is based on the effect of some additives (inorganic salts) to improve the pulp’s properties. The use of this method allows increasing the % solids in the pulp up to 40% with good rheological properties • CIPIMM 2B. Preparation of pulps by thermal treatment of the ore previous to the preparation of the pulps. This method is based on the thermal destruction of the clays structure. Its use allows to obtain pulps with 50 - 60 % solids with excellent rheological characteristics. As a collateral effect, the Ni and Co grades increases by 10 - 15%. • CIPIMM 2C. Pulp preparation by chemical treatment. This method is based on the chemical transformation of clays, to obtain without thickening, pulps with 43- 45% solids and excellent rheological properties. The use of one of the three technologies depends on the chemical and mineralogical composition of the ores and the results of technical-economical evaluations to determine which one is the best alternative before running higher scale tests."

Jan 1, 2014

By T. Saastamoinen, N. Heino

"The Olserum deposit located in Sweden hosts an indicated mineral resource of 4.5 million tonnes over 0.6 % TREO, exhibiting a relatively high proportion of HREE. Beneficiation of a composite drill core sample was studied in the flowsheet of magnetic separation of magnetite followed by REE minerals flotation. Primary testwork was performed to select an effective REE mineral collector and then the parameters of grinding size, collector and depressant dosages, slurry pH and density, conditioning time and temperature, and flotation time were tested for optimization of REE flotation. The studies of process mineralogy showed that the REE-bearing minerals monazite, xenotime and apatite were successfully enriched from the concentrations of 0.6%, 0.31% and 2.6% in the feed to those of 17.0%, 8.9% and 65.0% in the concentrate with the recoveries of 79.0%, 81.3% and 71.0%, respectively. INTRODUCTION The Olserum deposit located in Sweden comprises lower grade placer material with higher grade apatite-magnetite veins and hosts an indicated mineral resource of 4.5 million tonnes at 0.6% TREO, with 34% of that being HREO (EURARE, 2017). The mineralization was studied by Andersson et al. (2018). At early stage, high-temperature REE is characterized by abundant monazite-(Ce) and xenotime-(Y) coexisting with fluorapatite and subordinate amounts of (Y,REE,U,Fe)-(Nb,Ta) oxides. During a subsequent stage, allanite-(Ce) and ferriallanite-(Ce) formed locally, partly resulting from the breakdown of primary monazite-(Ce). Alteration of allanite-(Ce) or ferriallanite-(Ce) to bastnäsite-(Ce) and minor synchysite-(Ce) at lower temperatures represents the latest stage of REE mineral formation. The mineralogy and beneficiation were firstly studied by GTK Mintec in the EURARE project for a composite drill core sample. The Olserum is considerably smaller than the Norra Kärr deposit. However, REE are hosted by xenotime and monazite, both of which have well established processing pathways, and meanwhile, the Olserum has a high contribution of the high value critical REE (dysprosium (Dy), yttrium (Y), neodymium (Nd) and terbium (Tb)), which provide a unique advantage for its exploration (Tasman Metals Ltd., 2013). In this paper, flotation of the REE minerals in the Olserum ore was studied."

Jan 1, 2018

Domestic production of pyrite cinder reached 15.95 million tons in 2006. The pyrite cinder used in cement industry accounts for about 30% production. The remaining 70%, 11.17 million tons, was thrown away as waste, which brought serious environmental and resource problems. A new technology of composite pellet reduction-roasting and magnetic-separation (CPRM) has been developed to utilize pyrite cinder. Pyrite cinder sample, containing 45.56% Fe, 0.19% Cu and 1.45% S, was pelletized with addition of 5% composite agent in balling disc. Green balls after drying were reduced at 700~800 ? for 20min with 300kg/t pulverized coal injection in rotary kiln. After two stages of ball-grinding and four stages of magnetic separation, high grade magnetite concentrate with 66.23% Fe was produced, meanwhile impurities Cu and S was decreased to 0.048% and 0.053%, respectively. And iron recovery of 73.32%, desulphurization of 96.34% and decoppering degree of 74.73% were achieved. Key technique is that composite agent can accelerate reduction of Fe2O3 and transfer copper and sulphur into water-soluble inorganic salts, which can be removed during wet magnetic concentration. This new technology can be used to fully utilize pyrite cinder and produce high quality magnetite concentrates as feed for steel industry, which will help tackle the pollution problem of pyrite cinder and extend iron-bearing raw material sourcing for Chinese steel industry.

Jan 1, 2014

By T. Fraszczak, U. A. Peuker, T. Mütze, T. Leißner, A. Wikedzi

The present paper highlights on the comminution and liberation properties of two greisen-type lithium bearing-mica ore blends (L1, L2) subjected to different breakage devices; cone crusher (CC), roller crusher (RC), rotor beater mill (RBM) and a screen mill (SM). The particle size distribution (PSD) of the products from each device were evaluated to search for an appropriate PSD model using Gates-Gaudin-Schuhmann (GGS) and Rosin-Rammler (RR) functions. In order to determine an appropriate function that could better describe the PSDs from the devices used, the coefficient of determination (R2) was used as a criterion. In terms of mineral liberation studies, due to costs, only products from rotor beater mill (RBM) were examined through an automated scanning electron microscope (SEM) technique. It was found that RBM, RC and SM products were better described by the RR model than the GGS model with higher R2 values (0.97-1.0). However, cone crusher products for L1 were better described by GSS model, while that for L2 were better described by RR model. In terms of the spread of size distribution as indicated by RR model parameters, RC products were more uniformly distributed compared to products from other devices, for both ore blends. Also the RBM products were more scattered than products from other devices. The results indicate that the composition of individual ore blends affected the comminution products PSDs since different PSD model parameters were obtained for samples comminuted by same devices. The modal mineralogy of the two ore blends indicate both to be rich in quartz, topaz, zinnwaldite and muscovite. Further, the result indicate that, for both ore blends, zinnwaldite phase is more enriched in the fraction < 250 µm. Moreover, better liberation of zinnwaldite is observed for L1 compared to L2. This could be explained by differences of the two ore blends in three aspects; the nature of mineral association, reduction ratio of the fractions analysed and the nature of spread of the size distribution.

Jan 1, 2018

By Gautam Chandra Mondal

An attempt has been made to carry out qualitative assessment of mine water discharges from the different mines of West Bokaro Coalfields of Hazaribag district of Jharkhand, India. A total of 33 mine water samples were analyzed for pH, electrical conductivity (EC), major cations (Ca, Mg, Na, K), major anions (HCO3, SO4, Cl, NO3), and heavy metals (Fe, Mn, Cu, Zn, Pb, Cr, Ni, Co, As). The hydrochemical data has been evaluated in terms of major ion chemistry, solute acquisition processes and suitability of mine water for domestic, industrial and irrigation uses. The pH of the analyzed mine waters varies from 5.27?8.43 indicating acidic to alkaline nature of the water. The electrical conductivity (EC) values varied from 276 µScm-1 to 1598 µScm-1 for measured samples and spatial differences between the EC values reflects the wide variation in lithology, surface activities and hydrological regime prevailing in the region. The anion chemistry of the analyzed water samples shows the dominance of SO4 and HCO3 with a minor contribution from Cl, NO3 and F. The observed high values of sulphate in the mine water of the area may be attributed to the oxidative weathering of pyrites. On average chloride is contributing 5% of the total anionic balance (TZ-). Fluoride and nitrate have low concentrations and on average contributing <2% the total anions. The cation chemistry indicates that 79% of the samples are Ca>Mg>Na>K, while the 6% belong to Ca>Na>Mg>K and 1% of Ca>Mg>K>Na. Weathering of rock forming minerals and cation exchange processes normally control the levels of these cations. Concentrations of some heavy metals (Fe, Mn, Ni, Cr) are found to be well above the prescribed permissible levels recommended for the drinking water. The water quality assessment for drinking purposes indicates that most of the mine water having high TDS, total hardness (TH) and sulphate concentrations. This suggests that mine water of the study area is not suitable for direct use in drinking and domestic purposes and needs a proper treatment before its utilization. The assessment of water for irrigation uses show that the water is good to permissible quality and can be used for irrigation uses. However, high values of salinity, %Na, SAR, RSC and Mg-hazard at certain sites restrict its suitability for agriculture uses. Keywords: mine water; ion chemistry; quality assessment; West Bokaro coalfields

Sep 1, 2012

By Behzad Vaziri Hassas, Firat Karakas, Mehmet Celik, Onur Guven

Since dewatering is a costly process, removal of moisture from relatively fine size lignites is an important industrial problem. As the lignite gets finer, the presence of micropores and relatively low hydrophobic nature of lignite lead to trapping of large quantities of water in the coal matrix. Lignites used in power stations need to be dried to a certain degree of humidity before it is transferred to the combustion chamber. It is generally wise to dewater coal as much as possible by physical means before it is dried. However, dewatering cost in some cases may be prohibitive. Thus, sometimes removal of even little percent moisture may be of great help in such operations. Surfactants have been used to increase the efficiency of coal dewatering. It is crucial to select appropriate type and amount of surfactants in order to get higher efficiency. Since the hydrophobic characteristic of coals increases with increasing the coal rank, dewatering of bituminous and anthracite can be accomplished using low HLB surfactants (Oily), however, these surfactants are not efficient in the case of low rank coals like lignites and brown coals. It is suggested that adsorption of low HLB surfactants on high rank coals is governed by Acid-Base interactions rather than electrostatic and van der Waals forces. Since this characteristic in lignites is not strong enough, low HLB surfactants could not be effectively adsorbed on low rank coals to make surface more hydrophobic. In this paper, a special set-up has been designed to study the effect of high HLB surfactants on dewatering of fine lignite particles. It is shown that high HLB surfactants function more efficiently on low rank coals than low HLB ones.

Jan 1, 2014

By Y. G. Seredkin, A. A. Vasiliev, A. Y. Senchenko, A. V. Aksenov

"The valuable materials resulting from the processing of gold-bearing ores are often refractory to direct gold recovery through cyanidation. There are multiple methods for chemical liberation of gold prior to cyanidation such as pressure and biological oxidation as well as atmospheric oxidation which is typically used in combination with physical activation of material by ultrafine grinding such as the Albion ProcessTM. This paper will examine the data from process testworks carried out to estimate the efficiency of the Albion Process™ for the oxidation of materials with a wide composition range prior to cyanidation. The data will be compared to that obtained by direct cyanidation of the feed (without oxidation) and from the testing of pressure oxidation on the feed prior to cyanidation. Albion Process™ tests were conducted in Institute TOMS with participation of Glencore Technology Pty Ltd (Australia). Refractory concentrates obtained from the ores of several Russian and CIS deposits were used as feed for the testing. These concentrates were also subjected to a material composition study and testing using conventional recovery methods. The resulted test data make it possible to perform an integrated assessment of process properties for materials with different compositions, compare performance of various process flowsheets for the materials under study, and conclude on efficiency of Albion Process™ application for gold recovery from refractory materials different in their composition.INTRODUCTION It is often the case that gold ore concentrates are refractory to gold recovery by direct cyanidation. This refractory nature is as a rule attributable to fine gold dissemination in minerals, most often in pyrite and other sulphides, as well as to the increased amount of components impeding cyanide leaching of gold due to cyanide consumption and reducing process conditions. The refractoriness of the concentrates results in low gold recovery values when conventional cyanidation technology is used. In this context, various additional processes are applied to breakdown such refractory sulphide concentrates, i.e. mechanical breakdown (fine and ultrafine grinding), chemical breakdown (atmospheric oxidation, e.g. Leachox, acid-oxygen oxidation, pressure oxidation – POX, bacterial oxidation – BIOX), and thermochemical breakdown (various roasting methods). Such breakdown processes allow for increase in recovery of finely disseminated gold during the downstream cyanidation, however, their application is cost-intensive and does not always ensure economic benefit."

Jan 1, 2018

By K. Trybalski

Facing the optimization activities, which purpose is to minimize the copper processing costs, the main sources of their occurring were presented. In this purpose, the costs analysis was performed, divided to individual standings, for one of the polish copper beneficiation plants. It was proved, that the main component of the copper beneficiation costs is energy consumption, generated mainly in grinding and classification node, particularly by operating mills. The technological system ? grinding and classification node ? in KGHM Polska Miedz S.A., ZWR region Lubin was then selected to investigation. To evaluate the grinding and classification node, the energetic factors W were proposed, calculated on the basis of the energetic-technological data of process, given by node monitoring system. The correctness of the energetic factors selection to evaluate the work of this node and their practical application in industrial conditions was experimentally proved in other technological object. The selected technological object ? grinding and classification node ? was then mathematically modeled and optimized. The calculated energetic factors were the basis to build mathematical models, identifying industrial copper grinding and classification process. The models described correlation and character of dependency between factors and energetic-technical data of the process. These were regressive and neural networks models. On the basis of factors models, the optimization tasks were determined, which purpose was to select the optimal points of grinding and classification node work. Also, the estimated economical effect, possible to achieve after introduction of given monitoring values to grinding and classification node optimization system, was presented.

Jan 1, 2014

By Z. Hu

A complex polymetallic sulfide ore in Yunnan, China, has various valuable minerals, which are Chalcopyrite, Galena, Pyrite, Gold, Silver, and Magnetite. A reasonable new flowsheet with a bulk flotation and a flotation separation of sulfide minerals that are Chalcopyrite, Galena, and Pyrite was carried out at first stage. After that tailings were treated by low intensity magnetic separation to achieve magnetite concentrate. A high Pb concentrate assaying 60.00 percent Pb at total recovery of 75.71 percent with 40.50 g/t Au and 1390.00 g/t Ag, a final high Cu concentrate assaying 24.45 percent Cu at high recovery of 92.03 percent and a magnetite concentrate assaying 60.78 percent Fe at recovery of 33.61 percent with 18.45g/t Au and 234.99 g/t Ag, are obtained. The total recovery of Gold and Silver in Pb concentrate and Cu concentrate reached 71.63 percent and 67.32 percent, respectively. It is shown, that this new flowsheet could realize efficient recovery for all of the valuable minerals in the ore and is easy to be industrialized. Keywords: bulk flotation, magnetic separation, polymetallic sulfide ore, depressant

Sep 1, 2012

Micro-fine disseminated molybdenite was ground in a laboratory stirred mill using steel media and zirconium media respectively. The floatability of ground molybdenite and slurry chemistry was investigated. It was found that the total recovery of ground molybdenite using zirconium media was higher while the pH and Eh of the slurry are lower than that using steel media. When steel media was used, iron oxy-hydroxides had been generated coated on the surface of molybdenite, and decreased the floatability of molybdenite, especially of the -10µm particles. The iron and lead oxy-hydroxides was generated by the reaction between steel media with pyrite and galena associated with molybdenite. It was also found that changing the grinding media to inert can benefit the flotation of molybdenite. Keywords: stirred mill, grinding environment, floatability, micro-fine disseminated molybdenite, fine grinding

Sep 1, 2012

By H. G. Hedlund

Tailings in Mining Industry can be handled in different ways. Today tailings disposal is in focus by projecting new plants as well as treating and handling of old Tailings dams.The trend today is to process minerals, detoxify the Tailings and place them as dry surface Deposition or Underground Backfill. This paper will briefly present five different Mining plants in North and Central America, where Tailings have to be dewatered for dry depositing. The Metso-Sala VPA is a filter especially developed for dewatering and drying of Mineral Concentrate and Mineral Tailings. Keywords: tailings disposal, dewatering, drying, mineral tailings

Sep 1, 2012

By Gulsen Tozsin, Ekrem Kalkan, Taskin Oztas, Elif Agirman Akturk, Ercument Koc, Ali Ihsan Arol

Marble wastes are generated by quarries (marble quarry waste-MQW) and processing plants (marble cutting waste-MCW). The large amount of marble wastes is becoming serious problem for industry and environment because of discarded into rivers and lagoons, without any treatment. Marble wastes can cause environmental problem and economic loss if the waste is not used. However, this type of wastes has a good potential to be used as an amendment for the neutralization of acid soils. In this study, MQW and MCW were applied to an acid soil at different rates and their effectiveness on neutralization was evaluated by a laboratory incubation test. The results showed that soil pH increased from 4.71 to 6.36 and 6.84 by applications of MCW and MQW, respectively. It was suggested that MQW and MCW could be used as soil amendments for the neutralization of acid soils, and thus the negative impact of marble wastes on the environment could be reduced.

Jan 1, 2014

By S. Leroy

Grinding is the most energy consuming step in mineral processing, however, it is still poorly understood and its efficiency is difficult to monitor. Mill performances are traditionally measured at the mill discharge, on the basis of a mass percentage passing a certain sieve. This approach does not reflect what happens to the fines through milling. On another hand, if many macroscopic parameters, such as the percent solids of the pulp, its viscosity, or its mean residence time in the mill are known to be related to grinding efficiency, the link between these parameters and particle size distribution (PSD) is still unclear. Here, a methodology is established to understand the effect of ball mill operating conditions on particle size and shape distribution in the grinding process. The study focuses on the particular case of an Upper Group 2 (UG-2) platinum ore concentrator. Due to the very low grade of sulphide and PGM (Platinum group metals) in UG-2, grinding mechanisms are entirely control by gangue minerals. These two minerals have contrasted properties and PGM content and these properties immediately affect the entire recovery process. So, the grinding of both gangue minerals is studied on a size by size basis. At particle scale, three parameters are addressed: particle size, particle composition and particle shape. The specific behavior of chromite and silicate grains is demonstrated. As a conclusion, this study gives some clues to operate ball mills in a more efficient manner regarding chromite issue in the processing of UG-2. Keywords: ball milling control, UG-2, chromite, fine particle, particle shape, segregation

Sep 1, 2012

By M. Ghiani, R. Peretti, S. di Giovanni, G. Zonnedda, A. Serci, A. Zucca

"Beneficiation of the epithermal gold mineralizations associated with an extensive alteration zone in the Serrenti-Furtei region on the island of Sardinia, is proving a complex issue. Experimental investigations have in fact demonstrated that while the ores contained in the upper parts of the deposit are amenable to conventional cyanidation, the gold contained in the refractory ores in the lower portions needs to be recovered by means of flotation, combined with leaching where necessary.The results of commercial heap leaching, carbon-in-leach (CIL) processing and flotation, designed on the basis of the experimental findings and applied to the oxidized portions and transition zones of the deep sulphide mineralizations, confirmed the expectations emerging from the laboratory tests."

Jan 1, 2003

By Jun Xiao, Jianwen Yang, Yanhong Dong, Daixiong Chen

"MANGOTE Surface oxidizied mine is a gold-bearing deposit in Congo's Mai-Ndombe Province. In the past decades, the ore has been exploited in a crude way by local farmers, which directly causes the severe processing difficulty and lack of economy of cyanide leaching. Hunan Research Institute for Non-ferrous metals (HRIM) is currently investigating options to recover gold through understanding the mineralogical characteristics of MANGOTE surface oxidized ore. Chemical analysis , X-ray diffraction(XRD) and Quantitative Evaluation of Minerals by SCANing electron microscopy (QEMSCAN ) were conducted on samples from mine site. The bulk analysis results showed that gold separation of gold from gangue minerals was feasible after grinding the ore samples to 86.53% -74µm and adjusting the pulp specific weight at 100g/L, and gravity separation was conducted with using spiral chute after grading of fine particles. The research results highlight relationship between mineralogical characteristics of abandoned ore and economy of comprehensive utilization that might be directive experience to similar cases. INTRODUCTION The occurrence state of gold in natural gold minerals determines the basic recovery and recovery effect of gold(Komnitsas, C., & Pooley, F. D. 1989). The occurrence of gold in the ore refers to the form of gold in the ore.Generally the existing state of gold can be divided into four major categories according to the viewpoint of the dispersion system: independent minerals and gold, a coarse dispersed system;colloidal gold, a colloidal dispersion; solid solution gold, is atomic ion dispersion; adsorptive gold, according to the adsorbed particle is the micelle or ion, respectively is a colloidal dispersion or ion dispersion(Mao, S. D., & Yang, R. S. 2009; Liu, J. J. et al. 2007; Horisberger, M., & Rosset, J. 1977; Li, Y., & Audétat, A. 2013).With the increasing technology of comprehensive utilization of resources,varied plants can now process different gold ores with various occurrence states(Neesse, T. 2014; 7. Ogundare. et al.2014)."

Jan 1, 2018

By C. Igathinathane

Coal is the most widely used fossil fuel in the world, providing more than 25% of world?s electrical power. Since, the behavior of coal particles in crushing and grinding circuits, concentration operations, and solid-liquid separations is strongly dependent on size, a reliable and accurate measurement of particle size and particle size distribution (PSD) is a vital aspect in coal cleaning. This paper presents a method for the characterization of ground coal particles using image analysis. We utilized a machine vision (MV) approach that used a document scanner as the imaging device and a user-coded ImageJ plug-in that processed the image and automated the PSD analysis and output results in textual and graphical forms. This approach used a sum of volumes (SVolume) as weighting factor for particle length as the primary dimension of analysis and was successfully applied to ground coal. The plug-in was further improved for computational performance in this study. Mechanical sieving (MS) was also used to compare the MV results. MV results showed that the PSD of ground coal followed a uni-modal normal distribution, and the log-normal plot against particle size exhibited a linear trend for most of the range. MS results, however, had three linear segments, when the width-based sieving results were transformed to lengths by applying the shape factor (width/length), but a definite deviation between the PSD plots was observed. This study demonstrates successful application of the MV SVolume approach for PSD analysis of ground coal, which can be extended to similar particulate minerals and products. Keywords: dimension, fiji, image j, image analysis, coal, particle size, plug-in

Sep 1, 2012

By S. K. Sharma, R. Markandeya, G. Venkateswara

"In this study, a three level Box- Behnken factorial design combined with Response surface methodology (RSM) for modeling of process parameters of Multi Gravity Separator (MGS) for recovery Iron values from sub grade iron ore, Deposit No. 5, Bailadila complex has been developed. The three significant operational parameters of MGS, Drum rotational speed (RPM), Drum inclination (degrees) and quantity of wash water (LPM) were considered in the experimental work. Other parameters like feed percent solids, shake frequency and shake amplitude were maintained constant. The ‘as received’ sub grade iron ore sample is admixture of lump and fines and chemically assayed 40.80% Fe, 40.90% SiO2, 0.24% Al2O3 and 0.22% Loss on Ignition (LOI). The obtained results were evaluated with the Box-Behnken factorial design, RSM and also Quadratic programming(QP). Second order response functions were produced for Fe in terms of grade (%) and recovery (%) of the concentrate fraction. Taking advantage of QP, it was observed that maximum grade of 62.21% Fe achieved at an inclination of 4.3degrees, 2.7LPM of wash water and at a drum speed of 198 RPM. Similarly a maximum Fe recovery of 65.37% weight can be achieved at 4.3degrees inclination, 2.6LPM wash water and at a rotational speed of 212 RPM Predicted values of responses obtained using model equations were in good agreement with the experimental values. The influence of the process variables of the multi gravity separator concentrator on grade and recovery of concentrate fraction were presented and discussed."

Jan 1, 2014

By Z. C. Zhen

Basing on character of fine ores, and employing all the advantage of dissolved-air flotation, the study within the dissertation put forth the methods of superfine metal mineral flotation with dissolved-air flotation equipment, and constructed a full set of laboratory flotation system. Experiments both in water and in slurry were respectively carried out by means of this flotation equipment. Further study was also fulfilled on mechanism of air-dissolved released devices, and the key components of system including ejector, releaser and saturator were designed. Optimizing devices parameters were chosen by taking ideal performance of the devices into consideration, according to orthogonal experiments and tests on bubbles factors, those performance factors were called air release rate, air release efficiency. The results with some minerals are better than JJF flotation machine with 30 litres bulk. The Dissolved-air Flotation(DAF) machine shows great potentiality in treating super-fine metal mineral concentration. The research indicates the Dissolved-air Flotation(DAF) system has superiority over mechanical flotation machine in fine flotation. Air-dissolved released bubbles appear on the surface of hydrophobic minerals in priority, solving collision probability less in the tradition fine mineral separation, such that the metallurgy technology of fine metallic minerals are improved. The exploratory research is a foundation for industrial pilot, commercial test and equipment maturity in the future.

Jan 1, 2014

By Xin Tan

In this paper, two types of low-grade complex zinc oxide ores (sandstone and limestone ores) from Yunnan province, China were investigated. A large number of argillaceous and alkaline gangue makes it infeasible to treat the ores with heap leaching. Although wet metallurgy can be considered, the lower efficiency of liquid-solid separation, the high cost, and low revenue limit this technology to be put into practice in large-scale. In order to solve this problem, a new technology combining mineral processing method with metallurgy technique is studied to process this refractory ore that consists of sandstone ore with 5.84 per centZn and limestone ore with 6.50 per centZn. The results of the tests showed that zinc can effectively be recovered from two types of the ores by using the new technology, and the acid consumption can be remarkably reduced. For sandstone sample, 82.96 per cent Zn was recovered by flotation and final Zn recovery by flotation+ hydro-metallurgy can be up to 78.17 per cent from the ore. In addition, for sandstone, acid consumption can be reduced from 270kg/t by direct acid, leaching to 76.92kg/t by flotation + hydrometallurgy combination. For limestone sample, 85.90 per centZn was recovered by flotation and totally 80.95 per cent Zn can be recovered by new technology which is a combination of mineral processing and metallurgy. Besides, H2SO4 consumption can be reduced from 450kg/t for sandstone originally to113.79kg/t after using new technology. One merit of this new process technology is that the zinc sulfides and oxides can be recovered without desliming in the flotation cells at the different stage and make sure the concentrate products as a good feed for hydrometallurgical technology. This study provided pretty good technical support for tapping low-grade refractory zinc oxide ores. Keywords: low-grade zinc oxide ores, limonite, non-desliming beneficiation, flotation + hydrometallurgy combination

Sep 1, 2012