Search Documents

By Gábor Mucsi, Barnabás Csoke, Viktor Mádai, Zoltán Molnár, Viktor Török, Ádám Rácz

The application of the stirred media mill in dry mode came to the front only in recent years, but at the same time several questions arise, such as aggregation, agglomeration, sticking on the liners and the grinding media. During high energy milling, not only the particle size reduces, but among others, in numerous cases the crystal structure and the amorphous state of the material also change due to the mechanical activation taking place. The present paper deals with experiments carried out on the ultrafine fly ash grinding in dry mode at various grinding conditions in a stirred media mill to investigate the mechanochemical effect and the energy efficiency of the mill. During the experiments the particle size distribution, particle shape, specific surface area, amorphity and crystal structure of the products were examined. The product related stress model was used for the evaluation of the effect of milling parameters on the mechanical activation. It was found, based on the experimental results, that there is mechanochemical effect on crystal structure of fly ash in the stirred media mill, as it was revealed by X-ray diffraction and FTIR measurements. The experimental results made it possible to determine the effect of the rotor circumferential speed and so the stress intensity on the mechanical activation of fly ash could be revealed.

Jan 1, 2014

By J. J. Lui

Surfactant plays a critical role in many industrial processes such as petroleum, mining, environment and food processing, and daily life. For ionic surfactant systems, adsorption of surfactant at oil-water interface imposes a net charge to the interface. The nature and magnitude of the charges at the oil-water interface depend on charge characteristics of surfactant molecules, concentration of surfactant and solution pH. In our previous study, zeta potential measurement of hexadecane drop-lets in industrial process water was shown to be a simple, yet powerful method for identifying various types of ionic surfactants present in the aqueous system. In this paper, the site-binding model was applied to prediction of zeta potential of oil droplets in aqueous solutions containing a mixture of cationic and anionic surfactant molecules. The total number of interfacial sites for various types of surfactant involved was determined by applying the Gibbs adsorption equation to the measured interfacial tension-surfactant concentration profiles. The distribution of various types of surfactant molecules at the interfaces was evaluated by Langmuir isotherm constants. With the ionization constant of surfactant taken from the literature, the predicted zeta potentials of oil droplets in surfactant solutions from site binding model were shown in a reasonable agreement with the measured zeta potential values.

Jan 1, 2014

By Marco Le Roux, Martha Van Rensburg, Quentin Campbell

Fluidised bed drying is currently receiving much attention as a dewatering option during the beneficiation of fine (defined here as between 1 mm and 2 mm particles) coal. Apart from concerns about safety and combustion, the operating costs can be high if very high gas or air temperatures are used. The aim of this study was to investigate the removal of moisture from fine coal by using air at a lower temperature (25 - 55°C) within a controlled environment by lowering of the relative humidity of the air. It was firstly proven that fluidization has a major advantage over non-fluidized beds, with regards to drying rate and final moisture content. Hereafter several parameters that influence the dewatering rate and final moisture content were tested, from which it was concluded that the relative humidity of air acts as the largest driving force for dewatering. Parameters tested included relative humidity, temperature and coal composition. Energy balances showed a positive nett energy increase in the dried coal during combustion when related to the energy input during drying. In comparison with thermal drying technologies, fluidized bed drying was proven to be less energy intensive. It was therefore shown that this is a viable technology for the dewatering of fine coal.

Jan 1, 2014

By Seungwoo Park, Gaurav Soni, Roe-Hoan Yoon, Hyunsun Do, Kaiwu Huang

In a flotation froth (and foam), air bubbles become larger due to coalescence, causing bubble size to increase, bubble surface area to decrease, and hence casing less hydrophobic particles to drop off to the pulp phase below. Thus, bubble coarsening provides an important mechanism by which product grades are increased. On the other hand, excessive bubble coarsening results in low recoveries. In the present work, a model describing the process of bubbles becoming coarser in a foam as they rise to the top by deriving a mathematical relation between the Plateau border area, which controls film drainage rate, and the lamella film thickness, which controls bubble-coalescence rate. The model has been derived by assuming that liquid drainage rate increases due to slip at the air/water interface, and that the critical rupture thickness is determined by the capillary waves created by thermal motion. The model developed in the present work can predict the bubble size ratio between the top and bottom of a foam as functions of aeration rate, foam height, and surface tension (frother dosage). The model predictions are in good agreement with the changes in bubble sizes measured using a high-speed camera.

Jan 1, 2014

By Y. Lin

It is difficult to remove arsenic and bismuth from antimony in the process of crude electro refining. The electro refining of antimony has been studied using ammonium fluoride-antimony sulphate electrolyte system. The Influence of temperature, current density and additives on arsenic and bismuth removal from crude antimony has been investigated in this paper. Optimum process parameters, namely, temperature of 25?, current density of 400A/m2, distance between anode and cathode of 50mm, electrolytic period of 24 hours, oxalic acid dosage of 10g/L and complexon III dosage of 0.2 g/L have been ascertained.

Jan 1, 2014

By Paul W. Cleary

"DEM application in mineral processing has for many years been heavily focused on simulating mills of various types. This method can be used to simulate many other aspects of mineral processing operations and can be used both to enhance understanding of the underlying flows and of issues such a breakage, wear, blockage, product degradation, segregation and mixing. The application of DEM to four important classes of non-comminution problems and equipment commonly found in or near mineral processing plants are described. These are:- Particle transport (examples include a conveyor belt and an inclined screw conveyor)- Sampling (assessment of sample bias for cross-stream samplers)- Separation (the efficiency of vibrating screens)- Storage and reclaim (discharge from a multi-port hopper and segregation in a splitter bin with asymmetric ingoing and outgoing conveyor belts, apron feeders and impact plate)."

Jan 1, 2003

By Mohsen Hashemzadehfini

Nowadays heap leaching has become established as a mineral processing technology for treatment of some low grade minerals such as copper, gold, and zinc, etc. Heap height, particle size, leach reagent consumption, and metal recovery are four important metallurgical parameters in a hydrometallurgical process like heap leaching. This paper investigated the effects of heap height and particle size on copper recovery as well as acid consumption. Three heap heights of 2, 4 and 6 meters and two particle size fractions of less than 25.4 mm and 50.8 mm were selected as variables in the experiments. The research results showed the inverse relation between heap height and copper recovery as well as acid consumption. Under given conditions, the copper recoveries of minus 25.4 mm ore are 78.63%, 66.27% and 52.88% higher than that of minus 50.8 mm samples for the heap heights of 2, 4, and 6 m, respectively. Both copper recovery and acid consumption increase with decreasing particle size. Keywords: heap leaching, heap height, particle size, acid consumption

Sep 1, 2012

By Sami Makni, Ahmed Bouajila

"To remain competitive in an open market, mining companies are more and more requested to optimise their complex and highly multivariate processes. The increasing amount of process data, brought about by intensive use of instrumentation and the progress in computer data acquisition, enhances the need for more and more powerful and robust tools for the analysis and modelling of the process data. Now, with the emergence of multivariate data analysis (MDA) techniques, on-line clustering of mineral process behaviour is possible and could help in the extraction of valuable process operation indicators. MDA can be used in different mineral processes such as flotation, grinding, smelting etc.In this paper, we focus on grinding process considered as the most costly and power consuming node of the mineral processing scheme. Different objective-oriented levels of data clustering will be addressed.First, the evaluation of grinding operation taking into account data and constraints from all processes before (e.g. blasting, crushing) and after (e.g. flotation, leaching, etc.) the grinding node. The second level deals with process diagnosis by differentiating operation level and identifying behaviour drifts. Control and optimisation are two other levels concerned here with the selection of optimum trajectories in the drift correct.Industrial plant data are processed in order to illustrate the feasibility and the potentiality of MDA applications in addressing the clustering and interpretation of grinding mill behaviour."

Jan 1, 2003

Three high-grade limestone ores (CaO content over than 53 %) with different geological origin have been characterized for the synthesis of aragonite precipitated calcium carbonate. Limestone ores examined in this study showed different crystal particle size that cause difference in disintegration degree and surface area of the synthesized slaked limes. The limestone ore with smaller crystal particle size showed higher disintegration degree and also yielded slaked lime with smaller surface area, which is good for the synthesis of aragonite precipitated calcium carbonate. The synthesis of aragonite PCC using the limestone with a small crystal particle size was yielded needle-shaped aragonite with the aspect ratio of about 14. Keywords: limestone, lime, slaked lime, precipitated calcium carbonate, aragonite, accelerated carbonation

Sep 1, 2012

By D. Kosior

Influence of frothers (a-terpineol and n-octanol) concentration on kinetics of a three phase contact (TPC) formation by a bubble colliding with a hydrophobic surface (Teflon) of different roughness was studied using a high-speed camera (1040 frames per second). It was found that the Teflon surface roughness and the frother concentration strongly affected time of the TPC formation (tTPC) and time of drainage (tD) of the liquid film separating the colliding bubble from the solid surfaces. With increasing Teflon surface roughness, from ca 1 to 80 µm, the time of the TPC formation was shortened by over the order of magnitude, from ca 100 to a few milliseconds only. At low a-terpineol and n-octanol concentrations, thetTPC values were shorter than in distilled water due to lowering the bubble velocity in the frother presence and diminished bouncing of the colliding bubble. However, at high frothers concentrations the tTPC values were prolonged, despite that the bubble velocity was similar. The prolongation of the tTPC at high frother concentrations indicates that air (micro- and/or nano-bubbles) was present at the Teflon surfaces of different roughness. The mechanism of the tTPCprolongation at high frother dosage is described.

Sep 1, 2012

By Xubo Chen, Zhiqiang Hu, Zhijian Sun, Gaoyun Zhou

"The research aimed at developing an efficient and environmental frother,which was applied in the flotation of sulfide ores. The flotation properties of an efficient frother and pine oil have been studied relatively by flotation tests of lead and zinc sulfide ores. At the same time, the biodegradability of two kinds of frother has been studied by the method of biological respiratory curve. The test results show that the flotation properties of new frother are superior to pine oil such as flotation rate, dosage etc. and its biodegradability is superior to pine oil. INTRODUCTION Frother is a kind of important agent in flotation reagents.In practice, the criterion of the foaming performance of the frother is what is high and low according to flotation indexes. The difference of different minerals and flotation technologies has great influence on the foaming performance of frother, and it is very important to choose the corresponding frother. The type, dosage and selectivity of frother in flotation process must be considered carefully. In today's society, environmental protection and ecological protection are becoming more and more important, and the environmental and ecological damage from mine development has aroused increasingly more attention. The use of mine agents has promoted the development of mineral resources, greatly improves the recovering utilization of mineral resources, at the same time, the production and use of mine reagents also inevitably bring about pollution, and result some influence or damage in the ecological environment.The frother is a common kind of reagent in the flotation process of the concentrator. In many cases, the waste water in the concentrator can not be let out in the natural water because the higher content of the frother in the waste water results in higher index of COD.This will inevitably increase the cost of waste water treatment in the mine.Therefore, the choice of frother should not only consider its influence on the flotation index, but also consider its influence on environmental protection. Waste water treatment is a way to solve the waste water pollution, but it needs to cost a lot of fund, manpower and material resources.And the development of high efficiency pollution-free reagent is a good way to reduce the production cost of mining enterprises and reduce the environmental pollution."

Jan 1, 2018

By Hugo Barrientos

"The growing need to optimize the mining processes produces a need for users to have a simple, reliable, secure and cost-effective method to monitor the values of the variables measured in field. The solutions described in this paper, we will demonstrate how the implementation of Emerson Smart Wireless technology helps to optimize the leaching and electro winning processes. An effective monitoring of the variables involved in the operation of a heap leach, such as pressure, flow rate, pH, water level control and regulator valves can improve production and optimize the use of sulfuric acid, which results in a more effective management of resources and helps reducing input costs. Moreover, the constant monitoring of variables prevents the risk of landslides, reducing maintenance costs. In electro winning cells, the wireless solution measures variables such as pressure, flow rate, temperature and voltage provides a performance indicator for the entire operation, capable of detecting and predicting shorts, and monitoring the overall functioning of a cell or group of cells. As a result of the applications studied, users can monitor variables in real time, optimizing the use of resources, quickly detecting possible flaws in the process and reducing the risks in the operation. All these factors have a direct impact on company results."

Jan 1, 2014

By Khoi Nguyen, Luke Keeney

"Hardness" is an important yet diverse material physical property and is a key parameter in the mining industry in fields such as comminution, geotechnical and blast modelling. Several laboratory and field based measurement techniques exist to measure hardness (e.g. Point Load Testing, Vickers, Brinell, A*b, BMWi, UCS), all are designed for specific applications. Current tests are generally destructive and require specific sample preparation procedures which results in high cost tests that are not conducted in adequate quantities to map hardness across an ore body. The EQUOtip rebound hardness tester is a device that has been developed for application in ore body hardness domaining within the AMIRA P843 GeMIII Research Project. The rebound hardness test is non-destructive and suitable for application on half and whole diamond drill core. Data acquisition protocols and a data processing software application (EQProcess) have been developed to facilitate routine collection of comparative hardness information. This paper outlines the data acquisition and processing methodology and provides application examples of defining relative hardness domains in different geological deposit styles.

Jan 1, 2014

By F. C. Yi

Discontinuous and consecutive process was applied to probe into the Kinetics and adsorption theory for Cs+ adsorbed by Zeolites under the conditions of temperature, time and fixed-bed dynamic adsorption. It indicated that the sorption kinetics behavior of zeolite?s sorption on Cs+ is ac-cord with pseudo-secondary velocity equation, velocity constant k2=0.0005213 g?mg min-1, and equilibrium adsorptive capacity is 147.0588 mg?g-1; The equation can be expressed as: Y=0.0068X+0.0887; From the analyzing of diffusion coefficients on different temperatures and times, the coefficient of diffusion is not only related with the fabric of mineral and the character of ions but also the temperature and time; When the ambient temperature hoisted, the diffusion velocity augmented rapidly; Cs+ would get over a certain energy barrier when it enters into structure of zeo-lite; This energy is expressed by activation energy, and its value is E=131.668818 kJ?mol-1; There are two dominating adsorption mechanisms in the system of zeolite absorb Cs+: ionic interchange and surface coordinate adsorption.

Jan 1, 2014

By S. M. Saghaeian

The studies on the product finer than 12 mm due to crushing and sizing plant of Gol-e-Gohar Iron Ore mine showed which this material contains significant amount of valuable iron minerals. Based on the carried out experimental studies on representative samples of fine hematite iron ore, a processing flow sheet was designed to upgrade iron content. This plant is known as first hematite iron ore enrichment plant in Iran which the dry medium intensity magnetic separators (with magnetic field intensity 4500 gauss and high gradient) has been used. The main objective of the plant is production of high iron product with iron content more than 61% and weight recovery more than 55% from the feed with iron content of 54%. In this plant, at first material are screened by a single deck screen (6mm), then oversize particles is separated at one stage by magnetic separator, while undersize ones at two stages. Based on the results of experimental tests, a final high iron product with iron content of 62.4% and weight recovery 63.9% can be achieved. It should mention which the iron content can be enhanced through increasing the speed of magnetic separators especially at the part of separation of finer iron ore.

Jan 1, 2014

By E. A. Brocchi

This work is dedicated to the chemical treatment of a typical EAF dust by chlorine content agents. The residue contains 48% Fe2O3 and 28% ZnO mainly in the franklinite structural form. The others less compounds are: 4.00% CaO, 2.60% MnO, 2.20% MgO, 1.08% PbO, 0.36% Cr2O3, 0.21% B2O3, 0.03% CdO and 0.01% NiO. The experiments purpose is selectively to remove zinc from the residue leaving the iron behind. Thermodynamics studies have indicated some roasting possibilities. The experimental results have shown that both HCl leaching and carbochlorination will remove iron and zinc without any selectivity. However, either the chlorine or the calcium chloride roasting seems to form, preferentially, the zinc chloride. So, it will be presented how the EAF Dust can be treated by the using of chlorine roastings process such as carbochlorination in order to separate the zinc and iron present in the frankilinite, main EAF dust content.

Jan 1, 2014

By Carlos Pereira, Fábio de São José, Francielle Nogueira

Votorantim Metals Corporation is one of the leader companies in the extraction of zinc in Brazil. One of its mines, located in the city of Vazante - MG, was composed by zinc silicate ores, but recent studies have indicated a change in mineralization type with arise of zinc sulphide’s ore bodies with disseminations of galena (PbS) and silver. The liberation size between sphalerite and galena in this ore occurs in very fine granulometry (approximately 18µm), fact that has negatively influenced into the flotation process. Aiming to reduce this problem, studies about the use of dispersing in the flotation process have started. Thus, this study investigated the action of different reagents dispersing on the stability of the suspensions. The tests were carried out with samples of mineral galena and sphalerite using four types of dispersing within two different dosages and two pH. The reagents tested were sodium hexametaphosphate, sodium silicate, carboxymethiylcellulose, and sodium polyacrylate. The results of the dispersion tests were analysed in relation to dispersion index. The tests with hexametaphosphate showed high dispersion for both galena and sphalerite. The sodium polyacrylate and arboxymethiylcellulose showed a high dispersion index for galena and a low index for sphalerite implying that reagent can be used in the concentration process of galena.

Jan 1, 2014

By Rod Hocking, Nenad Djordjevic, Randolph Pax

"Semi Autogenous (SAG) mills exhibit complex interactions between the competing processes occurring inside them. Traditional practice is to measure the operation of the SAG mill at an operating point in terms of its load, power draw, steel load, ore throughput rate, water addition rate and more recently the feed size distribution. However significant departures of operating conditions can occur due to changes, for example, in ore hardness, the quest for higher throughputs and mill internal geometry.Fundamental to SAG mill operation are the internal processes that ensure that a given ore throughput and discharge grind size are obtained and maintained. These processes can be measured using non-contact acoustic emissions from the SAG mills which utilise the information rich noise that is generated by the grinding, flow and charge movement inside a mill.Non-contact acoustic in-mill measurements can be used for the validation of discrete element modelling (DEM). The approach being reported in this paper is to model the individual physical processes and then to simulated the assemblage of a physical mill."

Jan 1, 2003

By H. Palza, C. Ihle, S. Contreras

"Processing of minerals, particularly treatment of tailings, has been increasingly challenged by the presence of clays in the feed of thickeners. This occurrence is expected to become increasingly important given the nature of ore deposits currently being exploited and those that have been recently discovered. In sedimentation operations (solid-liquid separation), industrial flocculants often fail to coagulate clay-containing fines, generating supernatants with high levels of turbidity, thus implying operational problems. Recently, it has been reported that graphene oxide (GO), a graphite derivative with high oxygen-containing groups, could enhance the flocculation of clay systems, due to the interaction between clays and GO functional groups. In the present work, we investigated the effect of doping industrial flocculants (commercial polyacrylamide) with GO on the floculation of kaolinite suspensions in a solid-liquid separation stage. Separation performance was evaluated by studying flocculation kinetics using a focused beam reflectance measurement (FBRM) instrument, in a set of batch tests. A statistical analysis of the flocculation kinetics and floc population distribution was further carried out. Our results suggest the existence of a synergistic effect between the studied flocculants and GO. This effect is observed as a decrease of clay fine contents in the supernatant, thus improving solid-liquid separation eficiency for high clay containing tailings. INTRODUCTION Copper, given its mechanical, physical and chemical characteristics, is a critical material for the progress of society and so has been from early stages of mankind. Demand for this metal has increased due to the growth of cities and the technological explosion, leading to increase current mining production and reinforce the efforts in exploration for new deposits (Elshkaki et al. 2016). As copper-rich deposits are being depleted, it has been necessary to develop proper technology to mine deposits of lower grades and more complex mineralogies, keeping in mind that the economic window that allows the exploitation of them is reduced by the increase on operating costs (Crowson 2012 and Northey et al. 2014). High clay bearing minerals are found in many of those low-grade copper deposits, and they induce problems in all stages of the mineral processing route (Taner and Onen 2016). Particularly, in the solid-liquid separation stage, the flocculation process fails to remove the clay fraction from suspension and it leads to operational issues such as filter damage, overconsumption of reagents and the need to add an extra clarifying step for the recovered process water. Those problematics pose an interesting challenge."

Jan 1, 2018

By Di Liu, Yongjun Peng

"It was identified that clay minerals adversely affect fine coal flotation through slime coatings. In the study, it was interesting to find that an anionic polymer dispersant, lignosulfonate, successfully mitigated the negative effect of clay minerals in coal flotation using fresh water, but in saline water, it exacerbated coal flotation.In order to understand the mechanisms underpinning the different behaviour of lignosulfonate in coal flotation using fresh and saline water, the adsorption isotherm, and dynamic light scattering (DLS) measurements were conducted in this study. While DLS monitored the molecular conformation change (swelling or shrinking) of the polymer in fresh and saline water, adsorption isotherms enabled polymer adsorbed amount on clay and coal mineral surfaces to be determined. It was found that lignosulfonate adsorbed on the coal and clay mineral surfaces providing effective electrostatic repulsions and resulting in a mitigation of clay minerals from coal surfaces in deionised water. In the presence of saline water, however, polymer molecular conformation changed. Polymer molecules were compressed and adsorbed in form of aggregates. The adsorption amount of lignosulfonate on clay minerals increased in saline water. A low dosage of lignosulfonate could not provide sufficient electrosteric repulsion to disperse clay minerals. Moreover, the high adsorption amount of the polymer on coal and clay surfaces led to a more hydrophilic coal surface, and coal flotation was therefore depressed in saline water. This study provides a new insight into understanding the role of anionic polymeric dispersants in mineral flotation using different quality water."

Jan 1, 2014